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DE69916884D1 - Verzweigte alkyl-aromatische sulfonsäure-dispersionsmittel zur lösung von asphaltenen in mineralölen - Google Patents

Verzweigte alkyl-aromatische sulfonsäure-dispersionsmittel zur lösung von asphaltenen in mineralölen

Info

Publication number
DE69916884D1
DE69916884D1 DE69916884T DE69916884T DE69916884D1 DE 69916884 D1 DE69916884 D1 DE 69916884D1 DE 69916884 T DE69916884 T DE 69916884T DE 69916884 T DE69916884 T DE 69916884T DE 69916884 D1 DE69916884 D1 DE 69916884D1
Authority
DE
Germany
Prior art keywords
sulfonic acid
branched alkyl
asphaltes
solving
mineral oils
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69916884T
Other languages
English (en)
Other versions
DE69916884T2 (de
Inventor
Andrew Wiehe
Ramesh Varadaraj
G Jermansen
John Kennedy
Hendrick Brons
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
ExxonMobil Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Research and Engineering Co filed Critical ExxonMobil Research and Engineering Co
Application granted granted Critical
Publication of DE69916884D1 publication Critical patent/DE69916884D1/de
Publication of DE69916884T2 publication Critical patent/DE69916884T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/29—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of non-condensed six-membered aromatic rings
    • C07C309/30—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of non-condensed six-membered aromatic rings of six-membered aromatic rings substituted by alkyl groups
    • C07C309/31—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of non-condensed six-membered aromatic rings of six-membered aromatic rings substituted by alkyl groups by alkyl groups containing at least three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/33—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of six-membered aromatic rings being part of condensed ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/33—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of six-membered aromatic rings being part of condensed ring systems
    • C07C309/34—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of six-membered aromatic rings being part of condensed ring systems formed by two rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/33—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of six-membered aromatic rings being part of condensed ring systems
    • C07C309/34—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of six-membered aromatic rings being part of condensed ring systems formed by two rings
    • C07C309/35—Naphthalene sulfonic acids
    • C07C309/36—Naphthalene sulfonic acids substituted by alkyl groups
    • C07C309/37—Naphthalene sulfonic acids substituted by alkyl groups by alkyl groups containing at least three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2431—Organic compounds containing sulfur, selenium and/or tellurium sulfur bond to oxygen, e.g. sulfones, sulfoxides
    • C10L1/2437—Sulfonic acids; Derivatives thereof, e.g. sulfonamides, sulfosuccinic acid esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2462—Organic compounds containing sulfur, selenium and/or tellurium macromolecular compounds
    • C10L1/2475—Organic compounds containing sulfur, selenium and/or tellurium macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon to carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04—One of the condensed rings being a six-membered aromatic ring
    • C07C2602/10—One of the condensed rings being a six-membered aromatic ring the other ring being six-membered, e.g. tetraline
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/02—Ortho- or ortho- and peri-condensed systems
    • C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
    • C07C2603/22—Ortho- or ortho- and peri-condensed systems containing three rings containing only six-membered rings
    • C07C2603/26—Phenanthrenes; Hydrogenated phenanthrenes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
    • Y10S516/905—Agent composition per se for colloid system making or stabilizing, e.g. foaming, emulsifying, dispersing, or gelling
    • Y10S516/909—The agent contains organic compound containing sulfoxy*

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Working-Up Tar And Pitch (AREA)
  • Lubricants (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
DE69916884T 1998-12-01 1999-11-23 Verzweigte alkyl-aromatische sulfonsäure-dispersionsmittel zur lösung von asphaltenen in mineralölen Expired - Lifetime DE69916884T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/203,141 US6048904A (en) 1998-12-01 1998-12-01 Branched alkyl-aromatic sulfonic acid dispersants for solublizing asphaltenes in petroleum oils
US203141 1998-12-01
PCT/US1999/027772 WO2000032546A1 (en) 1998-12-01 1999-11-23 Branched alkyl-aromatic sulfonic acid dispersants for solubilizing asphaltenes in petroleum oils

Publications (2)

Publication Number Publication Date
DE69916884D1 true DE69916884D1 (de) 2004-06-03
DE69916884T2 DE69916884T2 (de) 2005-04-07

Family

ID=22752686

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69916884T Expired - Lifetime DE69916884T2 (de) 1998-12-01 1999-11-23 Verzweigte alkyl-aromatische sulfonsäure-dispersionsmittel zur lösung von asphaltenen in mineralölen

Country Status (9)

Country Link
US (1) US6048904A (de)
EP (1) EP1135354B1 (de)
JP (1) JP2002531591A (de)
AT (1) ATE265406T1 (de)
AU (1) AU756901B2 (de)
CA (1) CA2355196C (de)
DE (1) DE69916884T2 (de)
ES (1) ES2220134T3 (de)
WO (1) WO2000032546A1 (de)

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WO2001096503A2 (de) * 2000-06-15 2001-12-20 Clariant International Ltd Additive zur verbesserung von kaltfliesseigenschaften und lagerstabilität von rohölen
US6489368B2 (en) * 2001-03-09 2002-12-03 Exxonmobil Research And Engineering Company Aromatic sulfonic acid demulsifier for crude oils
US20040232051A1 (en) * 2001-03-09 2004-11-25 Ramesh Varadaraj Low viscosity hydrocarbon oils by sonic treatment
CN100516454C (zh) * 2001-07-31 2009-07-22 帝国大学改革有限公司 控制流体中沥青质沉淀的方法
DE10163244A1 (de) * 2001-12-21 2003-07-10 Cognis Deutschland Gmbh Verwendung von sulfierten Alkylphenolformaldehyden zur Stabilisierung von Asphaltenen in Rohöl
US20050279673A1 (en) * 2003-05-16 2005-12-22 Eppig Christopher P Delayed coking process for producing free-flowing coke using an overbased metal detergent additive
WO2004104139A1 (en) * 2003-05-16 2004-12-02 Exxonmobil Research And Engineering Company Delayed coking process for producing free-flowing shot coke
US7645375B2 (en) * 2003-05-16 2010-01-12 Exxonmobil Research And Engineering Company Delayed coking process for producing free-flowing coke using low molecular weight aromatic additives
US7658838B2 (en) * 2003-05-16 2010-02-09 Exxonmobil Research And Engineering Company Delayed coking process for producing free-flowing coke using polymeric additives
JP2007537343A (ja) * 2004-05-14 2007-12-20 エクソンモービル　リサーチ　アンド　エンジニアリング　カンパニー コーカードラムからの取り出しがより容易なコークスを製造するための原料残油のブレンディング
US7704376B2 (en) * 2004-05-14 2010-04-27 Exxonmobil Research And Engineering Company Fouling inhibition of thermal treatment of heavy oils
MXPA06011746A (es) * 2004-05-14 2007-01-16 Exxonmobil Res & Eng Co La produccion de coque de flujo substancialmente libre de un corte mas profundo de residuo de vacio en coquificacion retrasada.
US7727382B2 (en) * 2004-05-14 2010-06-01 Exxonmobil Research And Engineering Company Production and removal of free-flowing coke from delayed coker drum
BRPI0510984A (pt) * 2004-05-14 2007-12-04 Exxonmobil Res & Eng Co método para o melhoramento das propriedades de escoamento de uma carga de alimentação de óleo pesado por diminuição do seu módulo elástico, e, método de coqueificação retardado
US7901564B2 (en) * 2006-08-21 2011-03-08 Exxonmobil Research & Engineering Company Mitigation of refinery process unit fouling using high-solvency-dispersive-power (HSDP) resid fractions
US7837855B2 (en) * 2006-08-21 2010-11-23 Exxonmobil Research & Engineering Company High-solvency-dispersive-power (HSDP) crude oil blending for fouling mitigation and on-line cleaning
US7833407B2 (en) * 2006-08-21 2010-11-16 Exxonmobil Research & Engineering Company Method of blending high TAN and high SBN crude oils and method of reducing particulate induced whole crude oil fouling and asphaltene induced whole crude oil fouling
US20080047874A1 (en) * 2006-08-23 2008-02-28 Exxonmobil Research And Engineering Company Crude oil blending to reduce organic-based fouling of pre-heat train exchangers and furnaces
CO5930079A1 (es) * 2006-12-06 2008-06-27 Ecopetrol Sa Aditivos anti-gomas, antiensuciante y dispersantes de asfalto y procedimiento para su obtencion
US8440069B2 (en) * 2007-08-06 2013-05-14 Exxonmobil Research And Engineering Company Methods of isolating and using components from a high solvency dispersive power (HSDP) crude oil
US8062504B2 (en) * 2007-08-06 2011-11-22 Exxonmobil Research & Engineering Company Method for reducing oil fouling in heat transfer equipment
US7871510B2 (en) * 2007-08-28 2011-01-18 Exxonmobil Research & Engineering Co. Production of an enhanced resid coker feed using ultrafiltration
US7794587B2 (en) * 2008-01-22 2010-09-14 Exxonmobil Research And Engineering Company Method to alter coke morphology using metal salts of aromatic sulfonic acids and/or polysulfonic acids
US8425761B2 (en) * 2008-12-11 2013-04-23 Exxonmobil Research And Engineering Company Non-high solvency dispersive power (non-HSDP) crude oil with increased fouling mitigation and on-line cleaning effects
US9255043B2 (en) * 2011-08-31 2016-02-09 Chevron Oronite Company Llc Liquid crude hydrocarbon composition
US9120978B2 (en) 2012-02-24 2015-09-01 Baker Hughes Incorporated Exfoliation of asphaltenes for improved recovery of unconventional oils
US9017546B2 (en) 2012-06-19 2015-04-28 Baker Hughes Incorporated Exfoliation of asphaltenes
US9012377B2 (en) 2012-12-31 2015-04-21 Baker Hughes Incorporated Functionalized silicate nanoparticle composition, removing and exfoliating asphaltenes with same
US9683163B2 (en) 2012-12-31 2017-06-20 Baker Hughes Incorporated Functionalized silicate nanoparticle composition, removing and exfoliating asphaltenes with same
EP2940104B1 (de) 2014-03-31 2022-01-05 INDIAN OIL CORPORATION Ltd. Flüssigphasenadditiv zur verwendung in thermischen crackverfahren zur verbesserung der produktausbeute
MX368309B (es) 2014-12-11 2019-09-26 Mexicano Inst Petrol Liquidos zwitterionicos geminales base hidroxipropil betaina, proceso de obtencion y uso como modificadores de la mojabilidad con propiedades inhibitorias/dispersantes de asfaltenos.
CA2982344A1 (en) * 2015-03-17 2016-09-22 Baker Hughes, A Ge Company, Llc Functionalized silicate nanoparticle composition, removing and exfoliating asphaltenes with same
EP3795661B1 (de) * 2019-09-17 2022-03-09 Infineum International Limited Asphaltensolvatisierungs- und -dispersionsverfahren
EP3795660B1 (de) * 2019-09-17 2022-03-09 Infineum International Limited Bewuchshemmerverfahren für raffinerie
US20250163312A1 (en) * 2023-11-17 2025-05-22 Baker Hughes Oilfield Operations Llc Method of improving injection pressure and asphaltene remediation
CN117285708B (zh) * 2023-11-24 2024-01-30 西南石油大学 沥青质分散稳定剂及其制备方法

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GB2235203B (en) * 1989-08-25 1992-06-17 Sandoz Ltd Sulpho group-containing aromatic compounds,their production and use
DE4018873A1 (de) * 1990-06-13 1991-12-19 Basf Ag Verwendung von kondensaten auf basis von arylsulfonsaeuren und formaldehyd als dispergiermittel
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US5202056A (en) * 1991-12-30 1993-04-13 Texaco Inc. Composition of matter for oligomeric aliphatic ethers as asphaltene dispersants

Also Published As

Publication number Publication date
DE69916884T2 (de) 2005-04-07
EP1135354A1 (de) 2001-09-26
US6048904A (en) 2000-04-11
EP1135354A4 (de) 2002-02-06
EP1135354B1 (de) 2004-04-28
CA2355196A1 (en) 2000-06-08
AU1919600A (en) 2000-06-19
ES2220134T3 (es) 2004-12-01
WO2000032546A1 (en) 2000-06-08
ATE265406T1 (de) 2004-05-15
AU756901B2 (en) 2003-01-23
JP2002531591A (ja) 2002-09-24
CA2355196C (en) 2008-12-23

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