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DE60042038D1 - Siliziumdioxid-Nanoteilchen in Form eines trockenen Pulvers - Google Patents

Siliziumdioxid-Nanoteilchen in Form eines trockenen Pulvers

Info

Publication number
DE60042038D1
DE60042038D1 DE60042038T DE60042038T DE60042038D1 DE 60042038 D1 DE60042038 D1 DE 60042038D1 DE 60042038 T DE60042038 T DE 60042038T DE 60042038 T DE60042038 T DE 60042038T DE 60042038 D1 DE60042038 D1 DE 60042038D1
Authority
DE
Germany
Prior art keywords
dry powder
silica nanoparticles
nanoparticles
silica
dry
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60042038T
Other languages
English (en)
Inventor
Xiaodong Zhang
Brant U Kolb
Douglas A Hanggi
Bradley D Craig
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23701047&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE60042038(D1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Application granted granted Critical
Publication of DE60042038D1 publication Critical patent/DE60042038D1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00Preparations for dentistry
    • A61K6/20Protective coatings for natural or artificial teeth, e.g. sealings, dye coatings or varnish
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00Preparations for dentistry
    • A61K6/30Compositions for temporarily or permanently fixing teeth or palates, e.g. primers for dental adhesives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00Preparations for dentistry
    • A61K6/70Preparations for dentistry comprising inorganic additives
    • A61K6/71Fillers
    • A61K6/76Fillers comprising silicon-containing compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00Preparations for dentistry
    • A61K6/80Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/884Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
    • A61K6/887Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00Preparations for dentistry
    • A61K6/80Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/884Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
    • A61K6/891Compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/62Submicrometer sized, i.e. from 0.1-1 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/64Nanometer sized, i.e. from 1-100 nanometer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/259Silicic material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991Coated
    • Y10T428/2993Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
    • Y10T428/2995Silane, siloxane or silicone coating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991Coated
    • Y10T428/2998Coated including synthetic resin or polymer

Landscapes

  • Health & Medical Sciences (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Epidemiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Plastic & Reconstructive Surgery (AREA)
  • Nanotechnology (AREA)
  • Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Dental Preparations (AREA)
DE60042038T 1999-10-28 2000-02-25 Siliziumdioxid-Nanoteilchen in Form eines trockenen Pulvers Expired - Lifetime DE60042038D1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US42893799A 1999-10-28 1999-10-28

Publications (1)

Publication Number Publication Date
DE60042038D1 true DE60042038D1 (de) 2009-05-28

Family

ID=23701047

Family Applications (2)

Application Number Title Priority Date Filing Date
DE60022667T Expired - Lifetime DE60022667T2 (de) 1999-10-28 2000-02-25 Dentalmaterialien mit siliciumdioxid-nanoteilchen
DE60042038T Expired - Lifetime DE60042038D1 (de) 1999-10-28 2000-02-25 Siliziumdioxid-Nanoteilchen in Form eines trockenen Pulvers

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE60022667T Expired - Lifetime DE60022667T2 (de) 1999-10-28 2000-02-25 Dentalmaterialien mit siliciumdioxid-nanoteilchen

Country Status (7)

Country Link
US (1) US6899948B2 (de)
EP (2) EP1227781B9 (de)
JP (2) JP4800535B2 (de)
AU (1) AU3505400A (de)
CA (1) CA2387215C (de)
DE (2) DE60022667T2 (de)
WO (1) WO2001030307A1 (de)

Families Citing this family (238)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030134035A1 (en) * 1997-03-20 2003-07-17 Unisearch Limited, A.C.N. 000 263 025 Hydrophobic films
US6730156B1 (en) * 1999-10-28 2004-05-04 3M Innovative Properties Company Clustered particle dental fillers
JP4800535B2 (ja) 1999-10-28 2011-10-26 スリーエム イノベイティブ プロパティズ カンパニー ナノサイズシリカ粒子を含有する歯科材料
US6537563B2 (en) * 2000-05-11 2003-03-25 Jeneric/Pentron, Inc. Dental acid etchant composition and method of use
US7709029B2 (en) * 2001-01-24 2010-05-04 Ada Foundation Calcium-containing restoration materials
US6890968B2 (en) 2001-05-16 2005-05-10 Kerr Corporation Prepolymerized filler in dental restorative composite
US6593395B2 (en) 2001-05-16 2003-07-15 Kerr Corporation Dental composition containing discrete nanoparticles
WO2003015720A1 (en) * 2001-08-15 2003-02-27 3M Innovative Properties Company Hardenable self-supporting structures and methods
US7101616B2 (en) 2001-09-11 2006-09-05 3M Innovative Properties Company Smudge resistant nanocomposite hardcoats and methods for making same
FR2833484B1 (fr) * 2001-12-18 2004-12-10 Rhodia Chimie Sa Composition dentaire a base de solution de silice colloidale en phase continue silicone
US7393882B2 (en) 2002-01-31 2008-07-01 3M Innovative Properties Company Dental pastes, dental articles, and methods
US7008229B2 (en) * 2002-04-12 2006-03-07 3M Innovative Properties Company Stainless steel dental crowns with a polyester/epoxy coating
US6773261B2 (en) 2002-06-28 2004-08-10 3M Innovative Properties Company Processes for forming dental materials
US7134875B2 (en) 2002-06-28 2006-11-14 3M Innovative Properties Company Processes for forming dental materials and device
US7091259B2 (en) 2002-07-03 2006-08-15 3M Innovative Properties Company Dental fillers, pastes, and compositions prepared therefrom
US20040206932A1 (en) 2002-12-30 2004-10-21 Abuelyaman Ahmed S. Compositions including polymerizable bisphosphonic acids and methods
US7396862B2 (en) * 2003-02-06 2008-07-08 Weimer Alan W Dental composite filler particles
TWI236374B (en) * 2003-02-13 2005-07-21 Univ Nat Taiwan Light curable epoxy nano composite for dental restorative material
US7084182B2 (en) * 2003-03-13 2006-08-01 Tokuyama Corporation Photopolymerization initiator
US7282195B2 (en) * 2003-04-10 2007-10-16 Macdougald Ian T Flavored sealants
KR100708882B1 (ko) 2003-04-15 2007-04-17 (주) 보람케메탈 흄드 실리카를 이용한 나노 실리카 결정 분말의 제조방법
US7235118B2 (en) * 2003-04-16 2007-06-26 National Research Council Of Canada Process for agglomeration and densification of nanometer sized particles
US7998375B2 (en) * 2003-05-08 2011-08-16 Pentron Clinical Technologies, Llc Method of manufacturing high strength dental restorations
US20040241609A1 (en) * 2003-05-08 2004-12-02 Weitao Jia Method of manufacturing high strength dental restorations
WO2004100900A1 (en) * 2003-05-13 2004-11-25 Dentsply International Inc. Dental adhesive compositions and methods
ATE324856T1 (de) 2003-07-14 2006-06-15 3M Espe Ag Klebstoffzusammensetzung mit verringerter polarität nach der polymerisation
EP1502570A1 (de) * 2003-08-01 2005-02-02 Nanosolutions GmbH Röntgenopakes Dentalmaterial mit oberflächenmodifizierten Nanopartikeln
WO2005018581A2 (en) 2003-08-12 2005-03-03 3M Innovative Properties Company Self-etching dental compositions and methods
US7026367B2 (en) 2003-09-26 2006-04-11 3M Innovative Properties Company Photoiniators having triarylsulfonium and arylsulfinate ions
US7250452B2 (en) 2003-09-26 2007-07-31 3M Innovative Properties Company Dental compositions and methods with arylsulfinate salts
US7030169B2 (en) 2003-09-26 2006-04-18 3M Innovative Properties Company Arylsulfinate salts in initiator systems for polymeric reactions
US7064152B2 (en) 2003-09-26 2006-06-20 3M Innovative Properties Company Arylsulfinate salts in photoinitiator systems for polymerization reactions
US7189768B2 (en) * 2003-11-25 2007-03-13 3M Innovative Properties Company Solution containing surface-modified nanoparticles
US20050132928A1 (en) * 2003-12-22 2005-06-23 Culp Terry L. Dental composites placement techniques for direct restorations
DE102005002845A1 (de) * 2004-02-18 2005-09-15 Heraeus Kulzer Gmbh Dispersionen nanoskaliger, nicht-agglomerierter Teilchen zum Einsatz in Dentalmaterialien
US20060004121A1 (en) * 2004-03-10 2006-01-05 Xingzhe Ding Polymer-brush modified fillers for composites
HRP20080380T3 (hr) * 2004-04-15 2008-09-30 Dentofit A/S Ultrazvučno očvršćavanje zubarskih materijala za punjenje
NZ550000A (en) * 2004-04-15 2009-06-26 Dentofit As Ultrasonic curing of dental filling materials
KR100858373B1 (ko) * 2004-04-15 2008-09-17 덴토피트 에이/에스 치과용 충전재의 초음파 경화방법
US7090721B2 (en) * 2004-05-17 2006-08-15 3M Innovative Properties Company Use of nanoparticles to adjust refractive index of dental compositions
US7156911B2 (en) * 2004-05-17 2007-01-02 3M Innovative Properties Company Dental compositions containing nanofillers and related methods
US7090722B2 (en) 2004-05-17 2006-08-15 3M Innovative Properties Company Acid-reactive dental fillers, compositions, and methods
US7649029B2 (en) * 2004-05-17 2010-01-19 3M Innovative Properties Company Dental compositions containing nanozirconia fillers
DE102004025030A1 (de) * 2004-05-18 2005-12-15 S&C Polymer Silicon- und Composite-Spezialitäten GmbH Nano-Apatit-Füllstoffe enthaltende härtbare Restaurationsmaterialien
EP1784154A1 (de) 2004-07-08 2007-05-16 3M Innovative Properties Company Dentalverfahren, zusammensetzungen und kits mit säureempfindlichen farbstoffen
AU2005275241B2 (en) 2004-07-14 2011-12-01 3M Deutschland Gmbh Dental compositions conataining carbosilane polymers
EP1776079B1 (de) * 2004-07-14 2010-10-06 3M Espe Ag Dentalzusammensetzung mit epoxy-funktionalen polymerisierbaren verbindungen
EP1765262B1 (de) 2004-07-14 2009-03-04 3M Espe AG Dentalzusammensetzung mit ungesättigten halogenierten arylalkylether-bestandteilen
DE602005017633D1 (de) 2004-07-14 2009-12-24 3M Innovative Properties Co Dentalzusammensetzungen mit carbosilan-monomeren
WO2006005369A1 (en) 2004-07-14 2006-01-19 3M Espe Ag Dental composition containing an epoxy functional carbosilane compound
US20060035997A1 (en) 2004-08-10 2006-02-16 Orlowski Jan A Curable acrylate polymer compositions featuring improved flexural characteristics
CA2575976A1 (en) 2004-08-11 2006-02-23 3M Innovative Properties Company Self-adhesive compositions including a plurality of acidic compounds
FR2874498B1 (fr) * 2004-08-31 2006-11-24 Coste Bruno Clunet Element d'obturation et d'ancrage dentaire prefabrique en materiau composite radio opaque et translucide
DE602005014253D1 (de) * 2004-10-14 2009-06-10 Dentsply Int Inc Aus nur einer komponente bestehendes selbstätzendes haftmittel
DE602005025682D1 (de) 2004-11-16 2011-02-10 3M Innovative Properties Co Dentalfüllstoffe und zusammensetzungen mit phosphatsalzen
EP2832342A3 (de) 2004-11-16 2015-02-11 3M Innovative Properties Company of 3M Center Dentale Zusammensetzungen mit Calzium und Phosphor-freisetzendem Glass
KR101366911B1 (ko) 2004-11-16 2014-02-24 쓰리엠 이노베이티브 프로퍼티즈 컴파니 인-함유 표면 처리제를 포함하는 치과용 충전제, 및 그의조성물 및 방법
DE602005023509D1 (de) 2004-11-16 2010-10-21 3M Innovative Properties Co Dentalfüllstoffe, verfahren, zusammensetzungen mit einem caseinat
KR101330957B1 (ko) 2005-05-09 2013-11-18 쓰리엠 이노베이티브 프로퍼티즈 컴파니 하이브리드 단량체를 함유하는 치과용 조성물
US20060270752A1 (en) * 2005-05-26 2006-11-30 Ada Foundation Dental releasing materials
US20070123604A1 (en) * 2005-05-26 2007-05-31 Ada Foundation Dental releasing materials
DE602006015475D1 (de) 2005-08-05 2010-08-26 3M Espe Ag Dentalzusammensetzungen mit einem oberflächenmodifizierten füllstoff
DE102005041014A1 (de) * 2005-08-29 2007-03-01 Heraeus Kulzer Gmbh Lichthärtendes, selbstätzendes Nanopartikel enthaltendes Einkomponenten-Dentaladhäsiv
US7855242B2 (en) * 2005-09-01 2010-12-21 Pentron Clinical Technologies Llc Dental resin composition, method of manufacture, and method of use thereof
WO2007028159A2 (en) * 2005-09-02 2007-03-08 Dentsply International Inc. Dental sealant compositions containing nanometer- sized silica
US7495054B2 (en) 2005-09-19 2009-02-24 3M Innovative Properties Company Curable compositions containing dithiane monomers
EP1928395B1 (de) * 2005-09-22 2015-03-11 Gdf Gesellschaft Für Dentale Forschung Und Innovat Dentalmaterial
EP1787627A1 (de) 2005-11-17 2007-05-23 3M Innovative Properties Company Antimikrobielles Zahnabdruckmaterial
US7896650B2 (en) 2005-12-20 2011-03-01 3M Innovative Properties Company Dental compositions including radiation-to-heat converters, and the use thereof
US8026296B2 (en) 2005-12-20 2011-09-27 3M Innovative Properties Company Dental compositions including a thermally labile component, and the use thereof
US7658870B2 (en) 2005-12-20 2010-02-09 University Of Hawaii Polymer matrix composites with nano-scale reinforcements
US7776940B2 (en) 2005-12-20 2010-08-17 3M Innovative Properties Company Methods for reducing bond strengths, dental compositions, and the use thereof
DE102005061965A1 (de) * 2005-12-23 2007-07-05 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Oxidische Agglomeratpartikel, Verfahren zur Herstellung von Nanokompositen sowie deren Verwendung
CN101351182B (zh) 2005-12-29 2016-01-20 3M创新有限公司 牙科用组合物和具有多环芳族组分的引发剂体系
WO2007079144A1 (en) * 2005-12-29 2007-07-12 3M Innovative Properties Company Dental compositions with a water scavenger
US8071662B2 (en) 2005-12-29 2011-12-06 3M Innovative Properties Company Dental compositions with surface-treated filler for shelf stability
US7556743B2 (en) * 2006-03-06 2009-07-07 Southwest Research Institute Nanocomposites and methods for synthesis and use thereof
EP1849449A1 (de) * 2006-04-26 2007-10-31 3M Innovative Properties Company Füllstoff enthaltende Zusammensetzung, Verfahren zu seiner Herstellung und seine Verwendung
JP2007314773A (ja) * 2006-04-28 2007-12-06 Mitsubishi Chemicals Corp 高屈折率粒子含有樹脂組成物
ATE477283T1 (de) 2006-05-31 2010-08-15 3M Innovative Properties Co Polymerisierbare zusammensetzungen enthaltend salze aus barbitursäure-derivaten
US7498197B2 (en) * 2006-09-13 2009-03-03 Delphi Technologies, Inc. Silica nanoparticles thermoset resin compositions
ATE516794T1 (de) 2006-09-13 2011-08-15 3M Innovative Properties Co Dentalzusammensetzungen mit organogelatoren, produkte und verfahren
US20080070146A1 (en) 2006-09-15 2008-03-20 Cabot Corporation Hydrophobic-treated metal oxide
US8202502B2 (en) * 2006-09-15 2012-06-19 Cabot Corporation Method of preparing hydrophobic silica
US8435474B2 (en) * 2006-09-15 2013-05-07 Cabot Corporation Surface-treated metal oxide particles
US8455165B2 (en) * 2006-09-15 2013-06-04 Cabot Corporation Cyclic-treated metal oxide
US9539065B2 (en) 2006-10-23 2017-01-10 3M Innovative Properties Company Assemblies, methods, and kits including a compressible material
US20080096150A1 (en) 2006-10-23 2008-04-24 3M Innovative Properties Company Dental articles, methods, and kits including a compressible material
DE102006054879B4 (de) * 2006-11-20 2008-09-11 Heraeus Kulzer Gmbh Polymerisierbares Dentalmaterial auf der Basis von Methylmethacrylaten, geeignet zur Herstellung von Prothesenkunststoff
WO2008076739A2 (en) 2006-12-13 2008-06-26 3M Innovative Properties Company Methods of using a dental composition having an acidic component and a photobleachable dye
EP2114349B1 (de) * 2006-12-28 2016-09-14 3M Innovative Properties Company Dentalfüllstoff und verfahren
WO2008082929A2 (en) 2006-12-28 2008-07-10 3M Innovative Properties Company Adhesive composition for hard tissue
EP2114351B1 (de) * 2006-12-28 2016-07-13 3M Innovative Properties Company Dentalzusammensetzungen mit natürlicher zahnfluoreszenz
FR2911494B1 (fr) * 2007-01-19 2009-04-10 Rech S Tech Dentaires R T D Sa Element prothetique dentaire radio-opaque
WO2008096753A1 (ja) * 2007-02-08 2008-08-14 Kuraray Medical Inc. 歯科用組成物
US20080214689A1 (en) * 2007-03-02 2008-09-04 Cheng-Chien Yang Manufacturing method and foaming manufacturing method of polymethyl methacrylate/silica composite material
CA2942365C (en) 2007-05-11 2019-04-16 Dentsply International Inc. Dental compositions for coating restorations and tooth surfaces
US20080286724A1 (en) 2007-05-18 2008-11-20 Ormco Corporation Orthodontic adhesives
US8735463B2 (en) 2007-05-31 2014-05-27 Creighton University Self-healing dental composites and related methods
EP2008636A1 (de) * 2007-06-29 2008-12-31 3M Innovative Properties Company Dentale Zusammensetzung mit polyfunktionalem (Meth)Acrylat mit Urethan-, Harnstoff- oder Amidgruppen, Verfahren zu deren Herstellung und Verwendung
EP2025381A1 (de) * 2007-07-30 2009-02-18 Nanoresins AG Verfahren zum Entfernen basischer oder saurer Verbindungen aus einer lösungsmittelhaltigen Metalloxiddispersion insbesondere Kieselsäure
EP2042486A1 (de) * 2007-09-26 2009-04-01 3M Innovative Properties Company Auf Methacrylat basierende Monomere mit einer Urethanbindung, Herstellungsverfahren und Verwendung
US20110229838A1 (en) 2007-10-01 2011-09-22 Kalgutkar Rajdeep S Orthodontic composition with polymeric fillers
EP2214622B1 (de) * 2007-11-01 2014-12-03 3M Innovative Properties Company Dentale Zusammensetzungen und Initiator-Systeme mit farbstabilen Amin-Elektronendonatoren
ATE546107T1 (de) 2007-12-13 2012-03-15 3M Innovative Properties Co Kieferorthopädische artikel mit einer teilweise gehärteten zusammensetzung und anwendungs- und herstellungsverfahren
EP2072028A1 (de) 2007-12-21 2009-06-24 Ernst Mühlbauer GmbH & Co.KG Stumpfaufbaumaterial
EP2133063A1 (de) 2008-06-10 2009-12-16 3M Innovative Properties Company Initiatorsystem mit Biphenylen-Derivaten, Herstellungsverfahren und Verwendung dafür
EP2133064A1 (de) * 2008-06-10 2009-12-16 3M Innovative Properties Company Initiatorsystem mit einem Diarylalkylamin-Derivat, härtbare Zusammensetzung und deren Verwendung
ES2549983T3 (es) * 2008-06-12 2015-11-03 3M Innovative Properties Company Métodos de combinación de nanopartículas con una resina
EP2548546A1 (de) * 2008-08-13 2013-01-23 Ernst Mühlbauer GmbH & Co.KG Röntgenopaker Infiltrant
BRPI0913521A2 (pt) * 2008-09-04 2015-10-13 3M Innovative Properties Co composição dental endurecível e artigo dental
US20100068523A1 (en) * 2008-09-16 2010-03-18 Aveka, Incorporated Surface modification of and dispersion of particles
CN102224106A (zh) * 2008-10-15 2011-10-19 3M创新有限公司 具有氧化锆和二氧化硅纳米粒子的填料和复合材料
WO2010045096A2 (en) 2008-10-15 2010-04-22 3M Innovative Properties Company Dental compositions with fluorescent pigment
EP2376573B1 (de) * 2008-10-22 2019-12-18 3M Innovative Properties Company Dentalzusammensetzung, umfassend biphenyldi(meth)acrylat-monomer mit urethaneinheiten
RU2486890C2 (ru) * 2008-11-25 2013-07-10 Дзе Проктер Энд Гэмбл Компани Композиции для ухода за полостью рта, содержащие аморфный кварц
US8551457B2 (en) 2008-11-25 2013-10-08 The Procter & Gamble Company Oral care compositions comprising spherical fused silica
CN102317361B (zh) 2008-12-19 2014-07-02 3M创新有限公司 纳米方解石复合材料
US20100189663A1 (en) * 2009-01-24 2010-07-29 Gallis Karl W Mouth rinse compositions including chemically modified silica or silicate materials for sustained delivery to tooth surfaces
DE102009006173A1 (de) * 2009-01-26 2010-07-29 Ernst Mühlbauer Gmbh & Co. Kg Dentalmaterial
KR101914793B1 (ko) 2009-07-30 2018-11-02 쓰리엠 이노베이티브 프로퍼티즈 컴파니 노즐 및 그 제조 방법
KR101783062B1 (ko) 2009-08-28 2017-09-28 쓰리엠 이노베이티브 프로퍼티즈 컴파니 다작용성 양이온을 포함하는 중합성 이온성 액체 및 정전기 방지 코팅
EP2470509A2 (de) 2009-08-28 2012-07-04 3M Innovative Properties Company Zusammensetzungen und artikel mit einer polymeriszierbaren ionischen flüssigkeitsmischung und härtungsverfahren
WO2011050121A2 (en) 2009-10-21 2011-04-28 3M Innovative Properties Company Solventless functionalization, milling, and compounding process with reactive diluents
CN102639623B (zh) 2009-12-17 2014-11-05 3M创新有限公司 纳米方解石和乙烯基酯复合物
EP2513215B1 (de) 2009-12-17 2019-06-05 3M Innovative Properties Company Nanocalcitkomposite mit hoher magnesiumoberflächenkonzentration
EP2515794B1 (de) 2009-12-22 2020-05-06 3M Innovative Properties Company Zahnärztliche zusammensetzungen, fräsblöcke und verfahren dafür
EP2515827A2 (de) 2009-12-22 2012-10-31 3M Innovative Properties Company Härtbare zahnzusammensetzungen und artikel mit polymerisierbaren ionischen flüssigkeiten
US20110206749A1 (en) * 2010-02-19 2011-08-25 J.M. Huber Corporation Silica materials for reducing oral malador
US20110236444A1 (en) * 2010-03-25 2011-09-29 Darsillo Michael S Antimicrobial Silica Composites
US9237990B2 (en) 2010-03-31 2016-01-19 3M Innovative Properties Company Polymerizable isocyanurate monomers and dental compositions
US20130035433A1 (en) 2010-04-20 2013-02-07 3M Innovative Properties Company Pressure Sensitive Adhesives Containing Reactive, Surface-Modified Nanoparticles
CN105858600A (zh) 2010-04-23 2016-08-17 皮瑟莱根特科技有限责任公司 纳米晶体的合成、盖帽和分散
US9050252B2 (en) 2010-05-25 2015-06-09 3M Innovative Properties Company Method of surface treating inorganic oxide particles, hardenable dental compositions, surface treated particles, and surface treatment compounds
EP2401998A1 (de) 2010-07-02 2012-01-04 3M Innovative Properties Company Dentale Zusammensetzung, Satz aus Teilen und Verwendung davon
EP2412361A1 (de) 2010-07-29 2012-02-01 3M Innovative Properties Company Kits aus Teilen, Herstellungsverfahren und Verwendung davon
US9044292B2 (en) 2010-08-11 2015-06-02 3M Innovative Properties Company Dental articles including a ceramic and microparticle coating and method of making the same
EP2603160A2 (de) 2010-08-11 2013-06-19 3M Innovative Properties Company Polymerbeschichtete zahnkronen und verfahren zu ihrer herstellung
US9370404B2 (en) 2010-08-11 2016-06-21 Bhaskar V. Velamakanni Aesthetic and abrasion resistant coated dental articles and methods of making the same
US20130137064A1 (en) 2010-08-11 2013-05-30 3M Innovative Properties Company Coated dental crowns and method of making the same
WO2012036838A2 (en) 2010-09-15 2012-03-22 3M Innovative Properties Company Substituted saccharide compounds and dental compositions
EP2436364B1 (de) 2010-09-30 2017-05-31 VOCO GmbH Lackzusammensetzung umfassend ein Monomer mit einem polyalicyclischen Strukturelement
US8669302B2 (en) 2010-09-30 2014-03-11 Voco Gmbh Composite material comprising a monomer with a polyalicyclic structure element as a sealing material
JP5824061B2 (ja) * 2010-10-27 2015-11-25 スリーエム イノベイティブ プロパティズ カンパニー 半結晶性樹脂とナノクラスター充填剤とを含む歯科用組成物
CN103328374B (zh) 2010-10-27 2017-04-26 皮瑟莱根特科技有限责任公司 纳米晶体的合成、盖帽和分散
EP2658469B1 (de) 2010-12-30 2019-11-27 3M Innovative Properties Company Dentale bondingfähige anordnungen und verfahren mit einem komprimierbaren material
EP2481390A1 (de) 2011-01-31 2012-08-01 3M Innovative Properties Company Dentale Zusammensetzung, Satz aus Teilen und Verwendung davon
CN106671317A (zh) 2011-02-02 2017-05-17 3M创新有限公司 喷嘴及其制备方法
WO2012112321A2 (en) 2011-02-15 2012-08-23 3M Innovative Properties Company Dental compositions comprising mixture of isocyanurate monomer and tricyclodecane monomer
CN103370041B (zh) 2011-02-15 2016-06-15 3M创新有限公司 包含烯键式不饱和加成-断裂剂的牙科用组合物
EP2688508A1 (de) 2011-03-24 2014-01-29 3M Innovative Properties Company Dentales haftmittel mit einer beschichteten polymerkomponente
US8431626B2 (en) 2011-05-18 2013-04-30 3M Innovative Properties Company Disulfide monomers comprising ethylenically unsaturated norbornyl groups suitable for dental compositions
US8455565B2 (en) 2011-05-18 2013-06-04 3M Innovative Properties Company Disulfide monomers comprising ethylenically unsaturated groups suitable for dental compositions
US9433563B2 (en) 2011-06-29 2016-09-06 Bradley D. Craig Dental compositions comprising a fatty mono(meth)acrylate
EP2741728B1 (de) 2011-08-11 2019-06-26 3M Innovative Properties Company Dentale zusammensetzung, verfahren zur herstellung und verwendung damit
EP2747737B1 (de) 2011-08-23 2019-09-25 3M Innovative Properties Company Dentalzusammensetzungen mit additionsfragmentierungsmitteln
EP2578200B1 (de) 2011-10-04 2018-03-28 VOCO GmbH Zusammensetzungen zum Infiltrieren und/oder Versiegeln von Zahnhartsubstanz und entsprechende Verfahren
US9359689B2 (en) 2011-10-26 2016-06-07 Pixelligent Technologies, Llc Synthesis, capping and dispersion of nanocrystals
JP6129197B2 (ja) 2011-11-02 2017-05-17 スリーエム イノベイティブ プロパティズ カンパニー ノズルの製造方法
BR112014013111A2 (pt) 2011-12-01 2017-06-13 3M Innovative Properties Co composição dental autoadesiva de componente único, processo de produção e utilização do mesmo
EP2604247A1 (de) * 2011-12-15 2013-06-19 Dentsply DeTrey GmbH Verbundstofffüllpartikel und Verfahren zur Herstellung davon
US8999371B2 (en) 2012-03-19 2015-04-07 Arges Imaging, Inc. Contrast pattern application for three-dimensional imaging
US9381140B2 (en) 2012-08-31 2016-07-05 Kettenbach Gmbh & Co. Kg Radically polymerisable dental material, cured product and usage
US8986003B2 (en) 2012-09-13 2015-03-24 Orthoaccel Technologies, Inc. Pearlescent white aligners
WO2014071284A2 (en) 2012-11-05 2014-05-08 The Procter & Gamble Company Heat treated precipitated silica
CN104768519B (zh) 2012-11-12 2018-11-23 3M创新有限公司 包含加成-断裂剂的牙科组合物
KR102008353B1 (ko) 2012-12-17 2019-08-07 쓰리엠 이노베이티브 프로퍼티즈 컴파니 부가-단편화 올리고머
WO2014151363A1 (en) 2013-03-20 2014-09-25 3M Innovative Properties Company High refractive index addition-fragmentation agents
EP2986269A1 (de) 2013-04-15 2016-02-24 3M Innovative Properties Company Dentalzusammensetzung mit monomeren mit hohem brechungsindex
DE102013007894A1 (de) 2013-05-08 2014-11-13 Heraeus Kulzer Gmbh Langlebiges Dentalmaterial mit verbesserten transparenten Eigenschaften
WO2015006087A1 (en) 2013-07-08 2015-01-15 3M Innovative Properties Company Hardenable dental composition containing a mixture of agglomerated and aggregated nano-particles, kit of parts and use thereof
WO2015041863A1 (en) 2013-09-20 2015-03-26 3M Innovative Properties Company Trithiocarbonate-containing addition-fragmentation agents
EP3052050B1 (de) 2013-10-04 2021-07-28 3M Innovative Properties Company Rohling für eine dentalfräse
EP3058014B1 (de) 2013-10-16 2018-06-20 3M Innovative Properties Company Allyldisulfidhaltige zusatzfragmentierungsoligomere
EP3107523B1 (de) 2014-02-18 2018-10-17 3M Innovative Properties Company Dentale zusammensetzung und verwendung davon
US9730864B2 (en) 2014-02-18 2017-08-15 3M Innovative Properties Company Addition-fragmentation oligomers having high refractive index groups
DE102014107518A1 (de) * 2014-05-28 2015-12-03 Heraeus Kulzer Gmbh Reaktiver Mikro-Applikator mit Metall enthaltenden Additiven zur Verwendung mit dental Adhäsiven
WO2015200421A1 (en) 2014-06-27 2015-12-30 Corning Incorporated Uv-curable coating compositions for glass based on epoxy/oxetane compounds, epoxy functionalized silsesquioxane and epoxy functionalized nanoparticles.
RU2683315C2 (ru) 2014-07-10 2019-03-28 3М Инновейтив Пропертиз Компани Двухкомпонентный самоклеящийся стоматологический состав, способ его изготовления и применения
JP6820250B2 (ja) * 2014-07-31 2021-01-27 スリーエム イノベイティブ プロパティズ カンパニー 歯科用ミルブランク及び着色溶液を含むパーツキット
DE102014013807A1 (de) * 2014-09-23 2016-03-24 Dph Dental Partner Holding Gmbh Verfahren zur Präparation von dentalen Werkstücken mit reflektierenden Oberflächen
EP3206624B1 (de) 2014-10-14 2023-08-30 3M Innovative Properties Company Methode zum härten eines dentalartikels
US10350297B2 (en) 2014-10-31 2019-07-16 3M Innovative Properties Company Dental materials and methods
WO2016069290A1 (en) 2014-10-31 2016-05-06 3M Innovative Properties Company Dental materials and methods
JP6644079B2 (ja) 2015-02-20 2020-02-12 スリーエム イノベイティブ プロパティズ カンパニー 付加−開裂オリゴマー
JP6659716B2 (ja) 2015-03-05 2020-03-04 スリーエム イノベイティブ プロパティズ カンパニー セラミック繊維を有する複合材料
KR101746793B1 (ko) 2015-07-22 2017-06-14 주식회사 쿠보텍 금속 산화물을 함유하는 치과용 시멘트
DE102015012793A1 (de) * 2015-10-05 2017-04-06 Birgit Stührenberg Dentale Kompetenz GmbH & Co. KG Verblendelement zur Abdeckung einer Zahnoberfläche, Verfahren zur Herstellung des Verblendelements und Schichtaufbau mit dem Verblendelement
US10758456B2 (en) 2015-11-06 2020-09-01 3M Innovative Properties Company Redox polymerizable composition with photolabile transition metal complexes
US10617607B2 (en) 2015-11-06 2020-04-14 3M Innovative Properties Company Redox polymerizable dental composition with photolabile transition metal complexes
EP3383924B1 (de) 2015-12-03 2021-04-14 3M Innovative Properties Company Redox-polymerisierbare zusammensetzung mit fotolabilen reduktionsmitteln
WO2017100231A1 (en) 2015-12-08 2017-06-15 3M Innovative Properties Company Two-component self-adhesive dental composition, storage stable initiator system, and use thereof
BR112018016029B1 (pt) 2016-02-05 2021-11-16 3M Innovative Properties Company Composiqoes dentais compreendendo nanoparticulas que fornecem um diferencial de indice de refraqao entre resina polimerizavel e carga
CN108778229A (zh) 2016-03-07 2018-11-09 3M创新有限公司 预成形复合牙冠、其生产方法和用途
WO2017163610A1 (ja) 2016-03-25 2017-09-28 株式会社日本触媒 酸化ジルコニウムナノ粒子
US11650498B2 (en) 2016-06-30 2023-05-16 3M Innovative Properties Company Printable compositions including highly viscous components and methods of creating 3D articles therefrom
WO2018044565A1 (en) * 2016-09-02 2018-03-08 3M Innovative Properties Company Shaped gel articles and sintered articles prepared therefrom
US11129693B2 (en) 2016-09-06 2021-09-28 3M Innovative Properties Company Methods of improving dental restoration margins and articles
WO2018075275A1 (en) 2016-10-20 2018-04-26 3M Innovative Properties Company Photoinitiators with protected carbonyl group
JP7245775B2 (ja) 2016-12-01 2023-03-24 スリーエム イノベイティブ プロパティズ カンパニー 生体担体材料に使用するのに好適な無機シェル内に封入された塩基性コア材料
EP3586814B1 (de) * 2017-02-27 2024-01-31 GC Corporation Zahnärztliche härtbare zusammensetzung
US11160733B2 (en) 2017-05-15 2021-11-02 3M Innovative Properties Company Dental adhesive composition, preparation and use thereof
JP7813510B2 (ja) 2017-05-18 2026-02-13 ソルベンタム インテレクチュアル プロパティズ カンパニー 水混和性のシラン処理したナノサイズシリカ粒子を含む、グラスアイオノマー組成物及び方法。
BR112019026532A2 (pt) 2017-06-14 2020-06-23 3M Innovative Properties Company Composição curável para a produção de uma coroa composta dental e processo de produção
CN111050694B (zh) 2017-09-11 2022-04-12 3M创新有限公司 使用增材制造方法制成的可辐射固化组合物和复合材料制品
WO2019065777A1 (ja) * 2017-09-26 2019-04-04 クラレノリタケデンタル株式会社 歯科用ミルブランクおよびその製造方法
US11612548B2 (en) 2017-11-08 2023-03-28 3M Innovative Properties Company Radiopaque dental composition
US10932995B2 (en) 2017-11-08 2021-03-02 3M Innovative Properties Company Dental composition with high E-modulus
CN111433268B (zh) 2017-11-29 2022-07-05 康宁股份有限公司 高度负载的无机填充的水性树脂体系
WO2019123260A2 (en) 2017-12-19 2019-06-27 3M Innovative Properties Company Multi-part composition having staged viscosity prior to hardening
JP6865898B2 (ja) 2017-12-21 2021-04-28 スリーエム イノベイティブ プロパティズ カンパニー シラン処理された表面を有する歯科用無機充填剤
WO2019191564A1 (en) 2018-03-29 2019-10-03 Corning Incorporated Highly loaded inorganic filled organic resin systems
CN112055579B (zh) 2018-05-02 2024-01-23 3M创新有限公司 用于固定牙科用复合材料的单组分牙科用粘合剂组合物
WO2019234661A1 (en) 2018-06-06 2019-12-12 3M Innovative Properties Company Hardenable dental compositions comprising basic core material encapsulated in an inorganic shell and dispensing devices therewith
CN112437644A (zh) 2018-06-06 2021-03-02 3M创新有限公司 两部分牙科密封剂、用注射器装置施用的方法以及套件
EP3834806A4 (de) 2018-08-08 2022-04-06 GC Corporation Härtbare zusammensetzung für die zahnmedizin
CN112673035B (zh) 2018-09-14 2024-04-19 舒万诺知识产权公司 包含陶瓷纤维和纳米团簇的复合材料、牙科产品、套件盒及其制备和使用方法
US11642199B2 (en) 2018-09-24 2023-05-09 3M Innovative Properties Company Dental appliance with cosmetic therapeutic aqueous solution
US20220033345A1 (en) 2018-10-09 2022-02-03 3M Innovative Properties Company Addition-fragmentation agent with pendent amine groups
EP3880156B1 (de) 2018-11-14 2025-08-20 Solventum Intellectual Properties Company Lagerstabile zweikomponentige dualhärtende zahnärztliche zusammensetzung
KR102198371B1 (ko) * 2019-10-18 2021-01-05 연세대학교 산학협력단 치과용 조성물 및 이를 포함하는 치과 교정술 장치 제조 방법
US12209172B2 (en) 2020-04-08 2025-01-28 3M Innovative Properties Company Curable compositions and methods of using the same
CN115348854B (zh) 2020-04-08 2024-09-10 3M创新有限公司 可固化组合物以及使用可固化组合物的方法
US11404289B2 (en) * 2020-08-31 2022-08-02 Micron Technology, Inc. Semiconductor device assembly with graded modulus underfill and associated methods and systems
JP2023547191A (ja) 2020-10-28 2023-11-09 スリーエム イノベイティブ プロパティズ カンパニー 光重合性組成物を処理するための方法及びシステム
WO2022096973A1 (en) 2020-11-05 2022-05-12 3M Innovative Properties Company Imide addition-fragmentation agents
WO2022112886A1 (en) 2020-11-25 2022-06-02 3M Innovative Properties Company Curable dental compositions and uses thereof
CN116710023A (zh) 2020-12-30 2023-09-05 3M创新有限公司 可粘合的畸齿矫正组件和用于粘合的方法
WO2022195364A1 (en) 2021-03-17 2022-09-22 3M Innovative Properties Company Polymerizable 4,4'-spirobi[chromane]-2,2'-diones and curable compositions including the same
US20240199919A1 (en) 2021-04-19 2024-06-20 3M Innovative Properties Company Adhesive layer for flexographic plate mounting tape
US12398301B2 (en) 2021-12-06 2025-08-26 3M Innovative Properties Company Adhesives comprising cyclic imide addition-fragmentation and adhesion agents
JP7660768B2 (ja) 2021-12-06 2025-04-11 ソルベンタム インテレクチュアル プロパティズ カンパニー 歯科用組成物
JP2023151496A (ja) 2022-03-31 2023-10-16 株式会社ジーシー 処理シリカ分散単量体組成物の製造方法
US12311037B2 (en) 2022-04-26 2025-05-27 Solventum Intellectual Properties Company Dental composition containing a resorcinol or catechol moiety containing component and use thereof
DE102022116932A1 (de) * 2022-07-07 2024-01-18 Voco Gmbh Herstellung von dentalen Fräsrohlingen
JP2025524858A (ja) 2022-07-21 2025-08-01 ソルベンタム インテレクチュアル プロパティズ カンパニー 透明な歯科矯正アタッチメントを製造するための硬化性組成物
WO2024110805A1 (en) 2022-11-25 2024-05-30 Solventum Intellectual Properties Company Curable composition for use in a process of treating a dental situation in the mouth of a patient
JP2025540069A (ja) 2022-12-06 2025-12-11 ソルベンタム インテレクチュアル プロパティズ カンパニー 表面処理された充填剤、このような充填剤を含有する歯科用組成物、その製造方法及び使用

Family Cites Families (184)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2801185A (en) 1952-05-16 1957-07-30 Du Pont Silica hydrosol powder
US2948628A (en) * 1955-08-02 1960-08-09 Horizons Inc Method of making ceramic dielectric
US2984628A (en) 1956-11-29 1961-05-16 Du Pont Concentrated zirconia and hafnia aquasols and their preparation
US3018262A (en) 1957-05-01 1962-01-23 Shell Oil Co Curing polyepoxides with certain metal salts of inorganic acids
US3066112A (en) 1959-01-30 1962-11-27 Rafael L Bowen Dental filling material comprising vinyl silane treated fused silica and a binder consisting of the reaction product of bis phenol and glycidyl acrylate
US3179623A (en) 1959-01-30 1965-04-20 Rafael L Bowen Method of preparing a monomer having phenoxy and methacrylate groups linked by hydroxy glyceryl groups
GB1051391A (de) 1959-12-24
US3442817A (en) 1966-04-15 1969-05-06 Du Pont Preparation of zirconia and hafnia sols
US3514252A (en) 1967-07-07 1970-05-26 Grace W R & Co Process for the preparation of stabilized zirconia powders
US3860556A (en) 1968-03-15 1975-01-14 Minnesota Mining & Mfg Low water absorption dental restorative
CA878004A (en) 1968-06-14 1971-08-10 Ii Henry L. Lee Dental filling package
US3539533A (en) 1968-06-14 1970-11-10 Johnson & Johnson Dental filling material
US3708296A (en) 1968-08-20 1973-01-02 American Can Co Photopolymerization of epoxy monomers
US3709706A (en) 1969-05-16 1973-01-09 Minnesota Mining & Mfg Refractory fibers and other articles of zirconia and silica mixtures
US3629187A (en) 1969-06-25 1971-12-21 Dentsply Int Inc Dental compositions containing adduct of 2 2' - propane bis 3-(4-phenoxy)-1 2-hydroxy propane - 1 - methacrylate and isocyanate
US3709866A (en) 1970-06-01 1973-01-09 Dentsply Int Inc Photopolymerizable dental products
US3766132A (en) 1971-02-12 1973-10-16 Lee Pharmaceuticals Diacrylate esters of low viscosity and the use thereof as binders in dental restorative compositions
US3751399A (en) 1971-05-24 1973-08-07 Lee Pharmaceuticals Polyacrylate resin compositions
GB1408265A (en) 1971-10-18 1975-10-01 Ici Ltd Photopolymerisable composition
US3729313A (en) 1971-12-06 1973-04-24 Minnesota Mining & Mfg Novel photosensitive systems comprising diaryliodonium compounds and their use
US3808006A (en) 1971-12-06 1974-04-30 Minnesota Mining & Mfg Photosensitive material containing a diaryliodium compound, a sensitizer and a color former
US3741769A (en) 1972-10-24 1973-06-26 Minnesota Mining & Mfg Novel photosensitive polymerizable systems and their use
DE2406557C3 (de) 1974-02-12 1981-02-19 Kulzer & Co Gmbh, 6380 Bad Homburg Hydroxyl-Gruppen enthaltende Diester von Acrylsäuren und diese enthaltendes Zahnfüllungsmaterial
US4115346A (en) 1974-02-12 1978-09-19 Kulzer & Co. Gmbh Hydroxy group containing diesters of acrylic acids and their use in dental material
AU497960B2 (en) 1974-04-11 1979-01-25 Minnesota Mining And Manufacturing Company Photopolymerizable compositions
GB1512982A (en) 1974-05-02 1978-06-01 Gen Electric Salts
US4250311A (en) 1974-05-02 1981-02-10 General Electric Company P, As, and Sb hexafluoride onium salts as photoinitiators
US4027073A (en) * 1974-06-25 1977-05-31 Dow Corning Corporation Pigment-free coating compositions
GB1569021A (en) 1976-03-17 1980-06-11 Kuraray Co Adhesive cementing agents containing partial phosphonic orphosphonic acid esters
US4150012A (en) 1977-01-21 1979-04-17 Minnesota Mining And Manufacturing Company Discernible dental sealant
JPS587561B2 (ja) 1977-06-17 1983-02-10 株式会社神戸製鋼所 塵芥等の管路輸送システムにおける輸送管路への塵芥等の供給方法
US4292029A (en) 1978-05-15 1981-09-29 University Of Michigan Hydrophobic composite restorative materials and their use in tooth treatment
US4387240A (en) 1978-06-02 1983-06-07 Minnesota Mining And Manufacturing Company Oligomeric methacryl substituted alkylsiloxanes
US4216288A (en) 1978-09-08 1980-08-05 General Electric Company Heat curable cationically polymerizable compositions and method of curing same with onium salts and reducing agents
DE2850917A1 (de) 1978-11-24 1980-06-04 Bayer Ag Dentalwerkstoffe auf basis von organischen kunststoffen in pastoeser form
EP0013491B1 (de) 1979-01-05 1982-10-20 Imperial Chemical Industries Plc Dispersionen kieselartiger fester Körper in flüssigen organischen Medien
US4327014A (en) 1979-04-11 1982-04-27 Kanebo Ltd. Resin-forming material, implant material and compositions for restorative material suitable for medical or dental use
US4250053A (en) 1979-05-21 1981-02-10 Minnesota Mining And Manufacturing Company Sensitized aromatic iodonium or aromatic sulfonium salt photoinitiator systems
US4389497A (en) * 1979-11-22 1983-06-21 Espe Fabrik Parmazeutischer Praparate Gmbh Use of agglomerates of silicic acid as fillers in dental materials
US4379695A (en) 1980-06-02 1983-04-12 Scientific Pharmaceuticals, Inc. Dental material comprising dimethyacrylate adducts of glycidyl methacrylate with diesters of bis(hydroxymethyl) tricyclo[5.2.1.02,6 ]decane and dicarboxylic acids
US4348462A (en) 1980-07-11 1982-09-07 General Electric Company Abrasion resistant ultraviolet light curable hard coating compositions
JPS5828878B2 (ja) 1980-08-20 1983-06-18 三金工業株式会社 環状ピロ燐酸エステル誘導体
JPS5774369A (en) 1980-10-28 1982-05-10 Mitsui Petrochem Ind Ltd Coating composition
DE3170993D1 (en) 1981-03-24 1985-07-25 Blendax Werke Schneider Co Dental filling material
US4491508A (en) 1981-06-01 1985-01-01 General Electric Company Method of preparing curable coating composition from alcohol, colloidal silica, silylacrylate and multiacrylate monomer
JPS5879818A (ja) 1981-11-05 1983-05-13 Etsuro Kato 結晶質ジルコニアのコロイドゾル及びその製造方法
JPS58135131A (ja) 1982-02-02 1983-08-11 Etsuro Kato ジルコニア系微粉末の製造方法
US4512743A (en) 1982-02-05 1985-04-23 Johnson & Johnson Dental Products Company Method for masking discoloration on teeth
DE3369398D1 (en) 1982-05-19 1987-02-26 Ciba Geigy Ag Curable compositions containing metallocen complexes, activated primers obtained therefrom and their use
EP0094914B1 (de) 1982-05-19 1986-09-24 Ciba-Geigy Ag Photopolymerisation mittels organometallischer Salze
US5089536A (en) 1982-11-22 1992-02-18 Minnesota Mining And Manufacturing Company Energy polmerizable compositions containing organometallic initiators
JPS59107969A (ja) 1982-12-08 1984-06-22 加藤 悦朗 ジルコニア系固溶体単結晶超微粒子の分散したゾルおよび製造方法
DE3316851A1 (de) 1983-05-07 1984-11-08 Bayer Ag, 5090 Leverkusen Polymerisierbare dentalmassen und hieraus hergestellte dentalformkoerper
US5073476A (en) 1983-05-18 1991-12-17 Ciba-Geigy Corporation Curable composition and the use thereof
US4545924A (en) 1983-06-13 1985-10-08 Owens-Corning Fiberglas Corporation Production of a magnesium chloride gel system useful in ceramics and fiber production
US4442240A (en) 1983-07-14 1984-04-10 Bisco, Inc. Dental filling materials
US4612138A (en) 1983-08-04 1986-09-16 Nalco Chemical Company Stable acidic and alkaline metal oxide sols
JPS60103033A (ja) 1983-11-01 1985-06-07 Chichibu Cement Co Ltd ジルコニア系超微粉末の製造方法
DE3341888A1 (de) 1983-11-19 1985-05-30 Bayer Ag, 5090 Leverkusen Anorganisch-organische fuellstoffe, verfahren zu deren herstellung sowie deren verwendung in polymerisierbaren massen
DE3342601C1 (de) 1983-11-25 1985-03-14 Blendax-Werke R. Schneider Gmbh & Co, 6500 Mainz Verwendung von bromierten aromatischen Diacrylsaeure- bzw. Dimethacrylsaeureestern in dentalen Fuellungsmaterialien
JPS60137827A (ja) 1983-12-23 1985-07-22 Shin Etsu Chem Co Ltd ジルコニア微粉末の製造方法
US4544359A (en) 1984-01-13 1985-10-01 Pentron Corporation Dental restorative material
DE3403040A1 (de) 1984-01-30 1985-08-08 Blendax-Werke R. Schneider Gmbh & Co, 6500 Mainz Dentales fuellungsmaterial
JPS60176920A (ja) 1984-02-21 1985-09-11 Etsuro Kato ジルコニア系単結晶超微粒子の分散したゾルおよび製造方法
US4503169A (en) 1984-04-19 1985-03-05 Minnesota Mining And Manufacturing Company Radiopaque, low visual opacity dental composites containing non-vitreous microparticles
JPS60255622A (ja) 1984-05-30 1985-12-17 Toyo Soda Mfg Co Ltd 焼結性に優れたジルコニア系微粉末の製造方法
US5137448A (en) 1984-07-31 1992-08-11 Dentsply Research & Development Corp. Dental impression method with photocuring of impression material in light transmissive tray
US5177120A (en) 1984-07-31 1993-01-05 Dentsply Research & Development Corp. Chain extended urethane diacrylate and dental impression formation
US4547531A (en) 1984-08-02 1985-10-15 Pentron Corporation Two component (paste-paste) self-curing dental restorative material
GR852068B (de) 1984-08-30 1985-12-24 Johnson & Johnson Dental Prod
US4746685A (en) 1984-08-31 1988-05-24 Nippon Oil And Fats Co., Ltd. Light curable dental composition
DE3443221A1 (de) 1984-11-27 1986-06-05 ESPE Fabrik pharmazeutischer Präparate GmbH, 8031 Seefeld Bisacylphosphinoxide, ihre herstellung und verwendung
EP0184467A3 (de) 1984-12-06 1988-06-08 Berger, Jenson and Nicholson Limited Wasserverdünnbare Beschichtungszusammensetzungen
US4661540A (en) 1984-12-06 1987-04-28 Berger, Jenson & Nicholson Limited Water reducible coating compositions
DE3502594A1 (de) 1985-01-26 1986-07-31 Etablissement Dentaire Ivoclar, Schaan Roentgenopaker dentalwerkstoff
US4642126A (en) 1985-02-11 1987-02-10 Norton Company Coated abrasives with rapidly curable adhesives and controllable curvature
US4619817A (en) 1985-03-27 1986-10-28 Battelle Memorial Institute Hydrothermal method for producing stabilized zirconia
US5276068A (en) 1985-03-29 1994-01-04 Jeneric/Pentron, Inc. Dental resin materials
JPS61227917A (ja) 1985-04-03 1986-10-11 Nippon Shokubai Kagaku Kogyo Co Ltd ジルコニア系球形微粒子粉末の製造方法
JPS61270217A (ja) 1985-05-23 1986-11-29 Denki Kagaku Kogyo Kk 結晶質酸化ジルコニウム微粉末の製法
US4652274A (en) 1985-08-07 1987-03-24 Minnesota Mining And Manufacturing Company Coated abrasive product having radiation curable binder
JPS6265932A (ja) 1985-09-13 1987-03-25 Nippon Mining Co Ltd 高強度ジルコニア微粉末の製造方法
JPS6291421A (ja) 1985-10-18 1987-04-25 Tokyo Inst Of Technol 酸化ジルコニウム微粒子の製造方法
US4772530A (en) 1986-05-06 1988-09-20 The Mead Corporation Photosensitive materials containing ionic dye compounds as initiators
US4772511A (en) 1985-11-22 1988-09-20 Minnesota Mining And Manufacturing Company Transparent non-vitreous zirconia microspheres
JPH0764563B2 (ja) 1985-11-27 1995-07-12 悦朗 加藤 結晶質ジルコニアの微粉末及びその製造方法
JPH0651568B2 (ja) 1985-11-29 1994-07-06 電気化学工業株式会社 酸化ジルコニウム系微粉末の製法
JPH0729771B2 (ja) 1986-01-14 1995-04-05 悦朗 加藤 単斜ジルコニア超微結晶の高分散ゾルまたはゲルおよび製造方法
JPS62212224A (ja) 1986-03-14 1987-09-18 Taiyo Yuden Co Ltd ジルコニア系固溶体結晶質微粉末の製造方法
JPS62226815A (ja) 1986-03-27 1987-10-05 Nippon Shokubai Kagaku Kogyo Co Ltd ジルコニア系コロイドゾルの製造方法
JPS62260718A (ja) 1986-05-06 1987-11-13 Shigeyuki Somiya 水熱法による高純度ジルコニア−アルミナ系超微粉末の製造方法
JPS632809A (ja) 1986-06-19 1988-01-07 Nippon Shokubai Kagaku Kogyo Co Ltd 高純度ジルコニアゾルの製造方法
US4719091A (en) 1986-07-01 1988-01-12 Corning Glass Works Preparation of mono-sized zirconia powders by forced hydrolysis
US4778671A (en) 1986-07-14 1988-10-18 Corning Glass Works Preparation of unagglomerated metal oxide particles with uniform particle size
AU601491B2 (en) 1986-09-27 1990-09-13 Nissan Chemical Industries Ltd. Process for manufacturing fine zirconium oxide powder
DE3642290C1 (de) 1986-12-11 1987-07-02 Dentaire Ivoclar Ets Verfahren zur Verbesserung der Haftung von Kunststoffen auf Metallen
US4874450A (en) 1987-01-29 1989-10-17 The Mead Corporation Laminating transparent or translucent materials using ionic dye-counter ion complexes
DE3863940D1 (de) 1987-02-25 1991-09-05 Nippon Catalytic Chem Ind Verfahren zur erzeugung sehr kleiner, anorganischer, kugelfoermiger teilchen.
CA1323949C (en) 1987-04-02 1993-11-02 Michael C. Palazzotto Ternary photoinitiator system for addition polymerization
US4781940A (en) * 1987-06-26 1988-11-01 Johnson & Johnson Consumer Products, Inc. Method for producing filler for microfilled dental composite material
US4792577A (en) 1987-07-16 1988-12-20 Johnson & Johnson Consumer Products, Inc. Stain-resistant no-mix orthodontic adhesive
US4886624A (en) 1987-08-19 1989-12-12 Rhone-Poulenc, Inc. Colloidal alcohol-dispersible association complexes of ceric dioxide and a hydroxyphenyl carboxylic acid
US4859716A (en) 1987-11-06 1989-08-22 Den-Mat Corporation Microfilled dental composite and method for making it
JPH0346407Y2 (de) 1988-02-08 1991-10-01
FR2629071B1 (fr) 1988-03-22 1991-03-15 Produits Refractaires Oxyde de zirconium reactif et sa preparation
US4885332A (en) 1988-04-11 1989-12-05 Minnesota Mining And Manufacturing Company Photocurable abrasion resistant coatings comprising silicon dioxide dispersions
US4985340A (en) 1988-06-01 1991-01-15 Minnesota Mining And Manufacturing Company Energy curable compositions: two component curing agents
US5234870A (en) 1988-07-21 1993-08-10 Nippon Shokubai Kagaku Kogyo Co., Ltd. Zirconia sol and method for production thereof
US4954414A (en) 1988-11-08 1990-09-04 The Mead Corporation Photosensitive composition containing a transition metal coordination complex cation and a borate anion and photosensitive materials employing the same
JPH0667816B2 (ja) 1988-11-11 1994-08-31 株式会社クラレ 歯科用修復材
US5275759A (en) 1989-02-10 1994-01-04 Nippon Shokubai Kagaku Kogyo Co., Ltd. Zirconia sol, method for production thereof, porous ceramic-producing slurry, and porous ceramic product obtained by use thereof
US5219899A (en) 1989-04-22 1993-06-15 Degussa Aktiengesellschaft Pasty dental material which is an organopolysilane filler combined with a polymerizable bonding agent
DE3913250A1 (de) 1989-04-22 1990-10-25 Degussa Dentalmaterial (ii)
US5248706A (en) 1989-04-22 1993-09-28 Degussa Aktiengesellschaft Process for preparing a pasty dental material which is an organopolysiloxane filler combined with a polymerizable bonding agent
US5013585A (en) * 1989-06-13 1991-05-07 Shin-Etsu Chemical Co., Ltd. Method for the preparation of surface-modified silica particles
US5057393A (en) 1989-07-10 1991-10-15 The Mead Corporation Dye branched-alkyl borate photoinitiators
JPH0717820Y2 (ja) 1989-08-18 1995-04-26 国産電機株式会社 内燃機関安全装置
US5126394A (en) 1989-10-18 1992-06-30 Dow Corning Corporation Radiation curable abrasion resistant coatings from colloidal silica and acrylate monomer
US5190583A (en) 1989-12-04 1993-03-02 Transfer-Electric Gesellschaft Fur Aqueous coating composition and the use thereof for coating to be protected from light, especially ultraviolet radiation
DE69006472T2 (de) 1989-12-21 1994-09-01 Minnesota Mining & Mfg Zahnärztliche Zusammensetzungen, Verfahren zur Herstellung von geformten, zahnärztlichen Artikeln via "photoiniferte Polymerisation" von zahnärztlichen Zusammensetzungen und dadurch erzeugte geformte, zahnärztliche Artikel.
US5124417A (en) 1990-02-12 1992-06-23 Minnesota Mining And Manufacturing Company Initiators for cationic polymerization
US5084586A (en) 1990-02-12 1992-01-28 Minnesota Mining And Manufacturing Company Novel initiators for cationic polymerization
US5037579A (en) 1990-02-12 1991-08-06 Nalco Chemical Company Hydrothermal process for producing zirconia sol
US5055372A (en) 1990-04-23 1991-10-08 The Mead Corporation Photohardenable composition containing borate salts and ketone initiators
US5332779A (en) 1990-06-04 1994-07-26 Kawasaki Steel Corporation Polymerizable silica sol, adamantane derivative for use in the sol and cured resin prepared using the same
DE9103321U1 (de) 1991-03-19 1992-08-27 Thera Patent GmbH & Co KG Gesellschaft für industrielle Schutzrechte, 8031 Seefeld Transparentversiegelter Dentalkunststoffkörper
US5332429A (en) 1991-05-31 1994-07-26 Minnesota Mining And Manufacturing Company Method for treating fluoroaluminosilicate glass
DE4123946A1 (de) 1991-07-19 1993-01-28 Degussa Dentalmaterial mit alumoorganopolysiloxan-fuellstoff
JP2732968B2 (ja) 1991-09-06 1998-03-30 鐘紡株式会社 歯科用充填組成物
FR2681534B1 (fr) 1991-09-20 1995-01-27 Rhone Poulenc Chimie Solutions collouidales concentrees de particules monocristallines non agregees d'oxydes de metaux, leur procede de preparation et leur application a l'obtention de films.
DE4133621A1 (de) 1991-10-10 1993-04-22 Inst Neue Mat Gemein Gmbh Nanoskalige teilchen enthaltende kompositmaterialien, verfahren zu deren herstellung und deren verwendung fuer optische elemente
FR2689876B1 (fr) 1992-04-08 1994-09-02 Hoechst France Dispersions silico-acryliques, leur procédé d'obtention, leur application en stéréophotolithographie et procédé de préparation d'objets en résine.
DE4212633A1 (de) 1992-04-15 1993-10-21 Inst Neue Mat Gemein Gmbh Verfahren zur Herstellung oberflächenmodifizierter nanoskaliger keramischer Pulver
EP0641290B1 (de) 1992-05-20 1996-09-11 E.I. Du Pont De Nemours And Company Verfahren zur herstellung anorganischer gele
JPH06191827A (ja) 1992-09-04 1994-07-12 Ohara Inc シリカ球状単分散粒子の製造方法
US5502087A (en) 1993-06-23 1996-03-26 Dentsply Research & Development Corp. Dental composition, prosthesis, and method for making dental prosthesis
US5460701A (en) 1993-07-27 1995-10-24 Nanophase Technologies Corporation Method of making nanostructured materials
WO1995027680A1 (en) * 1994-04-11 1995-10-19 Ube Nitto Kasei Co., Ltd. Crosslinked resin-coated fine silica particles and process for producing the same
JP3859737B2 (ja) 1994-04-25 2006-12-20 三菱レイヨン株式会社 歯科用複合材料
JP3437881B2 (ja) 1994-05-12 2003-08-18 三菱レイヨン株式会社 硬化性組成物、複合充填材、及び歯科用修復材料
TW343961B (en) 1994-06-17 1998-11-01 Nissan Chemical Ind Ltd Aqueous zirconia sol and method of preparing same
DE4422118A1 (de) 1994-06-24 1996-01-04 Merck Patent Gmbh Präparationen von monodispersen kugelförmigen Oxidpartikeln
JP3214982B2 (ja) 1994-07-04 2001-10-02 株式会社トクヤマ 無機組成物
US5856373A (en) 1994-10-31 1999-01-05 Minnesota Mining And Manufacturing Company Dental visible light curable epoxy system with enhanced depth of cure
JP3542425B2 (ja) 1994-11-17 2004-07-14 キヤノン株式会社 インクジェット記録用水系分散インク、これを用いるインクジェット記録方法、インクカートリッジ、記録ユニットおよび記録装置
DE19508586C2 (de) 1995-03-13 1997-07-10 Degussa Polymerisierbarer Dentalwerkstoff
EP0767141B1 (de) 1995-03-15 2003-08-13 Hoya Corporation Verfahren zur herstellung eines niederschlags aus metalloxid
US5698483A (en) 1995-03-17 1997-12-16 Institute Of Gas Technology Process for preparing nanosized powder
DE19515820A1 (de) 1995-04-29 1996-10-31 Inst Neue Mat Gemein Gmbh Verfahren zur Herstellung schwach agglomerierter nanoskaliger Teilchen
US5648407A (en) 1995-05-16 1997-07-15 Minnesota Mining And Manufacturing Company Curable resin sols and fiber-reinforced composites derived therefrom
WO1997015526A1 (en) 1995-10-27 1997-05-01 E.I. Du Pont De Nemours And Company Hydrothermal process for making ultrafine metal oxide powders
DE19540623A1 (de) 1995-10-31 1997-05-07 Inst Neue Mat Gemein Gmbh Verfahren zur Herstellung von Kompositmaterialien mit hohem Grenzflächenanteil und dadurch erhältliche Kompositmaterialien
US5820978A (en) * 1995-11-09 1998-10-13 Minnesota Mining And Manufacturing Company Durability improved colloidal silica coating
US5886069A (en) 1995-11-13 1999-03-23 E. I. Du Pont De Nemours And Company Titanium dioxide particles having substantially discrete inorganic particles dispersed on their surfaces
JP3495171B2 (ja) * 1996-01-25 2004-02-09 サンメディカル株式会社 歯科用充填組成物
SE520727C2 (sv) 1996-03-04 2003-08-19 Ciba Sc Holding Ag Alkylfenylbisacylfosfinoxid och fotoinitiatorblandningar
ES2202511T3 (es) * 1996-04-22 2004-04-01 Merck Patent Gmbh Particulas de sio2 recubiertas.
DE19617931C5 (de) * 1996-04-26 2010-07-22 Ivoclar Vivadent Ag Verwendung eines gefüllten und polymerisierbaren Materials als Dentalmaterial
US5942559A (en) * 1996-08-26 1999-08-24 Ivoclar Ag Dental light-curing opaquer
EP0836845B1 (de) * 1996-08-26 2004-05-26 Ivoclar Vivadent AG Dentaler lichthärtender Opaker
WO1998013008A1 (en) 1996-09-27 1998-04-02 Southwest Research Institute Metal oxide compositions and methods
US6030914A (en) 1996-11-12 2000-02-29 Tosoh Corporation Zirconia fine powder and method for its production
JP4086338B2 (ja) 1996-12-06 2008-05-14 株式会社松風 歯科用弾性修復材料並びにそれを用いた歯科補綴材料の作製方法
US5760126A (en) 1996-12-20 1998-06-02 Minnesota Mining And Manufacturing Company Aqueous fluorochemical compositions and abrasion-resistant coatings therefrom
US6025406A (en) 1997-04-11 2000-02-15 3M Innovative Properties Company Ternary photoinitiator system for curing of epoxy resins
AU7653598A (en) * 1997-05-23 1998-12-11 Afga Gevaert Ag Coated particles
US5879715A (en) 1997-09-02 1999-03-09 Ceramem Corporation Process and system for production of inorganic nanoparticles
US5985168A (en) 1997-09-29 1999-11-16 University Of Pittsburgh Of The Commonwealth System Of Higher Education Magnetorheological fluid
US6693143B2 (en) * 1997-10-03 2004-02-17 Dentsply Detrey Gmbh Dental materials having a nanoscale filler
AU752003B2 (en) 1997-10-03 2002-09-05 Dentsply International Inc. Dental materials having a nanoscale filler
DE19806572B4 (de) 1998-02-17 2007-01-25 3M Espe Ag Adhäsive Befestigung von dentalen Füllungsmaterialien
US6121344A (en) 1998-06-19 2000-09-19 Kerr Corporation Optimum particle sized hybrid composite
US6030606A (en) 1998-06-22 2000-02-29 3M Innovative Properties Company Dental restoratives comprising Bis-EMA6
US6210790B1 (en) * 1998-07-15 2001-04-03 Rensselaer Polytechnic Institute Glass-like composites comprising a surface-modified colloidal silica and method of making thereof
JP2002520347A (ja) 1998-07-20 2002-07-09 デンツプライ・インターナショナル・インコーポレイテッド 半透明の耐摩耗性歯科用エナメル質材料および方法
US6051672A (en) * 1998-08-24 2000-04-18 Dow Corning Corporation Method for making hydrophobic non-aggregated colloidal silica
US6306926B1 (en) * 1998-10-07 2001-10-23 3M Innovative Properties Company Radiopaque cationically polymerizable compositions comprising a radiopacifying filler, and method for polymerizing same
US6098906A (en) * 1998-12-04 2000-08-08 Kerr Corporation Vibratory mill and method of use for low contamination grinding
US6417246B1 (en) 1999-09-21 2002-07-09 Jenerica/Pentron Incorporated Dental composite materials
US6376590B2 (en) 1999-10-28 2002-04-23 3M Innovative Properties Company Zirconia sol, process of making and composite material
US6572693B1 (en) * 1999-10-28 2003-06-03 3M Innovative Properties Company Aesthetic dental materials
US6387981B1 (en) 1999-10-28 2002-05-14 3M Innovative Properties Company Radiopaque dental materials with nano-sized particles
JP4800535B2 (ja) 1999-10-28 2011-10-26 スリーエム イノベイティブ プロパティズ カンパニー ナノサイズシリカ粒子を含有する歯科材料
US6586483B2 (en) * 2001-01-08 2003-07-01 3M Innovative Properties Company Foam including surface-modified nanoparticles

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DE60022667T2 (de) 2006-06-14
EP1227781B1 (de) 2005-09-14
CA2387215C (en) 2010-02-09
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US20020156152A1 (en) 2002-10-24
JP4800535B2 (ja) 2011-10-26
US6899948B2 (en) 2005-05-31
WO2001030307A1 (en) 2001-05-03
EP1227781A1 (de) 2002-08-07
JP2011178807A (ja) 2011-09-15
JP5255092B2 (ja) 2013-08-07
EP1586294B1 (de) 2009-04-15
JP2003512407A (ja) 2003-04-02
EP1586294A1 (de) 2005-10-19
EP1586294B2 (de) 2016-02-17
EP1227781B9 (de) 2006-03-08
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