EP1279399A1 - Foaming cosmetic composition for the bath - Google Patents
Foaming cosmetic composition for the bath Download PDFInfo
- Publication number
- EP1279399A1 EP1279399A1 EP02291543A EP02291543A EP1279399A1 EP 1279399 A1 EP1279399 A1 EP 1279399A1 EP 02291543 A EP02291543 A EP 02291543A EP 02291543 A EP02291543 A EP 02291543A EP 1279399 A1 EP1279399 A1 EP 1279399A1
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- EP
- European Patent Office
- Prior art keywords
- composition
- composition according
- total weight
- weight relative
- bath
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
- C11D1/655—Mixtures of sulfonated products with alkylolamides of carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
- C11D1/652—Mixtures of anionic compounds with carboxylic amides or alkylol amides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
Definitions
- the present invention relates to a foaming cosmetic composition for the bath comprising, in a cosmetically acceptable aqueous medium, at least: from 18 to 50% by weight of a lauryl ether sulfate of sodium, potassium, magnesium, ammonium, of triethanolamine or isopropanolamine or a mixture of these, and from 0.01 to 2% by weight of a viscosity agent chosen from (i) alkanolamides, (ii) alcohol-or-ethers of alcohols -or esters, polyoxyethylenated fats containing from 30 to 200 moles of ethylene oxide, provided that said composition is free of amphoteric or cationic surfactant.
- a viscosity agent chosen from (i) alkanolamides, (ii) alcohol-or-ethers of alcohols -or esters, polyoxyethylenated fats containing from 30 to 200 moles of ethylene oxide, provided that said composition is free of amphoteric or cationic surfactant.
- foam baths It is known to add cosmetic products intended to foam the bath to the water of a bath. Such products are generally called "bubble baths". To satisfy the consumer, the foam baths must make it possible to obtain a large volume of foam, and the foam must be able to last, while falling as little as possible, throughout the duration of the bath, that is to say most commonly for 20 minutes.
- the object of the present invention is to solve the problem mentioned above.
- the Applicant has now surprisingly discovered new compositions for a bubble bath which make it possible to obtain a large height of foam which is sufficiently durable throughout the duration of the bath.
- the foam produced by said composition is soft, creamy, easily rinsable, non-sticky and well tolerated by the skin.
- sodium, potassium, magnesium, ammonium, triethanolamine or isopropanolamine lauryl ether sulfate or mixtures thereof are preferably present in an amount ranging from 18 35% by weight relative to the total weight of the composition. According to the present invention, it is advantageously preferred to use sodium lauryl ether sulfate.
- the viscosity agent is preferably present in concentrations ranging from 0.1 to 1.5% by weight relative to the total weight of the composition.
- polyoxyethylenated fatty alcohols comprising from 30 to 200 moles of ethylene oxide
- oxyethylenated cetyl alcohol such as the product sold under the name NIKKOL BC-30TX t® by the company Nikkol
- oxyethylenated oleyl alcohol 50 EO
- oxyethylenated behenyl alcohol 30 EO
- NIKKOL BB-30® by the company Nikkol
- oxyethylenated stearyl alcohol 100 EO
- ethers of polyoxyethylenated fatty alcohols comprising from 30 to 200 moles of ethylene oxide
- R denotes a radical C 10 -C 30 alkyl
- R ′ denotes a C 10 -C 30 alkyl radical substituted by a hydroxyl radical
- n is an integer ranging from 30 to approximately 100.
- a compound of this type more particularly preferred is sold under the name ELFACOS GT 282 S® by the company AKZO; it is a compound of formula R- (OCH 2 CH 2 ) n -OR 'where R denotes a C 16 -C 18 alkyl radical, R' denotes the C 14 OH alkyl radical, and n is equal to 60, plus commonly known as the CTFA Dictionary under the name CETEARETH 60 MYRISTYL GLYCOL or HYDROGENATED TALLOWETH 60 MYRISTYL GLYCOL.
- polyoxyethylenated fatty esters comprising from 30 to 200 moles of ethylene oxide
- PEG-150 dibehenate designation CTFA
- ETHOX PEG 6000 Dibehenate® by the company Ethox
- polyethylene glycol palmito-stearate 120 EO
- STEARATE 6000 WL 1644® by the company Gattefosse
- polyethylene glycol stearate 40 EO
- MYRJ 52® society Uniqema.
- polyethylene glycol 150 OE distearate (designation CTFA: PEG-150 distearate) sold for example by the company AKZO under the name KESSCO PEG 6000 DS®, by the company UNIQUEMA under the name ATLAS G-1821 V® , or by the company CP HALL COMPANY under the name EMULVIS®.
- COCAMIDE MIPA design CTFA
- COCAMIDE MEA the product marketed under the name EMPILAN CIS® by the company ALBRIGHT & WILSON, or under the name REWOMID V3202® by the company GOLDSCHMIDT
- CTFA names the mixture of MYRISTAMIDE MEA and LAURAMIDE MEA
- NINOL LMP® the product sold under the name NINOL LMP® by the company STEPAN.
- COCAMIDE MEA monoethanolamide of coconut fatty acids
- the cosmetically acceptable aqueous medium of the composition according to the invention generally consists of water or of a mixture of water and at least one organic solvent.
- organic solvent polyols such as propylene glycol, glycerin, hexylene glycol, isoprene glycol, neopentyl glycol, polyethylene glycols or polyol ethers can be used. It is more particularly preferred to use a mixture of glycerin and hexylene glycol.
- the solvents may be present in proportions preferably of between 0 and 20% by weight approximately relative to the total weight of the composition, and even more preferably between 1 and 5% by weight approximately.
- composition in accordance with the invention preferably also comprises at least one adjuvant chosen from opacifying agents, thickening agents, skin conditioning agents such as vegetable or mineral oils, or waxes and ceramides, or polymers cationic or amphoteric, or silicones, humectants such as sorbitol, preservatives, pH agents, sequestering agents, dyes, perfumes and perfume peptizers.
- adjuvant chosen from opacifying agents, thickening agents, skin conditioning agents such as vegetable or mineral oils, or waxes and ceramides, or polymers cationic or amphoteric, or silicones, humectants such as sorbitol, preservatives, pH agents, sequestering agents, dyes, perfumes and perfume peptizers.
- the pH of the composition according to the invention is generally adjusted to around 4.5 to 7.5 by means of acidifying or basifying agents well known in the art in cosmetics.
- basifying agents there may be mentioned, by way of example, ammonia, alkali carbonates, alkanolamines such as mono-, di- and triethanolamines as well as their derivatives, hydroxyalkylamines and ethylenediamines oxyethylenated and / or oxypropylenes, sodium or potassium hydroxides and the compounds of the following formula: in which R is a propylene residue optionally substituted by a hydroxyl group or a C 1 -C 4 alkyl radical; R 1, R 2, R 3 and R 4, identical or different, represent a hydrogen atom, an alkyl radical in C 1 -C 4 hydroxyalkyl or C 1 -C 4.
- the acidifying agents are conventionally, by way of example, organic or mineral acids, of which citric acid, tartaric acid or lactic acid are more particularly preferred.
- OPACIFIER 680® polyethylene glycol (7 EO) tridecyl alcohol ether
- thickening agents mention may in particular be made of nonionic cellulosic thickeners (hydroxyethylcellulose, hydroxypropylcellulose), crosslinked polyacrylic acids sold under the name CARBOPOL®, and anionic, nonionic, cationic or amphoteric associative thickening polymers comprising at least one fatty chain ; we can also cite the sodium chloride which is more particularly preferred to use in the proportion of 1 to 2% by weight relative to the total weight of the composition.
- nonionic cellulosic thickeners hydroxyethylcellulose, hydroxypropylcellulose
- CARBOPOL® crosslinked polyacrylic acids sold under the name CARBOPOL®
- anionic, nonionic, cationic or amphoteric associative thickening polymers comprising at least one fatty chain ; we can also cite the sodium chloride which is more particularly preferred to use in the proportion of 1 to 2% by weight relative to the total weight of the composition.
- Another object of the present invention relates to a cosmetic foaming composition for the bath, comprising in a cosmetically acceptable aqueous medium, at least: from 18 to 35% of a sodium lauryl ether sulfate, from 0.1 to 1, 5% monoethanolamide of coconut fatty acids, from 1 to 5% of a mixture of glycerin and hexylene glycol, from 1 to 2% of sodium chloride, the quantities being expressed by weight relative to the total weight of the composition, said composition being free of amphoteric or cationic surfactant.
- composition according to the invention is preferably in the form of thickened liquid packaged in a bottle.
- composition for bubble bath was prepared: (contents expressed in grams of active ingredient) Lauryl ether sodium sulfate 21 Cocamide MEA 1 Glycerin 1 Hexylene glycol 1 Sodium chloride 1.8 Opacifying agent (Opacifier 680 sold by ROHM & HAAS 0.7 Citric acid 0.7 Perfume, color, preservative q..s. Demineralized water qs 100 20 grams of the composition thus prepared were poured into a transparent bathtub, under the water tap (38 ° C, constant flow, controlled hardness) and the bathtub was filled to about 100 liters of water.
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
La présente demande concerne une composition cosmétique moussante destinée à être ajoutée au bain et comprenant dans un milieu aqueux cosmétiquement acceptable, au moins : (a) 18 à 50% en poids par rapport au poids total de la composition, d'un lauryl éther sulfate de sodium, de potassium, de magnésium, d'ammonium, de triéthanolamine ou d'isopropanolamine ou un mélange de ceux-ci ; (b) 0,01 à 2% en poids par rapport au poids total de la composition d'un agent de viscosité choisi parmi (i) les alcanolamides, (ii) les alcools-ou-éthers d'alcools-ou esters, gras polyoxyéthylénés comportant de 30 à 200 moles d'oxyde d'éthylène, sous réserve que ladite composition soit exempte d'agent tensioactif amphotère ou cationique.The present application relates to a foaming cosmetic composition intended to be added to the bath and comprising in a cosmetically acceptable aqueous medium, at least: (a) 18 to 50% by weight relative to the total weight of the composition, of a lauryl ether sulfate sodium, potassium, magnesium, ammonium, triethanolamine or isopropanolamine or a mixture thereof; (b) 0.01 to 2% by weight relative to the total weight of the composition of a viscosity agent chosen from (i) alkanolamides, (ii) fatty alcohols or ethers of alcohols or esters polyoxyethylenated comprising from 30 to 200 moles of ethylene oxide, provided that said composition is free of amphoteric or cationic surfactant.
Description
La présente invention a trait à une composition cosmétique moussante pour le bain comprenant dans un milieu aqueux cosmétiquement acceptable, au moins : de 18 à 50% en poids d'un lauryl éther sulfate de sodium, de potassium, de magnésium, d'ammonium, de triéthanolamine ou d'isopropanolamine ou un mélange de ceux-ci, et de 0,01 à 2% en poids d'un agent de viscosité choisi parmi (i) les alcanolamides, (ii) les alcools-ou-éthers d'alcools-ou esters, gras polyoxyéthylénés comportant de 30 à 200 moles d'oxyde d'éthylène, sous réserve que ladite composition soit exempte d'agent tensioactif amphotère ou cationique.The present invention relates to a foaming cosmetic composition for the bath comprising, in a cosmetically acceptable aqueous medium, at least: from 18 to 50% by weight of a lauryl ether sulfate of sodium, potassium, magnesium, ammonium, of triethanolamine or isopropanolamine or a mixture of these, and from 0.01 to 2% by weight of a viscosity agent chosen from (i) alkanolamides, (ii) alcohol-or-ethers of alcohols -or esters, polyoxyethylenated fats containing from 30 to 200 moles of ethylene oxide, provided that said composition is free of amphoteric or cationic surfactant.
Il est connu d'additionner à l'eau d'un bain, des produits cosmétiques destinés à faire mousser le bain. De tels produits sont généralement appelés "bains moussants".
Pour satisfaire le consommateur, les bains moussants doivent permettre d'obtenir un volume de mousse important, et la mousse doit pouvoir durer, tout en chutant le moins possible, pendant toute la durée du bain, c'est à dire le plus couramment pendant 20 minutes.It is known to add cosmetic products intended to foam the bath to the water of a bath. Such products are generally called "bubble baths".
To satisfy the consumer, the foam baths must make it possible to obtain a large volume of foam, and the foam must be able to last, while falling as little as possible, throughout the duration of the bath, that is to say most commonly for 20 minutes.
Or la plupart des bains moussants jusqu'ici connus offrent un volume de mousse satisfaisant au début du bain mais ne permettent généralement pas de maintenir un volume de mousse satisfaisant après environ 20 minutes de bain. La hauteur de la mousse dans le bain diminue trop rapidement et la mousse finit par disparaître vers la fin du bain.However, most of the previously known foam baths offer a satisfactory volume of foam at the start of the bath, but generally do not make it possible to maintain a satisfactory volume of foam after approximately 20 minutes of bath. The height of the foam in the bath decreases too quickly and the foam eventually disappears towards the end of the bath.
Les bains moussants les plus couramment utilisés jusqu'ici renferment des associations de tensioactifs anioniques et notamment de lauryl éther sulfate avec des tensioactifs amphotères ou cationiques. Ce type de bain moussant ne résout pas de façon tout à fait satisfaisante le problème de la durabilité de la mousse au cours du bain.The most commonly used foam baths up to now contain combinations of anionic surfactants and in particular lauryl ether sulfate with amphoteric or cationic surfactants. This type of bubble bath does not completely resolve the problem of the durability of the foam during the bath.
La présente invention a pour but de résoudre le problème évoqué ci-dessus.The object of the present invention is to solve the problem mentioned above.
La Demanderesse a maintenant découvert de façon surprenante de nouvelles compositions pour bain moussant permettant d'obtenir une hauteur de mousse importante et suffisamment durable pendant toute la durée du bain. En outre, la mousse produite par ladite composition est douce, onctueuse, aisément rinçable, non collante et bien tolérée par la peau.The Applicant has now surprisingly discovered new compositions for a bubble bath which make it possible to obtain a large height of foam which is sufficiently durable throughout the duration of the bath. In addition, the foam produced by said composition is soft, creamy, easily rinsable, non-sticky and well tolerated by the skin.
Cette découverte est à la base de la présente invention.This discovery is the basis of the present invention.
La présente invention a donc pour objet une composition cosmétique moussante pour le bain comprenant dans un milieu aqueux cosmétiquement acceptable, au moins :
- (a) 18 à 50% en poids par rapport au poids total de la composition, d'un lauryl éther sulfate de sodium, de potassium, de magnésium, d'ammonium, de triéthanolamine ou de d'isopropanolamine ou un mélange de ceux-ci ;
- (b) 0,01 à 2% en poids par rapport au poids total de la composition d'un agent de viscosité choisi parmi (i) les alcanolamides, (ii) les alcools-ou-éthers d'alcools-ou esters, gras polyoxyéthylénés comportant de 30 à 200 moles d'oxyde d'éthylène,
- (a) 18 to 50% by weight relative to the total weight of the composition, of a lauryl ether sulfate of sodium, potassium, magnesium, ammonium, triethanolamine or isopropanolamine or a mixture of these this ;
- (b) 0.01 to 2% by weight relative to the total weight of the composition of a viscosity agent chosen from (i) alkanolamides, (ii) fatty alcohols or ethers of alcohols or esters polyoxyethylenated comprising from 30 to 200 moles of ethylene oxide,
Dans la composition conforme à l'invention, le lauryl éther sulfate de sodium, de potassium, de magnésium, d'ammonium, de triéthanolamine ou de d'isopropanolamine ou les mélanges de ceux-ci sont de préférence présents en une quantité allant de 18 à 35% en poids par rapport au poids total de la composition.
Selon la présente invention, on préfère avantageusement utiliser le lauryl éther sulfate de sodium.In the composition according to the invention, sodium, potassium, magnesium, ammonium, triethanolamine or isopropanolamine lauryl ether sulfate or mixtures thereof are preferably present in an amount ranging from 18 35% by weight relative to the total weight of the composition.
According to the present invention, it is advantageously preferred to use sodium lauryl ether sulfate.
Dans la composition conforme à l'invention, l'agent de viscosité est de préférence présent dans des concentrations allant de 0,1 à 1,5% en poids par rapport au poids total de la composition.In the composition according to the invention, the viscosity agent is preferably present in concentrations ranging from 0.1 to 1.5% by weight relative to the total weight of the composition.
Parmi les alcools gras polyoxyéthylénés comportant de 30 à 200 moles d'oxyde d'éthylène, on peut notamment citer : l'alcool cétylique oxyéthyléné (30 OE) tel que le produit commercialisé sous la dénomination NIKKOL BC-30TX t® par la société Nikkol, l'alcool oléylique oxyéthyléné (50 OE) tel que le produit commercialisé sous la dénomination NIKKOL BO-50® par la société Nikkol, l'alcool béhénylique oxyéthyléné (30 OE) tel que le produit commercialisé sous la dénomination NIKKOL BB-30® par la société Nikkol, l'alcool stéarylique oxyéthyléné (100 OE) tel que le produit commercialisé sous la dénomination BRIJ 700® par la société Uniquema.Among the polyoxyethylenated fatty alcohols comprising from 30 to 200 moles of ethylene oxide, there may be mentioned in particular: oxyethylenated cetyl alcohol (30 EO) such as the product sold under the name NIKKOL BC-30TX t® by the company Nikkol , oxyethylenated oleyl alcohol (50 EO) such as the product sold under the name NIKKOL BO-50® by the company Nikkol, oxyethylenated behenyl alcohol (30 EO) such as the product sold under the name NIKKOL BB-30® by the company Nikkol, oxyethylenated stearyl alcohol (100 EO) such as the product sold under the name BRIJ 700® by the company Uniquema.
Parmi les éthers d'alcools gras polyoxyéthylénés comportant de 30 à 200 moles d'oxyde d'éthylène, on préfère utiliser notamment les composés de formule générale R-(OCH2CH2)n―OR', pour laquelle, R désigne un radical alkyle en C10-C30, R' désigne un radical alkyle en C10-C30 substitué par un radical hydroxyle, et n est un nombre entier allant de 30 à environ 100. Un composé de ce type plus particulièrement préféré est vendu sous la dénomination ELFACOS GT 282 S® par la société AKZO; c'est un composé de formule R-(OCH2CH2)n-OR' où R désigne un radical alkyle en C16-C18 , R' désigne le radical alkyle C14OH, et n est égal à 60, plus couramment connu sous la dénomination du Dictionnaire C.T.F.A. sous l'appellation CETEARETH 60 MYRISTYL GLYCOL ou encore HYDROGENATED TALLOWETH 60 MYRISTYL GLYCOL.Among the ethers of polyoxyethylenated fatty alcohols comprising from 30 to 200 moles of ethylene oxide, it is preferable to use in particular the compounds of general formula R- (OCH 2 CH 2 ) n ―OR ', for which, R denotes a radical C 10 -C 30 alkyl, R ′ denotes a C 10 -C 30 alkyl radical substituted by a hydroxyl radical, and n is an integer ranging from 30 to approximately 100. A compound of this type more particularly preferred is sold under the name ELFACOS GT 282 S® by the company AKZO; it is a compound of formula R- (OCH 2 CH 2 ) n -OR 'where R denotes a C 16 -C 18 alkyl radical, R' denotes the C 14 OH alkyl radical, and n is equal to 60, plus commonly known as the CTFA Dictionary under the name CETEARETH 60 MYRISTYL GLYCOL or HYDROGENATED TALLOWETH 60 MYRISTYL GLYCOL.
Parmi les esters gras polyoxyéthylénés comportant de 30 à 200 moles d'oxyde d'éthylène, on peut notamment citer le PEG-150 dibehenate (appellation CTFA) tel que le produit commercialisé sous la dénomination ETHOX PEG 6000 Dibehenate® par la société Ethox, le palmito-stéarate de polyéthylène glycol (120 OE) tel que le produit commercialisé sous la dénomination STEARATE 6000 WL 1644® par la société Gattefosse, le stéarate de polyéthylène glycol (40 OE) tel que le produit commercialisé sous la dénomination MYRJ 52® par la société Uniquema. On préfère plus particulièrement utiliser le distéarate de polyéthylène glycol 150 OE ( appellation CTFA : PEG-150 distearate) vendu par exemple par la société AKZO sous la dénomination KESSCO PEG 6000 DS®, par la société UNIQUEMA sous la dénomination ATLAS G-1821 V®, ou par la société CP HALL COMPANY sous la dénomination EMULVIS®.Among the polyoxyethylenated fatty esters comprising from 30 to 200 moles of ethylene oxide, mention may in particular be made of PEG-150 dibehenate (designation CTFA) such as the product sold under the name ETHOX PEG 6000 Dibehenate® by the company Ethox, polyethylene glycol palmito-stearate (120 EO) such as the product marketed under the name STEARATE 6000 WL 1644® by the company Gattefosse, polyethylene glycol stearate (40 EO) such as the product marketed under the name MYRJ 52® by society Uniqema. It is more particularly preferred to use polyethylene glycol 150 OE distearate (designation CTFA: PEG-150 distearate) sold for example by the company AKZO under the name KESSCO PEG 6000 DS®, by the company UNIQUEMA under the name ATLAS G-1821 V® , or by the company CP HALL COMPANY under the name EMULVIS®.
Parmi les alcanolamides, on peut citer notamment le COCAMIDE MIPA (appellation CTFA) tel que le produit commercialisé sous la dénomination EMPILAN CIS® par la société ALBRIGHT & WILSON, ou sous la dénomination REWOMID V3202® par la société GOLDSCHMIDT, le mélange de MYRISTAMIDE MEA et de LAURAMIDE MEA (appellations CTFA) tel que le produit commercialisé sous la dénomination NINOL LMP® par la société STEPAN. On préfère plus particulièrement utiliser la monoéthanolamide d'acides gras de coprah (appellation CTFA : COCAMIDE MEA) vendu par exemple par la société COGNIS sous la dénomination COMPERLAN 100®.Among the alkanolamides, there may be mentioned in particular COCAMIDE MIPA (designation CTFA) such as the product marketed under the name EMPILAN CIS® by the company ALBRIGHT & WILSON, or under the name REWOMID V3202® by the company GOLDSCHMIDT, the mixture of MYRISTAMIDE MEA and LAURAMIDE MEA (CTFA names) such as the product sold under the name NINOL LMP® by the company STEPAN. It is more particularly preferred to use the monoethanolamide of coconut fatty acids (designation CTFA: COCAMIDE MEA) sold for example by the company COGNIS under the name COMPERLAN 100®.
Le milieu aqueux cosmétiquement acceptable de la composition conforme à l'invention est généralement constitué par de l'eau ou par un mélange d'eau et d'au moins un solvant organique. A titre de solvant organique, on peut utiliser les polyols comme le propylène glycol, la glycérine, l'hexylène glycol, l'isoprène glycol, le néopentyl glycol, les polyéthylène glycols ou les éthers de polyols. On préfère plus particulièrement utiliser un mélange de glycérine, et d'hexylène glycol.
Les solvants peuvent être présents dans des proportions de préférence comprises entre 0 et 20 % en poids environ par rapport au poids total de la composition, et encore plus préférentiellement entre 1 et 5 % en poids environ.The cosmetically acceptable aqueous medium of the composition according to the invention generally consists of water or of a mixture of water and at least one organic solvent. As organic solvent, polyols such as propylene glycol, glycerin, hexylene glycol, isoprene glycol, neopentyl glycol, polyethylene glycols or polyol ethers can be used. It is more particularly preferred to use a mixture of glycerin and hexylene glycol.
The solvents may be present in proportions preferably of between 0 and 20% by weight approximately relative to the total weight of the composition, and even more preferably between 1 and 5% by weight approximately.
La composition conforme à l'invention comprend de préférence en outre au moins un adjuvant choisi parmi les agents opacifiants, les agents épaississsants, les agents conditionneurs de la peau tels que les huiles végétales ou minérales, ou les cires et les céramides, ou les polymères cationiques ou amphotères, ou les silicones, les humectants tel que le sorbitol, les agents conservateurs, les agents de pH, les agents séquestrants, les colorants, les parfums et les peptisants de parfums.The composition in accordance with the invention preferably also comprises at least one adjuvant chosen from opacifying agents, thickening agents, skin conditioning agents such as vegetable or mineral oils, or waxes and ceramides, or polymers cationic or amphoteric, or silicones, humectants such as sorbitol, preservatives, pH agents, sequestering agents, dyes, perfumes and perfume peptizers.
Le pH de la composition conforme à l'invention est généralement ajusté aux environs de 4,5 à 7,5 au moyen d'agents acidifiants ou alcalinisants bien connus de la technique en cosmétique.
Parmi les agents alcalinisants on peut citer, à titre d'exemple, l'ammoniaque, les carbonates alcalins, les alcanolamines telles que les mono-, di- et triéthanolamines ainsi que leurs dérivés, les hydroxyalkylamines et les ethylènediamines oxyéthylénées et/ou oxypropylénées, les hydroxydes de sodium ou de potassium et les composés de formule suivante :
Les agents acidifiants sont classiquement, à titre d'exemple, des acides organiques ou minéraux dont on préfère plus particulièrement l'acide citrique, l'acide tartrique, ou l'acide lactique.The pH of the composition according to the invention is generally adjusted to around 4.5 to 7.5 by means of acidifying or basifying agents well known in the art in cosmetics.
Among the basifying agents, there may be mentioned, by way of example, ammonia, alkali carbonates, alkanolamines such as mono-, di- and triethanolamines as well as their derivatives, hydroxyalkylamines and ethylenediamines oxyethylenated and / or oxypropylenes, sodium or potassium hydroxides and the compounds of the following formula:
The acidifying agents are conventionally, by way of example, organic or mineral acids, of which citric acid, tartaric acid or lactic acid are more particularly preferred.
Parmi les agents opacifiants utilisables dans la composition conforme à l'invention, on peut citer par exemple les alcools gras à chaîne longue, les esters gras de polyol et les diéthers gras comme par exemple le distéaryl éther, bien connus de l'homme de l'art. On préfère notamment utiliser selon l'invention, le mélange aqueux de copolymère styrène/acrylate de sodium, lauryl sulfate de sodium, sorbate de potassium, polyéthylène glycol (7 OE) éther d'alcool tridécylique (appellation CTFA Trideceth-7) vendu sous la dénomination OPACIFIER 680® par la société ROHM & HAAS.Among the opacifying agents which can be used in the composition in accordance with the invention, mention may be made, for example, of long-chain fatty alcohols, fatty polyol esters and fatty diethers such as, for example, distearyl ether, well known to those skilled in the art. 'art. It is particularly preferred to use according to the invention, the aqueous mixture of styrene / sodium acrylate copolymer, sodium lauryl sulfate, potassium sorbate, polyethylene glycol (7 EO) tridecyl alcohol ether (designation CTFA Trideceth-7) sold under the name OPACIFIER 680® by the company ROHM & HAAS.
Parmi les agents épaississants, on peut citer notamment les épaississants cellulosiques non ioniques (hydroxyéthycellulose, hydroxypropylcellulose), les acides polyacryliques réticulés vendus sous la dénomination CARBOPOL®, et les polymères épaississants associatifs anioniques, non ioniques, cationiques ou amphotères comportant au moins une chaîne grasse; on peut également citer le chlorure de sodium que l'on préfère plus particulièrement utiliser dans la proportion de 1 à 2% en poids par rapport au poids total de la composition.Among the thickening agents, mention may in particular be made of nonionic cellulosic thickeners (hydroxyethylcellulose, hydroxypropylcellulose), crosslinked polyacrylic acids sold under the name CARBOPOL®, and anionic, nonionic, cationic or amphoteric associative thickening polymers comprising at least one fatty chain ; we can also cite the sodium chloride which is more particularly preferred to use in the proportion of 1 to 2% by weight relative to the total weight of the composition.
Bien entendu, l'homme de l'art veillera à choisir ce ou ces éventuels composés complémentaires de manière telle que les propriétés avantageuses attachées intrinsèquement à la composition conforme à l'invention ne soient pas, ou substantiellement pas, altérées par la ou les adjonctions envisagées.Of course, those skilled in the art will take care to choose this or these optional additional compounds in such a way that the advantageous properties intrinsically attached to the composition according to the invention are not, or not substantially, altered by the addition (s) considered.
Un autre objet de la présente invention a trait à une composition cosmétique moussante pour le bain, comprenant dans un milieu aqueux cosmétiquement acceptable, au moins : de 18 à 35% d'un lauryl éther sulfate de sodium, de 0,1 à 1,5% de monoéthanolamide d'acides gras de coprah, de 1 à 5% d'un mélange de glycérine et d'hexylène glycol, de 1 à 2% de chlorure de sodium, les quantités étant exprimées en poids par rapport au poids total de la composition, ladite composition étant exempte d'agent tensioactif amphotère ou cationique.Another object of the present invention relates to a cosmetic foaming composition for the bath, comprising in a cosmetically acceptable aqueous medium, at least: from 18 to 35% of a sodium lauryl ether sulfate, from 0.1 to 1, 5% monoethanolamide of coconut fatty acids, from 1 to 5% of a mixture of glycerin and hexylene glycol, from 1 to 2% of sodium chloride, the quantities being expressed by weight relative to the total weight of the composition, said composition being free of amphoteric or cationic surfactant.
La composition conforme à l'invention se présente de préférence sous la forme de liquide épaissi conditionné en flacon.The composition according to the invention is preferably in the form of thickened liquid packaged in a bottle.
L'exemple suivant illustre l'invention sans présenter un caractère limitatif.The following example illustrates the invention without being limiting in nature.
On a préparé la composition pour bain moussant suivante :
Avec le bain moussant ainsi réalisé, on a pu constaté une hauteur de mousse importante de l'ordre de 18 cm au temps zéro et ne chutant que d'environ 20% de sa valeur après 20 minutes, alors que les compositions pour bain moussant de l'art antérieur engendrent généralement une mousse dont la hauteur chute au bout du même temps, d'environ 40% de sa valeur.With the foam bath thus produced, it was possible to observe a significant height of foam of the order of 18 cm at time zero and falling only about 20% of its value after 20 minutes, while the compositions for foam bath the prior art generally generate a foam whose height drops after the same time, of about 40% of its value.
Claims (13)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0110115A FR2827768B1 (en) | 2001-07-27 | 2001-07-27 | FOAMING COSMETIC COMPOSITION FOR BATH |
| FR0110115 | 2001-07-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1279399A1 true EP1279399A1 (en) | 2003-01-29 |
Family
ID=8866022
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP02291543A Withdrawn EP1279399A1 (en) | 2001-07-27 | 2002-06-20 | Foaming cosmetic composition for the bath |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20030083211A1 (en) |
| EP (1) | EP1279399A1 (en) |
| JP (1) | JP2003055192A (en) |
| FR (1) | FR2827768B1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111909803A (en) * | 2020-09-17 | 2020-11-10 | 广州市白云区大荣精细化工有限公司 | Clothes fragrance-retaining composition and preparation method thereof |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4337585B2 (en) * | 2004-03-10 | 2009-09-30 | 新日本理化株式会社 | Thickener composition and method for producing the same, and thickening method using the thickener composition |
| KR101081303B1 (en) * | 2009-02-17 | 2011-11-08 | 한국콜마 주식회사 | Cosmetic Composition Of Oil Type Cleanser and Manufacturing Method Thereof |
| US9783325B1 (en) | 2010-08-07 | 2017-10-10 | Christy Booth Hierholzer | Bath water enhancing packet and method of use |
| US9790454B2 (en) * | 2016-03-02 | 2017-10-17 | The Procter & Gamble Company | Compositions containing alkyl sulfates and/or alkoxylated alkyl sulfates and a solvent comprising a diol |
| US9840684B2 (en) * | 2016-03-02 | 2017-12-12 | The Procter & Gamble Company | Compositions containing alkyl sulfates and/or alkoxylated alkyl sulfates and a solvent comprising a diol |
| JP6696404B2 (en) * | 2016-10-27 | 2020-05-20 | 日油株式会社 | Bubble bath composition |
| WO2018095532A1 (en) * | 2016-11-25 | 2018-05-31 | Lvmh Recherche | Aqueous cosmetic |
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- 2002-06-20 EP EP02291543A patent/EP1279399A1/en not_active Withdrawn
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111909803A (en) * | 2020-09-17 | 2020-11-10 | 广州市白云区大荣精细化工有限公司 | Clothes fragrance-retaining composition and preparation method thereof |
| CN111909803B (en) * | 2020-09-17 | 2021-11-30 | 广州市白云区大荣精细化工有限公司 | Clothes fragrance-retaining composition and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2827768A1 (en) | 2003-01-31 |
| FR2827768B1 (en) | 2005-08-26 |
| US20030083211A1 (en) | 2003-05-01 |
| JP2003055192A (en) | 2003-02-26 |
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