DE102009026899A1 - Cosmetic cleanser with deodorant effect - Google Patents

Abstract

The present invention relates to cosmetic cleaning compositions having a deodorizing effect, comprising a) a surfactant mixture, b) benzoic acid or a salt of benzoic acid, c) at least one compound of the formula (I), $ F1 in which R is a methyl, ethyl, propyl Isopropyl, butyl, hydroxymethyl, hydroxyethyl, ethyl glycol, hydroxypropyl or 1,2-dihydroxypropyl group, R is hydrogen or a methyl, ethylpropyl, isopropyl, butyl, pentyl, hexyl, heptyl , Octyl, benzyl, -CH-O-CH (CH) -CHCHCHCH group, and R represents hydrogen or a methyl, ethyl, propyl, isopropyl, butyl, benzyl group, provided that R is not simultaneously stand for hydrogen.

Description

The The present invention relates to a cosmetic cleaning composition based on a surfactant, due to a specific combination of active ingredients in addition to a cleaning also has a deodorizing effect. Furthermore, the present invention relates to the use of Active ingredient combination in a cosmetic cleanser as well a method for cleaning, care and deodorization of human Keratin fibers.

Cleaning supplies, For example, cosmetic cleansers for the skin and hair like liquid soaps, shampoos, shower baths, Bubble baths, shower gels and wash gels do not have to only have a good cleaning power, but should still good for the skin and mucous membranes be tolerated and also with frequent use do not cause excessive defatting or skin dryness. For this reason is tried for many years, as possible to incorporate many hair and skin conditioners into the cleansers - on the one hand, to meet the requirements for simultaneous cleaning and Care and on the other hand, so that the consumer by applying only one product that meets these two requirements met, both the advantage of time savings, as well can enjoy the benefit of cost savings (since optimally a care step with a skin or hair aftertreatment superfluous shall be).

Nevertheless consumers need to use multiple products to this day, which is mainly due to the fact that they are on the market 2in1 products still do not meet all requirements. Furthermore, to date, the subsequent use of the cleaning a deodorant usual. The daily application However, several cosmetic products often results to a strain on the skin. In particular, irritable skin with low irritation potential can be due to daily use several products still claimed, which is often allergic reactions, redness, itching or extreme Dry and flaky skin can result. Every cosmetic Means for itself usually contains Preservatives, perfumes and other ingredients containing the Irritate skin, and regular use of several Products brings the skin in contact with these substances several times. In addition, it belongs to many people at the present time traveling both professionally and privately to everyday life, and each of these consumers is careful not to mess with to load too much luggage. So it is especially for these consumers very much desirous of having a product that they use for cleaning, care and as a deodorant can. Such a 3in1 product would be both Promote the skin, as well as with a time and Cost savings go along (as no longer purchased three products and must be applied) and additionally the Significantly reduce the weight of luggage when traveling. Also, such a product could be easily in carry-on stowed, which in turn air travel in turn faster and makes it easier.

aim The present invention was therefore a means to develop Thoroughly cleanses and cares for the human keratin fibers and deodorized. Under care is understood that the human Skin and / or scalp does not dry when cleaning, but that at the same time they supplied active ingredients during cleaning which moisturise the skin and make it supple, get velvety and soft. In addition, the detergent should be effective against odor causing gram-positive bacteria and thus have a deodorant effect, so optimally on the application of a deodorant can be dispensed with.

These Targets were achieved to a high degree by benzoic acid or a salt of benzoic acid with at least one specific one Alcohol or ether derivative combined in a surfactant mixture has been. With this combination of active ingredients it was possible to cleanse and condition the human skin and / or scalp effectively and to deodorize, allowing for more products that care and serve deodorization could be waived. The active ingredient combination is thus suitable for incorporation in an aforementioned 3in1 product.

object The present invention is therefore a cosmetic cleaning composition with deodorizing effect, containing

a) a surfactant mixture,

• c) mindestens eine Verbindung der Formel (I),
  
  in der R¹ für eine Methyl-, Ethyl-, Propyl-, Isopropyl-, Butyl-, Hydroxymethyl-, Hydroxyethyl-, Ethylglycol-, Hydroxypropyl- oder 1,2-Dihydroxypropylgruppe, R² für Wasserstoff oder eine Methyl-, Ethyl-, Propyl-, Isopropyl-, Butyl-, Pentyl-, Hexyl-, Heptyl-, Octyl-, Benzyl-, -CH₂-O-CH(C₂H₅)-CH₂CH₂CH₂CH₃-Gruppe und R³ für Wasserstoff oder eine Methyl-, Ethyl-, Propyl-, Isopropyl-, Butyl-, Benzylgruppe steht, mit der Maßgabe, dass wenn R² und R³ nicht gleichzeitig für Wasserstoff stehen.

b) benzoic acid or a salt of benzoic acid,

• c) at least one compound of the formula (I)
  
  in the R ^{1 is} a methyl, ethyl, propyl, isopropyl, butyl, hydroxymethyl, hydroxyethyl, ethyl glycol, hydroxypropyl or 1,2-dihydroxypropyl group, R ^{2 is} hydrogen or a methyl, ethyl, , Propyl, isopropyl, butyl, pentyl, hexyl, heptyl, octyl, benzyl, -CH ₂ -O-CH (C ₂ H ₅ ) -CH ₂ CH ₂ CH ₂ CH ₃ - group and R ^{3 is} hydrogen or a methyl, ethyl, propyl, isopropyl, butyl, benzyl group, provided that when R ² and R ^{3 are} not simultaneously hydrogen.

For an optimal deodorant effect, it has proved best according to the invention, if at least one compound of the formula (I) is used as component c), in which
R ^{1 is} a methyl or a hydroxymethyl group,
R ^{2 is} hydrogen or an ethyl, propyl, isopropyl, butyl, pentyl, hexyl, benzyl, -CH ₂ -O-CH (C ₂ H ₅ ) -CH ₂ CH ₂ CH ₂ CH ₃ - Group and
R ^{3 is} hydrogen or a methyl, benzyl group,
with the proviso that when R ² and R ^{3 are} not simultaneously hydrogen.

Especially preferred is the deodorizing effect of the invention Cleaning and care products, if as component c) at least a compound is used from the group that is formed from phenoxyethanol, methylbenzyl alcohol, 1,2-butylene glycol, 1,2-pentanediol, 1,2-hexanediol, 1,2-hepanediol, 1,2-octanediol and / or ethylhexylglycerol.

In a first particularly preferred embodiment of the invention, ethylhexylglycerol is used as component c). The combination of ethylhexylglycerol with benzoic acid or a physiologically acceptable salt of benzoic acid in a surfactant mixture according to the invention results in an effective skin and / or scalp cleansing composition which is very well tolerated by the skin and noticeably improves the skin feel after cleansing. The slight burning or tightening of the skin after cleansing is reduced, and at the same time, the growth and proliferation of odor-causing Gram-positive bacteria is reliably reduced. This protects the natural skin flora. According to the invention, preference is given to using the combination of benzoic acid or a salt of benzoic acid with ethylhexyl glycerol in a mild surfactant base, since this additionally assists skin care and care. A preferred surfactant base will be described in detail in a later part of the description. Ethylhexylglycerol is commercially available - for example, under the trade name "Sensiva ^® SC 50" from Schülke & Mayr. It is in the compositions of the invention - based on their weight - in amounts of 0.01 to 5 wt .-%, preferably from 0.05 to 4 wt .-% and in particular in amounts of 0.1 to 3 wt .-% used.

In a second particularly preferred embodiment of the invention, a mixture of methylbenzyl alcohol, 1,2-hexanediol and 1,2-octanediol is used as component c). This active ingredient mixture in combination with benzoic acid or a physiologically acceptable salt of benzoic acid in surface-active compositions leads to cosmetic skin and / or scalp cleansing compositions according to the invention, which have an excellent antifungal and antimicrobial effect in addition to an excellent cleaning and care effect, and are effective against odor-causing bacteria , Furthermore, the active ingredient mixture in the combination of active substances according to the invention supports the skin moisture and thus the skin care, which in turn can be used to produce a cosmetic cleanser which meets the objectives of the invention (effective cleansing, care and deodorization in a 3-in-1 product) to a high degree. According to the invention suitable, for example, the use of the aforementioned active agent mixture c) as the commercial product "SymTriol ^®", which is offered by the company Symrise. The active compound mixture c) or the commercial product "SymTriol" is in the inventive compositions - based on their weight - in amounts of 0.01 to 5 wt .-%, preferably from 0.05 to 4 wt .-% and in particular in amounts of 0.1 to 3 wt .-% used.

In a third particularly preferred embodiment of the invention, the cleaning agents in addition to the surfactant base, benzoic acid or a physiologically acceptable salt of benzoic acid and ethylhexylglycerol and / or the active ingredient mixture of methylbenzyl alcohol, 1,2-hexanediol and 1,2-octanediol additionally contain phenoxyethanol. The addition of phenoxyethanol not only supports the antibacterial and antifungal properties of the detergents of the invention (and thus their effect against odor-causing microorganisms), but at the same time improve the conditioning of the skin, because they för maintenance and stabilization of skin moisture during cleansing. Phenoxyethanol is in the cleaning agents according to the invention - in terms of their weight - in amounts of 0.01 to 5 wt .-%, preferably from 0.05 to 3 wt .-% and in particular in amounts of 0.1 to 3 wt .-% used. Another particular advantage achieved by the combination of active substances according to the invention and in particular by the addition of phenoxyethanol to the preferred active ingredient combination according to the invention is that of further preservatives in compositions such as parabens or formaldehyde donors (which are undesirable on the skin due to their allergenic action ) can be omitted.

In a further particularly preferred embodiment of the Invention contains the inventive Cleaning agent thus in addition to the aforementioned preferred components c) and optionally phenoxyethanol no further preservatives.

The Total amount of all components c) in the inventive Detergents is - based on their Weight - 0.01 to 15 wt .-%, preferably from 0.05 to 10, more preferably 0.1 to 7.5% by weight and in particular from 0.2 to 5 Wt .-%.

When second essential component contain the inventive Detergent benzoic acid or a physiologically acceptable Salt of benzoic acid. Suitable salts are, for example the alkali metal salts of benzoic acid and especially the sodium salt. Benzoic acid or Na benzoate is used in the inventive Detergents - based on their weight - in Amounts from 0.01 to 10 wt .-%, preferably 0.05 to 7.5 wt .-%, more preferably 0.1 to 5 wt .-% and in particular 0.2 to 3 wt .-% used.

Next Benzoic acid or a physiologically acceptable Salt of benzoic acid and at least one component c) For example, a suitable surfactant base is the third essential component the cleaning compositions according to the invention.

Under The term surfactants are surface-active substances which is an anionic or cationic charge in the molecule wear. Also in the molecule both an anionic as well as cationic charge. This zwitterionic or amphoteric surfactants Also be used according to the invention. Farther The surfactants can also be non-ionic.

• – lineare und verzweigte Fettsäuren mit 8 bis 30 C-Atomen (Seifen),
• – Ethercarbonsäuren der Formel R-O-(CH₂-CH₂O)_XCH₂-COOH, in der R eine lineare Alkylgruppe mit 8 bis 30 C-Atomen und x = 0 oder 1 bis 16 ist,
• – Acylsarcoside mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Acyltauride mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Acylisethionate mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Sulfobernsteinsäuremono- und -dialkylester mit 8 bis 24 C-Atomen in der Alkylgruppe und Sulfobernsteinsäuremono-alkylpolyoxyethylester mit 8 bis 24 C-Atomen in der Alkylgruppe und 1 bis 6 Oxyethylgruppen,
• – lineare Alkansulfonate mit 8 bis 24 C-Atomen,
• – lineare Alpha-Olefinsulfonate mit 8 bis 24 C-Atomen,
• – Alpha-Sulfofettsäuremethylester von Fettsäuren mit 8 bis 30 C-Atomen,
• – Alkylsulfate und Alkylpolyglykolethersulfate der Formel R-O(CH₂-CH₂O)_XOSO₃H, in der R eine bevorzugt lineare Alkylgruppe mit 8 bis 30 C-Atomen und x = 0 oder 1 bis 12 ist,
• – Gemische oberflächenaktiver Hydroxysulfonate gemäß DE-A-37 25 030 ,
• – sulfatierte Hydroxyalkylpolyethylen- und/oder Hydroxyalkylenpropylenglykolether gemäß DE-A-37 23 354 ,
• – Sulfonate ungesättigter Fettsäuren mit 8 bis 24 C-Atomen und 1 bis 6 Doppelbindungen gemäß DE-A-39 26 344 ,
• – Ester der Weinsäure und Zitronensäure mit Alkoholen, die Anlagerungsprodukte von etwa 2–15 Molekülen Ethylenoxid und/oder Propylenoxid an Fettalkohole mit 8 bis 22 C-Atomen darstellen,
• – Alkyl- und/oder Alkenyletherphosphate der Formel (TI),
  
  in der R²⁹ bevorzugt für einen aliphatischen Kohlenwasserstoffrest mit 8 bis 30 Kohlenstoffatomen, R³⁰ für Wasserstoff, einen Rest (CH₂CH₂O)_nR²⁹ oder X, n für Zahlen von 1 bis 10 und X für Wasserstoff, ein Alkali- oder Erdalkalimetall oder NR³¹R³²R³³R³⁴, mit R³¹ bis R³⁴ unabhängig voneinander stehend für einen C₁ bis C₄-Kohlenwasserstoffrest, steht, – sulfatierte Fettsäurealkylenglykolester der Formel (TII) R³⁵CO(AlkO)_nSO₃M (TII)in der R³⁵CO- für einen linearen oder verzweigten, aliphatischen, gesättigten und/oder ungesättigten Acylrest mit 6 bis 22 C-Atomen, Alk für CH₂CH₂, CHCH₃CH₂ und/oder CH₂CHCH₃, n für Zahlen von 0,5 bis 5 und M für ein Kation steht, wie sie in der DE-OS 197 36 906.5 beschrieben sind,
• – Monoglyceridsulfate und Monoglyceridethersulfate der Formel (TIII),
  
  in der R³⁶CO für einen linearen oder verzweigten Acylrest mit 6 bis 22 Kohlenstoffatomen, x, y und z in Summe für 0 oder für Zahlen von 1 bis 30, vorzugsweise 2 bis 10, und X für ein Alkali- oder Erdalkalimetall steht. Typische Beispiele für im Sinne der Erfindung geeignete Monoglycerid(ether)sulfate sind die Umsetzungsprodukte von Laurinsäuremonoglycerid, Kokosfettsäuremonoglycerid, Palmitinsäuremonoglycerid, Stearinsäuremonoglycerid, Ölsäu remonoglycerid und Talgfettsäuremonoglycerid sowie deren Ethylenoxidaddukte mit Schwefeltrioxid oder Chlorsulfonsäure in Form ihrer Natriumsalze. Vorzugsweise werden Monoglyceridsulfate der Formel (TIII) eingesetzt, in der R³⁶CO für einen linearen Acylrest mit 8 bis 18 Kohlenstoffatomen steht.

Suitable anionic surfactants in preparations according to the invention are all anionic surfactants suitable for use on the human body. These are characterized by a water-solubilizing, anionic group such as. As a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group having about 8 to 30 carbon atoms. In addition, glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups may be present in the molecule. Examples of suitable anionic surfactants are, in each case in the form of the sodium, potassium and ammonium as well as the mono-, di- and trialkanolammonium salts having 2 to 4 C atoms in the alkanol group,

• - linear and branched fatty acids with 8 to 30 carbon atoms (soaps),
• Ether carboxylic acids of the formula RO- (CH ₂ -CH ₂ O) _X CH ₂ -COOH, in which R is a linear alkyl group having 8 to 30 C atoms and x = 0 or 1 to 16,
• Acylsarcosides having 8 to 24 C atoms in the acyl group,
• Acyltaurides having 8 to 24 carbon atoms in the acyl group,
• Acyl isethionates having 8 to 24 C atoms in the acyl group,
• Sulfosuccinic acid mono- and dialkyl esters having 8 to 24 C atoms in the alkyl group and sulfosuccinic acid monoalkyl polyoxyethyl esters having 8 to 24 C atoms in the alkyl group and 1 to 6 oxyethyl groups,
• - linear alkanesulfonates having 8 to 24 carbon atoms,
• - linear alpha-olefin sulfonates having 8 to 24 carbon atoms,
• Alpha-sulfofatty acid methyl esters of fatty acids having 8 to 30 C atoms,
• Alkyl sulfates and alkyl polyglycol ether sulfates of the formula RO (CH ₂ -CH ₂ O) _X OSO ₃ H, in which R is a preferably linear alkyl group having 8 to 30 C atoms and x = 0 or 1 to 12,
• Mixtures of surface active hydroxysulfonates according to DE-A-37 25 030 .
• - Sulfated Hydroxyalkylpolyethylen- and / or Hydroxyalkylenpropylenglykolether according to DE-A-37 23 354 .
• - Sulfonates of unsaturated fatty acids having 8 to 24 carbon atoms and 1 to 6 double bonds according to DE-A-39 26 344 .
• Esters of tartaric acid and citric acid with alcohols which are adducts of about 2-15 molecules of ethylene oxide and / or propylene oxide with fatty alcohols containing 8 to 22 carbon atoms,
• Alkyl and / or alkenyl ether phosphates of the formula (TI),
  
  in the R ^{29 is} preferably an aliphatic hydrocarbon radical having 8 to 30 carbon atoms, R ^{30 is} hydrogen, a radical (CH ₂ CH ₂ O) _n R ²⁹ or X, n is from 1 to 10 and X is hydrogen, an alkali metal radical or alkaline earth metal or NR ³¹ R ³² R ³³ R ³⁴ , where R ³¹ to R ³⁴ independently of one another represent a C ₁ to C ₄ -hydrocarbon radical, - sulfated fatty acid alkylene glycol esters of the formula (TII) R ³⁵ CO (AlkO) _n SO ₃ M (TII) in the R ³⁵ CO- for a linear or branched, aliphatic, saturated and / or unsaturated acyl radical having 6 to 22 C atoms, Alk for CH ₂ CH ₂ , CHCH ₃ CH ₂ and / or CH ₂ CHCH ₃ , n for numbers from 0.5 to 5 and M stands for a cation, as in the DE-OS 197 36 906.5 are described
• Monoglyceride sulphates and monoglyceride ether sulphates of the formula (TIII),
  
  in which R ³⁶ CO is a linear or branched acyl radical having 6 to 22 carbon atoms, x, y and z are in total 0 or numbers of 1 to 30, preferably 2 to 10, and X is an alkali or alkaline earth metal. Typical examples of monoglyceride (ether) sulfates suitable for the purposes of the invention are the reaction products of lauric acid monoglyceride, coconut fatty acid monoglyceride, palmitic acid monoglyceride, stearic acid monoglyceride, oleic acid remonoglyceride and tallow fatty acid monoglyceride and their ethylene oxide adducts with sulfur trioxide or chlorosulfonic acid in the form of their sodium salts. Preferably monoglyceride sulfates of the formula (TIII) are used, in which R ³⁶ CO is a linear acyl radical having 8 to 18 carbon atoms.

preferred anionic surfactants in the cleaning preparations according to the invention are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acids with 10 to 18 C atoms in the alkyl group and up to 12 glycol ether groups in the molecule as well as sulfosuccinic mono and dialkyl esters with 8 to 18 carbon atoms in the alkyl group and sulfosuccinic acid mono-alkyl polyoxyethyl esters with 8 to 18 C atoms in the alkyl group and 1 to 6 oxyethyl groups.

The or the anionic surfactant (s) are used in the inventive Compositions - by weight - in Amounts of from 0.5 to 25% by weight, preferably in amounts of from 1 to 20% by weight and in particular in amounts of 2 to 15 wt .-% used. alkyl polyglycol ether sulfates with 10 to 18 C atoms in the alkyl group and 1 to 3 glycol ether groups in the molecule are due to their Hautmilden characteristics particularly preferred anionic surfactants.

Zwitterionic surfactants are those surface-active compounds which carry in the molecule at least one quaternary ammonium group and at least one -COO ^(-) or -SO ₃ ^(-) group. Particularly suitable zwitterionic surfactants are the so-called betaines such as N-alkyl-N, N-dimethylammonium glycinates, for example cocoalkyl dimethylammonium glycinate, N-acylaminopropyl N, N-dimethylammonium glycinates, for example cocoacylaminopropyl-dimethylammonium glycinate, and 2-alkyl 3-carboxymethyl-3-hydroxyethyl-imidazolines each having 8 to 18 C atoms in the alkyl or acyl group and cocoacylaminoethylhydroxyethylcarboxymethylglycinate. According to the invention, particularly preferred zwitterionic surfactants are the fatty acid amide derivative known under the INCI name Cocamidopropyl Betaine and also alkyl betaines having 10 to 20 C atoms in the alkyl group.

Ampholytic surfactants are understood as meaning those surface-active compounds which, in addition to a C ₈ -C ₂₄ -alkyl or -acyl group in the molecule, contain at least one free amino group and at least one -COOH or -SO ₃ H group and are capable of forming internal salts , Examples of suitable ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each having about 8 to 24 C Atoms in the alkyl group. Especially preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and C ₁₂ -C ₁₈ acylsarcosine.

The or the amphoteric / zwitterionic surfactant (s) are incorporated in the Compositions of the invention - based on their weight - in amounts of 0.1 to 15 wt .-%, preferably in amounts of 0.5 to 10 wt .-% and in particular in quantities of 1 used to 7.5 wt .-%.

In a particularly preferred embodiment of the invention As a surfactant base, a particularly mild surfactant mixture is sought, suitable for use in cosmetic, nourishing skin care and / or hair cleansers. For such Surfactant mixture, it is preferred according to the invention a mixture of mild anionic and mild amphoteric and / or use zwitterionic surfactants. Examples of such Mixtures are, for example, alkyl ether sulfates, alkyl ether carboxylic acids, Acylglutamates or sulfosuccinates as well as alkyl betaines, sulfobetaines, Alkylamidoalkylbetaines, alkylamphoacetates and -propionates. Especially preferred is a mixture of alkyl ether sulfates and Alkylamidoalkylbetainen. Especially preferred with respect to skin milding properties The surfactant base is a combination of alkyl ether sulfates and Alkylamidoalkylbetainen in a ratio of 3: 1 to 1: 1.

• A. eine Mischung aus Alkylethersulfaten und Alyklamidoalkylbetainen in einem Verhältnis von 3:1 bis 1:1,
• B. 0,2 bis 3 Gew.-% Natriumbenzoat und
• C. 0,1 bis 3 Gew.-% Ethylhexylglycerin.

Particularly preferred cleaning formulations according to the invention

• A. a mixture of alkyl ether sulfates and alkyl cyclamethyl betaines in a ratio of 3: 1 to 1: 1,
• B. 0.2 to 3 wt .-% sodium benzoate and
• C. 0.1 to 3% by weight of ethylhexylglycerol.

• A. eine Mischung aus Alkylethersulfaten und Alyklamidoalkylbetainen in einem Verhältnis von 3:1 bis 1:1,
• B. 0,2 bis 3 Gew.-% Natriumbenzoat und
• C. 0,1 bis 3 Gew.-% einer Mischung aus Methylbenzylalkohol, 1,2-Hexandiol und 1,2-Octandiol (beispielsweise das Handelsprodukt SymTriol^® der Firma Symrise).

Furthermore, particularly preferred Reinigungszubereitrungen included

• A. a mixture of alkyl ether sulfates and alkyl cyclamethyl betaines in a ratio of 3: 1 to 1: 1,
• B. 0.2 to 3 wt .-% sodium benzoate and
• C. 0.1 to 3 wt .-% of a mixture of methyl benzyl alcohol, 1,2-hexanediol and 1,2-octanediol (for example, the commercial product Symtriol ^® Symrise).

These particularly preferred cosmetic cleaning preparations assets to protect the human skin and / or scalp gently and effectively clean and care at the same time. The skin or scalp becomes during and after cleaning not dried out, but Moisturized, leaving it supple and soft feels. Furthermore, the combination of the Active substances B. and C. to effectively combat gram-positive Bacteria made from sweat ingredients, sebum and Skin cell remains form unpleasant-smelling germs, making it more effective Deodorant effect is achieved with the skin cleansers, which the additional Use of deodorants is no longer necessary.

Of the Addition of 0.1 to 3% by weight of phenoxyethanol to one (or both) the two particularly preferred embodiments of Invention enhances the deodorant effect of the cleaning preparations and also makes the use of other preservatives superfluous.

• – Anlagerungsprodukte von 2 bis 50 Mol Ethylenoxid und/oder 0 bis 5 Mol Propylenoxid an lineare und verzweigte Fettalkohole mit 8 bis 30 C-Atomen, an Fettsäuren mit 8 bis 30 C-Atomen und an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe,
• – mit einem Methyl- oder C₂-C₆-Alkylrest endgruppenverschlossene Anlagerungsprodukte von 2 bis 50 Mol Ethylenoxid und/oder 0 bis 5 Mol Propylenoxid an lineare und verzweigte Fettalkohole mit 8 bis 30 C-Atomen, an Fettsäuren mit 8 bis 30 C-Atomen und an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe, wie beispielsweise die unter den Verkaufsbezeichnungen Dehydol^® LS, Dehydol^® LT (Cognis) erhältlichen Typen,
• – C₁₂-C₃₀-Fettsäuremono- und -diester von Anlagerungsprodukten von 1 bis 30 Mol Ethylenoxid an Glycerin,
• – Anlagerungsprodukte von 5 bis 60 Mol Ethylenoxid an Rizinusöl und gehärtetes Rizinusöl,
• – Polyolfettsäureester, wie beispielsweise das Handelsprodukt Hydagen^® HSP (Cognis) oder Sovermol-Typen (Cognis),
• – alkoxilierte Triglyceride,
• – alkoxilierte Fettsäurealkylester der Formel R³⁷CO-(OCH₂CHR³⁸)_wOR³⁹, (TIV), in der R³⁷CO für einen linearen oder verzweigten, gesättigten und/oder ungesättigten Acylrest mit 6 bis 22 Kohlenstoffatomen, R³⁸ für Wasserstoff oder Methyl, R³⁹ für lineare oder verzweigte Alkylreste mit 1 bis 4 Kohlenstoffatomen und w für Zahlen von 1 bis 20 steht,
• – Aminoxide,
• – Hydroxymischether, wie sie beipielsweise in der DE-OS 19738866 beschrieben sind,
• – Sorbitanfettsäureester und Anlagerungeprodukte von Ethylenoxid an Sorbitanfettsäureester wie beispielsweise die Polysorbate,
• – Zuckerfettsäureester und Anlagerungsprodukte von Ethylenoxid an Zuckerfettsäureester,
• – Anlagerungsprodukte von Ethylenoxid an Fettsäurealkanolamide und Fettamine,
• – Fettsäure-N-alkylglucamide,

To further assist gentle cleaning, it may be preferred according to the invention if the detergents also contain nonionic surfactants. These include as hydrophilic group z. A polyol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether groups. Such compounds are, for example

• - Addition products of 2 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear and branched fatty alcohols having 8 to 30 carbon atoms, to fatty acids having 8 to 30 carbon atoms and to alkylphenols having 8 to 15 carbon atoms in the alkyl group,
• - with a methyl or C ₂ -C ₆ alkyl radical end-capped addition products of 2 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear and branched fatty alcohols having 8 to 30 carbon atoms, to fatty acids having 8 to 30 C atoms and onto alkylphenols having 8 to 15 carbon atoms in the alkyl group, such as those available under the trade names Dehydol ^® LS, LT Dehydol ^® types (Cognis),
• C ₁₂ -C ₃₀ -fatty acid mono- and diesters of addition products of 1 to 30 mol of ethylene oxide with glycerol,
• Adducts of 5 to 60 moles of ethylene oxide with castor oil and hydrogenated castor oil,
• - polyol, such as the commercially available product ^® Hydagen HSP (Cognis) or Sovermol types (Cognis),
• - alkoxylated triglycerides,
• - alkoxylated fatty acid alkyl esters of the formula R ³⁷ CO- (OCH ₂ CHR ³⁸ ) _w OR ³⁹ , (TIV), in which R ³⁷ CO is a linear or branched, saturated and / or unsaturated acyl radical having 6 to 22 carbon atoms, R ^{38 is} hydrogen or methyl, R ³⁹ for linear or branched alkyl radicals having 1 to 4 carbon atoms and w for Numbers from 1 to 20,
• - amine oxides,
• Hydroxymix ethers, as described, for example, in US Pat DE-OS 19738866 are described
• Sorbitan fatty acid esters and adducts of ethylene oxide with sorbitan fatty acid esters such as the polysorbates,
• Sugar fatty acid esters and addition products of ethylene oxide with sugar fatty acid esters,
• Adducts of ethylene oxide with fatty acid alkanolamides and fatty amines,
• Fatty acid N-alkylglucamides,

A another group according to the invention suitable, nonionic Surfactants are the alkyl polyglucosides.

They correspond to the formula (I) R ¹ O- [G] _p (I) in which R ^{1 is} an alkyl and / or alkenyl radical having 4 to 22 carbon atoms, G is a sugar radical having 5 or 6 carbon atoms and p is a number from 1 to 10. They can be obtained by the relevant methods of preparative organic chemistry. Representatives of the extensive literature are here on the writings EP-A1-301 298 and WO 90/03977 A1 directed. The alkyl and / or alkenyl oligoglycosides can be derived from aldoses or ketoses having 5 or 6 carbon atoms, preferably glucose. The preferred alkyl and / or alkenyl oligoglycosides are thus alkyl and / or alkenyl oligoglucosides. The index number p in the general formula (I) indicates the degree of oligomerization (DP), ie the distribution of monoglycerides and oligoglycosides, and stands for a number between 1 and 10. While p must always be an integer in a given compound, and especially the If p = 1 to 6 can be assumed, the value p for a given alkyloligoglycoside is an analytically determined arithmetic variable, which usually represents a fractional number. Preference is given to using alkyl and / or alkenyl oligoglycosides having a mean degree of oligomerization p of from 1.1 to 3.0. From an application point of view, those alkyl and / or alkenyl oligoglycosides whose degree of oligomerization is less than 1.7 and in particular between 1.2 and 1.7 are preferred. The alkyl or alkenyl radical R ¹ can be derived from primary alcohols having 4 to 11, preferably 8 to 10 carbon atoms. Typical examples are butanol, caproic alcohol, caprylic alcohol, capric alcohol and undecyl alcohol, and technical mixtures thereof, as obtained, for example, in the hydrogenation of technical fatty acid methyl esters or in the hydrogenation of aldehydes from Roelen's oxosynthesis. Preference is given to alkyl oligoglucosides of the chain length C ₈ -C ₁₀ (DP = 1-3) which are obtained as a preliminary stream in the distillative separation of technical C ₈ -C ₁₈ coconut fatty alcohol and in a proportion of less than 6% by weight C ₁₂ - Alcohol can be contaminated as well as Alkyloligoglucoside based on technical C _9/11 -Oxoalkohole (DP = 1-3). The alkyl or alkenyl radical R ¹ can also be derived from primary alcohols having 12 to 22, preferably 12 to 14 carbon atoms. Typical examples are lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol, brassidyl alcohol and their technical mixtures, as can be obtained as described above. Very particularly preferred according to the invention are alkyl oligoglucosides based on hydrogenated C _12/14 coconut oil having a DP of 1-3, as are commercially available, for example, under the INCI name "Coco-Glucoside". The nonionic surfactants are in the compositions of the invention - based on their weight - preferably in amounts of 0.05 to 15 wt .-%, preferably from 0.1 to 10 wt .-% and in particular in amounts of 0.5 to 5 wt .-% used.

Of the pH of the cleaning compositions according to the invention ideally lies in a skin-friendly range of about 2.5 to 8, preferably in a range of 3 to 7 and in particular in a range of 3.5 to 6.

Next the aforementioned mandatory inventive Ingredients, the cleaning compositions a Set of other optional ingredients. To be favoured added to the cleaning compositions further active ingredients, the have cosmetic care properties to conditioning to support the skin during the cleaning process. As such, especially cosmetically suitable oil components, cationic polymers, plant extracts and / or humectants as further preferred optional components.

Oil components suitable according to the invention may be selected from mineral, natural or synthetic oil components such as petrolatum, paraffins, silicones, fatty alcohols, fatty acids, fatty acid esters and natural oils of plant and animal origin, and are incorporated into the cleaning composition Compositions - based on their total weight - in an amount of 0.005 to 20 wt .-%, preferably from 0.01 to 10 wt .-%, particularly preferably from 0.05 to 5 wt .-% and in particular from 0.2 to 3 wt .-% used (wherein the amount refers to the total content of all oil components in the cleaning agent according to the invention).

• (i) Polyalkylsiloxanen, Polyarylsiloxanen, Polyalkylarylsiloxanen, die flüchtig oder nicht flüchtig, geradkettig, verzweigt oder cyclisch, vernetzt oder nicht vernetzt sind;
• (ii) Polysiloxanen, die in ihrer allgemeinen Struktur eine oder mehrere organofunktionelle Gruppen enthalten, die ausgewählt sind unter: a) substituierten oder unsubstituierten aminierten Gruppen; b) (per)fluorierten Gruppen; c) Thiolgruppen; d) Carboxylatgruppen; e) hydroxylierten Gruppen; f) alkoxylierten Gruppen; g) Acyloxyalkylgruppen; h) amphoteren Gruppen; i) Bisulfitgruppen; j) Hydroxyacylaminogruppen; k) Carboxygruppen; l) Sulfonsäuregruppen; und m) Sulfat- oder Thiosulfatgruppen;
• (iii) linearen Polysiloxan(A)-Polyoxyalkylen(B)-Blockcopoylmeren vom Typ (A-B)_n mit n > 3;
• (iv) gepfropften Silikonpolymeren mit nicht silikonhaltigem, organischen Grundgerüst, die aus einer organischen Hauptkette bestehen, welche aus organischen Monomeren gebildet wird, die kein Silikon enthalten, auf die in der Kette sowie gegebenenfalls an mindestens einem Kettenende mindestens ein Polysiloxanmakromer gepfropft wurde;
• (v) gepfropften Silikonpolymeren mit Polysiloxan-Grundgerüst, auf das nicht silikonhaltige, organische Monomere gepfropft wurden, die eine Polysiloxan-Hauptkette aufweisen, auf die in der Kette sowie gegebenenfalls an mindestens einem ihrer Enden mindestens ein organisches Makromer gepfropft wurde, das kein Silikon enthält, wie beispielsweise das unter der INCI-Bezeichnung Bis-PEG/PPG-20/20 Dimethicone vertriebene Handelsprodukt Abil B 8832 der Firma Degussa;
• (vi) oder deren Gemischen.

The term silicone oils is understood by the person skilled in the art to mean several structures of organosilicon compounds. More preferably, the silicones are selected from at least one member of the organosilicon compounds formed from:

• (i) polyalkyl siloxanes, polyaryl siloxanes, polyalkylaryl siloxanes which are volatile or nonvolatile, straight chain, branched or cyclic, crosslinked or uncrosslinked;
• (ii) polysiloxanes containing in their general structure one or more organofunctional groups selected from: a) substituted or unsubstituted aminated groups; b) (per) fluorinated groups; c) thiol groups; d) carboxylate groups; e) hydroxylated groups; f) alkoxylated groups; g) acyloxyalkyl groups; h) amphoteric groups; i) bisulfite groups; j) hydroxyacylamino groups; k) carboxy groups; l) sulfonic acid groups; and m) sulfate or thiosulfate groups;
• (iii) linear polysiloxane (A) polyoxyalkylene (B) block copolymers of the (AB) _{n type} with n>3;
• (iv) grafted silicone polymers having a non-silicone-containing organic backbone consisting of an organic backbone formed from organic monomers containing no silicone to which at least one polysiloxane macromer has been grafted in the chain and optionally at least one chain end;
• (v) grafted polysiloxane backbone silicone polymers having grafted thereto non-silicone-containing organic monomers having a polysiloxane backbone to which at least one organic macromer containing no silicone has been grafted in the chain, and optionally at least at one of its ends , such as the commercial product Abil B 8832 from Degussa marketed under the INCI name Bis-PEG / PPG-20/20 dimethicone;
• (vi) or mixtures thereof.

In an embodiment of the present invention is the Conditioner a conditioning silicone with a viscosity from 20,000 to 120,000 mPa · s, most preferably from 40,000 to 80,000 mPa · s. Particular preference is given the conditioning silicone selected from dimethicones, Amodimethicones or dimethiconols.

As fatty acids can be used linear and / or branched, saturated and / or unsaturated fatty acids with 6-30 carbon atoms. Preferred are fatty acids with 10-22 carbon atoms. Among these could be mentioned, for example, isostearic as the commercial products Emersol ^® 871 and Emersol ^® 875, and isopalmitic acids such as the commercial product Edenur ^® IP 95, and all other products sold under the trade names Edenur ^® (Cognis) fatty acids. Further typical examples of such fatty acids are caproic, caprylic, 2-ethylhexanoic, capric, lauric, isotridecanoic, myristic, palmitic, palmitoleic, stearic, isostearic, oleic, elaidic, petroselic, linoleic, linolenic as well as their technical mixtures, the z. As in the pressure splitting of natural fats and oils, in the oxidation of aldehydes from the Roelen oxo synthesis or the dimerization of unsaturated fatty acids. Particularly preferred are usually the fatty acid cuttings obtainable from coconut oil or palm oil; In particular, the use of stearic acid is usually preferred.

As fatty alcohols it is possible to use saturated, mono- or polyunsaturated, branched or unbranched fatty alcohols with C ₆ -C ₃₀ -, preferably C ₁₀ -C ₂₂ - and very particularly preferably C ₁₂ -C ₂₂ -carbon atoms. Decanol, octanol, dodecadienol, decadienol, oleyl alcohol, eruca alcohol, ricinol alcohol, stearyl alcohol, isostearyl alcohol, cetyl alcohol, lauryl alcohol, myristyl alcohol, arachidyl alcohol, capryl alcohol, capric alcohol, can be used for the purposes of the invention. Linoleylalkohol, linolenyl alcohol and behenyl alcohol, and their Guerbet alcohols, this list should have exemplary and non-limiting character. However, the fatty alcohols are derived from preferably natural fatty acids, which can usually be based on recovery from the esters of fatty acids by reduction. Also usable according to the invention are those fatty alcohol cuts which are produced by reducing naturally occurring triglycerides such as beef tallow, palm oil, peanut oil, rapeseed oil, cottonseed oil, soybean oil, sunflower oil and linseed oil or fatty acid esters formed from their transesterification products with corresponding alcohols, and thus represent a mixture of different fatty alcohols. Such substances are, for example, under the names Stenol ^® , z. B. Stenol ^® 1618 or Lanette ^®, z. B. Lanette ^® O or Lorol ^®, z. B. Lorol® ^® C8, Lorol® ^® C14, C18 Lorol® ^{®, ®} Lorol® C8-18, HD Ocenol ^®, Crodacol ^®, z. B. Crodacol CS ^{®, ®} Novol, Eutanol ^® G, Guerbitol ^® 16, Guerbitol ^® 18, Guerbitol ^® 20, Isofol ^® 12, Isofol ^® 16, Isofol ^® 24, Isofol ^® 36, Isocarb 12 ^{®, ®} Isocarb 16 or Isocarb ^® 24 for sale. Of course, wool wax alcohols, as are commercially available, for example under the names of Corona ^®, White Swan ^®, Coronet ^® or Fluilan ^® can be used according to the invention. The fatty alcohols are used in amounts of 0.1-30 wt .-%, based on the total preparation, preferably in amounts of 0.1-20 wt .-%.

When Natural or synthetic waxes can be used according to the invention be solid paraffins or isoparaffins, carnauba waxes, bee waxes, Candelilla, ozokerite, ceresin, spermaceti, sunflower wax, Fruit waxes such as apple wax or citrus wax, Microwachse made of PE or PP. Such waxes are available for example via the company Kahl & Co., Trittau.

• – flüssige Paraffinöle, Isoparaffinöle und synthetische Kohlenwasserstoffe sowie Di-n-alkylether mit insgesamt zwischen 12 bis 36 C-Atomen, insbesondere 12 bis 24 C-Atomen, wie beispielsweise Di-n-octylether, Di-n-decylether, Di-n-nonylether, Di-n-undecylether, Di-n-dodecylether, n-Hexyl-n-octylether, n-Octyl-n-decylether, n-Decyl-n-undecylether, n-Undecyl-n-dodecylether und n-Hexyl-n-Undecylether sowie Di-tert-butylether, Di-iso-pentylether, Di-3-ethyldecylether, tert.-Butyl-n-octylether, iso-Pentyl-n-octylether und 2-Methyl-pentyl-n-octylether. Die als Handelsprodukte erhältlichen Verbindungen 1,3-Di-(2-ethyl-hexyl)-cyclohexan (Cetiol® S) und Di-n-octylether (Cetiol^® OE) können bevorzugt sein.
• – Esteröle. Unter Esterölen sind zu verstehen die Ester von C₆-C₃₀-Fettsäuren mit C₂-C₃₀-Fettalkoholen. Bevorzugt sind die Monoester der Fettsäuren mit Alkoholen mit 2 bis 24 C-Atomen. Beispiele für eingesetzte Fettsäurenanteile in den Estern sind Capronsäure, Caprylsäure, 2-Ethylhexansäure, Caprinsäure, Laurinsäure, Isotridecansäure, Myristinsäure, Palmitinsäure, Palmitoleinsäure, Stearinsäure, Isostearinsäure, Ölsäure, Elaidinsäure, Petroselinsäure, Linolsäure, Linolensäure, Elaeostearinsäure, Arachinsäure, Gadoleinsäure, Behensäure und Erucasäure sowie deren technische Mischungen, die z. B. bei der Druckspaltung von natürlichen Fetten und Ölen, bei der Oxidation von Aldehyden aus der Roelen'schen Oxosynthese oder der Dimerisierung von ungesättigten Fettsäuren anfallen. Beispiele für die Fettalkoholanteile in den Esterölen sind Isopropylalkohol, Capronalkohol, Caprylalkohol, 2-Ethylhexylalkohol, Caprinalkohol, Laurylalkohol, Isotridecylalkohol, Myristylalkohol, Cetylalkohol, Palmoleylalkohol, Stearylalkohol, Isostearylalkohol, Oleylalkohol, Elaidylalkohol, Petroselinylalkohol, Linolylalkohol, Linolenylalkohol, Elaeostearylalkohol, Arachylalkohol, Gadoleylalkohol, Behenylalkohol, Erucylalkohol und Brassidylalkohol sowie deren technische Mischungen, die z. B. bei der Hochdruckhydrierung von technischen Methylestern auf Basis von Fetten und ölen oder Aldehyden aus der Roelen'schen Oxosynthese sowie als Monomerfraktion bei der Dimerisierung von ungesättigten Fettalkoholen anfallen. Erfindungsgemäß besonders bevorzugt sind Isopropylmyristat (Rilanit^® IPM), Isononansäure-C₁₅-₁₈-alkylester (Cetiol^® SN), 2-Ethylhexylpalmitat (Cegesoft^® 24), Stearinsäure-2-ethylhexylester (Cetiol^® 868), Cetyloleat, Glycerintricaprylat, Kokosfettalkoholcaprinat/-caprylat (Cetiol^® LC), n-Butylstearat, Oleylerucat (Cetiol^® J 600), Isopropylpalmitat (Rilanit^® IPP), Oleyl Oleate (Cetiol^®), Laurinsäurehexylester (Cetiol^® A), Di-n-butyladipat (Cetiol^® B), Myristylmyristat (Cetiol^® MM), Cetearyl Isononanoate (Cetiol^® SN), Ölsäuredecylester (Cetiol^® V).
• – Dicarbonsäureester wie Di-n-butyladipat, Di-(2-ethylhexyl)-adipat, Di-(2-ethylhexyl)-succinat und Di-isotridecylacelaat sowie Diolester wie Ethylenglykol-dioleat, Ethylenglykol-di-isotridecanoat, Propylenglykol-di(2-ethylhexanoat), Propylenglykol-di-isostearat, Propylenglykol-di-pelargonat, Butandiol-di-isostearat, Neopentylglykoldicaprylat,
• – symmetrische, unsymmetrische oder cyclische Ester der Kohlensäure mit Fettalkoholen, beispielsweise beschrieben in der DE-OS 197 56 454 , Glycerincarbonat oder Dicaprylylcarbonat (Cetiol^® CC),
• – Trifettsäureester von gesättigten und/oder ungesättigten linearen und/oder verzweigten Fettsäuren mit Glycerin,
• – Fettsäurepartialglyceride, das sind Monoglyceride, Diglyceride und deren technische Gemische. Bei der Verwendung technischer Produkte können herstellungsbedingt noch geringe Mengen Triglyceride enthalten sein. Die Partialglyceride folgen vorzugsweise der Formel,
  
  in der R1, R2 und R3 unabhängig voneinander für Wasserstoff oder für einen linearen oder verzweigten, gesättigten und/oder ungesättigten Acylrest mit 6 bis 22, vorzugsweise 12 bis 18, Kohlenstoffatomen stehen mit der Maßgabe, dass mindestens eine dieser Gruppen für einen Acylrest und mindestens eine dieser Gruppen für Wasserstoff steht. Die Summe (m + n + q) steht für 0 oder Zahlen von 1 bis 100, vorzugsweise für 0 oder 5 bis 25. Bevorzugt steht R1 für einen Acylrest und R2 und R3 für Wasserstoff und die Summe (m + n + q) ist 0. Typische Beispiele sind Mono- und/oder Diglyceride auf Basis von Capronsäure, Caprylsäure, 2-Ethylhexansäure, Caprinsäure, Laurinsäure, Isotridecansäure, Myristinsäure, Palmitinsäure, Palmoleinsäure, Stearinsäure, Isostearinsäure, Ölsäure, Elaidinsäure, Petroselinsäure, Linolsäure, Linolensäure, Elaeostearinsäure, Arachinsäure, Gadoleinsäure, Behensäure und Erucasäure sowie deren technische Mischungen. Vorzugsweise werden Ölsäuremonoglyceride eingesetzt.

The natural and synthetic cosmetic oil bodies include, for example:

• Liquid paraffin oils, isoparaffin oils and synthetic hydrocarbons and di-n-alkyl ethers having a total of from 12 to 36 carbon atoms, in particular 12 to 24 carbon atoms, such as, for example, di-n-octyl ether, di-n-decyl ether, di-n- nonyl ether, di-n-undecyl ether, di-n-dodecyl ether, n-hexyl n-octyl ether, n-octyl n-decyl ether, n-decyl n-undecyl ether, n-undecyl n-dodecyl ether and n-hexyl n-undecyl ether and di-tert-butyl ether, di-iso-pentyl ether, di-3-ethyldecyl ether, tert-butyl n-octyl ether, iso-pentyl n-octyl ether and 2-methyl-pentyl-n-octyl ether. The compounds are available as commercial products 1,3-di- (2-ethyl-hexyl) -cyclohexane (Cetiol® S) and di-n-octyl ether (Cetiol ^® OE) may be preferred.
• - Ester oils. Ester oils are understood as meaning the esters of C ₆ -C ₃₀ -fatty acids with C ₂ -C ₃₀ -fatty alcohols. The monoesters of the fatty acids with alcohols having 2 to 24 carbon atoms are preferred. Examples of fatty acid components used in the esters are caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachidic acid, gadoleic acid, behenic acid and Erucic acid and their technical mixtures, the z. As in the pressure splitting of natural fats and oils, in the oxidation of aldehydes from the Roelen oxo synthesis or the dimerization of unsaturated fatty acids. Examples of the fatty alcohol components in the ester oils are isopropyl alcohol, caproic alcohol, capryl alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linolyl alcohol, linolenyl alcohol, elaeostearyl alcohol, arachyl alcohol, gadoleyl alcohol, Behenyl alcohol, erucyl alcohol and brassidyl alcohol and their technical mixtures, the z. B. incurred in the high-pressure hydrogenation of technical methyl esters based on fats and oils or aldehydes from the Roelen oxo synthesis and as a monomer fraction in the dimerization of unsaturated fatty alcohols. According to the invention, particularly preferred are isopropyl myristate (Rilanit ^® IPM), isononanoic acid C _15-18 alkyl esters (Cetiol ^® SN), 2-ethylhexyl palmitate (Cegesoft ^® 24), stearic acid-2-ethylhexyl ester (Cetiol ^® 868), cetyl oleate, glycerol tricaprylate, Kokosfettalkoholcaprinat / caprylate (Cetiol ^® LC), n-butyl stearate, oleyl erucate (Cetiol ^® J 600), isopropyl palmitate (IPP Rilanit ^®), oleyl Oleate (Cetiol ^®), hexyl laurate (Cetiol ^® A), di-n-butyl adipate (Cetiol ^® B), myristyl myristate (Cetiol ^® MM), Cetearyl Isononanoate (Cetiol ^® SN), decyl oleate (Cetiol ^® V).
• Dicarboxylic acid esters such as di-n-butyl adipate, di (2-ethylhexyl) adipate, di- (2-ethylhexyl) succinate and di-isotridecyl acelate, and diol esters such as ethylene glycol dioleate, ethylene glycol diisotridecanoate, propylene glycol di (2 ethylhexanoate), propylene glycol diisostearate, propylene glycol di-pelargonate, butanediol diisostearate, neopentyl glycol dicaprylate,
• Symmetrical, unsymmetrical or cyclic esters of carbonic acid with fatty alcohols, for example described in US Pat DE-OS 197 56 454 , Glycerol carbonate or dicaprylyl carbonate (Cetiol ^® CC),
• Triflic acid esters of saturated and / or unsaturated linear and / or branched fatty acids with glycerol,
• - fatty acid partial glycerides, ie monoglycerides, diglycerides and their technical mixtures. With the use of technical products production reasons may still contain small amounts of triglycerides. The partial glycerides preferably follow the formula
  
  in which R 1, R 2 and R 3 independently of one another represent hydrogen or a linear or branched, saturated and / or unsaturated acyl radical having 6 to 22, preferably 12 to 18, carbon atoms, with the proviso that at least one of these groups is an acyl radical and at least one of these groups is hydrogen. The sum (m + n + q) is 0 or numbers from 1 to 100, preferably 0 or 5 to 25. Preferably, R 1 is an acyl radical and R 2 and R 3 are hydrogen and the sum is (m + n + q) 0. Typical examples are mono- and / or diglycerides based on caproic, caprylic, 2-ethylhexanoic, capric, lauric, isotridecanoic, myristic, palmitic, palmitic, stearic, isostearic, oleic, elaidic, petroselic, linoleic, linolenic Arachic acid, gadoleic acid, behenic acid and erucic acid and their technical mixtures. Preferably, oleic acid monoglycerides are used.

In a particularly preferred embodiment of the invention we used a vegetable oil as the oil component.

When natural oils come for example amaranth seed oil, Apricot kernel oil, argan oil, avocado oil, babassu oil, Cottonseed oil, borage seed oil, camelina oil, Thistle oil, peanut oil, pomegranate seed oil, Grapefruit seed oil, hemp oil, rosehip seed oil, Hazelnut oil, elderflower seed oil, currant seed oil, Jojoba oil, cocoa butter, linseed oil, macadamia nut oil, Corn oil, almond oil, marula oil, evening primrose oil, Olive oil, palm oil, peach kernel oil, rapeseed oil, Rice oil, sea buckthorn oil, sea buckthorn seed oil, Sesame oil, shea butter, soybean oil, sunflower oil, Grapeseed oil, walnut oil or wild rose oil in question. Avocado oil according to the invention is particularly preferred, Apricot kernel oil, rose hip kernel oil, jojoba oil, Cocoa butter, almond oil, olive oil, peach kernel oil, Shea butter, sunflower oil and grapeseed oil.

in der R¹⁷= -H oder -CH₃ ist, R¹⁸, R¹⁹ und R²⁹ unabhängig voneinander ausgewählt sind aus C_1-4-Alkyl-, -Alkenyl- oder -Hydroxyalkylgruppen, m = 1, 2, 3 oder 4, n eine natürliche Zahl und X^– ein physiologisch verträgliches organisches oder anorganisches Anion ist, sowie Copolymere, bestehend im wesentlichen aus den in Formel (VII) aufgeführten Monomereinheiten sowie nichtionogenen Monomereinheiten, sind besonders bevorzugte kationische Polymere. Im Rahmen dieser Polymere sind diejenigen erfindungsgemäß bevorzugt, für die mindestens eine der folgenden Bedingungen gilt:

• – R¹⁷ steht für eine Methylgruppe
• – R¹⁸, R¹⁹ und R²⁰ stehen für Methylgruppen
• – m hat den Wert 2.

By cationic polymers suitable according to the invention are meant polymers which have groups in the main and / or side chain which may be "temporary" or "permanent" cationic. According to the invention, "permanently cationic" refers to those polymers which have a cationic group, irrespective of the pH of the agent. These are usually polymers containing a quaternary nitrogen atom, for example in the form of an ammonium group. Preferred cationic groups contain quaternary ammonium groups. In particular, those polymers in which the quaternary ammonium group is bonded via a C _1-4 hydrocarbon group to a polymer main chain constructed from acrylic acid, methacrylic acid or derivatives thereof have proven to be particularly suitable. Homopolymers of the general formula (VI),

wherein R ^{17 is} -H or -CH ₃ , R ¹⁸ , R ¹⁹ and R ^{29 are} independently selected from C _1-4 alkyl, alkenyl or hydroxyalkyl groups, m = 1, 2, 3 or 4 , n is a natural number and X ^{- is} a physiologically acceptable organic or inorganic anion, as well as copolymers consisting essentially of the monomer units listed in formula (VII) and nonionic monomer units, are particularly preferred cationic polymers. In the context of these polymers, preference is given to those according to the invention for which at least one of the following conditions applies:

• - R ¹⁷ is a methyl group
• - R ¹⁸ , R ¹⁹ and R ²⁰ are methyl groups
• - m has the value 2.

Suitable physiologically tolerated counterions X ^- include, for example, halide ions, sulfate ions, phosphate ions, methosulfate ions and organic ions such as lactate, citrate, tartrate and acetate ions. Preference is given to halide ions, in particular chloride. According to the invention suitable homopolymers or copolymers derived from the formula (VI), for example, the Salcare ^® SC 95, Salcare ^® SC 96 and Salcare ^® SC 92 available under the trade names commercially.

• – quaternisierte Cellulose-Derivate, wie sie unter den Bezeichnungen Celquat^® und Polymer JR^® im Handel erhältlich sind. Die Verbindungen Celquat^® H 100, Celquat^® L200 und Polymer JR^® 400 sind bevorzugte quaternierte Cellulose-Derivate,
• – hydrophob modifizierte Cellulosederivate, beispielsweise die unter dem Handelsnamen SoftCat^® vertriebenen kationischen Polymere,
• – kationische Alkylpolyglycoside,
• – kationiserter Honig, beispielsweise das Handelsprodukt Honeyquat^® 50,
• – kationische Guar-Derivate, wie insbesondere die unter den Handelsnamen Cosmedia^® Guar und Jaguar^® vertriebenen Produkte,
• – Polysiloxane mit quaternären Gruppen, wie beispielsweise die im Handel erhältlichen erhältlichen Produkte Q2-7224 (Hersteller: Dow Corning; ein stabilisiertes Trimethylsilylamodimethicon), Dow Corning^® 929 Emulsion (enthaltend ein hydroxyl-aminomodifiziertes Silicon, das auch als Amodimethicone bezeichnet wird), SM-2059 (Hersteller: General Electric), SLM-55067 (Hersteller: Wacker) sowie Abil^®-Quat 3270 und 3272 (Hersteller: Th. Goldschmidt; diquaternäre Polydimethylsiloxane, Quaternium-80),
• – polymere Dimethyldiallylammoniumsalze und deren Copolymere mit Estern und Amiden von Acrylsäure und Methacrylsäure. Die unter den Bezeichnungen Merquat^® 100 (Poly(dimethyldiallylammoniumchlorid)) und Merquat^® 550 (Dimethyldiallylammoniumchlorid-Acrylamid-Copolymer) im Handel erhältlichen Produkte sind Beispiele für solche kationischen Polymere,
• – Copolymere des Vinylpyrrolidons mit quaternierten Derivaten des Dialkylaminoalkylacrylats und -methacrylats, wie beispielsweise mit Diethylsulfat quaternierte Vinylpyrrolidon- Dimethylaminoethylmethacrylat-Copolymere. Solche Verbindungen sind unter den Bezeichnungen Gafquat^® 734 und Gafquat^® 755 im Handel erhältlich,
• – Vinylpyrrolidon-Vinylimidazoliummethochlorid-Copolymere, wie sie unter den Bezeichnungen Luviquat^® FC 370, FC 550, FC 905 und HM 552 angeboten werden,
• – quaternierter Polyvinylalkohol, sowie die unter den Bezeichnungen
• – Polyquaternium 2,
• – Polyquaternium 17,
• – Polyquaternium 18 und
• – Polyquaternium 27 bekannten Polymeren mit quartären Stickstoffatomen in der Polymerhauptkette.

Further preferred cationic polymers are, for example

• - Quaternized cellulose derivatives, such as those under the names Celquat ^® and Polymer JR ^® commercially available. The compounds Celquat ^® H 100, Celquat ^® L200 and Polymer JR ^® 400 are preferred quaternized cellulose derivatives
• - hydrophobically modified cellulose derivatives, for example those sold under the trade name SOFTCAT ^® cationic polymers,
• Cationic alkyl polyglycosides,
• - cationized honey, for example the commercial product Honeyquat ^® 50,
• - cationic guar derivatives, such as in particular the products sold under the trade names Cosmedia® ^® Guar and Jaguar ^®,
• - polysiloxanes with quaternary groups, such as the commercially available products Q2-7224 (manufacturer: Dow Corning; a stabilized trimethylsilylamodimethicone), Dow Corning ^® 929 Emulsion (containing a hydroxylamino-modified silicone which is also known as amodimethicone), SM -2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker) and Abil ^® quat 3270 and 3272 (manufacturer: Th Goldschmidt; diquaternary polydimethylsiloxanes, quaternium-80).,
• - Dimethyldiallylammoniumsalze polymeric and their copolymers with esters and amides of acrylic acid and methacrylic acid. Under the names Merquat ^® 100 (Poly (dimethyldiallylammonium chloride)) and Merquat ^® 550 (dimethyldiallylammonium chloride-acrylamide copolymer) are examples of such cationic polymers,
• - Copolymers of vinylpyrrolidone with quaternized derivatives of dialkylaminoalkyl acrylate and methacrylate, such as diethyl sulfate quaternized vinylpyrrolidone dimethylaminoethyl methacrylate copolymers. Such compounds are sold under the names Gafquat ^® 734 and Gafquat ^® 755 commercially,
• - vinylpyrrolidone vinylimidazoliummethochloride copolymers, such as those offered under the names Luviquat.RTM ^® FC 370, FC 550, FC 905 and HM 552,
• - Quaternized polyvinyl alcohol, as well as those under the names
• - Polyquaternium 2,
• - Polyquaternium 17,
• - Polyquaternium 18 and
• Polyquaternium 27 known polymers with quaternary nitrogen atoms in the polymer main chain.

Can be used as cationic polymers are sold under the names Polyquaternium-24 (commercial product z. B. Quatrisoft ^® LM 200), known polymers. , Gaffix ^® VC 713 (manufactured by ISP): Also according to the invention can be used the copolymers of vinylpyrrolidone, such as the commercial products Copolymer 845 (ISP manufacturer) are Gafquat ^® ASCP 1011, Gafquat ^® HS 110, Luviquat ^® 8155 and Luviquat ^® MS 370 available are.

Further cationic polymers according to the invention are the so-called "temporary cationic" polymers. These polymers usually contain an amino group which, at certain pH values, is present as quaternary ammonium group and thus cationic. For example, chitosan and its derivatives are preferred as Hydagen CMF ^®, Hydagen HCMF ^®, Kytamer ^® PC and Chitolam ^® NB / 101 are freely available commercially, for example under the trade names. Chitosans are deacetylated chitins, which are commercially available in different degrees of deacetylation and different degrees of degradation (molecular weights).

In a particularly preferred embodiment of the invention, the skin conditioning conditioning agents according to the invention comprise at least one cationic polymer which is selected from the group formed from cationic cellulose derivatives, cationic guar derivatives and / or polyquaternium-7 (Merquat 550) , Polyquaternium-6, Polyquaternium-10 and / or Polyquaternium-67 (SOFTCAT ^® polymers).

The or the cationic polymer (s) is (are) in the invention Cleaning compositions - based on their total weight - in Contained amounts of 0.1 to 5 wt .-%. Amounts of 0.2 to 3 wt .-%, in particular from 0.5 to 2 wt .-%, are particularly preferred.

Under According to the invention are suitable plant extracts Extracts made from all parts of a plant can be. Usually these extracts produced by extraction of the entire plant. But it can in some cases also be preferred, the extracts exclusively produce from flowers and / or leaves of the plant.

According to the invention especially the extracts of green tea, oak bark, stinging nettle, Witch hazel, hops, chamomile, burdock root, horsetail, hawthorn, Lime blossom, lychee, almond, aloe vera, spruce needle, Horse chestnut, sandalwood, juniper, coconut, Mango, Apricot, Lime, Wheat, Kiwi, Melon, Orange, Grapefruit, Sage, Rosemary, Birch, Mallow, Meadowfoam, Quendel, Yarrow, Thyme, lemon balm, toadstool, coltsfoot, marshmallow, ginseng, ginger root, Echinacea purpurea, Olea europea, Foeniculum vulgaris and Apim graveolens prefers.

When Extraction agent for the preparation of said plant extracts may be used water, alcohols and mixtures thereof become. Among the alcohols are lower alcohols such as ethanol and isopropanol, but especially polyhydric alcohols such as ethylene glycol and propylene glycol, both as the sole extractant also in mixture with water, preferred. Plant extracts based of water / propylene glycol in the ratio 1:10 to 10: 1 proved to be particularly suitable.

The Plant extracts can according to the invention both be used in pure as well as in diluted form. If used in diluted form, contain they usually about 2-80 wt .-% of active substance and as a solvent used in their extraction Extracting agent or extractant mixture.

additionally It may prove advantageous if in the inventive Compositions Humectants or Penetrationshilfsstoffe and / or swelling agent (M). These excipients provide for a better penetration of active ingredients into the keratin fiber or help to swell the keratin fiber. These are for example to include urea and urea derivatives, guanidine and its derivatives, arginine and its derivatives, water glass, imidazole and its derivatives, histidine and its derivatives, benzyl alcohol, Glycerol, glycol and glycol ethers, propylene glycol and propylene glycol ethers, for example, propylene glycol monoethyl ether, carbonates, bicarbonates, Diols and triols, and especially 1,2-diols and 1,3-diols such as 1,2-propanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-dodecanediol, 1,3-propanediol, 1,6-hexanediol, 1,5-pentanediol, 1,4-butanediol. Particularly according to the invention suitable is glycerol. The humectants are in the inventive Cleaning compositions - based on the total composition - in Amounts from 0.01 to 10 wt .-%, preferably in amounts of 0.05 to 5 wt .-% and in particular in amounts of 0.1 to 3 wt .-% used.

• a) ethoxylierten Fettalkohole,
• b) ethoxylierten hydrierten Rizinusöle und
• c) ethoxylierten Mono-, Di- oder Triglycerinester,

wobei das Verhältnis der Komponenten a):b):c) im Bereich von 1:(2–4):(3–4) liegt.The incorporation of other nourishing substances - in particular of oil components - can adversely affect the stability and the cleaning compositions according to the invention. To avoid this undesirable aspect, the cleaning compositions according to the invention for further stabilization of the oil component (s) and all other conditioning agents in a further preferred embodiment, a mixture of solubilizers is added, which are selected from the group of

• a) ethoxylated fatty alcohols,
• b) ethoxylated hydrogenated castor oils and
• c) ethoxylated mono-, di- or triglycerol esters,

wherein the ratio of components a): b): c) is in the range of 1: (2-4) :( 3-4).

The first obligatory component a) of the emulsifier mixture is an ethoxylated fatty alcohol, which is a straight-chain or branched, saturated or unsaturated C ₈ -C ₂₂ fatty alcohol, preferably a C ₁₀ -C ₂₀ fatty alcohol, more preferably one C ₁₂ -C ₁₈ fatty alcohol and in particular a C ₁₃ -C ₁₅ fatty alcohol having a degree of ethoxylation of 1 to 18, preferably from 5 to 16, particularly preferably from 7 to 14 and in particular from 8 to 12, is. Preferred components a) according to the invention are, for example, deceth-5, deceth-7, undeceth-7, laureth-4, laureth-5, laureth-6, laureth-7, laureth-8, laureth-9, laureth-10, laureth-12 , Trideceth-5, Trideceth-7, Trideceth-8, Trideceth-9, Trideceth-10, Triedceth-12, Myreth-8, Myreth-10 and Myreth-12. Particularly preferred are laureth-7, laureth-8, laureth-9, laureth-10, trideceth-5, trideceth-7, trideceth-8, trideceth-9, trideceth-10, and most preferred is trideceth-9.

Component b) is according to the invention ethoxylated hydrogenated castor oil having a degree of ethoxylation of 5 to 80, preferably from 10 to 60, particularly preferably from 25 to 50 and in particular from 35 to 45. Particularly suitable are PEG-10 Hydrogenated Castor Oil, PEG-25 Hydrogenated Castor Oil, PEG-40 Hydrogenated Castor Oil and PEG-60 Hydrogenated Castor Oil, is particularly suitable PEG-40 Hydrogenated Castor Oil, as it is marketed, eg under the trade name Cremophor ^® RH 410 or Eumulgin HRE ^® 455 commercially.

According to the invention, it is also possible to use components a) and b). to be used in a mixture. Such so-called "solubilizer" mixtures are commercially available, for example under the name solubilizer ^® 611674 or solubilizer ^® 660 352 available.

The third essential component c) of the emulsifier mixture is a monoester and / or a mixture of monoesters and diesters of glycerol with branched, or straight-chain, saturated or unsaturated fatty acids having a C chain length of 8 to 24, preferably 10 to 18 and in particular 12 to 16, which have a degree of ethoxylation of 1 to 20, preferably from 2 to 17, particularly preferably from 4 to 13 and in particular from 6 to 10. Ethoxylated glyceryl oleates and glyceryl cocoates According to the invention, and particularly preferred is PEG-7 glyceryl cocoate, such as is available commercially for example under the name Tegosoft ^® GC or Cetiol ^® HE.

The three emulsifiers a), b) and c) are used in the inventive Cleaning compositions - based on their total weight - each in an amount of 0.05 to 3 wt .-%, preferably from 0.1 to 2 wt .-% and in particular from 0.2 to 1.5 wt .-% used.

The Cleaning compositions according to the invention are useful as cosmetic compositions for cleaning the Skin and / or hair, such as a hair shampoo, shower gel, shower bath, Wash gel, facial cleanser, hand wash and / or bubble bath. As such, it can be in addition to the aforementioned compelling and preferred optional ingredients, other active ingredients, auxiliaries and additives which are described below.

Usable according to the invention are also cationic surfactants of the quaternary type Ammonium compounds, the esterquats and the amidoamines. preferred quaternary ammonium compounds are ammonium halides, especially chlorides and bromides, such as alkyltrimethylammonium chlorides, Dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, z. Cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, Distearyldimethylammonium chloride, lauryldimethylammonium chloride, Lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride, as well as those under the INCI names Quaternium-27 and Quaternium-83 known imidazolium compounds. The long alkyl chains of the above Surfactants preferably have 10 to 18 carbon atoms.

Esterquats are known substances which contain both at least one ester function and at least one quaternary ammonium group as a structural element. Preferred ester quats are quaternized ester salts of fatty acids with triethanolamine, quaternized ester salts of fatty acids with diethanolalkylamines and quaternized ester salts of fatty acids with 1,2-dihydroxypropyldialkylamines. Such products are marketed under the trade names Stepantex® ^{®, ®} and Dehyquart® Armocare® ^®. The products Armocare ^® VGH-70, a N, N-bis (2-palmitoyloxyethyl) dimethylammonium chloride, as well as Dehyquart ^® F-75, Dehyquart ^® C-4046, Dehyquart ^® 180 and Dehyquart ^® AU-35 are examples of such esterquats.

The alkylamidoamines are usually prepared by amidation of natural or synthetic fatty acids and fatty acid cuts with dialkylaminoamines. An inventively particularly suitable compound from this group of substances under the name Tegoamid ^® S 18 commercial stearamidopropyl dimethylamine is.

The cationic surfactants are preferred in amounts of from 0.05 to 10 % By weight, based on the total agent used. Amounts of 0.1 to 5 wt .-% are particularly preferred.

• – Anlagerungsprodukte von 4 bis 30 Mol Ethylenoxid und/oder 0 bis 5 Mol Propylenoxid an lineare Fettalkohole mit 8 bis 22 C-Atomen, an Fettsäuren mit 12 bis 22 C-Atomen und an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe,
• – C₁₂-C₂₂-Fettsäuremono- und -diester von Anlagerungsprodukten von 1 bis 30 Mol Ethylenoxid an Polyole mit 3 bis 6 Kohlenstoffatomen, insbesondere an Glycerin,
• – Ethylenoxid- und Polyglycerin-Anlagerungsprodukte an Methylglucosid-Fettsäureester, Fettsäurealkanolamide und Fettsäureglucamide,
• – C₈-C₂₂-Alkylmono- und -oligoglycoside und deren ethoxylierte Analoga, wobei Oligomerisierungsgrade von 1,1 bis 5, insbesondere 1,2 bis 2,0, und Glucose als Zuckerkomponente bevorzugt sind,
• – Gemische aus Alkyl-(oligo)-glucosiden und Fettalkoholen, zum Beispiel das im Handel erhältliche Produkt Montanov^® 68,
• – Anlagerungsprodukte von 5 bis 60 Mol Ethylenoxid an Rizinusöl und gehärtetes Rizinusöl,
• – Partialester von Polyolen mit 3–6 Kohlenstoffatomen mit gesättigten Fettsäuren mit 8 bis 22 C-Atomen,
• – Sterine. Als Sterine wird eine Gruppe von Steroiden verstanden, die am C-Atom 3 des Steroid-Gerüstes eine Hydroxylgruppe tragen und sowohl aus tierischem Gewebe (Zoosterine) wie auch aus pflanzlichen Fetten (Phytosterine) isoliert werden. Beispiele für Zoosterine sind das Cholesterin und das Landsterin. Beispiele geeigneter Phytosterine sind Ergosterin, Stigmasterin und Sitosterin. Auch aus Pilzen und Hefen werden Sterine, die sogenannten Mykosterine, isoliert.
• – Phospholipide. Hierunter werden vor allem die Glucose-Phospholipide, die z. B. als Lecithine bzw. Phosphatidylcholine aus z. B. Eidotter oder Pflanzensamen (z. B. Sojabohnen) gewonnen werden, verstanden.
• – Fettsäureester von Zuckern und Zuckeralkoholen wie Sorbit,
• – Polyglycerine und Polyglycerinderivate wie beispielsweise Polyglycerinpoly-12-hydroxystearat (Handelsprodukt Dehymuls^® PGPH),
• – Lineare und verzweigte Fettsäuren mit 8 bis 30 C-Atomen und deren Na-, K-, Ammonium-, Ca-, Mg- und Zn- Salze.

In a further preferred embodiment, the effect of the compositions according to the invention can be increased by emulsifiers. Such emulsifiers are, for example

• Addition products of from 4 to 30 mol of ethylene oxide and / or from 0 to 5 mol of propylene oxide onto linear fatty alcohols having from 8 to 22 carbon atoms, to fatty acids containing from 12 to 22 carbon atoms and to alkylphenols having from 8 to 15 carbon atoms in the alkyl group,
• C ₁₂ -C ₂₂ -fatty acid mono- and diesters of addition products of from 1 to 30 mol of ethylene oxide onto polyols having from 3 to 6 carbon atoms, in particular to glycerol,
• Ethylene oxide and polyglycerol addition products to methyl glucoside fatty acid esters, fatty acid alkanolamides and fatty acid glucamides,
• C ₈ -C ₂₂ -alkylmono- and -oligoglycosides and their ethoxylated analogues, preference being given to degrees of oligomerization of from 1.1 to 5, in particular from 1.2 to 2.0, and glucose as the sugar component,
• Glucosides mixtures of alkyl (oligo) and fatty alcohols, for example, the commercially available product ^® Montanov 68, -
• Adducts of 5 to 60 moles of ethylene oxide with castor oil and hydrogenated castor oil,
• Partial esters of polyols having 3-6 carbon atoms with saturated fatty acids having 8 to 22 C atoms,
• - sterols. Sterols are understood to mean a group of steroids which have a hydroxyl group on C-atom 3 of the steroid skeleton and are isolated both from animal tissue (zoosterols) and from vegetable fats (phytosterols). Examples of zoosterols are cholesterol and the land sterol. Examples of suitable phytosterols are ergosterol, stigmasterol and sitosterol. Mushrooms and yeasts are also used to isolate sterols, the so-called mycosterols.
• - Phospholipids. Of these, especially the glucose phospholipids z. B. as lecithins or phosphatidylcholines from z. Egg yolks or plant seeds (eg soybeans) are understood.
• Fatty acid esters of sugars and sugar alcohols such as sorbitol,
• - polyglycerols and polyglycerol derivatives such as polyglycerol poly-12-hydroxystearate (commercial product Dehymuls ^® PGPH),
• - Linear and branched fatty acids with 8 to 30 carbon atoms and their Na, K, ammonium, Ca, Mg and Zn salts.

The Emulsifiers are preferred in amounts of 0.1-25% by weight, in particular 0.5-15% by weight, based on the total agent, used.

in principle may contain nonionic emulsifiers with an HLB value of 8 to 18 are used. Nonionic emulsifiers with a HLB values of 10-15 may be preferred according to the invention be.

In a further embodiment of the invention, protein hydrolysates and / or derivatives thereof can be used to increase the activity of the composition according to the invention. Protein hydrolysates are product mixtures obtained by acid, alkaline or enzymatically catalyzed degradation of proteins (proteins). According to the invention, protein hydrolysates of both vegetable and animal origin can be used. Animal protein hydrolysates are, for example, elastin, collagen, keratin, silk and milk protein protein hydrolysates, which may also be present in the form of salts. Such products are, for example, under the trademarks Dehylan ^® (Cognis), Promois® ^® (Interorgana) Collapuron ^® (Cognis), Nutrilan® ^® (Cognis), Gelita-Sol ^® (German Gelatinefabriken Stoess & Co), Lexein ^® (Inolex) and kerasol tm ^® (Croda) sold.

Preferred according to the invention are protein hydrolysates of plant origin, eg. Soybean, almond, rice, pea, potato and wheat protein hydrolysates. Such products are, for example, under the trademarks Gluadin ^® (Cognis), Diahin ^® (Diamalt) ^® (Inolex) and Crotein ^® (Croda) available.

Although the use of the protein hydrolysates is preferred as such, amino acid mixtures or individual amino acids obtained otherwise, such as, for example, arginine, lysine, histidine or pyrroglutamic acid, may also be used in their place. Also possible is the use of derivatives of protein hydrolysates, for example in the form of their fatty acid condensation products. Such products are marketed for example under the names Lamepon ^® (Cognis), Gluadin ^® (Cognis), Lexein ^® (Inolex), Crolastin ^® (Croda) or Crotein ^® (Croda).

Cationized protein hydrolysates can also be used according to the invention, the protein hydrolyzate on which the animal is based, for example from collagen, milk or keratin, from the plant, for example from wheat, maize, rice, potatoes, soy or almonds, from marine life forms, for example from fish collages or algae , or from biotechnologically derived protein hydrolysates, can originate. The protein hydrolyzates on which the cationic derivatives according to the invention are based can be obtained from the corresponding proteins by chemical, in particular alkaline or acid hydrolysis, by enzymatic hydrolysis and / or a combination of both types of hydrolysis. The hydrolysis of proteins usually results in a protein hydrolyzate having a molecular weight distribution of about 100 daltons up to several thousand daltons. Preference is given to those cationic protein hydrolyzates whose underlying protein content has a molecular weight of 100 to 25,000 daltons, preferably 250 to 5000 daltons. Furthermore, cationic protein hydrolyzates are to be understood as meaning quaternized amino acids and mixtures thereof. The quaternization of the protein hydrolyzates or amino acids is often carried out using quaternary ammonium salts such as N, N-dimethyl-N- (n-alkyl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halides. Furthermore, the cationic protein hydrolysates may also be further derivatized. As typical examples of the cationic protein hydrolyzates and derivatives according to the invention, those mentioned under the INCI names in "International Cosmetic Ingredient Dictionary and Handbook," (seventh edition 1997, The Cosmetic, Toiletry and Fragrance Association 1101 17th Street, NW, suite 300, Washington, DC 20036-4702) mentioned and commercially available products called: cocodimonium Hydroxypropyl Hydrolyzed Collagen, Cocodimopnium Hydroxypropyl Hydrolyzed Casein, Cocodimonium Hydroxypropyl Hydrolyzed Collagen, Cocodimonium Hydroxypropyl Hydrolyzed Hair Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Rice Protein, Cocodimonium Hydroxypropyl Hydrolyzed Silk, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Cocodimonium Hydroxypropyl Silk Amino Acids, Hydroxypropyl Arginine Lauryl / Myristyl Ether HCl, Hydroxypropyltrimonium Gelatin, Hydroxypropyltrimonium Hydrolyzed Casein, Hydroxypropyltrimonium Hydrolyzed Collagen, Hydroxypropyltrimonium Hydrolyzed Conchiolin Protein, Hydroxypropyltrimonium Hydrolyzed keratin, Hydroxypropyltrimonium Hydrolyzed Rice Bran Protein, Hydroxyproypltrimonium Hydrolyzed Silk, Hydroxypropyltrimonium Hydrolyzed Soy Protein, Hydroxypropyl Hydrolyzed Vegetable Protein, Hydroxypropyltrimonium Hydrolyzed Wheat Protein, Hydroxypropyltrimonium Hydro lysed Wheat Protein / Siloxysilicate, Lauridimonium Hydroxypropyl Hydrolyzed Wheat Protein, Lauridimonium Hydroxypropyl Hydrolyzed Wheat Protein, Laurydimium Hydroxypropyl Hydrolyzed Wheat Protein / Siloxysilicate, Lauryldimonium Hydroxypropyl Hydrolyzed Casein, Lauryldimonium Hydroxypropyl Hydrolyzed Collagen, Lauryldimonium Hydroxypropyl Hydrolyzed Keratin, Lauryldimonium Hydroxypropyl Hydrolyzed Silk, Lauryldimonium Hydroxypropyl Hydrolyzed Soy Protein, Steardimonium Hydroxypropyl Hydrolyzed Casein, Steardimonium Hydroxypropyl Hydrolyzed Collagen, Steardimonium Hydroxypropyl Hydrolyzed Keratin, Steardimonium Hydroxypropyl Hydrolyzed Rice Protein, Steardimonium Hydroxypropyl Hydrolyzed Silk, Steardimonium Hydroxypropyl Hydrolyzed Soy Protein, Steardimonium Hydroxypropyl Hydrolyzed Vegetable Protein, Steardimonium Hydroxypropyl Hydrolyzed Wheat Protein, Steartrimonium Hydroxyethyl Hydrolyzed Collagen , Quaternium-76 Hydrolyzed Collagen, Quaternium-79 Hydrolyzed Collagen, Quaternium-79 Hydroly zed Keratin, Quaternium-79 Hydrolyzed Milk Protein, Quaternium-79 Hydrolyzed Silk, Quaternium-79 Hydrolyzed Soy Protein, Quaternium-79 Hydrolyzed Wheat Protein. Very particular preference is given to the cationic protein hydrolysates and derivatives based on plants.

The Protein hydrolysates and their derivatives are preferred in amounts from 0.01-10 wt .-%, based on the total agent used. Quantities of 0.1 to 5 wt .-%, in particular 0.1 to 3 wt .-%, are whole particularly preferred.

Also as advantageous, the combination of the invention has Composition with vitamins, provitamins and vitamin precursors and their derivatives proved. In this case, such according to the invention Vitamins, pro-vitamins and vitamin precursors are preferred, usually the groups A, B, C, E, F and H are assigned.

The group of substances called vitamin A includes retinol (vitamin A ₁ ) and 3,4-didehydroretinol (vitamin A ₂ ). The β-carotene is the provitamin of retinol. As vitamin A component according to the invention, for example, vitamin A acid and its esters, vitamin A aldehyde and vitamin A alcohol and its esters such as the palmitate and the acetate into consideration. The vitamin A component is preferably used in amounts of 0.05-1 wt .-%, based on the total preparation.

• • Vitamin B₁ (Thiamin)
• • Vitamin B₂ (Riboflavin)
• • Vitamin B₃. Unter dieser Bezeichnung werden häufig die Verbindungen Nicotinsäure und Nicotinsäureamid (Niacinamid) geführt. Erfindungsgemäß bevorzugt ist das Nicotinsäureamid, das in bevorzugt in Mengen von 0,05 bis 1 Gew.-%, bezogen auf das gesamte Mittel, eingesetzt wird.
• • Vitamin B₅ (Pantothensäure und Panthenol). Im Rahmen dieser Gruppe wird bevorzugt das Panthenol eingesetzt. Erfindungsgemäß einsetzbare Derivate des Panthenols sind insbesondere die Ester und Ether des Panthenols sowie kationisch derivatisierte Panthenole. Einzelne Vertreter sind beispielsweise das Panthenoltriacetat, der Panthenolmonoethylether und dessen Monoacetat sowie die in der WO 92/13829 offenbarten kationischen Panthenolderivate. Die genannten Verbindungen des Vitamin B₅-Typs werden bevorzugt in Mengen von 0,05–10 Gew.-%, bezogen auf das gesamte Mittel, eingesetzt. Mengen von 0,1–5 Gew.-% sind besonders bevorzugt.
• • Vitamin B₆ (Pyridoxin sowie Pyridoxamin und Pyridoxal).

The vitamin B group or the vitamin B complex include, among others

• • Vitamin B ₁ (thiamine)
• • Vitamin B ₂ (riboflavin)
• • Vitamin B ₃ . Under this name, the compounds nicotinic acid and nicotinamide (niacinamide) are often performed. Preferred according to the invention is the nicotinic acid amide, which is preferably used in amounts of from 0.05 to 1% by weight, based on the total agent.
• • Vitamin B ₅ (pantothenic acid and panthenol). Within this group the panthenol is preferred. Derivatives of panthenol which can be used according to the invention are, in particular, the esters and ethers of panthenol and also cationically derivatized panthenols. Individual representatives are for example the Panthenoltriacetat, the Panthenolmonoethylether and its monoacetate as well as in the WO 92/13829 disclosed cationic panthenol derivatives. The said compounds of the vitamin B ₅ type are preferably used in amounts of 0.05-10% by weight, based on the total agent. Amounts of 0.1-5 wt .-% are particularly preferred.
• • Vitamin B ₆ (pyridoxine and pyridoxamine and pyridoxal).

vitamin C (ascorbic acid). The usual amount of Vitamin C is 0.1 to 3 wt .-%, based on the total Medium. The use in the form of palmitic acid ester, the glucoside or phosphates may be preferred. The usage in combination with tocopherols may also be preferred.

Vitamin E (tocopherols, especially α-tocopherol). Tocopherol and its derivatives, including in particular the esters such as acetate, nicotinate, phosphate and succinate, are erfindungsge preferably used in amounts of 0.05-1 wt .-%, based on the total agent.

vitamin F. The term "vitamin F" is commonly used essential fatty acids, especially linoleic acid, Linolenic acid and arachidonic acid, understood.

vitamin H. As vitamin H, the compound becomes (3aS, 4S, 6aR) -2-oxohexahydrothienol [3,4-d] imidazole-4-valeric acid but for the meantime the trivial name Biotin has prevailed. Biotin is preferred in amounts of 0.0001 used to 1.0 wt .-%, in particular in amounts of 0.001 to 0.01 wt .-%.

Particularly according to the invention the use of vitamins, provitamins and vitamin precursors is preferred from the groups A, B, E and H. Panthenol and its derivatives as well Nicotinic acid amide and biotin are particularly preferred.

Farther may in a preferred embodiment of the invention in addition a UV filter (I) can be used. The invention to be used UV filters are subject in terms of their structure and their physical Features no general restrictions. Much more All UV filters that can be used in the cosmetics sector are suitable Absorption maximum in UVA (315-400 nm) -, in UVB (280-315 nm) - or in the UVC (<280 nm) range. UV filter with an absorption maximum in the UVB range, especially in the range of about 280 to about 300 nm, are particularly prefers.

The For example, UV filters can be selected from substituted benzophenones, p-aminobenzoic acid esters, Diphenylacrylic acid esters, cinnamic acid esters, salicylic acid esters, Benzimidazoles and o-aminobenzoic acid esters.

According to a further embodiment of the invention, preference is given to those UV filters which have a cationic group, in particular a quaternary ammonium group. Two preferred UV filters with cationic groups are the commercially available compounds cinnamic acid trimethyl ammonium chloride (Incroquat ^® UV-283) and Dodecyldimethylaminobenzamidopropyl-tosylate (Escalol ^® HP 610).

Of the or the UV filters (I) are usually used in amounts of 0.1-5 % By weight, based on the total agent used. Amounts of 0.4-2.5 % By weight are preferred.

Regarding the type of cosmetic cleaning preparations according to the invention There are no restrictions in principle. As packaging These preparations are, for example, creams, lotions, solutions, Waters, emulsions such as W / O, O / W, PIT emulsions (emulsions according to the teaching of phase inversion, called PIT), microemulsions and multiple emulsions, coarse, unstable, single or multi-phase shaking mixtures, Gels, sprays, aerosols and foam aerosols.

Next the invention compelling components and the other, above-mentioned preferred components in principle all others, those skilled in such cosmetic Medium known components are used.

• – Verdickungsmittel wie Gelatine oder Pflanzengumme, beispielsweise Agar-Agar, Guar-Gum, Alginate, Xanthan-Gum, Gummi arabicum, Karaya-Gummi, Johannisbrotkernmehl, Leinsamengummen, Dextrane, Cellulose-Derivate, z. B. Methylcellulose, Hydroxyalkylcellulose und Carboxymethylcellulose, Stärke-Fraktionen und Derivate wie Amylose, Amylopektin und Dextrine, Tone und Schichtsilikate wie z. B. Bentonit oder vollsynthetische Hydrokolloide wie z. B. Polyvinylalkohol, die Ca-, Mg- oder Zn – Seifen,
• – Strukturanten wie Maleinsäure und Milchsäure,
• – Lösungsmittel und -vermittler wie Ethanol, Isopropanol, Ethylenglykol, Propylenglykol, Glycerin und Diethylenglykol,
• – faserstrukturverbessernde Wirkstoffe, insbesondere Mono-, Di- und Oligosaccharide wie beispielsweise Glucose, Galactose, Fructose, Fruchtzucker und Lactose,
• – Farbstoffe zum Anfärben des Mittels,
• – weitere Substanzen zur Einstellung des pH-Wertes, wie beispielsweise α- und β-Hydroxycarbonsäuren,
• – Wirkstoffe wie Allantoin und Bisabolol,
• – Komplexbildner wie EDTA, NTA, β-Alanindiessigsäure und Phosphonsäuren,
• – Ceramide. Unter Ceramiden werden N-Acylsphingosin (Fettsäureamide des Sphingosins) oder synthetische Analogen solcher Lipide (sogenannte Pseudo-Ceramide) verstanden,
• – Trübungsmittel wie Latex, Styrol/PVP- und Styrol/Acrylamid-Copolymere,
• – Perlglanzmittel wie Ethylenglykolmono- und -distearat sowie PEG-3-distearat,
• – Pigmente,
• – Treibmittel wie Propan-Butan-Gemische, N₂O, Dimethylether, CO₂ und Luft,
• – Viskositätsregler wie Salze (NaCl).

Further active ingredients, auxiliaries and additives are, for example:

• Thickeners such as gelatin or vegetable gums, for example agar-agar, guar gum, alginates, xanthan gum, gum arabic, karaya gum, locust bean gum, linseed gums, dextrans, cellulose derivatives, e.g. As methylcellulose, hydroxyalkylcellulose and carboxymethylcellulose, starch fractions and derivatives such as amylose, amylopectin and dextrins, clays and phyllosilicates such. As bentonite or fully synthetic hydrocolloids such. As polyvinyl alcohol, the Ca, Mg or Zn - soaps,
• - structurants such as maleic acid and lactic acid,
• Solvents and mediators such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerol and diethylene glycol,
• Fiber-structure-improving active substances, in particular mono-, di- and oligosaccharides such as, for example, glucose, galactose, fructose, fructose and lactose,
• Dyes for staining the agent,
• Further substances for adjusting the pH, such as, for example, α- and β-hydroxycarboxylic acids,
• - active substances such as allantoin and bisabolol,
• Complexing agents such as EDTA, NTA, β-alaninediacetic acid and phosphonic acids,
• - Ceramides. Among ceramides N-acylsphingosine (fatty acid amides of sphingosine) or syntheti analogous to such lipids (so-called pseudo-ceramides),
• Opacifiers such as latex, styrene / PVP and styrene / acrylamide copolymers,
• Pearlescing agents such as ethylene glycol mono- and distearate and PEG-3-distearate,
• - pigments,
• Propellants such as propane-butane mixtures, N ₂ O, dimethyl ether, CO ₂ and air,
• - Viscosity regulator such as salts (NaCl).

• a) einer Tensidmischung
• b) Benzoesäure oder einem Salz der Benzoesäure und
• c) mindestens einer Verbindung der Formel I,
  
  in der R¹ für eine Methyl-, Ethyl-, Propyl-, Isopropyl-, Butyl-, Hydroxymethyl-, Hydroxyethyl-, Ethylglycol-, Hydroxypropyl- oder 1,2-Dihydroxypropylgruppe, R² für Wasserstoff oder eine Methyl-, Ethyl-, Propyl-, Isopropyl-, Butyl-, Pentyl-, Hexyl-, Heptyl-, Octyl-, Benzyl-, -CH₂-O-CH(C₂H₅)-CH₂CH₂CH₂CH₃-Gruppe und R³ für Wasserstoff oder eine Methyl-, Ethyl-, Propyl-, Isopropyl-, Butyl-, Benzylgruppe steht, mit der Maßgabe, dass wenn R² und R³ nicht gleichzeitig für Wasserstoff stehen, als reinigende und deodorierende Wirkstoffmischung in einem Shampoo, Duschgel, Duschbad, Waschgel, Gesichtsreiniger und/oder Handwaschmittel.

A second object of the invention is the use of a combination of

• a) a surfactant mixture
• b) benzoic acid or a salt of benzoic acid and
• c) at least one compound of the formula I,
  
  in the R ^{1 is} a methyl, ethyl, propyl, isopropyl, butyl, hydroxymethyl, hydroxyethyl, ethyl glycol, hydroxypropyl or 1,2-dihydroxypropyl group, R ^{2 is} hydrogen or a methyl, ethyl, , propyl, isopropyl, butyl, pentyl, hexyl, heptyl, octyl, benzyl, -CH ₂ -O-CH (C ₂ H ₅₎ -CH ₂ CH ₂ CH ₂ CH ₃ group, and R ^{3 is} hydrogen or a methyl, ethyl, propyl, isopropyl, butyl, benzyl group, with the proviso that when R ² and R ^{3 are} not simultaneously hydrogen, as a detergent and deodorant active ingredient mixture in a shampoo, Shower gel, shower bath, wash gel, facial cleanser and / or hand detergent.

One third subject of the invention is a method for simultaneous Cleaning, care and deodorization of human keratin fibers, in particular human skin, characterized in that an inventive Cleaning composition applied to the keratin fibers, distributed, and rinsed with water again.

The following examples illustrate the invention without, however, limiting it to:
All information is in weight percent unless otherwise stated.

Examples

The following cleaning compositions according to the invention were prepared: raw material 1 2 Fatty alcohol polyglycol ether sulfate (C12-14), 2EO, 70% AS 10 1 NaOH 50% 0.1 0.1 Cocoamidopropylbetaine 40% AS 10 10 Conditioner ^®1 P7 1.5 1.5 Glycerin 86% 1 1 Herbasol extract lychee - 0.1 sodium benzoate 0.4 0.4 citric acid 0.4 0.4 Almond oil, sweet 0.2 - Perfume 1 1 Solubilizer ⁶⁶⁰³⁵² ® ² - 1 ^Cetiol®3 HE 0.5 0.5 SymTriol ^®4 1 - phenoxyethanol - 1 Sensiva ^®5 SC 50 - 0.3 water ad 100 ad 100

The Cleansing the skin with cleansing compositions 1 or 2 resulted in effectively cleansed skin, which is soft and cared for. Furthermore, the cleaning compositions worked deodorising on the skin. This deodorant effect lasted up to 24 hours.

• 1 INCI-Bezeichnung: Polyquaternium-7, Aqua; Sigma
• 2 INCI-Bezeichnung: PEG-40 Hydrogenated Castor Oil, Trideceth-9, Propylene Glycol, Aqua; Symrise
• 3 INCI-Bezeichnung: PEG-7 Glyceryl Cocoate; Cognis
• 4 INCI-Bezeichnung: Methylbenzylalkohol, 1,2-Hexandiol, und 1,2-Octandiol; Symrise
• 5 INCI-Bezeichnung: Ethylhexylglycerin; Schälke & Mayr

The following commercial products were used:

• 1 INCI name: Polyquaternium-7, Aqua; Sigma
• 2 INCI name: PEG-40 Hydrogenated Castor Oil, Trideceth-9, Propylene Glycol, Aqua; Symrise
• 3 INCI name: PEG-7 Glyceryl Cocoate; Cognis
• 4 INCI name: methylbenzyl alcohol, 1,2-hexanediol, and 1,2-octanediol; Symrise
• 5 INCI name: ethylhexylglycerol; Schälke & Mayr

QUOTES INCLUDE IN THE DESCRIPTION

This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.

Cited patent literature

• - DE 3725030 A [0019]
• - DE 3723354 A [0019]
• - DE 3926344 A [0019]
• - DE 19736906 [0019]
• - DE 19738866 [0030]
• - EP 301298 A1 [0032]
• WO 90/03977 A1 [0032]
• DE 19756454 [0041]
• WO 92/13829 [0077]

Cited non-patent literature

• "International Cosmetic Ingredient Dictionary and Handbook," (seventh edition 1997, The Cosmetic, Toiletry and Fragrance Association, 1101 17th Street, NW, Suite 300, Washington, DC 20036-4702) [0073]

Claims (14)

Cosmetic cleaning composition having a deodorizing effect, comprising a) a surfactant mixture, b) benzoic acid or a salt of benzoic acid, c) at least one compound of the formula (I),

in the R ^{1 is} a methyl, ethyl, propyl, isopropyl, butyl, hydroxymethyl, hydroxyethyl, ethyl glycol, hydroxypropyl or 1,2-dihydroxypropyl group, R ^{2 is} hydrogen or a methyl, ethyl, , Propyl, isopropyl, butyl, pentyl, hexyl, heptyl, octyl, benzyl, -CH ₂ -O-CH (C ₂ H ₅ ) -CH ₂ CH ₂ CH ₂ CH ₃ - group and R ^{3 is} hydrogen or a methyl, ethyl, propyl, isopropyl, butyl, benzyl group, provided that when R ² and R ^{3 are} not simultaneously hydrogen. A composition according to claim 1, characterized in that in the formula IR ^{1 is} a methyl or a hydroxymethyl group, R ^{2 is} hydrogen or an ethyl, propyl, isopropyl, butyl, pentyl, hexyl, benzyl, CH ₂ -O-CH (C ₂ H ₅ ) -CH ₂ CH ₂ CH ₂ CH ₃ and R ^{3 is} hydrogen or methyl, benzyl, provided that when R ² and R ^{3 are} not simultaneously for Hydrogen stand. Composition according to one of the claims 1 or 2, characterized in that the compound of formula 1 is selected from at least one component of the group, which is formed from phenoxyethanol, methylbenzyl alcohol, 1,2-butylene glycol, 1,2-pentanediol, 1,2-hexanediol, 1,2-hepanediol, 1,2-octanediol and / or Ethylhexylglycerin. Composition according to one of the claims 1 to 3, characterized in that they as component c) Ethylhexylglycerin contains. Composition according to one of the claims 1 to 3, characterized in that they as component c) a Mixture of methylbenzyl alcohol, 1,2-hexanediol, and 1,2-octanediol contains. Composition according to one of the claims 4 or 5, characterized in that they additionally phenoxyethanol contains. Composition according to one of the claims 1 to 6, characterized in that - based on her Weight - the component (s) c) in an amount of 0.01 to 15% by weight, preferably from 0.05 to 10, more preferably from 0.1 to 7.5 wt .-% and in particular from 0.2 to 5 wt .-%. Composition according to one of the claims 1 to 7, characterized in that the surfactant mixture a) selected is from mild anionic and mild zwitterionic / amphoteric Surfactants. Composition according to one of the claims 1 to 8, characterized in that they - based on her Weight - 0.01 to 10 wt .-%, preferably 0.05 to 7.5 wt .-%, more preferably 0.1 to 5% by weight and in particular 0.2 to 3% by weight Benzoic acid or sodium benzoate contains. Composition according to one of the claims 1 to 9, characterized in that they additionally at least contains a solubilizer. Composition according to one of the claims 1 to 10, characterized in that they additionally at least contains a cationic polymer. Composition according to one of the claims 1 to 11, characterized in that they have a pH in the range from 2.5 to 8, preferably from 3 to 7 and in particular from 3.5 to 6 has. Using a combination of a) a surfactant mixture b) benzoic acid or a salt of benzoic acid and d) at least one compound of the formula I,

in the R ^{1 is} a methyl, ethyl, propyl, isopropyl, butyl, hydroxymethyl, hydroxyethyl, ethyl glycol, hydroxypropyl or 1,2-dihydroxypropyl group, R ^{2 is} hydrogen or a methyl, ethyl, , Propyl, isopropyl, butyl, pentyl, hexyl, heptyl, octyl, benzyl, -CH ₂ -O-CH (C ₂ H ₅ ) -CH ₂ CH ₂ CH ₂ CH ₃ - group and R ^{3 is} hydrogen or a methyl, ethyl, propyl, isopropyl, butyl, benzyl group, with the proviso that when R ² and R ^{3 are} not simultaneously hydrogen, as a detergent and deodorant active ingredient mixture in a shampoo, Shower gel, shower bath, wash gel, facial cleanser and / or hand detergent. Method for simultaneous cleaning, care and Deodorization of human keratin fibers, in particular human Skin, characterized in that a composition according to a of claims 1 to 12 applied to the keratin fibers, distributed and rinsed with water again.