DE880817C - Metal phosphide paste for combating pests, especially rodents - Google Patents
Metal phosphide paste for combating pests, especially rodentsInfo
- Publication number
- DE880817C DE880817C DER1981D DER0001981D DE880817C DE 880817 C DE880817 C DE 880817C DE R1981 D DER1981 D DE R1981D DE R0001981 D DER0001981 D DE R0001981D DE 880817 C DE880817 C DE 880817C
- Authority
- DE
- Germany
- Prior art keywords
- paste
- metal phosphide
- combating pests
- especially rodents
- phosphide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002184 metal Substances 0.000 title claims description 8
- 229910052751 metal Inorganic materials 0.000 title claims description 8
- 241000607479 Yersinia pestis Species 0.000 title claims description 4
- 241000283984 Rodentia Species 0.000 title claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 229940099259 vaseline Drugs 0.000 claims description 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 239000012876 carrier material Substances 0.000 claims 1
- -1 vaseline Chemical class 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000000126 substance Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 235000013575 mashed potatoes Nutrition 0.000 description 2
- 229920001817 Agar Polymers 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 241000206672 Gelidium Species 0.000 description 1
- 241000700159 Rattus Species 0.000 description 1
- 239000006011 Zinc phosphide Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 235000010419 agar Nutrition 0.000 description 1
- 230000027455 binding Effects 0.000 description 1
- 238000009739 binding Methods 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 210000000936 intestine Anatomy 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- HOKBIQDJCNTWST-UHFFFAOYSA-N phosphanylidenezinc;zinc Chemical compound [Zn].[Zn]=P.[Zn]=P HOKBIQDJCNTWST-UHFFFAOYSA-N 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 235000015277 pork Nutrition 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
- 229940048462 zinc phosphide Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/26—Phosphorus; Compounds thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Inorganic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
Zur Bekämpfung von Schädlingen, insbesondere Nagetieren, haben sich Metallphosphidverbindungen als ausgezeichnet wirksam erwiesen. Es genügt die Aufnahme einer verhältnismäßig kleinen Menge, um den Schädling mit Sicherheit abzutöten. Hauptsächlich wird Zinkphosphid für diese Zwecke verwendet. Ein Nachteil der Metallphosphidverbin'-dungen ist ihre leichte Zersetzbarkeit durch Säuren, Laugen und selbst durch Wasser. Die Metallphosphide können deshalb nur in Verbindung mit trockenen Köderstoffen·, wie z. B. Getreide, verwendet werden.To control pests, especially rodents, metal phosphide compounds have been used Proven to be extremely effective. It is sufficient to take in a relatively small amount to kill the pest with certainty. Mainly zinc phosphide is used for these purposes. A disadvantage of the metal phosphide compounds is their easy decomposability by acids, Alkalis and even water. The metal phosphides can therefore only be used in conjunction with dry bait substances, such as B. cereals can be used.
Für bestimmte große Anwendungsgebiete, z. B. zur Ratten-, Wühlmaus- und Werrenbekämpfung, ist jedoch die Verwendung einer streichbaren Paste erforderlich, die auch in Verbindung mit nassen Köderstoffen, z. B. Kartoffelbrei, frischen Rüben usw., gebraucht werden kann.For certain large areas of application, e.g. B. to control rats, vole and advertising, however, the use of a spreadable paste is required, also in conjunction with wet Bait substances, e.g. B. mashed potatoes, fresh beets, etc., can be used.
Die Herstellung einer solchen haltbaren Paste stößt wegen der Zersetzlichkeit der Metallphosphide auf Schwierigkeiten. Die Verwendung von wasserhaltigen, plastischen Stoffen, ζ. Β. Agar-Agar, Methylcellulose, verbietet sich, da das Phosphid in einer solchen; Paste sich zersetzt. Auch die Verwendung reiner Fette, z. B. Schweinefett, führt nicht zum Erfolg, da bereits der geringe Wassergehalt und die bei längerem Lagern entstehenden Fettsauren das Metallphosphid zersetzen.The manufacture of such a durable paste is uncomfortable because of the decomposability of the metal phosphides on difficulties. The use of water-based, plastic materials, ζ. Β. Agar-agar, methyl cellulose, Prohibited as the phosphide in such a; Paste decomposes. Also the use pure fats, e.g. B. pork fat, does not lead to success, since the low water content and the fatty acids formed during prolonged storage decompose the metal phosphide.
Es wurde gefunden, daß als Trägerstoff für Metallphosphidpasten hochmolekulare Kohlenwasserstoffe, wie z. B. Vaseline, geeignet sind. Obwohl man erwarten sollte, daß solche indifferenten Ver-It has been found that, as a carrier for metal phosphide pastes, high molecular weight hydrocarbons, such as B. Vaseline are suitable. Although one should expect that such indifferent
bindungen, die den Darm unzersetzt passieren und sogar noch als Gleitmittel wirken, die Einwirkung des Giftstoffes weitgehend verhindern würden, zeigte sich überraschenderweise, daß die Abtötung trotzdem rasch und sicher, auch bei Aufnahme von kleinen Mengen der Giftpaste, eintritt. Die Wirkung wird auch bei Verwendung von wasserhaltigen Köderstoffen, z.B. Kartoffelbrei, erzielt, wobei hier die hochmolekularen Kohlenwasserstoffe in idealer Weise das empfindliche Zirikphosphid vor dem Einfluß des Wassers schützen.bindings that pass through the intestine undecomposed and even act as lubricants are affected of the toxin would largely prevent, it was surprisingly found that the destruction nevertheless occurs quickly and safely, even if small amounts of the poisonous paste are absorbed. The effect is also obtained when using water-based Bait substances, e.g. mashed potatoes, achieved, with the high molecular weight hydrocarbons in ideal Way to protect the sensitive Zirikphosphid from the influence of water.
Die nach diesem Verfahren hergestellte Paste läßt sich daher ohne weiteres in Verbindung mit allen in Frage kommenden Ködern verwenden.The paste produced by this process can therefore be easily combined with use all bait in question.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DER1981D DE880817C (en) | 1944-11-15 | 1944-11-15 | Metal phosphide paste for combating pests, especially rodents |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DER1981D DE880817C (en) | 1944-11-15 | 1944-11-15 | Metal phosphide paste for combating pests, especially rodents |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE880817C true DE880817C (en) | 1953-06-25 |
Family
ID=7395775
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DER1981D Expired DE880817C (en) | 1944-11-15 | 1944-11-15 | Metal phosphide paste for combating pests, especially rodents |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE880817C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1122762B (en) * | 1960-03-31 | 1962-01-25 | Deutsche Ges Schaedlingsbek | Moisture-protected metal phosphide for pest control and process for its production |
| EP0643556A4 (en) * | 1992-06-05 | 1997-07-16 | Commw Scient Ind Res Org | Formulations, method and apparatus for the controlled generation of phosphine. |
| US6440390B2 (en) | 1992-06-05 | 2002-08-27 | Commonwealth Scientific And Industrial Research Organisation | Formulations containing a phosphide for use in the controlled generation of phosphine |
-
1944
- 1944-11-15 DE DER1981D patent/DE880817C/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1122762B (en) * | 1960-03-31 | 1962-01-25 | Deutsche Ges Schaedlingsbek | Moisture-protected metal phosphide for pest control and process for its production |
| EP0643556A4 (en) * | 1992-06-05 | 1997-07-16 | Commw Scient Ind Res Org | Formulations, method and apparatus for the controlled generation of phosphine. |
| RU2131190C1 (en) * | 1992-06-05 | 1999-06-10 | Коммонвелт Сайнтифик энд Индастриал Рисерч Организейшн | Composition useful in phosphine production, method and apparatus for controlled phosphine production, phosphide composition packed in moistureproof wrapping, and apparatus for fumigation gas production |
| US6440390B2 (en) | 1992-06-05 | 2002-08-27 | Commonwealth Scientific And Industrial Research Organisation | Formulations containing a phosphide for use in the controlled generation of phosphine |
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