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DE60011897D1 - Verfahren zur herstellung von alpha-olefin polymeren - Google Patents

Verfahren zur herstellung von alpha-olefin polymeren

Info

Publication number
DE60011897D1
DE60011897D1 DE60011897T DE60011897T DE60011897D1 DE 60011897 D1 DE60011897 D1 DE 60011897D1 DE 60011897 T DE60011897 T DE 60011897T DE 60011897 T DE60011897 T DE 60011897T DE 60011897 D1 DE60011897 D1 DE 60011897D1
Authority
DE
Germany
Prior art keywords
stage
gas phase
olefin polymers
producing alpha
phase reactor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60011897T
Other languages
English (en)
Other versions
DE60011897T2 (de
Inventor
Pauli Leskinen
Kauno Alastalo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Borealis Technology Oy
Original Assignee
Borealis Technology Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis Technology Oy filed Critical Borealis Technology Oy
Application granted granted Critical
Publication of DE60011897D1 publication Critical patent/DE60011897D1/de
Publication of DE60011897T2 publication Critical patent/DE60011897T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/002Scale prevention in a polymerisation reactor or its auxiliary parts
    • C08F2/005Scale prevention in a polymerisation reactor or its auxiliary parts by addition of a scale inhibitor to the polymerisation medium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/44Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/622Component covered by group C08F4/62 with an organo-aluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/626Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/62
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/05Transitioning, i.e. transition from one catalyst to another with use of a deactivating agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE60011897T 1999-05-04 2000-05-04 Verfahren zur Herstellung von α-Olefin Polymeren Expired - Lifetime DE60011897T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FI991015 1999-05-04
FI991015A FI991015A0 (fi) 1999-05-04 1999-05-04 Menetelmä alfa-olefiinipolymeerien valmistamiseksi
PCT/FI2000/000398 WO2000066640A1 (en) 1999-05-04 2000-05-04 Process for producing alfa-olefin polymers

Publications (2)

Publication Number Publication Date
DE60011897D1 true DE60011897D1 (de) 2004-08-05
DE60011897T2 DE60011897T2 (de) 2005-08-25

Family

ID=8554587

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60011897T Expired - Lifetime DE60011897T2 (de) 1999-05-04 2000-05-04 Verfahren zur Herstellung von α-Olefin Polymeren

Country Status (12)

Country Link
US (1) US6689846B1 (de)
EP (1) EP1183285B1 (de)
KR (1) KR100570557B1 (de)
CN (1) CN1175012C (de)
AT (1) ATE270309T1 (de)
AU (1) AU769562B2 (de)
BR (1) BR0010301B1 (de)
CA (1) CA2372574C (de)
DE (1) DE60011897T2 (de)
ES (1) ES2223513T3 (de)
FI (1) FI991015A0 (de)
WO (1) WO2000066640A1 (de)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1598377A1 (de) * 2004-05-21 2005-11-23 Borealis Polymers Oy Verfahren zur Herstellung von heterophaischem Polyolefin
DE102005002513B4 (de) * 2004-09-09 2007-09-13 Rema Lipprandt Gmbh & Co. Kg Verfahren zur Herstellung einer Steckdose und eines Steckers einer Geräte-Steckvorrichtung sowie einer Platinen-Steckvorrichtung, sowie Steckdose und Stecker hergestellt nach einem derartigen Verfahren
JP4987722B2 (ja) 2004-10-14 2012-07-25 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ オレフィン類の気相重合方法
US8110518B2 (en) * 2006-04-28 2012-02-07 Fina Technology, Inc. Fluorinated transition metal catalysts and formation thereof
US20070255022A1 (en) * 2006-04-28 2007-11-01 Fina Technology, Inc. Fluorinated transition metal catalysts and formation thereof
ES2360530T5 (es) * 2007-05-25 2014-02-10 Borealis Technology Oy Procedimiento de preparación de una resina polimérica de alfa-olefina
DE102007042252A1 (de) * 2007-09-06 2009-03-12 Basell Polyolefine Gmbh Kontinuierliche Zufuhr von Hilfsstoffen zur Polymerisation von Olefinen
US8138285B2 (en) * 2007-10-26 2012-03-20 Fina Technology, Inc. Fluorinated impregnated catalyst systems and methods of forming the same
ATE529450T1 (de) 2009-02-25 2011-11-15 Borealis Ag Multimodales polymer aus propylen, zusammensetzung damit und verfahren zur herstellung davon
EP2223944A1 (de) 2009-02-26 2010-09-01 Borealis AG Verfahren zur Herstellung von Semikristallin-Propylenpolymeren
US9637570B2 (en) * 2009-06-11 2017-05-02 Exxonmobil Chemical Patents Inc. Method and apparatus for reducing fouling
EP2452957A1 (de) 2010-11-12 2012-05-16 Borealis AG Verbessertes Verfahren zur Herstellung heterophasischer Propylencopolymere
EP2452960B1 (de) 2010-11-12 2015-01-07 Borealis AG Verfahren zur Herstellung von Propylencopolymeren mit einer extrem hohen Schmelzflussrate
EP2452959B1 (de) 2010-11-12 2015-01-21 Borealis AG Verfahren zur Herstellung von statistischen Propylencopolymeren und deren Verwendung
CN103429656B (zh) * 2010-12-20 2016-06-29 美国布拉斯科姆有限公司 具有增强的外观及优良的模塑流动性的基于丙烯的组合物
EP2953986A4 (de) * 2013-02-06 2016-04-20 Exxonmobil Chem Patents Inc Einsetzendes feuchtigkeitsverfahren zur erhöhung der produktivität von unterstützten ziegler-natta-katalysatoren
US9428598B2 (en) 2014-02-07 2016-08-30 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US11267916B2 (en) 2014-02-07 2022-03-08 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US10723824B2 (en) 2014-02-07 2020-07-28 Eastman Chemical Company Adhesives comprising amorphous propylene-ethylene copolymers
US10696765B2 (en) 2014-02-07 2020-06-30 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer
US10308740B2 (en) 2014-02-07 2019-06-04 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US10647795B2 (en) 2014-02-07 2020-05-12 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
RU2726620C1 (ru) * 2016-12-22 2020-07-15 Сабик Глобал Текнолоджис Б.В. Способы получения линейных альфа-олефинов
PL3567061T3 (pl) 2018-05-09 2024-02-26 Borealis Ag Kompozycja polipropylenowa dla rur
US11820879B2 (en) 2018-12-28 2023-11-21 Braskem S.A. Continuous feed of antistatic agent for gas phase polymerization process
US11352375B2 (en) 2018-12-28 2022-06-07 Braskem S.A. Auxiliaries for olefin polymerization process
EP3868793B1 (de) * 2020-02-24 2026-01-07 Borealis GmbH Verfahren zur herstellung von alpha-olefinpolymeren in einem mehrstufigen polymerisationsverfahren
PL4257640T3 (pl) 2022-04-04 2025-03-24 Borealis Ag Rura zawierająca kompozycję polipropylonową

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4182810A (en) * 1978-04-21 1980-01-08 Phillips Petroleum Company Prevention of fouling in polymerization reactors
FR2538398B1 (fr) 1982-12-24 1986-01-24 Charbonnages Ste Chimique Procede continu ameliore de fabrication d'homopolymeres ou de copolymeres de l'ethylene
JPS62116618A (ja) 1985-11-15 1987-05-28 Chisso Corp プロピレン−エチレンブロツク共重合体の連続製造法
JPH0730144B2 (ja) 1986-08-14 1995-04-05 チッソ株式会社 プロピレン−エチレンブロツク共重合体の連続製造法
US5026795A (en) * 1987-02-24 1991-06-25 Phillips Petroleum Co Process for preventing fouling in a gas phase polymerization reactor
EP0282929B2 (de) 1987-03-14 1997-10-22 Mitsubishi Kasei Corporation Verfahren zur Herstellung eines Propylen-alpha-Olefin-Blockkopolymers
US5037905A (en) 1989-12-07 1991-08-06 Union Carbide Chemicals And Plastics Technology Corporation Process for reducing polymer build-up in heat exchangers during polymerization of alpha-olefins
US5118757A (en) 1990-03-26 1992-06-02 Shell Oil Company Polymer production
FR2660926B1 (fr) * 1990-04-11 1992-07-31 Bp Chemicals Snc Prepolymere d'alpha-olefine contenant un metal de transition et procede de polymerisation d'alpha-olefine en phase gazeuse mettant en óoeuvre le prepolymere.
FI94164C (fi) 1991-03-21 1995-07-25 Borealis Polymers Oy Menetelmä juoksevaksi saatetun polymerointikatalyytin annostelemiseksi polymerointireaktoriin
FI88047C (fi) 1991-05-09 1993-03-25 Neste Oy Pao tvenne elektrondonorer baserad katalysator foer polymerisation av olefiner
IT1246614B (it) * 1991-06-03 1994-11-24 Himont Inc Procedimento per la polimerizzazione in fase gas delle olefine
AU678066B2 (en) 1993-09-16 1997-05-15 Shell Oil Company Polymer production
US5625012A (en) * 1994-06-29 1997-04-29 Union Carbide Chemicals & Plastics Technology Corporation Process for reducing polymer build-up in recycle lines and heat exchangers during polymerization of alpha olefins
IT1270125B (it) * 1994-10-05 1997-04-28 Spherilene Srl Processo per la ( co) polimerizzazione di olefine
FI101479B1 (fi) * 1994-12-22 1998-06-30 Borealis Polymers Oy Menetelmä likaantumisen estämiseksi polymerointireaktoreissa
FI104827B (fi) * 1995-04-12 2000-04-14 Borealis Polymers Oy Menetelmä likaantumisen ja kerrostumisen estämiseksi kaasufaasireaktoreissa
JP3355864B2 (ja) 1995-04-24 2002-12-09 チッソ株式会社 高剛性プロピレン・エチレンブロック共重合体の連続製造法

Also Published As

Publication number Publication date
CN1175012C (zh) 2004-11-10
CA2372574C (en) 2009-12-08
US6689846B1 (en) 2004-02-10
BR0010301A (pt) 2002-02-13
BR0010301B1 (pt) 2010-07-27
FI991015A0 (fi) 1999-05-04
KR20020013536A (ko) 2002-02-20
DE60011897T2 (de) 2005-08-25
ATE270309T1 (de) 2004-07-15
AU4569800A (en) 2000-11-17
AU769562B2 (en) 2004-01-29
CA2372574A1 (en) 2000-11-09
EP1183285B1 (de) 2004-06-30
WO2000066640A1 (en) 2000-11-09
KR100570557B1 (ko) 2006-04-24
EP1183285A1 (de) 2002-03-06
ES2223513T3 (es) 2005-03-01
CN1359397A (zh) 2002-07-17

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