EP1957371B1 - Shrinking process for producing solid, transportable and printable containers and device for carrying out said shrinking process - Google Patents
Shrinking process for producing solid, transportable and printable containers and device for carrying out said shrinking process Download PDFInfo
- Publication number
- EP1957371B1 EP1957371B1 EP06753186A EP06753186A EP1957371B1 EP 1957371 B1 EP1957371 B1 EP 1957371B1 EP 06753186 A EP06753186 A EP 06753186A EP 06753186 A EP06753186 A EP 06753186A EP 1957371 B1 EP1957371 B1 EP 1957371B1
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- European Patent Office
- Prior art keywords
- container
- air
- shrinking process
- film
- area
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B53/00—Shrinking wrappers, containers, or container covers during or after packaging
- B65B53/02—Shrinking wrappers, containers, or container covers during or after packaging by heat
- B65B53/06—Shrinking wrappers, containers, or container covers during or after packaging by heat supplied by gases, e.g. hot-air jets
- B65B53/063—Tunnels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B63/00—Auxiliary devices, not otherwise provided for, for operating on articles or materials to be packaged
- B65B63/08—Auxiliary devices, not otherwise provided for, for operating on articles or materials to be packaged for heating or cooling articles or materials to facilitate packaging
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B2220/00—Specific aspects of the packaging operation
- B65B2220/24—Cooling filled packages
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D71/00—Bundles of articles held together by packaging elements for convenience of storage or transport, e.g. portable segregating carrier for plural receptacles such as beer cans or pop bottles; Bales of material
- B65D71/06—Packaging elements holding or encircling completely or almost completely the bundle of articles, e.g. wrappers
- B65D71/08—Wrappers shrunk by heat or under tension, e.g. stretch films or films tensioned by compressed articles
Definitions
- the invention relates to a shrinking process for the production of solid, transportable and printable containers, in particular bottle containers with a height / width ratio of> 1, consisting of a wrapping of the goods to be packaged with a film so that an overlapping region of the film ends is formed on the bottom surface, heating or convection heating to fuse the free ends in the overlap area and a final heating while simultaneously stabilizing the resulting package by the shrinking operation.
- the WO 02/36436 A1 describes a multi-zone shrink tunnel with a pre-shrink zone with heated ambient air and a heat zone in which a lateral, final H exert mobilisdung the wrapped in foil goods.
- the goods are here first, preferably using a solid transport tray, combined into groups and wrapped in foil.
- the foil ends which overlap at the bottom of the container are sealed by blowing hot air over a wide area and are subjected to the final shrinkage process after a pre-shrinking process. So that the finished containers are printable, they must have constant dimensions and flat surfaces.
- the printable area should provide sufficient resistance to the pressure roller resting on the print roller, since otherwise a blurred printed image is produced.
- heating of the entire product is limited, e.g. in foods such as chilled dairy products or carbonated, pressurized beverages. Therefore, the shrinking temperatures were lowered, thereby prolonging the process time. However, the lower temperatures caused problems in the welding, so that not always the required strength in the container shell was achieved.
- the inventors also found that sealing the overlapping foil ends at lower temperature avoids significant heating of the products themselves, but especially with the continuous transport of the containers involves the problem that the enveloping film is inflated and slipping on side blowing with hot air. This reinforced the already described Tilting of individual objects of the goods to be packaged or to change their position.
- the object of the present invention was therefore to offer a shrinking process and a device for carrying out this shrinking process, the production of a solid container of goods with a height / width ratio of> 1, preferably> 2, with constant packing density and geometric shape without separate tray allows the individual goods to be heated at best superficially. For units that are or may only be heated on their surface, this means that the core temperature must be kept low and the energy released to the environment must be reduced. Other aspects include space requirements, process control with flexible container sizes and reduction of environmental pollution through outgassing of film materials.
- the incoming hot air is deflected under intimate interaction with the film at the bottom of the container and recycled in the reverse flow direction in the gas circulation system.
- This form of hot gas guide will be referred to as reverse flow hereinafter.
- reverse flow By a parallel movement of the convection zone and the bottom of the can at different speeds it is achieved that the convection zone migrates slowly during the transport of the container over the entire bottom surface, without causing heat accumulation or irregular shrinkage of the film on the container sides.
- Due to the special gas flow in the form of a reverse flow the heat transfer takes place in a defined convection zone from the hot gas into the bottom surface of the container.
- the zonal energy input can be optimally adapted to the material thickness or density of the film by controlling the flow velocity of the hot gas and optimally via the exactly definable heat exchange or convection surface.
- the device according to the invention for carrying out a shrinking process is shown in front view. It can be seen the supply and exhaust air system 5, 7 with the container 1, which is arranged on a conveyor belt 2 via a hot air source 3.
- the hot air applied in reverse flow serves to form a pre-stabilizing edge shell 32 in the bottom region of the container.
- the container 1 is shown in a system which has a lateral hot air supply 5.
- the goods (bottles) of the container are conveyed through a conveyor belt 6 in the product running direction through the shrinking 4.
- the container 1 with the enveloping film 8 passes in front of the hot air supply 5, there is the risk that the film casing is inflated by the air pressure and thereby threatens to slip. This is prevented by the previously formed edge shell in the region of the bottom of the container, which stabilizes the shape of the container and thus the arrangement of the goods.
- the shrinking system is shown in side view, wherein in the left part of the system laterally next to the hot air source 3, an exhaust system 7A 7B is indicated.
- the exhaust air is completely or partially recycled or recycled for the preparation of the hot air, so that in conjunction with the continuous transport heat accumulation can be avoided.
- the horizontally acting hot air nozzles 5a 5b are shown. These initiate the all-round shrinkage process on the container enclosed by a wrapping film 8.
- the two sections formation of the edge shell, finish shrinkage
- the hot air supply is designed as a reverse flow.
- the net-like structure of the conveyor belt 2 is partially covered by the slides 10, 11. This ensures that only the bottom surface 12 of the transported container or a sub-area is acted upon by the incoming hot air (mitwandernde convection zone).
- the hot gases flow at high pressure from the laterally disposed nozzles 5.
- the flow rate can be further increased and directed over the entire surface constantly against the film 8, since the container on the bottom surface has already been stabilized so that the order the bottle-shaped goods 13 turned over film 8 withstands a high lateral pressure load.
- the container 1 stands on a mesh or lattice-like structure 9, so that the hot air flowing out of the nozzle field 33 via the nozzle 14 has access to a Convection zone 15 of the conveyor belt 6 has.
- the convection zone 15 the heat transfer from the hot gas by convection takes place in the bottom surface 12 of the container. After deflection on the surface of the container bottom, the hot gas flows in the direction of arrow via suction openings 16, 17 back into the exhaust air area.
- Fig. 4 shows the transport of the container 1 via an inventively according to the principle of the reverse flow formed air exchange plate 29 with convection zone 15 for forming a stabilizing edge shell.
- the flow direction of the hot supply air 5 is deflected into the exhaust air system 7a, 7b.
- the zonal control of the longitudinal and transverse slides 23, 26 is necessary in order to achieve the follow-on movement of the convection zone and bottom surface 12 of the container while avoiding heat build-up.
- FIG. 5 On the left edge of the picture is in partial cross section of Fig. 5 a preferred variant of the invention designed according to the air exchange plate 29 for the discrete hot air in the area of the bottom of the container.
- the air exchange plate 29 includes sliding ribs 31, on which the net-like conveyor belt 18 is supported.
- the container 1 contains a plurality of products 19 enveloped by a shrink film 20.
- Zone activation can be done manually or automatically.
- the container 1 is conveyed in the direction of the arrow over the reticulated conveyor belt 18 in the sphere of influence of the hot air source 3 (vertical arrow).
- the longitudinal slide 23 is set manually. This can be adjusted via an eccentric adjustment 24 Fig. 7 respectively.
- the slider adjustment is controlled by a zone activation 25, with the help of the cross slide 26 depending on the position of the product or the container 1 on the conveyor belt 18 either activate the supply air or switch off.
- a perforated plate as a cross slide 26 and pipes 27 for the hot air supply and a separation housing 28 for the supply and exhaust air are required according to the embodiment.
- the above example shows how, in the device according to the invention, the hot gas is conducted to form a stabilizing edge shell on the principle of the reverse flow.
- the heating surface is represented by an air exchange plate, which includes a special gas guide in which the gas is transferred from an open to a closed loop system.
- On the heating surface is a field of pits, e.g. in channel or bell shape, wherein in each bell a centrally arranged Zu Kunststofftechnik is arranged in the form of a nozzle which has a very small distance from the heating surface.
- On the side of the bell are one or more exhaust units in the form of suction, whose diameter and number is selected so that the inflowing supply air is sucked off after deflection at the bottom of the container.
- the container 1 stands on a net or grid-like structure 9 or 10, so that the hot air flowing up from a sink or bell has access to the convection zone 15.
- the convection zone 15 the heat transfer from the hot gas by convection takes place in the bottom surface of the container. After deflection on the surface of the container bottom, the hot gas flows via suction openings 16, 17 back into the exhaust air area.
- the device according to the invention can be controlled in wide sections of the convection zone.
- a zone with the required energy requirement is supplied via temperature and flow profiles that the user can specify depending on the path.
- the energy requirement is calculated or determined empirically based on the material thickness, the material density or on the heat capacities of the film to be heated. Thereafter, the film can be tempered specifically.
- the plastic By cooling in the last process step, on the one hand, the plastic is transferred from the plastic region into the elastic region, the maximum stresses in the material increasing and solidifying. On the other hand, the film also shrinks during this cooling whereby the tensions in the film increase and the container stabilizing holding forces are greater. If the environment is too hot, it must be actively cooled because the ambient air is insufficient to solidify.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Auxiliary Devices For And Details Of Packaging Control (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
- Packages (AREA)
- Containers And Plastic Fillers For Packaging (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Die Erfindung betrifft einen Schrumpfprozess zur Herstellung von festen, transportfähigen und bedruckbaren Gebinden, insbesondere Flaschengebinde mit einem Höhen/Breitenverhältnis von >1, bestehend aus einem Umhüllen der zu verpackenden Güter mit einer Folie, sodass sich an der Bodenfläche ein überlappender Bereich der Folienenden ausbildet, einem Aufheizen durch Wärmeaustausch bzw. Konvektion, um die freien Enden im Überlappungsbereich zu verschmelzen und einem abschließenden Erhitzen, wobei gleichzeitig das entstehende Gebinde durch den Schrumpfvorgang stabilisiert wird.The invention relates to a shrinking process for the production of solid, transportable and printable containers, in particular bottle containers with a height / width ratio of> 1, consisting of a wrapping of the goods to be packaged with a film so that an overlapping region of the film ends is formed on the bottom surface, heating or convection heating to fuse the free ends in the overlap area and a final heating while simultaneously stabilizing the resulting package by the shrinking operation.
Schrumpfprozesse zur Herstellung von festen, transportfähigen und bedruckbaren Gebinden werden heutzutage in vielfacher Form bei Folienverpackungen durchgeführt, die als Verkaufseinheit von Flaschen verwendet wird. Die Folie dient hierbei auch als Werbeträger, beispielsweise bei Getränkeflaschen, die mit einer Schrumpffolie umhüllt sind. Üblicherweise werden zur Erwärmung der Schrumpffolien Heißgase verwendet, bei denen die Wärmeenergie durch Konvektion auf die Oberfläche des aufzuheizenden Gutes übertragen wird.Shrinking processes for the production of solid, transportable and printable containers are nowadays carried out in many forms in film packaging, which is used as a sales unit of bottles. The film also serves as an advertising medium, for example in beverage bottles, which are wrapped with a shrink film. Usually, hot gases are used to heat the shrink films, in which the heat energy is transferred by convection to the surface of the material to be heated.
Die
Es wurde festgestellt, dass besonders beim Transport während der Verpackung von Gütern mit hochliegendem Schwerpunkt, wie z.B. bei Flaschen mit einem Höhen-/Breitenverhältnis von deutlich > 1, vorzugsweise > 2, die im Überlappungsbereich der Folienenden aufrecht stehenden Güter dazu neigen, ihre Position relativ zu den anderen Objekten durch Kippen zu verändern. Die im Herstellungsprozess und beim Transport nicht vermeidbaren Vibrationen und Erschütterungen des Gebindes bewirken während des Schrumpfprozesses eine Instabilität und Ungleichmäßigkeit der Schrumpfung. Es wurde daher versucht, unter Verwendung einer festen Tragschale ein Gebinde mit gleicher, räumlicher Abmessung und reproduzierbaren Relativpositionen der Objekte zueinander herzustellen. Da es sich jedoch um Massenprodukte mit relativ niedrigen Stückpreisen handelt, kommt die separate Zuführung einer Schale für die Herstellung besonders stabiler Gebinde wegen des erhöhten ökonomischen Einsatzes von Material und Energien nicht in Betracht.It has been found that particularly during transport during the packaging of goods with high center of gravity, such. For bottles with a height / width ratio of significantly> 1, preferably> 2, the upright in the overlap region of the film ends goods tend to change their position relative to the other objects by tilting. The unavoidable vibrations and vibrations of the container during the manufacturing process and during transport cause instability and unevenness of the shrinkage during the shrinking process. It was therefore attempted to produce a container with the same spatial dimension and reproducible relative positions of the objects to each other using a solid tray. However, since these are mass products with relatively low unit prices, the separate supply of a shell for the production of particularly stable containers due to the increased economic use of material and energy is out of the question.
Bei bestimmten Produkten ist eine Erwärmung des gesamten Produktes nur begrenzt zulässig, z.B. bei Lebensmitteln wie gekühlten Milchprodukten oder bei mit Kohlendioxid versetzten, unter Druck stehenden Getränken. Daher wurden die Schrumpftemperaturen herabgesetzt, wodurch sich die Prozessdauer verlängerte. Allerdings führten die niedrigeren Temperaturen zu Problemen bei der Verschweißung, so dass nicht immer die erforderliche Festigkeit in der Gebindehülle erreicht wurde.For certain products, heating of the entire product is limited, e.g. in foods such as chilled dairy products or carbonated, pressurized beverages. Therefore, the shrinking temperatures were lowered, thereby prolonging the process time. However, the lower temperatures caused problems in the welding, so that not always the required strength in the container shell was achieved.
Die Erfinder stellten außerdem fest, dass eine Versiegelung der überlappenden Folienenden bei niedrigerer Temperatur zwar eine nennenswerte Erwärmung der Güter selbst vermeidet, jedoch insbesondere beim kontinuierlichen Transport der Gebinde mit dem Problem einhergeht, dass die umhüllende Folie bei seitlichem Anblasen mit Heißluft aufgeblasen wird und verrutscht. Dies verstärkte die bereits beschriebene Neigung von Einzelobjekten der zu verpackenden Güter zu kippen bzw. ihre Position zu verändern.The inventors also found that sealing the overlapping foil ends at lower temperature avoids significant heating of the products themselves, but especially with the continuous transport of the containers involves the problem that the enveloping film is inflated and slipping on side blowing with hot air. This reinforced the already described Tilting of individual objects of the goods to be packaged or to change their position.
Aufgabe der vorliegenden Erfindung war es daher, einen Schrumpfprozess sowie eine Vorrichtung zur Durchführung dieses Schrumpfprozesses anzubieten, die ohne separate Tragschale die Herstellung eines festen Gebindes aus Gütern mit einem Höhen-/ Breitenverhältnis von > 1, vorzugsweise > 2, bei gleichbleibender Packungsdichte und geometrischer Form ermöglicht, wobei die einzelnen Güter allenfalls oberflächlich erwärmt werden sollen. Bei Einheiten, die nur an ihrer Oberfläche erwärmt werden sollen oder dürfen, bedeutet dies, dass die Kerntemperatur niedrig zu halten ist und die Energieabgabe an die Umwelt reduziert werden muss. Weitere Aspekte sind Raumbedarf, Prozesssteuerung bei flexiblen Gebindegrößen und Reduzierung der Umweltbelastung durch Ausgasung von Folienwerkstoffen.The object of the present invention was therefore to offer a shrinking process and a device for carrying out this shrinking process, the production of a solid container of goods with a height / width ratio of> 1, preferably> 2, with constant packing density and geometric shape without separate tray allows the individual goods to be heated at best superficially. For units that are or may only be heated on their surface, this means that the core temperature must be kept low and the energy released to the environment must be reduced. Other aspects include space requirements, process control with flexible container sizes and reduction of environmental pollution through outgassing of film materials.
Diese Aufgabe wird mit einem Schrumpfprozess gemäß Anspruch 1 sowie einer Vorrichtung zur Durchführung des Schrumpfprozesses gemäß Anspruch 7 gelöst. Weitere Vorteile ergeben sich aus den abhängigen Ansprüchen sowie der folgenden Beschreibung.This object is achieved by a shrinking process according to
Mit dem neuen Schrumpfprozess konnte eine effiziente Energieübertragung erreicht werden, wobei der Wärmeübergangskoeffizient zwischen den beteiligten Medien bzw. Stoffen, die Art und Größe der jeweils beheizten Oberfläche und die Strömungsgeschwindigkeit des Heißgases über die gesamte Wärmeaustausch bzw. Konvektionsfläche sowie der Gasaustausch mit der Umgebung optimiert wurde. Durch bestimmte Maßnahmen konnte die Kerntemperatur niedrig gehalten werden und die Verpackungsfolie durch enge Begrenzung der hohen Temperaturen lokal verschweißt werden, wobei die Einzelobjekte (Verpackungsgüter) kurzzeitig nur an ihrer Oberfläche auf die erforderliche Schrumpftemperatur erwärmt wurden. Ferner konnte die Energieabgabe an die Umwelt dadurch reduziert werden, dass die zum Verschweißen der im Bodenbereich überlappenden Folienenden dienende Heißluft nur auf die Bodenfläche des Gebindes und somit zonal begrenzt gerichtet wurde. Dadurch konnte eine schnelle Formstabilisierung des Gebindes durch "Insitu"-Ausbildung einer Randschale erreicht werden, so dass die Güter bereits am Anfang des Schrumpfprozesses in ihrer Position zueinander fixiert wurden. Dadurch hielt das an der Bodenfläche bereits stabilisierte Gebinde beim seitlichen Anblasen mit Heißluft auch einer höheren Druckbelastungen stand, so dass der Anblasvorgang auf eine kurze Behandlungsdauer beschränkt werden konnte.With the new shrinking process, efficient energy transfer could be achieved, optimizing the heat transfer coefficient between the media involved, the type and size of each heated surface and the flow rate of the hot gas throughout the heat exchange or convection area, as well as the gas exchange with the environment , Through certain measures, the core temperature could be kept low and the packaging film was welded locally by narrow limitation of high temperatures, the individual objects (packaging goods) were briefly heated only on their surface to the required shrinking temperature. Furthermore, the energy output to the environment could be reduced by the fact that the hot air serving to weld the foil ends overlapping in the bottom region was directed only to the bottom surface of the container and thus zonal limited. Thus, a rapid stabilization of the shape of the container by "in-situ" formation of a marginal shell could be achieved, so that the goods already at the beginning of Shrinking process were fixed in position to each other. As a result, the container already stabilized on the bottom surface with hot air at the side was also able to withstand higher pressure loads, so that the blowing process could be limited to a short duration of treatment.
Gleichzeitig ergab sich beim kontinuierlichen Transport, insbesondere bei Gebinden mit großer Stellfläche der Vorteil, dass durch die beaufschlagte Heißluft ein Wärmestau in der Stellflächenmitte bzw. eine unzulässige Erwärmung des zu verpackenden Guts vermieden werden konnte. Bisher bestand die Gefahr, dass sich die Seitenteile des Gebindes durch die allseitig verströmende Heißluft erwärmten und den Schrumpfprozess der umhüllenden Folie unregelmäßig beeinflussten. Dieses Problem konnte durch einen schnellen kontinuierlichen Transport des Gebindes auf einer netzartigen Struktur in Kombination mit einer zonalen Beaufschlagung der Bodenflächen durch Heißluft gelöst werden. Hierbei wird Heißluft in Bündeln von diskret verteilten Gasstrahlen in eine Konvektionszone eingeleitet, welche durch den Gebindeboden einerseits sowie Abluftöffnungen andererseits begrenzt ist. Die einströmende Heißluft wird unter inniger Wechselwirkung mit der Folie am Gebindeboden umgelenkt und mit umgekehrter Strömungsrichtung in das Gaskreislaufsystem rückgeführt. Diese Form der Heißgasführung wird im Weiteren als Umkehrströmung bezeichnet werden. Durch eine Parallelbewegung von Konvektionszone und Gebindeboden mit unterschiedlicher Geschwindigkeit wird erreicht, dass die Konvektionszone während des Transportes des Gebindes langsam über die gesamte Bodenfläche mitwandert, ohne einen Wärmestau oder unregelmäßiges Schrumpfen der Folie an den Gebindeseiten zu verursachen. Durch die besondere Gasführung in Form einer Umkehrströmung erfolgt der Wärmeübergang in einer definierten Konvektionszone aus dem Heißgas in die Bodenfläche des Gebindes. Dabei kann der zonale Energieeintrag optimal der Materialstärke oder Dichte der Folie durch Steuerung der Strömungsgeschwindigkeit des Heißgases und optimal über die exakt definierbare Wärmetausch- bzw. Konvektionsfläche angepasst werden.At the same time resulted during continuous transport, especially in containers with a large footprint the advantage that heat accumulation in the middle of the parking space or an inadmissible heating of the goods to be packaged could be avoided by the hot air acted upon. So far, there was a danger that the side parts of the container heated by the hot air flowing on all sides and influenced the shrinking process of the enveloping film irregularly. This problem could be solved by a rapid continuous transport of the container on a net-like structure in combination with a zonal impact on the bottom surfaces by hot air. Here, hot air is introduced into bundles of discretely distributed gas jets in a convection zone, which is bounded by the container bottom on the one hand and exhaust vents on the other. The incoming hot air is deflected under intimate interaction with the film at the bottom of the container and recycled in the reverse flow direction in the gas circulation system. This form of hot gas guide will be referred to as reverse flow hereinafter. By a parallel movement of the convection zone and the bottom of the can at different speeds it is achieved that the convection zone migrates slowly during the transport of the container over the entire bottom surface, without causing heat accumulation or irregular shrinkage of the film on the container sides. Due to the special gas flow in the form of a reverse flow, the heat transfer takes place in a defined convection zone from the hot gas into the bottom surface of the container. In this case, the zonal energy input can be optimally adapted to the material thickness or density of the film by controlling the flow velocity of the hot gas and optimally via the exactly definable heat exchange or convection surface.
Die vorstehend genannten Vorteile werden erfindungsgemäß in überraschend einfacher und ökonomischer Weise erreicht. Im Folgenden wird die Erfindung anhand mehrerer Ausführungsbeispiele näher erläutert. Es zeigen:
- Fig. 1
- prinzipieller Aufbau einer Schrumpfanlage zur Herstellung von festen, transportfähigen und bedruckbaren Gebinden (Vorderansicht und Seitenansicht).
- Fig. 2
- perspektivische Ansicht einer erfindungsgemäß ausgebildeten Schrumpfvorrichtung
- Fig. 3
- prinzipielle Darstellung zur Umkehrströmung und Ausbildung einer Randschale anhand eines Querschnitts durch eine Luftaustauschplatte
- Fig. 4
- Transport eines Gebindes über eine erfindungsgemäß ausgebildete Vorrichtung zur Heißgasbeaufschlagung im Bodenbereich des Gebindes
- Fig. 5
- perspektivische Ansicht der Vorrichtung zur Heißgasbeaufschlagung
- Fig. 6
- Gesamtansicht der Vorrichtung zur Ausbildung einer Randschale
- Fig. 7
- Aufbau einer erfindungsgemäß ausgebildeten Vorrichtung zur Ausbildung einer Randschale
- Fig. 8
- Ablaufschema des erfindungsgemäßen Verfahrens zur Herstellung von festen transportfähigen und bedruckbaren Gebinden.
- Fig. 1
- basic structure of a shrinking plant for the production of solid, transportable and printable containers (front view and side view).
- Fig. 2
- Perspective view of a shrinking device designed according to the invention
- Fig. 3
- schematic representation of the reverse flow and forming a peripheral shell based on a cross section through an air exchange plate
- Fig. 4
- Transport of a container via an inventively designed device for Heißgasbeaufschlagung in the bottom region of the container
- Fig. 5
- Perspective view of the device for hot gas
- Fig. 6
- Overall view of the device for forming a peripheral shell
- Fig. 7
- Structure of an inventively designed device for forming a peripheral shell
- Fig. 8
- Flow chart of the process of the invention for the production of solid transportable and printable containers.
Im oberen Teil der
Im rechten Teil von
Im unteren Abschnitt der
Im rechten Teil der Schrumpfanlage sind die horizontal wirkenden Heißluftdüsen 5a 5b dargestellt. Diese leiten den allseitigen Schrumpfungsprozess an dem mit einer umhüllenden Folie 8 eingeschlossenen Gebinde ein. In der perspektivischen Darstellung nach
Im Abschnitt 4 der Anlage strömen die Heißgase mit hohem Druck aus den seitlich angeordneten Düsen 5. Die Strömungsgeschwindigkeit kann weiter erhöht und über die gesamte Fläche konstant gegen die Folie 8 gerichtet werden, da das Gebinde an der Bodenfläche bereits so stabilisiert wurde, dass die um die flaschenförmigen Güter 13 umgeschlagen Folie 8 einer hohen seitliche Druckbelastung standhält.In
Mit einem abschließenden Kühlen durch Anblasen mit Kaltluft (nicht dargestellt) wird zum einen der Kunststoff vom plastischen Bereich in den elastischen Bereich überführt, wobei die maximalen Spannungen im Material ansteigen und es sich dabei verfestigt. Zum anderen schrumpft die Folie auch noch bei dieser Abkühlung, wodurch die Spannungen in der Folie ansteigen und die das Gebinde stabilisierenden Haltekräfte die erforderliche Größe erreichen. Bei zu heißer Umgebung muss aktiv gekühlt werden, da die Temperatur der Umgebungsluft zur Verfestigung nicht ausreicht.
Im Zusammenhang mit dem in
In connection with in
Das Gebinde 1 steht auf einer netz- oder gitterartigen Struktur 9, so dass die aus dem Düsenfeld 33 aufströmende Heißluft über Düse 14 einen Zugang zu einer Konvektionszone 15 des Transportbandes 6 hat. In der Konvektionszone 15 erfolgt der Wärmeübergang aus dem Heißgas durch Konvektion in die Bodenfläche 12 des Gebindes ein. Nach Umlenkung auf der Oberfläche des Gebindebodens strömt das Heißgas in Pfeilrichtung über Absaugöffnungen 16, 17 zurück in den Abluftbereich.The
Am linken Bildrand ist im Teilquerschnitt der
Wenn der Transport des Gebindes 1 in Pfeilrichtung über die Luftaustauschptatte 29 erfolgt, werden die Zulufteinheiten 21 und die Ablufteinheiten 22 über registerartig angeordnete Quer- und Längsschieber gesteuert. Diese Steuerung, auch "Zonenaktivierung" genannt, ist in
Die Zonenaktivierung kann manuell oder automatisch gesteuert erfolgen. In dem Beispiel nach
Aus dem vorstehenden Beispiel ergibt sich, wie in der erfindungsgemäßen Vorrichtung das Heißgas zur Ausbildung einer stabilisierenden Randschale nach dem Prinzip der Umkehrströmung geführt wird. Die Heizfläche wird durch eine Luftaustauschplatte dargestellt, die eine spezielle Gasführung umfasst, bei der das Gas von einem offenen in einen geschlossenen Kreislaufsystem überführt wird. Auf der Heizfläche ist ein Feld von Vertiefungen, z.B. in Kanal- oder Glockenform, angeordnet, wobei in jeder Glocke eine zentrisch angeordnete Zulufteinheit in Form einer Düse angeordnet ist, die einen sehr geringen Abstand zur erwärmenden Fläche aufweist. Seitlich von der Glocke befinden sich eine oder mehrere Ablufteinheiten in Form von Absaugöffnungen, deren Durchmesser und Anzahl so gewählt ist, dass die einströmende Zuluft nach Umlenkung an der Gebindebodenfläche abgesaugt wird.The above example shows how, in the device according to the invention, the hot gas is conducted to form a stabilizing edge shell on the principle of the reverse flow. The heating surface is represented by an air exchange plate, which includes a special gas guide in which the gas is transferred from an open to a closed loop system. On the heating surface is a field of pits, e.g. in channel or bell shape, wherein in each bell a centrally arranged Zulufteinheit is arranged in the form of a nozzle which has a very small distance from the heating surface. On the side of the bell are one or more exhaust units in the form of suction, whose diameter and number is selected so that the inflowing supply air is sucked off after deflection at the bottom of the container.
Im Zusammenhang mit dem Teilquerschnitt durch eine Gleitplatte nach
Bei dieser Anordnung ist dafür gesorgt, dass die Vertiefungen oder im vorliegenden Fall die Glocken immer ganz oder zumindest am Rand vollständig von dem Boden des Gebindes abgedeckt werden. Durch die Umkehrströmung wird der Fehllufteinfluss minimiert. Auch bei Einsatz von weniger Energie und einer geringen Zuluftmenge wird die Ausbildung einer stabilisierenden Randschale erreicht. Dies gilt sogar bei einer parallelen Relativbewegung von Objekt und Heizfläche, da die Konvektionszone mitwandert.In this arrangement it is ensured that the recesses or in the present case, the bells are always completely or at least at the edge completely covered by the bottom of the container. The reverse flow minimizes the amount of false air. Even with the use of less energy and a low supply air, the formation of a stabilizing edge shell is achieved. This is true even with a parallel relative movement of object and heating surface, as the convection zone mitwandert.
Ferner ist die erfindungsgemäße Einrichtung in weiten Abschnitten der Konvektionszone steuerbar. Hierzu wird über Temperatur- und Strömungsprofile, die der Anwender wegabhängig vorgeben kann, eine Zone mit dem gewünschten Energiebedarf versorgt. Der Energiebedarf wird nach der Materialstärke, der Materialdichte oder nach den Wärmekapazitäten der aufzuheizenden Folie berechnet oder empirisch ermittelt. Danach kann die Folie gezielt temperiert werden.Furthermore, the device according to the invention can be controlled in wide sections of the convection zone. For this purpose, a zone with the required energy requirement is supplied via temperature and flow profiles that the user can specify depending on the path. The energy requirement is calculated or determined empirically based on the material thickness, the material density or on the heat capacities of the film to be heated. Thereafter, the film can be tempered specifically.
Eine schematische Übersicht des Verfahrensablaufs beim Schrumpfen zeigt die beiliegende
- 1. Umhüllen des Gebindes mit einer Folie
- 2. Ausbilden des Bodenbereichs mit überlappenden Folienenden
- 3. Anblasen der Überlappung mit in Umkehrströmung geführter Heißluft bei 200 bis 210°
- 4. zonal begrenzte Haltezeit bis zum Schmelzen der Folie, Dauer 1 - 2 Sekunden bei Strömungsgeschwindigkeiten von 25 - 35 Meter pro Sekunde
- 5. Formstabilisierung des Gebindes durch Ausbildung einer Randschale im Bodenbereich
- 6. vollständiges Schrumpfen der Folie durch seitliches Anblasen mittels Heißluft bei erhöhtem Druck
- 7. Anblasen mit Kaltluft zur Verfestigung der Folie
- 1. wrapping the container with a foil
- 2. Forming the bottom area with overlapping foil ends
- 3. Blowing the overlap with guided in reverse flow hot air at 200 to 210 °
- 4. zonally limited hold time until the film melts, lasting 1 - 2 seconds at flow rates of 25 - 35 meters per second
- 5. Shape stabilization of the container by forming a peripheral shell in the bottom area
- 6. complete shrinkage of the film by blowing side by hot air at elevated pressure
- 7. Blowing with cold air to solidify the film
Durch das Kühlen im letzten Verfahrensschritt wird zum einen der Kunststoff vom plastischen Bereich in den elastischen Bereich überführt, wobei die maximalen Spannungen im Material ansteigen und es sich dabei verfestigt. Zum anderen schrumpft die Folie auch noch bei dieser Abkühlung wodurch die Spannungen in der Folie ansteigen und die das Gebinde stabilisierenden Haltekräfte größer werden. Bei zu heißer Umgebung muss aktiv gekühlt werden, da die Umgebungsluft zur Verfestigung nicht ausreicht.By cooling in the last process step, on the one hand, the plastic is transferred from the plastic region into the elastic region, the maximum stresses in the material increasing and solidifying. On the other hand, the film also shrinks during this cooling whereby the tensions in the film increase and the container stabilizing holding forces are greater. If the environment is too hot, it must be actively cooled because the ambient air is insufficient to solidify.
- 11
- Gebindecontainer
- 22
- Förderbandconveyor belt
- 33
- HeißluftquelleHot air source
- 44
- Schrumpfanlageshrink wrapping machine
- 55
-
Heißluftzuführung
- a) Heißluftdüsen
- b) Heißluftdüsen
- a) hot air nozzles
- b) hot air nozzles
- 66
- Transportbandconveyor belt
- 77
-
Abluftsystem
- a) Abluftsystem
- b) Abluftsystem
- a) exhaust system
- b) exhaust air system
- 88th
- Foliefoil
- 99
- netzartige Strukturnet-like structure
- 1010
- Schieberpusher
- 1111
- Schieberpusher
- 1212
- Bodenflächefloor area
- 1313
- flaschenförmige Güterbottle-shaped goods
- 1414
- Düsejet
- 1515
- Konvektionszoneconvection
- 1616
-
Absaugöffnung (
Fig.3 ) Gleitplatte (Fig.5 )Suction opening (Figure 3 ) Sliding plate (Figure 5 ) - 1717
-
Absaugöffnung (
Fig.3 ) Gleitsteg (Fig.5 )Suction opening (Figure 3 ) Sliding bridge (Figure 5 ) - 1818
- Netzartiges TransportbandMesh-like conveyor belt
- 1919
-
Produkte (
Fig.5 ) Einflußbereich der Zuluft (Fig.6 )Products (Figure 5 ) Influence range of the supply air (Figure 6 ) - 2020
- Schrumpffolieshrink film
- 2121
- Zuluftdüsensupply nozzles
- 2222
- Abluftdüsenexhaust nozzle
- 2323
- Längsschieberlongitudinal slide
- 2424
- ExcenterverstellungEccentric
- 2525
- Zonenaktivierungzone activation
- 2626
- Querschieber LochplatteCross slide perforated plate
- 2727
- RohreTube
- 2828
- Trenngehäuseseparating housing
- 2929
- LuftaustauschplatteAir change plate
- 3030
- Schieberplatteslide plate
- 3131
- Gleitstegesliding webs
- 3232
- Randschaleperipheral shell
- 3333
- Düsenfeldnozzle array
Claims (12)
- Shrinking process for the production of solid, transportable and printable packages or containers, especially of bottle packages having a height/width ratio of >1 and containing heat-sensitive pourable or flowable products, consisting of enveloping the articles to be packaged with a film such that, on the base surface, an overlapping section of the ends of the film is formed, heating by heat exchange or convection in order to fuse the free ends together in the area of overlap, and a final heating in a shrink oven, the package or container so produced being stabilised by the shrinking process,
characterized in that
the inflowing hot air is first zonally confined to the base surface of the package or container, for forming a peripheral shell in the region of the bottoms of the bottles, and that during this process the shape of the package or container is stabilised, i.e. becomes rigid;
that during the stabilisation, the package or container is continuously transported and, during this process, the hot air, which is directed, in a bundle of discretely distributed gas jets, onto the base area of the package or container, is deflected and returned following a zonally confined heat exchange with the film;
and that, in the shrink oven, further hot gas is directed laterally against the continuously transported package or container at an increased lateral blow velocity in order to complete the shrinking process. - Shrinking process according to any one of the preceding claims, characterised in that the film is welded so as to form a base of the package or container and at the same time is shrunk, whereby a positive-locking shape of the base surface of the package or container is formed.
- Shrinking process according to any one of the preceding claims, characterised in that the packages or containers are moved on a conveyor device while the welding process is taking place, with the inflowing hot air being sucked off following the heat exchange and being controlled in such a way that the welding is confined to the area of overlap or to a partial area of the base.
- Shrinking process according to any one of the preceding claims, characterised in that the zonal application of hot air is accomplished by activation of discretely distributed supply air units and drawing-off air units which can be controlled mechanically, hydraulically or electrically.
- Shrinking process according to any one of the preceding claims, characterised in that in the drawing-off air unit there is created a partial vacuum which is sufficient to accelerate the hot air, coming from the supply air unit, in the area of overlap and to guide it at increased velocity over the film ends that are to be welded together.
- Shrinking process according to any one of the preceding claims, characterised in that the supply air units and drawing-off air units are controlled by transverse slides or longitudinal slides, with individual units of the discretely distributed supply air units and drawing-off air units being activated in accordance with the zonal application of hot air onto the film ends in the area of overlap.
- Device for carrying out a shrinking process for producing solid, transportable and printable packages or containers, especially bottle packages having a height/width ratio of >1 and containing heat-sensitive pourable or flowable products, consisting of a packaging machine in which the articles to be packaged are wrapped with a film, heated and then packaged to form a solid package or container in a shrink oven, wherein the packages or containers are moved on a transport belt while being heated, characterized in that said transport belt (6) has a netlike structure (9), wherein in the heating area underneath the transport belt there are arranged discretely distributed supply air and drawing-off air units (21, 22), whereas in the shrinking area hot-air nozzles (5) are directed against the packages or containers, for lateral application of hot air at increased blowing velocity,
and that underneath the netlike structure the supply air units and drawing-off air units (21, 22) are provided with transverse and longitudinal slides, which are arranged in a register-like manner, to effect a zonal confinement of the hot air stream to the base area of the package or container. - Device according to claim 7, characterised in that the supply air and drawing-off air is guided in a closed circuit underneath the transport belt (6).
- Device according to claim 7 or 8, characterised in that each supply air unit and drawing-off air unit (21, 22) is arranged in a recess provided in a slide plate (16), and that the supply air units and drawing-off air units required for heating the base surface, which are present in the form of discretely distributed recesses in the slide plate (16), are activated by means of transverse and longitudinal slides (23, 26) which are arranged in a register-like manner.
- Device according to claims 7, 8, 9, characterised in that said recesses are embodied as bells or channels.
- Device according to any one of the preceding claims, characterised in that the gas flow is embodied as a reverse flow, with the flow velocity of the hot gas being reversed after the heat exchange with the base surface.
- Device according to any one of the preceding claims, characterised in that the outflow direction or the inflow direction of the supply air units and drawing-off air units (21, 22) are arranged next to one another in a parallel manner.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL06753186T PL1957371T3 (en) | 2005-12-09 | 2006-05-19 | Shrinking process for producing solid, transportable and printable containers and device for carrying out said shrinking process |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005059295A DE102005059295B4 (en) | 2004-12-10 | 2005-12-09 | Shrinking process for the production of solid, transportable and printable containers and apparatus for carrying out such a shrinking process |
| PCT/DE2006/000870 WO2007065385A1 (en) | 2005-12-09 | 2006-05-19 | Shrinking process for producing solid, transportable and printable containers and device for carrying out said shrinking process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1957371A1 EP1957371A1 (en) | 2008-08-20 |
| EP1957371B1 true EP1957371B1 (en) | 2009-05-06 |
Family
ID=36741222
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP06753186A Active EP1957371B1 (en) | 2005-12-09 | 2006-05-19 | Shrinking process for producing solid, transportable and printable containers and device for carrying out said shrinking process |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7946100B2 (en) |
| EP (1) | EP1957371B1 (en) |
| JP (1) | JP5064410B2 (en) |
| CN (1) | CN101356094B (en) |
| AT (1) | ATE430697T1 (en) |
| BR (1) | BRPI0619593B1 (en) |
| DE (1) | DE502006003687D1 (en) |
| PL (1) | PL1957371T3 (en) |
| WO (1) | WO2007065385A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE202009005047U1 (en) | 2009-07-21 | 2009-09-17 | Krones Ag | shrink tunnel |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100293901A1 (en) * | 2009-05-20 | 2010-11-25 | Martin Malthouse | Shrink Systems for Labels |
| CN101633415B (en) * | 2009-08-06 | 2011-07-06 | 贵阳黔中化轻制品厂 | Methods for packaging and boxing integral wild-mouth bottles by heat-shrinkable film |
| DE102010012597A1 (en) * | 2010-03-24 | 2011-09-29 | Multivac Sepp Haggenmüller Gmbh & Co. Kg | Device for transporting objects |
| US20120240525A1 (en) * | 2011-03-25 | 2012-09-27 | Summerford Wayne C | Method and System for Applying Tamper Evident Banding |
| EP2653391B1 (en) * | 2012-04-18 | 2015-07-29 | Borealis AG | A process for collation shrink wrapping a plurality of individual containers |
| EP2653394B1 (en) * | 2012-04-18 | 2015-03-04 | Krones Aktiengesellschaft | Shrinking device with cover bar |
| DE102013103863A1 (en) * | 2013-04-17 | 2014-10-23 | Krones Aktiengesellschaft | Shrinking device and method for adjusting a shrinking device |
| DE102013104666A1 (en) * | 2013-05-07 | 2014-11-13 | Krones Ag | Apparatus and method for producing container assemblies |
| KR20160029532A (en) * | 2014-09-05 | 2016-03-15 | 김승섭 | Apparatus for supplying steam in steam packing machine |
| CN104260939A (en) * | 2014-09-21 | 2015-01-07 | 江苏艾津农化有限责任公司 | Steam heat shrink film packing machine |
| DE102017119145A1 (en) * | 2017-08-22 | 2019-02-28 | Krones Aktiengesellschaft | Shrinking device and method for sucking air from an interior of a shrinking device |
| CN107804530A (en) * | 2017-10-31 | 2018-03-16 | 佛山汉格斯环保科技有限公司 | A kind of environment protecting tableware heat shrinkage film machine |
| FR3090590B1 (en) * | 2018-12-20 | 2021-06-11 | C E R M E X Constructions Etudes Et Rech De Materiels Pour Lemballage Dexpedition | A method of packaging by bundling batches of products, a heating device and installation with such a device. |
| CN110053826A (en) * | 2019-04-25 | 2019-07-26 | 北京市继远斋食品厂 | A kind of thermal contraction machine |
| TWM646063U (en) * | 2023-05-04 | 2023-09-11 | 洪子欽 | Air hole adjustment device of heat shrinkage furnace for packaging |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3222800A (en) * | 1962-05-29 | 1965-12-14 | Weldotron Corp | Apparatus for shrinking wrappers of packages |
| US3309835A (en) * | 1964-01-23 | 1967-03-21 | Diamond Int Corp | Method and apparatus for producing packages with a heat-shrink film |
| US3353333A (en) * | 1965-05-10 | 1967-11-21 | Corley Miller Inc | Package sealing machine |
| US3430358A (en) * | 1967-01-30 | 1969-03-04 | Doughboy Ind Inc | Shrink tunnel with conveyer and air directing means |
| US3744146A (en) * | 1970-06-02 | 1973-07-10 | Mill Eng Inc | Shrink tunnel |
| US3727324A (en) * | 1970-09-18 | 1973-04-17 | Despatch Ind Inc | Shrink tunnel for palletized loads |
| JPS4938664U (en) * | 1972-07-11 | 1974-04-05 | ||
| DE2320424A1 (en) * | 1972-09-04 | 1974-03-14 | Lara Sa | PROCEDURE FOR CONTINUOUS PACKAGING OF ITEMS AND DEVICE FOR CARRYING OUT THE PROCEDURE |
| US3889394A (en) * | 1973-06-04 | 1975-06-17 | Fox Valley Corp | Heat shrink apparatus |
| US3866331A (en) * | 1974-03-07 | 1975-02-18 | Itp Corp | Flow control shrink wrap tunnel |
| JPS5312469U (en) * | 1976-07-12 | 1978-02-01 | ||
| FR2571687B1 (en) * | 1984-10-12 | 1987-04-24 | Minnesota Mining & Mfg | PACKAGING PROCESS UNDER RETRACTABLE FILM WITH TRANSPORT HANDLE, FILM FOR IMPLEMENTING IT AND PACKAGE CARRIED OUT WITH SUCH FILM, FOLLOWING THIS PROCESS |
| US4676006A (en) * | 1986-10-07 | 1987-06-30 | Ossid Corporation | Poultry basket water removal apparatus and method |
| US5062217A (en) * | 1990-11-13 | 1991-11-05 | Ossid Corporation | Selective sequential shrink apparatus and process |
| WO2002036436A1 (en) * | 2000-11-01 | 2002-05-10 | Claude Andrew Neagle | Adaptable packaging machine heat shrink tunnel |
| ITMI20011825A1 (en) * | 2001-08-29 | 2003-03-01 | Smi Spa | THERMORETRATION TUNNEL OVEN FOR THE PRODUCTION OF FILM PACKAGING OF HEAT SHRINKABLE MATERIAL AND RE PACKAGING PROCEDURE |
| US6689180B1 (en) * | 2002-11-14 | 2004-02-10 | Benison & Co., Ltd. | Hot air flow control device of heat-shrinking film packaging machine |
| US6772575B2 (en) * | 2002-12-30 | 2004-08-10 | Lantech Management Corp. And Lantech Holding Corp. | Shrink wrap apparatus and method of shrink wrapping products |
| US20040231481A1 (en) * | 2003-05-23 | 2004-11-25 | Floding Daniel Leonard | Apparatus for perforating or slitting heat shrink film |
-
2006
- 2006-05-19 CN CN2006800507429A patent/CN101356094B/en active Active
- 2006-05-19 AT AT06753186T patent/ATE430697T1/en active
- 2006-05-19 PL PL06753186T patent/PL1957371T3/en unknown
- 2006-05-19 WO PCT/DE2006/000870 patent/WO2007065385A1/en not_active Ceased
- 2006-05-19 JP JP2008542585A patent/JP5064410B2/en active Active
- 2006-05-19 BR BRPI0619593A patent/BRPI0619593B1/en active IP Right Grant
- 2006-05-19 EP EP06753186A patent/EP1957371B1/en active Active
- 2006-05-19 US US12/096,724 patent/US7946100B2/en active Active
- 2006-05-19 DE DE502006003687T patent/DE502006003687D1/en active Active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE202009005047U1 (en) | 2009-07-21 | 2009-09-17 | Krones Ag | shrink tunnel |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101356094A (en) | 2009-01-28 |
| CN101356094B (en) | 2011-11-30 |
| JP2009518239A (en) | 2009-05-07 |
| EP1957371A1 (en) | 2008-08-20 |
| BRPI0619593A2 (en) | 2011-10-04 |
| WO2007065385A1 (en) | 2007-06-14 |
| US7946100B2 (en) | 2011-05-24 |
| US20090013649A1 (en) | 2009-01-15 |
| JP5064410B2 (en) | 2012-10-31 |
| BRPI0619593A8 (en) | 2017-10-24 |
| ATE430697T1 (en) | 2009-05-15 |
| PL1957371T3 (en) | 2009-10-30 |
| BRPI0619593B1 (en) | 2018-10-09 |
| DE502006003687D1 (en) | 2009-06-18 |
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