DE19820949A1 - Hair spray composition with good application properties - Google Patents
Hair spray composition with good application propertiesInfo
- Publication number
- DE19820949A1 DE19820949A1 DE1998120949 DE19820949A DE19820949A1 DE 19820949 A1 DE19820949 A1 DE 19820949A1 DE 1998120949 DE1998120949 DE 1998120949 DE 19820949 A DE19820949 A DE 19820949A DE 19820949 A1 DE19820949 A1 DE 19820949A1
- Authority
- DE
- Germany
- Prior art keywords
- weight
- hair spray
- spray composition
- good application
- application properties
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 17
- 239000008266 hair spray Substances 0.000 title claims abstract description 14
- 229920000642 polymer Polymers 0.000 claims abstract description 14
- 239000000654 additive Substances 0.000 claims abstract description 6
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229940008099 dimethicone Drugs 0.000 claims abstract description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 5
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims abstract description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- ANXXYABAFAQBOT-UHFFFAOYSA-N dodecyl-methyl-bis(trimethylsilyloxy)silane Chemical compound CCCCCCCCCCCC[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C ANXXYABAFAQBOT-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000003960 organic solvent Substances 0.000 claims abstract description 4
- -1 siloxanes Chemical class 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 7
- 239000004604 Blowing Agent Substances 0.000 claims description 2
- ACXIAEKDVUJRSK-UHFFFAOYSA-N methyl(silyloxy)silane Chemical compound C[SiH2]O[SiH3] ACXIAEKDVUJRSK-UHFFFAOYSA-N 0.000 claims 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical compound [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract description 2
- 239000003380 propellant Substances 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 6
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 5
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 5
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 150000007942 carboxylates Chemical group 0.000 description 3
- 229940073561 hexamethyldisiloxane Drugs 0.000 description 3
- ZKYCLDTVJCJYIB-UHFFFAOYSA-N 2-methylidenedecanamide Chemical compound CCCCCCCCC(=C)C(N)=O ZKYCLDTVJCJYIB-UHFFFAOYSA-N 0.000 description 2
- MXRGSJAOLKBZLU-UHFFFAOYSA-N 3-ethenylazepan-2-one Chemical compound C=CC1CCCCNC1=O MXRGSJAOLKBZLU-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000003570 air Substances 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 2
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 description 1
- NMGPHUOPSWFUEB-UHFFFAOYSA-N 2-(butylamino)ethyl 2-methylprop-2-enoate Chemical compound CCCCNCCOC(=O)C(C)=C NMGPHUOPSWFUEB-UHFFFAOYSA-N 0.000 description 1
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 1
- YZTJKOLMWJNVFH-UHFFFAOYSA-N 2-sulfobenzene-1,3-dicarboxylic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1S(O)(=O)=O YZTJKOLMWJNVFH-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- UTOVMEACOLCUCK-PLNGDYQASA-N butyl maleate Chemical compound CCCCOC(=O)\C=C/C(O)=O UTOVMEACOLCUCK-PLNGDYQASA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000003766 combability Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- NKDDWNXOKDWJAK-UHFFFAOYSA-N dimethoxymethane Chemical compound COCOC NKDDWNXOKDWJAK-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- TVFJAZCVMOXQRK-UHFFFAOYSA-N ethenyl 7,7-dimethyloctanoate Chemical compound CC(C)(C)CCCCCC(=O)OC=C TVFJAZCVMOXQRK-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000013020 final formulation Substances 0.000 description 1
- 239000000834 fixative Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- QQVIHTHCMHWDBS-UHFFFAOYSA-L isophthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC(C([O-])=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-L 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- UZNHKBFIBYXPDV-UHFFFAOYSA-N trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)NCCC[N+](C)(C)C UZNHKBFIBYXPDV-UHFFFAOYSA-N 0.000 description 1
- WZKPOPMJOWWSBZ-UHFFFAOYSA-N trimethyl-[phenyl-[phenyl-bis(trimethylsilyloxy)silyl]oxy-trimethylsilyloxysilyl]oxysilane Chemical compound C=1C=CC=CC=1[Si](O[Si](C)(C)C)(O[Si](C)(C)C)O[Si](O[Si](C)(C)C)(O[Si](C)(C)C)C1=CC=CC=C1 WZKPOPMJOWWSBZ-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/88—Polyamides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
Abstract
Description
Für die Festigung von Haarfrisuren werden seit fast 50 Jahren erfolgreich synthetische Polymere eingesetzt. Während in der An fangszeit bevorzugt Vinyllactam-Homo- und Copolymere zum Einsatz gelangten, haben später carboxylatgruppenhaltige Polymere zu nehmend an Bedeutung gewonnen. Das gewünschte Eigenschaftsprofil wie starke Festigung bei hoher Luftfeuchtigkeit, Elastizität, Auswaschbarkeit vom Haar und Verträglichkeit mit den übrigen Formulierungskomponenten werden durch Copolymerisation einer Kombination von hydrophoben, elastifizierenden und carboxyl gruppen enthaltenden Monomeren erzielt (Lit.: Robert Y. Lochhead, Vol. 103, December 1988, 24 ff., Rolf-Dieter Reinhardt Cosmetics and Toiletries Manufacture World Wide 1995, 189m ff.).For setting hairstyles have been used for almost 50 years successfully used synthetic polymers. While in the An In the beginning, vinyl lactam homo- and copolymers are preferred later have polymers containing carboxylate groups gaining in importance. The desired property profile like strong consolidation with high air humidity, elasticity, Washable from the hair and compatibility with the rest Formulation components are obtained by copolymerization of a Combination of hydrophobic, elasticizing and carboxyl group-containing monomers (Lit .: Robert Y. Lochhead, Vol. 103, December 1988, 24 ff., Rolf-Dieter Reinhardt Cosmetics and Toiletries Manufacture World Wide 1995, 189m ff.).
Während die obengenannten Anforderungen heute von verschiedenen Polymertypen erreicht werden, wird immer häufiger der Griff der mit diesen Polymeren gefestigten Frisuren als unangenehm stumpf und "unnatürlich" empfunden. Versuche durch Zusätze zu den Formu lierungen zu einer Verbesserung zu gelangen, führten bisher nicht zu voll befriedigenden Ergebnissen: Die Zugabe üblicher Weich macher verbessert zwar den Griff, reduziert aber gleichzeitig in vielen Fällen die Festigungswirkung.While the above requirements are different today Polymer types are achieved, the grip of the hairstyles consolidated with these polymers as uncomfortably dull and felt "unnatural". Try adding to the formu There have so far been no improvements to fully satisfactory results: the addition of conventional soft machinist improves the grip, but at the same time reduces in the strengthening effect in many cases.
In US 5,599,524 werden Haarsprayzusammensetzungen beschrieben, die neben dem festigenden Polymer und üblichen Zusatzstoffen bestimmte Siloxane (Hexamethyldisiloxan, Bisphenylhexamethicone) in einer Menge von 0.6 bis 5 Gew.-% enthalten. Diese Haarspray zusammensetzungen weisen eine verbesserte Sprühcharakteristik auf, während andere Siloxane wie beispielsweise Dimethicone zu keiner verbesserten Sprühcharakteristik beitragen (Beispiel 1). Bei einer Polymermenge von 5 Gew.-% und einer Siloxanmenge von 1 Gew.-% besitzen diese Haarsprayzusammensetzungen bezüglich Glanz, Steifheit, Trockenkämmbarkeit und Flaking keine Vorteile gegen über den Siloxan-freien Haarsprayzusammensetzungen (Beispiel 3).No. 5,599,524 describes hairspray compositions which in addition to the setting polymer and usual additives certain siloxanes (hexamethyldisiloxane, bisphenylhexamethicone) contained in an amount of 0.6 to 5 wt .-%. This hairspray compositions have improved spray characteristics while other siloxanes such as dimethicone do not contribute to improved spray characteristics (example 1). With a polymer amount of 5% by weight and a siloxane amount of 1 % By weight have these hairspray compositions in terms of gloss, Rigidity, combability and flaking have no advantages over the siloxane-free hair spray compositions (Example 3).
Überraschenderweise wurde jetzt gefunden, daß Haarsprayzusammen setzungen mit einem genau definierten relativ niedrigen Gehalt an spezifischen Siloxanen besonders vorteilhafte anwendungs technische Eigenschaften besitzen. Surprisingly, it has now been found that hairspray together settlements with a precisely defined, relatively low salary with specific siloxanes particularly advantageous application possess technical characteristics.
Die Erfindung betrifft Haarsprayzusammensetzung enthaltend
The invention relates to hairspray composition containing
- A) 0,1 bis 15 Gew.-% festigende Polymere,A) 0.1 to 15% by weight of setting polymers,
- B) 0,01 bis 0,5 Gew.-% eines oder mehrerer Siloxane aus der Gruppe Hexamethyldisiloxan, Dimethicone Copolyol und Lauryl methicone Copolyol ist,B) 0.01 to 0.5 wt .-% of one or more siloxanes from the Group hexamethyldisiloxane, dimethicone copolyol and lauryl methicone copolyol is
- C) 0 bis 10 Gew.-% üblicher Zusatzstoffe,C) 0 to 10% by weight of conventional additives,
- D) Treibmittel,D) blowing agent,
-
E) organische Lösungsmittel und ggf. Wasser,
wobei die Komponenten (A) bis (E) zusammen 100 Gew.-% betragen.E) organic solvents and possibly water,
the components (A) to (E) together being 100% by weight.
Geeignete festigende Polymere (A) sind seit langem dem Fachmann bekannt, insbesondere solche aus Copolymere aus Vinylacetat/- Crotonsäure/Vinylneodecanoat; Octylacrylamid/Acrylat/Butylamino ethyl Methacrylat; Vinylacetat/ Crotonat; Polyvinylpyrrolidon (PVP); Polyvinylpyrrolidon/Vinylacetat; PVP/Acrylat; Vinylacetat/- Crotonsäure/Vinylpropionat; Acrylat/Acrylamid; Acrylat/Octyl - acrylamid und Alkylester von Polyvinylmethylether/Maleinsäure anhydrid; Diglycol/Cyclohexandimethanol/Isophthalat/Sulfoiso phthalat; Vinylacetat/Butylmaleat/Isobornylacrylat; Vinyl caprolactam/PVP/Dimethylaminoethylmethacrylat; Vinylacetat/Alkyl - maleat-Halbester/N-substituierte Acrylamid Terpolymere; Vinyl caprolactam/Vinylpyrrolidon/Methacrylamidopropyltrimethyl ammoniumchlorid Terpolymer; Methacrylat/Acrylat Copolymer Amin salz; Methacrylsäure/Tert. Butylacrylat u. ggf. weitere Acryl ester.Suitable setting polymers (A) have long been known to the person skilled in the art known, especially those made from copolymers of vinyl acetate / - Crotonic acid / vinyl neodecanoate; Octylacrylamide / acrylate / butylamino ethyl methacrylate; Vinyl acetate / crotonate; Polyvinyl pyrrolidone (PVP); Polyvinyl pyrrolidone / vinyl acetate; PVP / acrylate; Vinyl acetate / - Crotonic acid / vinyl propionate; Acrylate / acrylamide; Acrylate / octyl - acrylamide and alkyl esters of polyvinyl methyl ether / maleic acid anhydride; Diglycol / cyclohexanedimethanol / isophthalate / sulfoiso phthalate; Vinyl acetate / butyl maleate / isobornyl acrylate; Vinyl caprolactam / PVP / dimethylaminoethyl methacrylate; Vinyl acetate / alkyl - maleate half ester / N-substituted acrylamide terpolymers; Vinyl caprolactam / vinylpyrrolidone / methacrylamidopropyltrimethyl ammonium chloride terpolymer; Methacrylate / acrylate copolymer amine salt; Methacrylic acid / tert. Butyl acrylate u. possibly further acrylic ester.
Bei der Verwendung von carboxylatgruppenhaltigen Polymeren (A) werden die Carboxylatgruppen der Polymerisate, zweckmäßigerweise teilweise oder vollständig neutralisiert. Diese Neutralisierung kann bei der Herstellung der Polymeren oder bei Endformulierung der Haarsprayzusammensetzung erfolgen.When using carboxylate group-containing polymers (A) the carboxylate groups of the polymers, expediently partially or completely neutralized. This neutralization can be used in the preparation of the polymers or in the final formulation the hairspray composition.
Besonders geeignete Polymere (A) sind Vinylpyrrolidon Copolymere, wie sie beispielsweise unter dem Markennamen LUVISKOL® von der BASF Aktiengesellschaft vertrieben werden und Acrylatcopolymere wie sie beispielsweise unter dem Markennamen LUVIMER® und ULTRAHOLD® von der BASF Aktiengesellschaft vertrieben werden.Particularly suitable polymers (A) are vinyl pyrrolidone copolymers, as for example under the brand name LUVISKOL® from the BASF Aktiengesellschaft are distributed and acrylate copolymers as for example under the brand names LUVIMER® and ULTRAHOLD® are sold by BASF Aktiengesellschaft.
Die erfindungsgemäßen Haarfestigungsmittel enthalten die Polymere (A) in einer Menge von 0,5-15, bevorzugt von 2-10 Gew.-%. The hair fixatives according to the invention contain the polymers (A) in an amount of 0.5-15, preferably 2-10% by weight.
Die Siloxane (B) sind bekannt und kommerziell erhältlich. Hexa methyldisiloxan wird beispielsweise von der Firma Rhone-Poulenc unter dem Markennamen MIRASIL HMS® verkauft.The siloxanes (B) are known and commercially available. Hexa methyldisiloxane is for example from the company Rhone-Poulenc sold under the brand name MIRASIL HMS®.
Dimethicone Copolyol wird beispielsweise von Dow Chemicals Inc. unter dem Markennamen DOW CORNING 190®, oder von Union Carbide unter den Markennamen SILWET COPOLYMER L-7500®, L-7087®, L-7602®, L-7622® oder SILSOFT 900® vertrieben.For example, Dimethicone Copolyol is available from Dow Chemicals Inc. under the brand name DOW CORNING 190®, or from Union Carbide under the brand names SILWET COPOLYMER L-7500®, L-7087®, L-7602®, L-7622® or SILSOFT 900® sold.
Laurylmethicone Copolyol wird beispielsweise von Dow Chemicals Inc. unter dem Markennamen DOW CORNING 5200® vertrieben.Laurylmethicone copolyol is available, for example, from Dow Chemicals Inc. sold under the brand name DOW CORNING 5200®.
Die Siloxane (B) werden in einer Menge von 0,01-0,5 Gew.-%, bevorzugt 0,03-0,25 Gew.-% eingesetzt. Die Mengenangabe bezieht sich auf die fertig formulierte Haarsprayzusammensetzung.The siloxanes (B) are used in an amount of 0.01-0.5% by weight, preferably 0.03-0.25 wt .-% used. The quantity refers the formulated hairspray composition.
Die Siloxane können sowohl als Einzelverbindungen als auch als Mischung verwendet werden.The siloxanes can be used both as individual compounds and as Mixture can be used.
Als Zusatzstoffe (C) können übliche Zusatzstoffe wie Lichtschutz mittel, Parfümöle, Farbstoffe, Antistatika, Konservierungsmittel, Verdicker in einer Menge bis zu 10 Gew.-% zugegeben werden.Additives (C) can be conventional additives such as light protection medium, perfume oils, dyes, antistatic agents, preservatives, Thickeners can be added in an amount of up to 10% by weight.
Als Treibmittel (D) können üblicherweise Kohlenwasserstoffe wie Propan, Butan, Isobutan oder Mischungen davon allein oder in Ver bindung mit komprimierten Gasen wie Stickstoff, Luft oder Kohlen dioxid verwendet werden. (D) wird üblicherweise in Mengen von 10 bis 60 Gew.-% eingesetzt.Hydrocarbons such as Propane, butane, isobutane or mixtures thereof alone or in ver binding with compressed gases such as nitrogen, air or coal dioxide can be used. (D) is usually used in amounts of 10 to 60 wt .-% used.
Als Komponente (E) können organische Lösungsmittel allein oder zusammen mit Wasser eingesetzt werden. Bevorzugt werden flüchtige Alkohole wie Methanol, Ethanol, Propanol, Isopropanol, Butanol, Ketone wie Aceton, Ether wie Dimethoxymethan und Dimethylether und Methylenchlorid, Bevorzugt werden als (E) Ethanol oder Ethanol/Wasser Gemische, insbesondere 80 : 20 verwendet.As component (E) organic solvents alone or can be used together with water. Volatile are preferred Alcohols such as methanol, ethanol, propanol, isopropanol, butanol, Ketones such as acetone, ethers such as dimethoxymethane and dimethyl ether and methylene chloride, Preferred as (E) ethanol or ethanol / water mixtures are in particular 80:20 used.
Die Komponente (E) wird üblicherweise in Mengen von 25 bis 90 Gew.-% eingesetzt.Component (E) is usually used in amounts of 25 to 90 wt .-% used.
Im folgenden wurde eine Reihe von Haarsprayzusammensetzungen hergestellt und auf ihre anwendungstechnischen Eigenschaften überprüft. Der Übersichtlichkeit wegen sind die Ergebnisse in Tabelle 1 zusammengefaßt (Bewertung wie in der Schule). The following are a number of hair spray compositions manufactured and their application properties checked. For the sake of clarity, the results are in Table 1 summarized (evaluation as in school).
Claims (3)
- A) 0,1 bis 15 Gew.-% festigende Polymere,
- B) 0,01 bis 0,5 Gew.-% eines oder mehrerer Siloxane aus der Gruppe Hexamethyldisiloxan, Dimethicone Copolyol und Laurylmethicone Copolyol ist,
- C) 0 bis 10 Gew.-% üblicher Zusatzstoffe,
- D) Treibmittel,
- E) organische Lösungsmittel und ggf. Wasser, wobei die Komponenten (A) bis (E) zusammen 100 Gew.-% betragen.
- A) 0.1 to 15% by weight of setting polymers,
- B) 0.01 to 0.5% by weight of one or more siloxanes from the group consisting of hexamethyldisiloxane, dimethicone copolyol and laurylmethicone copolyol,
- C) 0 to 10% by weight of conventional additives,
- D) blowing agent,
- E) organic solvents and optionally water, the components (A) to (E) together being 100% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1998120949 DE19820949A1 (en) | 1998-05-11 | 1998-05-11 | Hair spray composition with good application properties |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1998120949 DE19820949A1 (en) | 1998-05-11 | 1998-05-11 | Hair spray composition with good application properties |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE19820949A1 true DE19820949A1 (en) | 1999-11-18 |
Family
ID=7867327
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1998120949 Withdrawn DE19820949A1 (en) | 1998-05-11 | 1998-05-11 | Hair spray composition with good application properties |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE19820949A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2858933A1 (en) * | 2003-08-22 | 2005-02-25 | Oreal | Aerosol device contains a hair treatment composition comprising a silicone and a copolymer with a monomer composition gradient and dimethyl ether as propellant |
| WO2008012938A1 (en) * | 2006-07-25 | 2008-01-31 | Shiseido Company, Ltd. | Aerosol type cosmetic hair preparations |
-
1998
- 1998-05-11 DE DE1998120949 patent/DE19820949A1/en not_active Withdrawn
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2858933A1 (en) * | 2003-08-22 | 2005-02-25 | Oreal | Aerosol device contains a hair treatment composition comprising a silicone and a copolymer with a monomer composition gradient and dimethyl ether as propellant |
| WO2005020941A3 (en) * | 2003-08-22 | 2005-06-09 | Oreal | Aerosol device containing a silicone, a graded copolymer and a propellant essentially comprising dimethylether |
| WO2008012938A1 (en) * | 2006-07-25 | 2008-01-31 | Shiseido Company, Ltd. | Aerosol type cosmetic hair preparations |
| CN101472549B (en) * | 2006-07-25 | 2012-03-21 | 株式会社资生堂 | Aerosol type cosmetic hair preparations |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0257444B1 (en) | Tercopolymers, their use in hair treatment compositions and hair treatment compositions containing them | |
| EP1002811B1 (en) | Soluble or water-dispersible graft copolymers based on a polyvinyllactam, the preparation and use thereof | |
| DE69524959T2 (en) | HAIR CARE COMPOSITIONS CONTAINING N-VINYLFORMAMIDE POLYMER AND METHOD FOR TREATING THE HAIR | |
| EP0897711B1 (en) | Product for the improvement of styling and gloss of hair | |
| DE69926613T2 (en) | AEROSOL fixative | |
| DE4421562C2 (en) | hair spray | |
| DE19834946C1 (en) | Aerosol foam composition and its use for the treatment of human hair | |
| DE69810326T3 (en) | AUTOFOBIC HAIRSPRAY COMPOSITIONS | |
| EP0756859B1 (en) | Hair care composition | |
| EP0841060B1 (en) | Hair-care composition for fixing the hair | |
| DE3205545A1 (en) | WATER-FREE NAIL POLISH | |
| EP0862908B1 (en) | Hair fixative with a polysiloxane | |
| DE19919785A1 (en) | Hair treatment agent with polymers of unsaturated saccharides, unsaturated saccharic acids or their derivatives | |
| WO2000069398A1 (en) | Hairspray composition containing siloxane | |
| EP0507896A1 (en) | Hair-fixing agent. | |
| EP0256458A2 (en) | Method of preparation of a copolymer for use as a hair fixative and hair fixing compositions containing it | |
| DE19820949A1 (en) | Hair spray composition with good application properties | |
| DE69706301T2 (en) | HAIR FIXING AGENT FORMULATED WITH SILICONE COPOLYOLS | |
| EP1117711A1 (en) | Cationic polymers and their use | |
| WO2003032936A1 (en) | Hair-fixing agent for cosmetic preparations | |
| DE19740651C1 (en) | Agent for improving hair formability and sheen | |
| DE69815208T2 (en) | Hair treatment compositions containing polymeric N-vinylacetamide and hair treatment method | |
| DE19805432C1 (en) | Hair styling formulation giving flexible hydrophobic polymer film without impairing spraying | |
| WO1993025178A1 (en) | Hair treatment agent | |
| DE19718185C1 (en) | New poly-N-acyl-alkylene-imine modified organo poly:siloxane compounds |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8130 | Withdrawal |