DE60016014D1 - Herstellung von polyethylenen - Google Patents
Herstellung von polyethylenenInfo
- Publication number
- DE60016014D1 DE60016014D1 DE60016014T DE60016014T DE60016014D1 DE 60016014 D1 DE60016014 D1 DE 60016014D1 DE 60016014 T DE60016014 T DE 60016014T DE 60016014 T DE60016014 T DE 60016014T DE 60016014 D1 DE60016014 D1 DE 60016014D1
- Authority
- DE
- Germany
- Prior art keywords
- olefins
- alpha
- ethylene
- blends
- process conditions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/607—Catalysts containing a specific non-metal or metal-free compound
- C08F4/609—Catalysts containing a specific non-metal or metal-free compound organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61904—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with another component of C08F4/60
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15658899P | 1999-09-29 | 1999-09-29 | |
| US156588P | 1999-09-29 | ||
| PCT/US2000/026643 WO2001023443A1 (en) | 1999-09-29 | 2000-09-28 | Manufacture of polyethylenes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60016014D1 true DE60016014D1 (de) | 2004-12-23 |
| DE60016014T2 DE60016014T2 (de) | 2005-11-24 |
Family
ID=22560194
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60016014T Expired - Lifetime DE60016014T2 (de) | 1999-09-29 | 2000-09-28 | Herstellung von polyethylenen |
Country Status (11)
| Country | Link |
|---|---|
| US (3) | US6555631B1 (de) |
| EP (1) | EP1228110B1 (de) |
| JP (1) | JP2003510427A (de) |
| KR (1) | KR20020037364A (de) |
| CN (2) | CN1939934B (de) |
| AT (1) | ATE282645T1 (de) |
| AU (1) | AU7726800A (de) |
| BR (2) | BR0014639B1 (de) |
| CA (1) | CA2379607A1 (de) |
| DE (1) | DE60016014T2 (de) |
| WO (1) | WO2001023443A1 (de) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6458979B1 (en) * | 1999-04-29 | 2002-10-01 | E. I. Du Pont De Nemours And Company | Polymerization of ethylene |
| MXPA04006611A (es) * | 2002-01-09 | 2004-10-04 | Du Pont | Catalizador para polimerizacion de olefinas. |
| US7081506B2 (en) * | 2003-10-23 | 2006-07-25 | Fina Technology, Inc. | Ethylene polymerization employing bis-imino pyridinyl transition metal catalyst components |
| US7410926B2 (en) * | 2003-12-30 | 2008-08-12 | Univation Technologies, Llc | Polymerization process using a supported, treated catalyst system |
| DE102004020525A1 (de) * | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Katalysatorsystem zur Olefinpolymerisation, dessen Herstellung und Verwendung |
| DE102004020524A1 (de) * | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung |
| US7442819B2 (en) * | 2004-07-09 | 2008-10-28 | E. I. Du Pont De Nemours And Company | Catalysts for olefin polymerization or oligomerization |
| EP1650231A1 (de) * | 2004-10-21 | 2006-04-26 | Total Petrochemicals Research Feluy | Polyolefine hergestellt mit Metallocen- und neuen Single-Site-Katalysatorkomponenten in einem Reaktor |
| US20070010626A1 (en) * | 2005-07-11 | 2007-01-11 | Shankernarayanan Manivakkam J | Polyethylene compositions |
| US7271121B2 (en) | 2005-07-21 | 2007-09-18 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
| US7268096B2 (en) | 2005-07-21 | 2007-09-11 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
| US7727926B2 (en) | 2005-07-21 | 2010-06-01 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization |
| US20070255026A1 (en) * | 2006-04-28 | 2007-11-01 | Fina Technology, Inc. | Process for polyolefin production using fluorinated transition metal catalysts having a low pH |
| BRPI0906091B8 (pt) | 2008-03-13 | 2019-05-14 | Dow Global Technologies Inc | polímetro etilênico e processo para preparar polímetros etilênicos. |
| US8633287B2 (en) * | 2009-08-17 | 2014-01-21 | E I Du Pont De Nemours And Company | Olefin polymerization process |
| US8618228B2 (en) * | 2010-01-21 | 2013-12-31 | Basell Polyolefine Gmbh | Process for the preparation of ethylene copolymer compositions in the presence of an oligomerization catalyst |
| EP2552863A1 (de) * | 2010-03-29 | 2013-02-06 | E.I. Du Pont De Nemours And Company | Schmiermittelkomponente |
| JP2012224842A (ja) * | 2011-03-30 | 2012-11-15 | Sumitomo Chemical Co Ltd | エチレン系重合体製造用触媒およびエチレン系重合体の製造方法 |
| US9586872B2 (en) | 2011-12-30 | 2017-03-07 | Chevron Phillips Chemical Company Lp | Olefin oligomerization methods |
| KR102102347B1 (ko) | 2012-05-09 | 2020-04-21 | 사솔 테크날러지 (프로프라이어터리) 리미티드 | 에틸렌의 사량체화 |
| EP3209722B1 (de) | 2014-10-21 | 2025-07-16 | Nova Chemicals (International) S.A. | Ethylen interpolymer produkt mit einem verdünnungsindex |
| CA2868640C (en) | 2014-10-21 | 2021-10-26 | Nova Chemicals Corporation | Solution polymerization process |
| US9944661B2 (en) | 2016-08-09 | 2018-04-17 | Chevron Phillips Chemical Company Lp | Olefin hydroboration |
| US10329412B2 (en) | 2017-02-16 | 2019-06-25 | Nova Chemicals (International) S.A. | Caps and closures |
| US10442921B2 (en) | 2017-04-19 | 2019-10-15 | Nova Chemicals (International) S.A. | Means for increasing the molecular weight and decreasing the density employing mixed homogeneous catalyst formulations |
| US10442920B2 (en) | 2017-04-19 | 2019-10-15 | Nova Chemicals (International) S.A. | Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations |
| US10995166B2 (en) | 2017-11-07 | 2021-05-04 | Nova Chemicals (International) S.A. | Ethylene interpolymer products and films |
| US10683376B2 (en) | 2017-11-07 | 2020-06-16 | Nova Chemicals (International) S.A. | Manufacturing ethylene interpolymer products at higher production rate |
| JP7050544B2 (ja) * | 2018-03-27 | 2022-04-08 | Eneos株式会社 | ワックス異性化油の製造方法 |
| US10882987B2 (en) | 2019-01-09 | 2021-01-05 | Nova Chemicals (International) S.A. | Ethylene interpolymer products having intermediate branching |
| US11046843B2 (en) | 2019-07-29 | 2021-06-29 | Nova Chemicals (International) S.A. | Ethylene copolymers and films with excellent sealing properties |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4937299A (en) * | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
| DE3621763A1 (de) | 1986-06-28 | 1988-01-21 | Bayer Ag | Verfahren zur herstellung von verzweigtem niederdruckpolyethen, neue niederdruckpolyethene und praeformierte bifunktionelle katalysatoren |
| FI85588C (fi) | 1989-06-05 | 1992-05-11 | Neste Oy | Foerfarande foer reglering av molekylviktsfoerdelningen och molekylvikten av oligomerisations- eller polymerisationsprodukter av eten. |
| US5071927A (en) | 1990-10-09 | 1991-12-10 | Phillips Petroleum Company | High-temperature slurry polymerization of ethylene |
| US5137994A (en) | 1991-05-23 | 1992-08-11 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the simultaneous trimerization and copolymerization of ethylene |
| EP0516019B1 (de) | 1991-05-27 | 1995-12-27 | Hoechst Aktiengesellschaft | Verfahren zur Herstellung von syndiotaktischen Polyolefinen mit breiter Molmassenverteilung |
| ES2155095T5 (es) * | 1993-10-21 | 2006-04-16 | Exxonmobil Oil Corporation | Mezclas de poliolefinas con distribucion bimodal de pesos moleculares. |
| JPH09143228A (ja) | 1995-11-22 | 1997-06-03 | Sumitomo Chem Co Ltd | エチレン−α−オレフィン共重合体の製造方法 |
| JPH09309926A (ja) * | 1996-05-17 | 1997-12-02 | Dow Chem Co:The | エチレン共重合体の製造方法 |
| WO1997048735A1 (en) * | 1996-06-17 | 1997-12-24 | Exxon Chemical Patents Inc. | Mixed transition metal catalyst systems for olefin polymerization |
| US5753785A (en) | 1996-12-16 | 1998-05-19 | Fina Technology, Inc. | Production of E-B copolymers with a single metallocene catalyst and a single monomer |
| IL129929A0 (en) * | 1996-12-17 | 2000-02-29 | Du Pont | Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt |
| US6214761B1 (en) * | 1996-12-17 | 2001-04-10 | E. I. Du Pont De Nemours And Company | Iron catalyst for the polymerization of olefins |
| US6177377B1 (en) * | 1996-12-18 | 2001-01-23 | Amherst Polymer Technology, Inc. | Polymer blends and process for preparation |
| DE19707236A1 (de) * | 1997-02-24 | 1998-08-27 | Targor Gmbh | Katalysatorzusammensetzung |
| US6103946A (en) * | 1997-07-15 | 2000-08-15 | E. I. Du Pont De Nemours And Company | Manufacture of α-olefins |
| US6114483A (en) * | 1997-08-27 | 2000-09-05 | E. I. Du Pont De Nemours And Company | Polymerization of olefins |
| CA2324310A1 (en) * | 1998-03-30 | 1999-10-07 | E.I. Du Pont De Nemours And Company | Polymerization of olefins |
| CN100441604C (zh) * | 1998-05-29 | 2008-12-10 | 纳幕尔杜邦公司 | 烯烃的共聚合 |
| GB9819847D0 (en) * | 1998-09-12 | 1998-11-04 | Bp Chem Int Ltd | Novel compounds |
-
2000
- 2000-09-28 WO PCT/US2000/026643 patent/WO2001023443A1/en not_active Ceased
- 2000-09-28 BR BRPI0014639-0A patent/BR0014639B1/pt not_active IP Right Cessation
- 2000-09-28 KR KR1020027004026A patent/KR20020037364A/ko not_active Withdrawn
- 2000-09-28 JP JP2001526591A patent/JP2003510427A/ja active Pending
- 2000-09-28 AU AU77268/00A patent/AU7726800A/en not_active Abandoned
- 2000-09-28 AT AT00967006T patent/ATE282645T1/de not_active IP Right Cessation
- 2000-09-28 DE DE60016014T patent/DE60016014T2/de not_active Expired - Lifetime
- 2000-09-28 EP EP00967006A patent/EP1228110B1/de not_active Expired - Lifetime
- 2000-09-28 BR BRPI0017587-0B1A patent/BR0017587B1/pt not_active IP Right Cessation
- 2000-09-28 CA CA002379607A patent/CA2379607A1/en not_active Abandoned
- 2000-09-28 CN CN2006101423259A patent/CN1939934B/zh not_active Expired - Lifetime
- 2000-09-28 CN CN00813383A patent/CN1377377A/zh active Pending
- 2000-09-28 US US09/672,612 patent/US6555631B1/en not_active Expired - Lifetime
-
2003
- 2003-02-06 US US10/359,336 patent/US6921795B2/en not_active Expired - Lifetime
- 2003-09-10 US US10/659,169 patent/US20040048989A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| BR0014639B1 (pt) | 2011-02-22 |
| WO2001023443A1 (en) | 2001-04-05 |
| CN1377377A (zh) | 2002-10-30 |
| JP2003510427A (ja) | 2003-03-18 |
| CN1939934B (zh) | 2010-09-01 |
| ATE282645T1 (de) | 2004-12-15 |
| US20040048989A1 (en) | 2004-03-11 |
| KR20020037364A (ko) | 2002-05-18 |
| BR0014639A (pt) | 2002-06-11 |
| DE60016014T2 (de) | 2005-11-24 |
| AU7726800A (en) | 2001-04-30 |
| EP1228110A1 (de) | 2002-08-07 |
| CA2379607A1 (en) | 2001-04-05 |
| EP1228110B1 (de) | 2004-11-17 |
| BR0017587B1 (pt) | 2013-07-16 |
| US6555631B1 (en) | 2003-04-29 |
| CN1939934A (zh) | 2007-04-04 |
| US6921795B2 (en) | 2005-07-26 |
| US20030149182A1 (en) | 2003-08-07 |
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