[go: up one dir, main page]

DE1127861B - Process for improving the abrasion resistance of fibers, yarns, woven, knitted or textile goods - Google Patents

Process for improving the abrasion resistance of fibers, yarns, woven, knitted or textile goods

Info

Publication number
DE1127861B
DE1127861B DED31827A DED0031827A DE1127861B DE 1127861 B DE1127861 B DE 1127861B DE D31827 A DED31827 A DE D31827A DE D0031827 A DED0031827 A DE D0031827A DE 1127861 B DE1127861 B DE 1127861B
Authority
DE
Germany
Prior art keywords
polyalkylene
dispersion
yarns
fibers
abrasion resistance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DED31827A
Other languages
German (de)
Inventor
Dr Karl Dithmar
Peter Koblischek
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Degussa GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE596350D priority Critical patent/BE596350A/fr
Application filed by Degussa GmbH filed Critical Degussa GmbH
Priority to DED31827A priority patent/DE1127861B/en
Priority to CH1182360A priority patent/CH433183A/en
Priority to FR843181A priority patent/FR1273565A/en
Publication of DE1127861B publication Critical patent/DE1127861B/en
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/35—Abrasion, pilling or fibrillation resistance

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Woven Fabrics (AREA)

Description

Es ist bekannt, flüchtige Verbindungen des SiIiciums, Aluminiums, Titans undZirkons, insbesondere ihre Chloride, bei erhöhten Temperaturen, z.B. bei 600 bis 1200° C, zu zersetzen, wobei die entsprechenden Oxyde entstehen. Hierbei arbeitet man zweckmäßig in Gegenwart oxydierender Gase, z.B. von Sauerstoff oder Luft, oder in Gegenwart hydrolysierender Gase, ζ. B. Luft oder Wasserdampf, oder mit Gemischen solcher Gase. Hierbei entstehen die Oxyde in sehr feinverteilter Form mit einer besonderen Oberfläche und Struktur. Das so erhaltene Siliciumdioxyd wird z. B. unter dem Handelsnamen Aerosil® vertrieben.It is known that volatile compounds of silicon Aluminum, titanium and zircon, especially their chlorides, at elevated temperatures, e.g. 600 to 1200 ° C, to decompose, whereby the corresponding oxides are formed. Here one works expediently in the presence of oxidizing gases, e.g. oxygen or air, or in the presence of hydrolyzing Gases, ζ. B. air or water vapor, or with mixtures of such gases. This creates the oxides in a very finely divided form with a special surface and structure. The silica thus obtained is z. B. sold under the trade name Aerosil®.

Es ist ferner bekannt, Fasern, Garne, Gewebe oder Textilwaren mit wäßrigen Dispersionen solcher Oxyde zu behändem. Die Oxyde werden von dem zu behandelnden Gut aufgenommen und geben ihm eine rauhe Oberfläche, die besonders beim Spinnen von Vorteil ist. Aus so behandelten Fasern gesponnene Garne haben eine bedeutend höhere Reißfestigkeit; die Scheuerfestigkeit wird aber durch diese Behandlung nicht verbessert. ~~~ It is also known to handle fibers, yarns, fabrics or textile goods with aqueous dispersions of such oxides. The oxides are absorbed by the material to be treated and give it a rough surface, which is particularly advantageous when spinning. Yarns spun from fibers treated in this way have a significantly higher tensile strength; however, this treatment does not improve the abrasion resistance. ~~~

Es ist schließlich bekannt, Garne und Gewebe mit wäßrigen Dispersionen von Polyäthylen zu behandeln. Hierbei kann die Scheuerfestigkeit um ein Mehrfaches verbessert werden.Finally, it is known to treat yarns and fabrics with aqueous dispersions of polyethylene. The abrasion resistance can be improved several times over.

Es wurde nun überraschenderweise gefunden, daß man die Scheuerfestigkeit von Fasern, Garnen, Geweben, Gewirken oder Textilwaren aus natürlichen oder synthetischen Stoffen wesentlich verbessern kann, wenn man das Gut mit einer wäßrigen Dispersion tränkt, die mindestens ein Oxyd von Silicium, Aluminium, Titan oder Zirkon und mindestens ein Polyalkylen, vorzugsweise Polyäthylen, enthält. Erfindungsgemäß verwendet man solche Oxyde, die durch Zersetzen einer flüchtigen Verbindung der entsprechenden Elemente in der Gasphase bei erhöhter Temperatur, vorzugsweise in Gegenwart hydrolysierender und bzw. oder oxydierender Gase gewonnen sind. Nach dem Tränken wird das Gewebe in an sich bekannter Weise getrocknet, vorzugsweise nachdem man den Überschuß der Tränkungsflüssigkeit entfernt hat.It has now been found, surprisingly, that the abrasion resistance of fibers, yarns, fabrics, Significantly improve knitted or textile goods made from natural or synthetic materials can, if the material is soaked with an aqueous dispersion containing at least one oxide of silicon, Aluminum, titanium or zirconium and at least one polyalkylene, preferably polyethylene, contains. According to the invention one uses such oxides, which by decomposing a volatile compound of the corresponding Elements in the gas phase at elevated temperature, preferably in the presence of hydrolyzing and / or oxidizing gases are obtained. After soaking, the tissue becomes in itself dried in a known manner, preferably after removing the excess of the impregnation liquid Has.

Es wurde ferner gefunden, daß es zweckmäßig ist, eine solche Dispersion zu verwenden, die auf 100 Teile des Fasergewichts 1 bis 25 Teile des Oxyds und des Polyalkylens enthält. Hierbei ist es vorteilhaft, auf 1 Teil des Oxyds 0,5 bis 5 Teile des Polyalkylens zu verwenden.It has also been found that it is convenient to use such a dispersion that is made up of 100 parts the fiber weight contains 1 to 25 parts of the oxide and the polyalkylene. Here it is advantageous to 1 part of the oxide to use 0.5 to 5 parts of the polyalkylene.

Als Polyalkylen kommen neben dem Polyäthylen beispielsweise auch Polyisobutylen und Polyisopropylen in Betracht. Als ausgezeichnet geeignet hat sichIn addition to polyethylene, there are also polyisobutylene and polyisopropylene, for example, as polyalkylene into consideration. Has proven to be excellently suited

Verfahren zum Verbessern
der Scheuerfestigkeit von Fasern, Garnen,
v Geweben, Gewirken oder TextilwarenMethod of improvement
the abrasion resistance of fibers, yarns,
v woven, knitted or textile products

Anmelder:Applicant:

Deutsche Gold- und Silber-ScheideanstaltGerman gold and silver refinery

vormals Roessler,
Frankfurt/M., Weißfrauenstr. 9formerly Roessler,
Frankfurt / M., Weißfrauenstr. 9

Dr. Karl Dithmar und Peter Koblischek,Dr. Karl Dithmar and Peter Koblischek,

Frankfurt/M.,
sind als Erfinder genannt wordenFrankfurt / M.,
have been named as inventors

ein Polyäthylen erwiesen, das einen geringen Polymerisationsgrad und daher einen niederen Schmelz^proved a polyethylene, which has a low degree of polymerization and therefore a low melting ^

as punkt, z. B. von etwa 90 bis 105° C, hat.the point, e.g. B. from about 90 to 105 ° C.

Der wäßrigen Dispersion können nach Bedarf Netz-, Emulgier- oder Dispergiermittel, vorzugsweise nichtionogener Art, zugesetzt werden. Der pH-Wert dieser Dispersion kann bei Bedarf durch Zusatz an sich bekannter Stoffe geregelt werden.Wetting agents, emulsifiers or dispersants, preferably of a nonionic type, can be added to the aqueous dispersion as required. The pH-value of this dispersion can be controlled in known fabrics by the addition as needed.

Zur Herstellung der Dispersion des Polyalkylens kann in an sich bekannter Weise so vorgegangen werden, daß man das Polyalkylen schmilzt und unter Rühren in heißes Wasser einträgt. Das Oxyd kann hierbei vorher, gleichzeitig oder nachher, z.B in Form einer wäßrigen Dispersion, zugegeben werden.To prepare the dispersion of the polyalkylene, the procedure known per se can be as follows: that the polyalkylene is melted and introduced into hot water with stirring. The oxide can in this case before, simultaneously or afterwards, e.g. in the form of an aqueous dispersion.

Nach dem Behändem mit der Dispersion kann man zunächst die überschüssige Flüssigkeit entfernen, z. B. durch Abschleudern oder Abpressen, und das Gut dann trocknen. In vielen Fällen werden besonders gute Erfolge erzielt, wenn man die Trockentemperatur über dem Schmelzpunkt des Polyalkylens hält oder das getrocknete Gut nachher kurze Zeit auf eine solche Temperatur erhitzt.After handling the dispersion, you can first remove the excess liquid, z. B. by centrifuging or pressing, and then dry the material. In many cases it will be Particularly good results are achieved if the drying temperature is above the melting point of the polyalkylene or the dried goods are heated to such a temperature for a short time afterwards.

Es ist zwar bekannt, textile Faserstoffe oder aus ihnen hergestellte Erzeugnisse dadurch zu veredeln, daß man auf ihrer Oberfläche durch thermische Hydrolyse von Aluminiumchlorid nach bekannten Methoden gewonneneAluminiumoxydaerogele aufbringt.It is known that textile fibers or products made from them can be refined by that on their surface by thermal hydrolysis of aluminum chloride by known methods applied alumina aerogels obtained.

Die hierzu verwendeten Dispersionen können auch Kunstharzemulsionen enthalten. Versuche haben aber gezeigt, daß gerade die Verwendung von PolyalkylenenThe dispersions used for this purpose can also contain synthetic resin emulsions. Attempts have but shown that it is precisely the use of polyalkylenes

209 560/485209 560/485

als Kunstharz in Dispersionen femverteilter Oxyde eine Scheuerfestigkeit ergibt, die zwei- bis vierfach höher liegt als eine Scheuerfestigkeit, die mit. entsprechenden Dispersionen unter Verwendung anderer Kunstharze erzielt wird. * - - -5as a synthetic resin in dispersions of widely distributed oxides results in a rub resistance that is two to fourfold is higher than an abrasion resistance with. appropriate dispersions using others Synthetic resins is achieved. * - - -5

Beispiel 1 '" 'Example 1 '" '

60 m eines Gewebes, das in Kette und Schuß aus Zellwollgarn besteht, wird, auf einem Foulard unter langsamer Durchführung durch eine wäßrige Dispersion geführt, die im Liter folgende Bestandteile enthält: : ;-." '-. .·.-;60 m of a fabric made in warp and weft of Zellwollgarn, is guided on a pad-mangle with slow passage through an aqueous dispersion containing, per liter, the following components:: - '' - · .-;...

66,6 g niederschmelzendes Polyäthylen (AOPolyäthylen 629),66.6 g low-melting polyethylene (AOPolyäthylen 629),

8,3 g äthoxylierter Fettalkohol,8.3 g ethoxylated fatty alcohol,

8,3 g Morpholin,
28,0 g femverteäföS: Si O2 (Aerosil).8.3 g morpholine,
28.0 g femverteaföS: Si O 2 (Aerosil).

Die Verweilzeit der Ware in dem Bad beträgt 15 Miauten. Nach dem Imprägnieren wird so weit abgequetscht, daß auf 100 Teile Trockengewicht noch 100 Teile Flüssigkeit verbleiben. Dann wird bei 105 bis 110° C getrocknet.The dwell time of the goods in the bath is 15 meows. So far after impregnation squeezed off so that 100 parts of liquid remain per 100 parts dry weight. Then at Dried at 105 to 110 ° C.

Die Prüfung auf Scheuerfestigkeit wird mit dem Karborund-Keil-Apparat von Professor Weltzien/ Krefeld mit 3 cm breiten Streifen durchgeführt. Das Belastungsgewicht beträgt 600 g, die Geschwindigkeit 100 Touren/Min., dieSpannhöheSOmm, der Scheuerwinkel (Ausschlag vom Keil) 40°. Die Messungen werden bei 65 % relativer Luftfeuchtigkeit und 20 bis 22° C durchgeführt. Die Ergebnisse sind in der nachstehenden Tabelle enthalten: -The abrasion resistance test is carried out with the carborundum wedge apparatus from Professor Weltzien / Krefeld carried out with 3 cm wide strips. The load weight is 600 g, the speed 100 tours / min., The clamping height SOmm, the rubbing angle (Deflection of the wedge) 40 °. The measurements are made at 65% relative humidity and 20 to 22 ° C. The results are in the following Table include: -

3535

4040

45 Die Ware wird ebenso wie im Beispiel 1 behandelt. Bei der Prüfung auf die Scheuerfestigkeit werden folgende Werte erhalten: 45 The goods are treated in the same way as in example 1. When testing the rub resistance, the following values are obtained:

Materialmaterial Anzahl der
Scheuerungen
bis zum
Verschleißnumber of
Chafing
until
wear and tear Steigerung
der
Scheuer-
festigkeit
%>increase
the
Abrasive
strength
%> Baumwolle unbehandelt ..
Baumwolle mit der Disper
sion behandelt
Baumwolle mitPolyäthylen,
ohne SiO2 behandelt
(zum Vergleich) Cotton untreated.
Cotton with the disper
sion treated
Cotton with polyethylene,
treated without SiO 2
(for comparison) 1390
11270
80081390
11270
8008 0
711
4770
711
477

Materialmaterial Anzahl der
Scheuerungen
bis zum
Verschleißnumber of
Chafing
until
wear and tear Steigerung
der
Scheuer
festigkeit
%increase
the
Chafing
strength
% Zellwolle unbehandelt ...
Zellwolle nach Beispiel 1
behandelt
Zellwolle mit Polyäthylen,
ohne SiO2 behandelt (als
Vergleich) Spun rayon untreated ...
Spun rayon according to Example 1
treated
Rayon with polyethylene,
treated without SiO 2 (as
Comparison) 1090
8535
39301090
8535
3930 0
683
2600
683
260

Beispiel 2Example 2

Ein in Kette und Schuß aus Baumwollgarn bestehendes schwarzes Popelinegewebe wird wie im Beispiel 1 mit einer wäßrigen Dispersion behandelt, die im Liter folgende Stoffe enthält:A warp and weft made of cotton thread black poplin fabric is treated with an aqueous dispersion as in Example 1, which contains the following substances per liter:

55,0 g Polyäthylen nach Beispiel 1, .55.0 g of polyethylene according to Example 1,.

10,0 g äthoxylierter Fettalkohol nach Beispiel 1,10.0 g ethoxylated fatty alcohol according to Example 1,

10.0 g MorphoEn, ...10.0 g MorphoEn, ...

18.1 g feinverteiltes SiO2.18.1 g finely divided SiO 2 .

Claims (5)

PATENTANSPRÜCHE:PATENT CLAIMS: 1. Verfahren zum Verbessern der Scheuerfestigkeit von Fasern, Garnen, Geweben, Gewirken oder Textilwaren aus natürlichen oder synthetischen Stoffen durch Tränken des zu behandelnden Gutes mit einer wäßrigen Dispersion mindestens eines Oxydes von Silicium, Aluminium, Titan oder Zirkon, das durch Zersetzen einer flüchtigen Verbindung dieser Elemente in der Gasphase bei erhöhter Temperatur, vorzugsweise in Gegenwart hydrolysierender und bzw. oder oxydierender Gase, gewonnen ist, und nachfolgendes Trocknen, gekennzeichnet durch die Verwendung einer Dispersion, die ein Polyalkylen, vorzugsweise Polyäthylen, enthält. 1. A method for improving the abrasion resistance of fibers, yarns, woven, knitted or textile goods made of natural or synthetic materials by impregnating the material to be treated with an aqueous dispersion of at least one oxide of silicon, aluminum, titanium or zirconium, which by decomposition of a volatile compound these elements is obtained in the gas phase at elevated temperature, preferably in the presence of hydrolyzing and / or oxidizing gases, and subsequent drying, characterized by the use of a dispersion which contains a polyalkylene, preferably polyethylene. 2. Verfahren nach Anspruch 1, gekennzeichnet durch die Verwendung einer Dispersion, die auf 100 Teile des Fasergewichts 1 bis 25 Teile des Oxyds und Polyalkylens enthalten.2. The method according to claim 1, characterized by the use of a dispersion which contain 1 to 25 parts of the oxide and polyalkylene per 100 parts of the fiber weight. 3. Verfahren nach Anspruch 1 oder 2, gekennzeichnet durch die Verwendung einer Dispersion, die auf 1 Teil des Oxyds 0,5 bis 5 Teile des Polyalkylens enthält.3. The method according to claim 1 or 2, characterized by the use of a dispersion, which contains 0.5 to 5 parts of the polyalkylene per 1 part of the oxide. 4. Verfahren nach einem der Ansprüche 1 bis 3, gekennzeichnet durch die Verwendung solcher Dispersionen, die Netz-, Emulgier- oder Dispergiermittel, vorzugsweise nichtionogener Art, enthalten.4. The method according to any one of claims 1 to 3, characterized by the use such dispersions, the wetting, emulsifying or dispersing agents, preferably non-ionic type, contain. 5. Verfahren nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, daß man das getränkte Gut während oder nach dem Trocknen auf Temperaturen über dem Schmelzpunkt des Polyalkylens erwärmt.5. The method according to any one of claims 1 to 4, characterized in that the soaked Good during or after drying to temperatures above the melting point of the Polyalkylene heated. 55 In Betracht gezogene Druckschriften:
Deutsche Auslegeschrift Nr. 1000 334;
Deutsche Patentschrift Nr. 946 704.55 Considered publications:
German Auslegeschrift No. 1000 334;
German patent specification No. 946 704. © 209 560/485 4.62© 209 560/485 4.62
DED31827A 1959-11-06 1959-11-06 Process for improving the abrasion resistance of fibers, yarns, woven, knitted or textile goods Pending DE1127861B (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
BE596350D BE596350A (en) 1959-11-06
DED31827A DE1127861B (en) 1959-11-06 1959-11-06 Process for improving the abrasion resistance of fibers, yarns, woven, knitted or textile goods
CH1182360A CH433183A (en) 1959-11-06 1960-10-21 Process for improving the abrasion resistance of textiles and textiles finished with them
FR843181A FR1273565A (en) 1959-11-06 1960-11-07 Fibers, threads, fabrics, knits or textile articles of increased abrasion resistance and method for their manufacture

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DED31827A DE1127861B (en) 1959-11-06 1959-11-06 Process for improving the abrasion resistance of fibers, yarns, woven, knitted or textile goods

Publications (1)

Publication Number Publication Date
DE1127861B true DE1127861B (en) 1962-04-19

Family

ID=7041074

Family Applications (1)

Application Number Title Priority Date Filing Date
DED31827A Pending DE1127861B (en) 1959-11-06 1959-11-06 Process for improving the abrasion resistance of fibers, yarns, woven, knitted or textile goods

Country Status (3)

Country Link
BE (1) BE596350A (en)
CH (1) CH433183A (en)
DE (1) DE1127861B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3443327C1 (en) * 1984-11-28 1985-09-05 Rosorius, Gerhard, 2085 Quickborn Process for improving the properties of textiles consisting of or containing native vegetable or animal fibers

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE946704C (en) * 1953-12-29 1956-08-02 Basf Ag Process for the production of impregnations on textiles
DE1000334B (en) * 1954-05-03 1957-01-10 Degussa Process for the finishing of textile fibers

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE946704C (en) * 1953-12-29 1956-08-02 Basf Ag Process for the production of impregnations on textiles
DE1000334B (en) * 1954-05-03 1957-01-10 Degussa Process for the finishing of textile fibers

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3443327C1 (en) * 1984-11-28 1985-09-05 Rosorius, Gerhard, 2085 Quickborn Process for improving the properties of textiles consisting of or containing native vegetable or animal fibers
US4773912A (en) * 1984-11-28 1988-09-27 Heidelinde Nordmann Process for increasing the performance of pleated silk or wool by treatment with keratolytic liquor and impregnating with glazing powder and heating

Also Published As

Publication number Publication date
CH433183A (en) 1967-09-30
CH1182360A4 (en) 1964-10-15
BE596350A (en)

Similar Documents

Publication Publication Date Title
DE762964C (en) Process for making cellulose fibers water repellent
DE1086669B (en) Process for waterproofing textiles, paper, cardboard, furs and feathers
DE3877443T2 (en) METHOD FOR GRAFTING FLUORINATED MONOMERS FOR WATERPROOFING TEXTILE MATERIAL.
DE1151780B (en) Process for changing the properties of molded articles made from high polymer polyesters
EP0108925B1 (en) Lubricating agent for textile fibre material
EP0572923A1 (en) Process for the "wash-and-wear" finishing of cellulose textile, without formaldehyde
DE69429360T2 (en) USE OF AN AQUEOUS TANNIC ACID SOLUTION TO IMPROVE Stain Repellency of Fiber Substrates
DE2622609A1 (en) PROCESS FOR THE DIRT-REPELLENT FINISHING OF POLYESTER TEXTILES
DE1127861B (en) Process for improving the abrasion resistance of fibers, yarns, woven, knitted or textile goods
EP0151402B1 (en) Composition for the melt spinning of synthetic fibrous materials
AT224600B (en) Process for the production of highly abrasion-resistant fibers, yarns, woven fabrics, knitted fabrics and textile goods
DE2326364A1 (en) SOLVENT BLEACHING PROCESS
EP0236735B1 (en) Transformed glass fibre with a modified heat resistance
DE1444012A1 (en) Process for bleaching cellulose fibers
DE1000334B (en) Process for the finishing of textile fibers
DE2140325C3 (en) Bleaching process for cellulose textiles
DE69104634T2 (en) Oxidized polygalactomannan for improved textile washing.
DE2212718C3 (en) Process for improving the flame resistance of natural or synthetic polyamide fibers
DE731667C (en) Process for finishing textile goods
US2107703A (en) Process for rendering wool material unshrinkable and nonfelting product made thereby
DE1034133B (en) Process for reducing pilling of textile material based on polyesters containing six-membered carbocyclic rings
GB2220009A (en) Stain resistant
DE348194C (en) Process to increase the strength and elasticity of wool, cotton and other vegetable fibers in a spinnable or spun state, as well as of artificial silk, hair and feathers in a dyed or undyed state
AT264444B (en) Method of treating keratin fibers to make them non-feltable
DE883884C (en) Process for finishing textile goods and other fiber material