DE102011089560A1 - Antiperspirant suspension spray with improved drug release and reduced textile soiling - Google Patents

Abstract

The present application relates to antiperspirant suspension sprays with improved release of active ingredient and reduced textile soiling.

Description

The present application relates to antiperspirant suspension sprays with improved release of active ingredient and reduced textile soiling.

Spray products are an indispensable part of modern everyday life. Numerous cosmetic products, such as hair sprays, deodorant sprays and oral sprays, allow a convenient, fast and uniform product application, which is highly appreciated by many consumers, thanks to the spray application. A product form particularly popular with consumers are antiperspirant sprays. These contain an antiperspirant aluminum salt, which reacts relatively sour in contact with water. For this reason, hydrous antiperspirant sprays are more of a niche product, because the development of a stable, non-corrosive and effective formulation is not trivial. In contrast, anhydrous antiperspirant sprays enjoy great popularity in the market. In this product form, the antiperspirant aluminum salt, which must be zirconium-free by law, is present in at least one liquid suspended under normal conditions. For better applicability, at least one lipophilic thickener is added to this suspension as suspending aid, usually a hydrophobically modified phyllosilicate which is preferably selected from disteardimonium hectorite, stearalkonium hectorite, stearalkonium bentonite, quaternium-18 hectorite, quaternium-18 bentonite and dihydrogenated tallow benzylmonium hectorite. In these commercial sprays, the antiperspirant active suspended in the anhydrous carrier is covered with an oil layer. During and after the application on the skin, this oil layer favors the spray pattern, that is, the active ingredient is not too much fogged, but reaches the skin specifically; In addition, the oil layer provides some adhesion of the powdered antiperspirant active to the skin. However, this oil layer may delay the release of the antiperspirant active into the effective water-soluble form. In particular, less volatile oils contribute to a delay in drug release. In addition, a high proportion of less volatile oils leads to poorly washable textile stains.

Cyclomethicone is already known in the art as a well-suited carrier oil for antiperspirant sprays. Since this oil has a relatively high volatility and thus does not block the antiperspirant active too strong, achieved with Cyclomethicone a very satisfactory release of Antitranspirantwirkstoffs and a relatively low Textilanschmutzung. The use of cyclomethicones should be avoided as far as possible due to its persistence.

It was therefore an object of the present application to formulate spray-free anhydrous antiperspirant compositions which, as far as possible, omit cyclomethicones which have improved release of the antiperspirant active ingredient and / or cause relatively little textile soiling.

Surprisingly, it has now been found that the release of the antiperspirant active from an anhydrous antiperspirant composition can be improved and / or the fabric soiling can be reduced if it comprises a relatively high level of volatile non-silicone oils, a relatively low level of non-volatile oils and 0 to less than 1 wt .-% cyclomethicone.

• a) mindestens ein schweißhemmendes Aluminiumsalz in einer Gesamtmenge von > 25 bis 40 Gew.-%,
• b) 0–5 Gew.-% freies Wasser, bezogen auf das Gewicht der treibmittelfreien Zusammensetzung,
• c) 30–75 Gew.-%, bevorzugt 50–70 Gew.-%, besonders bevorzugt 54–64 Gew.-%, einer Mischung von unter Normalbedingungen flüssigen kosmetischen Ölen, die kein ätherisches Öl und kein Riechstoff sind, wobei mehr als 60 Gew.-% bis weniger als 90 Gew.-% dieser Ölmischung, bezogen auf das Gewicht der Ölmischung, aus mindestens einem flüchtigen Isoparaffin oder einer flüchtigen Isoparaffinmischung, jeweils mit einem Dampfdruck bei 20°C von 8 bis 250 Pa, besteht und mehr als 10 Gew.-% bis weniger als 40 Gew.-% dieser Ölmischung, bezogen auf das Gewicht der Ölmischung, aus mindestens einem nicht-flüchtigen Esteröl oder einer nicht-flüchtigen Esterölmischung, jeweils mit einem Dampfdruck bei 20°C von weniger als 2,66 Pa (0,02 mm Hg),
• d) 0 bis weniger als 1 Gew.-% Cyclomethicone, bezogen auf das Gewicht der treibmittelfreien Zusammensetzung.

wobei sich die Gew.-%-Angaben auf das Gewicht der gesamten Zusammensetzung beziehen, mit Ausnahme der Angaben zu Merkmal c). The present invention is therefore an antiperspirant composition for personal care in the form of a propellant sprayable or sprayable with a propellant suspension containing

• a) at least one antiperspirant aluminum salt in a total amount of> 25 to 40 wt .-%,
• b) 0-5 wt .-% free water, based on the weight of the blowing agent-free composition,
• c) 30-75 wt .-%, preferably 50-70 wt .-%, particularly preferably 54-64 wt .-%, of a mixture of liquid under normal conditions cosmetic oils, which are not essential oil and no perfume, wherein more than 60 wt .-% to less than 90 wt .-% of this oil mixture, based on the weight of the oil mixture, from at least one volatile isoparaffin or a volatile Isoparaffinmischung, each with a vapor pressure at 20 ° C from 8 to 250 Pa, and more from 10% to less than 40% by weight of this oil blend, based on the weight of the oil blend, of at least one non-volatile ester oil or non-volatile ester oil blend, each having a vapor pressure of less than 2 at 20 ° C , 66 Pa (0.02 mm Hg),
• d) 0 to less than 1 wt .-% cyclomethicones, based on the weight of the blowing agent-free composition.

the weight percentages being based on the weight of the whole composition, with the exception of characteristic c).

The compositions of the invention are substantially anhydrous, ie they contain 0 to at most 5 wt .-%, preferably 0.5 to 4.5 wt .-%, particularly preferably 1 to 4 wt .-%, most preferably 1.5 to 3 Wt .-% free water, wherein also levels of free water of 1.6-2.4 wt .-%, 1.7-2.3 wt .-% and 1.8-2.2 wt .-% are preferred and where the amounts are based on the weight of the composition, without taking into account any existing propellant. The content of water of crystallization, water of hydration or similar molecularly bound water which is contained in the constituents used, in particular in the antiperspirant active ingredients, does not constitute free water for the purposes of the present application.

"Normal conditions" in the sense of the present application, a temperature of 20 ° C and a pressure of 1013.25 mbar. Melting point data also refer to a pressure of 1013.25 mbar.

Preferred compositions according to the invention are characterized in that the volatile isoparaffin is selected from isononane, isodecane, isoundecane, isododecane, isotridecane, isotetradecane, isopentadecane, and isohexadecane, and mixtures thereof, preferably selected from isodecane, isoundecane, isododecane, isotridecane, and mixtures thereof. The cosmetic oil is liquid under normal conditions. Under normal conditions liquid cosmetic oils are immiscible with water. Essential oils according to the invention are understood to mean mixtures of volatile components which are prepared by steam distillation from vegetable raw materials, such as. B. citrus oils. As far as in the present application of a cosmetic oil is mentioned, this is always a cosmetic oil that is not a fragrance and no essential oil, is liquid under normal conditions and immiscible with water.

Particularly preferred are C ₁₀ -C ₁₃ isoparaffin mixtures, especially those having a vapor pressure at 20 ° C of 10-400 Pa, preferably 13-100 Pa. The at least one volatile isoparaffin having a vapor pressure at 20 ° C. of 8 to 250 Pa is present in a total amount of> 18 to <67.5% by weight, preferably> 30 to <63% by weight, particularly preferably> 32, 4- <57.6 wt .-%, most preferably 40-55 wt .-%, each based on the total propellant-free composition. Particularly preferred compositions contain a C ₁₀ -C ₁₃ isoparaffin mixture having a vapor pressure at 20 ° C of 10-400 Pa in a total amount of> 18 to <67.5 wt .-%, preferably> 30- <63 wt. %, more preferably> 32.4- <57.6% by weight, most preferably 40-55% by weight, in each case based on the total blowing agent-free composition.

Compositions which are preferred according to the invention are furthermore characterized in that the non-volatile ester oil having a vapor pressure at 20 ° C. of less than 2.66 Pa (0.02 mm Hg) is selected from esters of linear or branched saturated or unsaturated fatty alcohols with 2- 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2-30 carbon atoms, which may be hydroxylated, and the benzoic acid esters of linear or branched C _8-22 alkanols, provided that they are liquid under normal conditions.

Preferred examples thereof are isopropyl palmitate, isopropyl stearate, isopropyl myristate, 2-hexyldecyl stearate, 2-hexyldecyl laurate, isononyl isononanoate, 2-ethylhexyl palmitate and 2-ethylhexyl stearate. Also preferred are isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyl dodecyl palmitate, butyloctanoic acid 2-butyl octanoate, diisotridecyl acetate, n-hexyl laurate, n-decyl oleate, oleyl oleate, oleyl erucate , Erucyloleat, C ₁₂ -C ₁₅ -alkyllactate and di-C ₁₂ -C ₁₃ -alkylmalate and the benzoic acid esters of linear or branched C _8-22 -alkanols, and mixtures of these esters. Particularly preferred are benzoic acid C ₁₂ -C ₁₅ alkyl esters, for. B. available as a commercial product Finsolv ^® TN (C ₁₂ -C ₁₅ alkyl benzoate), and isostearyl benzoate, z. As available as Finsolv ^® SB, 2-ethylhexyl, z. B. available as Finsolv ^® EB, and benzoic acid 2-octyldocecylester, z. As available as Finsolv ^® BOD. Another particularly preferred ester oil is triethyl citrate. Extremely preferred ester oils are isopropyl myristate and 2-ethylhexyl palmitate.

The at least one non-volatile ester oil having a vapor pressure at 20 ° C of less than 2.66 Pa (0.02 mm Hg) is in a total amount of> 3 to <30 wt .-%, preferably> 5- <28 wt .-%, more preferably> 5.4- <25.6 wt .-%, most preferably 10-20 wt .-%, each based on the total propellant-free composition.

Preferred antiperspirant aluminum salts are selected from the water-soluble astringent inorganic and organic salts of aluminum. According to the invention, aluminosilicates and zeolites do not belong to the antiperspirant active ingredients, but may be involved as absorbent components in the reduction of perspiration.

According to the invention, water solubility is understood as meaning a solubility of at least 3% by weight at 20 ° C., that is to say amounts of at least 3 g of the antiperspirant active are soluble in 97 g of water at 20 ° C.

Particularly preferred antiperspirant active ingredients are selected from aluminum chlorohydrate, in particular aluminum chlorohydrate having the general formula [Al ₂ (OH) ₅ Cl. 1-6 H ₂ O] _n , preferably [Al ₂ (OH) ₅ Cl. 2-3H ₂ O] _n , which may be in non-activated or in activated (depolymerized) form, and aluminum chlorohydrate having the general formula [Al ₂ (OH) ₄ Cl ₂ .1-6H ₂ O] _n , preferably [Al ₂ (OH) ₄ Cl ₂ · 2-3H ₂ O] _n , which may be in unactivated or activated (depolymerized) form.

The preparation of preferred antiperspirant active ingredients is for example in US 3887692 . US 3904741 . US 4359456 . GB 2048229 and GB 1347950 disclosed.

Also preferred are aluminum sesquichlorohydrate, aluminum dichlorohydrate, aluminum chlorohydrex-propylene glycol (PG) or aluminum chlorohydrex-polyethylene glycol (PEG), aluminum-glycol complexes, e.g. Aluminum-propylene glycol complexes, aluminum sesquichlorohydrex PG or aluminum sesquichlorohydrex PEG, aluminum PG-dichlorhydrex or aluminum PEG-dichlorhydrex, aluminum hydroxide, further selected from potassium aluminum sulfate with zero to 12 parts of water of crystallization (KAl (SO ₄ ) ₂ .0H ₂ O, KAl (SO _{4) 2} · 1H ₂ O, KAl (SO _{4) 2} · 2 H ₂ O, KAl (SO _{4) 2} · 3H ₂ O, KAl (SO _{4) 2} · 4H ₂ O, KAl (SO _{4) 2} · 5H ₂ O, KAl (SO _{4) 2} · 6 H ₂ O, KAl (SO _{4) 2} · 7 H ₂ O, KAl (SO _{4) 2} · 8H ₂ O, KAl (SO _{4) 2} · 9H ₂ O, KAl (SO ₄ ) ₂ · 10H ₂ O, KAl (SO ₄ ) ₂ · 11H ₂ O KAl (SO ₄ ) ₂ · 12H ₂ O = alum, partially hydrated alum or alum), aluminum undecylenoyl collagen amino acid, Sodium aluminum lactate + aluminum sulfate, sodium aluminum chlorhydroxylactate, aluminum bromohydrate, aluminum chloride, the aluminum salts of lipoamino acids, aluminum sulfate, aluminum lactate, aluminum chlorohydrate allantoinate and sodium aluminum chlorohydroxylactate. According to the invention, particularly preferred antiperspirant active ingredients are selected from what are known as "activated" aluminum salts, which are also referred to as "antiperspirant active ingredients" having enhanced activity (English: enhanced activity). Such agents are known in the art and are also commercially available. Their preparation is for example in GB 2048229, US 4775528 and US 6010688 disclosed. Activated aluminum salts are typically produced by heat treating a relatively dilute solution of the salt (eg, about 10% by weight salt) to increase its HPLC peak 4-to-peak 3 area ratio. The activated salt can then be dried to a powder, in particular spray-dried. In addition to the spray drying z. B. also suitable for drum drying.

Activated aluminum salts typically have a HPLC peak 4-to-peak 3 area ratio of at least 0.4, preferably at least 0.7, more preferably at least 0.9, with at least 70% of the aluminum attributable to these peaks.

Further preferred antiperspirant active ingredients are basic calcium aluminum salts, as used, for example, in US Pat US 2571030 are disclosed. These salts are prepared by reacting calcium carbonate with aluminum chlorhydroxide or aluminum chloride and aluminum powder or by adding calcium chloride dihydrate to aluminum chlorhydroxide.

Further preferred antiperspirant active substances are activated aluminum salts, as used, for example, in US Pat US 6245325 or US 6042816 containing 5-78% by weight (USP) of an activated antiperspirant aluminum salt, an amino acid or hydroxyalkanoic acid in such amount as to have an (amino acid or hydroxyalkanoic acid) to Al weight ratio of 2: 1-1: 20 and preferably 1 To provide 1 to 1:10, and a water-soluble calcium salt in such an amount as to provide a Ca: Al weight ratio of 1: 1-1: 28 and preferably 1: 2-1: 25. Particularly preferred solid activated antiperspirant Salt compositions, for example according to US 6245325 or US 6042816, contain 48-78% by weight (USP), preferably 66-75% by weight of an activated aluminum salt and 1-16% by weight, preferably 4-13% by weight. molecularly bound water (hydration water), further enough water-soluble calcium salt, that the Ca: Al weight ratio is 1: 1-1: 28, preferably 1: 2-1: 25, and so much amino acid that the amino acid is Al-weight ratio 2: 1-1: 20, preferably 1: 1-1: 10.

Further particularly preferred solid antiperspirant activated salt compositions, for example according to US 6245325 or US 6042816 , 48-78 wt .-% (USP), preferably 66-75 wt .-% of an activated aluminum salt and 1-16 wt .-%, preferably 4-13 wt .-% molecularly bound water (water of hydration), further so much water-soluble calcium salt that the Ca: Al weight ratio is 1: 1-1: 28, preferably 1: 2-1: 25, and so much glycine that the glycine to Al weight ratio 2: 1-1: 20, preferably 1: 1-1: 10, is. Further particularly preferred solid antiperspirant activated salt compositions, for example according to US 6245325 or US 6042816, contain 48-78% by weight (USP), preferably 66-75% by weight of an activated aluminum salt and 1-16% by weight, preferably 4 -13% by weight of molecularly bound water, furthermore sufficient water-soluble calcium salt, that the Ca: Al weight ratio is 1: 1-1: 28, preferably 1: 2-1: 25, and enough hydroxyalkanoic acid that the hydroxyalkanoic acid is Weight ratio 2: 1-1: 20, preferably 1: 1-1: 10. Preferred water-soluble calcium salts for the stabilization of antiperspirant salts are selected from calcium chloride, calcium bromide, calcium nitrate, calcium citrate, calcium formate, calcium acetate, calcium gluconate, calcium ascorbate, calcium lactate, calcium glycinate, calcium carbonate, calcium sulfate, calcium hydroxide, and mixtures thereof.

Preferred amino acids for the stabilization of the antiperspirant salts are selected from glycine, alanine, leucine, isoleucine, β-alanine, valine, cysteine, serine, tryptophan, phenylalanine, methionine, β-amino-n-butanoic acid and γ-amino-n-butanoic acid and the salts thereof, each in the d-form, the l-form and the dl-form; Glycine is particularly preferred.

Preferred hydroxyalkanoic acids for the stabilization of the antiperspirant salts are selected from glycolic acid and lactic acid.

Further preferred antiperspirant active substances are activated aluminum salts, as used, for example, in US Pat US 6902723 containing 5-78% by weight (USP) of an activated antiperspirant aluminum salt, an amino acid or hydroxyalkanoic acid in such amount as to have an (amino acid or hydroxyalkanoic acid) to Al weight ratio of 2: 1-1: 20 and preferably 1 To provide 1 to 1:10 and a water-soluble strontium salt in an amount to provide a Sr: Al weight ratio of 1: 1-1: 28 and preferably 1: 2-1: 25.

Particularly preferred solid antiperspirant activated salt compositions, for example according to US 6902723 containing 48-78 wt .-% (USP), preferably 66-75 wt .-% of an activated aluminum salt and 1-16 wt .-%, preferably 4-13 wt .-% molecularly bound water, further as much water-soluble strontium salt, in that the Sr: Al weight ratio is 1: 1-1: 28, preferably 1: 2-1: 25, and so much amino acid that the amino acid to Al weight ratio is 2: 1-1: 20, preferably 1: 1-1 : 10, is.

Further particularly preferred solid antiperspirant activated salt compositions, for example according to US 6902723 containing 48-78 wt .-% (USP), preferably 66-75 wt .-% of an activated aluminum salt and 1-16 wt .-%, preferably 4-13 wt .-% molecularly bound water, further as much water-soluble strontium salt, in that the Sr: Al weight ratio is 1: 1-1: 28, preferably 1: 2-1: 25, and so much glycine that the glycine to Al weight ratio is 2: 1-1: 20, preferably 1: 1-1 : 10, is.

Further particularly preferred solid antiperspirant activated salt compositions, for example according to US 6902723 containing 48-78 wt .-% (USP), preferably 66-75 wt .-% of an activated aluminum salt and 1-16 wt .-%, preferably 4-13 wt .-% molecularly bound water, further as much water-soluble strontium salt, in that the Sr: Al weight ratio is 1: 1-1: 28, preferably 1: 2-1: 25, and so much hydroxyalkanoic acid that the hydroxyalkanoic acid to Al weight ratio 2: 1-1: 20, preferably 1: 1-1 : 10, is.

Further preferred activated aluminum salts are those of the general formula Al ₂ (OH) _6-a Xa in which X is Cl, Br, I or NO ₃ and "a" is a value of 0.3 to 5, preferably of 0.8 to 2 , 5 and more preferably 1 to 2, such that the molar ratio of Al: X is 0.9: 1 to 2.1: 1, as described, for example, in U.S. Pat US 6074632 are disclosed. These salts generally associate some hydration water, typically 1 to 6 moles of water per mole of salt. Particularly preferred is aluminum chlorohydrate (ie, X is Cl in the aforementioned formula) and especially 5/6 basic aluminum chlorohydrate wherein "a" is 1 such that the molar ratio of aluminum to chlorine is 1.9: 1 to 2.1: 1 ,

Preferred aluminum salts have a metal-to-chloride molar ratio of 0.9-1.3, preferably 0.9-1.1, more preferably 0.9-1.0.

Particularly preferred compositions according to the invention are characterized in that the at least one antiperspirant active ingredient is contained in a total amount of> 25-40% by weight, preferably 26-35% by weight, based on the total weight of the anhydrous active substance (USP). in the total blowing agent-free composition.

In a particularly preferred embodiment, the composition comprises an astringent aluminum salt, especially aluminum chlorohydrate, for example, in powder form as Micro Dry ^® Ultrafine or Super Ultrafine from Reheis, Microdry 323 of Summit, as Chlorhydrol ^® as well as in activated form as Reach ^® sold by Reheis five hundred and first Under the name ^Reach® 301 an aluminum sesquichlorohydrate from Reheis is offered, which is likewise particularly preferred. Particular preference is also activated aluminum chlorohydrates that are available under the names Reach ^® 101 and Reach ^® 103 AACH 7171 by Reheis or Summit are.

Since the antiperspirant active ingredients are suspended in a water-immiscible carrier, it is preferred for reasons of product stability that the active ingredient particles have a number average particle size of 0.1-200 .mu.m, preferably 1-150 .mu.m, more preferably 3-100 .mu.m and extraordinarily preferably 5-80 μm. Preferred active substance particles have a volume-average particle size of 0.2-220 μm, preferably 3-160 μm, more preferably 4-125 μm, more preferably 5-120 μm and exceptionally preferably 10-80 μm.

Preferred aluminum salts have a metal-to-chloride molar ratio of 1.9-2.1, and for sesquichlorohydrates of 1.5: 1-1.8: 1, respectively.

Particularly preferred compositions according to the invention are characterized in that the at least one antiperspirant active ingredient is present in an amount of 27-38% by weight, preferably 30-35% by weight, particularly preferably 32-34% by weight on the total weight of the anhydrous active substance (USP) in the total blowing agent-free composition.

In a particularly preferred embodiment, the composition comprises an astringent aluminum salt, in particular aluminum chlorohydrate, particularly preferably aluminum chlorohydrate with an active substance (USP) free of water of crystallization of 72-88% by weight, based on the raw material tel quel. Preferred non-activated aluminum chlorohydrates, for example, in powder form as Micro Dry ^®, Micro Dry ^® Ultrafine or Micro Dry ^® -323 from Summit / Reheis, as Chlorhydrol ^® (powder) as well as in activated form as Reach ^® 101, Reach ^® 103, Reach ^® 501 from Reheis / Summit or AACH-7171 from Summit. Under the name ^Reach® 301 an aluminum sesquichlorohydrate from Reheis is offered, which is also particularly preferred. Particularly preferred compositions according to the invention are characterized in that the at least one antiperspirant aluminum salt is selected from activated aluminum chlorohydrates.

Further particularly preferred compositions according to the invention are characterized in that disteardimonium hectorites and at least one polar activator selected from ethanol,> 0 to 5 wt .-% of water and propylene carbonate, are contained, wherein the wt .-% indication based on the weight of refers to the entire composition. A further subject of the present application is an antiperspirant cosmetic product consisting of a composition according to claim 1, 2, 3, 4, 5, 6, 7 or 8, at least one propellant and an aerosol dispenser.

Propellants (propellant gases) which are preferred according to the invention are selected from propane, propene, n-butane, isobutane, isobutene, n-pentane, pentene, isopentane, isopentene, methane, ethane, dimethyl ether, nitrogen, air, oxygen , Nitrous oxide, dichlorofluoromethane, chlorodifluoromethane, chlorofluoromethane, 1,1,2,2-tetrachloro-1-fluoroethane, 1,1,1,2-tetrachloro-2-fluoroethane, 1,2,2-trichloro-1,1-difluoroethane , 1,1,2-trichloro-1,2-difluoroethane, 1,1,1-trichloro-2,2-difluoroethane, 2,2-dichloro-1,1,1-trifluoroethane, 1,2-dichloro-1 , 1,2-trifluoroethane, 2-chloro-1,1,1,2-tetrafluoroethane, 1-chloro-1,1,2,2-tetrafluoroethane, 1,1,2-trichloro-2-fluoroethane, 1,2 Dichloro-1,2-difluoroethane, 1,2-dichloro-1,1-difluoroethane, 1-chloro-1,2,2-trifluoroethane, 2-chloro-1,1,1-trifluoroethane, 1-chloro-1 , 1,2-trifluoroethane, 1,2-dichloro-1-fluoroethane, 1,1-dichloro-1-fluoroethane, 2-chloro-1,1-difluoroethane, 1-chloro-1,1-difluoroethane, 1-chloro 2-fluoroethane, 1-chloro-1-fluoroethane, 2-chloro-1,1-difluoroethene, 1,1,1,3-tetrafluoroethane, heptafluoro-n-propane, perfluoroethane, M onochlorodifluoromethane, 1,1-difluoroethane, both individually and in combination.

Particular preference is given to propane, n-butane, isobutane and, particularly preferably, mixtures of these blowing agents.

Also hydrophilic propellants, such. As carbon dioxide, can be used advantageously in the context of the present invention, when the proportion of hydrophilic gases is selected low and lipophilic propellant gas (eg., Propane / butane) is present in excess. Particular preference is given to propane, n-butane, isobutane and in particular mixtures of these propellants.

The amount of the blowing agent is preferably 5-95 wt .-%, particularly preferably 30-90 wt .-% and most preferably 60-86 wt .-%, and still more preferably 75-78 wt .-%, each based on the Total weight of the preparation consisting of the composition according to the invention and the propellant.

Suitable gas cylinders are vessels made of metal (aluminum, tinplate, tin), protected or non-splitterndem plastic or glass, which is externally coated with plastic in question, in their selection pressure and fracture resistance, corrosion resistance, easy filling and aesthetic Aspects, handiness, printability etc. play a role. Special internal protective lacquers ensure the corrosion resistance with respect to the suspension according to the invention. An inner protective lacquer preferred according to the invention is an epoxy-phenolic lacquer, as it is known, inter alia. available under the name Hoba 7407 P. Particularly preferably, the valves used on an internally painted valve disc, wherein the coating and valve material are compatible with each other. If aluminum valves are used, their valve plates can be internally z. B. be coated with Micoflex paint. If tinplate valves are used according to the invention, their valve disks can be internally z. B. be coated with PET (polyethylene terephthalate).

Preferred compositions according to the invention are characterized in that at least one encapsulated active ingredient is contained. The active compounds, which may advantageously be encapsulated, are in particular fragrances and / or cooling agents, but also other skin care active substances, such as vitamins, antioxidants, etc.

Preferred capsule material are water-soluble polymers such as starch, physically modified and / or chemically modified starches, cellulose derivatives, such as. As carboxymethylcellulose, methylcellulose, hydroxyethylcellulose or hydroxypropylmethylcellulose, carrageenans, alginates, maltodextrins, dextrins, vegetable gums, pectins, xanthans, polyvinyl acetate and polyvinyl alcohol, polyvinylpyrrolidine, polyamides, polyesters and homopolymers and copolymers of monomers selected from acrylic acid, methacrylic acid, maleic acid, fumaric acid , Itaconic acid and the esters and the salts of these acids, as well as any mixtures of these polymers.

Preferred capsule materials are chemically modified starches, especially aluminum starch octenyl succinate, e.g. The commercial product Dry Flo Plus from National Starch, or sodium starch octenylsuccinate, e.g. The commercial product Capsul from National Starch, further carboxymethylcellulose, carboxymethylcellulose, methylcellulose, hydroxyethylcellulose and hydroxypropylmethylcellulose, ethylcellulose, e.g. For example, the commercial product Tylose H 10 from Clariant, continue Carragheene, alginates and maltodextrins, and any mixtures of these polymers. The compositions and products of the present invention show the optimum ratio of drug release of the antiperspirant aluminum salt, low greasy textile soiling even after multiple wash cycles, high compatibility with other additives such as perfume capsules, deodorant capsules and aqueous silver salt solutions. The improvements are also noticeable to the untrained consumer.

Particularly preferred compositions according to the invention also contain at least one fragrance. The definition of a fragrance in the sense of the present application is in accordance with the expert definition as it can be found in the RÖMPP Chemie Lexikon, as of December 2007. Thereafter, a fragrance is a chemical compound with odor and / or taste that excites the hair cell receptors of the olfactory system (adequate stimulus). The necessary physical and chemical properties are a low molecular weight of at most 300 g / mol, a high vapor pressure, minimal water and high lipid solubility and weak polarity and the presence of at least one osmophoric group in the molecule. In order to delineate volatile, low molecular weight substances which are usually and also not regarded as perfuming agents, but primarily as solvents, such as, for example, ethanol, propanol, isopropanol and acetone, odorants according to the invention, fragrances according to the invention have a molecular weight of 74 to 300 g / mol, contain at least one osmophoric group in the molecule and have an odor and / or taste, that is, they excite the receptors of the hair cells of the olfactory system.

As perfumes, perfumes, perfume oils or perfume oil ingredients can be used. Perfume oils or fragrances can according to the invention individual fragrance compounds, eg. As the synthetic products of the ester type, ethers, aldehydes, ketones, alcohols and hydrocarbons. Fragrance compounds of the ester type are, for example, benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinylacetate (DMBCA), phenylethylacetate, benzylacetate, ethylmethylphenylglycinate, allylcyclohexylpropionate, styrallylpropionate, benzylsalicylate, cyclohexylsalicylate, floramate, melusate and jasmecyclate. The ethers include, for example, benzyl ethyl ether and ambroxane, to the aldehydes, for example, the linear alkanals having 8-18 C atoms, citral, citronellal, citronellyloxy-acetaldehyde, cyclamen aldehyde, lilial and bourgeonal, to the ketones such as the ionone, alpha-isomethylionone and Methylcedrylketon , among the alcohols anethole, citronellol, eugenol, geraniol, linalool, phenylethyl alcohol and the terpineols alpha-terpineol, beta-terpineol, gamma-terpineol and delta-terpineol, the hydrocarbons mainly include the terpenes such as limonene and pinene. Preferably, however, mixtures of different fragrances are used, which together produce an attractive fragrance. The fragrances can also be contained in encapsulated form. Particularly preferred compositions according to the invention contain at least one perfume in a total amount of 0.00001 to 10 wt .-%, preferably 0.5 to 7 wt .-%, most preferably 1-6 wt .-%, each based on the total weight of the composition ,

Further inventively preferred compositions contain at least one deodorant active ingredient in a total amount of 0.001-10 wt .-%, preferably 0.2-7 wt .-%, particularly preferably 1-5 wt .-%, most preferably 1.5-3 % By weight, the weight percentages being based on the total weight of the composition.

According to the invention, ethanol does not count as a deodorant active ingredient, but, if present, only as a constituent of the carrier.

In a preferred embodiment, the compositions according to the invention contain as deodorising agent at least one silver salt, which is preferably selected from silver sulphate, silver nitrate, silver citrate, silver dihydrogen citrate, silver lactate, silver acetate, silver malate, silver succinate, silver tartrate, silver mandelate, silver salicylate, silver gluconate, silver adipate and silver bergaractarate Mixtures of these salts. Highly preferred are silver sulfate, silver citrate, silver dihydrogen citrate and silver lactate, as well as mixtures of these salts.

Further preferred compositions according to the invention comprise at least one silver salt, which is preferably selected from silver sulfate, silver nitrate, silver citrate, silver dihydrogen citrate, silver lactate, silver acetate, silver malate, silver succinate, silver tartrate, silver mandelate, silver salicylate, silver gluconate, silver adipate and silver bergaractarate, as well as mixtures of these salts Amounts that silver in a total amount of 1-100 ppm, preferably 2-50 ppm, more preferably 5-20 ppm, most preferably 7-10 ppm, each based on the weight of the propellant-free composition is included. Based on the molecular weights of silver (107.87 g / mol) and the respective silver salt silver lactate z. B. has a molecular weight of 196.94 g / mol - can be calculated according to the required amount of silver salt (s).

wobei
die Reste R¹ bis R⁶ unabhängig voneinander ein Wasserstoffatom, eine Alkylgruppe mit 1 bis 10 Kohlenstoffatomen, die linear oder verzweigt und substituiert sein können mit OH-Gruppen oder Alkoxy-Gruppen mit 1 bis 5 Kohlenstoffatomen, oder eine Alkenylgruppe mit 2 bis 10 Kohlenstoffatomen, die linear oder verzweigt und substituiert sein können mit OH-Gruppen oder Alkoxy-Gruppen mit 1 bis 5 Kohlenstoffatomen,
die Reste R⁷ bis R¹¹ unabhängig voneinander ein Wasserstoffatom, ein Halogenatom, insbesondere ein Chloratom, oder eine Alkylgruppe mit 1 bis 10 Kohlenstoffatomen, die linear oder verzweigt und substituiert sein können mit OH-Gruppen oder Alkoxy-Gruppen mit 1 bis 5 Kohlenstoffatomen, insbesondere mit einer Methoyxgruppe,
m = 0 oder 1 ist, n, o, p = unabhängig voneinander ganze Zahlen von 0 bis 10 sind, wobei mindestens einer der Werte n, o, p ≠ 0 ist. In a further preferred embodiment, the compositions according to the invention contain as deodorising agent at least one aromatic alcohol of the structure (AA-1),

in which
R ¹ to R ⁶ independently represent a hydrogen atom, an alkyl group having 1 to 10 carbon atoms which may be linear or branched and substituted with OH groups or alkoxy groups having 1 to 5 carbon atoms, or an alkenyl group having 2 to 10 carbon atoms which may be linear or branched and substituted with OH groups or alkoxy groups having 1 to 5 carbon atoms,
the radicals R ⁷ to R ¹¹ independently of one another are a hydrogen atom, a halogen atom, in particular a chlorine atom, or an alkyl group having 1 to 10 carbon atoms, which may be linear or branched and substituted by OH groups or alkoxy groups having 1 to 5 carbon atoms, in particular with a methoxy group,
m = 0 or 1, n, o, p = are independently integers from 0 to 10, with at least one of the values n, o, p ≠ 0.

Particularly preferred products of the invention contain at least one alcohol AA-1, as described above, which is selected from anisalcohol, 2-methyl-5-phenyl-pentan-1-ol, 1,1-dimethyl-3-phenyl-propane-1 ol, benzyl alcohol, 2-phenylethan-1-ol, 3-phenylpropan-1-ol, 4-phenylbutan-1-ol, 5-phenylpentan-1-ol, 2-benzylheptan-1-ol, 2,2-dimethyl 3-phenylpropan-1-ol, 2,2-dimethyl-3- (3'-methylphenyl) -propan-1-ol, 2-ethyl-3-phenylpropan-1-ol, 2-ethyl-3- (3 ' -methylphenyl) -propan-1-ol, 3- (3'-chlorophenyl) -2-ethyl-propan-1-ol, 3- (2'-chlorophenyl) -2-ethyl-propan-1-ol, 3- (4 ') Chlorophenyl) -2-ethyl-propan-1-ol, 3- (3 ', 4'-dichlorophenyl) -2-ethyl-propan-1-ol, 2-ethyl-3- (2'-methyl-phenyl) -propan-1-ol, 2-Ethyl-3- (4'-methylphenyl) -propan-1-ol, 3- (3 ', 4'-dimethylphenyl) -2-ethyl-propan-1-ol, 2-ethyl-3- (4'-methoxyphenyl ) -propan-1-ol, 3- (3 ', 4'-dimethoxyphenyl) -2-ethyl-propan-1-ol, 2-allyl-3-phenylpropan-1-ol and 2-n-pentyl-3-phenylpropane 1-ol and mixtures thereof. Extraordinary preference is given to 2-benzylheptan-1-ol and mixtures of 2-benzylheptan-1-ol and phenoxyethanol. Further particularly preferred compositions according to the invention comprise at least one alcohol AA-1, as described above, in a total amount of 0.05-10% by weight, preferably 0.1-5% by weight, particularly preferably 0.2-2% by weight .-%, most preferably 0.3-1.5 wt .-%, each based on the weight of the composition. Extremely preferred compositions according to the invention contain 2-benzylheptan-1-ol in a total amount of 0.05-1.5 wt.%, Preferably 0.1-1 wt.%, Particularly preferably 0.2-0.5 wt. -%, in each case based on the weight of the composition. Also, the alcohols AA-1 may be contained in encapsulated form.

In a further preferred embodiment, the compositions according to the invention contain as deodorant active ingredient at least one 1,2-alkanediol having 5 to 12 C atoms, which is represented by the formula HO-CH ₂ -CH (OH) - (CH ₂ ) _n -CH ₃ in which n represents the numbers 2, 3, 4, 5, 6, 7, 8 or 9, as well as mixtures of these 1,2-alkanediols. 1,2-Alkanediols having 5 to 12 C atoms which are particularly preferred according to the invention are selected from 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, 1,2-decanediol and mixtures thereof. A very particularly preferred combination according to the invention are mixtures of 1,2-hexanediol and 1,2-octanediol, preferably in a weight ratio of from 10: 1 to 1:10, more preferably from 5: 1 to 1: 5, particularly preferably in a weight ratio of 1: 1 , Preferred compositions according to the invention contain at least one 1,2-alkanediol having 5 to 12 C atoms, which is described by the formula HO-CH ₂ -CH (OH) - (CH ₂ ) _n -CH ₃ , in which n is the numbers 2, 3, 4, 5, 6, 7, 8 or 9, in a total amount of 0.2-15 wt .-%, preferably 0.3-10 wt .-%, particularly preferably 0.4-5 wt % and most preferably 0.5-2% by weight, each based on the weight of the composition. Extremely preferred compositions of the invention contain from 0.2 to 0.5% by weight of 1,2-hexanediol and from 0.2 to 0.5% by weight of 1,2-octanediol, each based on the weight of the composition.

Further preferred compositions according to the invention are characterized by a content of the deodorant active ingredient 3- (2-ethylhexyloxy) -1,2-propanediol, preferably in a total amount of 0.05-5 wt .-%, preferably 0.1-2 wt %, more preferably 0.2-1.5 wt%, most preferably 0.5-1.0 wt%, each based on the weight of the composition.

Further preferred compositions according to the invention are characterized by a content of tropolone (2-hydroxy-2,4,6-cycloheptatrienone), preferably in an amount of 0.001-0.1% by weight, based on the weight of the composition.

Further preferred compositions according to the invention are characterized by a content of the deodorant active ingredient triethyl citrate. Triethyl citrate is a known deodorant active, which acts as an enzyme inhibitor for esterases and lipases and thus contributes to the broadband effect of inventive compositions. Preferred compositions according to the invention contain 0.5-15% by weight, preferably 3-8% by weight, more preferably 4-6% by weight, based in each case on the weight of the composition.

Compounds which inhibit at least one of the enzymes arylsulfatase, beta-glucuronidase, 5-lipoxygenase or cystathionine-beta-lyase likewise represent preferred deodorant active ingredients according to the invention.

Further preferred compositions according to the invention are characterized by a content of at least one compound which is an inhibitor of the enzyme arylsulfatase. Deodorant agents which are preferred according to the invention and act as arylsulfatase inhibitors are those as described in US Pat US 5643559 . US 5676937 . WO 2001/099376 A2 . EP 1430879 A1 and DE 10216368 A1 are disclosed. Further particularly preferred compositions according to the invention are characterized by a content of at least one compound which is an inhibitor of the enzyme arylsulfatase, in a total amount of 0.001-10% by weight, preferably 0.01-5% by weight, particularly preferably 0, 1-2.5 wt .-%, each based on the weight of the composition.

Further preferred compositions according to the invention are characterized by a content of at least one compound which is an inhibitor of the enzyme beta-glucuronidase. Deodorant agents which are preferred according to the invention and act as a beta-glucuronidase inhibitor are those as described in US Pat WO 2003/039505 A2 are disclosed. Further particularly preferred compositions according to the invention are characterized by a content of at least one compound which is an inhibitor of the enzyme beta-glucuronidase, in a total amount of 0.001-10% by weight, preferably 0.01-5% by weight, more preferably 0.1-2.5 wt .-%, each based on the weight of the composition.

Further preferred compositions according to the invention are characterized by a content of at least one compound which is an inhibitor of the enzyme lipase. Deodorant agents which are preferred according to the invention and act as lipase inhibitors are selected from those which are active in EP 1428520 A2 further selected from the aminomethylenemalonic acid derivatives according to DE 3018132 A1 , the ethylene oxide-propylene oxide copolymers according to GB 2335596 A1 and the salts of phytic acid according to EP 650 720 A1 , Further particularly preferred compositions according to the invention are characterized by a content of at least one compound which is an inhibitor of the enzyme lipase, in a total amount of 0.001-10% by weight, preferably 0.01-5% by weight, particularly preferably 0, 1-2.5 wt .-%, each based on the weight of the composition.

Further particularly preferred compositions according to the invention are characterized by a content of at least one compound which is an inhibitor of 5-lipoxygenase. Deodorant agents which are preferred according to the invention and act as 5-lipoxygenase inhibitors are disclosed in US Pat EP 1428519 A2 disclosed. Further particularly preferred compositions according to the invention are characterized by a content of at least one compound which is an inhibitor of the enzyme 5-lipoxygenase, in a total amount of 0.001-10% by weight, preferably 0.01-5% by weight, more preferably 0.1-2.5 wt .-%, each based on the weight of the composition.

Further particularly preferred compositions according to the invention are characterized by a content of at least one compound which is an inhibitor of the enzyme cystathionine beta-lyase. Deodorant agents which are preferred according to the invention and act as an inhibitor of cystathionine beta-lyase are selected from those which are known in the art EP 495918 B1 . WO 2006/079934 . DE 102010000746 A1 . WO 2010/031657 A1 and WO 2010/046291 A1 are disclosed. Further particularly preferred compositions according to the invention are characterized by a content of at least one compound which is an inhibitor of the enzyme cystathionine-beta-lyase, in a total amount of 0.001-10% by weight, preferably 0.01-5% by weight, particularly preferably 0.1-2.5 wt .-%, each based on the weight of the composition.

in der R¹ eine Alkyl-, Alkenyl- oder Hydroxyalkylgruppe mit 8 bis 22 C-Atomen oder eine Acylaminoalkylgruppe der Formel R⁵CONH(C_mH_2m)- ist, worin R⁵CO eine lineare Acylgruppe mit 8 bis 22 C-Atomen und m = 2 oder 3 ist, R² und R³ Alkylgruppen mit 1 bis 4 C-Atomen oder Hydroxyalkylgruppen mit 2 bis 4 C-Atomen oder Carboxyalkylgruppen der Formel -(CH₂)_z-COOM sind, worin z einen Wert von 1 bis 3 hat und M Wasserstoff oder ein Alkalimetallkation ist, x einen Wert von 1 bis 3 und y einen Wert von (3 – x) hat, M Wasserstoff oder ein Alkalimetallkation ist und A^– ein Anion ist. Further particularly preferred compositions according to the invention are characterized by a content of at least one cationic phospholipid of the formula KPL,

wherein R ^{1 is} an alkyl, alkenyl or hydroxyalkyl group having 8 to 22 carbon atoms or an acylaminoalkyl group of the formula R ⁵ CONH (C _m H _2m ) - wherein R ⁵ CO is a linear acyl group having 8 to 22 C atoms and m is 2 or 3, R ² and R ^{3 are} alkyl groups of 1 to 4 carbon atoms or hydroxyalkyl groups of 2 to 4 carbon atoms or carboxyalkyl groups of the formula - (CH ₂ ) _z -COOM, where z is 1 to 3 and M is hydrogen or an alkali metal cation, x is 1 to 3 and y is (3 - x), M is hydrogen or an alkali metal cation and A ^{- is} an anion.

Preferred alkyl groups having 8 to 22 C atoms are selected from an n-octyl, n-nonyl, n-decyl, n-undecyl, lauryl, n-tridecanyl, myristyl, n-pentadecanyl, cetyl , Palmityl, stearyl, elaidyl, arachidyl, behenyl and a cocyl group. A representative cocyl group, based on its total weight, consists of 4-9% by weight of n-octyl, 4-9% by weight of n-decyl, 45-55% by weight of lauryl, 15-21 Wt% myristyl, 8-13 wt% palmityl and 7-14 wt% stearyl groups. Preferred alkenyl groups having 8 to 22 C atoms are selected from a linoleyl group ((9Z, 12Z) -Octadeca-9,12-dien-1-yl) and a linolenyl group ((9Z, 12Z, 15Z) -Octadeca-9,12,15-trien-1-yl). A preferred hydroxyalkyl group having 8 to 22 C atoms is selected from a 12-hydroxystearyl group.

Particularly preferred cationic phospholipids of the formula KPL are those in which R ^{1 is} an acylaminoalkyl group of the formula R ⁵ CONH (C _m H _2m ) -, in which R ⁵ CO is a linear acyl group having 8 to 22 C atoms and m = 3 ,

in der R¹ eine Acylaminoalkylgruppe der Formel R⁵CONH(C_mH_2m)- ist, worin R⁵CO ausgewählt ist aus einer Cocoylgruppe, einer Lauroylgruppe, einer Myristoylgruppe und einer Linoleoyl-Gruppe und m = 3 ist, R² und R³ Methylgruppen sind, x = 2, y = 1, M ein Natriumion und A^– ein Chloridion sind. Bevorzugt ist mindestens ein kationisches Phospholipid der Formel KPL mit den vorstehend genannten Merkmalen in einer Gesamtmenge von 0,05–2 Gew.-%, bevorzugt 0,1–1 Gew.-%, besonders bevorzugt 0,15–0,4 Gew.-%, enthalten, jeweils bezogen auf das Gewicht der Zusammensetzung. Preferred compositions according to the invention contain as deodorant active ingredient a cationic phospholipid of the formula KPL,

wherein R ^{1 is} an acylaminoalkyl group of the formula R ⁵ CONH (C _m H _2m ) - wherein R ⁵ CO is selected from a cocoyl group, a lauroyl group, a myristoyl group and a linoleoyl group, and m = 3, R ² and R ^{3 are} methyl groups, x = 2, y = 1, M is a sodium ion and A ^{- is} a chloride ion. At least one cationic phospholipid of the formula KPL with the abovementioned features is preferably present in a total amount of 0.05-2% by weight, preferably 0.1-1% by weight, particularly preferably 0.15-0.4% by weight. %, in each case based on the weight of the composition.

in der R¹ eine Cocoylaminopropylgruppe (auch als Cocamidopropylgruppe bezeichnet) ist, R² und R³ Methylgruppen sind, x = 2, y = 1, M ein Natriumion und A^– ein Chloridion sind und die unter der INCI-Bezeichnung Cocamidopropyl PG-Dimonium Chloride Phosphate erhältlich ist, in einer Gesamtmenge von 0,05–2 Gew.-%, bevorzugt 0,1–1 Gew.-%, besonders bevorzugt 0,15–0,4 Gew.-%, jeweils bezogen auf das Gewicht der Zusammensetzung. Particularly preferred compositions according to the invention comprise a cationic phospholipid of the formula KPL,

in which R ^{1 is} a cocoylaminopropyl group (also referred to as cocamidopropyl group), R ² and R ^{3 are} methyl groups, x = 2, y = 1, M is a sodium ion and A ^{- is} a chloride ion and those under the INCI name cocamidopropyl PG-dimonium Chloride phosphates is available, in a total amount of 0.05-2 wt .-%, preferably 0.1-1 wt .-%, particularly preferably 0.15-0.4 wt .-%, each based on the weight of Composition.

in der R¹ eine Myristoylaminopropylgruppe ist, R² und R³ Methylgruppen sind, x = 2, y = 1, M ein Natriumion und A^– ein Chloridion sind und die unter der INCI-Bezeichnung Myristamidopropyl PG-Dimonium Chloride Phosphate erhältlich ist, in einer Gesamtmenge von 0,05–2 Gew.-%, bevorzugt 0,1–1 Gew.-%, besonders bevorzugt 0,15–0,4 Gew.-%, jeweils bezogen auf das Gewicht der Zusammensetzung. Further particularly preferred compositions according to the invention comprise a cationic phospholipid of the formula KPL,

wherein R ^{1 is} a myristoylaminopropyl group, R ² and R ^{3 are} methyl groups, x = 2, y = 1, M is a sodium ion and A ^{- is} a chloride ion and is available under the INCI name myristamidopropyl PG-Dimonium Chloride Phosphate, in a total amount of 0.05-2 wt .-%, preferably 0.1-1 wt .-%, particularly preferably 0.15-0.4 wt .-%, each based on the weight of the composition.

in der R¹ eine Lauroylaminopropylgruppe ist, R² und R³ Methylgruppen sind, x = 2, y = 1, M ein Natriumion und A^– ein Chloridion sind, in einer Gesamtmenge von 0,05–2 Gew.-%, bevorzugt 0,1–1 Gew.-%, besonders bevorzugt 0,15–0,4 Gew.-%, jeweils bezogen auf das Gewicht der Zusammensetzung. Further particularly preferred compositions according to the invention comprise a cationic phospholipid of the formula KPL,

wherein R ^{1 is} a lauroylaminopropyl group, R ² and R ^{3 are} methyl groups, x = 2, y = 1, M is a sodium ion and A ^{- is} a chloride ion, in a total amount of 0.05-2 wt%, preferably 0 , 1-1 wt .-%, particularly preferably 0.15-0.4 wt .-%, each based on the weight of the composition.

Further inventively preferred deodorant active ingredients are odor absorbers, deodorizing ion exchangers, germ-inhibiting active ingredients, prebiotic components and enzyme inhibitors or, particularly preferably, combinations of the active substances mentioned.

Silicates serve as odor absorbers, which at the same time advantageously support the rheological properties of the composition according to the invention. Among the silicates which are particularly preferred according to the invention are, in particular, phyllosilicates and, among these, in particular montmorillonite, kaolinite, IIit, beidellite, nontronite, saponite, hectorite, bentonite, smectite and talcum.

Other preferred odor absorbers are, for example, zeolites, Zinkricinoleat, cyclodextrins, certain metal oxides, such as. As alumina, and chlorophyll. They are preferably contained in a total amount of 0.1-10 wt .-%, particularly preferably 0.5-7 wt .-% and most preferably 1-5 wt .-%, each based on the total composition.

According to the invention, germ-inhibiting or antimicrobial active ingredients are understood as meaning those active substances which reduce the number of skin germs participating in the formation of the odor or inhibit their growth. These organisms include, among others, various species from the group of staphylococci, the group of Corynebacteria, anaerococci and micrococci.

Preferred antimicrobial or antimicrobial agents according to the invention are in particular organohalogen compounds and halides, quaternary ammonium compounds, a number of plant extracts and zinc compounds. These include u. a. Triclosan, chlorhexidine and chlorhexidine gluconate, 3,4,4'-trichlorocarbanilide, bromochlorophene, dichlorophen, chlorothymol, chloroxylenol, hexachlorophene, dichloro-m-xylenol, dequalinium chloride, domiphenbromide, ammonium phenolsulfonate, benzalkonium halides, benzalkonium cetyl phosphate, benzalkonium saccharinates, benzethonium chloride, cetylpyridinium chloride, laurylpyridinium chloride, laurylisoquinolinium bromide , Methylbenzethonium chloride. Furthermore, phenol, phenoxyethanol, disodium dihydroxyethylsulfosuccinylundecylenate, sodium bicarbonate, zinc lactate, sodium phenolsulfonate and zinc phenolsulfonate, ketoglutaric acid, terpene alcohols such as. As farnesol, chlorophyllin copper complexes, and carboxylic acid esters of mono-, di- and triglycerol (eg., Glycerinmonolaurat, diglycerol monocaprinate) preferred deodorant agents.

Preferred compositions according to the invention comprise at least one deodorant active ingredient selected from silver salts, aromatic alcohols of structure AA-1 with the abovementioned substituents, 1,2-alkanediols having 5 to 12 carbon atoms, alpha- (2-ethylhexyl) glycerol ethers (3 - (2-Ethylhexlyoxy) -1,2-propanediol), tropolone, triethyl citrate, cationic phospholipids of the formula KPL with the abovementioned substituents, and mixtures thereof.

The composition of some preferred oil-in-water emulsions according to the invention can be seen from the following tables. The quantities are, according to the wording of claim 1, always based on the total weight of the respective component in the composition. 1 2 3 4 antiperspirant aluminum salt > 25 to 40 26-35 26-35 26-35 Total amount of mixture of cosmetic oils 30-75 50-70 54-64 54-64 at least 1 volatile isoparaffin (8 to 250 Pa vapor pressure) > 18- <67.5 > 30- <63 > 32.4- <57.6 40-55 non-volatile ester oil, vapor pressure <2.66 Pa > 3- <30 > 5- <28 > 5.4- <25.6 10-20 Cyclomethicone 0 0 0 0 5 6 7 8th aluminum chlorohydrate > 25 to 40 26-35 26-35 26-35 Total amount of mixture of cosmetic oils 30-75 50-70 54-64 54-64 C10-13 isoparaffin > 18- <67.5 > 30- <63 > 32.4- <57.6 40-55 2-ethylhexyl palmitate > 3- <30 > 5- <28 > 5.4- <25.6 10-20 Cyclomethicone 0 0 0 0 9 10 11 12 aluminum chlorohydrate > 25 to 40 26-35 26-35 26-35 Total amount of mixture of cosmetic oils 30-75 50-70 54-64 54-64 C10-13 isoparaffin > 18- <67.5 > 30- <63 > 32.4- <57.6 40-55 isopropyl > 3- <30 > 5- <28 > 5.4- <25.6 10-20 Cyclomethicone 0 0 0 0 13 14 15 16 activated aluminum chlorohydrate > 25 to 40 26-35 26-35 26-35 Total amount of mixture of cosmetic oils 30-75 50-70 54-64 54-64 C10-13 isoparaffin > 18- <67.5 > 30- <63 > 32.4- <57.6 40-55 2-ethylhexyl palmitate > 3- <30 > 5- <28 > 5.4- <25.6 10-20 Cyclomethicone 0 0 0 0 17 18 19 20 activated aluminum chlorohydrate > 25 to 40 26-35 26-35 26-35 Total amount of mixture of cosmetic oils 30-75 50-70 54-64 54-64 C10-13 isoparaffin > 18- <67.5 > 30- <63 > 32.4- <57.6 40-55 isopropyl > 3- <30 > 5- <28 > 5.4- <25.6 10-20 Cyclomethicone 0 0 0 0

The following examples of antiperspirant sprays according to the invention are intended to illustrate the subject matter of the invention without limiting it thereto. Ingredients (INCI EU) Wt .-% - Percentage Butane 73 Propane 10 Isobutane 2 C10-13 isoparaffin 5.27 Aluminum Chlorohydrate (USP) 4.0 Crystal water (bound, not free) 1.0 Ethylhexyl palmitate 3.0 Perfume 1.0 Disteardimonium hectorite 0.55 Propylene carbonates 0.18 Ingredients (INCI EU) Wt .-% - Percentage Butane 71.0 Isobutane 2.1 Propane 10.4 Isopentane 1.0 pentanes 1.3 ethane 0.2 C10-13 isoparaffin 7.4 Isopropyl myristate 1 Perfume 1.09 Disteardimonium hectorite 0.38 no inci (crystall bound water) 1.0 Aluminum Chlorohydrate 4.0 Propylene carbonates 0.13

QUOTES INCLUDE IN THE DESCRIPTION

This list of the documents listed by the applicant has been generated automatically and is included solely for the better information of the reader. The list is not part of the German patent or utility model application. The DPMA assumes no liability for any errors or omissions.

Cited patent literature

• US 3887692 [0017]
• US Pat. No. 3904741 [0017]
• US 4359456 [0017]
• GB 2048229 [0017]
• GB 1347950 [0017]
• US 4775528 [0018]
• US 6010688 [0018]
• US 2571030 [0020]
• US 6245325 [0021, 0022]
• US 6042816 [0021, 0022]
• US 6902723 [0025, 0026, 0027, 0028]
• US 6074632 [0029]
• US 5643559 [0059]
• US 5676937 [0059]
• WO 2001/099376 A2 [0059]
• EP 1430879 A1 [0059]
• DE 10216368 A1 [0059]
• WO 2003/039505 A2 [0060]
• EP 1428520 A2 [0061]
• DE 3018132 A1 [0061]
• GB 2335596 A1 [0061]
• EP 650720 A1 [0061]
• EP 1428519 A2 [0062]
• EP 495918 B1 [0063]
• WO 2006/079934 [0063]
• DE 102010000746 A1 [0063]
• WO 2010/031657 A1 [0063]
• WO 2010/046291 A1 [0063]

Claims (10)

Anti-perspirant composition for personal care in the form of a propellant-free sprayable or sprayable with a propellant suspension, containing a) at least one antiperspirant aluminum salt in a total amount of> 25 to 40 wt .-%, b) 0-5 wt .-% free water, based on the weight of the blowing agent-free composition, c) 30-75 wt .-%, preferably 50-70 wt .-%, particularly preferably 54-64 wt .-%, of a mixture of liquid under normal conditions cosmetic oils, which are not essential oil and no perfume, wherein more than 60 wt .-% to less than 90 wt .-% of this oil mixture, based on the weight of the oil mixture, from at least one volatile isoparaffin or a volatile Isoparaffinmischung, each with a vapor pressure at 20 ° C from 8 to 250 Pa, and more from 10% to less than 40% by weight of this oil blend, based on the weight of the oil blend, of at least one non-volatile ester oil or non-volatile ester oil blend, each having a vapor pressure of less than 2 at 20 ° C , 66 Pa (0.02 mm Hg), d) 0 to less than 1 wt .-% cyclomethicones, based on the weight of the blowing agent-free composition. the weight percentages being based on the weight of the whole composition, with the exception of characteristic c). A composition according to claim 1, characterized in that the volatile isoparaffin is selected from isononane, isodecane, isoundecane, isododecane, isotridecane, isotetradecane, isopentadecane, and isohexadecane, and mixtures thereof, preferably selected from isodecane, isoundecane, isododecane, isotridecane, and mixtures thereof , A composition according to claim 1 or 2, characterized in that the at least one volatile isoparaffin having a vapor pressure at 20 ° C of 8 to 250 Pa in a total amount of> 18 to <67.5 wt .-%, preferably> 30- < 63 wt .-%, more preferably> 32.4- <57.6 wt .-%, most preferably 40-55 wt .-%, each based on the total propellant-free composition is included. A composition according to claim 1, 2 or 3, characterized in that the non-volatile ester oil is selected from esters of linear or branched saturated or unsaturated fatty alcohols having 2-30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2-30 carbon atoms be hydroxylated, and the benzoic acid esters of linear or branched C _8-22 alkanols, provided that these esters are liquid under normal conditions. Composition according to Claim 1, 2, 3 or 4, characterized in that the non-volatile ester oil is 2-ethylhexyl palmitate. Composition according to Claim 1, 2, 3 or 4, characterized in that the non-volatile ester oil is isopropyl myristate. A composition according to claim 1, 2, 3, 4, 5 or 6, characterized in that the at least one antiperspirant aluminum salt is selected from activated aluminum chlorohydrates. Composition according to Claim 1, 2, 3, 4, 5, 6 or 7, characterized in that disteardimonium hectorites and at least one polar activator selected from ethanol,> 0 to 5% by weight of water and propylene carbonate, are present the weight percentage refers to the weight of the total composition. An antiperspirant cosmetic product consisting of a composition according to claim 1, 2, 3, 4, 5, 6, 7 or 8, at least one propellant and an aerosol dispenser. Product according to Claim 9, characterized in that the amount of blowing agent is 5-95% by weight, preferably 30-90% by weight, more preferably 60-86% by weight, and most preferably 75-78% by weight. , is, in each case based on the total weight of the preparation, consisting of the composition according to the invention and the blowing agent.