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ES458109A1 - Procedimiento de transformacion de un ester de acido quiral. - Google Patents

Procedimiento de transformacion de un ester de acido quiral.

Info

Publication number
ES458109A1
ES458109A1 ES458109A ES458109A ES458109A1 ES 458109 A1 ES458109 A1 ES 458109A1 ES 458109 A ES458109 A ES 458109A ES 458109 A ES458109 A ES 458109A ES 458109 A1 ES458109 A1 ES 458109A1
Authority
ES
Spain
Prior art keywords
alcohol
ester
chiral
racemic
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES458109A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanofi Aventis France
Original Assignee
Roussel Uclaf SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roussel Uclaf SA filed Critical Roussel Uclaf SA
Publication of ES458109A1 publication Critical patent/ES458109A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B55/00—Racemisation; Complete or partial inversion
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/53—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and hydroxy groups bound to the carbon skeleton

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Procedimiento de transformación de un éster de ácido quiral (A) con un alcohol alpha-ciano-3-fenoxibencílico (B), óptimamente activo de estructura (R) o de estructura (S), de fórmula: *** ver imagen 01 o de una mezcla del éster del ácido quiral (A), del alcohol (B), de estructura (R), y de un éster del ácido quiral (A) del alcohol (B), de estructura (S), en proporciones no equimoleculares, en un éster del ácido quiral (A) del alcohol (B), de estructura racémica (R, S), caracterizado porque se somete un éster del ácido quiral (A) de un alcohol (B) óptimamente activo de estructura (R) o de estructura (S), o la mezcla de ésteres del alcohol de estructura (R), del éster del alcohol de estructura (S) en proporciones no equimoleculares.
ES458109A 1976-04-23 1977-04-22 Procedimiento de transformacion de un ester de acido quiral. Expired ES458109A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7612093A FR2348901A1 (fr) 1976-04-23 1976-04-23 Procede de transformation d'un ester d'acide chiral d'alcool secondaire alpha-cyane optiquement actif en ester d'acide chiral d'alcool secondaire alpha-cyane racemique

Publications (1)

Publication Number Publication Date
ES458109A1 true ES458109A1 (es) 1978-03-16

Family

ID=9172255

Family Applications (1)

Application Number Title Priority Date Filing Date
ES458109A Expired ES458109A1 (es) 1976-04-23 1977-04-22 Procedimiento de transformacion de un ester de acido quiral.

Country Status (18)

Country Link
US (1) US4151195A (es)
JP (1) JPS52148047A (es)
AU (1) AU510903B2 (es)
BE (1) BE853866A (es)
CA (1) CA1078864A (es)
CH (1) CH620890A5 (es)
DE (1) DE2718038C2 (es)
DK (1) DK171105B1 (es)
ES (1) ES458109A1 (es)
FR (1) FR2348901A1 (es)
GB (1) GB1582594A (es)
IE (1) IE45383B1 (es)
IT (1) IT1082199B (es)
LU (1) LU77185A1 (es)
NL (1) NL179280C (es)
SE (1) SE446725B (es)
SU (1) SU1200848A3 (es)
ZA (1) ZA772465B (es)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1599876A (en) * 1977-06-13 1981-10-07 Shell Int Research Conversion of a stereoisomer into its diastereoisomer
CH635563A5 (fr) 1977-07-07 1983-04-15 Sumitomo Chemical Co Procede pour la preparation d'un alpha-cyano-3-phenoxybenzyle optiquement actif.
CA1215717A (en) * 1977-09-26 1986-12-23 Samuel B. Soloway Process for converting a stereoisomeric ester into its diastereoisomer
JPS54103831A (en) * 1978-01-27 1979-08-15 Sumitomo Chem Co Ltd Separation of stereoisomers of higher active cyanoo33 phenoxybenzyl 22*44chlorophenyl**isovalerate
ZA7911B (en) * 1978-01-31 1980-01-30 Roussel Uclaf Optically-active substituted benzyl alcohol and process for preparing it
GB2044264B (en) * 1979-03-08 1983-05-05 Kuraray Co Racemic modification of cyclopropanecarboxylate
US4261921A (en) * 1979-06-06 1981-04-14 Fmc Corporation Process for preparation of a crystalline insecticidal pyrethroid enantiomer pair
US4308279A (en) * 1979-06-06 1981-12-29 Fmc Corporation Crystalline, insecticidal pyrethroid
JPS5657756A (en) * 1979-10-15 1981-05-20 Sumitomo Chem Co Ltd Preparation of more highly active carboxylic ester
CA1150301A (en) * 1979-11-27 1983-07-19 Michael J. Bull Cyclopropane carboxylic acid ester derivatives
US4260633A (en) * 1980-04-21 1981-04-07 Zoecon Corporation Pesticidal esters of amino acids
CA1150730A (en) * 1980-04-23 1983-07-26 Michael J. Bull Process for preparing cyclopropane carboxylic acid ester derivatives
CA1162560A (en) 1980-04-23 1984-02-21 Ronald F. Mason Process for preparing cyclopropane carboxylic acid ester derivatives
EP0291626A3 (en) 1982-11-22 1989-05-31 E.I. Du Pont De Nemours And Company Process for the preparation of optically-active cyanomethyl esters
DE3401483A1 (de) * 1984-01-18 1985-07-25 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung bestimmter enantiomerenpaare von permethrinsaeure-(alpha)-cyano-3-phenoxy-4-fluor-benzyl-ester
GB2187385A (en) * 1986-03-07 1987-09-09 Shell Int Research Method of combatting colorado beetles using chemical compounds and compositions containing the chemical compounds
GB9127355D0 (en) * 1991-12-24 1992-02-19 Ici Plc Isomerisation process
WO1993012695A1 (fr) * 1991-12-31 1993-07-08 Hiroshi Kashima Canape-lit
US6262278B1 (en) 1995-03-14 2001-07-17 President And Fellows Of Harvard College Stereoselective ring opening reactions
US5665890A (en) * 1995-03-14 1997-09-09 President And Fellows Of Harvard College Stereoselective ring opening reactions
US7320829B2 (en) * 1998-03-05 2008-01-22 Omnova Solutions Inc. Fluorinated polymer and amine resin compositions and products formed therefrom

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3046299A (en) * 1958-07-28 1962-07-24 Rhone Poulenc Sa Process for the preparation of cyclopropane-carboxylic acids of transform
GB1005722A (en) * 1963-04-23 1965-09-29 Sumitomo Chemical Co Process for producing trans-chrysanthemic acid esters
FR2036088A5 (es) * 1969-03-04 1970-12-24 Roussel Uclaf
SE366022B (es) * 1969-03-24 1974-04-08 Sumitomo Chemical Co
US3906026A (en) * 1972-05-16 1975-09-16 Sumitomo Chemical Co Process for preparing alkyl trans-chrysanthemate
DE2326077C2 (de) * 1972-05-25 1985-12-12 National Research Development Corp., London Ungesättigte Cyclopropancarbonsäuren und deren Derivate, deren Herstellung und diese enthaltende Insektizide
FR2240914A2 (en) 1973-08-15 1975-03-14 Nat Res Dev Insecticidal stereoisomeric esters - of 2,2-dimethyl-3-(2,2-di-halovinyl) cyclopropane carboxylic acid which are very toxic to houseflies
JPS525738A (en) * 1975-06-27 1977-01-17 Sumitomo Chem Co Ltd Process for racemization of optically active 2,2-dimethyl-3-(2,2-dichl orovinyl)-cyclopropanecarboxylic acid and its derivatives

Also Published As

Publication number Publication date
BE853866A (fr) 1977-10-24
DK176977A (da) 1977-10-24
AU2458577A (en) 1978-11-02
IE45383B1 (en) 1982-08-11
FR2348901A1 (fr) 1977-11-18
NL179280C (nl) 1986-08-18
CA1078864A (fr) 1980-06-03
SE446725B (sv) 1986-10-06
DK171105B1 (da) 1996-06-10
JPS52148047A (en) 1977-12-08
SU1200848A3 (ru) 1985-12-23
FR2348901B1 (es) 1983-01-28
DE2718038C2 (de) 1984-06-07
NL7704520A (nl) 1977-10-25
AU510903B2 (en) 1980-07-17
DE2718038A1 (de) 1977-11-17
IE45383L (en) 1977-10-23
NL179280B (nl) 1986-03-17
LU77185A1 (es) 1977-11-22
GB1582594A (en) 1981-01-14
CH620890A5 (es) 1980-12-31
US4151195A (en) 1979-04-24
JPS6127384B2 (es) 1986-06-25
ZA772465B (en) 1978-06-28
IT1082199B (it) 1985-05-21
SE7704517L (sv) 1977-10-24

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Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 19990201