DE930287C - Process for the preparation of interpolymerization products - Google Patents
Process for the preparation of interpolymerization productsInfo
- Publication number
- DE930287C DE930287C DEA11932D DEA0011932D DE930287C DE 930287 C DE930287 C DE 930287C DE A11932 D DEA11932 D DE A11932D DE A0011932 D DEA0011932 D DE A0011932D DE 930287 C DE930287 C DE 930287C
- Authority
- DE
- Germany
- Prior art keywords
- unsaturated
- preparation
- interpolymerization
- products
- interpolymerization products
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 5
- 229920000180 alkyd Polymers 0.000 claims description 10
- 229920000570 polyether Polymers 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- 229910000831 Steel Inorganic materials 0.000 claims 1
- 239000010959 steel Substances 0.000 claims 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241001643597 Evas Species 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Polyesters Or Polycarbonates (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
Verfahren zur Herstellung von Interpolymerisationsprodukten Die Erfindung betrifft ein Verfahren zur Herstellung von Interpolymerisationsprodukten aus wenigstens einem polymerisierbaren Ester eines mehrwertigen Alkohols und einer a-ungesättigten, a, P-Polyrarbonsäure (nacbs.tebend kurz »ungesättigtes Alkyd'harz« genannt) mit Polyäthern, die sieh mit dem ungesättigten Alkydharz vertragen.Process for making interpolymerization products The invention relates to a process for the preparation of interpolymerization products from at least a polymerizable ester of a polyhydric alcohol and an α-unsaturated, a, P-polyrarboxylic acid (hereinafter referred to as "unsaturated alkyd resin" for short) with Polyethers that are compatible with the unsaturated alkyd resin.
Die Polyäther lassen sich von der allgemeinen Formel ableiten, in der R Wasserstoff oder ein Alkylradial bedeutet. An Stelle der ungesättigten Alkydharze als einer Komponente für die Herstellung der Interpolymeri.sationsp.rodukte können auch modifizierte Alkydbarze verwendet werden., wie sie z. B. erhalten werden aus einem mehrwertigen Alkohol und einer a-ungesättigten, a, ß-Pälycarbonsäu:re mit einer veresterbaren Monoxyverbindung, wie z. B. einem einwertigen Alkohol oder einer Monocarbonsäure, oder auch aus mehrwertigem Alkohol und einer a-ungesättigten, a, ß-Polycarbonsäure mit einer gesättigten Polycarbonsäure oder deren Anhydrid, wie z. B. Bernsteinsäure oder Phthal@säu,reanbydrid.The polyethers can be derived from the general formula derive, in which R is hydrogen or an alkyl radical. Instead of the unsaturated alkyd resins as a component for the production of the interpolymerization products, modified alkyd resins can also be used, as are e.g. B. obtained from a polyhydric alcohol and an a-unsaturated, a, ß-Pälycarbonsäu: re with an esterifiable monoxy compound, such as. B. a monohydric alcohol or a monocarboxylic acid, or from polyhydric alcohol and an α-unsaturated, α, ß-polycarboxylic acid with a saturated polycarboxylic acid or its anhydride, such as. B. succinic acid or phthalic acid, reanbydride.
Diie Pol'ymerisation kann in Anwesenheit eines Katalysators erfolgen, der sich in einem Polyäther leicht auflösen oder dispergieren läßt, oder ohne einen solchen. Die Polymerisation wird vorzugsweise bei 6o bis i2o° durchgeführt, doch :ist die Anwendung anderer Temperaturen, z. B. von 2o bis i30°, nicht ausgeschlossen.The polymerization can take place in the presence of a catalyst, which is in a polyether easy to dissolve or disperse, or without one. The polymerization is preferably carried out at 6o to 12o °, but: is the use of other temperatures, z. B. from 2o to i30 °, not excluded.
Die Interpolymerisationsprodukte ,gemäß der Erfindung sind als lösungsmi.ttelfreie Lacke verwend-* bar, die z. B. als Klebmittel für Schichtstoffe und insbesondere zur Herstellung von Grlimmerschichtprodukten dienen können. Sie lassen sich aber auch gießen, spritzen oder pressen, Evas mit den ungesättigten Alkydharzen allein nicht möglich Ist.The interpolymerization products according to the invention are free from solvents Paints usable * that z. B. as an adhesive for laminates and in particular can serve for the production of Grimerschicht products. But you can also pour, inject or press, Evas with the unsaturated alkyd resins alone not possible.
Beispiel i8 Tei,le eines ungesättigten Alkyd:harzes aus Itakonsäure und Äthylenglykol werden mit 2 Teilen Diallyläther, in dem o,2 Teile Benzodperoxyd gelöst send, gemischt und 6o Stunden auf 65° erwärmt. I)a's erhaltene Interpolymeri'sätionsprodukt ist hart, durchsichtig, unlöslich und unschmelzbar und fast farblos.Example 18 parts of an unsaturated alkyd resin from itaconic acid and ethylene glycol are mixed with 2 parts of diallyl ether, in which o, 2 parts of benzodperoxide dissolved, mixed and heated to 65 ° for 60 hours. I) a's interpolymerization product obtained is hard, transparent, insoluble and infusible and almost colorless.
Claims (2)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US930287XA | 1939-10-31 | 1939-10-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE930287C true DE930287C (en) | 1955-07-14 |
Family
ID=22236450
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEA11932D Expired DE930287C (en) | 1939-10-31 | 1940-11-01 | Process for the preparation of interpolymerization products |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE930287C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1254362B (en) * | 1961-06-05 | 1967-11-16 | Pittsburgh Plate Glass Co | Process for the production of copolymers |
-
1940
- 1940-11-01 DE DEA11932D patent/DE930287C/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1254362B (en) * | 1961-06-05 | 1967-11-16 | Pittsburgh Plate Glass Co | Process for the production of copolymers |
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