DE1133337B - Process for wide finishing - Google Patents
Process for wide finishingInfo
- Publication number
- DE1133337B DE1133337B DEF27030A DEF0027030A DE1133337B DE 1133337 B DE1133337 B DE 1133337B DE F27030 A DEF27030 A DE F27030A DE F0027030 A DEF0027030 A DE F0027030A DE 1133337 B DE1133337 B DE 1133337B
- Authority
- DE
- Germany
- Prior art keywords
- parts
- sizing
- wide
- chains
- threads
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 5
- 238000004513 sizing Methods 0.000 claims description 13
- 229920000297 Rayon Polymers 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000011356 non-aqueous organic solvent Substances 0.000 claims description 4
- 239000002964 rayon Substances 0.000 claims description 3
- 239000004753 textile Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims 1
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 9
- 239000004744 fabric Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 4
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229950011008 tetrachloroethylene Drugs 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 229920002681 hypalon Polymers 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/10—Processes in which the treating agent is dissolved or dispersed in organic solvents; Processes for the recovery of organic solvents thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
Verfahren zum Breitschlichten Zusatz zum Patent 1089 723 Gegenstand des Hauptpatentes 1089 723 und des ersten Zusatzpatentes 1098 487 sind Verfahren zum Breitschlichten von Ketten aus Reyon bzw. aus anderen Textilfäden; diese Verfahren sind dadurch gekennzeichnet, daß man die Ketten in breitem Zustand mit Lösungen von solchen Mischpolymerisaten in organischen Lösungsmitteln behandelt, die aus sauren Estern von a,ß-Äthylendicarbonsäuren einerseits und aus mischpolymerisierbaren Vinylverbindungen und bzw. oder aus Divinylverbindungen mit konjugierten Doppelbindungen andererseits hergestellt sind.Process for wide sizing Addendum to patent 1089 723 The subject of the main patent 1089 723 and the first additional patent 1098 487 are processes for wide sizing of chains made of rayon or other textile threads; These processes are characterized in that the chains are treated in the broad state with solutions of such copolymers in organic solvents which are made from acidic esters of α, ß-ethylenedicarboxylic acids on the one hand and from copolymerizable vinyl compounds and / or from divinyl compounds with conjugated double bonds on the other .
Es wurde gefunden, daß man zum Breitschlichten der Ketten an Stelle der angeführten Mischpolymerisate auch andere, in nichtwäßrigen organischen Lösungsmitteln lösliche filmbildende Substanzen, die überhaupt als Schlichtemittel geeignet sind, verwenden kann, vorzugsweise solche, deren K-Wert nach Fikentscher, Cellulosechemie, Bd. 13 (l932), S. 60, zwischen 1Ö und 40 liegt. Beispielsweise erwähnt seien Chlorkautschuk, Polychlorbutadien; Polyisobutylen, Polyacrylsäureester, chlorsulfoniertes Polyäthylen, Polyvinyläther, Polyvinylacetat oder Mischpolymerisate aus Vinylchlorid und Vinylestern.It has been found that for sizing the chains wide instead of the copolymers listed also others in non-aqueous organic solvents soluble film-forming substances that are generally suitable as sizing agents, can use, preferably those whose K value according to Fikentscher, Cellulosechemie, Vol. 13 (1932), p. 60, between 10 and 40. Examples include chlorinated rubber, Polychlorobutadiene; Polyisobutylene, polyacrylic acid ester, chlorosulfonated polyethylene, Polyvinyl ether, polyvinyl acetate or copolymers of vinyl chloride and vinyl esters.
Schlichtemittel in nichtwäßrigen organischen Lösungsmitteln hat man bislang noch nicht zum Schlichten von Ketten aus Reyon bzw. anderen Textilfäden in breitem Zustand eingesetzt, vielmehr hat man zu diesem Zweck die Schlichtemirtel stets nur in Form von wäßrigen Lösungen angewandt. Die Verwendung von Schlichtemitteln in nichtwäßrigen organischen Lösungsmitteln bietet den `Torteil, daß hierbei keine Naßdehnung der Fäden eintritt.Sizing agents in non-aqueous organic solvents are available So far not for sizing chains made of rayon or other textile threads used in a wide state, rather one has the Schlichtemirtel for this purpose always used only in the form of aqueous solutions. The use of sizing agents in non-aqueous organic solvents offers the `` gate part '' that here no Wet stretching of the threads occurs.
Die in den nachfolgenden Beispielen angegebenen Teile sind Gewichtsteile.The parts given in the following examples are parts by weight.
Beispiel 1 Eine Kette aus in an sich bekannter Weise gefärbtem Acetatreyon, die auf 1 cm 80 Fäden der metrischen Nummer 90 enthält, wird auf einer Lufttrockenschlichtemaschine mit einer Lösung geschlichtet, die aus 50 Teilen eines Polychlorbutadiens vom mittleren Kristallisationsgrad, 20 Teilen Hartparaffin vom Schmelzpunkt 52/53° C, 280 Teilen Methylenchlorid und 650 Teilen Perchloräthylen besteht. Die geschlichtete Kette wird bei 100° C getrocknet und anschließend mit einem hydrophoben, ebenfalls in an sich bekannter Weise gefärbten Schußmaterial aus Acetatreyon zu einem Taftgewebe verwebt. Man erhält ein weitgehend wasserdichtes und wasserabstoßendes Gewebe, das zu Regenmänteln weiterverarbeitet werden kann. Beispiel 2 Eine Kette aus ungefärbten endlosen Polyamidfäden auf der Grundlage von s-Caprolactam, die auf 1 cm 80 Fäden der metrischen Nummer 200 enthält, wird durch Eintauchen und Abquetschen auf einer Lufttrockenschlichtemaschine mit einer Lösung geschlichtet, die aus 50 Teilen chlorsölfoniertem Polyäthylen, 285 Teilen Methylenchlorid und 665 Teilen Perchloräthylen besteht. Die geschlichtete Kette wird bei 100'C getrocknet und anschließend mit einem ungefärbten Schußmaterial aus Polyamidfäden auf der Grundlage von e-Caprolactam zu einem weißen Satingewebe verwebt. Das erhaltene Gewebe ist weitgehend krumpfecht und besitzt einen angenehmen Griff, der waschbeständig ist; es kann ohne weitere Ausrüstung im Stück als Blusenstoff benutzt werden.Example 1 A chain made of acetate redone colored in a manner known per se, which contains 80 threads of the metric number 90 per 1 cm, is on an air-dry sizing machine sized with a solution that consists of 50 parts of a polychlorobutadiene from the middle Degree of crystallization, 20 parts of hard paraffin with a melting point of 52/53 ° C., 280 parts Methylene chloride and 650 parts of perchlorethylene consists. The simple chain is dried at 100 ° C and then with a hydrophobic, also in Acetate-red weft material dyed in a known manner into a taffeta fabric interwoven. A largely waterproof and water-repellent fabric is obtained, the can be further processed into raincoats. Example 2 A chain of uncolored endless polyamide threads on the basis of s-caprolactam, which on 1 cm 80 threads The metric number contains 200 is made by dipping and squeezing on a Air dry sizing machine sized with a solution made from 50 parts of chlorine-oiled There is polyethylene, 285 parts of methylene chloride and 665 parts of perchlorethylene. The sized chain is dried at 100'C and then with an undyed Weft material made of polyamide threads based on e-caprolactam to a white Satin weave woven. The fabric obtained is largely resistant to shrinkage and possesses a pleasant handle that is washable; it can be done without any further equipment can be used as a blouse fabric in one piece.
Beispiel 3 Eine Kette aus in an sich bekannter Weise gefärbtem Viskosereyon, die auf 1 cm 60 Fäden der metrischen Nummer 75 enthält, wird mit einer Lösung aus 75 Teilen des nachstehend erläuterten Phthalsäurealkydharzes, 275 Teilen Methylenchlorid und 650 Teilen Perchloräthylen auf einer Lufttrockenschlichtemaschine ' geschlichtet dann getrocknet und mit einem ungefärbten oder ebenfalls in an sich bekannter Weise gefärbten Viskose-Schußmaterial zu einem Taftgewebe verarbeitet. Man erhält so ein Gewebe, das infolge der Abwesenheit von Wasser während des Schlichtens und Trocknens weitgehend krumpfarm ist und einen für den Gebrauch ansprechenden Griff zeigt, ohne daß es noch einer Appretur im Stück bedarf. Das verwendete Phthalsäurealkydharz war in an sich bekannter Weise aus 27 Teilen Phthalsäureanhydrid, 10,5 Teilen Adipinsäure, 2,5 Teilen Maleinsäure, 20 Teilen Vorlauffettsäure und 40 Teilen Trimethylolpropan hergestellt worden.Example 3 A chain made of viscose rayon colored in a manner known per se, which contains 60 threads of the metric number 75 per 1 cm, is made with a solution 75 parts of the phthalic acid alkyd resin illustrated below, 275 parts of methylene chloride and 650 parts of perchlorethylene were 'sized on an air dry sizing machine then dried and with an uncolored or likewise in a manner known per se dyed viscose weft material processed into a taffeta fabric. You get one like that Fabric produced as a result of the absence of water during sizing and drying is largely low-wrinkle and shows an appealing handle for use, without that a finishing touch is still required in the piece. The phthalic alkyd resin used was in a known manner from 27 parts of phthalic anhydride, 10.5 parts of adipic acid, 2.5 parts of maleic acid, 20 parts of first-run fatty acid and 40 parts of trimethylolpropane has been manufactured.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF27030A DE1133337B (en) | 1958-11-13 | 1958-11-13 | Process for wide finishing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF27030A DE1133337B (en) | 1958-11-13 | 1958-11-13 | Process for wide finishing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1133337B true DE1133337B (en) | 1962-07-19 |
Family
ID=7092265
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEF27030A Pending DE1133337B (en) | 1958-11-13 | 1958-11-13 | Process for wide finishing |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE1133337B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0004843A3 (en) * | 1978-04-17 | 1979-11-14 | Rohm Gmbh | Textile yarn sizing agents soluble in halogenated hydrocarbons; process for sizing textile yarns |
-
1958
- 1958-11-13 DE DEF27030A patent/DE1133337B/en active Pending
Non-Patent Citations (1)
| Title |
|---|
| None * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0004843A3 (en) * | 1978-04-17 | 1979-11-14 | Rohm Gmbh | Textile yarn sizing agents soluble in halogenated hydrocarbons; process for sizing textile yarns |
| US4233200A (en) | 1978-04-17 | 1980-11-11 | Rohm Gmbh | Method of sizing textile yarns and sizing agents therefor |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE1133337B (en) | Process for wide finishing | |
| DE1469293C3 (en) | Process for eliminating or reducing fi iz shrinkage in wool or woolen articles | |
| CH347737A (en) | Camouflage net | |
| DE870543C (en) | Process for improving the properties of fully synthetic fibers | |
| DE676267C (en) | Process for the finishing of woolen goods | |
| DE1294337B (en) | Process for improving the hydrophilic properties of threads, fibers or the like made of linear polyesters | |
| DE874758C (en) | Method of making a changeant colored fabric | |
| DE1098487B (en) | Process for wide finishing | |
| AT220577B (en) | Process for cleaning textile articles which have optionally been pre-cleaned with anhydrous, organic solvents | |
| DE916764C (en) | Process to give natural or artificial threads and fibers or yarns and fabrics a water-repellent character | |
| DE969011C (en) | Process for crease-proof finishing of cellulosic textiles | |
| DE621578C (en) | Process for etching wool dyes with sulfoxylate | |
| DE1063319B (en) | Process for the production of fishing nets from polyamide threads with non-skid knots | |
| DE2214997A1 (en) | Process for generating antistatic effects in textiles | |
| DE918442C (en) | Process to give natural or artificial fibers and threads or yarns or fabrics a water-repellent character | |
| DE896937C (en) | Method of mothproofing wool | |
| DE943589C (en) | Process for improving the dyeability of polyamide textile fabrics | |
| AT153406B (en) | Shaped structures made of braids and. Like. And process for their preparation. | |
| DE1619099A1 (en) | Process for increasing the shrinkage resistance of wool | |
| DE660571C (en) | In whole or in part waterproof clothing | |
| AT266034B (en) | Process for the finishing of cellulose fiber-containing, permanently deformable textile fabrics | |
| DE1143965B (en) | Process for the production of threads or fibers from acrylonitrile polymers | |
| DE1535776B1 (en) | Pile fabric and process for its manufacture | |
| DE1635557A1 (en) | Process for the production of textile flat structures and textile flat structures | |
| DE1610980B2 (en) | Process for the treatment of textile goods |