ES439036A1 - Metodo para formar una capa metalica sobre la superficie de un cuerpo de polimero de poliimida. - Google Patents
Metodo para formar una capa metalica sobre la superficie de un cuerpo de polimero de poliimida.Info
- Publication number
- ES439036A1 ES439036A1 ES439036A ES439036A ES439036A1 ES 439036 A1 ES439036 A1 ES 439036A1 ES 439036 A ES439036 A ES 439036A ES 439036 A ES439036 A ES 439036A ES 439036 A1 ES439036 A1 ES 439036A1
- Authority
- ES
- Spain
- Prior art keywords
- forming
- metallic layer
- polyimide polymer
- polymer body
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/38—Improvement of the adhesion between the insulating substrate and the metal
- H05K3/381—Improvement of the adhesion between the insulating substrate and the metal by special treatment of the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K13/00—Etching, surface-brightening or pickling compositions
- C09K13/02—Etching, surface-brightening or pickling compositions containing an alkali metal hydroxide
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1603—Process or apparatus coating on selected surface areas
- C23C18/1607—Process or apparatus coating on selected surface areas by direct patterning
- C23C18/1608—Process or apparatus coating on selected surface areas by direct patterning from pretreatment step, i.e. selective pre-treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1603—Process or apparatus coating on selected surface areas
- C23C18/1607—Process or apparatus coating on selected surface areas by direct patterning
- C23C18/1612—Process or apparatus coating on selected surface areas by direct patterning through irradiation means
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
- C23C18/2006—Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30
- C23C18/2046—Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30 by chemical pretreatment
- C23C18/2073—Multistep pretreatment
- C23C18/2086—Multistep pretreatment with use of organic or inorganic compounds other than metals, first
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
- C23C18/28—Sensitising or activating
- C23C18/285—Sensitising or activating with tin based compound or composition
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
- C23C18/28—Sensitising or activating
- C23C18/30—Activating or accelerating or sensitising with palladium or other noble metal
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Chemically Coating (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US48541074A | 1974-07-03 | 1974-07-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES439036A1 true ES439036A1 (es) | 1977-02-01 |
Family
ID=23928053
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES439036A Expired ES439036A1 (es) | 1974-07-03 | 1975-07-01 | Metodo para formar una capa metalica sobre la superficie de un cuerpo de polimero de poliimida. |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US4112139A (es) |
| JP (1) | JPS5119067A (es) |
| BR (1) | BR7504107A (es) |
| CA (1) | CA1053994A (es) |
| DE (1) | DE2529571A1 (es) |
| ES (1) | ES439036A1 (es) |
| FR (1) | FR2277114A1 (es) |
| GB (1) | GB1497620A (es) |
| IT (1) | IT1039133B (es) |
Families Citing this family (64)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5349071A (en) * | 1976-10-15 | 1978-05-04 | Hitachi Ltd | Selective etching of polyimide system film |
| US4261800A (en) * | 1977-08-15 | 1981-04-14 | Western Electric Co., Inc. | Method of selectively depositing a metal on a surface of a substrate |
| JPS6054906B2 (ja) * | 1978-01-31 | 1985-12-02 | 財団法人特殊無機材料研究所 | セラミツクス焼結成形体の製造法 |
| JPS54140968A (en) * | 1978-04-25 | 1979-11-01 | Hitachi Ltd | Method of forming circuit |
| NL7806773A (nl) * | 1978-06-23 | 1979-12-28 | Philips Nv | Additieve werkwijze voor het vervaardigen van metaal- patronen op kunststofsubstraten. |
| US4360968A (en) * | 1981-07-27 | 1982-11-30 | Western Electric Company, Incorporated | Method for reducing solder sticking on a printed wiring board |
| DE3149919A1 (de) * | 1981-12-11 | 1983-06-23 | Schering Ag, 1000 Berlin Und 4619 Bergkamen | Verfahren zum haftfesten metallisieren von polyimid |
| US4430418A (en) | 1982-09-30 | 1984-02-07 | E. I. Du Pont De Nemours And Company | Radiation-sensitive polyimide precursor composition derived from a diaryl fluoronated diamine compound |
| JPH0652732B2 (ja) * | 1985-08-14 | 1994-07-06 | 三菱電機株式会社 | パツシベ−シヨン膜の形成方法 |
| US4639290A (en) * | 1985-12-09 | 1987-01-27 | Hughes Aircraft Company | Methods for selectively removing adhesives from polyimide substrates |
| US4701351A (en) * | 1986-06-16 | 1987-10-20 | International Business Machines Corporation | Seeding process for electroless metal deposition |
| EP0272420A3 (en) * | 1986-12-22 | 1989-11-02 | General Electric Company | Photopatterned aromatic polymeric substrates, method for making same and use |
| US4775449A (en) * | 1986-12-29 | 1988-10-04 | General Electric Company | Treatment of a polyimide surface to improve the adhesion of metal deposited thereon |
| CN87100440B (zh) * | 1987-01-27 | 1988-05-11 | 中国人民解放军装甲兵工程学院 | 在不导电材料上刷镀铜的方法 |
| US4725504A (en) * | 1987-02-24 | 1988-02-16 | Polyonics Corporation | Metal coated laminate products made from textured polyimide film |
| US4992144A (en) * | 1987-02-24 | 1991-02-12 | Polyonics Corporation | Thermally stable dual metal coated laminate products made from polyimide film |
| US4894124A (en) * | 1988-02-16 | 1990-01-16 | Polyonics Corporation | Thermally stable dual metal coated laminate products made from textured polyimide film |
| US4806395A (en) * | 1987-02-24 | 1989-02-21 | Polyonics Corporation | Textured polyimide film |
| US4832799A (en) * | 1987-02-24 | 1989-05-23 | Polyonics Corporation | Process for coating at least one surface of a polyimide sheet with copper |
| US4882200A (en) * | 1987-05-21 | 1989-11-21 | General Electric Company | Method for photopatterning metallization via UV-laser ablation of the activator |
| US4877718A (en) * | 1988-09-26 | 1989-10-31 | Rennsselaer Polytechnic Institute | Positive-working photosensitive polyimide operated by photo induced molecular weight changes |
| US4931310A (en) * | 1988-11-25 | 1990-06-05 | International Business Machines Corporation | Process for treating the surface of polyimides to improve properties to receive metal layer |
| US5242713A (en) * | 1988-12-23 | 1993-09-07 | International Business Machines Corporation | Method for conditioning an organic polymeric material |
| JP2538043B2 (ja) * | 1989-04-05 | 1996-09-25 | 松下電器産業株式会社 | パタ―ン形成用材料とそれを用いたパタ―ン形成基板の作製方法 |
| US5084299A (en) * | 1989-08-10 | 1992-01-28 | Microelectronics And Computer Technology Corporation | Method for patterning electroless plated metal on a polymer substrate |
| US5192581A (en) * | 1989-08-10 | 1993-03-09 | Microelectronics And Computer Technology Corporation | Protective layer for preventing electroless deposition on a dielectric |
| US4981715A (en) * | 1989-08-10 | 1991-01-01 | Microelectronics And Computer Technology Corporation | Method of patterning electroless plated metal on a polymer substrate |
| US5133840A (en) * | 1990-05-15 | 1992-07-28 | International Business Machines Corporation | Surface midification of a polyimide |
| US5441770A (en) * | 1990-05-18 | 1995-08-15 | Shipley Company Inc. | Conditioning process for electroless plating of polyetherimides |
| JP2524436B2 (ja) * | 1990-09-18 | 1996-08-14 | インターナショナル・ビジネス・マシーンズ・コーポレイション | 表面処理方法 |
| JP2768390B2 (ja) * | 1990-12-11 | 1998-06-25 | インターナショナル・ビジネス・マシーンズ・コーポレイション | 無電解金属付着のために基体をコンディショニングする方法 |
| JPH0760821B2 (ja) * | 1991-05-17 | 1995-06-28 | インターナショナル・ビジネス・マシーンズ・コーポレイション | ポリマー基材の状態調整方法 |
| US5183692A (en) * | 1991-07-01 | 1993-02-02 | Motorola, Inc. | Polyimide coating having electroless metal plate |
| JP2765673B2 (ja) * | 1992-06-04 | 1998-06-18 | インターナショナル・ビジネス・マシーンズ・コーポレイション | メタライゼーション層及びその形成方法 |
| US5380560A (en) * | 1992-07-28 | 1995-01-10 | International Business Machines Corporation | Palladium sulfate solution for the selective seeding of the metal interconnections on polyimide dielectrics for electroless metal deposition |
| US5348574A (en) * | 1993-07-02 | 1994-09-20 | Monsanto Company | Metal-coated polyimide |
| JPH0948864A (ja) * | 1995-08-03 | 1997-02-18 | Kanegafuchi Chem Ind Co Ltd | ポリイミドフィルムの接着性改善方法及び接着性を改善したポリイミドフィルム |
| US5755859A (en) * | 1995-08-24 | 1998-05-26 | International Business Machines Corporation | Cobalt-tin alloys and their applications for devices, chip interconnections and packaging |
| DE10024239C1 (de) * | 2000-05-15 | 2001-09-20 | Atotech Deutschland Gmbh | Verfahren zum galvanotechnischen Behandeln von Werkstücken mit einer Palladiumkolloidlösung |
| US6685793B2 (en) | 2001-05-21 | 2004-02-03 | 3M Innovative Properties Company | Fluoropolymer bonding composition and method |
| US7485371B2 (en) * | 2004-04-16 | 2009-02-03 | 3M Innovative Properties Company | Bonding compositions |
| US6753087B2 (en) * | 2001-05-21 | 2004-06-22 | 3M Innovative Properties Company | Fluoropolymer bonding |
| US6630047B2 (en) | 2001-05-21 | 2003-10-07 | 3M Innovative Properties Company | Fluoropolymer bonding composition and method |
| US20050208308A1 (en) * | 2001-05-21 | 2005-09-22 | 3M Innovative Properties Company | Bonding compositions |
| US6645557B2 (en) * | 2001-10-17 | 2003-11-11 | Atotech Deutschland Gmbh | Metallization of non-conductive surfaces with silver catalyst and electroless metal compositions |
| US6752894B2 (en) | 2001-12-14 | 2004-06-22 | 3M Innovative Properties Company | Process for modifying a polymeric surface |
| US6844030B2 (en) | 2001-12-14 | 2005-01-18 | 3M Innovative Properties Company | Process for modifying a polymeric surface |
| US20050238812A1 (en) * | 2002-06-04 | 2005-10-27 | Bhangale Sunil M | Method for electroless metalisation of polymer substrate |
| US6951604B2 (en) * | 2002-08-13 | 2005-10-04 | Tokai Rubber Industries, Ltd. | Production method for flexible printed board |
| US20040126708A1 (en) * | 2002-12-31 | 2004-07-01 | 3M Innovative Properties Company | Method for modifying the surface of a polymeric substrate |
| US7273531B2 (en) * | 2003-11-05 | 2007-09-25 | 3M Innovative Properties Company | Method of modifying a fluoropolymeric substrate and composite articles thereby |
| US20050276911A1 (en) * | 2004-06-15 | 2005-12-15 | Qiong Chen | Printing of organometallic compounds to form conductive traces |
| US20070237977A1 (en) * | 2006-04-07 | 2007-10-11 | United States Of America As Represented By The Administrator Of The National Aeronautics And Spac | Thin Metal Film System To Include Flexible Substrate And Method Of Making Same |
| JP5215182B2 (ja) * | 2006-07-04 | 2013-06-19 | 新日鉄住金化学株式会社 | ポリイミド樹脂層の表面改質方法及び金属張積層板の製造方法 |
| US7649439B2 (en) * | 2006-08-18 | 2010-01-19 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Flexible thin metal film thermal sensing system |
| US8198976B2 (en) * | 2006-08-18 | 2012-06-12 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Flexible thin metal film thermal sensing system |
| CN101688308B (zh) * | 2007-07-02 | 2012-10-10 | 荏原优莱特科技股份有限公司 | 金属层叠聚酰亚胺底座及其制造方法 |
| US20090149589A1 (en) * | 2007-12-05 | 2009-06-11 | College Of William And Mary | Method for generating surface-silvered polymer structures |
| CA2917871A1 (en) | 2013-07-09 | 2015-01-15 | United Technologies Corporation | Plated tubular lattice structure |
| WO2015006433A2 (en) | 2013-07-09 | 2015-01-15 | United Technologies Corporation | Plated polymer fan |
| US20160376709A1 (en) * | 2013-07-09 | 2016-12-29 | United Technologies Corporation | Industrial products formed from plated polymers |
| WO2015017095A2 (en) | 2013-07-09 | 2015-02-05 | United Technologies Corporation | Plated polymer nosecone |
| CA2917967A1 (en) | 2013-07-09 | 2015-01-15 | United Technologies Corporation | Plated polymer compressor |
| JP5956553B2 (ja) * | 2014-12-24 | 2016-07-27 | キヤノン・コンポーネンツ株式会社 | めっき皮膜付樹脂製品及びその製造方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3558352A (en) * | 1966-10-27 | 1971-01-26 | Ibm | Metallization process |
| US3573973A (en) * | 1967-11-13 | 1971-04-06 | Ibm | High speed additive circuit process |
| US3791939A (en) * | 1972-05-15 | 1974-02-12 | Western Electric Co | Method of selectively depositing a metal on a surface |
| US3821016A (en) * | 1972-05-19 | 1974-06-28 | Western Electric Co | Method of forming an adherent metallic pattern on a polyimide surface |
| US3775121A (en) * | 1972-08-09 | 1973-11-27 | Western Electric Co | Method of selectively depositing a metal on a surface of a substrate |
-
1975
- 1975-06-10 CA CA228,978A patent/CA1053994A/en not_active Expired
- 1975-06-11 GB GB24945/75A patent/GB1497620A/en not_active Expired
- 1975-06-19 IT IT24556/75A patent/IT1039133B/it active
- 1975-06-24 JP JP50077102A patent/JPS5119067A/ja active Pending
- 1975-06-30 BR BR5262/75A patent/BR7504107A/pt unknown
- 1975-07-01 ES ES439036A patent/ES439036A1/es not_active Expired
- 1975-07-02 DE DE19752529571 patent/DE2529571A1/de not_active Withdrawn
- 1975-07-02 FR FR7520810A patent/FR2277114A1/fr active Granted
-
1976
- 1976-09-20 US US05/724,809 patent/US4112139A/en not_active Expired - Lifetime
- 1976-09-20 US US05/724,810 patent/US4078096A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CA1053994A (en) | 1979-05-08 |
| JPS5119067A (es) | 1976-02-16 |
| IT1039133B (it) | 1979-12-10 |
| FR2277114A1 (fr) | 1976-01-30 |
| GB1497620A (en) | 1978-01-12 |
| BR7504107A (pt) | 1976-07-20 |
| FR2277114B1 (es) | 1979-10-19 |
| US4078096A (en) | 1978-03-07 |
| DE2529571A1 (de) | 1976-01-22 |
| US4112139A (en) | 1978-09-05 |
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