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DE1207181B - Covering agent for the production of etched patterns on metal foils - Google Patents

Covering agent for the production of etched patterns on metal foils

Info

Publication number
DE1207181B
DE1207181B DEB65321A DEB0065321A DE1207181B DE 1207181 B DE1207181 B DE 1207181B DE B65321 A DEB65321 A DE B65321A DE B0065321 A DEB0065321 A DE B0065321A DE 1207181 B DE1207181 B DE 1207181B
Authority
DE
Germany
Prior art keywords
production
covering
resistant
acid
metal foils
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DEB65321A
Other languages
German (de)
Inventor
Dipl-Chem Karl Hoffmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Blaupunkt Werke GmbH
Original Assignee
Blaupunkt Werke GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Blaupunkt Werke GmbH filed Critical Blaupunkt Werke GmbH
Priority to DEB65321A priority Critical patent/DE1207181B/en
Priority to GB4670562A priority patent/GB1002046A/en
Publication of DE1207181B publication Critical patent/DE1207181B/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F1/00Etching metallic material by chemical means
    • C23F1/02Local etching
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/02Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding
    • H05K3/06Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding the conductive material being removed chemically or electrolytically, e.g. by photo-etch process
    • H05K3/061Etching masks
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • H05K1/0266Marks, test patterns or identification means
    • H05K1/0269Marks, test patterns or identification means for visual or optical inspection
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/01Dielectrics
    • H05K2201/0137Materials
    • H05K2201/0166Polymeric layer used for special processing, e.g. resist for etching insulating material or photoresist used as a mask during plasma etching
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2203/00Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
    • H05K2203/07Treatments involving liquids, e.g. plating, rinsing
    • H05K2203/0756Uses of liquids, e.g. rinsing, coating, dissolving
    • H05K2203/0769Dissolving insulating materials, e.g. coatings, not used for developing resist after exposure
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2203/00Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
    • H05K2203/07Treatments involving liquids, e.g. plating, rinsing
    • H05K2203/0779Treatments involving liquids, e.g. plating, rinsing characterised by the specific liquids involved
    • H05K2203/0786Using an aqueous solution, e.g. for cleaning or during drilling of holes
    • H05K2203/0793Aqueous alkaline solution, e.g. for cleaning or etching
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2203/00Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
    • H05K2203/16Inspection; Monitoring; Aligning
    • H05K2203/161Using chemical substances, e.g. colored or fluorescent, for facilitating optical or visual inspection
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/0073Masks not provided for in groups H05K3/02 - H05K3/46, e.g. for photomechanical production of patterned surfaces
    • H05K3/0076Masks not provided for in groups H05K3/02 - H05K3/46, e.g. for photomechanical production of patterned surfaces characterised by the composition of the mask

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing Of Printed Circuit Boards (AREA)
  • ing And Chemical Polishing (AREA)

Description

BUNDESREPUBLIK DEUTSCHLANDFEDERAL REPUBLIC OF GERMANY

DEUTSCHESGERMAN

PATENTAMTPATENT OFFICE

AUSLEGESCHRIFTEDITORIAL

Int. α.:Int. α .:

Nummer.
Aktenzeichen:
Anmeldetag:
Auslegetag:
Number.
File number:
Registration date:
Display day:

C23fC23f

Deutsche KL: 48 dl-1/02German KL: 48 dl-1/02

B65321VIb/48dl
23. Dezember 1961
16. Dezember 1965
B65321VIb / 48dl
December 23, 1961
December 16, 1965

Die Erfindung betrifft die Verwendung von säurebeständigen, aber in alkalischen wäßrigen Lösungen leicht löslichen oder verseifbaren Harzen.The invention relates to the use of acid-resistant, but in alkaline aqueous solutions easily soluble or saponifiable resins.

Bei der Herstellung sogenannter gedruckter Schaltungen nach einem Ätzverfahren wird auf ein mit Kupferfolie kaschiertes Trägermaterial ein entsprechendes Leitungsmuster mittels einer säurebeständigen Farbe aufgedruckt und die freien Teile in entsprechenden Ätzbädern mit mehr oder minder saurer Reaktion weggeätzt.When producing so-called printed circuits using an etching process, one with Copper foil-clad carrier material a corresponding line pattern by means of an acid-resistant Color printed and the free parts in corresponding etching baths with more or less acidic reaction etched away.

Das Aufdrucken der Abdeckmittel als Leitungsmuster erfolgt vorzugsweise im Siebdruckverfahren mit besonders konsistenten Lacken, welchen Verdickungsmittel, Füll- und Farbstoffe beigegeben sind. Als Lacke dienen dabei meistens säurebeständige, wasserfeste, unverseifbare Harze, z. B. Cumaronharze. The printing of the covering means as a line pattern is preferably carried out using the screen printing process with particularly consistent lacquers, which thickeners, fillers and dyes are added. Acid-resistant, water-resistant, unsaponifiable resins, e.g. B. coumarone resins.

Nach dem Ätzen wird die säurewiderstandsfähige Lackschicht für gewöhnlich in organischen Lacklösungsmitteln wie Xylol, Benzin oder vorzugsweise Trichloräthylen abgelöst, wobei besonders hierfür geeignete Waschapparate verwendet werden. Vor dem Waschvorgang müssen die Platten jedoch getrocknet werden.After etching, the acid-resistant lacquer layer is usually in organic lacquer solvents such as xylene, gasoline or preferably trichlorethylene replaced, especially this suitable washing machines are used. However, the plates must be dried before washing will.

Für die Herstellung sogenannter gedruckter Schaltungen, die ein Massenerzeugnis sind, ist aber ein möglichst automatisch arbeitendes, kontinuierliches Verfahren erwünscht, bei dem keine Einzelbearbeitung der Teile erfolgt und alle Behandlungsstufen aus einfachen, insbesondere chemischen Tauchprozessen bestehen.For the production of so-called printed circuits, which are a mass product, is a As automatically as possible, continuous process is desired, in which no individual processing of the parts and all treatment stages from simple, in particular chemical, immersion processes exist.

Bei den bekannten kontinuierlich arbeitenden Verfahren werden jedoch, insbesondere durch das Reinigen und Zwischentrocknen, aufwendige Apparaturen erforderlich und die Herstellung langwierig.In the known continuously operating processes, however, in particular by the Cleaning and intermediate drying, complex equipment required and the production time-consuming.

Bei der Herstellung von geätzten Mustern auf Metallfolien, insbesondere bei der Herstellung von gedruckten Schaltungen nach dem Siebdruckverfahren, lassen sich diese Nachteile gemäß der Erfindung durch die Verwendung von säurebeständigen, aber in alkalischen wäßrigen Lösungen leicht löslichen oder verseifbaren Harzen als Abdeckmittel vermeiden. Hierbei eignen sich besonders Phenol-Novolack, Kolophonium, Naturschellack, Maleinatharze oder Alkydharze als Abdeckmittel.In the production of etched patterns on metal foils, especially in the production of printed circuits by the screen printing process, these disadvantages according to the Invention through the use of acid-resistant, but in alkaline aqueous solutions Avoid easily soluble or saponifiable resins as covering agents. Here are particularly suitable Phenol novolac, rosin, natural shellac, maleinate resins or alkyd resins as covering agents.

Es ist zwar bekannt, bei Ätzverfahren als Abdeckmittel Harze, z. B. Alkydharze oder Maleinharz, zu verwenden, die sich mit hochprozentigen, eventuell stark erwärmten alkalischen Lösungsmitteln wie Natronlauge lösen lassen, jedoch eignen sich derartig verhältnismäßig alkalifeste Stoffe nicht für die Herstellung von gedruckten Schaltungen, da das die Abdeckmittel bei der Herstellung von geätzten
Mustern auf Metallfolien
Although it is known to use resins, e.g. B. alkyd resins or maleic resin to use, which can be solved with high-percentage, possibly strongly heated alkaline solvents such as caustic soda, but such relatively alkali-resistant substances are not suitable for the production of printed circuits, as the cover means in the production of etched
Patterns on metal foils

Anmelder:Applicant:

Blaupunkt-Werke G. m. b. H.,
Hildesheim, Robert-Bosch-Str. 200
Blaupunkt-Werke G. mb H.,
Hildesheim, Robert-Bosch-Str. 200

Als Erfinder benannt:Named as inventor:

Dipl.-Chem. Karl Hoffmann, HildesheimDipl.-Chem. Karl Hoffmann, Hildesheim

Leitungszüge bildende Kupfer im allgemeinen auf ein Hartpapier aufkaschiert ist, dessen Zusammensetzung auf einer Phenol-Resolharz-Basis beruht. Dieses Hartpapier würde infolge seiner geringen Alkalifestigkeit zumindest angelöst werden, was insbesondere bei geringen Oberflächenverunreinigungen zwischen den einzelnen Leiterbahnen z. B. zu Kriechströmen bzw. zu untragbaren Isolationswiderständen führen kann.Conductor forming copper is generally laminated to a hard paper, the composition of which is based on a phenolic resole resin. This hard paper would be due to its low Alkali resistance are at least partially dissolved, which is particularly the case with low surface contamination between the individual conductor tracks z. B. to leakage currents or intolerable insulation resistance can lead.

Weiterhin ist es gemäß einer Weiterbildung der Erfindung von Vorteil, wenn das Abdeckmittel zur Erzielung einer größeren Konsistenz einen Füllstoff und zur Sichtbarmachung einen Farbstoff, insbesondere einen säurewiderstandsfähigen und alkalilöslichen Füll- und Farbstoff enthält. Dabei können die Füll- und Farbstoffe in hochdisperser Form im Abdeckmittel enthalten sein und vorzugsweise aus Kieselsäure und Berliner Blau bestehen.Furthermore, according to a development of the invention, it is advantageous if the covering means for To achieve a greater consistency, a filler and, for visualization, a dye, in particular contains an acid-resistant and alkali-soluble filler and dye. Here you can the fillers and dyes are contained in highly dispersed form in the covering agent and preferably from Silicic acid and Prussian blue exist.

Das alkalische Lösungsmittel kann eine wäßrige Alkalilauge, z. B. NaOH, mit einer Konzentration von 1 bis 2% sein.The alkaline solvent can be an aqueous alkali, e.g. B. NaOH, at a concentration from 1 to 2%.

Nach einer Weiterbildung der Erfindung, unter Verwendung eines Abdeckmittels mit der kennzeichnenden Eigenschaft der Alkalilöslichkeit, wird eine durchgehend nasse Behandlung der gedruckten Schaltung in einer wie in der GalvanotechnikAccording to a development of the invention, using a covering means with the characterizing Property of alkali solubility, is a continuous wet treatment of the printed Circuit in a like in electroplating

üblichen Wanderanlage ermöglicht, ohne daß eine Zwischentrocknung und die Verwendung teurer oder gefährlicher organischer Lösungsmittel erforderlich ist. Die Benutzung der bekannten Lösungsmittel erforderte nach der bisherigen Technik außerdem in den meisten Fällen die Anwendung aufwendiger Ultraschallwaschgeräte oder eine mechanische bzw. manuelle Nachreinigung jeder einzelnen gedrucktenusual hiking system allows without an intermediate drying and the use of expensive or hazardous organic solvent is required. The use of known solvents In most cases, the previous technology also required a more complex application Ultrasonic washers or mechanical or manual cleaning of each individual printed

'-■ '■ "·-■' ' : 509758/419'- ■' ■ "· - ■ '' : 509758/419

1010

Schaltung, um eine ausreichende Reinigung zu erzielen. Das erfindungsgemäße Abdeckmittel wird durch einfaches Eintauchen während 1 bis 2 Minuten in einer 1 bis 2%igen Natronlauge bei Zimmertemperatur rückstandslos abgelöst.Circuit to achieve adequate cleaning. The covering means according to the invention is by simply dipping for 1 to 2 minutes in a 1 to 2% sodium hydroxide solution at room temperature removed without leaving any residue.

Da die gewählten Füll- und Farbstoffe im Alkalibad ebenfalls leicht zersetzt bzw. dispergiert werden, kann die weitere Reinigung der gedruckten Schaltung durch Blankbeizen ebenfalls mittels eines einfachen Tauchverfahrens in passenden Beizlösungen erfolgen. Eine einfache Trocknung, die sogenannte Schlußoder Fertigtrocknung, beendet den Herstellungsprozeß. Since the selected fillers and dyes are also easily decomposed or dispersed in the alkali bath, the further cleaning of the printed circuit by blank pickling can also be done using a simple Dipping process take place in suitable pickling solutions. A simple drying process, the so-called final or finished drying, ends the manufacturing process.

Claims (6)

Patentansprüche:Patent claims: 1. Verwendung von säurebeständigen, aber in alkalischen wäßrigen Lösungen leicht löslichen öder verseifbaren Harzen als Abdeckmittel bei der Herstellung von geätzten Mustern auf Metallfolien, insbesondere bei der Herstellung von ge- ao druckten Schaltungen nach dem Siebdruckverfahren. 1. Use of acid-resistant, but easily soluble in alkaline aqueous solutions or saponifiable resins as a covering agent in the production of etched patterns on metal foils, especially in the production of printed circuits using the screen printing process. 2. Abdeckmittel nach Anspruch 1, gekennzeichnet durch den Gehalt an einem säurewiderstandsfähigen und alkalilöslichen Füllstoff und an einem ebenfalls säurewiderstandsfähigen r und alkalilöslichen Farbstoff. S.2. covering according to claim 1, characterized by the content of an acid-resistant and alkali-soluble filler, and also on a acid-resistant and alkali-soluble dye r. S. 3. Abdeckmittel nach Anspruch 1, gekennzeichnet durch einen Gehalt an Phenol-Novolak, Kolophonium, Naturschellack, Maleinatharz oder Alkydharz.3. Covering means according to claim 1, characterized by a content of phenol novolak, Colophony, natural shellac, maleic resin or alkyd resin. 4. Abdeckmittel nach Anspruch 2, gekennzeichnet durch hochdisperse Füll- oder Farbstoffe, die vorzugsweise aus Kieselsäure und Berliner Blau bestehen.4. Covering means according to claim 2, characterized by highly disperse fillers or dyes, which preferably consist of silica and Prussian blue. 5. Abdeckmittel nach Anspruch 1 bis 4, gekennzeichnet durch rückstandslose Löslichkeit in 1 bis 2%iger Natronlauge.5. Covering means according to claim 1 to 4, characterized by residue-free solubility in 1 to 2% sodium hydroxide solution. 6. Verfahren zur Herstellung von geätzten Mustern auf Metallfolien, insbesondere Siebdruckverfahren zur Herstellung von gedruckten Schaltungen, unter Verwendung des Abdeckmittels nach Anspruch 1 bis 6, dadurch gekennzeichnet, daß die Ätzung, die Entfernung des Abdeckmittels und die anschließende Blankbeizung ohne Zwischentrocknung vorgenommen werden.6. Process for the production of etched patterns on metal foils, in particular screen printing processes for the production of printed circuits, using the masking agent according to claim 1 to 6, characterized in that the etching, the removal of the Covering agent and the subsequent blank staining carried out without intermediate drying will. In Betracht gezogene Druckschriften:
Deutsche Auslegeschrift Nr. 1085 170;
britische Patentschrift Nr. 813 803;
USA.-Patentschrift 2 975140;
Paul Eisler, »Gedruckte Schaltungen«, 1961, 220.
Considered publications:
German Auslegeschrift No. 1085 170;
British Patent No. 813,803;
U.S. Patent 2,975,140;
Paul Eisler, "Printed Circuits", 1961, 220.
509 758/419 12.65 © Bundesdruckerei Berlin509 758/419 12.65 © Bundesdruckerei Berlin
DEB65321A 1961-12-23 1961-12-23 Covering agent for the production of etched patterns on metal foils Pending DE1207181B (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DEB65321A DE1207181B (en) 1961-12-23 1961-12-23 Covering agent for the production of etched patterns on metal foils
GB4670562A GB1002046A (en) 1961-12-23 1962-12-11 Method for producing etched printed circuits on metal foils

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB65321A DE1207181B (en) 1961-12-23 1961-12-23 Covering agent for the production of etched patterns on metal foils

Publications (1)

Publication Number Publication Date
DE1207181B true DE1207181B (en) 1965-12-16

Family

ID=6974728

Family Applications (1)

Application Number Title Priority Date Filing Date
DEB65321A Pending DE1207181B (en) 1961-12-23 1961-12-23 Covering agent for the production of etched patterns on metal foils

Country Status (2)

Country Link
DE (1) DE1207181B (en)
GB (1) GB1002046A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3201880A1 (en) * 1982-01-22 1983-08-04 Egbert 6106 Erzhausen Kühnert Process for the residue-free removal of coatings from printed circuit boards and apparatus for performing the process
JP3533665B1 (en) 2002-12-17 2004-05-31 オムロン株式会社 A method for manufacturing an electronic component module and a method for manufacturing a data carrier capable of reading electromagnetic waves.

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB813803A (en) * 1955-08-31 1959-05-21 Saunders Roe Ltd Improvements relating to etch-resistant materials and etching methods
DE1085170B (en) * 1958-03-15 1960-07-14 Pictograph Ltd Method and device for the production of printing forms or printing blocks
US2975140A (en) * 1954-07-27 1961-03-14 Klem Chemicals Inc Organic finish remover and method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2975140A (en) * 1954-07-27 1961-03-14 Klem Chemicals Inc Organic finish remover and method
GB813803A (en) * 1955-08-31 1959-05-21 Saunders Roe Ltd Improvements relating to etch-resistant materials and etching methods
DE1085170B (en) * 1958-03-15 1960-07-14 Pictograph Ltd Method and device for the production of printing forms or printing blocks

Also Published As

Publication number Publication date
GB1002046A (en) 1965-08-18

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