ES409932A1 - Catalyst system preparation and olefin polymerisation therewith - Google Patents
Catalyst system preparation and olefin polymerisation therewithInfo
- Publication number
- ES409932A1 ES409932A1 ES409932A ES409932A ES409932A1 ES 409932 A1 ES409932 A1 ES 409932A1 ES 409932 A ES409932 A ES 409932A ES 409932 A ES409932 A ES 409932A ES 409932 A1 ES409932 A1 ES 409932A1
- Authority
- ES
- Spain
- Prior art keywords
- catalytic
- catalytic component
- metal
- integer
- support material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 14
- 239000000463 material Substances 0.000 abstract 8
- 229910052751 metal Inorganic materials 0.000 abstract 8
- 239000002184 metal Substances 0.000 abstract 8
- 229920006395 saturated elastomer Polymers 0.000 abstract 3
- 229910052723 transition metal Inorganic materials 0.000 abstract 3
- 150000003624 transition metals Chemical class 0.000 abstract 3
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000001350 alkyl halides Chemical class 0.000 abstract 1
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 abstract 1
- 239000010419 fine particle Substances 0.000 abstract 1
- 230000026030 halogenation Effects 0.000 abstract 1
- 238000005658 halogenation reaction Methods 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Procedure for obtaining olefinic polymers by olefin polymerization, at temperatures from 0 to 200ºC and pressures from 0.1 to 200 atmospheres, by means of a catalyst system of (1) a support material of fine particles, showing a particle diameter of 0, 1 to 2000 microns, inorganic, containing metals and halogen, in each case in chemical bond, as well as (2) a catalyst applied to the support material, of the Ziegler type, of (2.1) a catalytic component of a chloride, oxychloride or titanium, zirconium or vanadium alkoxychloride, as well as (2.2.) A catalytic component of a saturated metal alkyl, saturated metal alkoxyalkyl, or metal, magnesium or zinc saturated metal alkyl halide, characterized in that a system is used catalytic in which (A) the support material (1) is a material, which has been obtained by keeping it under heat for 1 to 100, preferably 2 to 50 hours at a temperature ra 110 to 600, preferably 200 to 400 ° C, and subsequent halogenation to a halogen content of the material of 20 to 70, preferably 30 to 65% by weight, of a substance of general formula (MeII) m. (MeIII) n . (OH) o. (CO3) p. (H2O) q, in which MeII means a metal, or transition metal, present in a divalent state; MeIII a metal, or transition metal, present in a trivalent state, an integer from 2 to 8, n an integer from 2 to 4, or an integer from 8 to 18, p an integer from 1 to 2 , q an integer from 2 to 6, under the condition that the relation 2.m + 3.n = or + 2.p = is equal to an integer from 16 to 26, and (B) the components are joined by joining the support material (1) first with a stop of the catalytic component (2.2) to form a previous stage of the catalytic system, then, this first stage meets with the catalytic component (2.1) to form a second previous stage of the catalytic system and finally This second stage meets with a further part of the catalytic component (2.2) to form the catalytic system itself; under the conditions that in the first preliminary stage per 100 grams of support material (1) 0.01 to 10 mol-grams of catalytic component (2.2) correspond to the fact that in the second preliminary stage per 100 grams of support material (1) 0.015 corresponds to 40 moles-grams of catalytic component (2.1) and that in the catalytic system itself the atomic ratio between the transition metal of the catalytic component (2.1) and the metal of the part of the second catalytic component (2.2) attached with the second previous stage, it is in the area between 100: 10 and 100: 20,000 (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19712163852 DE2163852C3 (en) | 1971-12-22 | 1971-12-22 | Process for the production of olefin polymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES409932A1 true ES409932A1 (en) | 1975-12-01 |
Family
ID=5828874
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES409932A Expired ES409932A1 (en) | 1971-12-22 | 1972-12-22 | Catalyst system preparation and olefin polymerisation therewith |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JPS4870789A (en) |
| AT (1) | AT322202B (en) |
| AU (1) | AU465716B2 (en) |
| BE (1) | BE793222A (en) |
| DE (1) | DE2163852C3 (en) |
| ES (1) | ES409932A1 (en) |
| FR (1) | FR2164776B1 (en) |
| GB (1) | GB1380950A (en) |
| IT (1) | IT974242B (en) |
| NL (1) | NL7217390A (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1096364A (en) * | 1976-05-14 | 1981-02-24 | Oscar D. Nowlin | Magnesium reducing agent prepared in absence of complexing diluent milled with organoaluminum |
| DE2831829A1 (en) * | 1978-07-20 | 1980-01-31 | Basf Ag | METHOD FOR PRODUCING A COMPONENT FOR POLYMERIZATION CATALYSTS |
| DE2914168A1 (en) * | 1979-04-07 | 1980-10-23 | Basf Ag | METHOD FOR PRODUCING HOMOUND AND COPOLYMERISATS FROM ALPHA MONOOLEFINES BY MEANS OF A ZIEGLER CATALYST SYSTEM |
| US5565400A (en) * | 1993-08-20 | 1996-10-15 | Uop | Hydrothermally stable metal oxide solid solutions as carriers for catalytic composites |
| US5393722A (en) * | 1993-08-20 | 1995-02-28 | Uop | Hydrothermally stable metal oxide solid solutions |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1582543A (en) * | 1968-07-01 | 1969-10-03 | ||
| NL136668C (en) * | 1969-01-24 |
-
0
- BE BE793222D patent/BE793222A/en not_active IP Right Cessation
-
1971
- 1971-12-22 DE DE19712163852 patent/DE2163852C3/en not_active Expired
-
1972
- 1972-12-13 AU AU49994/72A patent/AU465716B2/en not_active Expired
- 1972-12-19 GB GB5847472A patent/GB1380950A/en not_active Expired
- 1972-12-20 NL NL7217390A patent/NL7217390A/xx not_active Application Discontinuation
- 1972-12-21 FR FR7245600A patent/FR2164776B1/fr not_active Expired
- 1972-12-21 AT AT1092472A patent/AT322202B/en not_active IP Right Cessation
- 1972-12-21 IT IT5494072A patent/IT974242B/en active
- 1972-12-22 ES ES409932A patent/ES409932A1/en not_active Expired
- 1972-12-22 JP JP12827972A patent/JPS4870789A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE2163852C3 (en) | 1980-01-24 |
| FR2164776B1 (en) | 1976-08-27 |
| DE2163852A1 (en) | 1973-06-28 |
| JPS4870789A (en) | 1973-09-25 |
| AU4999472A (en) | 1974-06-13 |
| FR2164776A1 (en) | 1973-08-03 |
| NL7217390A (en) | 1973-06-26 |
| AT322202B (en) | 1975-05-12 |
| DE2163852B2 (en) | 1979-05-23 |
| GB1380950A (en) | 1975-01-22 |
| IT974242B (en) | 1974-06-20 |
| BE793222A (en) | 1973-06-22 |
| AU465716B2 (en) | 1975-10-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 19890222 |