EP4248160B1 - Tube bundle heat exchanger - Google Patents
Tube bundle heat exchanger Download PDFInfo
- Publication number
- EP4248160B1 EP4248160B1 EP21798942.5A EP21798942A EP4248160B1 EP 4248160 B1 EP4248160 B1 EP 4248160B1 EP 21798942 A EP21798942 A EP 21798942A EP 4248160 B1 EP4248160 B1 EP 4248160B1
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- EP
- European Patent Office
- Prior art keywords
- tube
- heat exchanger
- heat exchange
- tube bundle
- recess
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
- F28D7/16—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F1/00—Tubular elements; Assemblies of tubular elements
- F28F1/10—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses
- F28F1/12—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element
- F28F1/34—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element and extending obliquely
- F28F1/36—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element and extending obliquely the means being helically wound fins or wire spirals
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F9/00—Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
- F28F9/02—Header boxes; End plates
- F28F9/04—Arrangements for sealing elements into header boxes or end plates
- F28F9/16—Arrangements for sealing elements into header boxes or end plates by permanent joints, e.g. by rolling
- F28F9/162—Arrangements for sealing elements into header boxes or end plates by permanent joints, e.g. by rolling by using bonding or sealing substances, e.g. adhesives
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F9/00—Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
- F28F9/02—Header boxes; End plates
- F28F9/04—Arrangements for sealing elements into header boxes or end plates
- F28F9/16—Arrangements for sealing elements into header boxes or end plates by permanent joints, e.g. by rolling
- F28F9/18—Arrangements for sealing elements into header boxes or end plates by permanent joints, e.g. by rolling by welding
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F2275/00—Fastening; Joining
- F28F2275/02—Fastening; Joining by using bonding materials; by embedding elements in particular materials
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F2275/00—Fastening; Joining
- F28F2275/04—Fastening; Joining by brazing
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F2275/00—Fastening; Joining
- F28F2275/06—Fastening; Joining by welding
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F2275/00—Fastening; Joining
- F28F2275/06—Fastening; Joining by welding
- F28F2275/067—Fastening; Joining by welding by laser welding
Definitions
- the invention relates to a tube bundle heat exchanger according to the preamble of claim 1.
- US 2008/235950 A1 eg discloses such a tube bundle heat exchanger.
- Shell-and-tube heat exchangers are used to transfer heat from a first fluid to a second fluid.
- a shell-and-tube heat exchanger usually has a hollow cylinder inside which a large number of tubes are arranged.
- One of the two fluids can be passed through the tubes, the other fluid through the hollow cylinder, in particular around the tubes.
- the tubes are attached by their ends to one or more tube plates of the shell-and-tube heat exchanger along their circumference.
- the tubes are, for example, firmly bonded to the tube sheet at their ends.
- the tubes and the tube sheet are each made of aluminum or an aluminum alloy and are bonded to the tube sheet by means of laser welding.
- the intensity of the laser beam generated is over 1 MW/cm2. It is also planned that the tubes of the tube bundle heat exchanger are bonded to the tube sheet before laser welding. be connected in a form-fitting manner.
- the tube bundle heat exchanger to be manufactured has, in its finished, operational state, a large number of tubes arranged inside a hollow cylinder.
- the tube sheet can be designed as a plate and has holes whose diameters essentially correspond to the outside diameters of the tubes. Each tube is attached with one of its ends to one of these holes.
- the tubes can run in a straight line within the hollow cylinder as a straight tube heat exchanger.
- two tube plates are provided, which are arranged at opposite ends of the straight tube heat exchanger. Each tube is attached at one of its ends to one of these two tube plates.
- the tubes can also run in a U-shape within the hollow cylinder as a U-tube heat exchanger.
- a U-tube heat exchanger usually has only one tube plate. Since the tubes are bent in a U-shape in this case, they can each be attached to the same tube plate at both ends.
- the publication WO 2017/ 125 253 A1 a method for connecting tubes of a tube bundle heat exchanger to a tube sheet is known.
- the tubes are connected to the tube sheet by means of laser welding bonded together.
- a laser beam is generated and focused on a spot to be welded in a connection area between the pipe and the tube sheet.
- the laser beam is moved in such a way that it makes a first movement across the connection area and a second movement superimposed on the first movement, which is different from the first movement.
- the second movement specifically influences the melt pool dynamics and advantageously modifies a vapor capillary that is formed.
- the invention is based on the object of connecting tubes of a tube bundle heat exchanger to a tube sheet reliably and with little effort in high quality.
- the invention includes a tube bundle heat exchanger with an enveloping outer shell and at least one tube sheet, which together define an interior of the tube bundle heat exchanger.
- the tube bundle heat exchanger comprises a tube bundle with a plurality of heat exchanger tubes, which are arranged in the interior through which a first fluid can flow and are optionally supported by additional support plates.
- the heat exchanger tubes have integral ribs formed on the outside of the tube that run helically around the tube, with a rib base, rib flanks and rib tip, and a channel with a channel base is formed between the ribs.
- the tube bundle heat exchanger comprises at least one inlet on the outer shell, via which a second fluid can be introduced into the interior, and at least one outlet, via which the second fluid can be discharged from the interior.
- the tube bundle heat exchanger comprises optionally at least one connection box arranged on the at least one tube sheet for distribution, deflection or collection of the first fluid.
- the at least one tube sheet has recesses as passage points, each recess having an inner surface.
- the heat exchanger tubes protrude with their outer ribbing at least into the recesses of the tube sheet, whereby a joint gap is formed between the inner surface of a recess and the outer ribbing of a heat exchanger tube located within the recess.
- the heat exchanger tubes have a material connection with the tube sheet by means of joining material and including the external ribbing, which is formed only in a first partial section of the recess extending from the front side of a heat exchanger tube in the axial direction, in that the joining gap is filled with joining material in this first partial section, so that a second partial section of the recess remains in which the joining gap is not filled with joining material, wherein the heat exchanger tube in the region of the second partial section on the outside of the tube still has external ribbing.
- the heat exchanger tubes have external ribbing within the passage points where they enter or pass through a tube sheet. This external ribbing is enclosed by the material for a material-locking connection, thus hermetically sealing the passage of gas or liquid.
- a combination of force-locking and form-locking can also be used to advantage.
- the joining material penetrates in the axial direction only to a certain extent in a first section from the front side into the joint gap, since the outer ribs prevent free passage, as is the case with a smooth tube, for example.
- the outer ribs therefore form barriers that must be flowed around or melted. Flowing around is particularly important in the joining processes of soldering and gluing.
- the outer fins of the heat exchanger tube are partially melted.
- the melt flow is then preferably stopped at one of the outer fins as soon as the temperature of the melt is no longer sufficient to melt a fin further inside. This barrier stops the melt from penetrating further into the joint gap. In this way, a defined flow process of the joining material is provided during the joining process, which completely closes the joint point at or near the front of the tube.
- a heat exchanger tube can optionally have an internal structure.
- the internal structure can be designed in the form of an internally rotating helix with a predetermined twist angle.
- the pitch of the rotating external fins can be the same, less than or greater than the pitch of the rotating helix specified by the twist angle.
- the two structures can therefore differ in that the design of the external fins and the internal structure can be designed independently of one another and thus optimized in order to ensure a material bond between the outside of a heat exchanger tube and the vessel wall.
- the ratio of the maximum structural height of the external fins and the maximum structural height of the internal structure is preferably in the range of 1.25 to 5 for condenser tubes and preferably in the range of 0.5 to 2 for evaporator tubes.
- the tube bundle heat exchangers according to the invention can be built much more compactly.
- the external finning continues into the tube sheet, which means that the number of heat exchanger tubes per unit can be significantly reduced.
- the finned tubes enable more efficient use of energy or the reduction of filling quantities, which reduces operating costs.
- the invention is based on the idea that a material-locking connection between the heat exchanger tubes and the tube sheets can be achieved in a particularly reliable and high-quality manner with little effort.
- a heat exchanger tube with its external ribbing enters the tube sheet or passes through the tube sheet. The external ribbing then remains immediately adjacent to the material-locking connection between the tubes and the tube sheet.
- the first section filled with joining material can be less than 70% of the length of the entire joint gap in the axial direction.
- the filled first section of the joint gap advantageously comprises only less than 50% of the total length.
- a filling level of 20% of the first section can be sufficient to produce a fluid-tight, material-tight connection.
- the clear width between the fin tips of a heat exchanger tube and the inner surface of the recess can be a maximum of 30% of the fin height measured from the channel base to the fin tip.
- the barrier effect of the outer fins is increased by this clear width.
- the joining material can be introduced in a targeted manner via this clear width of the joining gap to form the filled first section.
- Another flow channel for the joining material is the channel formed by the integral ribs that are formed in a helical shape. The channel cross-section is, however, determined by the rib height and the distance between adjacent ribs and is usually smaller than the selected clear width.
- the material connection can advantageously be designed to be gas-tight and pressure-resistant.
- a hermetic seal is important to prevent fluid exchange with the environment in every operating mode.
- the heat exchanger tubes in the passage points have an inner tube diameter D2 which is larger than the inner tube diameter D1 of the heat exchanger tubes outside the passage points.
- the process involves an expansion of the heat exchanger tube, resulting in an increased internal passage diameter D2.
- the expansion then causes the external fins to be squeezed within a passage point. Nevertheless, the material-tight connection ensures a stable hermetic seal.
- the heat exchanger tubes can be soldered, glued or welded into the tube sheet.
- connection may also be others which reliably join the heat exchanger tubes to the tube sheet by means of a material-locking connection.
- the external ribbing on the outside of the heat exchanger tubes can preferably run in the circumferential direction or in the axial direction parallel to the tube axis.
- the outside of the heat exchanger tubes can have spirally circumferential external ribbing. With spirally circumferential external ribbing, only a residual gap and the channel spirally circumferential with external ribbing must be reliably sealed by the material-locking connection.
- At least one first heat exchanger tube can consist of a first material and at least one second heat exchanger tube can consist of a second material that differs from the first material.
- steel tubes with particularly high strength can offer a particular advantage.
- Copper tubes optimize efficient heat transfer.
- Other materials such as titanium, aluminum, aluminum alloys and copper-nickel alloys, can also be considered.
- Fig. 1 shows a schematic side view of a tube bundle heat exchanger 1 with an enveloping outer shell 2 and two tube plates 3, which together define an interior 4 of the tube bundle heat exchanger 1.
- the tube bundle heat exchanger 1 comprises a tube bundle with a large number of heat exchanger tubes 5, which are arranged in the interior 4 and through which a first fluid for heat transfer can flow and are supported by additional support plates 6. Such support plates 6 are often also used as baffles for the fluid flow.
- the tube bundle heat exchanger 1 also comprises connection boxes 7, which distribute, divert or collect the first fluid inside the heat exchanger tubes as required.
- a heat exchanger tube 5 with outer fins 51 is enlarged.
- integral ribs 51 are formed on the outside of the pipe and run helically around the pipe axis A.
- Fig. 2 shows schematically a front view of a section of a tube sheet 3 with passages 31.
- the recess in the Tube sheet 3 is preferably just large enough for a heat exchanger tube 5 with its external ribbing 51 to be inserted and connected there in a materially bonded manner.
- Welded, adhesive and soldered connections as a materially bonded connection 20 can be made at the passage point 31, starting from the front side, over a first section of the wall thickness of a tube sheet 3 and form a fluid-tight connection.
- a Figure 2 not visible, unfilled remainder of the joint gap in the tube sheet wall 3 preserved.
- Fig. 3 shows schematically a vertical section of the tube sheet 3 in the plane of the passage point 31 of a heat exchanger tube 5.
- the heat exchanger tube 5 shown has an external ribbing 51 on the outside.
- the heat exchanger tube 5 passes through the tube sheet 3 at the recess 31 as a passage point in the illustrated embodiment. At this passage point 31, the heat exchanger tube 5 has a continuous external ribbing 51.
- a Figure 3 A material-locking connection 20 that has not yet been made, for example in the form of a weld seam with the tube sheet 3 that runs around the circumference of the tube, is located in a section of the joint gap 10 after the joining process.
- advantageous new intermetallic phases can form in the melt bath at the weld point 20.
- Laser welding is a particularly suitable method for producing a material-locking connection with a locally limited melt flow.
- Fig. 4 shows schematically a detailed view of a section of a material connection 20 of the tube sheet 3 with a heat exchanger tube 5.
- the heat exchanger tube 5 is inserted in the direction of the tube axis A into the recess 31 made in the tube sheet 3 and ends with the front side 53 with the outer tube sheet surface.
- the heat exchanger tubes 5 have integral ribs 51 formed on the outside of the tube in a helical shape with a rib base 511, rib flanks 512 and rib tip 513.
- a channel 52 with a channel base 521 is formed between adjacent ribs 51.
- a weld seam is shown as a material-locking connection 20, which is formed, for example, during laser welding. If necessary, suitable welding additives are used on the material side during joining. In this way, the material flow and the quantity can be precisely tailored to the desired joint connection.
- certain areas of the tube sheet 3 as well as some outer ribs 51 on the heat exchanger tube 5 are at least partially melted by the heat input of a laser and integrated as joining material 20.
- the melt enters the joining gap 10 starting from the front side 53, but is blocked after a certain penetration depth, so that only a first front-side section 101 of the joining gap 10 is filled, including the outer ribbing 51. Further passage of the melt is prevented by a rib 51, which is no longer melted or flowed around due to the decreasing temperature at the melt front and thus acts as a barrier. In this way, a defined flow process of the joining material 20 is provided during the joining process, which can completely close the joint point already at or near the pipe front side 53.
- the heat exchanger tubes 5 thus have a material connection 20 with the tube sheet 3, which is formed only in a first partial section 101 of the recess 31 extending in the axial direction from the end face 53 of a heat exchanger tube 5.
- a second partial section 102 of the recess 31 is not filled with joining material.
- the heat exchanger tube 5 also has an external ribbing 51 on the outside of the tube.
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
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- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
- Details Of Heat-Exchange And Heat-Transfer (AREA)
Description
Die Erfindung betrifft einen Rohrbündelwärmetauscher gemäß dem Oberbegriff des Anspruchs 1.
Rohrbündelwärmetauscher dienen dazu, Wärme von einem ersten Fluid auf ein zweites Fluid zu übertragen. Zu diesem Zweck weist ein Rohrbündelwärmetauscher zumeist einen Hohlzylinder auf, in dessen Innerem eine Vielzahl von Rohren angeordnet ist. Eines der beiden Fluide kann durch die Rohre geleitet werden, das andere Fluid durch den Hohlzylinder, insbesondere um die Rohre herum. Die Rohre sind mit ihren Enden an einem Rohrboden oder mehreren Rohrböden des Rohrbündelwärmetauschers entlang ihres Umfangs befestigt.Shell-and-tube heat exchangers are used to transfer heat from a first fluid to a second fluid. For this purpose, a shell-and-tube heat exchanger usually has a hollow cylinder inside which a large number of tubes are arranged. One of the two fluids can be passed through the tubes, the other fluid through the hollow cylinder, in particular around the tubes. The tubes are attached by their ends to one or more tube plates of the shell-and-tube heat exchanger along their circumference.
Im Zuge des Herstellungsprozesses eines Rohrbündelwärmetauschers werden die Rohre mit ihren Enden beispielsweise stoffschlüssig mit dem Rohrboden verbunden. Generell ist es wünschenswert, eine Möglichkeit bereitzustellen, um Rohre eines Rohrbündelwärmetauschers mit einem Rohrboden des Rohrbündelwärmetauschers auf aufwandsarme und kostengünstige Weise in hoher Qualität miteinander zu verbinden.During the manufacturing process of a tube bundle heat exchanger, the tubes are, for example, firmly bonded to the tube sheet at their ends. In general, it is desirable to provide a way to connect tubes of a tube bundle heat exchanger to a tube sheet of the tube bundle heat exchanger in a low-effort and cost-effective manner with high quality.
Aus der Druckschrift
Der herzustellende Rohrbündelwärmetauscher weist in seinem gefertigten, betriebsbereiten Zustand eine Vielzahl von Rohren auf, die im Inneren eines Hohlzylinders angeordnet sind. Der Rohrboden kann als eine Platte ausgebildet sein und weist Bohrungen auf, welche in ihrem Durchmesser im Wesentlichen den Außendurchmessern der Rohre entsprechen. Jedes Rohr ist mit einem seiner Enden jeweils an einer dieser Bohrungen befestigt.The tube bundle heat exchanger to be manufactured has, in its finished, operational state, a large number of tubes arranged inside a hollow cylinder. The tube sheet can be designed as a plate and has holes whose diameters essentially correspond to the outside diameters of the tubes. Each tube is attached with one of its ends to one of these holes.
Die Rohre können innerhalb des Hohlzylinders als Geradrohr-Wärmetauscher geradlinig verlaufen. In diesem Fall sind zwei Rohrböden vorgesehen, welche an gegenüberliegenden Enden des Geradrohr-Wärmetauschers angeordnet sind. Jedes Rohr ist mit jeweils einem seiner Enden dabei an jeweils einem dieser zwei Rohrböden befestigt.The tubes can run in a straight line within the hollow cylinder as a straight tube heat exchanger. In this case, two tube plates are provided, which are arranged at opposite ends of the straight tube heat exchanger. Each tube is attached at one of its ends to one of these two tube plates.
Die Rohre können innerhalb des Hohlzylinders auch als U-Rohr-Wärmetauscher U-förmig verlaufen. Ein derartiger U-Rohr-Wärmetauscher weist üblicherweise nur einen Rohrboden auf. Da die Rohre in diesem Fall U-förmig gebogen sind, können sie jeweils mit ihren beiden Enden an demselben Rohrboden befestigt werden.The tubes can also run in a U-shape within the hollow cylinder as a U-tube heat exchanger. Such a U-tube heat exchanger usually has only one tube plate. Since the tubes are bent in a U-shape in this case, they can each be attached to the same tube plate at both ends.
Aus der
Des Weiteren ist aus der Druckschrift
Der Erfindung liegt die Aufgabe zugrunde, Rohre eines Rohrbündelwärmetauschers mit einem Rohrboden zuverlässig und in aufwandsarmer Weise in hoher Qualität zu verbinden.The invention is based on the object of connecting tubes of a tube bundle heat exchanger to a tube sheet reliably and with little effort in high quality.
Die Erfindung wird durch die Merkmale des Anspruchs 1 wiedergegeben. Die weiteren rückbezogenen Ansprüche betreffen vorteilhafte Aus- und Weiterbildungen der Erfindung.The invention is represented by the features of
Die Erfindung schließt einen Rohrbündelwärmetauscher mit einem umhüllenden Außenmantel sowie zumindest einem Rohrboden ein, die zusammen einen Innenraum des Rohrbündelwärmetauschers definieren. Der Rohrbündelwärmetauscher umfasst ein Rohrbündel mit einer Vielzahl von Wärmeaustauscherrohren, die im Innenraum angeordnet von einem ersten Fluid durchströmbar sind und wahlweise durch zusätzliche Stützbleche gestützt werden. Die Wärmeaustauscherrohre weisen auf der Rohraußenseite ausgeformte schraubenlinienförmig umlaufende integrale Rippen mit Rippenfuß, Rippenflanken und Rippenspitze auf und zwischen den Rippen ist ein Kanal mit einem Kanalgrund ausgebildet. Der Rohrbündelwärmetauscher umfasst zumindest einen Einlass am Außenmantel, über den ein zweites Fluid in den Innenraum eingeleitet werden kann, und zumindest einen Auslass, über den das zweite Fluid aus dem Innenraum abgeleitet werden kann. Der Rohrbündelwärmetauscher umfasst wahlweise mindestens einen an dem mindestens einen Rohrboden angeordneten Anschlusskasten zur Verteilung, Umlenkung oder Sammlung des ersten Fluids. Der mindestens eine Rohrboden weist Ausnehmungen als Durchtrittstellen auf, wobei jede Ausnehmung eine innere Oberfläche besitzt. Die Wärmeaustauscherrohre ragen mit ihrer Außenberippung in die Ausnehmungen des Rohrbodens zumindest hinein, wodurch ein Fügespalt jeweils zwischen der inneren Oberfläche einer Ausnehmung und der innerhalb der Ausnehmung befindlichen Außenberippung eines Wärmeaustauscherrohrs ausgebildet ist. Die Wärmeaustauscherrohre weisen mittels Fügematerial und unter Einbeziehung der Außenberippung eine stoffschlüssige Verbindung mit dem Rohrboden auf, welche lediglich in einem sich von der Stirnseite eines Wärmeaustauscherrohrs in axialer Richtung erstreckenden, ersten Teilabschnitt der Ausnehmung ausgebildet ist, indem in diesem ersten Teilabschnitt der Fügespalt mit Fügematerial ausgefüllt ist, so dass ein zweiter Teilabschnitt der Ausnehmung verbleibt, in dem der Fügespalt nicht mit Fügematerial ausgefüllt ist, wobei das Wärmeaustauscherrohr im Bereich des zweiten Teilabschnitts auf der Rohraußenseite weiterhin eine Außenberippung aufweist.The invention includes a tube bundle heat exchanger with an enveloping outer shell and at least one tube sheet, which together define an interior of the tube bundle heat exchanger. The tube bundle heat exchanger comprises a tube bundle with a plurality of heat exchanger tubes, which are arranged in the interior through which a first fluid can flow and are optionally supported by additional support plates. The heat exchanger tubes have integral ribs formed on the outside of the tube that run helically around the tube, with a rib base, rib flanks and rib tip, and a channel with a channel base is formed between the ribs. The tube bundle heat exchanger comprises at least one inlet on the outer shell, via which a second fluid can be introduced into the interior, and at least one outlet, via which the second fluid can be discharged from the interior. The tube bundle heat exchanger comprises optionally at least one connection box arranged on the at least one tube sheet for distribution, deflection or collection of the first fluid. The at least one tube sheet has recesses as passage points, each recess having an inner surface. The heat exchanger tubes protrude with their outer ribbing at least into the recesses of the tube sheet, whereby a joint gap is formed between the inner surface of a recess and the outer ribbing of a heat exchanger tube located within the recess. The heat exchanger tubes have a material connection with the tube sheet by means of joining material and including the external ribbing, which is formed only in a first partial section of the recess extending from the front side of a heat exchanger tube in the axial direction, in that the joining gap is filled with joining material in this first partial section, so that a second partial section of the recess remains in which the joining gap is not filled with joining material, wherein the heat exchanger tube in the region of the second partial section on the outside of the tube still has external ribbing.
Mit anderen Worten: Die Wärmeaustauscherrohre weisen innerhalb der Durchtrittsstellen, an denen sie in einen Rohrboden ein oder durch einen Rohrboden hindurchtreten eine Außenberippung auf. Diese Außenberippung wird durch das Material für eine stoffschlüssige Verbindung umschlossen und so ein Durchtritt von Gas oder Flüssigkeit hermetisch abgedichtet. Zum reinen Stoffschluss können auch Kombination zusammen mit Kraftschluss und Formschluss in vorteilhafter Weise eingesetzt werden.In other words: The heat exchanger tubes have external ribbing within the passage points where they enter or pass through a tube sheet. This external ribbing is enclosed by the material for a material-locking connection, thus hermetically sealing the passage of gas or liquid. For pure material-locking, a combination of force-locking and form-locking can also be used to advantage.
Das Fügematerial dringt in axialer Richtung nur zu einem gewissen Grad in einem ersten Teilabschnitt von der Stirnseite her in den Fügespalt ein, da die Außenrippen einem freien Durchtritt, wie beispielsweise bei einem Glattrohr gegeben, entgegenstehen. Die Außenrippen bilden folglich Barrieren, die umströmt oder aufgeschmolzen werden müssen. Das Umströmen ist insbesondere bei den Fügeverfahren Löten und Kleben von besonderer Bedeutung. Beim Schweißen wird stirnseitig die Außenberippung des Wärmeaustauscherrohrs zum Teil mit aufgeschmolzen. Der Schmelzefluss wird dann bevorzugt an einer der Außenrippen gestoppt, sobald die Temperatur der Schmelze nicht mehr ausreicht, eine weiter innen liegende Rippe aufzuschmelzen. Diese Barriere stoppt das weitere Eindringen der Schmelze im Fügespalt. Auf diese Weise ist ein definierter Fließvorgang des Fügematerials beim Fügevorgang gegeben, der die Fügestelle bereits an oder in der Nähe der Rohrstirnseite vollständig verschließt.The joining material penetrates in the axial direction only to a certain extent in a first section from the front side into the joint gap, since the outer ribs prevent free passage, as is the case with a smooth tube, for example. The outer ribs therefore form barriers that must be flowed around or melted. Flowing around is particularly important in the joining processes of soldering and gluing. During welding, the outer fins of the heat exchanger tube are partially melted. The melt flow is then preferably stopped at one of the outer fins as soon as the temperature of the melt is no longer sufficient to melt a fin further inside. This barrier stops the melt from penetrating further into the joint gap. In this way, a defined flow process of the joining material is provided during the joining process, which completely closes the joint point at or near the front of the tube.
Zur Außenberippung kann ein Wärmeaustauscherrohr zudem wahlweise eine Innenstruktur aufweisen. Die Innenstruktur kann in Gestalt einer innen umlaufenden Helix mit einem vorgegebenen Drallwinkel ausgeführt sein. Für den Fall, dass die Außenseite der Wärmeaustauscherrohre eine spiralig umlaufende Außenberippung aufweist, kann die Steigung der umlaufenden Außenberippung gleich, geringer oder größer als die durch den Drallwinkel vorgegebene Steigung der umlaufenden Helix ausgebildet sein. Beide Strukturen können sich folglich dahingehend unterscheiden, dass zur stoffschlüssigen Verbindung der Außenseite eines Wärmeaustauscherrohrs mit der Behälterwandung die Gestaltung der Außenberippung und der Innenstruktur unabhängig voneinander gestaltet und so optimiert werden können.In addition to the external fins, a heat exchanger tube can optionally have an internal structure. The internal structure can be designed in the form of an internally rotating helix with a predetermined twist angle. In the event that the outside of the heat exchanger tubes has spirally rotating external fins, the pitch of the rotating external fins can be the same, less than or greater than the pitch of the rotating helix specified by the twist angle. The two structures can therefore differ in that the design of the external fins and the internal structure can be designed independently of one another and thus optimized in order to ensure a material bond between the outside of a heat exchanger tube and the vessel wall.
Zur Optimierung des Wärmeaustauschs sind beiden Strukturen jedoch gewisse Grenzen vorgegeben. So liegt das Verhältnis der maximalen Strukturhöhe der Außenberippung und der maximalen Strukturhöhe der Innenstruktur für Verflüssigerrohre bevorzugt im Bereich von 1,25 bis 5 und für Verdampferrohre bevorzugt im Bereich von 0,5 bis 2.However, to optimize heat exchange, certain limits are imposed on both structures. For example, the ratio of the maximum structural height of the external fins and the maximum structural height of the internal structure is preferably in the range of 1.25 to 5 for condenser tubes and preferably in the range of 0.5 to 2 for evaporator tubes.
Vor allem Investitionskosten sollen gespart werden, da die erfindungsgemäßen Rohrbündelwärmetauscher wesentlich kompakter gebaut werden können. Hierbei setzt sich die Außenberippung bis in den Rohrboden hinein fort, wodurch die Anzahl der Wärmeaustauscherrohre pro Einheit deutlich reduziert werden kann. Je nach Anforderung ermöglichen die Rippenrohre einen effizienteren Energieeinsatz oder die Reduzierung von Füllmengen, was die Betriebskosten senkt.Above all, investment costs are to be saved, since the tube bundle heat exchangers according to the invention can be built much more compactly. The external finning continues into the tube sheet, which means that the number of heat exchanger tubes per unit can be significantly reduced. Depending on the requirements, the finned tubes enable more efficient use of energy or the reduction of filling quantities, which reduces operating costs.
Die Erfindung geht dabei von der Überlegung aus, dass eine stoffschlüssige Verbindung der Wärmeaustauscherrohre mit den Rohrböden besonders zuverlässig und aufwandsarm in hoher Qualität erzielt wird. Erfindungsgemäß tritt ein Wärmeaustauscherrohr mit seiner außenseitigen Außenberippung in den Rohrboden ein oder durch den Rohrboden hindurch. An die stoffschlüssige Verbindung der Rohre mit dem Rohrboden verbleibt dann unmittelbar angrenzend die Außenberippung erhalten. Dies hat den besonderen Vorteil, dass im Inneren des Rohrbündelwärmetauschers die Wärmeaustauscherrohre für eine effiziente Wärmeübertragung eine durchgängige Außenberippung aufweisen.The invention is based on the idea that a material-locking connection between the heat exchanger tubes and the tube sheets can be achieved in a particularly reliable and high-quality manner with little effort. According to the invention, a heat exchanger tube with its external ribbing enters the tube sheet or passes through the tube sheet. The external ribbing then remains immediately adjacent to the material-locking connection between the tubes and the tube sheet. This has the particular advantage that the heat exchanger tubes inside the tube bundle heat exchanger have continuous external ribbing for efficient heat transfer.
Bei einer vorteilhaften Ausführungsform der Erfindung kann der mit Fügematerial ausgefüllte erste Teilabschnitt in axialer Richtung weniger als 70 % der Länge des gesamten Fügespalts betragen. Vorteilhafterweise umfasst der ausgefüllte erste Teilabschnitt des Fügespalts lediglich weniger als 50 % der Gesamtlänge. Insbesondere bei Schweißverbindungen können bereits auch 20 % Füllgrad des ersten Teilabschnitts genügen, um eine fluiddichte stoffschlüssige Verbindung herzustellen.In an advantageous embodiment of the invention, the first section filled with joining material can be less than 70% of the length of the entire joint gap in the axial direction. The filled first section of the joint gap advantageously comprises only less than 50% of the total length. In particular in the case of welded joints, a filling level of 20% of the first section can be sufficient to produce a fluid-tight, material-tight connection.
Vorteilhafterweise kann die lichte Weite zwischen den Rippenspitzen eines Wärmeaustauscherrohrs und der inneren Oberfläche der Ausnehmung maximal 30 % der vom Kanalgrund bis zur Rippenspitze gemessenen Rippenhöhe betragen. Über diese lichte Weite wird die Barrierewirkung der Außenrippen variiert. Insbesondere bei den Fügeverfahren Löten und Kleben kann das Fügematerial über diese lichte Weite des Fügespalts zur Ausbildung des gefüllten ersten Teilabschnitts gezielt eingebracht werden. Ein weiterer Fließkanal für das Fügematerial stellt zudem der durch die ausgeformten schraubenlinienförmig umlaufenden integralen Rippen gebildete Kanal dar. Der Kanalquerschnitt ist allerdings durch die Rippenhöhe und des Abstandes benachbarter Rippen vorgegeben und üblicherweise gegenüber der gewählten lichten Weite geringer ausgeprägt.Advantageously, the clear width between the fin tips of a heat exchanger tube and the inner surface of the recess can be a maximum of 30% of the fin height measured from the channel base to the fin tip. The barrier effect of the outer fins is increased by this clear width. varies. Particularly with the joining processes of soldering and gluing, the joining material can be introduced in a targeted manner via this clear width of the joining gap to form the filled first section. Another flow channel for the joining material is the channel formed by the integral ribs that are formed in a helical shape. The channel cross-section is, however, determined by the rib height and the distance between adjacent ribs and is usually smaller than the selected clear width.
Vorteilhafterweise kann die stoffschlüssige Verbindung gasdicht und druckbeständig ausgeführt sein. Über die Funktionen hinsichtlich mechanischer Stabilität verbunden mit einer effizienten Wärmeübertragung hinaus ist eine hermetische Abdichtung zur Verhinderung eines Fluidaustausches mit der Umgebung in jedem Betriebsmodus wichtig.The material connection can advantageously be designed to be gas-tight and pressure-resistant. In addition to the functions of mechanical stability combined with efficient heat transfer, a hermetic seal is important to prevent fluid exchange with the environment in every operating mode.
Bei einer vorteilhaften Ausführungsform der Erfindung weisen die Wärmeaustauscherrohre in den Durchtrittsstellen einen Rohrinnendurchmesser D2 auf, der größer ist als der Rohrinnendurchmesser D1 der Wärmeaustauscherrohre außerhalb der Durchtrittsstellen.In an advantageous embodiment of the invention, the heat exchanger tubes in the passage points have an inner tube diameter D2 which is larger than the inner tube diameter D1 of the heat exchanger tubes outside the passage points.
Wenn die Wärmeaustauscherrohre innerhalb der Durchtrittsstellen, an denen sie in den Rohrboden ein oder durch den Rohrboden hindurchtreten immer noch eine Außenberippung aufweisen, liegt verfahrensseitig eine Aufweitung des Wärmeaustauscherrohrs mit der Folge eines vergrößerten Durchtrittsinnendurchmessers D2 zugrunde. Durch eine Aufweitung wird dann innerhalb einer Durchtrittsstelle die Außenberippung gequetscht. Dennoch sorgt die stoffschlüssige Verbindung für eine stabile hermetische Abdichtung.If the heat exchanger tubes still have external fins within the passage points where they enter or pass through the tube sheet, the process involves an expansion of the heat exchanger tube, resulting in an increased internal passage diameter D2. The expansion then causes the external fins to be squeezed within a passage point. Nevertheless, the material-tight connection ensures a stable hermetic seal.
Bei einer vorteilhaften Ausführungsform der Erfindung können die Wärmeaustauscherrohre in den Rohrboden gelötet, geklebt oder geschweißt sein.In an advantageous embodiment of the invention, the heat exchanger tubes can be soldered, glued or welded into the tube sheet.
Zu den genannten bevorzugten Verbindungsarten können auch weitere hinzutreten, welche die Wärmeaustauscherrohre mittels einer stoffschlüssigen Verbindung mit dem Rohrboden zuverlässig fügen.In addition to the preferred types of connection mentioned above, there may also be others which reliably join the heat exchanger tubes to the tube sheet by means of a material-locking connection.
Prinzipiell kann die Außenberippung auf der Außenseite der Wärmeaustauscherrohre bevorzugt in umfänglicher Richtung oder in axialer Richtung parallel zur Rohrachse verlaufen. Bei einer vorteilhaften Ausführungsform der Erfindung kann die Außenseite der Wärmeaustauscherrohre eine spiralig umlaufende Außenberippung aufweisen. Bei einer spiraligen Außenberippung muss lediglich ein Restspalt und der spiralig mit einer Außenberippung umlaufende Kanal durch die stoffschlüssige Verbindung zuverlässig abgedichtet werden.In principle, the external ribbing on the outside of the heat exchanger tubes can preferably run in the circumferential direction or in the axial direction parallel to the tube axis. In an advantageous embodiment of the invention, the outside of the heat exchanger tubes can have spirally circumferential external ribbing. With spirally circumferential external ribbing, only a residual gap and the channel spirally circumferential with external ribbing must be reliably sealed by the material-locking connection.
Auch wenn regelmäßig für die Wärmeaustauscherrohre ein geeignetes einheitliches Material bevorzugt ist, kann in vorteilhafter Ausgestaltung der Erfindung mindestens ein erstes Wärmeaustauscherrohr aus einem ersten Material bestehen und mindestens ein zweites Wärmeaustauscherrohr aus einem zweiten Material bestehen, welches sich vom ersten Material unterscheidet. Hinsichtlich der mechanischen Stabilität können Stahlrohre mit besonders hoher Festigkeit einen besonderen Vorteil bieten. Kupferrohre bewirken hingegen eine Optimierung hinsichtlich einer effizienten Wärmeübertragung. Auch andere Materialien, wie beispielsweise Titan, Aluminium, Aluminiumlegierungen sowie Kupfer-Nickel-Legierungen kommen in Betracht.Even if a suitable uniform material is generally preferred for the heat exchanger tubes, in an advantageous embodiment of the invention at least one first heat exchanger tube can consist of a first material and at least one second heat exchanger tube can consist of a second material that differs from the first material. With regard to mechanical stability, steel tubes with particularly high strength can offer a particular advantage. Copper tubes, on the other hand, optimize efficient heat transfer. Other materials, such as titanium, aluminum, aluminum alloys and copper-nickel alloys, can also be considered.
Ausführungsbeispiele der Erfindung werden anhand der schematischen Zeichnungen näher erläutert.Embodiments of the invention are explained in more detail with reference to the schematic drawings.
Darin zeigen:
- Fig. 1
- schematisch eine Seitenansicht eines Rohrbündelwärmetauschers mit Detailansicht eines Wärmeaustauscherrohrs mit Außenrippen,
- Fig. 2
- schematisch eine Frontansicht eines Ausschnitts eines Rohrbodens mit Du rchtrittsstelle,
- Fig.3
- schematisch einen senkrechten Schnitt des Rohrbodens in der Ebene der Durchtrittsstelle der Wärmeaustauscherrohre, und
- Fig. 4
- schematisch eine Detailansicht eines Schnittes einer stoffschlüssigen Verbindung des Rohrbodens mit einem Wärmeaustauscherrohr.
- Fig. 1
- schematically a side view of a tube bundle heat exchanger with detailed view of a heat exchanger tube with external fins,
- Fig. 2
- schematically a front view of a section of a tube sheet with passage point,
- Fig.3
- schematically a vertical section of the tube sheet in the plane of the passage point of the heat exchanger tubes, and
- Fig. 4
- schematically a detailed view of a section of a material connection of the tube sheet with a heat exchanger tube.
Einander entsprechende Teile sind in allen Figuren mit denselben Bezugszeichen versehen.Corresponding parts are provided with the same reference numerals in all figures.
Die Wärmeaustauscherrohre 5 weisen auf der Rohraußenseite ausgeformte schraubenlinienförmig umlaufende integrale Rippen 51 mit Rippenfuß 511, Rippenflanken 512 und Rippenspitze 513 auf. Zwischen benachbarten Rippen 51 ist ein Kanal 52 mit einem Kanalgrund 521 ausgebildet. In
Die Wärmeaustauscherrohre 5 weisen so eine stoffschlüssige Verbindung 20 mit dem Rohrboden 3 auf, welche lediglich in einem sich von der Stirnseite 53 eines Wärmeaustauscherrohrs 5 in axialer Richtung erstreckenden, ersten Teilabschnitt 101 der Ausnehmung 31 ausgebildet ist. Ein zweiter Teilabschnitt 102 der Ausnehmung 31 ist nicht mit Fügematerial ausgefüllt. Im zweiten Teilabschnitt 102 weist Wärmeaustauscherrohr 5 auf der Rohraußenseite weiterhin eine Außenberippung 51 auf.The
- 11
- Rohrbündelwärmetauschershell-and-tube heat exchangers
- 22
- Außenmantelouter shell
- 33
- Rohrbodentube sheet
- 3131
- Ausnehmung, Durchtrittstellerecess, passage point
- 311311
- innere Oberfläche der Ausnehmunginner surface of the recess
- 44
- Innenrauminterior
- 55
- Wärmeaustauscherrohrheat exchanger tube
- 5151
- integrale Rippen, Außenrippenintegral ribs, external ribs
- 511511
- Rippenfußrib foot
- 512512
- Rippeflankerib flank
- 513513
- Rippespitzerib tip
- 5252
- Kanalchannel
- 521521
- Kanalgrundcanal bottom
- 5353
- Stirnseitefront side
- 66
- Stützblechsupport plate
- 77
- Anschlusskastenjunction box
- 88
- Einlassinlet
- 99
- Auslassoutlet
- 1010
- Fügespaltjoint gap
- 101101
- ersten Teilabschnittfirst section
- 102102
- zweiter Teilabschnittsecond section
- 2020
- stoffschlüssige Verbindung, Fügematerialmaterial-locking connection, joining material
- AA
- Rohrachse, axiale Richtungpipe axis, axial direction
- D1, D2D1, D2
- Rohrinnendurchmesserpipe inner diameter
- PfeilArrow
- Fluidflussfluid flow
Claims (6)
- Tube bundle heat exchanger (1) having a surrounding outer covering (2) and at least one tube base (3) which together define an inner space (4) of the tube bundle heat exchanger (1), comprising- a tube bundle having a large number of heat exchange tubes (5) which in a state arranged in the inner space (4) can be flowed through by a first fluid and are optionally supported by additional metal support sheets (6),
wherein the heat exchange tubes (5) have integral ribs (51) which are formed on the outer side of the tube and which extend in a helical line and which have a rib base (511), rib flanks (512) and a rib tip (513) and between the ribs (51) a channel (52) having a channel base (521) is formed,- on the outer covering (2) at least one inlet (8), via which a second fluid can be introduced into the inner space (4), and at least one outlet (9), via which the second fluid can be discharged from the inner space (4),- optionally at least one connection box (7) which is arranged on the at least one tube base (3) for distributing, redirecting or collecting the first fluid,wherein the at least one tube base (3) has recesses (31) as passage locations, wherein each recess (31) has an inner surface (311),characterised in that- the heat exchange tubes (5) at least protrude with the outer ribbing (51) thereof into the recesses (31) of the tube base (3), whereby a joint gap (10) is formed in each case between the inner surface (311) of a recess (31) and the outer ribbing (51), which is located inside the recess (31), of a heat exchange tube (5),- in that the heat exchange tubes (5) by means of joining material (20) and incorporating the outer ribbing (51) have a materially engaging connection (20) to the tube base (3), which is formed only in a first part-portion (101), which extends from the front face (53) of a heat exchange tube (5) in an axial direction (A), of the recess (31) by the joint gap (10) being filled with joining material (20) in this first part-portion (101) so that a second part-portion (102), in which the joint gap (10) is not filled with joining material, of the recess (31) remains, wherein the heat exchange tube (5) in the region of the second part-portion (102) at the outer tube side further has an outer ribbing (51) . - Tube bundle heat exchanger (1) according to claim 1, characterised in that the first part-portion (101) which is filled with the joining material (20) in an axial direction (A) is less than 70% of the length of the entire joint gap (10) .
- Tube bundle heat exchanger (1) according to claim 1 or 2, characterised in that the clear width between the rib tips (513) of a heat exchange tube (5) and the inner surface (311) of the recess (31) is a maximum of 30% of the rib height measured from the channel base (521) up to the rib tip (513).
- Tube bundle heat exchanger (1) according to any one of claims 1 to 3, characterised in that the materially engaging connection (20) is configured to be gas-tight and pressure-resistant.
- Tube bundle heat exchanger (1) according to any one of claims 1 to 4, characterised in that the heat exchange tubes (5) have in the recesses as passage locations (31) a tube inner diameter D2 which is greater than the tube inner diameter D1 of the heat exchange tubes (5) outside the passage locations (31).
- Tube bundle heat exchanger (1) according to any one of claims 1 to 5, characterised in that the heat exchange tubes (5) are soldered, adhesively bonded or welded in the tube base (3).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SI202130241T SI4248160T1 (en) | 2020-11-17 | 2021-10-21 | HEAT EXCHANGER WITH TUBE BUNDLE |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102020007022 | 2020-11-17 | ||
| PCT/EP2021/000127 WO2022106045A1 (en) | 2020-11-17 | 2021-10-21 | Tube bundle heat exchanger |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP4248160A1 EP4248160A1 (en) | 2023-09-27 |
| EP4248160B1 true EP4248160B1 (en) | 2024-10-02 |
Family
ID=78413965
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP21798942.5A Active EP4248160B1 (en) | 2020-11-17 | 2021-10-21 | Tube bundle heat exchanger |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US12345476B2 (en) |
| EP (1) | EP4248160B1 (en) |
| JP (1) | JP7583930B2 (en) |
| KR (1) | KR20230110247A (en) |
| CN (1) | CN116670459A (en) |
| CA (1) | CA3195755A1 (en) |
| HU (1) | HUE069375T2 (en) |
| MX (1) | MX2023005414A (en) |
| PL (1) | PL4248160T3 (en) |
| PT (1) | PT4248160T (en) |
| SI (1) | SI4248160T1 (en) |
| TW (1) | TWI899355B (en) |
| WO (1) | WO2022106045A1 (en) |
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2021
- 2021-10-21 CA CA3195755A patent/CA3195755A1/en active Pending
- 2021-10-21 KR KR1020237010569A patent/KR20230110247A/en active Pending
- 2021-10-21 PT PT217989425T patent/PT4248160T/en unknown
- 2021-10-21 HU HUE21798942A patent/HUE069375T2/en unknown
- 2021-10-21 US US18/246,410 patent/US12345476B2/en active Active
- 2021-10-21 EP EP21798942.5A patent/EP4248160B1/en active Active
- 2021-10-21 SI SI202130241T patent/SI4248160T1/en unknown
- 2021-10-21 MX MX2023005414A patent/MX2023005414A/en unknown
- 2021-10-21 CN CN202180074805.9A patent/CN116670459A/en active Pending
- 2021-10-21 PL PL21798942.5T patent/PL4248160T3/en unknown
- 2021-10-21 JP JP2023522815A patent/JP7583930B2/en active Active
- 2021-10-21 WO PCT/EP2021/000127 patent/WO2022106045A1/en not_active Ceased
- 2021-10-21 TW TW110139129A patent/TWI899355B/en active
Also Published As
| Publication number | Publication date |
|---|---|
| SI4248160T1 (en) | 2025-03-31 |
| PL4248160T3 (en) | 2025-03-03 |
| CA3195755A1 (en) | 2022-05-27 |
| PT4248160T (en) | 2024-11-04 |
| JP2023548673A (en) | 2023-11-20 |
| US20230392871A1 (en) | 2023-12-07 |
| EP4248160A1 (en) | 2023-09-27 |
| TW202227771A (en) | 2022-07-16 |
| HUE069375T2 (en) | 2025-03-28 |
| WO2022106045A1 (en) | 2022-05-27 |
| JP7583930B2 (en) | 2024-11-14 |
| US12345476B2 (en) | 2025-07-01 |
| TWI899355B (en) | 2025-10-01 |
| CN116670459A (en) | 2023-08-29 |
| KR20230110247A (en) | 2023-07-21 |
| MX2023005414A (en) | 2023-05-22 |
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