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EP2270119B1 - Composition de carburant - Google Patents

Composition de carburant Download PDF

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Publication number
EP2270119B1
EP2270119B1 EP10180913.5A EP10180913A EP2270119B1 EP 2270119 B1 EP2270119 B1 EP 2270119B1 EP 10180913 A EP10180913 A EP 10180913A EP 2270119 B1 EP2270119 B1 EP 2270119B1
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EP
European Patent Office
Prior art keywords
gasoline fuel
mono
use according
volume
groups
Prior art date
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Revoked
Application number
EP10180913.5A
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German (de)
English (en)
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EP2270119A1 (fr
Inventor
Harald Schwahn
Dietmar Posselt
Erich K. Fehr
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BASF SE
Original Assignee
BASF SE
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Application filed by BASF SE filed Critical BASF SE
Priority to EP20174630.2A priority Critical patent/EP3736317A1/fr
Priority to PL10180913T priority patent/PL2270119T3/pl
Publication of EP2270119A1 publication Critical patent/EP2270119A1/fr
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Publication of EP2270119B1 publication Critical patent/EP2270119B1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/08—Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)

Definitions

  • the present invention relates to a fuel composition containing a special low-alkanol-containing gasoline fuel in a larger amount and selected gasoline fuel additives in a smaller amount.
  • Carburetors and intake systems of gasoline engines are increasingly contaminated by contaminants caused by dust particles from the air, unburned hydrocarbon residues from the combustion chamber and the crankcase ventilation gases passed into the carburetor.
  • valve seat wear-resistant additives based on alkali or alkaline earth metal compounds have been developed.
  • Modern gasoline engines require fuels with a complex property profile for trouble-free use, which can only be guaranteed in combination with appropriate gasoline additives.
  • Such gasoline fuels generally consist of a complex mixture of chemical compounds and are characterized by physical quantities.
  • the interaction between gasoline fuels and the corresponding additives is, however, in need of improvement in the known fuel compositions with regard to the cleaning or keeping-clean effect and the valve seat wear-inhibiting effect.
  • the WO 01/85874 discloses a fuel composition containing a petrol with a sulfur content of max. 150 ppm, an olefin content of max. 21 vol .-%, a benzene content of max. 1.0 vol .-%, an aromatic content of max. 42 vol .-%, a carrier oil mixture and a detergent additive.
  • the fuel composition can include alcohols such as methanol (maximum 3% by volume), ethanol (maximum 5% by volume), isopropanol (maximum 10% by volume), t-butanol (maximum 7% by volume) or isobutanol (maximum 10 vol .-%) included.
  • Comparable fuel compositions are also from the EP-A-1277828 known.
  • Comparable maximum alcohol levels are in the older one WO 03/074637 disclosed for gasoline fuel compositions which are additive with special mixtures of detergent additive and carrier oil.
  • the older one WO 03/076554 describes the use of special hydrocarbylamines to reduce injector deposits in gasoline engines, where the lead-free gasoline used can contain 0.1-15% by volume of additives such as methanol, ethanol and MTBE.
  • the object of the present invention was therefore to find a more effective gasoline-gasoline fuel additive composition. In particular, more effective additive formulations should be found.
  • the use of a combination of a straight-chain or branched, saturated C 1 -C 6 mono- or diol or mixtures thereof, and at least one gasoline fuel additive with detergent action, for reducing deposits in the intake system of a gasoline engine can be determined according to CEC F-05 -A-93, where the petrol additive in an amount of 1 to 5000 ppm by weight and the alkanol in a content of 5 to 75 vol .-%, based on the total volume of the petrol, a petrol with a sulfur content of maximum 150 ppm by weight is metered in, this gasoline fuel additive having at least one hydrophobic hydrocarbon radical with a number average molecular weight (MN) of 85 to 20,000 and at least one polar grouping.
  • MN number average molecular weight
  • the lower alkanol used according to the invention is a straight-chain or branched, saturated C 1 -C 6 mono- or diol, in particular a C 1 -C 3 mono-alkanol, such as methanol, ethanol, n- or i-propanol, or a mixture of several of these alkanols.
  • the alkanol content based on the total volume of the fuel composition, is 5 to 75% by volume, preferably 10 to 65% by volume, in particular 20 to 55% by volume, such as. B. 30 - 40 vol .-% or 40 - 50 vol .-%.
  • the content of other alcohols and ethers in petrol is usually relatively low. Typical maximum contents are 7% by volume for tert-butanol, 10% by volume for isobutanol and 15% by volume for ethers with 5 or more carbon atoms in the molecule.
  • the aromatic content of the petrol is preferably at most 40% by volume, in particular at most 38% by volume. Preferred ranges for the aromatic content are 20 to 42% by volume, in particular 25 to 40% by volume.
  • the sulfur content of the petrol is preferably at most 100 ppm by weight, in particular at most 50 ppm by weight. Preferred ranges for the sulfur content are 0.5 to 150 ppm by weight, in particular 1 to 100 ppm by weight.
  • the petrol has an olefin content of at most 21% by volume, preferably at most 18% by volume, in particular at most 10% by volume. Preferred ranges for the olefin content are 6 to 21% by volume, in particular 7 to 18% by volume.
  • the petrol has a benzene content of at most 1.0% by volume, in particular at most 0.9% by volume.
  • Preferred ranges for the benzene content are 0.5 to 1.0% by volume, in particular 0.6 to 0.9% by volume.
  • the petrol has an oxygen content of at most 2.7% by weight, preferably from 0.1 to 2.7% by weight, especially from 1.0 to 2.7% by weight, in particular from 1.2 to 2.0% by weight.
  • Particularly preferred is a petrol which simultaneously has an aromatic content of at most 38 vol.%, An olefin content of at most 21 vol.%, A sulfur content of at most 50 ppm by weight, a benzene content of at most 1.0 vol.% And one Has oxygen content of 1.0 to 2.7 wt .-%.
  • the summer vapor pressure of petrol is usually a maximum of 70 kPa, especially 60 kPa (each at 370C).
  • the research octane number ("RON") of the petrol is usually 90 to 100.
  • a common range for the corresponding engine octane number (“MOZ”) is 80 to 90.
  • the hydrophobic hydrocarbon residue in the petrol additives which ensures sufficient solubility in the fuel, has a number average molecular weight (Mn) of 85 to 20,000, in particular 113 to 10,000, especially 300 to 5,000.
  • Mn number average molecular weight
  • Such additives based on highly reactive polyisobutene, which from the polyisobutene, which can contain up to 20% by weight of n-butene units, by hydroformylation and reductive amination with ammonia, monoamines or polyamines such as dimethylaminopropylamine , Ethylenediamine, diethylenetriamine, triethylenetetramine or tetraethylenepentamine can be produced in particular from the EP-A 244 616 known.
  • additives containing monoamino groups (a) are the compounds obtainable from polyisobutene epoxides by reaction with amines and subsequent dehydration and reduction of the amino alcohols, as described in particular in DE-A 196 20 262 are described.
  • nitropolyisobutanes e.g. alpha, beta-dinitropolyisobutane
  • mixed hydroxynitropolyisobutanes e.g. alpha-nitro-beta-hydroxypolyisobutane
  • Additives containing carboxyl groups or their alkali metal or alkaline earth metal salts (d) are preferably copolymers of C 2 -C 40 olefins with maleic anhydride with a total molecular weight of 500 to 20,000, the carboxyl groups of which are wholly or partly to the alkali metal or alkaline earth metal salts and a remaining one The rest of the carboxyl groups are reacted with alcohols or amines.
  • Such additives are particularly from EP-A 307 815 known. Such additives serve mainly to prevent valve seat wear and can, as in the WO-A 87/01126 described, are advantageously used in combination with conventional fuel detergents such as poly (iso) butenamines or polyetheramines.
  • Additives containing sulfonic acid groups or their alkali metal or alkaline earth metal salts are preferably alkali metal or alkaline earth metal salts of a sulfosuccinic acid alkyl ester, as described in particular in EP-A 639 632 is described.
  • Such additives mainly serve to prevent valve seat wear and can advantageously be used in combination with conventional fuel detergents such as poly (iso) butenamines or polyether amines.
  • Polyoxy-C 2 - to C 4 -alkylene (f) additives are preferably polyethers or polyetheramines which are obtainable by reaction of C 2 - to C 60 alkanols, C 6 - to C 30 alkanediols, mono- or di-C 2 -C 30 alkylamines, C 1 -C 30 alkylcyclohexanols or C 1 -C 30 alkylphenols with 1 to 30 mol ethylene oxide and / or propylene oxide and / or butylene oxide per hydroxyl group or amino group and, in the case of the polyetheramines, by subsequent reductive amination with ammonia, monoamines or polyamines.
  • Such products are used in particular in EP-A 310 875 , EP-A 356 725 , EP-A 700 985 and US-A 4 877 416 described.
  • polyethers such products also have carrier oil properties. Typical examples of this are tridecanol or isotridecanol butoxylates, isononylphenol butoxylates and polyisobutenol butoxylates and propoxylates as well as the corresponding reaction products with ammonia.
  • Additives containing carboxylic acid ester groups (g) are preferably esters of mono-, di- or tricarboxylic acids with long-chain alkanols or polyols, in particular those with a minimum viscosity of 2 mm 2 / s at 100 ° C., as described in particular in DE-A 38 38 918 are described.
  • Aliphatic or aromatic acids can be used as mono-, di- or tricarboxylic acids, and long-chain representatives with, for example, 6 to 24 carbon atoms are particularly suitable as ester alcohols or polyols.
  • esters are adipates, phthalates, isophthalates, terephthalates and trimellitates of iso-octanol, iso-nonanol, iso-decanol and iso-tridecanol. Products of this type also fulfill carrier oil properties.
  • Derivatives with aliphatic polyamines such as ethylene diamine, diethylene triamine, triethylene tetramine or tetraethylene pentamine are of particular interest.
  • Such gasoline fuel additives are particularly in US-A 4,849,572 described.
  • Groupings (i) containing additives produced by Mannich reaction of substituted phenols with aldehydes and mono- or polyamines are preferably reaction products of polyisobutene-substituted phenols with formaldehyde and mono- or polyamines such as ethylene diamine, diethylene triamine, triethylene tetramine, tetraethylene pentamine or dimethylaminopropylamine.
  • Such "polyisobutene Mannich bases" are particularly in the EP-A 831 141 described.
  • the fuel composition which has been additized according to the invention may also contain other customary components and additives.
  • solvents or diluents there are aliphatic and aromatic hydrocarbons, e.g. Solvent Naphtha.
  • corrosion inhibitors for example based on ammonium salts of organic carboxylic acids which tend to form films, or of heterocyclic aromatics in the case of non-ferrous metal corrosion protection, antioxidants or stabilizers, for example based on amines such as p-phenylenediamine, dicyclohexylamine or derivatives thereof or of phenols such as 2,4-di -tert.-butylphenol or 3,5-di-tert.-butyl-4-hydroxyphenylpropionic acid, demulsifiers, antistatic agents, metallocenes such as ferrocene or methylcyclopentadienylmanganese tricarbonyl, lubricity improvers (lubricity additives) such as certain fatty acids, alkenylsuccinic acid esters, bis (hydroxyalkyl) fatty amides or castor oil and dyes (markers). Sometimes amines are also added to lower the pH of the fuel.
  • antioxidants or stabilizers for example
  • Combinations of the described gasoline with a mixture of gasoline additives with the polar grouping (f) and corrosion inhibitors and / or lubricity improvers based on carboxylic acids or fatty acids, which may be present as monomeric and / or dimeric species, are also particularly suitable for the fuel composition according to the invention .
  • Typical mixtures of this type contain polyisobutenamines in combination with alkanol-started polyethers such as tridecanol or isotridecanol butoxylates or - propoxylates, polyisobutenamines in combination with alkanol-started polyether amines such as tridecanol or isotridecanol butoxylate-ammonia reaction products and alkanol-initiated polyol amine-combiners with alkanol-started polyol amine-combination or ether-alkoxylate-combination products such as tri-alkanolate or trolecidylolamine-amine-like combination products alkanol-started polyethers such as tridecanol or isotridecanol butoxylates or propoxylates, in each case together with the corrosion inhibitors or lubricity improvers mentioned.
  • alkanol-started polyethers such as tridecanol or isotridecanol
  • gasoline fuel additives with the polar groupings (a) to (i) and the other components mentioned are metered into the gasoline fuel and develop their effect there.
  • the components or additives can be added to the petrol individually or as a previously prepared concentrate (“additive package”).
  • the petrol additives mentioned with the polar groups (a) to (i) are usually added to the petrol in an amount of 1 to 5000 ppm by weight, in particular 5 to 3000 ppm by weight, especially 10 to 1000 ppm by weight .
  • the other components and additives mentioned are added, if desired, in amounts customary for this.
  • the same cleaning or cleaning or valve seat wear-inhibiting effect can be achieved as in comparable fuel compositions without the addition of low alkanol.
  • the same amounts of detergent or valve seat wear-inhibiting agent in the fuel composition according to the invention compared to conventional fuel compositions, there is a significantly better cleaning or purifying or valve seat wear-inhibiting effect.
  • the fuel composition according to the invention additionally shows advantages in that fewer deposits are formed in the combustion chamber of the gasoline engine and that less additive is introduced into the engine oil via the fuel dilution.
  • Mn 1000 g / mol
  • carrier oil tridecanol etherified with 22 units of butylene oxide
  • Example 1 was repeated using OK 2 instead of OK 1.
  • Example 1 was repeated using OK 3 instead of OK 1.
  • TCD combustion chamber deposits

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Detergent Compositions (AREA)

Claims (19)

  1. Utilisation d'une combinaison d'un monoalcool ou d'un diol saturé en C1-6, linéaire ou ramifié, ou de mélanges correspondants, et d'au moins un additif d'essence dotée d'un effet détergent, pour la réduction de dépôts dans le système d'admission d'un moteur à essence, déterminable selon la norme CEC F-05-A-93,
    l'additif d'essence étant ajouté en une quantité de 1 à 5 000 ppm en poids et l'alcanol étant ajouté en une teneur de 5 à 75 % en volume, par rapport au volume total de l'essence, à une essence dotée d'une teneur en soufre d'au maximum 150 ppm en poids, cet additif d'essence présentant au moins un radical hydrocarboné hydrophobe doté d'un poids moléculaire moyen en nombre (Mn) de 85 à 20 000 et au moins un groupement polaire, le groupement polaire étant choisi parmi :
    (a) des groupes monoamino ou polyamino comportant jusqu'à 6 atomes d'azote, au moins un atome d'azote possédant des propriétés basiques,
    (b) des groupes nitro, éventuellement en combinaison avec des groupes hydroxyle,
    (c) des groupes hydroxyle en combinaison avec des groupes monoamino ou polyamino, au moins un atome d'azote possédant des propriétés basiques,
    (d) des groupes carboxyle ou leurs sels de métal alcalin ou de métal alcalino-terreux,
    (e) des groupes acide sulfonique ou leurs sels de métal alcalin ou de métal alcalino-terreux,
    (f) des groupements polyoxy-C2-4-alkylène, qui sont terminés par des groupes hydroxyle, des groupes monoamino ou polyamino, au moins un atome d'azote possédant des propriétés basiques, ou par des groupes carbamate,
    (g) des groupes ester d'acide carboxylique,
    (h) parmi des groupements issus de l'anhydride succinique comportant des groupes hydroxy et/ou amino et/ou amido et/ou imido et
    (i) des groupements produits par une transformation de Mannich de phénols substitués avec des aldéhydes et des monoamines ou des polyamines.
  2. Utilisation selon la revendication 1, l'additif d'essence doté de groupements polaires (a) étant choisi parmi des polyalcènemonoamines et des polyalcènepolyamines à base de polypropène, de polybutène ou de polyisobutène dotées de Mn = 300 à 5 000.
  3. Utilisation selon la revendication 1, l'additif d'essence doté de groupements polaires (b) étant choisi parmi des produits de transformation de polyisobutènes de degré moyen de polymérisation P = 5 à 100 avec des oxydes d'azote ou des mélanges d'oxydes d'azote et d'oxygène.
  4. Utilisation selon la revendication 1, l'additif d'essence doté de groupements polaires (c) étant choisi parmi des produits de transformation d'époxydes de polyisobutène, pouvant être obtenus à partir de polyisobutène présentant des doubles liaisons majoritairement terminales doté de Mn = 300 à 5 000, avec de l'ammoniac, des monoamines ou des polyamines.
  5. Utilisation selon la revendication 1, l'additif d'essence doté de groupements polaires (d) étant choisi parmi des copolymères de C2-40-oléfines avec de l'anhydride d'acide maléique dotés d'une masse molaire totale de 500 à 20 000, dont des groupes carboxyle sont transformés entièrement ou partiellement en sels de métal alcalin ou de métal alcalino-terreux et un radical restant des groupes carboxyle est transformé avec des alcools ou des amines.
  6. Utilisation selon la revendication 1, l'additif d'essence doté de groupements polaires (e) étant choisi parmi des sels de métal alcalin ou de métal alcalino-terreux d'un ester d'alkyle d'acide sulfosuccinique.
  7. Utilisation selon la revendication 1, l'additif d'essence doté de groupements polaires (f) étant choisi parmi des polyéthers ou des polyétheramines, pouvant être obtenu(e)s par transformation de C2-30-alcanols, de C6-60-alcanediols, de mono-C2-30-alkylamines ou de di-C2-30-alkylamines, de C1-30-alkylcyclohexanols ou de C1-30-alkylphénols avec 1 à 30 moles d'oxyde d'éthylène et/ou d'oxyde de propylène et/ou d'oxyde de butylène par groupe hydroxyle ou par groupe amino et, dans le cas des polyétheramines, par amination réductrice ultérieure avec de l'ammoniac, des monoamines ou des polyamines.
  8. Utilisation selon la revendication 1, l'additif d'essence doté de groupements polaires (g) étant choisi parmi des esters d'acides monocarboxyliques, d'acides dicarboxyliques ou d'acides tricarboxyliques avec des alcanols ou des polyols à longue chaîne.
  9. Utilisation selon la revendication 1, l'additif d'essence doté de groupements polaires (h) étant choisi parmi des dérivés d'anhydride d'acide polyisobuténylsuccinique, pouvant être obtenus par transformation de polyisobutène conventionnel ou hautement réactif doté de Mn = 300 à 5 000 avec de l'anhydride de l'acide maléique par une voie thermique ou par l'intermédiaire du polyisobutène chloré, les dérivés d'anhydride d'acide polyisobuténylsuccinique étant choisis parmi des dérivés avec des polyamines aliphatiques comme l'éthylènediamine, la diéthylènetriamine, la triéthylènetétramine ou la tétraéthylènepentamine.
  10. Utilisation selon la revendication 1, l'additif d'essence doté de groupements polaires (i) étant choisi parmi des produits de transformation de phénols substitués par polyisobutène avec du formaldéhyde et des monoamines ou des polyamines.
  11. Utilisation selon l'une quelconque des revendications 1 à 10, contenant une essence dotée d'une teneur en oléfines de maximum 21 % en volume par rapport au volume de l'essence sans additif, laquelle ne contient pas de monoalcools ou de diols saturés en C1-6, linéaires ou ramifiés, ou de mélanges correspondants.
  12. Utilisation selon l'une quelconque des revendications 1 à 11, contenant une essence dotée d'une teneur en benzène d'au maximum 1,0 % en volume par rapport au volume de l'essence sans additif, laquelle ne contient pas de monoalcools ou de diols saturés en C1-6, linéaires ou ramifiés, ou de mélanges correspondants.
  13. Utilisation selon l'une quelconque des revendications 1 à 12, contenant une essence dotée d'une teneur en oxygène d'au maximum 2,7 % en poids par rapport au volume de l'essence sans additif, laquelle ne contient pas de monoalcools ou de diols saturés en C1-6, linéaires ou ramifiés, ou de mélanges correspondants.
  14. Utilisation selon l'une quelconque des revendications 1 à 13, contenant une essence dotée d'une teneur en composés aromatiques d'au maximum 42 % en volume par rapport au volume de l'essence sans additif, laquelle ne contient pas de monoalcools ou de diols saturés en C1-6, linéaires ou ramifiés, ou de mélanges correspondants.
  15. Utilisation selon les revendications 1 à 14, contenant les additifs d'essence dotés des groupements polaires (a) à (i) en une quantité de 10 à 1 000 ppm en poids.
  16. Utilisation d'un monoalcool ou d'un diol saturé en C1-6, linéaire ou ramifié, ou de mélanges correspondants en une proportion de 5 à 75 % en volume, par rapport au volume total de l'essence, dans des essences pauvres en soufre dotées d'une teneur en soufre de maximum 150 ppm en poids, pour l'amélioration de l'effet d'un additif doté d'un effet détergent, les effets d'additif étant déterminables selon la norme CEC F-05-A-93 et cet additif d'essence étant défini selon l'une quelconque des revendications 1 à 10.
  17. Utilisation d'au moins un additif d'essence doté d'un effet détergent, pour la réduction de dépôts dans le système d'admission d'un moteur à essence, déterminable selon la norme CEC F-05-A-93, l'additif d'essence étant ajouté en une quantité de 1 à 5 000 ppm en poids à une essence dotée d'une teneur en soufre d'au maximum 150 ppm en poids, cet additif d'essence étant défini selon l'une quelconque des revendications 1 à 10 et l'essence contenant un monoalcool ou un diol saturé en C1-6, linéaire ou ramifié, ou des mélanges correspondants, et l'alcanol étant contenu en une teneur de 20 à 75 % en volume, par rapport au volume total de l'essence.
  18. Utilisation selon la revendication 1 ou 16, l'alcanol étant contenu en une teneur de 10 à 65 % en volume, par rapport au volume total de l'essence.
  19. Utilisation selon la revendication 1, 16, 17 ou 18, l'alcanol étant choisi parmi des C1-3-monoalcanols et l'additif détergent étant choisi parmi
    (a) des polyalcènemonoamines et des polyalcènepolyamines à base de polypropène, de polybutène ou de polyisobutène dotées de Mn = 300 à 5 000 ; et
    (i) des produits de transformation de phénols substitués par polyisobutène avec du formaldéhyde et des monoamines ou des polyamines.
EP10180913.5A 2003-04-11 2004-04-08 Composition de carburant Revoked EP2270119B1 (fr)

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KR20060006781A (ko) 2006-01-19
KR101320732B1 (ko) 2013-10-21
SI1615985T1 (sl) 2014-02-28
BRPI0409171A (pt) 2006-04-11
WO2004090079A1 (fr) 2004-10-21
CA2810284A1 (fr) 2004-10-21
CA2810284C (fr) 2015-06-16
JP2006522846A (ja) 2006-10-05
JP4452712B2 (ja) 2010-04-21
CN1802425A (zh) 2006-07-12
EP1615985B1 (fr) 2013-12-11
DK1615985T3 (en) 2014-03-03
AU2004227095B2 (en) 2010-07-15
CA2520578A1 (fr) 2004-10-21
PL1615985T3 (pl) 2014-05-30
JP2010013665A (ja) 2010-01-21
RU2005134823A (ru) 2006-06-10
JP2013209664A (ja) 2013-10-10
PL2270119T3 (pl) 2021-01-25
EP3736317A1 (fr) 2020-11-11
US20060196110A1 (en) 2006-09-07
DE10316871A1 (de) 2004-10-21
AU2004227095A1 (en) 2004-10-21
ZA200509086B (en) 2007-02-28
CN100545244C (zh) 2009-09-30
CA2520578C (fr) 2013-06-18
KR101186408B1 (ko) 2012-09-27
PT1615985E (pt) 2014-01-29
CL2004000766A1 (es) 2005-02-04
EP2270119A1 (fr) 2011-01-05
AR044001A1 (es) 2005-08-24
KR20120081230A (ko) 2012-07-18
MXPA05010183A (es) 2005-11-08
NO20054374L (no) 2005-09-29
EP1615985A1 (fr) 2006-01-18
MY162483A (en) 2017-06-15

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