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ES2122017T5 - Zeolita zsm-5. - Google Patents

Zeolita zsm-5.

Info

Publication number
ES2122017T5
ES2122017T5 ES93912876T ES93912876T ES2122017T5 ES 2122017 T5 ES2122017 T5 ES 2122017T5 ES 93912876 T ES93912876 T ES 93912876T ES 93912876 T ES93912876 T ES 93912876T ES 2122017 T5 ES2122017 T5 ES 2122017T5
Authority
ES
Spain
Prior art keywords
zsm
zeolita
atomos
tectosilicate
zeolite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93912876T
Other languages
English (en)
Other versions
ES2122017T3 (es
Inventor
Johannes Petrus Verduijn
Luc Roger Marc Martens
Johan Adriaan Martens
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8211393&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2122017(T5) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Application granted granted Critical
Publication of ES2122017T3 publication Critical patent/ES2122017T3/es
Publication of ES2122017T5 publication Critical patent/ES2122017T5/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C01B39/082—Gallosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C01B39/40—Type ZSM-5 using at least one organic template directing agent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/22—MFI, e.g. ZSM-5. silicalite, LZ-241

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

SE PUEDE PREPARAR UNA ZEOLITA ZSM -5 CRISTALINA DE TECTOSILICATO QUE COMPRENDE AGLOMERANTES SUSTANCIALMENTE CON FORMA DE AGUJA. LA ZEOLITA ZSM NMR SI29 QUE TIENE AL MENOS TRES PICOS QUE INDICAN LA PRESENCIA DE ATOMOS DE SI EN LA ESTRUCTURA QUE TIENE 0,1 O 2 ATOMOS COMO LIMITES CONTIGUOS MAS CERCANOS.
ES93912876T 1992-06-05 1993-06-04 Zeolita zsm-5. Expired - Lifetime ES2122017T5 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP92305182 1992-06-05

Publications (2)

Publication Number Publication Date
ES2122017T3 ES2122017T3 (es) 1998-12-16
ES2122017T5 true ES2122017T5 (es) 2001-05-01

Family

ID=8211393

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93912876T Expired - Lifetime ES2122017T5 (es) 1992-06-05 1993-06-04 Zeolita zsm-5.

Country Status (12)

Country Link
US (1) US5783321A (es)
EP (1) EP0643671B2 (es)
JP (1) JPH07506802A (es)
KR (1) KR100282970B1 (es)
CN (1) CN1048001C (es)
AU (1) AU4322493A (es)
DE (1) DE69320190T3 (es)
ES (1) ES2122017T5 (es)
MX (1) MX9303409A (es)
SG (1) SG73398A1 (es)
WO (1) WO1993025476A1 (es)
ZA (1) ZA933879B (es)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1037415C (zh) * 1994-01-29 1998-02-18 复旦大学 一种无粘结剂疏水硅沸石吸附剂的制备方法
CA2182994A1 (en) * 1994-02-22 1995-08-24 Exxonmobil Chemical Patents, Inc. Oligomerization and catalysts therefor
CN1122572C (zh) * 1997-02-04 2003-10-01 中国科学院大连化学物理研究所 甲烷无氧脱氢芳构化的杂原子分子筛催化剂及其应用
DE19951781A1 (de) 1999-10-27 2001-05-03 Sued Chemie Ag Verfahren zur Herstellung von synthetischen Zeolithen mit MFI-Struktur
US6368571B1 (en) 2000-01-28 2002-04-09 Chk Group, Inc. ZSM-5 made from siliceous ash
US6500992B1 (en) * 2000-11-09 2002-12-31 King Fahd University Of Petroleum & Minerals Synthesis of methyl tertiary butyl ether from methanol and isobutene using aluminum-fluoride-modified zeolite catalysts
US7227048B2 (en) 2001-12-31 2007-06-05 Exxonmobil Chemical Patents Inc. Converting oxygenates to olefins over a catalyst comprising acidic molecular sieve of controlled carbon atom to acid site ratio
US20050186127A1 (en) * 2002-10-18 2005-08-25 Emitec Gesellschaft Fur Emissionstechnologie Mbh Catalyst carrier body with passivation layer and method for producing the same
US7241716B2 (en) 2003-11-10 2007-07-10 Exxonmobil Chemical Patents Inc. Protecting catalytic sites of metalloaluminophosphate molecular sieves
GB0702327D0 (en) * 2007-02-07 2007-03-21 Leuven K U Res & Dev Zeolite materials and synthesis method thereof
KR101395454B1 (ko) * 2007-09-20 2014-05-15 삼성전자주식회사 그레이디드 굴절률을 갖는 광학 필름 및 이의 제조방법
US20110009685A1 (en) * 2008-03-31 2011-01-13 Sebastien Kremer MFI Molecular Sieve Composition and the Method of Making the Same
CN102791375B (zh) 2010-03-08 2014-12-24 陶氏环球技术有限责任公司 用于将乙醇直接转化为丙烯的催化剂组合物
DE102010053054A1 (de) * 2010-12-01 2012-06-06 Süd-Chemie AG Mechanochemische Herstellung von Zeolithen
CN104379504B (zh) * 2012-04-24 2016-10-12 巴斯夫欧洲公司 沸石材料及其利用烯基三烷基铵化合物的制备方法
US9475041B2 (en) 2012-04-24 2016-10-25 Basf Se Zeolitic materials and methods for their preparation using alkenyltrialkylammonium compounds
KR101950552B1 (ko) * 2012-12-07 2019-02-20 엑손모빌 리서치 앤드 엔지니어링 컴퍼니 개선된 모폴로지를 갖는 zsm-5 결정의 합성
CN103007985B (zh) * 2012-12-20 2014-09-24 清华大学 一种将醇、醚转化为芳烃的催化剂及其制备、使用方法
EP2935102B1 (en) * 2012-12-21 2017-01-25 ExxonMobil Chemical Patents Inc. Small crystal zsm-5 and its use
KR101874299B1 (ko) * 2012-12-28 2018-07-06 클라리언트 인터내셔널 리미티드 향료를 수득하기 위한 방법
BR112016000038B1 (pt) 2013-07-04 2021-03-16 Total Research & Technology Feluy composições catalisadoras compreendendo cristais de peneiras moleculares de tamanho pequeno depositados em um material poroso
WO2020197890A1 (en) 2019-03-28 2020-10-01 Exxonmobil Chemical Patents Inc. Processes for converting benzene and/or toluene via methylation
US11691933B2 (en) 2019-03-28 2023-07-04 Exxonmobil Chemical Patents Inc. Processes and systems for converting benzene and/or toluene via methylation
CN113574038B (zh) 2019-03-28 2024-10-22 埃克森美孚化学专利公司 经由甲基化转化苯和/或甲苯的方法
CN110467198B (zh) * 2019-08-08 2021-02-02 大连理工大学 一种多级孔zsm-5纳米聚集体微球及制备方法
US20250128999A1 (en) 2021-09-16 2025-04-24 ExxonMobil Technology and Engineering Company Xylene Isomer Separation Processes
CN118159511A (zh) 2021-10-12 2024-06-07 埃克森美孚化学专利公司 生产二甲苯产物的分段烷基化
WO2023204947A1 (en) 2022-04-19 2023-10-26 Exxonmobil Chemical Patents Inc. Processes for oxidizing p-xylene or p-xylene-containing mixtures
CN117019208B (zh) * 2023-08-17 2025-08-22 福州大学 一种用于丙烷脱氢制丙烯高温稳定性的PtZn@分子筛催化剂及其制备方法

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NL294141A (es) * 1962-07-06
US3702886A (en) * 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3808326A (en) * 1971-03-19 1974-04-30 Grace W R & Co Preparation of zeolites
US3781225A (en) * 1972-04-17 1973-12-25 Mobil Oil Corp Treatment of colloidal zeolites
US4341748A (en) * 1973-12-13 1982-07-27 Mobil Oil Corporation Method for producing zeolites
US4166099A (en) * 1974-04-20 1979-08-28 W. R. Grace & Co. Preparation of zeolites
US4139600A (en) * 1977-04-22 1979-02-13 Mobil Oil Corporation Synthesis of zeolite ZSM-5
DE2831334A1 (de) * 1978-07-17 1980-02-07 Basf Ag Verfahren zur herstellung von kristallinen aluminosilikatzeolithen
CA1144137A (en) * 1979-12-26 1983-04-05 Donald A. Hickson Method for preparing crystalline zeolites
NL8101543A (nl) * 1981-03-30 1982-10-18 Shell Int Research Kristallijne silicaten.
AU559968B2 (en) * 1982-04-29 1987-03-26 Mobil Oil Corp. Controlled morphology high silica zeolites
NZ206295A (en) * 1982-11-22 1986-09-10 Mobil Oil Corp Preparation of zeolites
US4552731A (en) * 1983-11-10 1985-11-12 Exxon Research And Engineering Co. Process for preparing crystalline zeolite composition ERC-2
EP0202797B1 (en) * 1985-05-14 1993-01-27 Mobil Oil Corporation A method for the synthesis of zeolites
DE3535128A1 (de) * 1985-10-02 1987-04-02 Degussa Katalytische dealkoxylierung von geminalen di-alkoxyverbindungen, geeignete katalysatoren und deren herstellung
US4952385A (en) * 1987-03-02 1990-08-28 Georgia Tech Research Corp. Ferrisilicate molecular sieve and use as a catalyst
EP0292363B1 (fr) * 1987-05-22 1993-04-21 Rhone-Poulenc Chimie Zéolites de structures MFI à base de silice et d'oxyde de titane et procédé de synthèse de celles-ci
US4797267A (en) * 1987-12-23 1989-01-10 Mobil Oil Corporation Method of producing rod-shaped ZSM-5 zeolite
NZ227524A (en) * 1988-01-07 1990-04-26 Mobil Oil Corp Preparation of crystalline gallosilicate having the structure of zeolite zsm-5
US5028406A (en) * 1989-11-29 1991-07-02 Union Oil Company Of California Crystalline galliosilicate with the mordenite structure
JP2844098B2 (ja) * 1989-12-20 1999-01-06 旭化成工業株式会社 Ｚｓｍ―５微粒子体の製造法
US5174981A (en) * 1991-10-04 1992-12-29 Mobil Oil Corp. Synthesis of crystalline ZSM-5-type material
CA2128624C (en) * 1992-01-30 2001-11-20 Georges M. K. Mathys Alkene oligomerization

Also Published As

Publication number Publication date
SG73398A1 (en) 2000-06-20
MX9303409A (es) 1994-06-30
DE69320190T2 (de) 1999-03-25
CN1089574A (zh) 1994-07-20
ZA933879B (en) 1993-12-27
CN1048001C (zh) 2000-01-05
EP0643671A1 (en) 1995-03-22
KR100282970B1 (ko) 2001-12-01
DE69320190T3 (de) 2001-08-02
KR950701886A (ko) 1995-05-17
AU4322493A (en) 1994-01-04
WO1993025476A1 (en) 1993-12-23
DE69320190D1 (de) 1998-09-10
US5783321A (en) 1998-07-21
EP0643671B1 (en) 1998-08-05
JPH07506802A (ja) 1995-07-27
EP0643671B2 (en) 2001-03-14
ES2122017T3 (es) 1998-12-16

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