EP1572335B1 - Micromelangeur lamellaire statique - Google Patents
Micromelangeur lamellaire statique Download PDFInfo
- Publication number
- EP1572335B1 EP1572335B1 EP03780105.7A EP03780105A EP1572335B1 EP 1572335 B1 EP1572335 B1 EP 1572335B1 EP 03780105 A EP03780105 A EP 03780105A EP 1572335 B1 EP1572335 B1 EP 1572335B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- micro
- aperture
- plate
- slot
- mixer according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000003068 static effect Effects 0.000 title claims description 25
- 238000003475 lamination Methods 0.000 title claims description 21
- 239000012530 fluid Substances 0.000 claims description 52
- 238000002156 mixing Methods 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 4
- 230000001804 emulsifying effect Effects 0.000 claims description 3
- 238000007864 suspending Methods 0.000 claims description 3
- 238000009792 diffusion process Methods 0.000 claims description 2
- 238000003698 laser cutting Methods 0.000 claims 2
- 238000003466 welding Methods 0.000 claims 2
- 238000004026 adhesive bonding Methods 0.000 claims 1
- 239000000919 ceramic Substances 0.000 claims 1
- 238000009826 distribution Methods 0.000 claims 1
- 238000004049 embossing Methods 0.000 claims 1
- 230000003628 erosive effect Effects 0.000 claims 1
- 238000005530 etching Methods 0.000 claims 1
- 239000011521 glass Substances 0.000 claims 1
- 238000000608 laser ablation Methods 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 238000003801 milling Methods 0.000 claims 1
- 230000000737 periodic effect Effects 0.000 claims 1
- 238000001020 plasma etching Methods 0.000 claims 1
- 239000004033 plastic Substances 0.000 claims 1
- 238000003825 pressing Methods 0.000 claims 1
- 238000004080 punching Methods 0.000 claims 1
- 238000005476 soldering Methods 0.000 claims 1
- 238000007789 sealing Methods 0.000 description 5
- FIKFLLIUPUVONI-UHFFFAOYSA-N 8-(2-phenylethyl)-1-oxa-3,8-diazaspiro[4.5]decan-2-one;hydrochloride Chemical compound Cl.O1C(=O)NCC11CCN(CCC=2C=CC=CC=2)CC1 FIKFLLIUPUVONI-UHFFFAOYSA-N 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/40—Static mixers
- B01F25/42—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
- B01F25/421—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions by moving the components in a convoluted or labyrinthine path
- B01F25/422—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions by moving the components in a convoluted or labyrinthine path between stacked plates, e.g. grooved or perforated plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/40—Static mixers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/20—Jet mixers, i.e. mixers using high-speed fluid streams
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F33/00—Other mixers; Mixing plants; Combinations of mixers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F33/00—Other mixers; Mixing plants; Combinations of mixers
- B01F33/30—Micromixers
- B01F33/301—Micromixers using specific means for arranging the streams to be mixed, e.g. channel geometries or dispositions
- B01F33/3012—Interdigital streams, e.g. lamellae
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F33/00—Other mixers; Mixing plants; Combinations of mixers
- B01F33/30—Micromixers
- B01F33/301—Micromixers using specific means for arranging the streams to be mixed, e.g. channel geometries or dispositions
- B01F33/3012—Interdigital streams, e.g. lamellae
- B01F33/30121—Interdigital streams, e.g. lamellae the interdigital streams being concentric lamellae
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S366/00—Agitating
- Y10S366/03—Micromixers: variable geometry from the pathway influences mixing/agitation of non-laminar fluid flow
Definitions
- the invention relates to a micromixer for mixing, dispersing, emulsifying or suspending at least two fluid phases, which must contain at least one slot plate with slot openings and an aperture plate arranged above it with blind slots.
- the slot openings in the slot plate (s) and diaphragm plate (s) are designed as through holes.
- Static micromixers are key elements of microreaction technology.
- Statistical micromixers exploit the principle of multilamination to achieve rapid mixing of fluid phases by diffusion. By a geometrical configuration of alternately arranged lamellae, it is possible to ensure a good mixing in the microscopic range.
- Multilamination mixers of structured and periodically stacked thin plates have already been extensively described in the literature; Examples of this can be found in the German patents DE 44 16 343 . DE 195 40 292 . DE 199 17 156 A1 and the German patent application DE 199 28 123 , The German patent application DE 199 27 554 also describes a micromixer for mixing two or more educts, in contrast to the multilamination mixers consisting of structured and periodically stacked thin plates, the micromixer having mixing cells.
- Each of these mixing cells has a feed chamber to which at least two groups of channel fingers adjoin, which engage in a comb-like manner between the channel fingers to form mixing areas.
- Above the mixing area are outlet slots that extend perpendicular to the channel fingers and through which the product exits. Due to the parallel connection in two spatial directions, a significantly higher throughput is possible.
- the advantages achieved by the invention are that the static lamination micro mixing can be manufactured inexpensively, is easy to clean and the fluids to be mixed are mixed together quickly and effectively.
- the pressure loss is so low that it can also be used for large throughputs.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Claims (13)
- Micro-mélangeur statique à stratification servant à mélanger, disperser, émulsifier ou mettre en suspension au moins deux phases fluides, et présentant :une partie inférieure de boîtier (10) qui présente des canaux séparés d'amenée (11a/b) ouverts sur le côté supérieur de la partie inférieure de boîtier,une plaque fendue (20) placée sur la partie inférieure de boîtier et dans laquelle des ouvertures en fente (22a/b) sont disposées par paires sous la forme d'ouvertures continues à bord fermé et d'une largeur d'au moins 500 micromètres,une plaque d'écran (30) placée sur la plaque fendue et présentant au moins une ouverture d'écran (31) continue, en forme de fente à bord fermé et dont la largeur est d'au moins 500 micromètres etun espace de mélange (45) situé au-dessus de la plaque d'écran,l'ouverture en fente de la paire d'ouvertures en fente ménagées dans la plaque fendue (20) recouvre par une de ses extrémités un des canaux d'amenée (11) de la partie inférieure de boîtier (10) tandis que l'autre ouverture en fente de la paire recouvre par une extrémité un autre canal d'amenée (11) ménagé dans la partie inférieure de boîtier (10), les deux ouvertures en fente de la paire formant avec la même ouverture (31) de l'écran ménagée dans la plaque d'écran exactement une surface de superposition.
- Micro-mélangeur selon la revendication 1, caractérisé en ce que la section transversale des ouvertures en fente ménagées dans la plaque a la forme d'un entonnoir ou d'un biseau.
- Micro-mélangeur selon les revendications 1 ou 2, caractérisé en ce que les fentes ménagées dans la plaque d'écran sont parallèles et décalées l'une par rapport à l'autre et/ou disposées l'une par rapport à l'autre selon un motif périodique.
- Micro-mélangeur selon les revendications 1 à 3, caractérisé en ce que les ouvertures ménagées dans la plaque fendue et les ouvertures ménagées dans la plaque d'écran sont disposées à un angle mutuel de 90°.
- Micro-mélangeur selon les revendications 1 à 4, caractérisé en ce que les ouvertures ménagées dans la plaque fendue et les ouvertures ménagées dans la plaque d'écran ont une largeur inférieure à 100 µm.
- Micro-mélangeur selon les revendications 1 à 5, caractérisé en ce que la plaque fendue et la plaque d'écran sont réalisées totalement ou en partie en métal, verre, céramique, matière synthétique ou en une combinaison de ces matériaux.
- Micro-mélangeur selon les revendications 1 à 6, caractérisé en ce que la plaque fendue et la plaque d'écran sont réalisées par estampage, gaufrage, fraisage, érosion, gravure, gravure au plasma, découpe au laser, enlèvement au laser ou par la technique dite LIGA, mais de préférence par découpe au laser ou par la technique LIGA.
- Micro-mélangeur selon les revendications 1 à 7, caractérisé en ce que la plaque fendue et la plaque d'écran sont constituées d'un empilement de minces plaques micro-structurées.
- Micro-mélangeur selon la revendication 8, caractérisé en ce que les minces plaques micro-structurées sont reliées les unes aux autres en correspondance de matière par brasage, soudage, soudage par diffusion, collage ou en correspondance mécanique par vissage, compression ou rivetage.
- Micro-mélangeur selon les revendications 1 à 9, caractérisé en ce que le micro-mélangeur est placé dans un boîtier prévu dans ce but.
- Micro-mélangeur selon les revendications 1 à 10, caractérisé en ce que le boîtier contient des canaux qui permettent une répartition spatiale des phases fluides.
- Micro-mélangeur selon les revendications 1 à 11, caractérisé en ce que les canaux de répartition des fluides sont disposés dans le boîtier en parallèle et décalage mutuel, radialement, concentriquement ou les uns derrière les autres.
- Procédé de mélange, de dispersion, d'émulsification ou de mise en suspension d'au moins deux phases fluides, caractérisé en ce qu'il utilise au moins un micro-mélangeur statique à stratification selon l'une des revendications 1 à 12.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE20218972U | 2002-12-07 | ||
| DE20218972U DE20218972U1 (de) | 2002-12-07 | 2002-12-07 | Statischer Laminationsmikrovermischer |
| PCT/EP2003/013603 WO2004052518A2 (fr) | 2002-12-07 | 2003-12-03 | Micromelangeur lamellaire statique |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1572335A2 EP1572335A2 (fr) | 2005-09-14 |
| EP1572335B1 true EP1572335B1 (fr) | 2013-05-29 |
Family
ID=7977747
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP03780105.7A Expired - Lifetime EP1572335B1 (fr) | 2002-12-07 | 2003-12-03 | Micromelangeur lamellaire statique |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7909502B2 (fr) |
| EP (1) | EP1572335B1 (fr) |
| JP (2) | JP4847700B2 (fr) |
| KR (1) | KR100806401B1 (fr) |
| CN (1) | CN100360218C (fr) |
| AU (1) | AU2003288216A1 (fr) |
| DE (1) | DE20218972U1 (fr) |
| WO (1) | WO2004052518A2 (fr) |
Families Citing this family (74)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6969505B2 (en) | 2002-08-15 | 2005-11-29 | Velocys, Inc. | Process for conducting an equilibrium limited chemical reaction in a single stage process channel |
| US6622519B1 (en) | 2002-08-15 | 2003-09-23 | Velocys, Inc. | Process for cooling a product in a heat exchanger employing microchannels for the flow of refrigerant and product |
| US7014835B2 (en) | 2002-08-15 | 2006-03-21 | Velocys, Inc. | Multi-stream microchannel device |
| DE20218972U1 (de) | 2002-12-07 | 2003-02-13 | Ehrfeld Mikrotechnik AG, 55234 Wendelsheim | Statischer Laminationsmikrovermischer |
| US7294734B2 (en) | 2003-05-02 | 2007-11-13 | Velocys, Inc. | Process for converting a hydrocarbon to an oxygenate or a nitrile |
| US8580211B2 (en) | 2003-05-16 | 2013-11-12 | Velocys, Inc. | Microchannel with internal fin support for catalyst or sorption medium |
| US7307104B2 (en) | 2003-05-16 | 2007-12-11 | Velocys, Inc. | Process for forming an emulsion using microchannel process technology |
| US7220390B2 (en) | 2003-05-16 | 2007-05-22 | Velocys, Inc. | Microchannel with internal fin support for catalyst or sorption medium |
| US7485671B2 (en) | 2003-05-16 | 2009-02-03 | Velocys, Inc. | Process for forming an emulsion using microchannel process technology |
| DE10333922B4 (de) * | 2003-07-25 | 2005-11-17 | Wella Ag | Bauteile für statische Mikromischer, daraus aufgebaute Mikromischer und deren Verwendung zum Mischen, zum Dispergieren oder zur Durchführung chemischer Reaktionen |
| CA2535842C (fr) | 2003-08-29 | 2012-07-10 | Velocys Inc. | Procede permettant de separer l'azote du methane a l'aide d'une technologie de processus de microcanal |
| US7029647B2 (en) | 2004-01-27 | 2006-04-18 | Velocys, Inc. | Process for producing hydrogen peroxide using microchannel technology |
| US7084180B2 (en) | 2004-01-28 | 2006-08-01 | Velocys, Inc. | Fischer-tropsch synthesis using microchannel technology and novel catalyst and microchannel reactor |
| US9023900B2 (en) | 2004-01-28 | 2015-05-05 | Velocys, Inc. | Fischer-Tropsch synthesis using microchannel technology and novel catalyst and microchannel reactor |
| US8747805B2 (en) | 2004-02-11 | 2014-06-10 | Velocys, Inc. | Process for conducting an equilibrium limited chemical reaction using microchannel technology |
| DE502005005027D1 (de) | 2004-02-17 | 2008-09-25 | Ehrfeld Mikrotechnik Bts Gmbh | Mikromischer |
| DE102005003965A1 (de) * | 2005-01-27 | 2006-08-10 | Ehrfeld Mikrotechnik Gmbh | Mikromischer |
| US7459508B2 (en) | 2004-03-02 | 2008-12-02 | Velocys, Inc. | Microchannel polymerization reactor |
| US20070140042A1 (en) * | 2004-06-04 | 2007-06-21 | Gerhard Schanz | Multicomponent packaging with static micromixer |
| DE102004035462A1 (de) * | 2004-07-22 | 2006-03-16 | Ehrfeld Mikrotechnik Bts Gmbh | Vorrichtung und Verfahren zur kontinuierlichen Durchführung chemischer Prozesse |
| EP1781389A2 (fr) | 2004-07-23 | 2007-05-09 | Velocys, Inc. | Procede de distillation mettant en oeuvre la technologie des microcanaux |
| US7305850B2 (en) | 2004-07-23 | 2007-12-11 | Velocys, Inc. | Distillation process using microchannel technology |
| CN101023068B (zh) | 2004-08-12 | 2013-02-13 | 万罗赛斯公司 | 使用微通道工艺技术将乙烯转化成环氧乙烷的方法 |
| WO2006039568A1 (fr) | 2004-10-01 | 2006-04-13 | Velocys Inc. | Procede de melange multiphase par technologie de traitement a micro-canaux |
| CA2586971C (fr) | 2004-11-12 | 2013-07-23 | Velocys Inc. | Procede utilisant la technologie de microcanal pour conduire une reaction d'alkylation ou d'acylation |
| WO2006055609A1 (fr) | 2004-11-16 | 2006-05-26 | Velocys Inc. | Procede reactionnel multiphase faisant appel a une technologie de microcanaux |
| US7507274B2 (en) | 2005-03-02 | 2009-03-24 | Velocys, Inc. | Separation process using microchannel technology |
| US20080159069A1 (en) * | 2005-04-06 | 2008-07-03 | Stichting Voor De Technische Wentenschappen | Inlet Section for Micro-Reactor |
| KR100695151B1 (ko) | 2005-05-18 | 2007-03-14 | 삼성전자주식회사 | 교차 채널을 이용한 유체 혼합 장치 |
| US9101890B2 (en) | 2005-05-25 | 2015-08-11 | Velocys, Inc. | Support for use in microchannel processing |
| US7935734B2 (en) | 2005-07-08 | 2011-05-03 | Anna Lee Tonkovich | Catalytic reaction process using microchannel technology |
| CN100345617C (zh) * | 2005-09-22 | 2007-10-31 | 上海交通大学 | 磁电式循环混合器 |
| JP4855471B2 (ja) * | 2005-09-26 | 2012-01-18 | エルジー・ケム・リミテッド | 積層反応装置 |
| DE102005049294C5 (de) | 2005-10-14 | 2012-05-03 | Ehrfeld Mikrotechnik Bts Gmbh | Verfahren zur Herstellung organischer Peroxide mittels Mikroreaktionstechnik |
| DE102005060280B4 (de) * | 2005-12-16 | 2018-12-27 | Ehrfeld Mikrotechnik Bts Gmbh | Integrierbarer Mikromischer sowie dessen Verwendung |
| CN1800161B (zh) * | 2006-01-16 | 2010-11-10 | 华东理工大学 | 一种用于连续生产过氧化甲乙酮的方法和微反应装置 |
| CN101479317A (zh) * | 2006-05-23 | 2009-07-08 | 巴斯夫欧洲公司 | 制备聚醚多元醇的方法 |
| US20110158852A1 (en) * | 2008-07-18 | 2011-06-30 | Castro Gustavo H | Offset path mixers and fluid systems includng the same |
| WO2010009239A2 (fr) * | 2008-07-18 | 2010-01-21 | 3M Innovative Properties Company | Mélangeurs statiques à passages sinueux et systèmes à fluide les incluant |
| WO2010009247A2 (fr) * | 2008-07-18 | 2010-01-21 | 3M Innovative Properties Company | Mélangeurs en y entrecroisés et systèmes à fluide les incluant |
| JP2012519577A (ja) | 2009-03-06 | 2012-08-30 | エールフエルト・ミクロテヒニク・ベー・テー・エス・ゲー・エム・ベー・ハー | 同軸の小型のスタティックミキサおよびその使用 |
| DE102009038019B4 (de) * | 2009-08-12 | 2011-11-17 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | 3D Mikro-Strukturierung zur Erzeugung von Misch- und Kanalstrukturen in Multilayertechnologie zur Verwendung in oder zum Aufbau von Reaktoren |
| JP5212313B2 (ja) * | 2009-08-24 | 2013-06-19 | 株式会社日立プラントテクノロジー | 乳化装置 |
| CN101716473B (zh) * | 2009-11-04 | 2011-11-30 | 中国科学院长春光学精密机械与物理研究所 | 芯片内微混合器及其制作方法 |
| EP2506961B1 (fr) | 2009-11-30 | 2014-01-08 | Corning Incorporated | Mélangeurs à courbure en u et à corps en nid-d'abeilles |
| EP2383245A3 (fr) | 2010-04-20 | 2012-02-22 | Bayer Technology Services GmbH | Procédé d'oxydation continue de thioéthers |
| JP5062383B2 (ja) * | 2010-06-28 | 2012-10-31 | Dic株式会社 | マイクロミキサー |
| WO2012025548A1 (fr) | 2010-08-27 | 2012-03-01 | Solvay Sa | Procédé pour la préparation d'alcénones |
| JP5642488B2 (ja) * | 2010-10-04 | 2014-12-17 | 株式会社神戸製鋼所 | 流路構造体 |
| JP2012120962A (ja) * | 2010-12-07 | 2012-06-28 | Kobe Steel Ltd | 流路構造体 |
| WO2013096788A1 (fr) | 2011-12-21 | 2013-06-27 | Ikaria Development Subsidiary One Llc | Procédé pour la fabrication de solution d'alginate partiellement réticulé |
| JP5832282B2 (ja) * | 2011-12-28 | 2015-12-16 | 株式会社フジクラ | マイクロミキサ |
| EP2664607A1 (fr) | 2012-05-16 | 2013-11-20 | Solvay Sa | Processus de fluoration |
| GB201214122D0 (en) | 2012-08-07 | 2012-09-19 | Oxford Catalysts Ltd | Treating of catalyst support |
| CN103977720B (zh) * | 2013-09-10 | 2016-01-13 | 中国中化股份有限公司 | 一种组合式层状流体配分混合装置及其应用 |
| WO2015104976A1 (fr) * | 2014-01-09 | 2015-07-16 | 株式会社日立ハイテクノロジーズ | Dispositif de mélange de liquides et dispositif de chromatographie en phase liquide |
| US10161690B2 (en) * | 2014-09-22 | 2018-12-25 | Hamilton Sundstrand Space Systems International, Inc. | Multi-layer heat exchanger and method of distributing flow within a fluid layer of a multi-layer heat exchanger |
| US9937472B2 (en) | 2015-05-07 | 2018-04-10 | Techmetals, Inc. | Assembly operable to mix or sparge a liquid |
| WO2016201218A2 (fr) | 2015-06-12 | 2016-12-15 | Velocys, Inc. | Procédé de conversion de gaz de synthèse |
| KR101688419B1 (ko) * | 2016-08-11 | 2016-12-21 | (주)케이클라우드 | 가상개인정보를 이용한 보안 운송장 발급관리 시스템 및 방법 |
| CN106423006A (zh) * | 2016-10-31 | 2017-02-22 | 山东豪迈化工技术有限公司 | 一种对冲微反应单元及微反应器 |
| CN106823946B (zh) * | 2017-01-19 | 2022-08-16 | 南京理工大学 | 一种振荡流微混合器 |
| WO2019012399A1 (fr) | 2017-07-14 | 2019-01-17 | 3M Innovative Properties Company | Adaptateur pour le transport de plusieurs flux de liquide |
| BR112020001161A2 (pt) * | 2017-07-20 | 2020-07-21 | Hydra-Flex Inc. | dispositivo de diluição para distribuição de fluido |
| WO2019168130A1 (fr) * | 2018-02-28 | 2019-09-06 | 国立大学法人東京工業大学 | Dispositif de génération de microgouttelettes/bulles |
| CN108273456B (zh) * | 2018-03-29 | 2023-07-04 | 睦化(上海)流体工程有限公司 | 一种微孔涡流板式混合反应器及其应用 |
| CN110433876B (zh) * | 2018-05-03 | 2022-05-17 | 香港科技大学 | 微流控装置及其制造方法、口罩和过滤悬浮颗粒的方法 |
| GB201817692D0 (en) * | 2018-10-30 | 2018-12-19 | Ge Healthcare | Mixing device |
| US11633703B2 (en) | 2020-04-10 | 2023-04-25 | Sonny's Hfi Holdings, Llc | Insert assembly for foaming device |
| US11938480B2 (en) * | 2020-05-14 | 2024-03-26 | The Board Of Trustees Of The University Of Illinois Urbana, Illinois | Microfluidic diagnostic device with a three-dimensional (3D) flow architecture |
| EP4249109A4 (fr) * | 2020-11-20 | 2024-11-13 | Japan Science and Technology Agency | Dispositif de génération de micro-gouttelettes de liquide à deux phases |
| WO2022197506A1 (fr) | 2021-03-15 | 2022-09-22 | Sonny's Hfi Holdings, Llc | Dispositif de génération de mousse |
| CN114797613B (zh) * | 2021-11-08 | 2024-08-02 | 上海立得催化剂有限公司 | 一种氯化镁球形分散系统及方法 |
| CN114534652B (zh) * | 2022-02-08 | 2024-07-19 | 上海天泽云泰生物医药有限公司 | 波形微结构混合单元及其用途 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US422671A (en) * | 1890-03-04 | willis | ||
| US3881701A (en) * | 1973-09-17 | 1975-05-06 | Aerojet General Co | Fluid mixer reactor |
| US5534328A (en) * | 1993-12-02 | 1996-07-09 | E. I. Du Pont De Nemours And Company | Integrated chemical processing apparatus and processes for the preparation thereof |
| US5887977A (en) * | 1997-09-30 | 1999-03-30 | Uniflows Co., Ltd. | Stationary in-line mixer |
| DE10041823A1 (de) * | 2000-08-25 | 2002-03-14 | Inst Mikrotechnik Mainz Gmbh | Verfahren und statischer Mikrovermischer zum Mischen mindestens zweier Fluide |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL6710428A (fr) | 1967-07-27 | 1969-01-29 | ||
| US4222671A (en) * | 1978-09-05 | 1980-09-16 | Gilmore Oscar Patrick | Static mixer |
| JPS55147729A (en) | 1979-05-08 | 1980-11-17 | Sharp Corp | Data inpt unit |
| JPS5662120A (en) * | 1979-10-25 | 1981-05-27 | Hitachi Chem Co Ltd | Production of unsaturated polyester molded object having high surface hardness |
| JPS5710752Y2 (fr) * | 1980-10-16 | 1982-03-02 | ||
| DE3782044T2 (de) * | 1987-04-10 | 1993-03-25 | Chugoku Kayaku | Mischapparat. |
| DE3926466C2 (de) | 1989-08-10 | 1996-12-19 | Christoph Dipl Ing Caesar | Mikroreaktor zur Durchführung chemischer Reaktionen von zwei chemischen Stoffen mit starker Wärmetönung |
| US5016707A (en) * | 1989-12-28 | 1991-05-21 | Sundstrand Corporation | Multi-pass crossflow jet impingement heat exchanger |
| DE4416343C2 (de) * | 1994-05-09 | 1996-10-17 | Karlsruhe Forschzent | Statischer Mikro-Vermischer |
| US5595712A (en) * | 1994-07-25 | 1997-01-21 | E. I. Du Pont De Nemours And Company | Chemical mixing and reaction apparatus |
| JP2587390B2 (ja) * | 1994-10-03 | 1997-03-05 | 特殊機化工業株式会社 | 液体の超微粒化混合装置 |
| DE19511603A1 (de) * | 1995-03-30 | 1996-10-02 | Norbert Dr Ing Schwesinger | Vorrichtung zum Mischen kleiner Flüssigkeitsmengen |
| CA2222126A1 (fr) * | 1995-06-16 | 1997-01-03 | Fred K. Forster | Procede et dispositif miniaturise d'extraction differentielle |
| DE19540292C1 (de) | 1995-10-28 | 1997-01-30 | Karlsruhe Forschzent | Statischer Mikrovermischer |
| DE19541266A1 (de) * | 1995-11-06 | 1997-05-07 | Bayer Ag | Verfahren und Vorrichtung zur Durchführung chemischer Reaktionen mittels eines Mikrostruktur-Lamellenmischers |
| JPH10314566A (ja) * | 1997-05-19 | 1998-12-02 | Sumitomo Heavy Ind Ltd | マイクロスタティックミキサー |
| DE19917156B4 (de) * | 1999-04-16 | 2006-01-19 | INSTITUT FüR MIKROTECHNIK MAINZ GMBH | Verfahren zur Herstellung einer Wasser-in-Dieselöl-Emulsion als Kraftstoff sowie dessen Verwendungen |
| CN2376326Y (zh) * | 1999-05-24 | 2000-05-03 | 倪新宇 | 多孔波纹静态混合器 |
| US6485690B1 (en) * | 1999-05-27 | 2002-11-26 | Orchid Biosciences, Inc. | Multiple fluid sample processor and system |
| DE19927554C2 (de) | 1999-06-16 | 2002-12-19 | Inst Mikrotechnik Mainz Gmbh | Mikromischer |
| DE19928123A1 (de) | 1999-06-19 | 2000-12-28 | Karlsruhe Forschzent | Statischer Mikrovermischer |
| US7223364B1 (en) * | 1999-07-07 | 2007-05-29 | 3M Innovative Properties Company | Detection article having fluid control film |
| JP4284841B2 (ja) | 2000-08-07 | 2009-06-24 | 株式会社島津製作所 | 液体混合器 |
| DE10055858A1 (de) | 2000-11-10 | 2002-05-29 | Kundo Systemtechnik Gmbh | Vorrichtung zum Herstellen von mit Kohlendioxid versetztem Tafelwasser |
| DE10055856C2 (de) | 2000-11-10 | 2003-04-10 | Kundo Systemtechnik Gmbh | Vorrichtung zum Herstellen von mit Kohlendioxid versetztem Tafelwasser |
| JP3694877B2 (ja) | 2001-05-28 | 2005-09-14 | 株式会社山武 | マイクロ混合器 |
| JP3694876B2 (ja) | 2001-05-28 | 2005-09-14 | 株式会社山武 | マイクロ乳化器 |
| JP3727594B2 (ja) * | 2002-01-18 | 2005-12-14 | 富士写真フイルム株式会社 | マイクロミキサー |
| DE20209009U1 (de) | 2002-06-11 | 2002-08-29 | Ehrfeld Mikrotechnik AG, 55234 Wendelsheim | Kammförmiger Mikrovermischer |
| DE20218972U1 (de) | 2002-12-07 | 2003-02-13 | Ehrfeld Mikrotechnik AG, 55234 Wendelsheim | Statischer Laminationsmikrovermischer |
-
2002
- 2002-12-07 DE DE20218972U patent/DE20218972U1/de not_active Expired - Lifetime
-
2003
- 2003-12-03 WO PCT/EP2003/013603 patent/WO2004052518A2/fr not_active Ceased
- 2003-12-03 US US10/535,262 patent/US7909502B2/en active Active
- 2003-12-03 EP EP03780105.7A patent/EP1572335B1/fr not_active Expired - Lifetime
- 2003-12-03 KR KR1020057010057A patent/KR100806401B1/ko not_active Expired - Lifetime
- 2003-12-03 JP JP2004557974A patent/JP4847700B2/ja not_active Expired - Lifetime
- 2003-12-03 AU AU2003288216A patent/AU2003288216A1/en not_active Abandoned
- 2003-12-03 CN CNB2003801053256A patent/CN100360218C/zh not_active Expired - Lifetime
-
2011
- 2011-04-28 JP JP2011101777A patent/JP2011183386A/ja not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US422671A (en) * | 1890-03-04 | willis | ||
| US3881701A (en) * | 1973-09-17 | 1975-05-06 | Aerojet General Co | Fluid mixer reactor |
| US5534328A (en) * | 1993-12-02 | 1996-07-09 | E. I. Du Pont De Nemours And Company | Integrated chemical processing apparatus and processes for the preparation thereof |
| US5887977A (en) * | 1997-09-30 | 1999-03-30 | Uniflows Co., Ltd. | Stationary in-line mixer |
| DE10041823A1 (de) * | 2000-08-25 | 2002-03-14 | Inst Mikrotechnik Mainz Gmbh | Verfahren und statischer Mikrovermischer zum Mischen mindestens zweier Fluide |
Non-Patent Citations (3)
| Title |
|---|
| DE BELLEFON C ET AL: "Microreactors for dynamic high throughput screening of fluid-liquid molecular catalysis", ANGEWANDTE CHEMIE, WILEY - V C H VERLAG GMBH & CO. KGAA, DE, vol. 19, 1 January 2000 (2000-01-01), pages 3584 - 3587, XP003022882, ISSN: 0044-8249 * |
| EHRFELD W ET AL: "CHARACTERIZATION OF MIXING IN MICROMIXERS BY A TEST REACTION: SINGLE MIXING UNITS AND MIXER ARRAYS", INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, AMERICAN CHEMICAL SOCIETY, US, vol. 38, no. 3, 1 January 1999 (1999-01-01), pages 1075 - 1082, XP000940846, ISSN: 0888-5885, DOI: 10.1021/IE980128D * |
| HAVERKAMP V ET AL: "The potential of micromixers for contacting of disperse liquid phases", FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, SPRINGER, BERLIN, DE, vol. 364, 1 January 1999 (1999-01-01), pages 617 - 624, XP002260622, ISSN: 0937-0633, DOI: 10.1007/S002160051397 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100360218C (zh) | 2008-01-09 |
| JP2011183386A (ja) | 2011-09-22 |
| KR100806401B1 (ko) | 2008-02-21 |
| KR20050085326A (ko) | 2005-08-29 |
| AU2003288216A8 (en) | 2004-06-30 |
| DE20218972U1 (de) | 2003-02-13 |
| CN1780681A (zh) | 2006-05-31 |
| US20060087917A1 (en) | 2006-04-27 |
| JP4847700B2 (ja) | 2011-12-28 |
| JP2006508795A (ja) | 2006-03-16 |
| AU2003288216A1 (en) | 2004-06-30 |
| US7909502B2 (en) | 2011-03-22 |
| WO2004052518A2 (fr) | 2004-06-24 |
| WO2004052518A3 (fr) | 2005-06-09 |
| EP1572335A2 (fr) | 2005-09-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP1572335B1 (fr) | Micromelangeur lamellaire statique | |
| DE3783880T2 (de) | Strukturierte kolonnenpackung. | |
| DE69829697T2 (de) | Wärmetauscher und/oder Vorrichtung zur Mischung von Fluiden | |
| DE69400127T2 (de) | Wärmeaustauscher für elektronische Bauteile und elektrische Apparate | |
| EP2167270B1 (fr) | Distributeur de gaz a plusieurs rondelles soudées par diffusion et procédé de fabrication d'un tel distributeur de gaz | |
| EP1506054B1 (fr) | Microreacteur et micro-echangeur thermique | |
| EP2045556B1 (fr) | Echangeur thermique à plaques | |
| EP1866066B1 (fr) | Système melangeur, reacteur et systéme reacteur | |
| DE112018004787T5 (de) | Multi-fluid wärmetauscher | |
| EP1185359B1 (fr) | Micromelangeur | |
| EP0879083A1 (fr) | Dispositif de melange de petites quantites de liquides | |
| DE102010030781A1 (de) | Wärmeübertragerplatte, damit versehener Plattenwärmeübertrager und Verfahren zum Herstellen eines Plattenwärmeübertragers | |
| DE10123092A1 (de) | Verfahren und statischer Mischer zum Mischen mindestens zweier Fluide | |
| EP1475596B1 (fr) | Echangeur de chaleur à plaques avec plaques à parois simples et doubles | |
| DE2803810A1 (de) | Stroemungskanal fuer die verteilung eines reaktionsmittels in einem reaktionsgefaess | |
| EP1856734A1 (fr) | Micro-echangeur de chaleur | |
| DE69625531T2 (de) | Platten - Stoff- und Wärmetauscher | |
| DE10034343A1 (de) | Plattenwärmetauscher | |
| DE102005010341A1 (de) | Wärmetauscherplatte und Plattenpaket | |
| DE2753189A1 (de) | Oberflaechenausbildung in einer vorrichtung zum fuehren von fluiden | |
| EP1689013B1 (fr) | Pile à combustible | |
| WO2006034666A1 (fr) | Recuperateur a microcanaux produit a partir de feuilles empilees | |
| DE20219871U1 (de) | Rautenmischer | |
| DE69910729T2 (de) | Plattenwärmetauscher mit keilförmiger dichtung | |
| DE1451246B2 (de) | Wärmetauscher mit mehreren Plattenelementen |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PT RO SE SI SK TR |
|
| AX | Request for extension of the european patent |
Extension state: AL LT LV MK |
|
| 17P | Request for examination filed |
Effective date: 20051209 |
|
| RBV | Designated contracting states (corrected) |
Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PT RO SE SI SK TR |
|
| DAX | Request for extension of the european patent (deleted) | ||
| RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: MERKEL, TILL Inventor name: EHRFELD, WOLFGANG Inventor name: KROSCHEL, MATTHIAS Inventor name: HERBSTRITT, FRANK |
|
| TPAC | Observations filed by third parties |
Free format text: ORIGINAL CODE: EPIDOSNTIPA |
|
| 17Q | First examination report despatched |
Effective date: 20090817 |
|
| GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
| GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
| GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
| AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PT RO SE SI SK TR |
|
| REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
| RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: HERBSTRITT, FRANK Inventor name: KROSCHEL, MATTHIAS Inventor name: EHRFELD, WOLFGANG Inventor name: MERKEL, TILL |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
| REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 614005 Country of ref document: AT Kind code of ref document: T Effective date: 20130615 |
|
| REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: GERMAN |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 50314806 Country of ref document: DE Effective date: 20130725 |
|
| REG | Reference to a national code |
Ref country code: NL Ref legal event code: T3 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130930 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130830 Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130529 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130909 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130529 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130529 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130829 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130529 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130529 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130529 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130529 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130529 |
|
| PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
| 26N | No opposition filed |
Effective date: 20140303 |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 50314806 Country of ref document: DE Effective date: 20140303 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20131203 Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130529 |
|
| REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20131203 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130529 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130529 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20031203 |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 13 |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 14 |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 15 |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R079 Ref document number: 50314806 Country of ref document: DE Free format text: PREVIOUS MAIN CLASS: B01F0013000000 Ipc: B01F0033000000 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20221221 Year of fee payment: 20 Ref country code: GB Payment date: 20221219 Year of fee payment: 20 Ref country code: FR Payment date: 20221216 Year of fee payment: 20 Ref country code: DE Payment date: 20221216 Year of fee payment: 20 Ref country code: AT Payment date: 20221219 Year of fee payment: 20 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 20221219 Year of fee payment: 20 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 20221220 Year of fee payment: 20 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: IT Payment date: 20221220 Year of fee payment: 20 |
|
| P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230517 |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R071 Ref document number: 50314806 Country of ref document: DE |
|
| REG | Reference to a national code |
Ref country code: NL Ref legal event code: MK Effective date: 20231202 |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
| REG | Reference to a national code |
Ref country code: GB Ref legal event code: PE20 Expiry date: 20231202 |
|
| REG | Reference to a national code |
Ref country code: BE Ref legal event code: MK Effective date: 20231203 |
|
| REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK07 Ref document number: 614005 Country of ref document: AT Kind code of ref document: T Effective date: 20231203 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION Effective date: 20231202 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION Effective date: 20231202 |