DE3528843A1 - SELF-DECONTAMINATING DETERGENTS - Google Patents
SELF-DECONTAMINATING DETERGENTSInfo
- Publication number
- DE3528843A1 DE3528843A1 DE19853528843 DE3528843A DE3528843A1 DE 3528843 A1 DE3528843 A1 DE 3528843A1 DE 19853528843 DE19853528843 DE 19853528843 DE 3528843 A DE3528843 A DE 3528843A DE 3528843 A1 DE3528843 A1 DE 3528843A1
- Authority
- DE
- Germany
- Prior art keywords
- weight
- percent
- detergent
- fatty acid
- hydrogen peroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003599 detergent Substances 0.000 title claims description 22
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000000194 fatty acid Substances 0.000 claims abstract description 27
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 26
- 229930195729 fatty acid Natural products 0.000 claims abstract description 26
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 24
- 239000012141 concentrate Substances 0.000 claims abstract description 21
- 150000003863 ammonium salts Chemical class 0.000 claims abstract description 9
- 239000004094 surface-active agent Substances 0.000 claims abstract description 9
- 150000001447 alkali salts Chemical class 0.000 claims abstract description 7
- 239000000654 additive Substances 0.000 claims abstract description 4
- 239000006210 lotion Substances 0.000 claims description 15
- 239000003755 preservative agent Substances 0.000 claims description 13
- 239000000645 desinfectant Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000003513 alkali Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000012459 cleaning agent Substances 0.000 claims description 5
- 239000003205 fragrance Substances 0.000 claims description 4
- 239000002562 thickening agent Substances 0.000 claims description 4
- 239000000975 dye Substances 0.000 claims description 3
- 230000003020 moisturizing effect Effects 0.000 claims 1
- 230000009972 noncorrosive effect Effects 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- 230000000996 additive effect Effects 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- -1 salts Acids Chemical class 0.000 description 6
- 235000013162 Cocos nucifera Nutrition 0.000 description 5
- 244000060011 Cocos nucifera Species 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- 235000002639 sodium chloride Nutrition 0.000 description 5
- 238000005406 washing Methods 0.000 description 4
- LPMBTLLQQJBUOO-KTKRTIGZSA-N (z)-n,n-bis(2-hydroxyethyl)octadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(CCO)CCO LPMBTLLQQJBUOO-KTKRTIGZSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- 206010061217 Infestation Diseases 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 244000052616 bacterial pathogen Species 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 230000003641 microbiacidal effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- KCLRQIRQHGDVMV-UHFFFAOYSA-N 2-bromo-5-nitro-1,3-dioxane Chemical compound [O-][N+](=O)C1COC(Br)OC1 KCLRQIRQHGDVMV-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- GHXZTYHSJHQHIJ-UHFFFAOYSA-N Chlorhexidine Chemical compound C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 GHXZTYHSJHQHIJ-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000004164 Wax ester Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 229960003260 chlorhexidine Drugs 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002169 ethanolamines Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 244000000010 microbial pathogen Species 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000001508 potassium citrate Substances 0.000 description 1
- 229960002635 potassium citrate Drugs 0.000 description 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
- 235000011082 potassium citrates Nutrition 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- 235000019386 wax ester Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Cosmetics (AREA)
Abstract
Description
Wassermischbare Konzentrate mit einem hohen Gehalt an Tensiden zum Beispiel vom Typ der Handwaschlotionen stellen für Mikroorganismen ideale Nährböden dar, so daß diese Produkte vor dem Befall und der Zersetzung durch Mikroorganismen - insbesondere Bakterien, Pilze und Sporenbildner - geschützt werden müssen. Der unerwünschte Eintrag solcher Mikroorganismen kann beispielsweise bei der Herstellung oder bei der Verwendung des Produktes auftreten. Es ist übliche Praxis, Reinigungsmittel beziehungsweise entsprechende Konzentrate der geschilderten Art durch Konservierungsstoffe zu schützen, wobei eine durch die Kosmetikverordnung begrenzte Anzahl von Konservierungsstoffen zur Verfügung steht.Water-miscible concentrates with a high surfactant content for example of the type of hand washing lotions for microorganisms ideal breeding grounds, so that these products before Infestation and decomposition by microorganisms - in particular Bacteria, fungi and spore formers - must be protected. The undesired entry of such microorganisms can, for example in the manufacture or use of the product occur. It is common practice to use detergents respectively corresponding concentrates of the type described by preservatives to protect, one through the Cosmetics Regulation limited number of preservatives available stands.
Handwaschlotionen unterliegen nicht dem Arzneimittelgesetz. An sie müssen aber beim Einsatz insbesondere im Medizinalbereich, also im Krankenhaus, in der Arztpraxis oder allgemein bei der Krankenpflege besondere Anforderungen gestellt werden. Bei den hier geschilderten Anwendungsfällen besteht die erhöhte Gefahr einer Kontamination der wassermischbaren Lotionen mit pathogenen Mikroorganismen und Sporenbildnern. Die entsprechenden Reinigungsmittel sollten dementsprechend die Fähigkeit besitzen, eventuell auftretende Verkeimungen selbsttätig zu eliminieren. Das ist mit den gebräuchlichen Konservierungsmitteln, die in den zugelassenen Einsatzkonzentrationen nur mikrobistatische, jedoch keine mikrobizide Wirkung zeigen, nicht möglich.Hand wash lotions are not subject to the Medicines Act. At however, when used in particular in the medical field, So in the hospital, in the doctor's office or in general at the Nursing special requirements are made. Both The use cases described here are at increased risk contamination of the water-miscible lotions with pathogenic Microorganisms and spore formers. The appropriate cleaning agents should accordingly have the ability to eliminate any germs that may occur. The comes with the common preservatives found in the approved use concentrations only microbistatic, however show no microbicidal effect, not possible.
Zur Entwicklung autosteriler Reinigungsmittel beispielsweise von der Art der Handwaschlotionen für den Medizinalbereich muß dementsprechend nach Möglichkeiten gesucht werden, durch Zusatz geringer Mengen an toxikologisch - insbesondere dermatologisch - unbedenklicher Substanzen neben der bereits durch den Zusatz von Konservierungsstoffen erreichten Haltbarmachung eine mikrobizide Wirkung zu erreichen.For the development of autosterile cleaning agents, for example from the type of hand washing lotions for the medical field must accordingly, opportunities are sought through Adding small amounts of toxicologically - in particular dermatological - harmless substances in addition to the already achieved by adding preservatives Preservation to achieve a microbicidal effect.
Es ist bekannt, daß man durch Zugabe geringer Mengen von Wasserstoffperoxid zu wässrigen Desinfektionsmitteln selbstdekontaminierende Hautdesinfektionsmittel gewinnen kann. So schildert die DE-OS 29 04 217 Desinfektionsmittel auf Basis von wässrigen Alkohollösungen, die zusätzlich geringe Mengen von Wasserstoffperoxid enthalten. Desinfektionsmittel dieser Art sind in der Lage, unfreiwillig eingebrachte Sporen abzutöten und damit das Desinfektionsmittel im Gebrauch keimfrei zu halten.It is known that by adding small amounts of Hydrogen peroxide to self-decontaminating aqueous disinfectants Skin disinfectant can win. So describes the DE-OS 29 04 217 disinfectants based on aqueous alcohol solutions that additionally contain small amounts of Contain hydrogen peroxide. Disinfectants of this type are able to involuntarily introduce spores and thus keep the disinfectant sterile during use.
Gemäß der heutigen Praxis ist es allerdings üblich, zur Verbesserung der Haptik und der Handhabung von Reinigungsmitteln der beschriebenen Art und insbesondere von Handwaschlotionen diese durch den Einsatz von organischen Verdickungsmitteln auf Viskositäten etwa im Bereich von 500 bis 5000 mPas, insbesondere auf Viskositäten im Bereich von etwa 500 bis 4000 mPas - gemessen z. B. mit einem Rotationsviskosimeter der Fa. Brookfield, Modell LVF, bei 20°C, Spindel 4 / 20 VpM - einzustellen. Der Zusatz von Wasserstoffperoxid zu solchen eingedickten tensidhaltigen Reinigungsmittelkonzentraten bringt erhebliche Konfektionierungsprobleme, da schon durch den Zusatz geringer Mengen an Wasserstoffperoxid die viskositätsregulierenden Eigenschaften der herkömmlichen Verdicker verloren gehen. However, according to today's practice, it is common to improve the feel and handling of cleaning agents of the type described and in particular hand wash lotions this through the use of organic thickeners Viscosities in the range from 500 to 5000 mPas, in particular on viscosities in the range of about 500 to 4000 mPas - measured e.g. B. with a rotary viscometer from Brookfield, model LVF, at 20 ° C, spindle 4/20 VpM - to be set. The addition from hydrogen peroxide to such thickened surfactant Detergent concentrates bring considerable assembly problems, because the addition of small amounts of hydrogen peroxide the viscosity regulating properties of conventional ones Thickeners are lost.
Die Erfindung geht von der Aufgabe aus, tensidhaltige eingedickte Reinigungsmittel und insbesondere Reinigungsmittelkonzentrate zur Verfügung zu stellen, die durch Mitverwendung geringer Mengen an Wasserstoffperoxid die Fähigkeit zur selbsttätigen Sterilisation besitzen, in ihrem physikalischen Erscheinungsbild gleichwohl den gewünschten viskos angedickten Massen entsprechen.The invention is based on the task of thickened surfactant Detergents and especially detergent concentrates to make available less by sharing Amounts of hydrogen peroxide have the ability to work automatically Have sterilization in their physical appearance nevertheless correspond to the desired viscous thickened masses.
Die Lösung dieser erfindungsgemäßen Aufgabenstellung geht von der Feststellung aus, daß die gemeinsame Verwendung von Wasserstoffperoxid mit der im folgenden geschilderten Kombination von Fettsäurealkanolamiden und anorganischen Salzen zum gewünschten Eigenschaftsbild führt.The solution to this problem according to the invention is based on Noting that sharing of Hydrogen peroxide with the combination described below of fatty acid alkanolamides and inorganic salts for desired property profile leads.
Gegenstand der Erfindung sind dementsprechend angedickte wassermischbare und autosterile Reinigungsmittelkonzentrate, insbesondere für den Einsatz als Handwaschlotion im Medizinalbereich, die waschaktive Tenside neben toxikologisch und insbesondere dermatologisch verträglichen Desinfektions- und/oder Konservierungsmitteln enthalten und dadurch gekennzeichnet sind, daß sie zusammen mit einer geringen Menge an Wasserstoffperoxid als Eindickungsmittel eine Kombination von Fettsäurealkanolamiden und wasserlöslichen Alkali- und/oder Ammoniumsalzen enthalten.The invention accordingly relates to thickened portions water-miscible and autosterile detergent concentrates, especially for use as a hand wash lotion in the Medical field, the detergent surfactants in addition to toxicological and especially dermatologically compatible disinfectant and / or Contain preservatives and characterized are that together with a small amount of A combination of hydrogen peroxide as a thickener Fatty acid alkanolamides and water-soluble alkali and / or Contain ammonium salts.
Erfindungsgemäß gelingt mit dieser neuen Möglichkeit der Viskositätsregelung die Einstellung von Viskositäten der Wasserstoffperoxid enthaltenden Waschlotionen auf den in der Praxis besonders gewünschten Bereich bis etwa 5000 mPas und insbesondere von etwa 500 bis 4000 mPas (Brookfield, wie zuvor bestimmt).According to the invention, this new possibility of viscosity control succeeds the adjustment of viscosities of the hydrogen peroxide containing washing lotions on the in practice in particular desired range up to about 5000 mPas and in particular from about 500 to 4000 mPas (Brookfield, as previously determined).
Die Fettsäurealkanolamide leiten sich insbesondere von Fettsäuren des C-Zahlbereichs von etwa 10 bis 22 insbesondere des Bereichs von etwa 12 bis 18 ab. Die Fettsäuren können dabei gesättigt, anteilsweise aber auch olefinisch ungesättigt sein. Besonders geeignet sind z. B. Fettsäurealkanolamidgemische, die sich einerseits von Kokosfettsäuren und andererseits von Ölsäure ableiten.The fatty acid alkanolamides are derived in particular from fatty acids the C number range from about 10 to 22 in particular the range from about 12 to 18. The fatty acids can be saturated, but partly also be olefinically unsaturated. Particularly suitable are z. B. fatty acid alkanolamide mixtures, the one hand derived from coconut fatty acids and on the other hand from oleic acid.
Fettsäuredialkananolamide und insbesondere Fettsäurdiethanolamide sind die erfindungsgemäß bevorzugten Mischungskomponenten zur Viskositätsregelung. Geeignet sind insbesondere Kombinationen von Kokosfettsäurediethanolamid und Ölsäurediethanolamid in Mischungsverhältnissen im Bereich von 0,2 bis 5:1.Fatty acid dialkananolamides and especially fatty acid diethanolamides are the mixture components preferred according to the invention for Viscosity control. Combinations are particularly suitable of coconut fatty acid diethanolamide and oleic acid diethanolamide in Mixing ratios in the range of 0.2 to 5: 1.
Zusammen mit den Fettsäurealkanolamiden werden wasserlösliche Alkali- und/oder Ammoniumsalze eingesetzt. Nicht korrosive, oxidationsbeständige einfache Salze dieser Art sind bevorzugt, wobei Ammoniumsalzen und hier insbesondere dem Ammoniumsulfat besondere Bedeutung zukommen kann.Together with the fatty acid alkanolamides, water-soluble alkali and / or ammonium salts used. Not corrosive, oxidation resistant simple salts of this type are preferred, wherein Ammonium salts and especially ammonium sulfate can be of particular importance.
Geeignete andere wasserlösliche Salze sind beispielsweise Natrium- und/oder Kaliumsalze anorganischer Säuren wie Natriumchlorid, Kaliumchlorid, Natriumsulfat aber auch entsprechende Salze organischer Säuren wie Kaliumcitrat.Suitable other water-soluble salts are, for example, sodium and / or potassium salts of inorganic acids such as sodium chloride, Potassium chloride, sodium sulfate but also corresponding organic salts Acids such as potassium citrate.
Die Reinigungsmittelkonzentrate enthalten das Wasserstoffperoxid üblicherweise in Mengen von etwa 0,05 bis maximal etwa 2 Gewichtsprozent - bezogen auf das Gesamtgewicht des Reinigungsmittelkonzentrats - wobei bevorzugt Wasserstoffperoxid in Mengen von etwa 0,1 bis 1,5 Gewichtsprozent und insbesondere in Mengen von etwa 0,2 bis 1 Gewichtsprozent vorliegt. Zusammen mit dem Wasserstoffperoxid können übliche Konservierungsmittel entsprechend des Anhang VI der EG-Richtlinie Kosmetik zugegen sein. Als Beispiele seien genannt Ester der p-Hydroxybenzoesäure, Brom-5-nitro-1,3-dioxan, 2,4,4′-Trichlor-2-hydroxydiphenylether, Chlorhexidin, Phenolderivate und Aldehyde. The detergent concentrates contain the hydrogen peroxide usually in amounts of about 0.05 to a maximum of about 2 Weight percent - based on the total weight of the detergent concentrate - Preferably hydrogen peroxide in quantities from about 0.1 to 1.5 percent by weight and especially in amounts from about 0.2 to 1 percent by weight. Together with the Hydrogen peroxide can be used as a common preservative of Annex VI of the EC Cosmetics Directive be. Examples include esters of p-hydroxybenzoic acid, Bromo-5-nitro-1,3-dioxane, 2,4,4′-trichloro-2-hydroxydiphenyl ether, Chlorhexidine, phenol derivatives and aldehydes.
Bei der gemeinsamen Verwendung von Wasserstoffperoxid und Konservierungsmitteln liegt das Mischungsverhältnis solcher von H2O2 abweichender Konservierungsmittel zum Wasserstoffperoxid vorzugsweise im Mengenbereich von 0 bis 2:1.When hydrogen peroxide and preservatives are used together, the mixing ratio of such preservatives deviating from H 2 O 2 to hydrogen peroxide is preferably in the range from 0 to 2: 1.
Als Tensidkomponenten kommen alle üblichen, einschlägigen Verbindungen in Betracht, genannt seien beispielsweise die bekannten Alkylethersulfate, Amidethersulfate, Sulfobernsteinsäureester, Eiweiß-Fettsäure-Kondensate in Form ihrer Na- oder (NH4)- oder Ethanolamin-Salze.Suitable surfactant components are all customary, relevant compounds, for example the known alkyl ether sulfates, amide ether sulfates, sulfosuccinic acid esters, protein-fatty acid condensates in the form of their Na or (NH 4 ) or ethanolamine salts.
Neben den bisher genannten Komponenten können die Reinigungsmittelkonzentrate übliche sonstige Mischungsbestandteile, wie Rückfetter, z. B. Glycerin-EO-Fettsäure-Ester, Fettalkohol-polyalkylen- ether, Polyol-Fettsäure-Ester, Wachester, Perlglanzmittel, z. B. Fettsäuremonoethanolamid, Fettalkoholethersulfate, Duftstoffe und/oder Farbstoffe enthalten.In addition to the components mentioned so far, the cleaning agent concentrates can usual other components of the mixture, such as Refatting agents, e.g. B. Glycerin EO fatty acid ester, fatty alcohol polyalkylene ether, polyol fatty acid esters, wax esters, pearlescent agents, e.g. B. fatty acid monoethanolamide, fatty alcohol ether sulfates, fragrances and / or dyes.
Besonders geeignete Reinigungsmittelkonzentrate der erfindungsgemäßen
Art enthalten in wässriger und/oder wasserlöslich organischer
Lösung bzw. Aufschlemmung die folgenden Komponenten
in den folgenden Mengenbereichen - Gewichtsprozent jeweils wieder
bezogen auf das Gesamtgewicht des Reinigungsmittelkonzentrats:
5 bis 15 Gewichtsprozent waschaktiver Tenside
0,5 bis 5 Gewichtsprozent der sonstigen Zusatzmittel wie
Rückfetter, Perglanzmittel, Duft- und Farbstoffe
0,2 bis 1 Gewichtsprozent Wasserstoffperoxid, gewünschtenfalls
in Gemisch mit üblichen Konservierung-
und/oder Desinfektionsmitteln
0,5 bis 3,5 Gewichtsprozent der Fettsäurealkanolamide, insbesondere
eine Kombination von Kokosfettsäurediethanolamid
und Ölsäurediethanolamid im Verhältnis
von 0,2 bis 5:1
0,8 bis 2,5 Prozent der Alkali- und/oder AmmoniumsalzeParticularly suitable detergent concentrates of the type according to the invention contain the following components in aqueous and / or water-soluble organic solution or slurry in the following quantitative ranges - percent by weight, again based on the total weight of the detergent concentrate:
5 to 15 percent by weight of detergent surfactants
0.5 to 5 percent by weight of other additives such as refatting agents, pearlescent agents, fragrances and colorants
0.2 to 1 percent by weight of hydrogen peroxide, if desired in a mixture with conventional preservatives and / or disinfectants
0.5 to 3.5 percent by weight of the fatty acid alkanolamides, in particular a combination of coconut fatty acid diethanolamide and oleic acid diethanolamide in a ratio of 0.2 to 5: 1
0.8 to 2.5 percent of the alkali and / or ammonium salts
Die Viskosität der Reinigungsmittelkonzentrate ist bevorzugt auf den Bereich von etwa 500 bis 5000, insbesondere auf den Bereich von etwa 500 bis 4000 mPas eingestellt. Konfektionierungen der geschilderten Art zeigen den Effekt der Selbstdekontamination. Sie sind bei Lagerversuchen unter Wechselklimabedingungen im Temperaturbereich von 0 bis 40°C stabil. The viscosity of the detergent concentrates is preferably up to the range from about 500 to 5000, especially on the range from about 500 to 4000 mPas. Packing of the described type show the effect of self-decontamination. They are in storage tests under changing climate conditions in the temperature range stable from 0 to 40 ° C.
Es wurde eine Handwaschlotion (Lotion A) der folgenden
Zusammensetzung hergestellt:
6 Gew.-% Natriumsalz eines C14-Fettalkoholethersulfats mit
4 EO
3 Gew.-% handelsübliches Triethanolaminsalz eines
Kondensationsproduktes aus Eiweißhydrolysat
und Fettsäure (Lamepon ® ST 40; Hersteller:
Chemische Fabrik Grünau, Illertissen)
1 Gew.-% C16-Fettsäuremonoethanolamid
2 Gew.-% Anlagerungsprodukt von 8 EO an Glycerin,
verestert mit 3 Mol Kokosfettsäure
1 Gew.-% Propylenglykol
2 Gew.-% Ammoniumsulfat
1 Gew.-% Kokosfettsäurediethanolamid
1 Gew.-% Ölsäurediethanolamid
0,2 Gew.-% 12-Hydroxybenzoesäuremethylester
0,2 Gew.-% Wasserstoffperoxid
ad 100 Gew.-% Duftstoffe, Farbstoffe, WasserA hand wash lotion (Lotion A) with the following composition was produced:
6% by weight sodium salt of a C 14 fatty alcohol ether sulfate with 4 EO
3% by weight of commercially available triethanolamine salt of a condensation product of protein hydrolyzate and fatty acid (Lamepon ® ST 40; manufacturer: Chemische Fabrik Grünau, Illertissen)
1% by weight of C 16 fatty acid monoethanolamide
2% by weight adduct of 8 EO on glycerol, esterified with 3 moles of coconut fatty acid
1% by weight propylene glycol
2% by weight ammonium sulfate
1% by weight of coconut fatty acid diethanolamide
1% by weight oleic acid diethanolamide
0.2% by weight of 12-hydroxybenzoic acid methyl ester
0.2% by weight of hydrogen peroxide
ad 100% by weight of fragrances, dyes, water
Zu Vergleichszwecken wurde eine Handwaschlotion derselben Zusammensetzung, jedoch ohne den Zusatz von 0,2 Gew.-% Wasserstoffperoxid hergestellt (Lotion B).A hand wash lotion was used for comparison purposes Composition, but without the addition of 0.2% by weight Hydrogen peroxide produced (Lotion B).
Proben dieser Lotionen wurden mit den in der nachstehenden Tabelle angegebenen Keimen massiv kontaminiert und das mikrobiologische Verhalten der Lotionen bei der Lagerung festgestellt. Samples of these lotions were made with those in the following Table of germs massively contaminated and that microbiological behavior of the lotions during storage detected.
Damit steht also die Möglichkeit zur Verfügung, nach Bakterien-, Pilz- oder Sporen-Befall viskositätsstabile Handwaschlotionen herzustellen, die sich selbst dekontaminieren.So there is the possibility to search for bacteria, To produce fungal or spore infestation, viscosity-stable hand-washing lotions, that decontaminate themselves.
Claims (6)
etwa 5 bis 15 Gewichtsprozent waschaktive Tenside,
etwa 0,2 bis 1 Gewichtsprozent Wasserstoffperoxid, gewünschtenfalls in Abmischung mit üblichen Konservierungsmitteln
etwa 0,5 bis 3,5 Gewichtsprozent Fettsäurealkanolamide,
etwa 0,8 bis 2,5 Gewichtsprozent wasserlösliche Alkali- und/oder Ammoniumsalze,
etwa 0,5 bis 5 Gewichtsprozent übliche Zusatzstoffe, - Gewichtsprozent jeweils bezogen auf das Gesamtgewicht des Reinigungsmittelkonzentrates.6. Detergent concentrates according to claims 1 to 5, characterized in that they contain the following mixture components in aqueous preparation:
about 5 to 15 percent by weight of detergent surfactants,
about 0.2 to 1 percent by weight of hydrogen peroxide, if desired in a mixture with conventional preservatives
about 0.5 to 3.5 percent by weight of fatty acid alkanolamides,
about 0.8 to 2.5 percent by weight of water-soluble alkali and / or ammonium salts,
about 0.5 to 5 percent by weight of conventional additives, - percent by weight in each case based on the total weight of the detergent concentrate.
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19853528843 DE3528843A1 (en) | 1985-08-10 | 1985-08-10 | SELF-DECONTAMINATING DETERGENTS |
| US06/892,023 US4746451A (en) | 1985-08-10 | 1986-07-30 | Self-decontaminating cleansing preparations |
| DE8686110724T DE3676004D1 (en) | 1985-08-10 | 1986-08-02 | SELF-DECONTAMINATING DETERGENTS. |
| AT86110724T ATE58915T1 (en) | 1985-08-10 | 1986-08-02 | SELF-DECONTAMINATING CLEANERS. |
| EP86110724A EP0212407B1 (en) | 1985-08-10 | 1986-08-02 | Self-decontaminating detergent |
| JP61189479A JPS6239698A (en) | 1985-08-10 | 1986-08-11 | Self-purifying cleansing preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19853528843 DE3528843A1 (en) | 1985-08-10 | 1985-08-10 | SELF-DECONTAMINATING DETERGENTS |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE3528843A1 true DE3528843A1 (en) | 1987-02-12 |
Family
ID=6278290
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19853528843 Withdrawn DE3528843A1 (en) | 1985-08-10 | 1985-08-10 | SELF-DECONTAMINATING DETERGENTS |
| DE8686110724T Expired - Fee Related DE3676004D1 (en) | 1985-08-10 | 1986-08-02 | SELF-DECONTAMINATING DETERGENTS. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE8686110724T Expired - Fee Related DE3676004D1 (en) | 1985-08-10 | 1986-08-02 | SELF-DECONTAMINATING DETERGENTS. |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4746451A (en) |
| EP (1) | EP0212407B1 (en) |
| JP (1) | JPS6239698A (en) |
| AT (1) | ATE58915T1 (en) |
| DE (2) | DE3528843A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19623571A1 (en) * | 1996-06-13 | 1997-12-18 | Henkel Kgaa | Thickener for aqueous hydrogen peroxide solutions |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5066497A (en) * | 1988-07-28 | 1991-11-19 | Albert L. Jacobs, Jr. | Antimicrobial veterinary compositions and methods |
| US4935248A (en) * | 1988-07-28 | 1990-06-19 | Albert L. Jacobs | Antimicrobial veterinary compositions and methods |
| JPH06501043A (en) * | 1990-09-28 | 1994-01-27 | ザ、プロクター、エンド、ギャンブル、カンパニー | Polyhydroxy fatty acid amide surfactants in bleach-containing detergent compositions |
| DE4304066C2 (en) * | 1993-02-11 | 1995-01-26 | Beiersdorf Ag | Use of high electrolyte concentrations in cosmetic cleaners |
| US6235299B1 (en) * | 1998-02-27 | 2001-05-22 | Buckman Laboratories International Inc | Potentiation of biocide activity using diethanolamide |
| PL332783A1 (en) * | 1999-04-27 | 2000-11-06 | Nowakowski Grzegorz | Pharmaceutic preparation in the form of gel |
| DE10013796A1 (en) * | 2000-03-20 | 2001-09-27 | Kaercher Gmbh & Co Alfred | Decontamination composition useful for treating surfaces contaminated with chemical warfare agents comprises an active agent, a neutral salt, an emulsifier and a solvent derived from natural fatty acids |
| FR2827768B1 (en) * | 2001-07-27 | 2005-08-26 | Oreal | FOAMING COSMETIC COMPOSITION FOR BATH |
| US9192598B2 (en) * | 2008-06-25 | 2015-11-24 | University Of North Texas Health Science Center At Fort Worth | Prevention of bacterial growth and biofilm formation by ligands that act on cannabinoidergic systems |
| JP4900370B2 (en) * | 2008-12-01 | 2012-03-21 | パナソニック株式会社 | Steam iron |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB962585A (en) * | 1961-11-03 | 1964-07-01 | Unilever Ltd | Detergent compositions |
| NL128284C (en) * | 1964-12-29 | |||
| DE1924325A1 (en) * | 1969-05-13 | 1970-11-19 | Henkel & Cie Gmbh | Clear liquid cleaning agent concentrates |
| US3833565A (en) * | 1972-09-29 | 1974-09-03 | Procter & Gamble | Phenylantimony bis(2-pyridinethiol 1-oxide) |
| US4130501A (en) * | 1976-09-20 | 1978-12-19 | Fmc Corporation | Stable viscous hydrogen peroxide solutions containing a surfactant and a method of preparing the same |
| US4321156A (en) * | 1977-03-30 | 1982-03-23 | S. C. Johnson & Son, Inc. | Shampoo composition |
| CA1146851A (en) * | 1978-05-01 | 1983-05-24 | Donald F. Greene | Hydrogen peroxide disinfecting and sterilizing compositions |
| DE2904217A1 (en) * | 1979-02-05 | 1980-08-14 | Henkel Kgaa | DISINFECTANTS BASED ON ALCOHOLS AND ITS USE FOR SKIN DISINFECTION |
| US4329334A (en) * | 1980-11-10 | 1982-05-11 | Colgate-Palmolive Company | Anionic-amphoteric based antimicrobial shampoo |
| US4491539A (en) * | 1981-06-04 | 1985-01-01 | The Procter & Gamble Company | Liquid cleansing product with skin feel additives |
| US4387040A (en) * | 1981-09-30 | 1983-06-07 | Colgate-Palmolive Company | Liquid toilet soap |
-
1985
- 1985-08-10 DE DE19853528843 patent/DE3528843A1/en not_active Withdrawn
-
1986
- 1986-07-30 US US06/892,023 patent/US4746451A/en not_active Expired - Fee Related
- 1986-08-02 AT AT86110724T patent/ATE58915T1/en not_active IP Right Cessation
- 1986-08-02 EP EP86110724A patent/EP0212407B1/en not_active Expired - Lifetime
- 1986-08-02 DE DE8686110724T patent/DE3676004D1/en not_active Expired - Fee Related
- 1986-08-11 JP JP61189479A patent/JPS6239698A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19623571A1 (en) * | 1996-06-13 | 1997-12-18 | Henkel Kgaa | Thickener for aqueous hydrogen peroxide solutions |
| DE19623571C2 (en) * | 1996-06-13 | 2000-06-08 | Cognis Deutschland Gmbh | Thickener for aqueous hydrogen peroxide solutions |
Also Published As
| Publication number | Publication date |
|---|---|
| US4746451A (en) | 1988-05-24 |
| JPS6239698A (en) | 1987-02-20 |
| EP0212407A2 (en) | 1987-03-04 |
| ATE58915T1 (en) | 1990-12-15 |
| EP0212407B1 (en) | 1990-12-05 |
| EP0212407A3 (en) | 1988-09-07 |
| DE3676004D1 (en) | 1991-01-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8141 | Disposal/no request for examination |