DE60309874D1 - Malonsäuerenitril-verbindungen und ihre verwendung als pestizide - Google Patents
Malonsäuerenitril-verbindungen und ihre verwendung als pestizideInfo
- Publication number
- DE60309874D1 DE60309874D1 DE60309874T DE60309874T DE60309874D1 DE 60309874 D1 DE60309874 D1 DE 60309874D1 DE 60309874 T DE60309874 T DE 60309874T DE 60309874 T DE60309874 T DE 60309874T DE 60309874 D1 DE60309874 D1 DE 60309874D1
- Authority
- DE
- Germany
- Prior art keywords
- malonsauerenitrile
- pesticides
- compounds
- malonsauerenitrile compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/84—Nitriles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/54—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/57—Nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/61—Halogen atoms or nitro radicals
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002208059 | 2002-07-17 | ||
| JP2002208059 | 2002-07-17 | ||
| PCT/JP2003/008579 WO2004006677A1 (en) | 2002-07-17 | 2003-07-07 | Malononitrile compounds and their use as pesticides |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60309874D1 true DE60309874D1 (de) | 2007-01-04 |
| DE60309874T2 DE60309874T2 (de) | 2007-03-15 |
Family
ID=30112836
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60309874T Expired - Lifetime DE60309874T2 (de) | 2002-07-17 | 2003-07-07 | Malonsäuerenitril-verbindungen und ihre verwendung als pestizide |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US7026340B2 (de) |
| EP (1) | EP1521528B1 (de) |
| CN (1) | CN100343233C (de) |
| AR (1) | AR040557A1 (de) |
| AT (1) | ATE345683T1 (de) |
| AU (1) | AU2003281174A1 (de) |
| BR (1) | BR0312638A (de) |
| DE (1) | DE60309874T2 (de) |
| ES (1) | ES2276090T3 (de) |
| IL (1) | IL165588A (de) |
| SA (1) | SA03240207B1 (de) |
| WO (1) | WO2004006677A1 (de) |
Families Citing this family (88)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005063694A1 (en) | 2003-12-26 | 2005-07-14 | Sumitomo Chemical Company, Limited | Nitrile compound and its use in pest control |
| CN1910147B (zh) | 2004-01-16 | 2011-04-20 | 住友化学株式会社 | 丙二腈化合物及其用途 |
| DE602005004040T2 (de) * | 2004-01-16 | 2008-12-11 | Sumitomo Chemical Co., Ltd. | Malononitrilverbindungen als Pestizide |
| RU2347779C2 (ru) | 2004-01-16 | 2009-02-27 | Сумитомо Кемикал Компани, Лимитед | Соединение малононитрила в качестве пестицида для борьбы с вредителями сельского хозяйства |
| MY146405A (en) | 2005-03-01 | 2012-08-15 | Basf Ag | Fast-release microcapsule products |
| SI1904475T1 (sl) | 2005-07-07 | 2011-12-30 | Basf Se | N-tio-antranilamidne spojine in njihova uporaba kot pesticidi |
| EP1912958A1 (de) * | 2005-08-05 | 2008-04-23 | Basf Se | Substituierte malonsäurenitrilverbindungen zur bekämpfung tierischer schädlinge |
| US20090270259A1 (en) * | 2005-09-23 | 2009-10-29 | Basf Se | Novel Agrochemical Formulations |
| EP1973404B1 (de) | 2005-12-22 | 2015-10-28 | Merial, Inc. | Malonsäuredinitrilverbindungen |
| EP2044008A1 (de) | 2006-06-22 | 2009-04-08 | Basf Se | Malonsäuredinitrilverbindungen |
| CN103931612A (zh) | 2006-09-14 | 2014-07-23 | 巴斯夫欧洲公司 | 杀虫剂组合物 |
| BRPI0718717A2 (pt) | 2006-11-10 | 2013-11-26 | Basf Se | Modificação cristalina ii de fipronil, fipronil sólido, processo para preparar a modificação cristalina ii, mistura pesticida ou parasiticida sinergística, composição pesticida ou parasiticida, uso da modificação cristalina ii, ou do fipronil sólido, ou da mistura, ou da composição, métodos para controlar pragas, para proteger uma planta da infestação e ataque por pragas, para proteger semente, e para tratar, controlar, prevenir ou proteger animais contra infestação ou infecção por parasitas, semente, uso da modificação cristalina ii, ou do fipronil sólido, ou da mistura, ou da composição, e, processo para a preparação de uma composição para trtar, controlar, prevenir ou proteger animais contra infestação ou infecção por parasitas |
| PL2083629T5 (pl) | 2006-11-10 | 2016-03-31 | Basf Se | Krystaliczna odmiana fipronilu |
| UA110598C2 (uk) | 2006-11-10 | 2016-01-25 | Басф Се | Спосіб одержання кристалічної модифікації фіпронілу |
| EA018341B1 (ru) | 2006-11-10 | 2013-07-30 | Басф Се | Новая кристаллическая модификация фипронила и ее применение |
| JP5323714B2 (ja) | 2006-11-30 | 2013-10-23 | ビーエーエスエフ ソシエタス・ヨーロピア | Ｎ−ビニルアミドコポリマーを含む農薬製剤 |
| WO2008065050A1 (en) | 2006-11-30 | 2008-06-05 | Basf Se | Agrochemical formulations comprising co-polymers based on diisocyanates |
| KR20130105936A (ko) * | 2006-11-30 | 2013-09-26 | 다우 아그로사이언시즈 엘엘씨 | 2-치환된-5-(1-알킬티오)알킬피리딘의 제조 방법 |
| US9006142B2 (en) | 2006-11-30 | 2015-04-14 | Basf Se | Agrochemical formulations comprising 1-vinyl-2-pyrrolidinone co-polymers |
| US9480250B2 (en) | 2006-12-01 | 2016-11-01 | Basf Se | Production of solid solutions of pesticides by short-term superheating and rapid drying |
| ATE549325T1 (de) | 2007-01-26 | 2012-03-15 | Basf Se | 3-amino-1,2-benzisothiazol-verbindungen zur bekämpfung von tierpest ii |
| AU2008240710A1 (en) | 2007-04-23 | 2008-10-30 | Basf Se | Plant productivity enhancement by combining chemical agents with transgenic modifications |
| US8211924B2 (en) | 2007-07-03 | 2012-07-03 | Basf Se | 1-(azolin-2-yl)amino-1,2-diphenylethane compounds for combating animal pests |
| NZ599997A (en) | 2007-08-16 | 2013-08-30 | Basf Se | Seed treatment compositions and methods |
| JP2011510033A (ja) | 2008-01-25 | 2011-03-31 | シンジェンタ パーティシペーションズ アクチェンゲゼルシャフト | 化合物 |
| JP2011518909A (ja) | 2008-04-24 | 2011-06-30 | ビーエーエスエフ ソシエタス・ヨーロピア | アルコールアルコキシレート、それを含む作用剤、および農薬分野におけるアジュバントとしてのアルコールアルコキシレートの使用 |
| JP2011530661A (ja) | 2008-08-08 | 2011-12-22 | ビーエーエスエフ ソシエタス・ヨーロピア | 活性成分の制御放出を伴う有効成分含有繊維表面構造体、その使用、およびその生産のための方法 |
| EP2391206B1 (de) | 2009-01-27 | 2014-10-08 | Basf Se | Verfahren zur Behandlung von Saatgut |
| WO2010089244A1 (en) | 2009-02-03 | 2010-08-12 | Basf Se | Method for dressing seeds |
| AU2010220293B2 (en) | 2009-03-04 | 2014-09-11 | Basf Se | 3-arylquinazolin-4-one compounds for combating invertebrate pests |
| JP2012522750A (ja) | 2009-04-01 | 2012-09-27 | ビーエーエスエフ ソシエタス・ヨーロピア | 無脊椎動物害虫を駆除するためのイソキサゾリン化合物 |
| KR20120060780A (ko) | 2009-04-28 | 2012-06-12 | 바스프 코포레이션 | 발포성 살충제 조성물 |
| EP2451804B1 (de) | 2009-07-06 | 2014-04-30 | Basf Se | Pyridazinverbindungen zur bekämpfung von wirbellosen schädlingen |
| US9125414B2 (en) | 2009-07-24 | 2015-09-08 | Basf Se | Pyridine derivatives compounds for controlling invertebrate pests |
| CN102596968B (zh) | 2009-07-30 | 2015-05-06 | 梅里亚有限公司 | 杀虫的4-氨基-噻吩并[2,3-d]-嘧啶化合物及其使用方法 |
| CA2771752A1 (en) | 2009-08-28 | 2011-03-03 | Basf Corporation | Foamable pesticide compositions and methods of application |
| WO2011036074A1 (en) | 2009-09-24 | 2011-03-31 | Basf Se | Aminoquinazoline compounds for combating invertebrate pests |
| WO2011057942A1 (en) | 2009-11-12 | 2011-05-19 | Basf Se | Insecticidal methods using pyridine compounds |
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| ES2573793T3 (es) | 2010-03-23 | 2016-06-10 | Basf Se | Compuestos de piridazina para controlar plagas de invertebrados |
| JP2013522347A (ja) | 2010-03-23 | 2013-06-13 | ビーエーエスエフ ソシエタス・ヨーロピア | 無脊椎有害生物を防除するためのピリダジン化合物 |
| CN102834391A (zh) | 2010-03-23 | 2012-12-19 | 巴斯夫欧洲公司 | 防治无脊椎动物害虫的哒嗪化合物 |
| CN103025161A (zh) | 2010-05-24 | 2013-04-03 | 明治制果药业株式会社 | 有害生物防治剂 |
| TWI587786B (zh) | 2010-05-28 | 2017-06-21 | 巴地斯顏料化工廠 | 農藥混合物 |
| WO2012007426A1 (en) | 2010-07-13 | 2012-01-19 | Basf Se | Azoline substituted isoxazoline benzamide compounds for combating animal pests |
| JP2013532643A (ja) | 2010-07-22 | 2013-08-19 | ビーエーエスエフ ソシエタス・ヨーロピア | 無脊椎有害生物を防除するための新規なヘタリール（チオ）カルボキサミド化合物 |
| JP2013537885A (ja) | 2010-09-13 | 2013-10-07 | ビーエーエスエフ ソシエタス・ヨーロピア | 無脊椎有害生物ｉｉを防除するためのピリジン化合物 |
| EP2615917A2 (de) | 2010-09-13 | 2013-07-24 | Basf Se | Pyridinverbindungen zur bekämpfung von wirbellosen schädlingen iii |
| US8609700B2 (en) | 2010-09-13 | 2013-12-17 | Basf Se | Pyridine compounds for controlling invertebrate pests I |
| EP2621897A1 (de) | 2010-10-01 | 2013-08-07 | Basf Se | Iminverbindungen |
| JP2013540116A (ja) | 2010-10-01 | 2013-10-31 | ビーエーエスエフ ソシエタス・ヨーロピア | 殺有害生物剤としてのイミン置換−２，４−ジアリール−ピロリン誘導体 |
| WO2012076704A2 (en) | 2010-12-10 | 2012-06-14 | Basf Se | Pyrazole compounds for controlling invertebrate pests |
| WO2012084670A1 (en) | 2010-12-20 | 2012-06-28 | Basf Se | Pesticidal active mixtures comprising pyrazole compounds |
| WO2012085081A1 (en) | 2010-12-22 | 2012-06-28 | Basf Se | Sulfoximinamide compounds for combating invertebrate pests ii |
| KR20140025429A (ko) | 2011-04-06 | 2014-03-04 | 바스프 에스이 | 동물 해충을 퇴치하기 위한 치환된 피리미디늄 화합물 |
| UA110825C2 (uk) | 2011-04-21 | 2016-02-25 | Басф Се | Пестицидні сполуки піразолу |
| BR112014003221A2 (pt) | 2011-08-12 | 2017-04-18 | Basf Se | composto da fórmula geral (i), método para preparação de um comporto da fórmula (i), composição agrícola ou veterinária, métodos para combater ou controlar pragas invertebradas, para a proteção de plantas em crecimento contra o ataque ou infestação por pragas invertebradas, para a proteção de sementes contra insetos terrestres e das raízes e galhos de mudas contra insetos terrestres e foliares, semente, uso de um composto e método para tratamento de um animal infestado ou infectado por parasitas ou para evitar que animais fiquem infestados ou infectados por parasitas ou para proteção de um animal contra infestação ou infecção por parasitas |
| US20140179519A1 (en) | 2011-08-12 | 2014-06-26 | Basf Se | N-thio-anthranilamide compounds and their use as pesticides |
| KR20140054211A (ko) | 2011-08-12 | 2014-05-08 | 바스프 에스이 | 안트라닐아미드 화합물 및 살충제로서의 그의 용도 |
| IN2014CN01024A (de) | 2011-08-12 | 2015-04-10 | Basf Se | |
| ES2558166T3 (es) | 2011-08-12 | 2016-02-02 | Basf Se | Compuestos de N-tio-antranilamida y su uso como pesticidas |
| JP2014522874A (ja) | 2011-08-12 | 2014-09-08 | ビーエーエスエフ ソシエタス・ヨーロピア | アントラニルアミド化合物および殺虫剤としてのその使用 |
| JP2014524434A (ja) | 2011-08-18 | 2014-09-22 | ビーエーエスエフ ソシエタス・ヨーロピア | 有害無脊椎動物を駆除するためのカルバモイルメトキシベンズアミドおよびカルバモイルメチルチオベンズアミドおよびカルバモイルメチルアミノベンズアミド |
| IN2014CN01217A (de) | 2011-08-18 | 2015-04-24 | Basf Se | |
| CN103889960A (zh) | 2011-08-18 | 2014-06-25 | 巴斯夫欧洲公司 | 用于防治无脊椎动物害虫的氨基甲酰基甲氧基-和氨基甲酰基甲硫基-及氨基甲酰基甲基氨基苯甲酰胺 |
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| US9487523B2 (en) | 2012-03-14 | 2016-11-08 | Merck Sharp & Dohme Corp. | Process for making CGRP receptor antagonists |
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| JP6279563B2 (ja) | 2012-06-20 | 2018-02-14 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | ピラゾール化合物およびピラゾール化合物を含む殺有害生物性混合物 |
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| CN102993085B (zh) * | 2012-11-28 | 2014-08-20 | 河南省商业科学研究所有限责任公司 | 2,2’-(2,2’-联吡啶-4,4’-二次甲基)二丙二腈及其取代物的合成方法 |
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| CA2945766C (en) | 2014-04-17 | 2023-09-26 | Merial, Inc. | Use of malononitrile compounds for protecting animals from parasites |
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| CN108651896A (zh) * | 2018-04-24 | 2018-10-16 | 大连工业大学 | 一种即食巴沙鱼片的制作方法 |
| CN113906038A (zh) * | 2019-06-04 | 2022-01-07 | 3M创新有限公司 | 多官能氟化化合物、由该化合物制成的氟化聚合物以及相关方法 |
| CN111233619A (zh) * | 2020-03-17 | 2020-06-05 | 河北师范大学 | 一种合成4-卤代-1,1,2-三氟-1-丁烯的方法 |
| WO2025242701A1 (en) | 2024-05-22 | 2025-11-27 | Basf Se | Seed treatment compositions |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2957007A (en) * | 1957-12-06 | 1960-10-18 | Eastman Kodak Co | O, o-dialkyl s-[(dicyano methyl) alkyl] phosphorothiolothionates |
| JPH1029966A (ja) * | 1996-07-17 | 1998-02-03 | Mitsubishi Chem Corp | マロノニトリル誘導体およびこれを有効成分とする除草剤 |
| JP2003026510A (ja) * | 2001-05-09 | 2003-01-29 | Sumitomo Chem Co Ltd | マロノニトリル化合物およびその有害生物防除用途 |
-
2003
- 2003-07-07 CN CNB038169789A patent/CN100343233C/zh not_active Expired - Fee Related
- 2003-07-07 AT AT03741228T patent/ATE345683T1/de not_active IP Right Cessation
- 2003-07-07 US US10/516,343 patent/US7026340B2/en not_active Expired - Fee Related
- 2003-07-07 WO PCT/JP2003/008579 patent/WO2004006677A1/en not_active Ceased
- 2003-07-07 EP EP03741228A patent/EP1521528B1/de not_active Expired - Lifetime
- 2003-07-07 AU AU2003281174A patent/AU2003281174A1/en not_active Abandoned
- 2003-07-07 DE DE60309874T patent/DE60309874T2/de not_active Expired - Lifetime
- 2003-07-07 BR BR0312638-2A patent/BR0312638A/pt active Search and Examination
- 2003-07-07 ES ES03741228T patent/ES2276090T3/es not_active Expired - Lifetime
- 2003-07-14 AR AR20030102521A patent/AR040557A1/es unknown
- 2003-07-16 SA SA3240207A patent/SA03240207B1/ar unknown
-
2004
- 2004-12-06 IL IL165588A patent/IL165588A/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| IL165588A (en) | 2010-05-31 |
| EP1521528B1 (de) | 2006-11-22 |
| AU2003281174A1 (en) | 2004-02-02 |
| SA03240207B1 (ar) | 2008-03-29 |
| AR040557A1 (es) | 2005-04-13 |
| CN100343233C (zh) | 2007-10-17 |
| DE60309874T2 (de) | 2007-03-15 |
| CN1668195A (zh) | 2005-09-14 |
| IL165588A0 (en) | 2006-01-15 |
| ES2276090T3 (es) | 2007-06-16 |
| US7026340B2 (en) | 2006-04-11 |
| BR0312638A (pt) | 2005-06-07 |
| EP1521528A1 (de) | 2005-04-13 |
| US20050176784A1 (en) | 2005-08-11 |
| ATE345683T1 (de) | 2006-12-15 |
| WO2004006677A1 (en) | 2004-01-22 |
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