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DE1032872B - lubricant - Google Patents

lubricant

Info

Publication number
DE1032872B
DE1032872B DED23604A DED0023604A DE1032872B DE 1032872 B DE1032872 B DE 1032872B DE D23604 A DED23604 A DE D23604A DE D0023604 A DED0023604 A DE D0023604A DE 1032872 B DE1032872 B DE 1032872B
Authority
DE
Germany
Prior art keywords
fluorides
lubricants
lubricant
oil
solid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DED23604A
Other languages
German (de)
Inventor
Dr-Ing Max Eitel
Dr Wilhelm Sibert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daimler Benz AG
Original Assignee
Daimler Benz AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daimler Benz AG filed Critical Daimler Benz AG
Priority to DED23604A priority Critical patent/DE1032872B/en
Publication of DE1032872B publication Critical patent/DE1032872B/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02Water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/041Carbon; Graphite; Carbon black
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/041Carbon; Graphite; Carbon black
    • C10M2201/042Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
    • C10M2201/081Inorganic acids or salts thereof containing halogen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
    • C10M2201/082Inorganic acids or salts thereof containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
    • C10M2201/084Inorganic acids or salts thereof containing sulfur, selenium or tellurium
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/101Condensation polymers of aldehydes or ketones and phenols, e.g. Also polyoxyalkylene ether derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/02Unspecified siloxanes; Silicones
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04Siloxanes with specific structure
    • C10M2229/05Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10Form in which the lubricant is applied to the material being lubricated semi-solid; greasy

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Description

Schmiermittel Die Erfindung betrifft die Schmierung von Maschinen oder gleitend beanspruchten Teilen und besteht in der Verwendung von Fluoriden als Schmiermittel.Lubricants The invention relates to the lubrication of machines or slidingly claimed parts and consists in the use of fluorides as Lubricant.

Die Schmierwirkung bekannter Schmiermittel, wie C51, wird durch den Zusatz von Fluorid erheblich verbessert. Erfindungsgemäß werden die Fluoride auch in Verbindung mit für feste Schmierstoffe an sich bekannten flüssigen Trägern, wie Glyzerin, höheren mehrwertigen Alkoholen oder Silikonen, als Schmiermittel verwendet. In weiterer Ausgestaltung der Erfindung werden Fluoride auch in Verbindung mit für feste Schmierstoffe an sich bekannten festen Trägern, wie Lacken, Kunst- oder Naturharzen, verwendet.The lubricating effect of known lubricants, such as C51, is enhanced by the Addition of fluoride significantly improved. According to the invention, the fluorides are also in connection with liquid carriers known per se for solid lubricants, such as Glycerin, higher polyhydric alcohols, or silicones, are used as lubricants. In a further embodiment of the invention, fluorides are also used in conjunction with for solid lubricants solid carriers known per se, such as paints, synthetic or natural resins, used.

Mit Fluoriden, wie Flußspat und Kryolith, wurden auf der Almen-Wieland-Ölprüfmaschine Versuche angestellt, die zu gleich guten Ergebnissen führten wie die Versuche mit Sulfiden. Natriumfluorid als Zusatz zu Öl ergibt eine Schmierfähigkeit, wie sie beim Zusatz von Zinksulfid zu Öl festgestellt wird. Mit 1 % Fluorid in Öl, das für sich 300 kg Belastung aushält, konnte auf der Almen-Wieland-Prüfmaschine wie bei Zinksulfid eine Belastung von 1500 kg erreicht werden.Fluorides such as fluorspar and cryolite were used on the Almen-Wieland oil testing machine Tests made which led to the same good results as the tests with Sulphides. Sodium fluoride added to oil gives lubricity like them when zinc sulfide is added to oil. With 1% fluoride in oil that is used for can withstand a load of 300 kg on the Almen-Wieland testing machine, as with Zinc sulfide a load of 1500 kg can be achieved.

Mit dem Vierkugelapparat wurde folgender Versuch durchgeführt: Kryolith und/oder Flußspat wurden mit farblosem Zaponlack angerührt und auf die Kugeln des Vierkugelapparates aufgebracht. Mit Öl, das für sich 200 kg Belastung aushält, konnte die Druckfestigkeit des Schmierfilmes auf 700 kg gesteigert werden. Dies entspricht den mit Zink- oder Molybdänsulfid erzielten Werten.The following experiment was carried out with the four-ball apparatus: Cryolite and / or fluorspar were mixed with colorless zapon varnish and placed on the balls of the Four ball apparatus applied. With oil that can withstand a load of 200 kg the compressive strength of the lubricating film can be increased to 700 kg. This matches with the values achieved with zinc or molybdenum sulfide.

Auch als Trockenschmiermittel erhält Flußspat mehr Belastung aus als Graphit. Mit in Wasser suspendierten Fluoriden kann man ähnliche Versuche durchführen wie mit Fluoriden und Öl.Even as a dry lubricant, fluorspar is exposed to more stress than Graphite. Similar experiments can be carried out with fluorides suspended in water like with fluorides and oil.

Es ist bekannt, daß Stoffe, wie Teflon (Polytetrafluoräthylen) oder Hostaflon (Polychlorfluoräthylen), gute Gleiteigenschaften aufweisen. Es ist auch bekannt, als Ölbasis eines feinverteiltes Indium enthaltenden Schmiermittels an Stelle von halogenierten Kohlewasserstoffen Fluorkohlenstoffverbindungen zu verwenden. Des weiteren hat man bereits den Viskositätsindex von leichten Schmierölsorten durch Zusatz geringer Mengen von perfluorierten oder per-Chlorierten organischen Säuren verbessert.It is known that substances such as Teflon (polytetrafluoroethylene) or Hostaflon (polychlorofluoroethylene), have good sliding properties. It is also known as the oil base of a finely divided indium-containing lubricant Place of halogenated hydrocarbons to use fluorocarbon compounds. Furthermore, the viscosity index of light types of lubricating oil has already been studied Addition of small amounts of perfluorinated or per-chlorinated organic acids improved.

Ferner sind Kunstharze und Gleitlager aus Kunstharzpreßstoffen mit einem Gehalt an Calciumfluorid bekannt. Bei Verwendung von Flußspat als Füllstoff von Phenol-Aldehyd-Harzen lassen sich dichte, mechanisch feste und elektrisch hochwertige Preßteile herstellen. Bei der Herstellung von Gleitlagern aus Kunstharzpreßstoffen rangieren aber die Fluoride Flußspat oder Kryolith gewissermaßen erst an letzter Stelle hinter Silikaten, Karbonaten, Oxyden und Sulfaten als Füllstoffe. Die guten Schmiereigenschaften der Fluoride sind bei diesen bekannten Fällen der Verwendung aber offensichtlich nicht erkannt worden.Furthermore, synthetic resins and plain bearings are made from synthetic resin molded materials a content of calcium fluoride known. When using fluorspar as a filler Phenol-aldehyde resins can be used to produce dense, mechanically strong and electrically high quality Manufacture pressed parts. In the manufacture of plain bearings from synthetic resin molded materials but the fluorides fluorspar or cryolite rank last, so to speak Place behind silicates, carbonates, oxides and sulfates as fillers. The good ones Lubricating properties of the fluorides are known in these cases of use but obviously not recognized.

Claims (4)

PATENTANSPRÜCHE: 1. Verwendung von Fluorideri als Schmiermittel. PATENT CLAIMS: 1. Use of Fluorideri as a lubricant. 2. Verwendung von Fluoriden nach Anspruch 1 in Verbindung mit bekannten Schmiermitteln. 2. Use of fluorides according to claim 1 in connection with known lubricants. 3. Verwendung von Fluoriden nach Anspruch 1 in Verbindung mit für feste Schmierstoffe an sich bekannten flüssigen Trägern, wie Glyzerin, höheren ulehrwertigen Alkoholen oder Silikonen. 3. Use of fluorides according to claim 1 in conjunction with for solid lubricants liquid carriers known per se, such as glycerine, higher polyhydric alcohols or silicones. 4. Verwendung von Fluoriden nach Anspruch 1 in Verbindung mit für feste Schmierstoffe an sich bekannten festen Trägern, wie Lacken, Kunst-oder Naturharzen. In Betracht gezogene Druckschriften: Französische Patentschrift Nr. 838 779; Scheiter: Chemie und Technologie der künstlichen Harze (1949), 529.4. Use of fluorides according to claim 1 in connection with for solid lubricants solid carriers known per se, such as paints, synthetic or natural resins. Documents considered: French Patent No. 838 779; Failure: Chemistry and Technology of Artificial Resins (1949), 529.
DED23604A 1956-08-18 1956-08-18 lubricant Pending DE1032872B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DED23604A DE1032872B (en) 1956-08-18 1956-08-18 lubricant

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DED23604A DE1032872B (en) 1956-08-18 1956-08-18 lubricant

Publications (1)

Publication Number Publication Date
DE1032872B true DE1032872B (en) 1958-06-26

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ID=7037878

Family Applications (1)

Application Number Title Priority Date Filing Date
DED23604A Pending DE1032872B (en) 1956-08-18 1956-08-18 lubricant

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1074795B (en) 1960-02-04 Institut Dr.-Ing. Reinhard Straumann A.G., Waidenburg (Schweiz) lubricant
DE1090363B (en) * 1958-09-26 1960-10-06 Trafotherm Physikalische Werks Mineral lubricating oil
EP1625192A4 (en) * 2003-05-15 2008-06-25 Jet Lube Resin bonded particulate anti-seize agent, lubricating system made therefrom and methods of making and using same

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR838779A (en) * 1937-06-03 1939-03-15 Bakelite Gmbh Pressed artificial resin masses for sliding bearings

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR838779A (en) * 1937-06-03 1939-03-15 Bakelite Gmbh Pressed artificial resin masses for sliding bearings

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1074795B (en) 1960-02-04 Institut Dr.-Ing. Reinhard Straumann A.G., Waidenburg (Schweiz) lubricant
DE1090363B (en) * 1958-09-26 1960-10-06 Trafotherm Physikalische Werks Mineral lubricating oil
EP1625192A4 (en) * 2003-05-15 2008-06-25 Jet Lube Resin bonded particulate anti-seize agent, lubricating system made therefrom and methods of making and using same

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