DE1210240B - Preparations for the control of insects - Google Patents
Preparations for the control of insectsInfo
- Publication number
- DE1210240B DE1210240B DEB58828A DEB0058828A DE1210240B DE 1210240 B DE1210240 B DE 1210240B DE B58828 A DEB58828 A DE B58828A DE B0058828 A DEB0058828 A DE B0058828A DE 1210240 B DE1210240 B DE 1210240B
- Authority
- DE
- Germany
- Prior art keywords
- effect
- effective
- insects
- preparations
- control
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 241000238631 Hexapoda Species 0.000 title description 2
- 238000002360 preparation method Methods 0.000 title description 2
- 150000001875 compounds Chemical class 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 239000002917 insecticide Substances 0.000 claims 1
- 239000004480 active ingredient Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 241000255601 Drosophila melanogaster Species 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 241001674044 Blattodea Species 0.000 description 2
- 241000257159 Musca domestica Species 0.000 description 2
- 235000013601 eggs Nutrition 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
- 241000256118 Aedes aegypti Species 0.000 description 1
- 206010002091 Anaesthesia Diseases 0.000 description 1
- 241001124076 Aphididae Species 0.000 description 1
- 241001425390 Aphis fabae Species 0.000 description 1
- 241000238659 Blatta Species 0.000 description 1
- 241000256113 Culicidae Species 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000257226 Muscidae Species 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 241001674048 Phthiraptera Species 0.000 description 1
- 210000001015 abdomen Anatomy 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000037005 anaesthesia Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- -1 dithiophosphoric acid ester Chemical class 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- WABYCCJHARSRBH-UHFFFAOYSA-N metaclazepam Chemical compound C12=CC(Br)=CC=C2N(C)C(COC)CN=C1C1=CC=CC=C1Cl WABYCCJHARSRBH-UHFFFAOYSA-N 0.000 description 1
- 231100000926 not very toxic Toxicity 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical class O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/655—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms
- C07F9/65515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a five-membered ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
Mittel zur Bekämpfung von Insekten Es ist bekannt, Dithiophosphorsäureester von Sulfolanen als insektizide Wirkstoffe zu verwenden (USA.-Patentschrift 2882278). Die Wirkung der Verbindungen befriedigt jedoch nicht.Means for combating insects It is known dithiophosphoric acid ester of sulfolanes to be used as insecticidal active ingredients (US Pat. No. 2882278). However, the effect of the compounds is not satisfactory.
Es wurde gefunden, daß Verbindungen der Formel in der R eine Hydroxylgruppe oder den Rest bedeutet, eine gute insektizide Wirkung haben Sie sind außerdem wenig toxisch für Warmblüter.It has been found that compounds of the formula in which R is a hydroxyl group or the remainder means that they have a good insecticidal effect. They are also not very toxic to warm-blooded animals.
Die erfindungsgemäßen Mittel werden m bekannter Weise durch Mischen der Wirkstoffe mit üblichen Streckmitteln, gegebenenfalls unter Zusatz von Netz-oder Dispergiermitteln, hergestellt Die Herstellung der Wirkstoffe kann z. B. in der Weise erfolgen, daß man 3,4Dihydroxy-tetrahydraofuran mit 1 oder 2 Mol O,O-Diäthyl-thionophosphorsäurechlorid, gegebenenfalls in Gegenwart sãurebindender Mittel, umsetzt. The agents according to the invention are produced in a known manner by mixing of the active ingredients with customary extenders, optionally with the addition of wetting agents or Dispersants, prepared The preparation of the active ingredients can be, for. B. in the Way done that 3,4Dihydroxy-tetrahydraofuran with 1 or 2 moles of O, O-diethyl-thionophosphoric acid chloride, optionally in the presence of acid-binding agents.
Ein erfindungsgemãß zu verwendender Wirkstoff ist beispielsweise die folgende Substanz: Brechungsindex n200 = 1,5155.An active ingredient to be used according to the invention is, for example, the following substance: Refractive index n200 = 1.5155.
Das folgende Beispiel erläutert die Wirkung der erfindungsgemäßen Mittel. The following example illustrates the effect of the invention Middle.
B e i s p i e l Für die Versuche wurden folgende Wirkstoffe verwendet: USA.-Patent 2 882 27S, Beispiel 1; Toxizität: etwa 230mglkg Ratte per os; Toxizität: etwa 100 mg1kg Ratte per os.Example The following active ingredients were used for the experiments: U.S. Patent 2,882,27S, Example 1; Toxicity: about 230 mg / kg rat per os; Toxicity: about 100 mg / kg rat per os.
Folgende Versuche wurden durchgeführt: a) Kontaktversuch mit der Essiglliege (Drosophila melanogaster) in Bechergläsern von 250 ml Inhalt. Die Substanzen werden in acetonischer Lösung gleichmäßig auf die Wandungen verteilt. Die Wirkung wird nach 6 Stunden bestimmt. b) Applikationstest mit Stubeniliegen (Musca domestica). Die acetonische Lösung wird der Fliege in Narkose auf das ventrale Abdomen gegeben. Die Wirkung nach 4 Stunden wird beurteilt. c) Dauerkontaktversuch an Schaben (Blatta oder talis). Die Schaben werden in Litergläsern 100 mg Stäubemittel ausgesetzt. Die Wirkung nach 48 Stunden wird gewertet. d) Wirkung auf Stechmückenlarven (Aedes aegypti). The following tests were carried out: a) Contact test with the Vinegar bed (Drosophila melanogaster) in beakers of 250 ml. The substances are evenly distributed in acetone solution on the walls. The effect is determined after 6 hours. b) Application test with indoor beds (Musca domestica). The acetone solution is applied to the ventral part of the fly under anesthesia Abdomen given. The effect after 4 hours is assessed. c) Continuous contact attempt on cockroaches (Blatta or talis). The cockroaches become 100 mg dust in liter jars exposed. The effect after 48 hours is assessed. d) Effect on mosquito larvae (Aedes aegypti).
Larven werden 24 Stunden der Wirkung der in Wasser emulgierten Wirkstoffe ausgesetzt q Zuchtversuch mit der Essigfliege (Drosophila melanogaster). 40 ml eines mit Eiern belegten Nährbodens werden mit Wirkstoff behandelt. Larvae are exposed to the action of the active ingredients emulsified in water for 24 hours exposed q Breeding experiment with the vinegar fly (Drosophila melanogaster). 40 ml one Nutrient media covered with eggs are treated with active ingredient.
Die Wirkung wird bis zum Schlüpfen der unbehandelten Kontrolleier beobachtet. f) Spritzversuche gegen Blattläuse (Aphis fabae). The effect continues until the untreated control eggs hatch observed. f) Spray tests against aphids (Aphis fabae).
Getopfte Bohnenpflanzen mit Blatfläusen werden im Labor mit den in
Wasser emulgierten Wirkstoffen tropfnaß gespritzt. Die Wirkung wird nach 24 Stunden
bestimmt. g) Hungrigen Stubenfliegen (Musca domestica) werden Milchzuckertabletten
(100 mg) angeboten, die den zu prüfenden Stoff enthalten. Die Wirkung wird nach
24 Stunden bestimmt.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB58828A DE1210240B (en) | 1960-08-03 | 1960-08-03 | Preparations for the control of insects |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB58828A DE1210240B (en) | 1960-08-03 | 1960-08-03 | Preparations for the control of insects |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1210240B true DE1210240B (en) | 1966-02-03 |
Family
ID=6972216
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEB58828A Pending DE1210240B (en) | 1960-08-03 | 1960-08-03 | Preparations for the control of insects |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE1210240B (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2882278A (en) * | 1956-08-09 | 1959-04-14 | Eastman Kodak Co | Organophosphorus derivatives of dihydrothiophene 1, 1-dioxide |
-
1960
- 1960-08-03 DE DEB58828A patent/DE1210240B/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2882278A (en) * | 1956-08-09 | 1959-04-14 | Eastman Kodak Co | Organophosphorus derivatives of dihydrothiophene 1, 1-dioxide |
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