[go: up one dir, main page]

ES395227A1 - Metodo de obtencion de compuestos derivados de vinil fosfo-ro activos como pesticidas. - Google Patents

Metodo de obtencion de compuestos derivados de vinil fosfo-ro activos como pesticidas.

Info

Publication number
ES395227A1
ES395227A1 ES395227A ES395227A ES395227A1 ES 395227 A1 ES395227 A1 ES 395227A1 ES 395227 A ES395227 A ES 395227A ES 395227 A ES395227 A ES 395227A ES 395227 A1 ES395227 A1 ES 395227A1
Authority
ES
Spain
Prior art keywords
phosphonothioates
carbomethoxy
base
reaction
methylvinyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES395227A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
STAUFFEK CHEMICAL Co
Original Assignee
STAUFFEK CHEMICAL Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by STAUFFEK CHEMICAL Co filed Critical STAUFFEK CHEMICAL Co
Publication of ES395227A1 publication Critical patent/ES395227A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/655—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms
    • C07F9/65515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a five-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
    • C07F9/165—Esters of thiophosphoric acids
    • C07F9/173—Esters of thiophosphoric acids with unsaturated acyclic alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/22—Amides of acids of phosphorus
    • C07F9/24—Esteramides
    • C07F9/2404—Esteramides the ester moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/2412—Esteramides the ester moiety containing a substituent or a structure which is considered as characteristic of unsaturated acyclic alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
    • C07F9/4071—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4078—Esters with unsaturated acyclic alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/42—Halides thereof
    • C07F9/425—Acid or estermonohalides thereof, e.g. RP(=X)(YR)(Hal) (X, Y = O, S; R = H, or hydrocarbon group)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/44—Amides thereof
    • C07F9/4434—Amides thereof the ester moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4442—Esters with unsaturated acyclic alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/572—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6527—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07F9/653—Five-membered rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Método de obtención de compuestos derivados de vinil fósforo activos como pesticidas , caracterizado esencialmente porque los compuestos son sintetizados haciendo reaccionar un dicloridato de fosforo con un ester beta-keto en presencia de un disolvente como el benceno, tetrahidrofuren y semejantes, y una base, pudiendo hacerse reaccionar el producto por esta reacción mediante un reactivo nucleofílico para formar el producto final, llevándose a cabo esta última reacción en presencia de una base
ES395227A 1970-09-21 1971-09-20 Metodo de obtencion de compuestos derivados de vinil fosfo-ro activos como pesticidas. Expired ES395227A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US7413670A 1970-09-21 1970-09-21

Publications (1)

Publication Number Publication Date
ES395227A1 true ES395227A1 (es) 1975-10-16

Family

ID=22117935

Family Applications (1)

Application Number Title Priority Date Filing Date
ES395227A Expired ES395227A1 (es) 1970-09-21 1971-09-20 Metodo de obtencion de compuestos derivados de vinil fosfo-ro activos como pesticidas.

Country Status (11)

Country Link
US (1) US3784589A (es)
AU (1) AU3318471A (es)
BE (1) BE772806A (es)
BR (1) BR7106230D0 (es)
DE (1) DE2146904A1 (es)
ES (1) ES395227A1 (es)
FR (1) FR2108296A5 (es)
GB (1) GB1366374A (es)
IL (1) IL37758A (es)
NL (1) NL7112960A (es)
ZA (1) ZA716287B (es)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3940458A (en) * 1972-02-29 1976-02-24 Mobil Oil Corporation 1-Carbamoyl vinyl phosphates
DE2212906A1 (de) * 1972-03-17 1973-09-27 Bayer Ag 1-carbalkoxy-2-cyano-vinyl-(thiono)phosphor-(phosphon)-saeureester bzw. -esteramide, verfahren zu ihrer herstellung und ihre verwendung als insektizide und akarizide
IL43068A (en) * 1972-09-08 1976-08-31 Ciba Geigy Ag Thio-and dithiophosphoric acid esters,their manufacture and their use in pest control
US4006228A (en) * 1974-09-20 1977-02-01 Ciba-Geigy Corporation Pesticidally active thio- and dithiophosphoric acid esters
DE2455763A1 (de) * 1974-11-26 1976-08-12 Bayer Ag O-vinylthiono(thiol)phosphor(phosphon)-saeureester, verfahren zu ihrer herstellung und ihre verwendung als insektizide
DE2533601A1 (de) * 1975-07-26 1977-02-10 Bayer Ag Vinyl-(thiono)(thiol)phosphor(phosphon)-saeureester, verfahren zu ihrer herstellung und ihre verwendung als insektizide, akarizide und nematizide
DE2536977A1 (de) * 1975-08-20 1977-03-03 Bayer Ag Vinyl(di- bzw. tri)thiophosphor (phosphon)-saeureester bzw. -esteramide, verfahren zu ihrer herstellung und ihre verwendung als insektizide und akarizide
US4046884A (en) * 1976-03-01 1977-09-06 Velsicol Chemical Corporation N-(α-Aminoalkylidene)phosphor- and phosphonamidates, and method for controlling insects
US4652301A (en) * 1983-05-16 1987-03-24 Stauffer Chemical Co. Herbicide compositions of extended soil life
US4544651A (en) * 1984-04-16 1985-10-01 Stauffer Chemical Company S-2-(Carboalkoxyvinyl) trithiophosphonate insecticides
US8198445B2 (en) * 2007-03-09 2012-06-12 National University Corporation Nagoya University Phosphoramide compound, method for producing the same, ligand, complex, catalyst and method for producing optically active alcohol

Also Published As

Publication number Publication date
GB1366374A (en) 1974-09-11
IL37758A0 (en) 1971-11-29
IL37758A (en) 1975-03-13
BR7106230D0 (pt) 1973-04-10
DE2146904A1 (de) 1972-03-23
US3784589A (en) 1974-01-08
FR2108296A5 (es) 1972-05-19
ZA716287B (en) 1972-05-31
NL7112960A (es) 1972-03-23
BE772806A (fr) 1972-03-20
AU3318471A (en) 1973-03-15

Similar Documents

Publication Publication Date Title
NL177483C (nl) Werkwijze voor de bereiding van een hardbaar mengsel dat geschikt is voor gebruik als constructiemateriaal.
ES395227A1 (es) Metodo de obtencion de compuestos derivados de vinil fosfo-ro activos como pesticidas.
ES441908A2 (es) Un procedimiento mejorado para la preparacion de un agente tensoactivo por transesterificacion de sacarosa con un tri- glicerido.
ES435893A1 (es) Un procedimiento de preparacion de pisobutilfenilpropionatode lisina.
ES432334A1 (es) Procedimiento de obtencion de derivados 1-amido alquil-4- sulfonil-piperazina.
ES323192A1 (es) Procedimiento para la obtencion de un nuevo derivado de ester de acido fosforico.
ES395352A1 (es) Un procedimiento para preparar un fosforotionoamidato.
ES425600A1 (es) Procedimiento de obtencion de un nuevo derivado de pirroli- dinona.
ES433483A1 (es) Un procedimiento para la preparacion de neohesperidin-dihi-drocalcona.
ES323191A1 (es) Procedimiento para la obtencion de un nuevo derivado de ester de acido fosforico.
ES376364A1 (es) Un procedimiento de preparar una gama-cianobutiraldimina.
ES426893A1 (es) Un procedimiento para la 11a-deshalogenacion de un compues-to de 11a-halo-6-metilentetraciclina.
NL7504268A (nl) Werkwijze voor de afscheiding van bis-(4-chloorfenyl)- -sulfon uit een reactiemengsel.
ES397009A1 (es) Procedimiento de obtencion de un nuevo derivado de acido p-clorofenoxi-isobutirico.
ES386488A1 (es) Un procedimiento para la preparacion de ampicilina.
ES323189A1 (es) Procedimiento para la obtencion de un nuevo derivado de ester de acido fosforico.
ES405907A1 (es) Procedimiento para preparar esteres organicos de acido fos-forico.
ES392540A1 (es) Un procedimiento para preparar una composicion que consis- te sustancialmente en alfa-clordano y beta-clordano.
ES450336A1 (es) Un procedimiento para la manufactura de clorotiantreno.
ES426755A1 (es) Un procedimiento de preparacion del ester mixto 1 - 2 - (p-clorofenoxi) - 2 - metilpropianoato, 2 - nicotinato de eti- lenglicol.
ES379131A1 (es) Procedimiento para la preparacion de poliuretanos preferi- blemente no espumados.
ES332018A1 (es) Un procedimiento para preparar nuevos compuestos de accion pigmentante.
ES399352A1 (es) Un procedimiento para la obtencion de n-butil-bromuro ci- clopentilester de escopolamonium.
ES474444A1 (es) Procedimiento de obtencion de un derivado de acido isobuti- rico
ES433493A1 (es) Procedimiento para la preparacion del ester cis 3,3,5-tri- metilciclohexilico del acido dl-alfa-nicotinoiloxifenilace- tico.