DE20007651U1 - Hair dye - Google Patents

Description

Hair dye

The present invention relates to a hair dye based on a peroxide-reacting oxidation dye system which provides permanent, intense shades which can either be used as such or, in combination with other developers and/or couplers, to achieve further colour nuances and which do not damage the hair even when used repeatedly over a short period of time.

The developer substances most commonly used in hair dyes are 1,4-diaminobenzene (p-phenylenediamine) and 1-methyl-2,5-diaminobenzene (p-toluenediamine). Although the use of these substances largely meets the color-technical requirements of users, there are still color nuances that cannot be fully achieved.

It has already been proposed to close this gap by using alternative developing substances. This is possible to a limited extent by using tetraaminopyrimidine or 2-(2,5-diaminophenyl)ethanol (cf. EP-A 7537 and EP-B 400 330); however, compromises in the color intensity of other shades must then be accepted.

A largely optimal solution to this problem is provided by the use of 2-(2'-hydroxyethylamino)-5-aminotoluene or its water-soluble salts described in EP-A 615 743 and the triaminohydroxypyrimidines known from EP-B 467 026, in particular 2,5,6-triamino-4-hydroxypyrimidine, 2,4,5-

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Triamino-6-hydroxypyrimidine, 4,5,6-triamino-2-hydroxypyrimidine or their salts, especially the sulfates, as developer substances in hair dyes. However, even this still leaves some color-technical wishes unfulfilled.

The invention is therefore based on the task of creating a hair dye which is suitable for producing a large number of shades and which does not damage the hair even when used repeatedly for a short period of time.

This object is achieved in that such a hair dye contains an oxidation dye system which reacts with peroxide and consists of a combination of 2,5-diaminohydroquinone or its water-soluble salts and at least one further coupler and/or developer substance.

This is preferably selected from the group 1-methoxy-2-amino-4-(ß-hydroxyethylamino)benzene, 2-amino-3-hydroxypyridine, 2,5-diaminopyridine, 2,6-diaminopyridine, S-amino^-methylamino-e-methoxypyridine, 2-(dimethylamino)-5-aminopyridine, 1-(ß-hydroxyethyl)-2,5-diaminobenzene, 1-(2'-hydroxyethylamino)-5-aminotoluene, 1-amino-4-bis-(2'-hydroxyethyl)aminobenzene, a tetraaminopyrimidine, in particular 2,4,5,6-tetraaminopyrimidine, a triaminohydroxypyrimidine, in particular 2,5,6-triamino-4-hydroxypyrimidine, 2-amino-5-N,N-diethylaminotoluene, 1,4-diaminobenzene, 1,3-diaminobenzene, 2,5-diaminotoluene, resorcinol, 2-methylresorcinol, 4-chlororesorcinol, 2-amino-4-chlorophenol, 1,6-dihydroxynaphthalene, 1,7-dihydroxynaphthalene, 2-aminophenol, 3-aminophenol, 4-aminophenol, 1 -methyl^-hydroxy^-aminobenzene, 5-amino-2 -methoxyphenol, 5-amino-3-methylphenol, 2-methyl-5-hydroxyethylaminophenol, 4-amino-3-methylphenol, 5-amino-2-methylphenol, 2-amino-4-ß-hydroxyethylaminoanisole and/or 1-naphthol b^w.. everyone.wa9seclösliQhen"Qalzen;··· .: : : .:

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However, this does not mean that the addition of further developers and couplers should be excluded.

When these compositions are used on a conventional base, very expressive, intense, permanent hair colors are obtained after oxidation with peroxide, especially in the yellow, brown and pink range, which can be varied to other color nuances by adding appropriate additional developers and couplers.

The 2,5-diaminohydroquinone is preferably present as a water-soluble salt, in particular as a hydrochloride.

The additional use of other known developing substances is also possible. In addition to those already mentioned above, 5-aminosalicylic acid and/or 1,2,4-triaminobenzene are particularly worth mentioning.

The total concentration of the developing substances is usually between about 0.05 and 5%, preferably 0.1 and 4%, in particular 0.25 to 0.5% and 2.5 to 3% by weight of the total composition of the hair dye (without oxidizing agent), whereby the information in each case refers to the proportion of free base.

The preferred weight ratio of 2,5-diaminohydroquinone to the other developer and coupler substances is between about 1:8 to 8:1, preferably about 1:5 to 5:1, in particular 1:2 to 2:1.

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The coupler substance(s) as reaction partner of the developer substance(s) are present in the hair dyes according to the invention in approximately the same molar proportion as the developer substances, i.e. in amounts of 0.05 to 5.0%, preferably 0.1 to 4%, in particular 0.5 to 3% by weight of the total composition (without oxidizing agent), whereby the information in each case refers to the proportion of free base.

If desired, the compositions according to the invention can also contain so-called shading agents for fine-tuning the desired color tone, in particular direct dyes.

Such nuancers are, for example, nitro dyes such as 2-amino-4,6-dinitrophenol, 2-amino-4-nitrophenol, 2-amino-6-chloro-4-nitrophenol, etc., preferably in amounts of about 0.05 to 2.5%, in particular 0.1 to 1% by weight of the color composition (without oxidizing agent).

The hair dyes according to the invention can contain the basic and additive substances, conditioning agents, etc. that are customary in such agents and that are known to the person skilled in the art from the prior art and are described, for example, in the monograph by K. Schrader, "Grundlagen und Rezepturen der Kosmetika", 2nd edition (Hüthig Buch Verlag, Heidelberg, 1989), pp. 782 to 815. They can be in the form of solutions, creams, gels or in the form of aerosol preparations; suitable carrier material compositions are sufficiently known from the prior art.

For application, the oxidation dye precursor according to the invention is mixed with an oxidizing agent. The preferred oxidizing agent is hydrogen peroxide _, e-fJfö

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However, other peroxides such as urea peroxide and melamine peroxide can also be used.

The pH value of the ready-to-use hair dye, i.e. after mixing with peroxide, can be either in the weakly acidic range, i.e. a range from 5.5 to 6.9, in the neutral range or in the alkaline range, i.e. between pH 7.1 and 10.

In the following, various : i:" .·' Mil Examples of implementation; to explain the •# · invention given. basis Stearyl alcohol 8.0 (wt.%) Coconut fatty acid monoethanolamide 4.5 1,2-Propanediol mono/distearate 1.3 Coconut fatty alcohol polyglycol ether 4.0 Sodium lauryl sulfate 1.0 Oleic acid 2.0 1,2-Propanediol 1.5 Na-EDTA 0.5 Sodium sulphite 1.0 Protein hydrolysate 0.5 Ascorbic acid 0.2 Perfume 0.4 Ammonia, 25% 1.0 Ammonium chloride 0.5 Panthenol 0.8 Water @ 100,00 ·· ···· ·■ ···· · ·
·· · ·····* · ·
··· · · ·· *

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The oxidation dye combinations according to the invention were incorporated into this base, with a corresponding reduction in the water content.

The dyeing was carried out on wool patches and strands of bleached human hair by applying a 1:1 mixture of dye precursor and 6% hydrogen peroxide solution (pH value of the mixture: 9.8) and leaving it for 20 minutes at room temperature, followed by rinsing and drying.

The following colorations were achieved:

Example 1:

0.48 (% by weight) a.S-diaminohydroquinone dihydrochloride

(PC-85)

0.28 1-methyl-2-hydroxy-4-aminobenzene

Coloring:

Shiny light pink.

Example 2:

0.48 (wt%) PC-85

0.25 2,6-Diaminopyridine

Coloring:

Shiny light yellow.

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Example 3:

0.48 (wt%) PC-85

0.50 2,5-Diaminotoluene sulfate

Coloring:

Shiny brown-pink.

Example 4:

0.48 (wt%) PC-85

0.25 4-Aminophenol

Coloring:

Shiny reddish brown pink.

Example 5:

0.48 (wt%) PC-85

0.24 1,3-diaiminobenzene

Coloring:

Shiny yellow-pink.

Example 6:

0.48 (wt%) PC-85

0.49 2-Amino-5-diethylaminotoluene dihydro-

chloride coloring:

Shiny light grey pink.

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Example 7:

0.48 (wt%) PC-85

0.28 2-methylresorcinol

Color:

Shiny yellow-pink.

Example 8:

0.48 (wt%) PC-85

0.28 6-Amino-3-methylphenol

Color:

Intense, shiny golden yellow.

Example 9:

0.48 (wt%) PC-85

0.28 4-Amino-3-methylphenol

Color:

Shiny light pink.

Example 10:

0.48 (wt%) PC-85

0.54 4-Hydroxy-2,5,6-triaminopyrimidine sulfate

Color:

Shiny yellow-pink.

Claims (2)

1. Hair dye based on an oxidation dye precursor which reacts with peroxide, containing 2,5-diaminohydroquinone and/or its water-soluble salts and at least one further developer and/or coupler substance. 2. Hair dye according to claim 1, containing as further developer and coupler substance(s) at least one component selected from the group 1-methoxy-2-amino-4-(β-hydroxyethylamino)benzene, 2-amino-3-hydroxypyridine, 2,5-diaminopyridine, 2-amino-3-hydroxypyridine, 2,6-diaminopyridine, 3-amino-2-methylamino-6-methoxypyridine, 2-(dimethylamino)-5-aminopyridine, 1-(β-hydroxyethyl)-2,5-diaminobenzene, 2-(2'-hydroxyethylamino)-5-aminotoluene, 1-amino-4-bis-(2'-hydroxyethyl)-aminobenzene, a tetraaminopyrimidine, a triaminohydroxypyrimidine, 5-amino-2-methylphenol, 5-amino-3-methylphenol, 2-methyl- 5-hydroxyethylaminophenol, 4-amino-3-methylphenol, 2-amino-5-N,N-diethylaminotoluene, 1,4-diaminobenzene, 2,5-diaminotoluene, 2-amino-4-chlorophenol, 1,3-diaminobenzene, 1-methyl-2-hydroxy-4-aminobenzene, 1,6-dihydroxynaphthalene, 1,7-dihydroxynaphthalene, resorcinol, 2-methylresorcinol, 4-chlororesorcinol, 1-naphthol, 4-aminophenol, 2-aminophenol, 5-amino-2-methoxyphenol, 2-amino-4-βhydroxyethylaminoanisole and/or 3-aminophenol or their water-soluble salts.