EP1097031B1 - Mittel und verfahren zur schutzbehandlung von holz - Google Patents
Mittel und verfahren zur schutzbehandlung von holz Download PDFInfo
- Publication number
- EP1097031B1 EP1097031B1 EP99926219A EP99926219A EP1097031B1 EP 1097031 B1 EP1097031 B1 EP 1097031B1 EP 99926219 A EP99926219 A EP 99926219A EP 99926219 A EP99926219 A EP 99926219A EP 1097031 B1 EP1097031 B1 EP 1097031B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- parts
- wood
- composition according
- oil
- methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002023 wood Substances 0.000 title claims abstract description 22
- 230000001681 protective effect Effects 0.000 title claims abstract description 7
- 238000000034 method Methods 0.000 title claims description 12
- 239000003795 chemical substances by application Substances 0.000 title abstract description 15
- 239000011280 coal tar Substances 0.000 claims abstract description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 28
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims abstract description 7
- 241000238631 Hexapoda Species 0.000 claims abstract description 3
- 239000003139 biocide Substances 0.000 claims abstract 2
- 239000003921 oil Substances 0.000 claims description 29
- 235000019198 oils Nutrition 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 14
- 239000011230 binding agent Substances 0.000 claims description 11
- 229920001223 polyethylene glycol Polymers 0.000 claims description 9
- 239000002202 Polyethylene glycol Substances 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 7
- 239000000975 dye Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 239000001993 wax Substances 0.000 claims description 5
- 230000000694 effects Effects 0.000 claims description 4
- 239000000944 linseed oil Substances 0.000 claims description 4
- 235000021388 linseed oil Nutrition 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- 229920000180 alkyd Polymers 0.000 claims description 3
- 150000001735 carboxylic acids Chemical class 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 150000007522 mineralic acids Chemical class 0.000 claims description 3
- 239000003549 soybean oil Substances 0.000 claims description 3
- 235000012424 soybean oil Nutrition 0.000 claims description 3
- 238000001228 spectrum Methods 0.000 claims description 3
- 239000003619 algicide Substances 0.000 claims description 2
- 230000000844 anti-bacterial effect Effects 0.000 claims description 2
- 239000003899 bactericide agent Substances 0.000 claims description 2
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- 238000005470 impregnation Methods 0.000 claims description 2
- 239000002917 insecticide Substances 0.000 claims description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical class CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims 1
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- 150000003842 bromide salts Chemical class 0.000 claims 1
- 150000003841 chloride salts Chemical class 0.000 claims 1
- 150000004694 iodide salts Chemical class 0.000 claims 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims 1
- 239000000839 emulsion Substances 0.000 abstract description 14
- 239000010875 treated wood Substances 0.000 abstract description 11
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- 230000000740 bleeding effect Effects 0.000 abstract description 3
- 230000009471 action Effects 0.000 abstract description 2
- 230000001988 toxicity Effects 0.000 abstract description 2
- 231100000419 toxicity Toxicity 0.000 abstract description 2
- 229940108066 coal tar Drugs 0.000 abstract 4
- 206010061217 Infestation Diseases 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 230000000149 penetrating effect Effects 0.000 abstract 1
- 239000002641 tar oil Substances 0.000 description 15
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- 238000002360 preparation method Methods 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 5
- 229920000847 nonoxynol Polymers 0.000 description 5
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 description 4
- IEORSVTYLWZQJQ-UHFFFAOYSA-N 2-(2-nonylphenoxy)ethanol Chemical compound CCCCCCCCCC1=CC=CC=C1OCCO IEORSVTYLWZQJQ-UHFFFAOYSA-N 0.000 description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- XJMWHXZUIGHOBA-UHFFFAOYSA-N azane;propanoic acid Chemical compound N.CCC(O)=O XJMWHXZUIGHOBA-UHFFFAOYSA-N 0.000 description 4
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 description 4
- -1 copper salts Chemical class 0.000 description 4
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- 208000032843 Hemorrhage Diseases 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
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- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 3
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- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 239000011976 maleic acid Substances 0.000 description 3
- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 description 3
- 239000003223 protective agent Substances 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- BPTPEBDKCNQNIV-ALOPSCKCSA-N (2s,6r)-4-[3-(2-tert-butylphenyl)-2-methylpropyl]-2,6-dimethylmorpholine Chemical compound C=1C=CC=C(C(C)(C)C)C=1CC(C)CN1C[C@H](C)O[C@H](C)C1 BPTPEBDKCNQNIV-ALOPSCKCSA-N 0.000 description 2
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 description 2
- YTOPFCCWCSOHFV-UHFFFAOYSA-N 2,6-dimethyl-4-tridecylmorpholine Chemical compound CCCCCCCCCCCCCN1CC(C)OC(C)C1 YTOPFCCWCSOHFV-UHFFFAOYSA-N 0.000 description 2
- UFNOUKDBUJZYDE-UHFFFAOYSA-N 2-(4-chlorophenyl)-3-cyclopropyl-1-(1H-1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1CC(O)(C=1C=CC(Cl)=CC=1)C(C)C1CC1 UFNOUKDBUJZYDE-UHFFFAOYSA-N 0.000 description 2
- 239000004251 Ammonium lactate Substances 0.000 description 2
- 229940123208 Biguanide Drugs 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- GHXZTYHSJHQHIJ-UHFFFAOYSA-N Chlorhexidine Chemical compound C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 GHXZTYHSJHQHIJ-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- QTDRLOKFLJJHTG-UHFFFAOYSA-N Furmecyclox Chemical compound C1=C(C)OC(C)=C1C(=O)N(OC)C1CCCCC1 QTDRLOKFLJJHTG-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- ISRUGXGCCGIOQO-UHFFFAOYSA-N Rhoden Chemical compound CNC(=O)OC1=CC=CC=C1OC(C)C ISRUGXGCCGIOQO-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 229940059265 ammonium lactate Drugs 0.000 description 2
- 235000019286 ammonium lactate Nutrition 0.000 description 2
- RZOBLYBZQXQGFY-HSHFZTNMSA-N azanium;(2r)-2-hydroxypropanoate Chemical compound [NH4+].C[C@@H](O)C([O-])=O RZOBLYBZQXQGFY-HSHFZTNMSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 150000001639 boron compounds Chemical class 0.000 description 2
- TWFZGCMQGLPBSX-UHFFFAOYSA-N carbendazim Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 2
- GYSSRZJIHXQEHQ-UHFFFAOYSA-N carboxin Chemical compound S1CCOC(C)=C1C(=O)NC1=CC=CC=C1 GYSSRZJIHXQEHQ-UHFFFAOYSA-N 0.000 description 2
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 2
- QQQYTWIFVNKMRW-UHFFFAOYSA-N diflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC=C(Cl)C=C1 QQQYTWIFVNKMRW-UHFFFAOYSA-N 0.000 description 2
- 239000012990 dithiocarbamate Substances 0.000 description 2
- HJUFTIJOISQSKQ-UHFFFAOYSA-N fenoxycarb Chemical compound C1=CC(OCCNC(=O)OCC)=CC=C1OC1=CC=CC=C1 HJUFTIJOISQSKQ-UHFFFAOYSA-N 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- UYJUZNLFJAWNEZ-UHFFFAOYSA-N fuberidazole Chemical compound C1=COC(C=2NC3=CC=CC=C3N=2)=C1 UYJUZNLFJAWNEZ-UHFFFAOYSA-N 0.000 description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 2
- RONFGUROBZGJKP-UHFFFAOYSA-N iminoctadine Chemical compound NC(N)=NCCCCCCCCNCCCCCCCCN=C(N)N RONFGUROBZGJKP-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 2
- LDKKGAXZNKDWEU-UHFFFAOYSA-N n-[1-(6-chloropyridin-3-yl)-4-methyl-4,5-dihydroimidazol-2-yl]nitramide Chemical compound [O-][N+](=O)NC1=NC(C)CN1C1=CC=C(Cl)N=C1 LDKKGAXZNKDWEU-UHFFFAOYSA-N 0.000 description 2
- LXCJGJYAOVCKLO-UHFFFAOYSA-N n-cyclohexyl-n-hydroxynitrous amide Chemical compound O=NN(O)C1CCCCC1 LXCJGJYAOVCKLO-UHFFFAOYSA-N 0.000 description 2
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 2
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 2
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- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 description 2
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- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000035900 sweating Effects 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- JLYXXMFPNIAWKQ-UHFFFAOYSA-N γ Benzene hexachloride Chemical compound ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/44—Tar; Mineral oil
- B27K3/46—Coal tar
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/50—Mixtures of different organic impregnating agents
Definitions
- the present invention relates to means based on coal tar oil for the Protective treatment of wood. It also relates to a protective treatment procedure of wood using the agents according to the invention.
- coal tar oil to protect wood against rotting and insect attack has been known since the middle of the 19th century and has been known for Conservation of masts, fences, sleepers etc. in use.
- coal tar oil in the form of emulsions in water or aqueous Protective salt solutions (zinc salts, copper salts) apply. This form of application
- tar oils continued to be the majority were used in the undiluted state.
- homoogenization analogous to that in Milk
- dispersers e.g.
- a disadvantage of this known method is the fact that the emulsions are proportional are unstable and that the effective proportion of coal tar due to the emulsion is reduced by the proportion of water and the emulsifier (s), so that the The amount to be introduced must be increased in order to provide effective and lasting protection guarantee.
- JP-A-56072502 describes compositions for wood protection treatment the Coal tar oil, quaternary Ammonium compounds and Contain water.
- the object of the present invention was therefore the disadvantages of the known production processes and to eliminate or reduce applications of tar oil emulsions. According to the invention, this object is achieved by the means according to claim 1 and the Treatment method according to claim 6 solved.
- the pungent smell of coal tar oil is particularly evident in two- and three-core Aromatics, e.g. B. naphthalene and alkylnaphthalenes. Leave this only partially separate by distillation, since after their complete removal a tar oil If the viscosity is too high and cannot be handled even at 100-120 ° C.
- the Agents according to the invention also permit use by the nature of their preparation more viscous and thus highly deodorized tar oils, which is the use of coal tar oil also in sensitive areas, e.g. B. thresholds for subways, facilitated or makes it possible in the first place.
- the agents according to the invention preferably contain to improve the (storage) Stability up to 20 parts of a polyglycol compound.
- a polyglycol compound include, for example Polyethylene glycols and polypropylene glycols, as well as their alkyl and aryl ethers and esters.
- Polyethylene glycol compounds such as, for example, are particularly preferred Polyethylene glycol, ethoxylated phenols and diethylene glycol monobutyl ether.
- These preferably contain one or more constituents from the group of the resins, Binders, waxes, dyes and pigments.
- Particularly preferred binders are alkyd resins and similar resins based on natural oils such as linseed oil or soybean oil, especially those that are reacted with Ethylene oxide or propylene oxide are water-soluble or water-dilutable.
- the agents according to the invention contain to broaden the spectrum of action preferably additionally an effective amount of one or more insecticides, fungicides, Algicides or bactericides.
- binders such.
- B. drying alkyd resins, acrylates or others Polymers can improve the surfaces of the treated wood mechanically and optically, combined with a further reduction in mobility (leaching and Bleeding) of coal tar oil.
- the systems according to the invention can still be used in contrast to coal tar oil by adding dyes or pigments alone Modify in such a way that the treated wood can be colored can.
- By adding waxes it is possible to mattify the surfaces of the treated wood, combined with a strong water-repellent Effect that reduces the absorption of dripping water without the moisture exchange to hinder over the vapor phase.
- This preparation forms stable, milky (opaque) or clear mixtures with a low viscosity that can be introduced into the wood with good penetration and without penetration by means of a boiler pressure process (application of vacuum and pressure).
- a boiler pressure process application of vacuum and pressure.
- the amount required for comprehensive protection of the wood is 20-80 kg / m 3 wood.
- the agents according to the invention are preferably used in vacuum boiler pressure systems such that the means by means of pressure differences in the to be protected Wood.
- the process steps include a pre-vacuum phase, a Flood phase, while maintaining the vacuum, and a pressure phase. If necessary the process is completed with a final vacuum. Control of the brought in Protective agent mass is made by weighing. For easily soakable woods or types of wood the water content in the compositions can be increased even further compared to the examples become.
- the impregnation is preferably carried out without the addition of heat, that is to say approximately at ambient temperature. If necessary, the water introduced into the wood with the agents can be removed by heat treatment. If the preparations also contain polymers that are suitable for curing under the influence of elevated temperatures, the wood can be treated with superheated steam. This vaporization then leads to post-diffusion and more even distribution of the agents, combined with more effective fixation. Polyethylene glycols that may be present in the preparations give them a dimensionally stabilizing effect, combined with a significantly reduced tendency of the wood treated with them to crack.
- coal tar 8 parts N -Cocosalkyl- N, N -dimethyl- N -benzylammonium acetate 4 parts Nonylphenol ethoxylate (8-12 EO groups) 10 parts diethylene 38 pieces water
- coal tar 10 parts N- cocoalkyl- N, N -dimethyl- N -benzylammonium chloride 10 parts Polyethylene glycol (MW approx. 300) 30 parts water
- coal tar 8 parts N -Cocosalkyl- N, N -dimethyl- N -benzylammonium acetate 4 parts Nonylphenol ethoxylate (8-12 EO groups) 10 parts diethylene 8 parts binder 30 parts water
- coal tar 10 parts N- cocoalkyl- N, N -dimethyl- N -benzylammonium chloride 10 parts Polyethylene glycol (MW approx. 300) 2 parts wax 28 parts water
- a concentrate was produced according to the following recipe: 60 parts Coal tar oil, type B WEI 20 parts N, N -didecyl- N -methyl- N -poly (oxethyl) ammonium propionate 20 parts Binder prepared by heating 94 parts of linseed oil and 3 parts of maleic acid to 180 ° C and subsequent esterification with 3 parts of polyethylene glycol (10 EO groups) at 195 ° C
- the concentrate thus obtained was ready for use with water in a ratio of 1: 9 Diluted emulsion.
- a concentrate was produced according to the following recipe: 65 parts Coal tar oil, type B WEI 15 parts N, N -didecyl- N -methyl- N -poly (oxethyl) ammonium propionate 15 parts Binder made by heating 92 parts of soybean oil and 3 parts of maleic acid to 180 ° C and subsequent esterification with 5 parts of polypropylene glycol (12 PO groups) at 170 ° C 1st chapter Silicon defoamer 1st chapter propiconazole 3 parts water
- a concentrate was produced according to the following recipe: 70 parts Coal tar oil, type B WEI 10 parts N, N -didecyl- N -methyl- N -poly (oxethyl) ammonium propionate 19 parts Binder made by heating 85 parts of polybutadiene oil and 5 parts of maleic acid to 150 ° C and subsequent esterification with 10 parts of polyethylene glycol (10 EO groups) at 150 ° C 1st chapter oil-soluble dye
- the concentrate thus obtained was ready for use with water in a ratio of 1: 9 Diluted emulsion.
- a concentrate was produced according to the following recipe: 60 parts Coal tar oil, type B WEI 10 parts N, N -didecyl- N, N -dimethylammonium chloride, 80% in water 19 parts Binder made by heating 80 parts linseed oil and 12 parts neopentyl glycol to 170 ° C and then reacting with 8 parts ethylene oxide under pressure 10 parts diethylene
- the concentrate thus obtained was ready for use with water in a ratio of 1: 9 Diluted emulsion.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SI9930500T SI1097031T1 (en) | 1998-07-12 | 1999-07-02 | Agents and method for the protective treatment of wood |
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19831036 | 1998-07-12 | ||
| DE19831036 | 1998-07-12 | ||
| DE19926884A DE19926884A1 (de) | 1998-07-12 | 1999-06-12 | Mittel und Verfahren zur Schutzbehandlung von Holz |
| DE19926884 | 1999-06-12 | ||
| PCT/CH1999/000288 WO2000002716A1 (de) | 1998-07-12 | 1999-07-02 | Mittel und verfahren zur schutzbehandlung von holz |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1097031A1 EP1097031A1 (de) | 2001-05-09 |
| EP1097031B1 true EP1097031B1 (de) | 2003-11-05 |
Family
ID=26047351
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP99926219A Expired - Lifetime EP1097031B1 (de) | 1998-07-12 | 1999-07-02 | Mittel und verfahren zur schutzbehandlung von holz |
Country Status (19)
| Country | Link |
|---|---|
| EP (1) | EP1097031B1 (no) |
| AT (1) | ATE253438T1 (no) |
| AU (1) | AU759694B2 (no) |
| BR (1) | BR9912049B1 (no) |
| CA (1) | CA2336931C (no) |
| CZ (1) | CZ299917B6 (no) |
| DE (1) | DE29923154U1 (no) |
| DK (1) | DK1097031T3 (no) |
| EE (1) | EE04793B1 (no) |
| ES (1) | ES2211097T3 (no) |
| HU (1) | HU229630B1 (no) |
| IL (1) | IL140666A0 (no) |
| NO (1) | NO323895B1 (no) |
| NZ (1) | NZ509289A (no) |
| PL (1) | PL191467B1 (no) |
| PT (1) | PT1097031E (no) |
| SK (1) | SK285573B6 (no) |
| TR (1) | TR200100041T2 (no) |
| WO (1) | WO2000002716A1 (no) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040146733A1 (en) * | 2001-04-03 | 2004-07-29 | Joachim Fritschi | Method for the protective treatment of wood and derived timber products |
| DE10129749B4 (de) * | 2001-06-20 | 2005-11-03 | Steffen, Günter | Verfahren zur Herstellung eines eine wasserlösliche Holzschutzlasur und ein algizides Mittel aufweisenden Holzschutzmittels |
| EP1405563A1 (en) | 2001-07-10 | 2004-04-07 | Yoshimatsu, Michiharu | Wood-based refined tar-containing coating compostions |
| DE10341883B4 (de) * | 2003-09-09 | 2006-11-02 | Carl Berninghausen | Verwendung eines Imprägniermittels zur Holzschutzbehandlung |
| SE0600623L (sv) * | 2006-03-18 | 2007-05-15 | Jape Produkter I Haessleholm A | Skydd mot mögelangrepp på obehandlat virke |
| MX2022003773A (es) * | 2019-10-08 | 2022-04-25 | Swimc Llc | Tinte de madera a base de agua sin lapeado. |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5672902A (en) * | 1979-11-19 | 1981-06-17 | Katayama Chemical Works Co | High permeable kyanizing insecticide of creosote oil |
| AU604471B2 (en) * | 1985-12-17 | 1990-12-20 | Commonwealth Scientific And Industrial Research Organisation | Preservative composition |
| DE3811199A1 (de) * | 1988-04-01 | 1989-10-19 | Mueller Bauchemie | Holzschutzmittel |
| GB8908794D0 (en) * | 1989-04-19 | 1989-06-07 | Janssen Pharmaceutica Nv | Synergistic compositions containing propiconazole and tebuconazole |
| DE4117844A1 (de) * | 1991-05-31 | 1992-12-03 | Basf Ag | Waessrige traenkharzloesungen |
| DE19528095A1 (de) * | 1995-08-01 | 1997-02-06 | Total Deutschland Gmbh | Zubereitung auf der Basis eines speziellen Steinkohlenteeröls und einer Mineralölfraktion sowie deren Verwendung |
-
1999
- 1999-06-12 DE DE29923154U patent/DE29923154U1/de not_active Expired - Lifetime
- 1999-07-02 DK DK99926219T patent/DK1097031T3/da active
- 1999-07-02 CZ CZ20010040A patent/CZ299917B6/cs not_active IP Right Cessation
- 1999-07-02 WO PCT/CH1999/000288 patent/WO2000002716A1/de not_active Ceased
- 1999-07-02 CA CA002336931A patent/CA2336931C/en not_active Expired - Fee Related
- 1999-07-02 HU HU0102995A patent/HU229630B1/hu not_active IP Right Cessation
- 1999-07-02 PL PL345611A patent/PL191467B1/pl unknown
- 1999-07-02 EP EP99926219A patent/EP1097031B1/de not_active Expired - Lifetime
- 1999-07-02 NZ NZ509289A patent/NZ509289A/en not_active IP Right Cessation
- 1999-07-02 SK SK2035-2000A patent/SK285573B6/sk not_active IP Right Cessation
- 1999-07-02 BR BRPI9912049-6A patent/BR9912049B1/pt not_active IP Right Cessation
- 1999-07-02 AT AT99926219T patent/ATE253438T1/de active
- 1999-07-02 AU AU43566/99A patent/AU759694B2/en not_active Ceased
- 1999-07-02 EE EEP200100024A patent/EE04793B1/xx not_active IP Right Cessation
- 1999-07-02 PT PT99926219T patent/PT1097031E/pt unknown
- 1999-07-02 ES ES99926219T patent/ES2211097T3/es not_active Expired - Lifetime
- 1999-07-02 TR TR2001/00041T patent/TR200100041T2/xx unknown
- 1999-07-21 IL IL14066699A patent/IL140666A0/xx not_active IP Right Cessation
-
2001
- 2001-01-11 NO NO20010183A patent/NO323895B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| PT1097031E (pt) | 2004-03-31 |
| DK1097031T3 (da) | 2004-02-23 |
| AU759694B2 (en) | 2003-04-17 |
| NZ509289A (en) | 2003-05-30 |
| HUP0102995A3 (en) | 2003-01-28 |
| HU229630B1 (en) | 2014-03-28 |
| PL345611A1 (en) | 2002-01-02 |
| EP1097031A1 (de) | 2001-05-09 |
| CA2336931A1 (en) | 2000-01-20 |
| IL140666A0 (en) | 2002-02-10 |
| NO323895B1 (no) | 2007-07-16 |
| ES2211097T3 (es) | 2004-07-01 |
| CA2336931C (en) | 2008-09-16 |
| AU4356699A (en) | 2000-02-01 |
| PL191467B1 (pl) | 2006-05-31 |
| SK20352000A3 (sk) | 2001-05-10 |
| DE29923154U1 (de) | 2000-03-30 |
| NO20010183L (no) | 2001-02-13 |
| CZ200140A3 (cs) | 2002-01-16 |
| TR200100041T2 (tr) | 2001-07-23 |
| EE04793B1 (et) | 2007-04-16 |
| ATE253438T1 (de) | 2003-11-15 |
| NO20010183D0 (no) | 2001-01-11 |
| BR9912049A (pt) | 2001-04-03 |
| EE200100024A (et) | 2002-06-17 |
| BR9912049B1 (pt) | 2010-06-01 |
| CZ299917B6 (cs) | 2008-12-29 |
| SK285573B6 (sk) | 2007-04-05 |
| HUP0102995A2 (hu) | 2001-11-28 |
| WO2000002716A1 (de) | 2000-01-20 |
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