ES409872A1 - Inorganic carriers for ziegler catalysts and the use thereof in the manufacture of olefin polymers - Google Patents
Inorganic carriers for ziegler catalysts and the use thereof in the manufacture of olefin polymersInfo
- Publication number
- ES409872A1 ES409872A1 ES409872A ES409872A ES409872A1 ES 409872 A1 ES409872 A1 ES 409872A1 ES 409872 A ES409872 A ES 409872A ES 409872 A ES409872 A ES 409872A ES 409872 A1 ES409872 A1 ES 409872A1
- Authority
- ES
- Spain
- Prior art keywords
- catalytic component
- metal
- support material
- saturated
- catalytic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 239000000969 carrier Substances 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 229920000098 polyolefin Polymers 0.000 title 1
- 230000003197 catalytic effect Effects 0.000 abstract 6
- 239000000463 material Substances 0.000 abstract 6
- 229910052751 metal Inorganic materials 0.000 abstract 6
- 239000002184 metal Substances 0.000 abstract 6
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 2
- 229920006395 saturated elastomer Polymers 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- 229910052723 transition metal Inorganic materials 0.000 abstract 2
- 150000003624 transition metals Chemical class 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000001350 alkyl halides Chemical class 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 abstract 1
- 239000010419 fine particle Substances 0.000 abstract 1
- 230000026030 halogenation Effects 0.000 abstract 1
- 238000005658 halogenation reaction Methods 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Procedure for obtaining olefinic polymers, by polymerization of olefins, at temperatures from 0 to 200ºC and pressures from 0.1 to 200 atmospheres, by means of a catalyst system of (1) a support material of fine particles, showing a particle diameter of 0.1 to 2000 microns, inorganic, containing metals and halogen, in each case in chemical bond, as well as (2) a catalyst applied on the support material of the Ziegler type, of (2.1.) A catalytic component of a chloride, oxychloride or titanium, zirconium or vanadium alkoxychloride, as well as (2.2) a catalytic component of a saturated metal alkyl, saturated alkoxyalkyl metal or saturated metal alkylhalide of the metals aluminum, magnesium or zinc, under the conditions that the proportion by weight between the support material (1) and the catalytic component (2.1) related to the transition metal is in the range of 100: 0.1 to 100: 12 and the atomic ratio between e the transition metal of the catalytic component (2.1.) And the metal of the catalytic component (2.2) is in the zone of 100: 10 to 100: 20,000 characterized in that a catalytic system is used in which the support material (1) is a material, which has been obtained by keeping it under heat for 1 to 100, preferably 2 to 50 hours, at a temperature of 110 to 600, preferably 200 to 400ºC and subsequent halogenation to a halogen content of the material of 20 to 70, preferably 30 to 65% by weight, of a substance of the general formula (MeII) m. (MeIII) n. (OH) o. (CO3) P. (H2O) q (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19712163851 DE2163851C3 (en) | 1971-12-22 | 1971-12-22 | Process for the production of olefin polymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES409872A1 true ES409872A1 (en) | 1975-11-16 |
Family
ID=5828873
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES409872A Expired ES409872A1 (en) | 1971-12-22 | 1972-12-21 | Inorganic carriers for ziegler catalysts and the use thereof in the manufacture of olefin polymers |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JPS4870788A (en) |
| AT (1) | AT321575B (en) |
| AU (1) | AU465953B2 (en) |
| BE (1) | BE793220A (en) |
| DE (1) | DE2163851C3 (en) |
| ES (1) | ES409872A1 (en) |
| FR (1) | FR2164757B1 (en) |
| GB (1) | GB1380949A (en) |
| IT (1) | IT974158B (en) |
| NL (1) | NL7217221A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2831829A1 (en) * | 1978-07-20 | 1980-01-31 | Basf Ag | METHOD FOR PRODUCING A COMPONENT FOR POLYMERIZATION CATALYSTS |
| US5565400A (en) * | 1993-08-20 | 1996-10-15 | Uop | Hydrothermally stable metal oxide solid solutions as carriers for catalytic composites |
| US5393722A (en) * | 1993-08-20 | 1995-02-28 | Uop | Hydrothermally stable metal oxide solid solutions |
| DE10028432A1 (en) | 2000-06-13 | 2001-12-20 | Basell Polyolefine Gmbh | High-activity olefin polymerization catalysts leaving little or no particulate residue in the polymer comprise calcined hydrotalcite carrier and organo-transition metal compound |
-
0
- BE BE793220D patent/BE793220A/en not_active IP Right Cessation
-
1971
- 1971-12-22 DE DE19712163851 patent/DE2163851C3/en not_active Expired
-
1972
- 1972-12-13 AU AU49993/72A patent/AU465953B2/en not_active Expired
- 1972-12-18 NL NL7217221A patent/NL7217221A/xx not_active Application Discontinuation
- 1972-12-19 GB GB5847372A patent/GB1380949A/en not_active Expired
- 1972-12-19 IT IT5483472A patent/IT974158B/en active
- 1972-12-20 FR FR7245478A patent/FR2164757B1/fr not_active Expired
- 1972-12-21 ES ES409872A patent/ES409872A1/en not_active Expired
- 1972-12-21 AT AT1092172A patent/AT321575B/en not_active IP Right Cessation
- 1972-12-22 JP JP12827872A patent/JPS4870788A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| BE793220A (en) | 1973-06-22 |
| GB1380949A (en) | 1975-01-22 |
| IT974158B (en) | 1974-06-20 |
| AU465953B2 (en) | 1975-10-09 |
| AU4999372A (en) | 1974-06-13 |
| DE2163851A1 (en) | 1973-06-28 |
| FR2164757A1 (en) | 1973-08-03 |
| AT321575B (en) | 1975-04-10 |
| DE2163851C3 (en) | 1980-01-24 |
| JPS4870788A (en) | 1973-09-25 |
| FR2164757B1 (en) | 1976-01-30 |
| NL7217221A (en) | 1973-06-26 |
| DE2163851B2 (en) | 1979-05-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 19890218 |