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EP0622451B1 - Compostions parfumées de blanchiment à l'hypochlorite - Google Patents

Compostions parfumées de blanchiment à l'hypochlorite Download PDF

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Publication number
EP0622451B1
EP0622451B1 EP93870070A EP93870070A EP0622451B1 EP 0622451 B1 EP0622451 B1 EP 0622451B1 EP 93870070 A EP93870070 A EP 93870070A EP 93870070 A EP93870070 A EP 93870070A EP 0622451 B1 EP0622451 B1 EP 0622451B1
Authority
EP
European Patent Office
Prior art keywords
acetal
acetate
composition
dimethyl
perfume
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Revoked
Application number
EP93870070A
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German (de)
English (en)
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EP0622451A1 (fr
Inventor
Francesco Agostini
Giulia Ottavia Bianchetti
Francis Perrichon
Mauro Gallo
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Procter and Gamble Co
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Procter and Gamble Co
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Priority to AT93870070T priority Critical patent/ATE174054T1/de
Priority to ES93870070T priority patent/ES2127267T3/es
Priority to EP98870103A priority patent/EP0867503A3/fr
Priority to DE69322375T priority patent/DE69322375T2/de
Priority to DK93870070T priority patent/DK0622451T3/da
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to EP93870070A priority patent/EP0622451B1/fr
Publication of EP0622451A1 publication Critical patent/EP0622451A1/fr
Publication of EP0622451B1 publication Critical patent/EP0622451B1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3956—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes

Definitions

  • the present invention relates to a liquid bleaching composition which is suitable both for laundry and household applications.
  • Compositions herein are particularly suitable in laundry applications, as a prewash bleaching composition.
  • Liquid bleaching compositions are well known In the art. Amongst the different bleaching compositions available, those relying on bleaching by hypochlorite are often preferred, mainly for performance reasons. These hypochlorite-based compositions are typically used in dilute form and are suitable both for laundry and household applications. However a major drawback associated with chlorine-based compositions is the malodor they generate during and after use. Indeed, not only does the composition itself smell chlorine bleach, but the malodor remains noticeable on fabrics or surfaces which have been treated with said compositions, as well as on the skin of the user of the composition, even after the bleaching composition has been thoroughly rinsed away.
  • Formulators have tried to solve that problem by designing perfumed chlorine-based bleaching compositions. However, this has proved difficult mainly for two reasons. Firstly, only a few perfume components are available which are stable in a strong oxidative environment such as a chlorine-based bleaching composition, resulting in limited flexibility in designing perfumes for such compositions. Secondly, chlorine bleach odor is strong and therefore difficult to mask even when perfumes are present.
  • a chlorine-based bleaching composition suitable for use in diluted form could be formulated, which exhibits a reduced chlorine odor upon use, by adding a pH buffering means, preferably a carbonate salt and/or a silicate salt in an aqueous bleaching composition, said composition comprising an alkali metal hypochlorite (2% - 10% by weight) and a bleach stable perfume and being formulated, at a pH of from 11.5 to 14.
  • a pH buffering means preferably a carbonate salt and/or a silicate salt
  • WO 88/05461 discloses a bleaching composition comprising sodium hypochlorite, sodium carbonate and sodium hydroxide.
  • US 4 287 079 discloses aqueous cleaning compositions to be applied from squirt bottle comprising a particulate abrasive, a two part thickener consisting essentially of a mixture of fumed silicon dioxide and smectite clay, an aqueous hypohalite bleach solution, an alkaline builder and perfume like isobornylacetate. Said compositions are suitable for cleaning hard surfaces, no laundry application is disclosed.
  • GB-A-2 076 010 discloses thickened aqueous bleach compositions comprising an alkali metal hypochlorite, one or more carboxylated surfactants, metal hydroxide, electrolytes such as calcium carbonate and perfume. Said compositions are suitable for cleaning vertical and inclined surfaces, no laundry application is disclosed.
  • EP-A-30 401 discloses liquid thickened chlorine bleaching compositions having a pH of from 10 to 12.5 and comprising hypochlorite, a buffering means like alkali metal salts of carbonic acid and of silicilic acid, perfume and a thickening system, i.e. a mixture of two different detergent active compounds. Said compositions are useful for bleaching hard surfaces, no laundry application is disclosed.
  • EP-A-204 472 discloses a thickened aqueous cleaning composition
  • a thickened aqueous cleaning composition comprising a specific tertiary amino oxide and an alkali metal or alkaline earth metal mono- or polyalkylated benzene or naphthalene sulphonate in which the alkyl groups contain from 1 to 4 carbon atoms.
  • Said compositions may further comprise hypochlorite, metal hydroxide, alkali metal carbonate and perfume like isobornylacetate dihydroter pincol, dihydroterpinyl acetate and isoborneol.
  • Alkali metal carbonate may be present as a contaminant of commercially available hypochlorite solution at a level of from 0.01% to 0.1% by weight of the hypochlorite solution.
  • Said compositions are suitable for cleaning non-horizontal structural surfaces, no laundry application is disclosed.
  • US 4 235 732 discloses alkaline aqueous hypochlorite cleaning compositions containing paraffin sulphonate surfactant, an inorganic colloid-forming clay, insoluble particulate abrasive, an inorganic alkaline salt capable of maintaining the composition pH within the range of from about 10 to 14 and perfume.
  • Different bleaching applications are disclosed including bleaching of textiles.
  • US 3 876 551 discloses aqueous perfumed compositions (pH 12 to 13.5) containing an alkali metal hypochlorite, a stable perfume oil and a surface active agent consisting solely of an amine oxide composition which consists essentially of one or more morpholine and/or dimethyl C 11 -C 13 straight chain alkyl amine oxides. No pH buffering means are disclosed. Said compositions are suitable for laundry and domestic bleaching.
  • EP-A-186 386 discloses an aqueous composition and having a pH above 12, comprising sodium hypochlorite, perfume, optical brighteners and amine oxides. No pH buffering means are disclosed. Said compositions are suitable for laundry applications.
  • the present invention encompasses an aqueous liquid bleaching composition suitable for use in diluted form, said composition having a pH as is of from 11.5 to 14 and comprising:
  • the present invention further encompasses a method of bleaching fabrics which comprises the steps of:
  • the present invention also encompasses the use of a pH buffering means, in an aqueous liquid bleaching composition suitable for use in diluted form, said composition having a pH as is of from 11.5 to 14 and comprising from 2% to 10% by weight of the total composition of an alkali metal hypochlorite, and a bleach stable perfume, whereby said perfume causes no more than 10% AvCl2 loss in 5 days at 50C, to reduce the chlorine odor during and after use.
  • compositions according to the present invention are aqueous bleaching compositions.
  • they comprise hypochlorite in an aqueous matrix.
  • alkali metal hypochlorite Various forms of alkali metal hypochlorite are commercially available and, although this is not critical for the present invention, it is preferred herein to use sodium hypochlorite.
  • Compositions according to the present invention comprise a bleaching amount of alkali metal hypochlorite, which represents from 2% to 10% by weight of the total composition, based on active chlorine, of alkali metal hypochlorite.
  • Preferred compositions herein comprise from 3% to 6% of alkali metal hypochlorite.
  • compositions according to the present invention have a pH as is of from 11.5 to 14, preferably from 12.5 to 14. Suitable means to achieve such a pH value include potassium and sodium hydroxide.
  • compositions according to the present invention are suitable for use in diluted form.
  • the expression "use in diluted form” herein includes dilution by the user, which occurs for instance in household application or hand laundry applications, as well as dilution by other means, such as in a washing machine. Typical dilution levels are of from 0.5% to 20% for hand laundry application, 0.1% to 10% in a washing machine, and 0.5 to 20% for household application.
  • the pH of the composition as is changes, i.e. decreases, to a certain pH value which is hereinafter referred to as the pH of the diluted composition.
  • the pH of the diluted composition is buffered to a substantially constant value throughout use, i.e. from the moment the dilution is completed and until the hypochlorite bleaching composition is started to be rinsed away.
  • composition according to the present invention comprise pH buffering means whereby the pH of the diluted composition remains constant throughout use.
  • silicate or carbonate salts or mixtures thereof.
  • Particularly useful are alkali metal salts of silicate and carbonate, preferably sodium silicate and sodium carbonate, both of which are commercially available, or mixtures thereof.
  • the compositions according to the present invention comprise a mixture of sodium carbonate and sodium silicate.
  • the compositions herein comprise from 0.2% to 5% by weight of the total composition of sodium carbonate, preferably from 0.5% to 3%, and from 0.02% to 3% by weight of the total composition of sodium silicate, preferably from 0.04% to 3%.
  • the present invention is based on the finding that the addition of a pH buffering means, preferably a carbonate salt (typically at a level of 0.2% to 5% by weight) and/or a silicate salt (typically at a level of 0.02% to 3% by weight), in an aqueous liquid bleaching composition suitable for use in diluted form, said composition having a pH as is of from 11.5 to 14 and comprising an alkali metal hypochlorite and a bleach stable perfume as defined herein, reduces the chlorine odor during and after use.
  • a pH buffering means preferably a carbonate salt (typically at a level of 0.2% to 5% by weight) and/or a silicate salt (typically at a level of 0.02% to 3% by weight)
  • the compositions according to the present invention comprise a bleach stable perfume, whereby said perfume causes no more than 10% loss of available chlorine in 5 days at 50°c, preferably not more than 8% loss of available chlorine.
  • a bleach stable perfume whereby said perfume causes no more than 10% loss of available chlorine in 5 days at 50°c, preferably not more than 8% loss of available chlorine.
  • most perfume ingredients are incompatible for use in a strong oxidizing environment such as hypochlorite bleaching compositions.
  • the hypochlorite attacks the perfume, resulting not only in the degradation of the perfume but also in the loss of available chlorine, thus bleaching power.
  • Perfumes useful for use herein do not cause loss of available chlorine outside the limits described hereinabove.
  • the capacity of a perfume to meet this criteria is evaluated by comparing a composition with the perfume to a composition without, to account for the loss of available chlorine which is not due to the perfume.
  • the available chlorine is measured in the fresh compositions, i.e. just after they are made, and in the same compositions after 5 days storage at 50 °c, using the method described for instance in "Analyses des Eaux et Extraits de Javel” by Latica syndicalerance de L'eau de Javel et des building connexes, Pages 9-10 (1984). The % loss of available chlorine is then calculated.
  • perfume it is meant herein individual perfume components as well as mixtures thereof.
  • Bleach stable perfumes include components in the class of acetals, aldehydes, esters, alcohols, ketones, ethers, nitriles, terpenes, as well as miscellaneous materials, including materials of natural origin.
  • suitable acetals components include 1,2,3,4,6,7,8-octahydro 2,3,8,8-tetramethyl -2 acetal naphtalene, available from IFF under the trade name Iso E Super®, octane 1,1-dimethoxy acetal, commercially available from Dragoco under the trade name Resedyl Acetal ®, 1,3-dioxane 2,4,6-trimethyl 4-phenyl acetal, commercially available from Dragoco under the trade name Vertacetal ®, 1,3-dioxolane 2-hexyl acetal, commercially available from Dragoco under the trade name Ylamone ®, phenylacetaldehyde dimethyl acetal, aldehyde dimethyl acetal, citral diethyl acetal, and acetaldehyde phenyl ethyl propyl acetal.
  • Suitable perfume components within the class of esters include dihydro terpinyl acetate, tetrahydro linalyl acetate, benzene propanoltrimethyl acetate, commercially available from Dragoco under the trade name Vetikol Acetate ®, ortho tertiary butyl cyclohexanol acetate, ortho tertiary amyl cyclohexanyl acetate, fenchyl acetate, iso bornyl acetate, styrallyl acetate.
  • Suitable perfume components within the class of alcohols include 4-tert-butylcyciohexanol, dihydro terpineol, tetrahydro geraniol, tetrahydro myrcenol, tetrahydro linaleol, fenchyl alcohol, dimethyl octanol, 2,5-dimethyl heptan-2-ol, commercially available from IFF under the trade name Dimetol ®, phenyl methyl ethyl carbinol, dimethyl benzyl carbinol, dimethyl phenyl ethyl carbinol.
  • Suitable perfume components from the class of ketones include menthone, iso menthone racemic, dimethyl octanone, fenchone-1,1,3-trimethyl bicyclo-1,2,2-heptanone 2, benzophenone.
  • Suitable perfume components from the class of ethers include monoterpenes and cyclic monoterpenes ethers, commercially available from Givaudan Roure under the trade name Lime Oxide ®, diphenyl oxide, iso amyl phenyl ethyl ether, paracrasyl methyl ether, phenyl ethyl methyl ether, beta naphtol methyl ether, methyl diphenyl ether.
  • Suitable perfume components in the class of nitriles include 3-cyclopentane 2,2,3-trimethyl 1-acetonitrile, commercially available from Dragoco under the trade name Cantryl ®, bicyclo [2.2.1] heptane-2 carbonitrile, commercially available from Dragoco under the trade name Romaryl ®, 5-phenyl-3-methyl-pentaneacid nitrile, dodecanenitrile, tetrahydro geranyl nitrile.
  • Suitable terpenes as perfume components herein include para cymene and terpinolene.
  • Suitable materials of natural origin include essential oils and resins such as eucalyptus oil, cistus oil, patchouli oil.
  • suitable miscellaneous materials include eucalyptol and 2,4,6-trinitro-3,5-dimethyl-tert-butyl benzene.
  • the compositions according to the present invention typically comprise from 0.000002% to 2% by weight of the total composition of said perfume, preferably from 0.000005% to 0.5 %.
  • compositions according to the present invention further comprise a bleach-stable perfume solubilizer, i.e. a surface active ingredient which helps the homogeneization or solubilization of the perfume in the composition.
  • Suitable bleach-stable perfume solubilizers include amine oxides, alkyl ethoxy methyl carboxylates, alkyl phenyl ethoxy methyl carboxylates, diphenyl oxide sulphonates, sarcosinates, taurates, betaines, quaternary ammoniun salts, sulphates, sulphonates, and mixtures thereof.
  • compositions according to the present invention typically comprise from 0.000001% to 20% by weight of the total composition of a perfume solubilizer, preferably from 0.000002% to 5%.
  • the present invention further encompasses a method of bleaching fabrics which comprises the steps of first contacting said fabrics with an aqueous liquid bleaching composition suitable for use in diluted form, having a pH as is of from 11.5 to 14 and comprising:
  • a composition of pH 13.1 is prepared which contains 5% available chlorine, 0.7% sodium hydroxide, 1% sodium carbonate, 0.02% benzophenone, 0.02% nonyl phenyl ethoxy(7) methyl carboxylate and water up to 100%.
  • the loss of available chlorine is the same with and without benzophenone and amounts to about 14% loss of available chlorine in 5 days at 50°c.
  • Said compositions is used in a method of bleaching fabrics according to the present invention.
  • a composition of pH 13.2 is prepared which contains 5% available chlorine, 0.7% sodium hydroxide, 1% sodium carbonate, 1.0% sodium silicate, 0.03% tetrahydromyrcenol, 0.04% nonyl phenyl ethoxy(7) methyl carboxylate, and water up to 100%.
  • the loss of available chlorine is the same with and without tetrahydromercenol and amounts to about 14% loss of available chlorine in 5 days at 50°C.
  • composition exemplified herein after (example 3 to 6) are designed for use in a method of bleaching fabrics according to the present invention.
  • a composition of pH 13.2 is prepared which contains 5% available chlorine, 0.8% sodium hydroxide, 1% sodium carbonate, 0.03% tetrahydrolynalool, 0.07% nonyl ethoxy(5) methyl carboxylate and water up to 100%.
  • the loss of available chlorine is the same with and without tetrahydrolynalool and amounts to about 16% loss of available chlorine in 5 days at 50°c.
  • a composition of pH 13.0 is prepared which contains 5% available chlorine, 0.7% sodium hydroxide, 1% sodium silicate, 0.03% fenchylacetate, 0.08% nonyl ethoxy(5) methyl carboxylate, and water up to 100%.
  • the loss of available chlorine is the same with and without fenchylacetate and amounts to about 16% loss of available chlorine in 5 days at 50°c.
  • a composition of pH 13.2 is prepared which contains 5% available chlorine, 0.8% sodium hydroxide, 1% sodium carbonate, 0.03% ortho tertiary amyl cyclohexanyl acetate, 0.1% diphenyl oxide, and water up to 100%.
  • the loss of available chlorine is the same with and without fenchylacetate and amounts to about 16% loss of available chlorine in 5 days at 50°c.
  • a composition of pH 13.0 is prepared which contains 5% available chlorine, 0.7% sodium hydroxide, 1% sodium silicate, 0.03% eucaliptol, 0.04% nonyl phenyl ethoxy(7) methyl carboxylate, and water up to 100%.
  • the loss of available chlorine is the same with and without fenchylacetate and amounts to about 16% loss of available chlorine in 5 days at 50°c.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Claims (10)

  1. Composition de blanchiment liquide aqueuse pouvant être utilisée sous forme diluée, ladite composition ayant un pH tel quel de 11,5 à 14 et comprenant:
    un parfum stable vis-à-vis des agents de blanchiment, ledit parfum ne provoquant pas plus de 10% de perte de Cl2 actif en 5 jours à 50°C,
    de 2% à 10%, en poids de la composition totale, d'un hypochlorite de métal alcalin,
    de 0,2% à 5%, en poids de la composition totale, d'un sel carbonate et de 0,02% à 3% en poids d'un sel silicate,
    et dans laquelle ledit parfum stable vis-à-vis des agents de blanchiment est choisi dans le groupe constitué par le 1,2,3,4,6,7,8-octahydro-2,3,8,8-tétraméthyl-2-acétalnaphtalène, l'octane-1,1-diméthoxyacétal, le 1,3-dioxane-2,4,6-triméthyl-4-phénylacétal, le 1,3-dioxolane-2-hexylacétal, le phénylacétaldéhyde-diméthylacétal, l'aldéhyde-diméthylacétal, le citral-diéthylacétal, l'acétaldéhyde, le phényléthylpropylacétal, l'acétate de dihydroterpinyle, l'acétate d'isobornyle, l'acétate de tétrahydrolinalyle, l'acétate de benzènepropanoltriméthyle, l'acétate d'ortho-tert-butylcyclohexanol, l'acétate d'ortho-tert-amylcyclohexanyle, l'acétate de Fenchyle, l'acétate de styrallyle, le 4-tert-butylcyclohexanol, le dihydroterpinéol, le tétrahydrogéraniol, le tétrahydromyrcénol, le tétrahydrolinaléol, l'alcool fenchylique, le diméthyloctanol, le 2,5-diméthylheptan-2-ol, le phénylméthyléthylcarbinol, le diméthylbenzylcarbinol, le diméthylphényléthylcarbinol, la Menthone, l'isomenthone racémique, la diméthyloctanone, la Fenchone-1,1,3-triméthylbicyclo-1,2,2-heptanone-2, la benzophénone, les monoterpènes et les éthers de monoterpénes cycliques, l'oxyde de diphényle, l'isoamylphényléthyléther, le para-crésylméthyléther, le phényléthylméthyléther, l'éther méthylique de β-naphtol, le méthyldiphényléther, le 3-cyclopentane-2,2,3-triméthyl-1-acétonitrile, le bicyclo[2,2,1]heptane-2-carbonitrile, le 5-phényl-3-méthylpentanenitrile acide, le dodécanenitrile, le tétrahydrogéranylnitrile, le para-cymène et le terpinolène, l'eucalyptol, le 2,4,6-trinitro-3,5-diméthyl-tert-butylbenzène, les huiles essentielles et les résines, notamment l'essence d'eucalyptus, l'essence de ciste et l'essence de patchouli, et leurs mélanges.
  2. Composition selon la revendication 1, qui comprend de 3% à 6%, en poids de la composition totale, rapporté au chlore actif, d'hypochlorite.
  3. Composition selon les revendications 1 et 2, dans laquelle ledit parfum ne provoque pas plus de 8% de perte de chlore actif en 5 jours à 50°C.
  4. Composition selon l'une quelconque des revendications précédentes, dans laquelle ledit pH est de 12,5 à 14.
  5. Composition selon l'une quelconque des revendications précédentes, qui comprend de 0,000002% à 2%, de préférence de 0,000005% à 0,5%, en poids de la composition totale, dudit parfum stable vis-à-vis des agents de blanchiment.
  6. Composition selon l'une quelconque des revendications précédentes, qui comprend en outre de 0,000001% à 20%, en poids de la composition totale, d'un solubilisant du parfum, de préférence de 0,000002% à 5%.
  7. Procédé de blanchiment du linge, qui comprend les étapes consistant à:
    mettre d'abord en contact ledit linge avec une composition de blanchiment liquide aqueuse pouvant être utilisée sous forme diluée, ladite composition ayant un pH tel quel de 11,5 à 14 et comprenant:
    un parfum stable vis-à-vis des agents de blanchiment, ledit parfum ne provoquant pas plus de 10% de perte de Cl2 actif en 5 jours à 50°C,
    de 2% à 10%, en poids de la composition totale, d'un hypochlorite de métal alcalin,
    de 0,2% à 5%; en poids de la composition totale, d'un sel carbonate et/ou de 0,02% à 3% en poids d'un sel silicate,
    une quantité, susceptible d'effectuer la solubilisation d'un parfum, d'un tensioactif solubilisant les parfums choisi dans le groupe constitué par les oxydes d'amine, les alkyléthoxyméthylcarboxylates, les alkylphényléthoxyméthylcarboxylates, les diphényloxysulfonates, les sarcosinates, les taurates, les bétaïnes, les sels d'ammonium quaternaire, et leurs mélanges,
    et dans laquelle ledit parfum stable vis-à-vis des agents de blanchiment est choisi dans le groupe constitué par le 1,2,3,4,6,7,8-octahydro-2,3,8,8-tétraméthyl-2-acétalnaphtalène, l'octane-1,1-diméthoxyacétal, le 1,3-dioxane-2,4,6-triméthyl-4-phénylacétal, le 1,3-dioxolane-2-hexylacétal, le phénylacétaldéhyde-diméthylacétal, l'aldéhyde-diméthylacétal, le citraldiéthylacétal, l'acétaldéhyde, le phényléthylpropylacétal, l'acétate de dihydroterpinyle, l'acétate d'isobornyle, l'acétate de tétrahydrolinalyle, l'acétate de benzènepropanoltriméthyle, l'acétate d'ortho-tert-butylcyclohexanol, l'acétate d'ortho-tert-amylcyclohexanyle, l'acétate de Fenchyle, l'acétate de styrallyle, le 4-tert-butylcyclohexanol, le dihydroterpinéol, le tétrahydrogéraniol, le tétrahydromyrcénol, le tétrahydrolinaléol, l'alcool fenchylique, le diméthyloctanol, le 2,5-diméthylheptan-2-ol, le phénylméthyléthylcarbinol, le diméthylbenzylcarbinol, le diméthylphényléthylcarbinol, la Menthone, l'isomenthone racémique, la diméthyloctanone, la Fenchone-1,1,3-triméthylbicyclo-1,2,2-heptanone-2, la benzophénone, les monoterpènes et les éthers de monoterpènes cycliques, l'oxyde de diphényle, l'isoamylphényléthyléther, le para-crésylméthyléther, le phényléthylméthyléther, l'éther méthylique de β-naphtol, le méthyldiphényléther, le 3-cyclopentane-2,2,3-triméthyl-1-acétonitrile, le bicyclo[2.2.1]heptane-2-carbonitrile, le 5-phényl-3-méthylpentanenitrile acide, le dodécanenitrile, le tétrahydrogéranylnitrile, le para-cymène et le terpinolène, l'eucalyptol, le 2,4,6-trinitro-3,5-diméthyl-tert-butylbenzène, les huiles essentielles et les résines, notamment l'essence d'eucalyptus, l'essence de ciste et l'essence de patchouli, et leurs mélanges,
    laisser ensuite le linge en contact avec ladite composition pendant une durée suffisante pour blanchir ledit linge,
    rincer ensuite ledit linge dans de l'eau pour éliminer ladite composition.
  8. Procédé selon la revendication 7, qui comprend en outre l'étape suivante consistant à laver ledit linge avec une composition détergente comprenant au moins un agent tensioactif.
  9. Utilisation, dans une composition de blanchiment liquide aqueuse pouvant être utilisée sous forme diluée, ladite composition ayant un pH tel quel de 11,5 à 14 et comprenant de 2% à 10% en poids dc la composition totale, d'un hypochlorite de métal alcalin et un parfum stable vis-à-vis des agents de blanchiment, ledit parfum ne provoquant pas plus de 10% de perte de Cl2 actif en 5 jours à 50°C, d'un moyen tampon de pH pour réduire l'odeur de chlore pendant et après l'emploi.
  10. Utilisation selon la revendication 9, dans laquelle ledit moyen tampon de pH est un sel carbonate dans une proportion de 0,2% à 5% en poids de la composition totale et/ou un sel silicate dans une proportion de 0,02% à 3% en poids de la composition totale.
EP93870070A 1993-04-26 1993-04-26 Compostions parfumées de blanchiment à l'hypochlorite Revoked EP0622451B1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
ES93870070T ES2127267T3 (es) 1993-04-26 1993-04-26 Composiciones blanqueadoras perfumadas de hipoclorito.
EP98870103A EP0867503A3 (fr) 1993-04-26 1993-04-26 Compositions parfumées de blanchiment à l'hypochlorite
DE69322375T DE69322375T2 (de) 1993-04-26 1993-04-26 Parfümierte Hypochloritbleichmittel
DK93870070T DK0622451T3 (da) 1993-04-26 1993-04-26 Parfumerede hypochlorit-blegesammensætninger
AT93870070T ATE174054T1 (de) 1993-04-26 1993-04-26 Parfümierte hypochloritbleichmittel
EP93870070A EP0622451B1 (fr) 1993-04-26 1993-04-26 Compostions parfumées de blanchiment à l'hypochlorite

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP93870070A EP0622451B1 (fr) 1993-04-26 1993-04-26 Compostions parfumées de blanchiment à l'hypochlorite

Related Child Applications (1)

Application Number Title Priority Date Filing Date
EP98870103A Division EP0867503A3 (fr) 1993-04-26 1993-04-26 Compositions parfumées de blanchiment à l'hypochlorite

Publications (2)

Publication Number Publication Date
EP0622451A1 EP0622451A1 (fr) 1994-11-02
EP0622451B1 true EP0622451B1 (fr) 1998-12-02

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Family Applications (2)

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EP93870070A Revoked EP0622451B1 (fr) 1993-04-26 1993-04-26 Compostions parfumées de blanchiment à l'hypochlorite
EP98870103A Withdrawn EP0867503A3 (fr) 1993-04-26 1993-04-26 Compositions parfumées de blanchiment à l'hypochlorite

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP98870103A Withdrawn EP0867503A3 (fr) 1993-04-26 1993-04-26 Compositions parfumées de blanchiment à l'hypochlorite

Country Status (5)

Country Link
EP (2) EP0622451B1 (fr)
AT (1) ATE174054T1 (fr)
DE (1) DE69322375T2 (fr)
DK (1) DK0622451T3 (fr)
ES (1) ES2127267T3 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7067153B2 (en) 2000-09-25 2006-06-27 Cognis France S.A. Microcapsule powder
EP2179748A1 (fr) 2008-10-27 2010-04-28 The Procter & Gamble Système de désodorisation
EP2179747A1 (fr) 2008-10-27 2010-04-28 The Procter & Gamble Company Procédé pour réduire les mauvaises odeurs

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0743391A1 (fr) * 1995-05-16 1996-11-20 The Procter & Gamble Company Procédé de blanchiment des tissus
DE69528185D1 (de) 1995-12-22 2002-10-17 Procter & Gamble Hypochloritbleichmittelzusammensetzungen
DE19700799C2 (de) * 1997-01-13 1999-02-04 Henkel Kgaa Wäßrige Textilbleichmittel
EP0867501A1 (fr) * 1997-03-27 1998-09-30 The Procter & Gamble Company Compositions de blanchiment
US5939368A (en) * 1997-10-08 1999-08-17 Firmenich Sa Use of 1-methoxy-2-methyl-3-phenylpropane, 1-(2-methoxypropyl)-4-methylbenzene and 3-methoxy-2,2,3-trimethyl-1-phenylbutane in perfumery
WO1999058635A1 (fr) * 1998-05-08 1999-11-18 Henkel Kommanditgesellschaft Auf Aktien Agents de blanchiment et de desinfection
DE19855329A1 (de) 1998-12-01 2000-06-08 Henkel Kgaa Aktivchlorhaltige Zubereitungen mit stabilisierten optischen Aufhellern
DE19855347C1 (de) * 1998-12-01 2000-09-21 Henkel Kgaa Aktivchlorhaltige Zubereitungen mit stabilisierten Duftstoffen
ES2213948T3 (es) 1999-07-02 2004-09-01 Cognis Iberia, S.L. Microcapsulas ii.
ATE258417T1 (de) 1999-07-02 2004-02-15 Cognis Iberia Sl Mikrokapseln - i
ES2247749T3 (es) 1999-07-02 2006-03-01 Cognis Ip Management Gmbh Microcapsulas iii.
EP1064910B1 (fr) 1999-07-02 2005-09-14 Cognis IP Management GmbH Microcapsules
US6824705B1 (en) * 2003-05-19 2004-11-30 Colgate-Palmolive Co. Bleach odor reducing composition
DE102005062008B3 (de) 2005-12-22 2007-08-30 Henkel Kgaa Geruchsreduktion hypochlorithaltiger Mittel
DE102005063177A1 (de) 2005-12-30 2007-07-05 Henkel Kgaa Erhöhung der Stabilität hypochlorihaltiger Waschmittel
DE102007034539A1 (de) * 2007-07-20 2009-01-22 Henkel Ag & Co. Kgaa Schonendes Bleichmittel
US10465149B2 (en) 2016-03-02 2019-11-05 Harris Research, Inc. Stain and odor treatment
JP6781866B2 (ja) * 2018-01-12 2020-11-11 加地貿易 株式会社 塩素系洗浄剤の残り香における塩素臭の消臭剤及び清掃方法

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NL7908798A (nl) * 1979-12-05 1981-07-01 Unilever Nv Vloeibaar, verdikt chloorbleekmiddel.
GB2076010B (en) * 1980-05-13 1984-05-16 Sandoz Products Ltd Bleach composition
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EP0186386B1 (fr) * 1984-12-28 1992-03-04 The Procter & Gamble Company Composition de blanchiment liquide d'hypochlorite contenant des azurants optiques dissous dans de l'amine oxide
GB8513293D0 (en) * 1985-05-28 1985-07-03 Procter & Gamble Ntc Ltd Cleaning compositions
JPS62205199A (ja) * 1986-03-03 1987-09-09 花王株式会社 安定な液体漂白剤組成物

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7067153B2 (en) 2000-09-25 2006-06-27 Cognis France S.A. Microcapsule powder
EP2179748A1 (fr) 2008-10-27 2010-04-28 The Procter & Gamble Système de désodorisation
EP2179747A1 (fr) 2008-10-27 2010-04-28 The Procter & Gamble Company Procédé pour réduire les mauvaises odeurs

Also Published As

Publication number Publication date
DK0622451T3 (da) 1999-08-16
EP0867503A2 (fr) 1998-09-30
ATE174054T1 (de) 1998-12-15
DE69322375D1 (de) 1999-01-14
EP0622451A1 (fr) 1994-11-02
DE69322375T2 (de) 1999-06-24
EP0867503A3 (fr) 1999-01-20
ES2127267T3 (es) 1999-04-16

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