DE102009026855A1 - Scented washing, cleaning or care products - Google Patents

Abstract

It describes a fragrance giving washing, cleaning or care products containing fragrance aldehydes and (optionally substituted) ethylenediamine and / or (optionally substituted) propylenediamine. This allows surprising odor advantages of the objects treated with it, in particular as regards the aspects of intensity and durability of the scent impression. In this case, the total amount of perfume contained in the agent can even be reduced, and yet odor advantages can be achieved on the objects.

Description

The The present invention relates to a washing, cleaning or care agent, containing ethylenediamines and / or propylenediamines. It concerns Further, a textile cleaning or conditioning method, wherein the Textile to be cleaned textile laundry using a corresponding washing, cleaning or care products subjected becomes. It relates to the use of such a cleaning agent and / or conditioning of textile fabrics, in particular in an automatic washing machine. It concerns the use of ethylenediamine and / or propylenediamine for extension the scent effect of the washing, cleaning or care product as well to achieve a long - lasting fresh smell when using the Washing, cleaning or care products.

at the use of detergents, cleaning or care products the consumer is not just the target, the objects to be treated to wash, clean or care, but he wishes also that the treated objects, such. As textiles, according to the Like to smell laundry well. In particular from this Basically, most commercially available washing, Cleaning or care products Fragrances.

At the Use of conventional washing, cleaning or care products remains after the application, especially after washing, however often only a relatively weak one Fragrance on the treated object, especially the laundry, back. Therefore, there is an ongoing consumer side Need for washing, cleaning or care products, which improved object scenting, in particular textile scenting, allow, especially with regard to the fragrance intensity, especially with regard to a sense of freshness.

The The object of the present invention was therefore to provide washing, cleaning or to provide conditioners which have improved fragrance intensity in use, in particular in the context of textile treatment, demonstrate.

• (a) Duftaldehyde sowie
• (b) (ggf. substituierte) Ethylendiamine und/oder (ggf. substituierte) Propylendiamine.

This object has been achieved by a washing, cleaning or care product containing

• (a) fragrance aldehydes as well
• (b) (optionally substituted) ethylenediamines and / or (optionally substituted) propylenediamines.

It could surprisingly be found that the inventive Washing, cleaning or care products in the application improved Show fragrance intensity, especially in connection with the Textile treatment. For example, could in the application of a Laundry treatment agent, such as. B. detergent and softener, an improved fragrance intensity of the treated laundry being found. This applies to both the wet and in particular also for dry laundry. This was also a better durability of the fragrance impression found, d. H. the desired one Fragrance impression lasted longer. Furthermore, corresponding Products a particularly good storage stability. The invention Funds also allow the total amount of perfume, which is included on average, to reduce, and yet odor benefits to achieve on the washed textiles, especially with a view on the feeling of freshness.

In a preferred embodiment of the invention an agent according to the invention is characterized that component (a) and component (b) are separated into the washing, Cleaning or care matrix are added. At this Approach is particularly advantageous scent intensities in according to the invention allows. It is z. B. according to the invention possible, the Component (a) with the remaining perfume in to introduce the product and component (b) in a separate To introduce step. Furthermore, it is also possible according to the invention the components (a) and (b) in a single step in the product to bring in, for. B. together with the rest of the perfuming, if components (a) and (b) are present separately during the addition, z. B. as separate components of a perfume oil.

According to one Another preferred embodiment is as a component (b) 1,2-diaminoethane, propane-1,3-diamine, 1,2-dianilinoethane, N, N'-dimethylethylenediamine, N, N'-diethylethyl-1,3-diamine, N, N'-diisopropylethyl-1,3-diamine, N, N'-dimethylpropane-1,3-diamine, N, N'-diethylpropane-1,3-diamine and / or N, N'-diisopropylpropane-1,3-diamine used.

As fragrance aldehydes, it is possible to use all customary fragrant aldehydes which are typically used to produce a pleasant scent sensation. Suitable fragrance aldehydes are known to the person skilled in the art. Suitable fragrance aldehydes may be any aldehydes, especially those which impart a desired fresh scent or sensation of freshness. Because this is particularly ge invention wishes, especially with a view to a particularly intense and long lasting feeling of freshness. It may be individual aldehydes or aldehyde mixtures. The fragrance aldehydes may in particular have an aliphatic, cycloaliphatic, aromatic, ethylenically unsaturated structure or a combination of these structures. There may also be other heteroatoms or polycyclic structures. The structures may have suitable substituents such as hydroxyl or amino groups.

If in the agent according to the invention as a component (a) a fragrance aldehyde is used, selected from Adoxal, Anisaldehyde, cymal, ethylvanillin, florhydral, helional, heliotropin, Hydroxycitronellal, koavon, lauraldehyde, lyral, methylnonylacetaldehyde, P.T. Bucinal, phenylacetaldehyde, undecylenaldehyde, vanillin, 2,6,10-trimethyl-9-undecenal, 3-dodecene-1-al, alpha-n-amylcinnamaldehyde, 4-methoxybenzaldehyde, benzaldehyde, 3- (4-tert-butylphenyl) -propanal, 2-methyl-3- (para-methoxyphenyl) propanal, 2-methyl-4- (2,6,6-timethyl-2 (1) -cyclohexen-1-yl) butanal, 3-phenyl-2-propenal, cis- / trans-3,7-dimethyl-2,6-octadiene-1-al, 3,7-dimethyl-6-octene-1-al, [(3,7-dimethyl-6-octenyl) oxy] acetaldehyde, 4-isopropylbenzaldehyde, 1,2,3,4,5,6,7,8-octahydro-8,8-dimethyl-2-naphthaldehyde, 2,4-dimethyl-3-cyclohexene-1-carboxaldehyde, 2-methyl-3- (isopropylphenyl) propanal, 1-decanal, decyl aldehyde, 2,6-dimethyl-5-heptenal, 4- (tricyclo [5.2.1.0 (2,6)] decylidene-8) -butanal, octahydro-4,7-methane-1H-indenecarboxaldehyde, 3-ethoxy-4-hydroxybenzaldehyde, para-ethyl-alpha, alphadimethylhydrocinnamaldehyde, alpha-methyl-3,4- (methylenedioxy) -hydrocinnamaldehyde, 3,4-methylenedioxybenzaldehyde, alpha-n-hexylcinnamic aldehyde, m-cymene-7-carboxaldehyde, alpha-methylphenylacetaldehyde, 7-hydroxy-3,7-dimethyloctanal, undecenal, 2,4,6-trimethyl-3-cyclohexene-1-carboxaldehyde, 4- (3) (4-methyl-3-pentenyl) -3-cyclohexene-carboxaldehyde, 1-dodecanal, 2,4-dimethylcyclohexene-3-carboxaldehyde, 4- (4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde, 7-methoxy-3,7-dimethyloctane-1-al 2-methylundecanal, 2-methyldecanal, 1-nonanal, 1-octanal, 2,6,10-trimethyl-5,9-undecadienal, 2-methyl-3- (4-tert-butyl) propanal, dihydrocinnamaldehyde, 1-methyl-4- (4-methyl-3-pentenyl) -3-cyclohexene-1-carboxaldehyde, 5- or 6-methoxyhexahydro-4,7-methanindane-1 or 2-carboxaldehyde, 3,7-dimethyloctan-1-al, 1-undecanal, 10-undecene-1-al, 4-hydroxy-3-methoxybenzaldehyde, 1-methyl-3- (4-methylpentyl) -3-cyclohexenecarboxaldehyde, 7-hydroxy-3,7-dimethyl-octanal, trans-4-decenal, 2,6-nonadienal, para-tolylacetaldehyde, 4-methylphenylacetaldehyde, 2-methyl-4- (2,6,6-trimethyl-1-cyclohexen-1-yl) -2-butenal, ortho-methoxycinnamaldehyde, 3,5,6-trimethyl-3-cyclohexene carboxaldehyde, 3,7-dimethyl-2-methylene-6-octenal, Phenoxyacetaldehyde, 5,9-dimethyl-4,8-decadienal, peonyaldehyde (6,10-dimethyl-3-oxa-5,9-undecadien-1-al), hexahydro-4,7-methanindane-1-carboxaldehyde, 2-methyl octanal, alpha-methyl-4- (1-methylethyl) benzene acetaldehyde, 6,6-dimethyl-2-norpinen-2-propionaldehyde, para-methylphenoxyacetaldehyde, 2-methyl-3-phenyl-2-propene-1-al 3,5,5-trimethylhexanal, hexahydro-8,8-dimethyl-2-naphthaldehyde, 3-propylbicyclo [2.2.1] hept-5-ene-2-carbaldehyde, 9-decenal, 3-methyl-5-phenyl-1-pentanal, Methylnonylacetaldehyde, hexanal, trans-2-hexenal, 1-p-menthene-q-carboxaldehyde or mixtures thereof, so is a preferred embodiment of the invention.

Furthermore, it is advantageous in the context of the invention to use fragrance ketones in addition to the fragrance aldehyde. A preferred embodiment of the invention is therefore present if in addition at least one fragrance ketone is used, in particular selected from buccoxime; iso-jasmone; Methyl-beta-naphthyl ketone; musk indanone; Tonalid / Musk plus; alpha Damascon, beta damascone, delta damascone, iso-damascone, damascenone, damarose, methyldihydrojasmonate, menthone, carvone, camphor, fenchone, alpha-ionone, beta-ionone, gamma-methyl called ionone, fleuramon, dihydrojasmon, cis-jasmone, ^® iso-e-Super, Methylcedrenylketon or Methylcedry ion, acetophenone, methylacetophenone, p-methoxyacetophenone, methyl-beta-naphtylketon, benzylacetone, benzophenone, para hydroxy, celery ketone or Livescone, 6-Isopropyldecahydro-2 -naphtone, dimethyloctenone, frescomethylene, 4- (1-ethoxyvinyl) -3,3,5,5-tetramethylcyclohexanone, methylheptenone, 2- (2- (4-methyl-3-cyclohexen-1-yl) -propyl) -cyclopentanone, 1 - (p-Menthene-6 (2) yl) -1-propanone, 4- (4-hydroxy-3-methoxyphenyl) -2-butanone, 2-acetyl-3,3-dimethylnorbornane, 6,7-dihydro -1,1,2,3,3-pentamethyl-4 (5H) in-danone, 4-damascol, dulcinyl or cassion, gelson, hexalon, isocyclone E, methylcyclocitron, methyllavedelketone, orivone, paratertiary butylcyclohexanone, Verdon, Delphon, Muscon , Neobutenon, Plicaton, Ve lou-ton, 2,4,4,7-tetramethyl-oct-6-en-3-one, tetrameran or mixtures thereof. Preferably, the ketones may be selected from alpha Damascone, delta damascone, iso damascone, carvone, gamma-methylionone, iso-E-super, 2,4,4,7-tetramethyl-oct-6-en-3-one, benzylacetone, Beta damascone, damascenone, methyl dihydrojasmonate, methyl cedrylon, hedione and mixtures thereof.

For other suitable fragrances, selected from aldehydes and ketones, is on Steffen Arctander Published 1960 and 1969, respectively, Reprinted 2000 ISBN: Aroma Chemicals Vol. 1: 0-931710-37-5, Aroma Chemicals Vol. 2: 0-931710-38-3 , referenced.

In a further preferred embodiment of the invention, component (b) is present in amounts of from 0.001% by weight to 3% by weight, preferably from 0.01 to 2% by weight, in particular from 0.1 to 1% by weight the mean, based on the total In this way, particularly good scent results in terms of Invention feasible. If an agent according to the invention contains 0.001% by weight to 3% by weight, preferably 0.01% to 2% by weight, in particular 0.1% to 1% by weight, of fragrance aldehydes,% by weight, based on the total agent, so is also a preferred embodiment of the invention. Thus, also very good scent results within the meaning of the invention can be represented. In particular, it is advantageous for achieving particularly good scent results if the ratio of component (a) to component (b) is 25: 1 to 1: 5. Then again there is a preferred embodiment of the invention.

Farther it is preferred that the total amount of fragrance of the agent, therefore also includes all fragrance aldehydes contained, 0.01 to 10 wt .-%, preferably 0.1 to 5 wt .-%, in particular 0.3 to 3 wt .-% is. This corresponds to a preferred embodiment of the invention.

According to one Another preferred embodiment of the invention the agent according to the invention in solid form, preferably in powder form or in granular form or in shape of molded articles, for. B. tablets. It is also possible that the inventive agent is in liquid form, preferably in gel form. Also this corresponds to a preferred embodiment of the invention.

Next the fragrance aldehydes and the (optionally substituted) ethylenediamine and / or (optionally substituted) propylenediamine, the inventive Agents include other suitable ingredients, but especially surfactants. When the agent according to the invention is at least 5% by weight, preferably at least 8% by weight, in particular at least 10% by weight Containing surfactant, in particular anionic surfactant and / or nonionic surfactant, such is a preferred embodiment of the invention in front. A reasonable upper limit for surfactant z. B. at 40 wt .-% or 30 wt .-% or 20 wt .-%, wt .-% in each case on the entire remedy. Surfactants will be more detailed below described.

One Another object of the invention is a Textilreinigungs- or conditioning method in which the textile to be cleaned a Textile laundry using a novel Washing, cleaning or care product is subjected, in particular in an automatic washing machine, preferably at temperatures not above 60 ° C, especially not over 40 ° C.

One Another object of the invention is also in the use of a inventive washing, cleaning or care agent for cleaning and / or conditioning of textile fabrics, in particular in an automatic washing machine, preferably at temperatures not above 60 ° C, especially not over 40 ° C.

One Another object of the invention is the use of (possibly substituted) ethylenediamine and / or (optionally substituted) propylenediamine as a separately added component in fragrance-containing washing, Cleaning or care products containing fragrance aldehyde, to extend the fragrance effect of the washing, cleaning or care products. "Separately added component" refers This is based on the fragrance aldehydes and should also mean that ethylenediamine and / or (optionally substituted) propylenediamine and the Duftaldehyde as separate entities in the Washing, cleaning or care products. It is Z. Belly possible, the components (a) and (b) in a single Step into the product, z. B. together with the rest Perfuming, provided that the components (a) and (b) in the Added separately, z. B. as separate components of a Perfume oil.

One Another object of the invention is the use of (possibly substituted) ethylenediamine and / or (optionally substituted) propylenediamine as a separately added component in fragrance-containing washing, Cleaning or care products containing fragrance aldehyde, to achieve a long lasting freshness smell during use of washing, cleaning or care products. "Added separately Component "is to be understood as described above.

at the washing, cleaning or care agent may in particular a textile treatment agent in the form of a laundry detergent, Fabric softener, softening detergent or washing aid act. Likewise, it may be z. B. a detergent for hard Surfaces, such as preferably a dishwashing detergent, in particular a machine dishwashing detergent. As well it may be cleaning agents such. Household cleaner, all-purpose cleaner, Window cleaner, floor cleaner, etc. act. Preferably It can be a product for cleaning toilet bowls and urinals act, advantageously a Spülreiniger for hanging in the toilet bowl or cistern, especially one so-called toilet stone. In the sense of the care product is preferred to cosmetics, such as. As hair shampoos, deodorants, etc., which suitable for personal care and / or cleaning are. For the purposes of the care product, it may also include air care products and room air improvers act.

According to one preferred embodiment is in the inventive Means therefore a textile treatment agent, an ironing aid, a cleaning cloth, a laundry detergent, a fabric softener, a cleaning agent, in particular for hard and / or soft Surfaces, a household cleaner, a care product, a laundry detergent, a room fragrance, an air freshener, a conditioner, a colorant, a fabric softener, a conditioning substrate, a cleaning agent, a cosmetic agent, a bleaching agent, a descaling agent, a car care product, floor care products, Herdpflegemittel, leather care products, furniture care products, a scouring agent, a disinfectant, a fragrance, a mold remover and / or a precursor of the foregoing Medium. It is an advantage of the invention that the invention Means are very stable on storage.

To a further preferred embodiment of the invention are in the agent according to the invention additional (s) Contain fragrance (s), in particular selected from the Group comprising fragrances natural or synthetic Origin, preferably more volatile perfumes, higher boiling Fragrances, solid fragrances and / or adherent fragrances.

Tenacious Fragrances that are advantageous in the context of the present invention can be used, for example, essential oils such Angelica root oil, aniseed oil, Arnica blossom oil, Basil oil, bay oil, bergamot oil, champacabell oil, Edling fir oil, Edel fir cone oil, Elemiöl, Eucalyptus oil, fennel oil, spruce alder oil, galbanum oil, Geranium oil, ginger grass oil, guaiac wood oil, Gurjun Balm Oil, Helichrysum Oil, Ho Oil, Ginger oil, iris oil, cajeput oil, calamus oil, Chamomile oil, camphor oil, kanga oil, cardamom oil, Cassia oil, pine needle oil, copaiba balsam oil, Coriander oil, spearmint oil, caraway oil, Cumin oil, lavender oil, lemon grass oil, lime oil, Tangerine oil, lemon balm oil, musk kernel oil, Myrrh oil, clove oil, neroli oil, niaouli oil, Olibanum Oil, Orange Oil, Origanum Oil, Palmarosa Oil, Patchouli oil, Peruvian balsam oil, Petitgrain oil, Pepper oil, peppermint oil, allspice oil, pine oil, Rose oil, rosemary oil, sandalwood oil, celery oil, Spiked oil, star aniseed oil, turpentine oil, thuja oil, Thyme oil, verbena oil, vetiver oil, juniper berry oil, Wormwood oil, wintergreen oil, ylang-ylang oil, Hyssop oil, cinnamon oil, cinnamon oil, Citron oil, lemon oil and cypress oil.

But also higher-boiling or solid fragrances natural or of synthetic origin may be within the scope of the present invention Invention as adherent fragrances or fragrance mixtures, ie Fragrances are used. These connections include the following compounds as well as mixtures of these: Ambrettolide, α-amylcinnamaldehyde, anethole, anisaldehyde, anisalcohol, Anisole, methyl anthranilate, acetophenone, benzylacetone, Benzaldehyde, ethyl benzoate, benzophenone, benzyl alcohol, Benzyl acetate, benzyl benzoate, benzyl formate, benzyl valerate, borneol, Bornyl acetate, α-bromostyrene, n-decyl aldehyde, n-dodecyl aldehyde, Eugenof, eugenol methyl ether, eucalyptol, farnesol, fenchone, fenchyl acetate, Geranyl acetate, geranyl formate, heliotropin, heptincarboxylic acid methyl ester, Heptaldehyde, hydroquinone dimethyl ether, hydroxycinnamaldehyde, hydroxycinnamyl alcohol, Indole, iron, isoeugenol, isoeugenol methyl ether, isosafrole, jasmon, Camphor, Karvakrol, Karvon, p-cresol methyl ether, coumarin, p-methoxyacetophenone, Methyl-n-amyl ketone, methyl-methyl-methane-methylester, p-methylacetophenone, methylchavikole, p-methylquinoline, methyl-β-naphthylketone, Methyl n-nonyl acetaldehyde, methyl n-nonyl ketone, muskon, β-naphthol ethyl ether, β-naphthol methyl ether, Nerol, nitrobenzene, n-nonylaldehyde, nonyl alcohol, n-octylaldehyde, p-oxy-acetophenone, pentadecanolide, β-phenylethyl alcohol, Phenylacetaldehyde dimethyl acetal, phenylacetic acid, pulegone, safrole, Salicylic acid isoamyl ester, salicylic acid methyl ester, Salicylic acid hexyl ester, cyclohexyl salicylate, Santalol, skatole, terpineol, thymen, thymol, γ-undelactone, Vaniline, veratrum aldehyde, cinnamaldehyde, cinnamyl alcohol, cinnamic acid, Cinnamic acid ethyl ester, cinnamic acid benzyl ester. To In particular, the more volatile perfumes count the lower-boiling fragrances natural or synthetic Origin, which can be used alone or in mixtures. Examples of more volatile fragrances are Alkyl isothiocyanates (alkyl-mustard oils), butanedione, limonene, Linalool, linayl acetate and propionate, menthol, menthone, methyl-n-heptenone, Phellandrene, phenylacetaldehyde, terpinyl acetate, citral, citronellal.

to accelerated or delayed release of fragrances All methods known in the art may be used as far as they appear to the skilled person to be suitable. According to a preferred Embodiment of the invention comprises the inventive Agent-supported and / or encapsulated perfume.

According to a further preferred embodiment, the washing, care or cleaning agent according to the invention, at least one, preferably more, active components, especially washing, care, cleaning active and / or cosmetic components, advantageously selected from the group comprising anionic surfactants, cationic Surfactants, amphoteric surfactants, nonionic surfactants, acidifiers, alkalizing agents, anti-wrinkle compounds, antibacterial agents, antioxidants, anti redeposition agents, antistatic agents, builders, bleaches, bleach activators, bleach stabilizers, bleach catalysts anti-caking agents, co-builders, fragrances, anti-shrinkage agents, electrolytes, enzymes, colorants, colorants, dyes, color transfer inhibitors, fluorescers, fungicides, germicides, odoriferous substances, adjuvants, hydrotropes, rinse aids, chelating agents, preservatives, corrosion inhibitors, water-miscible organic solvents, optical brighteners, Perfumes, perfume carriers, pearlescers, pH adjusters, repellents and impregnating agents, polymers, swelling and anti-slip agents, foam inhibitors, phyllosilicates, dirt repellents, silver protectants, silicone oils, soil release agents, UV protectants, viscosity regulators, thickeners, discoloration inhibitors, grayness inhibitors , Vitamins and / or fabric softener. For the purposes of this invention, data for the agent according to the invention in% by weight, unless otherwise stated, relate to the total weight of the composition according to the invention.

The Quantities of the individual ingredients in the inventive Means are oriented in each case to the purpose of the relevant Medium and the professional is with the orders of magnitude the quantities of ingredients to be used or can these in the corresponding specialist literature. Depending on the purpose the agent according to the invention will be, for example select the surfactant content higher or lower. Usually can z. For example, the surfactant content of, for example, detergents between 10 and 50 wt .-%, preferably between 12.5 and 30 wt .-% and in particular between 15 and 25% by weight while detergent for automatic dishwashing z. B. between 0.1 and 10 wt .-%, preferably between 0.5 and 7.5 wt .-% and especially between 1 and 5 wt .-% surfactants may contain.

The Agents of the invention may be surfactants preferably anionic surfactants, nonionic surfactants and mixtures thereof, but also cationic surfactants come into question. Suitable nonionic surfactants are, in particular, ethoxylation and / or propoxylation products of alkyl glycosides and / or linear or branched alcohols each having 12 to 18 carbon atoms in the alkyl moiety and 3 to 20, preferably 4 to 10 alkyl ether groups. Farther are corresponding ethoxylation and / or propoxylation products of N-alkylamines, vicinal diols, fatty acid esters and Fatty acid amides which, with regard to the alkyl moiety, are those mentioned long-chain alcohol derivatives, as well as alkylphenols with 5 to 12 C-atoms in the alkyl radical useful.

suitable anionic surfactants are in particular soaps and those containing or sulfonate groups with preferably alkali ions as cations. Useful soaps are preferably the alkali salts of the saturated ones or unsaturated fatty acids having 12 to 18 carbon atoms. Such fatty acids may also be incomplete neutralized form can be used. Among the useful surfactants of the sulfate type include the salts of sulfuric acid half esters of fatty alcohols containing 12 to 18 carbon atoms and the sulfation products of mentioned nonionic surfactants with a low degree of ethoxylation. Suitable surfactants of the sulfonate type include linear ones Alkylbenzenesulfonates with 9 to 14 C atoms in the alkyl moiety, alkanesulfonates with 12 to 18 carbon atoms, as well as olefinsulfonates with 12 to 18 carbon atoms, in the implementation of corresponding monoolefins with sulfur trioxide arise as well as alpha-sulfo fatty acid esters, which in the Sulfonation of fatty acid methyl or ethyl esters arise.

Cationic surfactants are preferably selected from esterquats and / or quaternary ammonium compounds (QAV) according to the general formula (R ^I ) (R ^II ) (R ^III ) (R ^IV ) N ⁺ X ^- in which R ^I to R ^{IV represent} the same or different C _1-22 -alkyl, C _7-28 -Arylalkylreste or heterocyclic radicals, wherein two or in the case of an aromatic inclusion as in pyridine even three radicals together with the nitrogen atom, the heterocycle, z. A pyridinium or imidazolinium compound, and X ^{- represents} halide ions, sulfate ions, hydroxide ions or like anions. QACs are by reacting tertiary amines with alkylating agents, such as. As methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethylene oxide produced. The alkylation of tertiary amines with a long alkyl radical and two methyl groups succeeds particularly easily, and the quaternization of tertiary amines with two long radicals and one methyl group can be carried out with the aid of methyl chloride under mild conditions. Amines which have three long alkyl radicals or hydroxy-substituted alkyl radicals are less reactive and are z. B. quaternized with dimethyl sulfate. Suitable QACs are, for example, benzalkonium chloride (N alkyl-N, N dimethyl-benzylammonium chloride), benzalkone B (m, p-dichlorobenzyldimethyl-C ₁₂ -alkylammonium chloride, benzoxonium chloride (benzyl-dodecyl-bis (2-hydroxyethyl) -ammonium chloride), Cetrimonium bromide (N-hexadecyl-N, N-trimethyl-ammonium bromide), Benzetonium chloride (N, N-dimethyl-N [2- [2- [p- (1,1,3,3-tetramethyl-butyl) -phenoxy] -ethoxy] -ethyl ] benzylammonium chloride), dialkyldimethylammonium chlorides such as di-n-decyldimethylammonium chloride, didecyldimethylammonium bromide, dioctyldimethylammonium chloride, 1-cetylpyridinium chloride and thiazoline iodide, and mixtures thereof Preferred QACs are the benzalkonium chlorides having C ₈ -C ₂₂ -alkyl radicals, in particular C ₁₂ -C ₁₄ -alkyl-benzyl-dimethylammonium chloride.

verstanden werden, in der R⁵ für einen Alkyl- oder Alkenylrest mit 12 bis 22 Kohlenstoffatomen und 0, 1, 2 oder 3 Doppelbindungen, R⁶ und R⁷ unabhängig voneinander für H, OH oder O(CO)R⁵, s, t und u jeweils unabhängig voneinander für den Wert 1, 2 oder 3 und X^– für ein Anion, insbesondere Halogenid, Methosulfat, Methophosphat oder Phosphat sowie Mischungen aus diesen, steht. Bevorzugt sind Verbindungen, die für R⁶ die Gruppe O(CO)R⁵ und für R⁵ einen Alkylrest mit 16 bis 18 Kohlenstoffatomen enthalten. Besonders bevorzugt sind Verbindungen, bei denen R⁷ zudem für OH steht. Beispiele für Verbindungen der Formel (IV) sind Methyl-N-(2-hydroxyethyl)-N,N-di(talgacyl-oxyethyl)ammonium-methosulfat, Bis-(palmitoyl)-ethyl-hydroxyethyl-methyl-ammonium-methosulfat oder Methyl-N,N-bis(acyloxyethyl)-N-(2-hydroxyethyl)ammonium-methosulfat. Werden quarternierte Verbindungen der Formel (IV) eingesetzt, die ungesättigte Gruppen aufweisen, sind die Acylgruppen bevorzugt, deren korrespondierende Fettsäuren eine Jodzahl zwischen 5 und 80, vorzugsweise zwischen 10 und 60 und insbesondere zwischen 15 und 45 aufweisen und/oder die ein cis/trans-Isomerenverhältnis (in Mol-%) von größer als 30:70, vorzugsweise größer als 50:50 und insbesondere größer als 70:30 haben. Handelsübliche Beispiele sind die von der Firma Stepan unter dem Warenzeichen Stepantex^® vertriebenen Methylhydroxyalkyldialkoyloxyalkylammoniummethosulfate oder die unter dem Handelsnamen Dehyquart^® bekannten Produkte der Firma Cognis Deutschland GmbH beziehungsweise die unter der Bezeichnung Rewoquat^® bekannten Produkte des Herstellers Goldschmidt-Witco.Esterquats are here preferably compounds of the general formula IV,

in which R ^{5 is} an alkyl or alkenyl radical having 12 to 22 carbon atoms and 0, 1, 2 or 3 double bonds, R ⁶ and R ^{7 are} independently H, OH or O (CO) R ⁵ , s, t and u are each independently of the other the value 1, 2 or 3 and X ^{- is} an anion, in particular halide, methosulfate, methophosphate or phosphate and mixtures of these. Preference is given to compounds which contain the group O (CO) R ⁵ for R ⁶ and an alkyl radical having 16 to 18 carbon atoms for R ⁵ . Particularly preferred are compounds in which R ^{7 is} also OH. Examples of compounds of the formula (IV) are methyl N- (2-hydroxyethyl) -N, N-di (tallowacyl-oxyethyl) ammonium methosulfate, bis (palmitoyl) -ethyl-hydroxyethyl-methyl-ammonium methosulfate or methyl -N, N-bis (acyloxyethyl) -N- (2-hydroxyethyl) ammonium methosulfate. If quaternized compounds of the formula (IV) which have unsaturated groups are used, preference is given to the acyl groups whose corresponding fatty acids have an iodine number between 5 and 80, preferably between 10 and 60 and in particular between 15 and 45 and / or which have a cis / trans Isomer ratio (in mol%) of greater than 30:70, preferably greater than 50:50 and in particular greater than 70:30 have. Commercial examples are sold by Stepan under the trade name Stepantex® ^® methylhydroxyalkyldialkoyloxyalkylammonium or those known under the trade name Dehyquart® ^® products from Cognis Germany GmbH or the known under the name Rewoquat ^® products by manufacturer Goldschmidt-Witco.

surfactants are in the inventive compositions in proportions of preferably 5% by weight to 50% by weight, in particular 8% by weight to 30 wt .-%, contained. Especially in laundry aftertreatment agents are preferably up to 30 wt .-%, in particular 5 wt .-% to 15 wt .-% of surfactants, among these, preferably at least partially Cationic surfactants, used.

An agent according to the invention preferably contains at least one water-soluble and / or water-insoluble, organic and / or inorganic builder. The water-soluble organic builder substances include polycarboxylic acids, in particular citric acid and sugar acids, monomeric and polymeric aminopolycarboxylic acids, in particular methylglycinediacetic acid, nitrilotriacetic acid and ethylenediaminetetraacetic acid and polyaspartic acid, polyphosphonic acids, in particular aminotris (methylenephosphonic acid), ethylenediaminetetrakis (methylenephosphonic acid) and 1-hydroxyethane-1,1-diphosphonic acid, polymeric hydroxy compounds such as dextrin and polymeric (poly) carboxylic acids, polymeric acrylic acids, methacrylic acids, maleic acids and copolymers thereof, which may also contain polymerized small amounts of polymerizable substances without carboxylic acid functionality. The molecular weight of the homopolymers of unsaturated carboxylic acids is generally between 5,000 and 200,000, that of the copolymers between 2,000 and 200,000, preferably 50,000 to 120,000, in each case based on the free acid. A particularly preferred acrylic acid-maleic acid copolymer has a molecular weight of 50,000 to 100,000. Suitable, although less preferred, compounds of this class are copolymers of acrylic or methacrylic acid with vinyl ethers, such as vinylmethyl ethers, vinyl esters, ethylene, propylene and styrene, in which the acid content is at least 50% by weight. As water-soluble organic builders, it is also possible to use terpolymers which contain two unsaturated acids and / or salts thereof as monomers and vinyl alcohol and / or a vinyl alcohol derivative or a carbohydrate as the third monomer. The first acidic monomer or its salt is derived from a monoethylenically unsaturated C ₃ -C ₈ -carboxylic acid and preferably from a C ₃ -C ₄ -monocarboxylic acid, in particular from (meth) -acrylic acid. The second acidic monomer or its salt can be a derivative of a C ₄ -C ₈ -dicarboxylic acid, with maleic acid being particularly preferred. The third monomeric unit is formed in this case of vinyl alcohol and / or preferably an esterified vinyl alcohol. In particular, preferred are vinyl alcohol derivatives which are an ester of short-chain carboxylic acids, for example C ₁ -C ₄ carboxylic acids, with vinyl alcohol. Preferred polymers contain from 60% by weight to 95% by weight, in particular from 70% by weight to 90% by weight, of (meth) acrylic acid or (meth) acrylate, particularly preferably acrylic acid or acrylate, and maleic acid or Maleinate and 5 wt .-% to 40 wt .-%, preferably 10 wt .-% to 30 wt .-% of vinyl alcohol and / or vinyl acetate. Very particular preference is given to polymers in which the weight ratio of (meth) acrylic acid or (meth) acrylate to maleic acid or maleate is between 1: 1 and 4: 1, preferably between 2: 1 and 3: 1 and in particular 2: 1 and 2 , 5: 1 lies. Both the amounts and the weight ratios are based on the acids. The second acidic monomer or its salt can also be a derivative of an allylsulfonic acid, which in 2-position with an alkyl radical, preferably with a C ₁ -C ₄ alkyl radical, or an aromatic radical which is preferably derived from benzene or benzene derivatives substituted. Preferred terpolymers contain from 40% by weight to 60% by weight, in particular from 45 to 55% by weight, of (meth) acrylic acid or (meth) acrylate, particularly preferably acrylic acid or acrylate, from 10% by weight to 30% by weight. %, preferably 15 wt .-% to 25 wt .-% methallylsulfonic acid or Methallylsulfonat and as the third monomer 15 wt .-% to 40 wt .-%, preferably 20 wt .-% to 40 wt .-% of a carbohydrate. This carbohydrate may be, for example, a mono-, di-, oligo- or polysaccharide, mono-, di- or oligosaccharides being preferred. Particularly preferred is sucrose. The use of the third monomer presumably incorporates predetermined breaking points into the polymer which are responsible for the good biodegradability of the polymer. These terpolymers generally have a molecular weight between 1,000 and 200,000, preferably between 200 and 50,000 and in particular between 3,000 and 10,000. Further preferred copolymers are those which contain acrolein and acrylic acid / acrylic acid salts or vinyl acetate as monomers. The organic builder substances can be used, in particular for the preparation of liquid agents, in the form of aqueous solutions, preferably in the form of 30 to 50 percent by weight aqueous solutions. All of the acids mentioned are generally used in the form of their water-soluble salts, in particular their alkali metal salts.

organic If desired, builders may be used in quantities up to 40% by weight, in particular up to 25% by weight, and preferably from 1% by weight to 8% by weight. Quantities close to the mentioned upper limit are preferably in pasty or liquid, in particular hydrous, inventive Funds used. Laundry aftertreatment preparations according to the invention, such as As fabric softener, may optionally also be free of organic builder.

When Water-soluble inorganic builder materials are especially Alkali silicates and polyphosphates, preferably sodium triphosphate, into consideration. As water-insoluble, water-dispersible Inorganic builder materials may in particular be crystalline or amorphous alkali metal aluminosilicates, if desired in amounts of up to 50% by weight, preferably not more than 40% by weight and in liquid agents, in particular from 1% by weight to 5 wt .-%, are used. Among these are the crystalline ones Detergent grade sodium aluminosilicates, in particular Zeolite A, P and optionally X, preferred. Quantities near the mentioned Upper limit are preferably in solid, particulate Funds used. Suitable aluminosilicates have in particular no particles with a grain size over 30 microns and preferably consist of at least 80 wt .-% of particles smaller than 10 μm in size.

Suitable substitutes or partial substitutes for the said aluminosilicate are crystalline alkali silicates which may be present alone or in a mixture with amorphous silicates. The alkali metal silicates useful as builders in the compositions according to the invention preferably have a molar ratio of alkali metal oxide to SiO ₂ below 0.95, in particular from 1: 1.1 to 1:12, and may be present in amorphous or crystalline form. Preferred alkali metal silicates are the sodium silicates, in particular the amorphous sodium silicates, with a molar ratio of Na ₂ O: SiO ₂ of 1: 2 to 1: 2.8. The crystalline silicates which may be present alone or in admixture with amorphous silicates, are crystalline layer silicates with the general formula Na ₂ Si _x O 2 _{+ x 1} · yH ₂ O are used in which x, the so-called module, a number from 1.9 to 4 and y is a number from 0 to 20 and preferred values for x are 2, 3 or 4. Preferred crystalline phyllosilicates are those in which x in the abovementioned general formula assumes the values 2 or 3. In particular, both β- and δ-sodium disilicates (Na ₂ Si ₂ O ₅ .yH ₂ O) are preferred. Also prepared from amorphous alkali silicates, practically anhydrous crystalline alkali metal silicates of the abovementioned general formula in which x is a number from 1.9 to 2.1, can be used in inventive compositions. In a further preferred embodiment of the composition according to the invention, a crystalline sodium layer silicate with a modulus of 2 to 3 is used, as can be prepared from sand and soda. Crystalline sodium silicates with a modulus in the range from 1.9 to 3.5 are used in a further preferred embodiment of compositions according to the invention. If alkali metal aluminosilicate, in particular zeolite, is also present as an additional builder substance, the weight ratio of aluminosilicate to silicate, based in each case on anhydrous active substances, is preferably 1:10 to 10: 1. In agents containing both amorphous and crystalline alkali metal silicates, the weight ratio of amorphous alkali metal silicate to crystalline alkali metal silicate is preferably 1: 2 to 2: 1 and especially 1: 1 to 2: 1.

builders are if desired in the invention Means preferably in amounts up to 60 wt .-%, in particular of 5 wt .-% to 40 wt .-%, contained. invention Laundry aftertreatment, such as. B. fabric softener, are preferably free of inorganic builder.

Suitable peroxygen compounds are, in particular, organic peracids example persaure salts of organic acids, such as phthalimidopercaproic acid, perbenzoic acid or salts of diperdodecanedioic acid, hydrogen peroxide and under the conditions of use hydrogen peroxide-releasing inorganic salts, such as perborate, percarbonate and / or persilicate into consideration. If solid peroxygen compounds are to be used, they can be used in the form of powders or granules, which can also be enveloped in a manner known in principle. Particular preference is given to using alkali percarbonate, alkali perborate monohydrate or, in particular, in liquid media, hydrogen peroxide in the form of aqueous solutions which contain from 3% by weight to 10% by weight of hydrogen peroxide. If an agent according to the invention contains bleaches, such as preferably peroxygen compounds, they are present in amounts of preferably up to 50% by weight, in particular from 5% by weight to 30% by weight. The addition of small amounts of known bleach stabilizers such as phosphonates, bristles or metaborates and metasilicates and magnesium salts such as magnesium sulfate may be useful.

When Bleach activators may be compounds that are under perhydrolysis conditions aliphatic peroxycarboxylic acids with preferably 1 to 10 C-atoms, in particular 2 to 4 C-atoms, and / or optionally substituted Perbenzoic acid, are used. Are suitable Substances which contain O- and / or N-acyl groups of said C atomic number and / or optionally substituted benzoyl groups. Preferred are multiply acylated alkylenediamines, in particular tetraacetylethylenediamine (TAED), acylated triazine derivatives, in particular 1,5-diacetyl-2,4-dioxohexahydro-1,3,5-triazine (DADHT), acylated glycolurils, especially tetraacetylglycoluril (TAGU), N-acylimides, especially N-nonanoylsuccinimide (NOSI), acylated Phenolsulfonates, especially n-nonanoyl or isononanoyloxybenzenesulfonate (n- or iso-NOBS), carboxylic anhydrides, in particular Phthalic anhydride, acylated polyhydric alcohols, in particular Triacetin, ethylene glycol diacetate, 2,5-diacetoxy-2,5-dihydrofuran and enol ester, as well as acetylated sorbitol and mannitol, respectively their mixtures (SORMAN), acylated sugar derivatives, in particular Pentaacetylglucose (PAG), Pentaacetylfruktose, Tetraacetylxylose and octaacetyl lactose and acetylated, optionally N-alkylated Glucamine and gluconolactone, and / or N-acylated lactams, for example N-benzoyl. Hydrophilic substituted acyl acetals and acyl lactams are also preferably used. Also combinations of conventional Bleach activators can be used. Such bleach activators can in the usual amount range, preferably in amounts of 1 wt .-% to 10 wt .-%, in particular 2 wt .-% to 8 wt .-%, based on total agent, be included.

additionally to the conventional bleach activators listed above or in their place may also be sulfonimines and / or bleach-enhancing transition metal salts or transition metal complexes as so-called Be included bleach catalysts. Among the candidate transition metal compounds In particular, manganese, iron, cobalt, ruthenium or molybdenum-salt complexes and their N-analogues, Manganese, iron, cobalt, ruthenium or molybdenum carbonyl complexes, manganese, Iron, cobalt, ruthenium, molybdenum, titanium, vanadium and copper complexes with nitrogen-containing tripod ligands, cobalt, Iron, copper and ruthenium-ammine complexes. Combinations of bleach activators and transition metal bleach catalysts also be used. Bleach-enhancing transition metal complexes, in particular with the central atoms Mn, Fe, Co, Cu, Mo, V, Ti and / or Ru, may be in usual quantities, preferably in an amount up to 1% by weight, in particular from 0.0025% by weight to 0.25 Wt .-% and particularly preferably from 0.01 wt .-% to 0.1 wt .-%, respectively based on total resources.

When Enzymes useful in the compositions are those of the class of Proteases, cutinases, amylases, pullulanases, hemicellulases, cellulases, Lipases, oxidases and peroxidases and mixtures thereof in question. Particularly suitable are fungi or bacteria, such as Bacillus subtilis, Bacillus licheniformis, Streptomyces griseus, Humicola lanuginosa, Humicola insolens, Pseudomonas pseudoalcaligenes or Pseudomonas cepacia derived enzymatic agents. The optionally used enzymes can be adsorbed to carriers and / or embedded in encasing substances to counter them Protect premature inactivation. They are if desired in the agents according to the invention preferably in amounts not exceeding 5% by weight, in particular of 0.2% by weight up to 2% by weight.

The Agents can as optical brighteners, for example, derivatives the Diaminostilbendisulfonsäure or their alkali metal salts contain. For example, salts of 4,4'-bis (2-anilino-4-morpholino-1,3,5-triazinyl-6-amino) stilbene-2,2'-disulfonic acid are suitable or similar compounds, instead of the morpholino group a diethanolamino group, a methylamino group, an anilino group or carry a 2-methoxyethylamino group. Furthermore you can Brighteners of the type of substituted diphenylstyrene may be present for example, the alkali salts of 4,4'-bis (2-sulfostyryl) -diphenyl, 4,4'-bis (4-chloro-3-sulfostyryl) -diphenyl or 4- (4-chlorostyryl) -4 '- (2-sulfostyryl) -diphenyls. Also mixtures The aforementioned brightener can be used.

To The suitable foam inhibitors include, for example Organopolysiloxanes and their mixtures with microfine, optionally Silanized silica and Pa-raffinwachse and their Mixtures with silanated silica or bis-fatty acid alkylenediamides. With advantages are also mixtures of different foam inhibitors used, for example, those of silicones, paraffins or waxes. Preferably, the foam inhibitors, in particular silicone and / or Paraffin-containing foam inhibitors, on a granular, in water soluble or dispersible carrier substance bound. In particular, mixtures of paraffin waxes are and bistearylethylenediamides are preferred.

additionally the means may also contain components which and fatsauswaschbarkeit from textiles positively affect, so-called soil release agents. This effect becomes particularly clear when a textile is dirty, which has been repeatedly with a agent according to the invention containing these oil and fat-dissolving component, washed has been. Among the preferred oil and fat dissolving Components include, for example, nonionic cellulose ethers such as methylcellulose and methylhydroxypropylcellulose with a proportion to methoxyl groups of 15 to 30 wt .-% and to hydroxypropoxyl groups from 1 to 15% by weight, based in each case on the nonionic cellulose ether, as well as the known from the prior art polymers of phthalic acid and / or terephthalic acid or derivatives thereof monomeric and / or polymeric diols, in particular polymers of ethylene terephthalates and / or polyethylene glycol terephthalates or anionic and / or nonionically modified derivatives of these.

The Agents may also be color transfer inhibitors, preferably in amounts of 0.1 wt .-% to 2 wt .-%, in particular 0.1 wt .-% to 1 wt .-%, which in a preferred embodiment of the Invention Polymers of vinylpyrrolidone, vinylimidazole, vinylpyridine-N-oxide or copolymers of these. Useful are both polyvinyl pyrrolidones with molecular weights of 15,000 to 50,000 as well as polyvinylpyrrolidones with molecular weights above 1 000 000, in particular from 1 500 000 to 4,000,000, N-vinylimidazole / N-vinylpyrrolidone copolymers, Polyvinyloxazolidones, copolymers based on vinyl monomers and Carbonsäureamiden, pyrrolidone group-containing polyester and Polyamides, grafted polyamidoamines and polyethyleneimines, polymers with amide groups from secondary amines, polyamine N-oxide polymers, Polyvinyl alcohols and copolymers based on acrylamidoalkenylsulfonic acids. But can also be used enzymatic systems, comprising a peroxidase and hydrogen peroxide or a hydrogen peroxide-yielding substance in water. The addition a mediator compound for the peroxidase, for example an acetosyringone, a phenol derivative or a phenotiazine or phenoxazine, is preferred in this case, in addition to above-mentioned polymeric dye transfer inhibiting agents can be used. Polyvinylpyrrolidone points to Use in agents according to the invention preferably an average molecular weight in the range of 10 000 to 60 000, especially in the range of 25,000 to 50,000. Among the copolymers are those of vinylpyrrolidone and vinylimidazole in the molar ratio 5: 1 to 1: 1 with an average molecular weight in the range of 5,000 to 50,000, in particular 10,000 to 20,000 are preferred.

graying have the task of removing the dirt from the textile fiber to keep suspended in the fleet. These are water-soluble Colloids mostly organic nature suitable, such as starch, Glue, gelatin, salts of ether carboxylic acids or ether sulfonic acids starch or cellulose or salts of acidic sulfuric acid esters cellulose or starch. Also water-soluble, Acidic group-containing polyamides are for this purpose suitable. Furthermore, other than the above-mentioned starch derivatives can be used use, for example, aldehyde levels. Preferred may Cellulose ethers, such as carboxymethyl cellulose (Na salt), methyl cellulose, Hydroxyalkylcellulose and mixed ethers, such as methylhydroxyethylcellulose, Methylhydroxypropylcellulose, methylcarboxymethylcellulose and their Mixtures, for example in amounts of 0.1 to 5 wt .-%, based on the means to be used.

To in the inventive compositions, in particular if they are in liquid or pasty form, usable organic solvents Alcohols having 1 to 4 carbon atoms, in particular methanol, ethanol, isopropanol and tert-butanol, diols having 2 to 4 C atoms, in particular ethylene glycol and propylene glycol, as well as mixtures thereof and those mentioned Classes of derivable ether. Such water-miscible Solvents are in the inventive Preferably in amounts of not more than 30% by weight, in particular from 6% to 20% by weight.

to Setting a desired, through the mixture the remaining components are not self-generating pH the agents according to the invention can be and environmentally friendly acids, in particular citric acid, Acetic acid, tartaric acid, malic acid, lactic acid, Glycolic acid, succinic acid, glutaric acid and / or adipic acid, but also mineral acids, in particular sulfuric acid, or bases, in particular ammonium or alkali hydroxides. Such pH regulators are in the agents according to the invention preferably not over 20 wt .-%, in particular from 1.2 wt .-% to 17 wt .-%, contain.

The Preparation of solid inventive means prepares no difficulties and can be known in principle, for example by spray-drying or granulation, optional Peroxygen compound and optional bleach catalyst optionally be added later. For the production according to the invention Agents with increased bulk density, in particular in the range of 650 g / l to 950 g / l, is an extrusion step preferred method. The production of liquid also means according to the invention Difficulties and can also be done in a known manner.

According to one preferred embodiment, the inventive Teaching to be used, the perfume part in washing, Significantly reduce cleaning and personal care products. This makes it possible to perfumed products as well to offer for such particularly sensitive consumers the normally perfumed products due to special incompatibilities and irritation only limited or not use can. In this context are mainly skin care products and deodorants, but also detergents, such as. B. Hand wash to call.

• – Aniontenside, wie vorzugsweise Alkylbenzolsulfonat, Alkylsulfat, z. B. in Mengen von vorzugsweise 5–30 Gew.-%
• – Nichtionische Tenside, wie vorzugsweise Fettalkoholpolyglycolether, Alkylpolyglucosid, Fettsäureglucamid z. B. in Mengen von vorzugsweise 0,5–15 Gew.-%
• – Gerüststoffe, wie z. B. Zeolith, Polycarboxylat, Natriumcitrat, in Mengen von z. B. 0–70 Gew.-%, vorteilhafterweise 5–60 Gew.-%, vorzugsweise 10–55 Gew.-%, insbesondere 15–40 Gew.-%,
• – Alkalien, wie z. B. Natriumcarbonat, in Mengen von z. B. 0–35 Gew.-% vorteilhafterweise 1–30 Gew.-%, vorzugsweise 2–25 Gew.-%, insbesondere 5–20 Gew.-%,
• – Bleichmittel, wie z. B. Natriumperborat, Natriumpercarbonat, in Mengen von z. B. 0–30 Gew.-% vorteilhafterweise 5–25 Gew.-%, vorzugsweise 10–20 Gew.-%,
• – Korrosionsinhibitoren, z. B. Natriumsilicat, in Mengen von z. B. 0–10 Gew.-%, vorteilhafterweise 1–6 Gew.-%, vorzugsweise 2–5 Gew.-%, insbesondere 3–4 Gew.-%,
• – Stabilisatoren, z. B. Phosphonate, vorteilhafterweise 0–1 Gew.-%,
• – Schauminhibitor, z. B. Seife, Siliconöle, Paraffine vorteilhafterweise 0–4 Gew.-%, vorzugsweise 0,1–3 Gew.-%, insbesondere 0,2–1 Gew.-%,
• – Enzyme, z. B. Proteasen, Amylasen, Cellulasen, Lipasen, vorteilhafterweise 0–2 Gew.-%, vorzugsweise 0,2–1 Gew.-%, insbesondere 0,3–0,8 Gew.-%,
• – Vergrauungsinhibitor, z. B. Carboxymethylcellulose, vorteilhafterweise 0–1 Gew.-%,
• – Verfärbungsinhibitor, z. B. Polyvinylpyrrolidon-Derivate, vorzugsweise 0–2 Gew.-%,
• – Stellmittel, z. B. Natriumsulfat, vorteilhafterweise 0–20 Gew.-%,
• – Optische Aufheller, z. B. Stilben-Derivat, Biphenyl-Derivat, vorteilhafterweise 0–0,4 Gew.-%, insbesondere 0,1–0,3 Gew.-%,
• – ggf. weitere Duftstoffe
• – ggf. Wasser
• – ggf. Seife
• – ggf. Bleichaktivatoren
• – ggf. Cellulosderivate
• – ggf. Schmutzabweiser, Gew.-% jeweils bezogen auf das gesamte Mittel.

A preferred solid, in particular powdered, detergent according to the invention may contain, in addition to the constituents according to the invention (ie, (a) fragrant aldehydes and (b) (optionally substituted) ethylenediamines and / or (optionally substituted) propylenediamines) components which, for. B. are selected from the following:

• - Aniontenside, such as preferably alkylbenzenesulfonate, alkyl sulfate, z. B. in amounts of preferably 5-30 wt .-%
• Nonionic surfactants, such as preferably fatty alcohol polyglycol ethers, alkylpolyglucoside, fatty acid glucamide z. B. in amounts of preferably 0.5-15 wt .-%
• - builders, such. As zeolite, polycarboxylate, sodium citrate, in amounts of z. B. 0-70 wt .-%, advantageously 5-60 wt .-%, preferably 10-55 wt .-%, in particular 15-40 wt .-%,
• - Alkalis, such as. For example, sodium carbonate, in amounts of z. B. 0-35 wt .-% advantageously 1-30 wt .-%, preferably 2-25 wt .-%, in particular 5-20 wt .-%,
• - Bleaching agents, such as. For example, sodium perborate, sodium percarbonate, in amounts of z. B. 0-30 wt .-% advantageously 5-25 wt .-%, preferably 10-20 wt .-%,
• - corrosion inhibitors, z. For example, sodium silicate, in amounts of z. B. 0-10 wt .-%, advantageously 1-6 wt .-%, preferably 2-5 wt .-%, in particular 3-4 wt .-%,
• - Stabilizers, z. As phosphonates, advantageously 0-1 wt .-%,
• Foam inhibitor, e.g. As soap, silicone oils, paraffins advantageously 0-4 wt .-%, preferably 0.1-3 wt .-%, in particular 0.2-1 wt .-%,
• - enzymes, eg. B. proteases, amylases, cellulases, lipases, advantageously 0-2 wt .-%, preferably 0.2-1 wt .-%, in particular 0.3-0.8 wt .-%,
• - Grayness inhibitor, z. B. carboxymethylcellulose, advantageously 0-1 wt .-%,
• - Discoloration inhibitor, z. B. polyvinylpyrrolidone derivatives, preferably 0-2 wt .-%,
• - Adjusting agent, z. For example, sodium sulfate, advantageously 0-20 wt .-%,
• - Optical brightener, z. B. stilbene derivative, biphenyl derivative, advantageously 0-0.4 wt .-%, in particular 0.1-0.3 wt .-%,
• - If necessary, other fragrances
• - If necessary water
• - if necessary, soap
• - optionally bleach activators
• - If necessary, cellulose derivatives
• - If necessary, dirt deflector, wt .-% in each case based on the total agent.

In another preferred embodiment of the invention is the washing, cleaning or care product in liquid Form before, preferably in gel form. Preferred liquid Washing, cleaning or care products have water contents of z. B. 10-95 wt .-%, preferably 20-80 wt .-% and in particular 30-70% by weight, based on the total agent. In the case of liquid concentrates, the water content also be particularly low, z. B. <30 Wt .-%, preferably <20 Wt .-%, in particular <15 Wt .-%, wt .-% in each case based on the total mean. The liquid agents may also be nonaqueous Solvent included.

• – Aniontenside, wie vorzugsweise Alkylbenzolsulfonat, Alkylsulfat, z. B. in Mengen von vorzugsweise 5–40 Gew.-%
• – Nichtionische Tenside, wie vorzugsweise Fettalkoholpolyglycolether, Alkylpolyglucosid, Fettsäureglucamid z. B. in Mengen von vorzugsweise 0,5–25 Gew.-%
• – Gerüststoffe, wie z. B. Zeolith, Polycarboxylat, Natriumcitrat, vorteilhafterweise 0–15 Gew.-%, vorzugsweise 0,01–10 Gew.-%, insbesondere 0,1–5 Gew.-%,
• – Schauminhibitor, z. B. Seife, Siliconöle, Paraffine, in Mengen von z. B. 0–10 Gew.-%, vorteilhafterweise 0,1–4 Gew.-%, vorzugsweise 0,2–2 Gew.-%, insbesondere 1–3 Gew.-%,
• – Enzyme, z. B. Proteasen, Amylasen, Cellulasen, Lipasen, in Mengen von z. B. 0–3 Gew.-%, vorteilhafterweise 0,1–2 Gew.-%, vorzugsweise 0,2–1 Gew.-%, insbesondere 0,3–0,8 Gew.-%,
• – Optische Aufheller, z. B. Stilben-Derivat, Biphenyl-Derivat, in Mengen von z. B. 0–1 Gew.-%, vorteilhafterweise 0,1–0,3 Gew.-%, insbesondere 0,1–0,4 Gew.-%,
• – ggf. weitere Duftstoffe
• – ggf. Stabilisatoren,
• – Wasser
• – ggf. Seife, in Mengen von z. B. 0–25 Gew.-%, vorteilhafterweise 1–20 Gew.-%, vorzugsweise 2–15 Gew.-%, insbesondere 5–10 Gew.-%,
• – ggf. Lösungsmittel (vorzugsweise Alkohole), vorteilhafterweise 0–25 Gew.-%, vorzugsweise 1–20 Gew.-%, insbesondere 2–15 Gew.-%, Gew.-% jeweils bezogen auf das gesamte Mittel.

A preferred liquid, in particular gel detergent according to the invention may contain, in addition to the constituents according to the invention, in particular still components which z. B. are selected from the following:

• - Aniontenside, such as preferably alkylbenzenesulfonate, alkyl sulfate, z. B. in amounts of preferably 5-40 Wt .-%
• Nonionic surfactants, such as preferably fatty alcohol polyglycol ethers, alkylpolyglucoside, fatty acid glucamide z. B. in amounts of preferably 0.5-25 wt .-%
• - builders, such. B. zeolite, polycarboxylate, sodium citrate, advantageously 0-15 wt .-%, preferably 0.01-10 wt .-%, in particular 0.1-5 wt .-%,
• Foam inhibitor, e.g. As soap, silicone oils, paraffins, in amounts of z. B. 0-10 wt .-%, advantageously 0.1-4 wt .-%, preferably 0.2-2 wt .-%, in particular 1-3 wt .-%,
• - enzymes, eg. As proteases, amylases, cellulases, lipases, in amounts of z. B. 0-3 wt .-%, advantageously 0.1-2 wt .-%, preferably 0.2-1 wt .-%, in particular 0.3-0.8 wt .-%,
• - Optical brightener, z. B. stilbene derivative, biphenyl derivative, in amounts of z. B. 0-1 wt .-%, advantageously 0.1-0.3 wt .-%, in particular 0.1-0.4 wt .-%,
• - If necessary, other fragrances
• - stabilizers if necessary,
• - Water
• - If necessary, soap, in quantities of z. B. 0-25 wt .-%, advantageously 1-20 wt .-%, preferably 2-15 wt .-%, in particular 5-10 wt .-%,
• - If necessary, solvents (preferably alcohols), advantageously 0-25 wt .-%, preferably 1-20 wt .-%, in particular 2-15 wt .-%, wt .-% in each case based on the total agent.

• – Kationische Tenside, wie insbesondere Esterquats, z. B. in Mengen von 5–30 Gew.-%,
• – Cotenside, wie z. B. Glycerolmonostearat, Stearinsäure, Fettalkohole, Fettalkoholethoxylate, z. B. in Mengen von 0–5 Gew.-%, vorzugsweise 0,1–4 Gew.-%,
• – Emulgatoren, wie z. B. Fettaminethoxylate, z. B. in Mengen von 0–4 Gew.-%, vorzugsweise 0,1–3 Gew.-%,
• – ggf. weitere Duftstoffe
• – Farbstoffe, vorzugsweise im ppm-Bereich
• – Stabilisatoren, vorzugsweise im ppm-Bereich
• – Lösemittel, wie insbesondere Wasser, in Mengen von vorzugsweise 60–90 Gew.-%,
• – Gew.-% jeweils bezogen auf das gesamte Mittel.

In addition to the constituents according to the invention, a preferred liquid softener according to the invention may in particular also contain components which are selected from the following:

• - Cationic surfactants, such as in particular esterquats, z. In amounts of 5-30% by weight,
• - cosurfactants, such as. As glycerol monostearate, stearic acid, fatty alcohols, fatty alcohol ethoxylates, eg. In amounts of 0-5% by weight, preferably 0.1-4% by weight,
• - emulsifiers, such as. B. fatty amine ethoxylates, e.g. In amounts of 0-4 wt.%, Preferably 0.1-3 wt.%,
• - If necessary, other fragrances
• - Dyes, preferably in the ppm range
• Stabilizers, preferably in the ppm range
• Solvents, in particular water, in amounts of preferably 60-90% by weight,
• -% by weight, based in each case on the total agent.

Example:

It was the fragrance effect of a commercial particulate Detergent containing 0.9 wt .-% Octanal examined. This corresponds to the detergent A.

Also was the scent effect of an otherwise comparable commercial particulate detergent examined, which also Contains 0.9 wt .-% octanal and also still 1.4 wt .-% N, N'-dimethylethylenediamine. This corresponds to the detergent B.

to Examination of the scent effect of detergents A and B were washing tests in a commercial washing machine (Miele washing machine Type W 1734 WPS; Laundry: cotton textiles and half linen in quantity of 3.0 kg; Main wash program at 40 ° C).

The washed laundry was subsequently a panel presented by 7 olfactory people, the intensity the laundry smell in the wet state as well as in the dry Condition (7 days after the wash) valued. For checking the laundry smell after 7 days, the wet laundry was previously dried on a leash and combined after drying and kept in an open shelf until 7 days since the wash had passed.

The intensity was rated by each evaluator on a scale of 1 to 6, where the value 1 stands for a fragrance that is only slightly perceptible, while the value 6 stands for a very intense fragrance. The evaluation was repeated twice. From the total ratings, the average value was finally calculated. The following average values were obtained: Scent intensity of wet laundry Intensity of dry laundry after 7 days Detergent A 5.3 1.5 Detergent B 4.1 4.1

The Detergent B consistent with the invention resulted thus significantly improved compared to Detergent A. Fragrance intensity in the dry laundry after 7 Days.

As well was the scent effect of a commercial liquid Softener examined, which contained 0.9 wt .-% octanal. This corresponds to the softener A. Also, the Odor effect of an otherwise comparable commercial liquid softener, which also Contains 0.9 wt .-% octanal. This fabric softener contained also 1.4% by weight of N, N'-dimethylethylenediamine. This matches with the fabric softener B.

to Examination of the fragrance effect of fabric softeners A and B were Washing tests in a commercial washing machine (Miele Washing machine type W 1734 WPS; Laundry: cotton textiles and half linen in the amount of 3.0 kg; Main wash program at 40 ° C).

The washed laundry was subsequently turned presented to a panel of 7 odorous people, which the intensity of the laundry smell when wet and in the dry state (7 days after the wash), analogous to the investigation of the detergent, as already described.

The following average values were obtained: Scent intensity of wet laundry Intensity of dry laundry after 7 days Fabric softener A 5.7 1.7 Detergent B 4.3 3.9

Of the Softener B which was in accordance with the invention led consequently to one compared to softener A clearly improved fragrance intensity in dry laundry after 7 days.

QUOTES INCLUDE IN THE DESCRIPTION

This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.

Cited non-patent literature

• - Steffen Arctander Published 1960 and 1969, respectively, Reprinted 2000 ISBN: Aroma Chemicals Vol. 1: 0-931710-37-5, Aroma Chemicals Vol. 2: 0-931710-38-3 [0012]

Claims (15)

Washing, cleaning or care preparations containing (A) Fragrance aldehydes as well (b) (optionally substituted) ethylenediamines and / or (optionally substituted) propylenediamines. Composition according to claim 1, characterized characterized in that component (a) and component (b) are separated be added to the washing, cleaning or care matrix. Means according to one of the claims 1 or 2, characterized in that as component (b) 1,2-diaminoethane, Propane-1,3-diamine, 1,2-dianilinoethane, N, N'-dimethylethylenediamine, N, N'-diethylethyl-1,3-diamine, N, N'-diisopropylethyl-1,3-diamine, N, N'-dimethylpropane-1,3-diamine, N, N'-diethylpropane-1,3-diamine and / or N, N'-diisopropylpropane-1,3-diamine is used. Means according to one of the claims 1 to 3, characterized in that as component (a) a fragrance aldehyde selected from Adoxal, anisaldehyde, Cymal, Ethylvanillin, Florhydral, Helional, Heliotropin, Hydroxycitronellal, Koavon, Lauraldehyde, Lyral, Methylnonylacetaldehyde, P.T. Bucinal, Phenylacetaldehyde, undecylenaldehyde, vanillin, 2,6,10-trimethyl-9-undecenal, 3-dodecene-1-al, alpha-n-amylcinnamaldehyde, 4-methoxybenzaldehyde, benzaldehyde, 3- (4-tert-butylphenyl) -propanal, 2-methyl-3- (para-methoxyphenyl) propanal, 2-methyl-4- (2,6,6-timethyl-2 (1) -cyclohexen-1-yl) butanal, 3-phenyl-2-propenal, cis- / trans-3,7-dimethyl-2,6-octadiene-1-al, 3,7-dimethyl-6-octene-1-al, [(3,7-dimethyl-6-octenyl) oxy] acetaldehyde, 4-isopropylbenzyl aldehyde, 1,2,3,4,5,6,7,8-octahydro-8,8-dimethyl-2-naphthaldehyde, 2,4-dimethyl-3-cyclohexene-1-carboxaldehyde, 2-methyl-3- (isopropylphenyl) propanal, 1-decanal, decyl aldehyde, 2,6-dimethyl-5-heptenal, 4- (tricyclo [5.2.1.0 (2,6)] decylidene-8) -butanal, octahydro-4,7-methane-1H-indenecarboxaldehyde, 3-ethoxy-4-hydroxybenzaldehyde, para-ethyl-alpha, alphadimethylhydrocinnamaldehyde, alpha-methyl-3,4- (methylenedioxy) -hydrocinnamaldehyde, 3,4-methylenedioxybenzaldehyde, alpha-n-hexylcinnamic aldehyde, m-cymene-7-carboxaldehyde, alpha-methylphenylacetaldehyde, 7-hydroxy-3,7-dimethyloctanal, undecenal, 2,4,6-trimethyl-3-cyclohexene-1-carboxaldehyde, 4- (3) (4-methyl-3-pentenyl) -3-cyclohexene-carboxaldehyde, 1-dodecanal, 2,4-dimethylcyclohexene-3-carboxaldehyde, 4- (4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde, 7-methoxy-3,7-dimethyloctane-1-al 2-methylundecanal, 2-methyldecanal, 1-nonanal, 1-octanal, 2,6,10-trimethyl-5,9-undecadienal, 2-methyl-3- (4-tert-butyl) propanal, Dihydrocinnamaldehyde, 1-methyl-4- (4-methyl-3-pentenyl) -3-cyclohexene-1-carboxaldehyde, 5- or 6-methoxyhexahydro-4,7-methanindane-1 or 2-carboxaldehyde, 3,7-dimethyloctan-1-al, 1-undecanal, 10-undecene-1-al, 4-hydroxy-3-methoxybenzaldehyde, 1-methyl-3- (4-methylpentyl) -3-cyclohexenecarboxaldehyde, 7-hydroxy-3,7-dimethyl-octanal, trans-4-decenal, 2,6-nonadienal, para-tolylacetaldehyde, 4-methylphenylacetaldehyde, 2-methyl-4- (2,6,6-trimethyl-1-cyclohexen-1-yl) -2-butenal, ortho-methoxycinnamaldehyde, 3,5,6-trimethyl-3-cyclohexene carboxaldehyde, 3,7-dimethyl-2-methylene-6-octenal, phenoxyacetaldehyde, 5,9-dimethyl-4,8-decadienal, peonyaldehyde (6,10-dimethyl-3-oxa-5,9-undecadiene-1-al), Hexahydro-4,7-methanindane-1-carboxaldehyde, 2-methyloctanal, alpha-methyl-4- (1-methylethyl) benzene-acetaldehyde, 6,6-dimethyl-2-norpinen-2-propionaldehyde, para-methylphenoxyacetaldehyde, 2-methyl-3-phenyl-2-propene-1-al 3,5,5-trimethylhexanal, hexahydro-8,8-dimethyl-2-naphthaldehyde, 3-propylbicyclo [2.2.1] hept-5-ene-2-carbaldehyde, 9-decenal, 3-methyl-5-phenyl-1-pentanal, Methylnonylacetaldehyde, hexanal, trans-2-hexenal, 1-p-menthene-q-carboxaldehyde or mixtures thereof. Means according to one of the claims 1 to 4, characterized in that the component (b) in quantities from 0.001% to 3% by weight in the agent on the entire remedy. Means according to one of the claims 1 to 5, characterized in that it contains from 0.001% to 3% by weight Fragrance aldehydes, wt .-% based on the total agent. Means according to one of the claims 1 to 6, characterized in that the ratio of Component (a) to component (b) is 25: 1 to 1: 5. Means according to one of the claims 1 to 7, characterized in that the total amount of fragrance of the agent is 0.01 to 10 wt .-%. Means according to any one of claims 1-8, characterized in that it is in solid form, preferably in powder form. Means according to any one of claims 1-8, characterized in that it is in liquid form, preferably in gel form. Agent according to one of claims 1-10, characterized in that it is at least 5% by weight, preferably contains at least 8 wt .-%, in particular at least 10 wt .-% surfactant, in particular anionic surfactant and / or nonionic surfactant. Textile cleaning or conditioning process, at which the textile to be cleaned textile laundry under Use of a washing, cleaning or care product after one of claims 1-11 is subjected, in particular in an automatic washing machine. Use of a washing, cleaning or care product according to any one of claims 1-12 for cleaning and / or Conditioning of textile fabrics, in particular in an automatic washing machine. Use of (optionally substituted) ethylenediamine and / or (optionally substituted) propylene diamine as separately added Component in perfume-containing washing, cleaning or care products, which contain fragrance aldehyde, to prolong the Odor effect of the washing, cleaning or care agent. Use of (optionally substituted) ethylenediamine and / or (optionally substituted) propylene diamine as separately added Component in perfume-containing washing, cleaning or care products, which contain fragrance aldehyde to achieve a long-lasting Fresh smell when using the washing, cleaning or care product.