ES263156A1 - Process for making foamed styrene polymers - Google Patents
Process for making foamed styrene polymersInfo
- Publication number
- ES263156A1 ES263156A1 ES0263156A ES263156A ES263156A1 ES 263156 A1 ES263156 A1 ES 263156A1 ES 0263156 A ES0263156 A ES 0263156A ES 263156 A ES263156 A ES 263156A ES 263156 A1 ES263156 A1 ES 263156A1
- Authority
- ES
- Spain
- Prior art keywords
- styrene
- polymers
- mixture
- hydrated inorganic
- foamable mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title abstract 14
- 229920000642 polymer Polymers 0.000 title abstract 9
- 238000000034 method Methods 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 abstract 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 4
- 229910000329 aluminium sulfate Inorganic materials 0.000 abstract 3
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 abstract 3
- 235000011128 aluminium sulphate Nutrition 0.000 abstract 3
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 abstract 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 2
- 239000005909 Kieselgur Substances 0.000 abstract 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 abstract 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 abstract 2
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 2
- 239000000378 calcium silicate Substances 0.000 abstract 2
- 229910052918 calcium silicate Inorganic materials 0.000 abstract 2
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- 238000002425 crystallisation Methods 0.000 abstract 2
- 239000006260 foam Substances 0.000 abstract 2
- 229920001519 homopolymer Polymers 0.000 abstract 2
- 239000004615 ingredient Substances 0.000 abstract 2
- 229910017053 inorganic salt Inorganic materials 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 abstract 2
- 239000001095 magnesium carbonate Substances 0.000 abstract 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 abstract 2
- 239000002480 mineral oil Substances 0.000 abstract 2
- 235000010446 mineral oil Nutrition 0.000 abstract 2
- 239000002667 nucleating agent Substances 0.000 abstract 2
- 229920000620 organic polymer Polymers 0.000 abstract 2
- 239000004014 plasticizer Substances 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- 235000012424 soybean oil Nutrition 0.000 abstract 2
- 239000003549 soybean oil Substances 0.000 abstract 2
- 229920001169 thermoplastic Polymers 0.000 abstract 2
- 239000004416 thermosoftening plastic Substances 0.000 abstract 2
- 239000004408 titanium dioxide Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 239000011787 zinc oxide Substances 0.000 abstract 2
- 230000008025 crystallization Effects 0.000 abstract 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 abstract 1
- 229910052939 potassium sulfate Inorganic materials 0.000 abstract 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 abstract 1
- 235000019345 sodium thiosulphate Nutrition 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/125—Water, e.g. hydrated salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Foams are produced from thermoplastic organic polymers using as the expanding agent a hydrated inorganic salt or mixture thereof capable of evolving water of crystallization at the plastifying temperature of the polymer. Polymers operable in the process are homopolymers of styrene, copolymers of styrene and minor amounts of acrylonitrile or methyl methacrylate and blends of styrene polymers with 2-15% of one or more rubbery butadiene-styrene polymers. Numerous hydrated inorganic salts are specified those used in the examples are Al2(SO4)3 18H2O, Al2(SO4)3 K2SO4 24H2O and Na2S2O3 5H2O. Optionally nucleating agents, e.g. finely divided aluminium oxide, calcium silicate, diatomaceous earth, sodium bicarbonate, magnesium carbonate, calcium carbonate, zinc oxide and titanium dioxide, and liquid plasticizers, e.g. white mineral oil, soy bean oil and butyl stearate may be added to the foamable mixture. The various ingredients of the foamable mixture are blended together and extruded at temperatures from about 140 DEG to 160 DEG C.ALSO:Foams are produced from thermoplastic organic polymers using as the expanding agent a hydrated inorganic salt or mixture thereof capable of evolving water of crystallisation at the plastifying temperature of the polymer. Polymers operable in the process are homopolymers of styrene, copolymers of styrene and a minor amount of acrylonitrile or methyl methacrylate and blends of styrene polymers with from 2 to 15% of one or more rubbery butadiene-styrene polymers. Numerous hydrated inorganic salts are specified those used in the examples are Al2(SO4)3,18H2O, Al2(SO4)3,K2SO4,24H2O and Na2S2O3,5H2O. Optionally nucleating agents, e.g. finely divided aluminium oxide, calcium silicate, diatomaceous earth, sodium bicarbonate, magnesium carbonate, calcium carbonate, zinc oxide and titanium dioxide, and liquid plasticizers, e.g. white mineral oil, soy bean oil and butyl stearate may be added to the foamable mixture. The various ingredients of the foamable mixture are blended together and extruded at temperatures from about 140 to 160 DEG C.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US85858859A | 1959-12-10 | 1959-12-10 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES263156A1 true ES263156A1 (en) | 1961-03-01 |
Family
ID=25328655
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES0263156A Expired ES263156A1 (en) | 1959-12-10 | 1960-12-10 | Process for making foamed styrene polymers |
Country Status (4)
| Country | Link |
|---|---|
| DE (1) | DE1178206B (en) |
| ES (1) | ES263156A1 (en) |
| FR (1) | FR1282128A (en) |
| GB (1) | GB903564A (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3300419A (en) * | 1963-07-15 | 1967-01-24 | Evans Prod Co | Phenolic resin cellular materials and method for making same |
| US3457205A (en) * | 1963-12-19 | 1969-07-22 | Lakeside Plastics Corp | Composition for making coated expanded polystyrene foam |
| US3309439A (en) * | 1964-11-06 | 1967-03-14 | Lakeside Plastics Corp | Method of producing an expanded polystyrene foam having a dense surface |
| US3375209A (en) * | 1964-05-25 | 1968-03-26 | Charles R. Kemper | Porous film and method of making |
| US3404104A (en) * | 1964-12-21 | 1968-10-01 | Phillips Petroleum Co | Polyolefin foam |
| FR2177584B1 (en) * | 1972-03-30 | 1974-12-20 | Charbonnages Ste Chimique | |
| US4330635A (en) * | 1980-04-04 | 1982-05-18 | Monsanto Company | Foamable polymeric composition |
| US4304874A (en) * | 1980-05-06 | 1981-12-08 | Arco Polymers, Inc. | Fire-retardant anhydride copolymers |
| DE3131446A1 (en) * | 1981-08-07 | 1983-02-24 | Basf Ag, 6700 Ludwigshafen | METHOD FOR THE PRODUCTION OF FINE-CELLED FOAMS FROM STYRENE POLYMERS |
| US4407768A (en) * | 1982-01-08 | 1983-10-04 | Phillips Petroleum Company | Foamable polymeric composition comprising propylene polymer and hydrated alumina |
| EP0860465A1 (en) * | 1997-02-21 | 1998-08-26 | Dsm N.V. | Foamed thermoplastic elastomeric article |
| WO1998037131A1 (en) * | 1997-02-21 | 1998-08-27 | Dsm N.V. | Foamed thermo-elastic article |
| DE69906527T2 (en) * | 1998-06-23 | 2004-04-08 | Dsm N.V. | FOAMED OBJECT FROM THERMOPLASTIC ELASTOMER AND METHOD FOR THE PRODUCTION THEREOF |
| CN106317445B (en) * | 2015-06-29 | 2019-01-15 | 北京化工大学 | A kind of supported crystalline hydrate foaming agent, preparation method and application |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2911382A (en) * | 1956-09-21 | 1959-11-03 | Monsanto Chemicals | Process of making extruded styrene polymer foams |
-
1960
- 1960-12-06 GB GB4199260A patent/GB903564A/en not_active Expired
- 1960-12-08 DE DE1960D0034905 patent/DE1178206B/en active Pending
- 1960-12-09 FR FR846500A patent/FR1282128A/en not_active Expired
- 1960-12-10 ES ES0263156A patent/ES263156A1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB903564A (en) | 1962-08-15 |
| DE1178206B (en) | 1964-09-17 |
| FR1282128A (en) | 1962-01-19 |
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