DE102009001569A1 - Lilial substitute - Google Patents

Abstract

According to recent findings, Lilial may have a mutagenic potential, according to which classification according to the EU classification criteria could be recommended as category 3 (M: 3). Due to the toxicological concerns, it is a concern in the sense of preventive consumer protection to replace this substance (Lilial) with other, less problematic fragrances or fragrances without losing their perfumery and quality. This was achieved through the use of certain fragrance compositions.

Description

The The present invention relates to a fragrance composition with which one can replace the toxicologically controversial Lilial equivalent. It also concerns their use for producing a lily of the valley fragrance. Further concerns various means, such as detergents and cleaners, which comprise such a fragrance composition.

a lot of perfumes are added to technical and household products, to mask their unpleasant odor and / or these To olfactorize products or objects treated with them. For detergents and cleaners is in addition to the self-scented the Product also the overlap disturbing In addition to odors very much desired from the wash liquors, In particular, however, is the scenting of the substrates to be treated of great Importance. The selection of the fragrances and their composition depends It all depends on what association it caused in the application shall be. For example, it can be used by all means to do with washing or cleaning, be beneficial, flowery To include notes in the composition, as these a variety Consumers have particularly positive feelings of spring freshness as well To provide care. Floral notes (flower notes) or scents (flower scents) are in widespread in nature. Known examples are z. Jasmine, Lilac, rose, iris or violet. The mixture of different floral notes will be in perfumery Called a bouquet. With a bouquet of floral notes, especially the Care properties of a product to be scented. A very popular floral fragrance is the one of the lily of the valley. A lily of the valley scent with high consumer acceptance and good stability in many Products is the Lilial (CAS 80-54-6; 3- (4-tert-butylphenyl) -2-methylpropanal). Lilial is used in technical products such as laundry detergents used as a fragrance, and produces a very desired and pleasant lily of the valley scent note. Lilial lets herself also good in technical products, such as detergents and cleaners work and is in these over stable over a wide pH range. In addition, it has a good substantivity, so allows a long-lasting scent effect. But Lilial points to new findings possibly a mutagenic potential, according to which it should be classified as a category according to the EU classification criteria 3 (M: 3) could be classified. For CMR substances (CMR = carcinogen, mutagen, reproductive toxicity) of the category 3 must be demonstrated that the quantities used for the consumer are harmless. Because of the toxicological concerns it is a concern in the sense of a preventive consumer protection, this Fabric (Lilial) by other, less problematic fragrances or fragrances exchange.

Therefore It was the task given to this invention, a lilial surrogate so that in typical product applications, such as for washing and cleaning agents, for the use of Lilial at least partly, preferably completely can be dispensed with, without any perfumery and creative power quality to lose.

• (a) 3-(4-tert-Butylphenyl)propionaldehyd (Bourgeonal) (vorzugsweise in Mengen von 0,01–99 Gew.-%, vorteilhafterweise 0,01–40 Gew.-%, insbesondere von 0,1–20 Gew.-%),
• (b) 2-Methyl-4-phenylbutan-2-ol (Dimethylphenylethylcarbinol) (vorzugsweise in Mengen von 0,01–99 Gew.-%, vorteilhafterweise in Mengen von 0,01–20 Gew.-%, insbesondere von 0,01–15 Gew.-%).
• (c) cis-4-(Isopropyl)cyclohexanemethanol (Mayol) (vorzugsweise in Mengen von 0,01–99 Gew.-%, vorteilhafterweise in Mengen von 0,01–20 Gew.-%, insbesondere von 0,5–15 Gew.-%),
• (d) 1-(1-hydroxyethyl)-4-(1-methylethyl)cyclohexan (Mischung der Diastereoisomeren) (Mugetanol) (vorzugsweise in Mengen von 0,01–99 Gew.-%, vorteilhafterweise in Mengen von 0,01–90 Gew.-%, insbesondere von 0,5–40 Gew.-%),
• (e) (4-Methyl-3-pentenyl)cyclohexenecarbaldehyd (Citrusal) (vorzugsweise in Mengen von 0,01–99 Gew.-%, vorteilhafterweise in Mengen von 0,01–40 Gew.-%, insbesondere von 0,1–20 Gew.-%),
• (f) 3-(p-(2-Methylpropyl)phenyl)-2-methylpropionaldehyd (Silvial) (vorzugsweise in Mengen von 0,01–99 Gew.-%, vorteilhafterweise in Mengen von 0,1–90 Gew.-%, insbesondere von 1–40 Gew.-%),
• (g) 3-p-Cumenyl-2-methylpropionaldehyd (Cyclamenaldehyd) (vorzugsweise in Mengen von 0,01–99 Gew.-%, vorteilhafterweise in Mengen von 0,1–90 Gew.-%, insbesondere von 1–40 Gew.-%),
• (h) mixture of: cis-tetrahydro-2-isobutyl-4-methylpyran-4-ol; trans-tetrahydro-2-isobutyl-4-methylpyran-4-ol; (Florol) (vorzugsweise in Mengen von 0,01–99 Gew.-%, vorteilhafterweise in Mengen von 0,1–40 Gew.-%, insbesondere von 1–40 Gew.-%),

This object has been achieved by a fragrance composition containing at least 1 component selected from

• (a) 3- (4-tert-butylphenyl) propionaldehyde (Bourgeonal) (preferably in amounts of 0.01-99 wt .-%, advantageously 0.01-40 wt .-%, in particular of 0.1-20 wt .-%),
• (b) 2-methyl-4-phenylbutan-2-ol (dimethylphenylethylcarbinol) (preferably in amounts of 0.01-99% by weight, advantageously in amounts of 0.01-20% by weight, in particular of 0, 01-15% by weight).
• (c) cis-4- (isopropyl) cyclohexanemethanol (Mayol) (preferably in amounts of 0.01-99% by weight, advantageously in amounts of 0.01-20% by weight, in particular of 0.5-15 wt .-%),
• (d) 1- (1-hydroxyethyl) -4- (1-methylethyl) cyclohexane (mixture of diastereoisomers) (mugetanol) (preferably in amounts of 0.01-99% by weight, advantageously in amounts of 0.01%). 90% by weight, in particular from 0.5-40% by weight),
• (e) (4-Methyl-3-pentenyl) cyclohexenecarbaldehyde (Citrusal) (preferably in amounts of 0.01-99 wt .-%, advantageously in amounts of 0.01-40 wt .-%, in particular of 0.1 -20% by weight),
• (f) 3- (p- (2-methylpropyl) phenyl) -2-methylpropionaldehyde (silvial) (preferably in amounts of 0.01-99% by weight, advantageously in amounts of 0.1-90% by weight , in particular from 1-40% by weight),
• (g) 3-p-Cumenyl-2-methylpropionaldehyde (cyclamenaldehyde) (preferably in amounts of 0.01-99% by weight, advantageously in amounts of 0.1-90% by weight, in particular 1-40% by weight .-%),
• (h) mixture of: cis -tetrahydro-2-isobutyl-4-methyl-pyran-4-ol; trans-tetrahydro-2-isobutyl-4-methyl-pyran-4-ol; (Florol) (preferably in amounts of 0.01-99 wt .-%, advantageously in amounts of 0.1-40 wt .-%, in particular 1-40 wt .-%),

The perfume composition may consist entirely of one or more of components (a) to (h). It is preferred that the fragrance composition according to the invention at least 2, preferably at at least 3, advantageously at least 4, more preferably at least 5, more preferably contains at least 6 components from group (a) to (h), in particular contains all components (a) to (h).

It a particular advantage of this invention is that said perfume composition a particularly substantive and long-lasting lily-of-the-valley fragrance especially when using Citrusal, Silvila, Borgeonal, Mugetanol, cyclamenaldehyde and / or mayol, especially related with the application in the field of textile washing and care as well as in the cosmetic Area, but also in the so-called air-care sector. The named Fragrance composition can be stable in the various compositions the textile laundry and care as well of the cosmetic sector and the air care sector become. The fragrance composition mentioned is toxicologically less problematic as the Lilial to be replaced. It is an advantage of the invention that the perfume composition according to the invention, alone and in mixture with other fragrances, a fragrance-enhancing Effect, d. H. the entire scent impression on scented Object becomes more intense and he stops longer at.

• (i) 6-Methoxy-2,6-dimethylheptan-1-al (Methoxymelonal) (vorzugsweise in Mengen von 0,01–10 Gew.-%, insbesondere von 0,01–5 Gew.-%),
• (j) 5,9-Dimethyl-4,8-decadienal (Geraldehyde) (vorzugsweise in Mengen von 0,01–10 Gew.-%, insbesondere von 0,01–5 Gew.-%),
• (k) beta.-methyl-3-(1-methylethyl)benzenepropanal (Florhydral) (vorzugsweise in Mengen von 0,01–10 Gew.-%, insbesondere von 0,01–5 Gew.-%),
• (l) Octahydro-8,8-dimethylnaphthalene-2-carbaldehyd (Cyclomyral) (vorzugsweise in Mengen von 0,01–10 Gew.-%, insbesondere von 0,01–5 Gew.-%),
• (m) alpha.-Methyl-1,3-benzodioxole-5-propionaldehyd (Helional) (vorzugsweise in Mengen von 0,01–20 Gew.-%, insbesondere von 0,01–5 Gew.-%),
• (n) 5-Methyl-2-(1-methylbutul)-5-propyl-1,3-dioxan (Troenan) (vorzugsweise in Mengen von 0,01–10 Gew.-%, insbesondere von 0,01–5 Gew.-%),
• (o) 3-(o-Ethylphenyl)-2,2-dimethylpropionaldehyd (Floralozone) (vorzugsweise in Mengen von 0,01–10 Gew.-%, insbesondere von 0,01–5 Gew.-%),
• (p) Farnesol (vorzugsweise in Mengen von 0,01–30 Gew.-%, insbesondere von 0,01–5 Gew.-%),
• (q) 3,7,11-Trimethyldodeca-1,6,10-trien-3-ol, (gemischte Isomere) (Nerolidol) (vorzugsweise in Mengen von 0,01–50 Gew.-%, insbesondere von 0,01–40 Gew.-%),
• (r) Cyclohexylsalicylat (vorzugsweise in Mengen von 0,01–20 Gew.-%, insbesondere von 0,1–10 Gew.-%),
• (s) Hexylsalicylat (vorzugsweise in Mengen von 0,01–20 Gew.-%, insbesondere von 0,1–10 Gew.-%),
• (t) Benzylsalicylat (vorzugsweise in Mengen von 0,01–20 Gew.-%, insbesondere von 0,1–10 Gew.-%),
• (u) Amylsalicylat (vorzugsweise in Mengen von 0,01–20 Gew.-%, insbesondere von 1–10 Gew.-%),
• (v) Triethylcitrat (vorzugsweise in Mengen von 1–90 Gew.-%, insbesondere von 5–80 Gew.-%) und/oder
• (w) Dipropylenglycol (vorzugsweise in Mengen von 1–90 Gew.-%, insbesondere von 5–80 Gew.-%), Gew.-% jeweils bezogen auf die Gesamtmenge der Duftstoffkomposition.

According to a further preferred embodiment of the invention, a preferred perfume composition is characterized in that it contains at least 2, preferably at least 4, advantageously at least 6, more preferably at least 8, even more advantageously at least 10 components from group (i) to (w):

• (i) 6-methoxy-2,6-dimethylheptan-1-al (methoxymelonal) (preferably in amounts of 0.01-10% by weight, especially 0.01-5% by weight),
• (j) 5,9-dimethyl-4,8-decadienal (geraldehyde) (preferably in amounts of 0.01-10% by weight, especially 0.01-5% by weight),
• (k) beta-methyl-3- (1-methylethyl) benzene propropanal (Florhydral) (preferably in amounts of 0.01-10% by weight, in particular 0.01-5% by weight),
• (l) octahydro-8,8-dimethylnaphthalenes-2-carbaldehyde (cyclomyral) (preferably in amounts of 0.01-10% by weight, in particular 0.01-5% by weight),
• (m) alpha-methyl-1,3-benzodioxole-5-propionaldehyde (helional) (preferably in amounts of 0.01-20% by weight, in particular 0.01-5% by weight),
• (n) 5-methyl-2- (1-methylbutyl) -5-propyl-1,3-dioxane (troenan) (preferably in amounts of 0.01-10% by weight, especially 0.01-5% by weight) .-%),
• (o) 3- (o-ethylphenyl) -2,2-dimethylpropionaldehyde (Floralozone) (preferably in amounts of 0.01-10% by weight, in particular 0.01-5% by weight),
• (p) farnesol (preferably in amounts of 0.01-30% by weight, in particular of 0.01-5% by weight),
• (q) 3,7,11-trimethyldodeca-1,6,10-trien-3-ol, (mixed isomers) (nerolidol) (preferably in amounts of 0.01-50% by weight, especially 0.01 -40% by weight),
• (r) cyclohexyl salicylate (preferably in amounts of 0.01-20% by weight, especially 0.1-10% by weight),
• (s) hexyl salicylate (preferably in amounts of 0.01-20% by weight, in particular of 0.1-10% by weight),
• (t) benzyl salicylate (preferably in amounts of 0.01-20% by weight, especially 0.1-10% by weight),
• (u) amyl salicylate (preferably in amounts of 0.01-20% by weight, especially 1-10% by weight),
• (v) triethyl citrate (preferably in amounts of 1-90% by weight, especially 5-80% by weight) and / or
• (W) dipropylene glycol (preferably in amounts of 1-90 wt .-%, in particular 5-80 wt .-%), wt .-% in each case based on the total amount of the perfume composition.

According to one another preferred embodiment of the invention the perfume composition according to the invention Cyclamenaldehyde, Silvial and / or Mugetanol and at least 4 others Components from the group (i) to (w), preferably cyclamenaldehyde and silvial or else cyclamenaldehyde and mugetanol or else silvial and mugetanol or especially cyclamenaldehyde, silvial and Mugetanol is included. Such a fragrance composition makes it possible in particular good results regarding the intended replacement of Lilial, especially in the field of application of washing or cleaning agents, especially with regard to a pronounced substantivity of the desired Fragrance impression during or as a result of textile washing.

If the perfume composition according to the invention Citrusal, Bourgeonal and / or Mayol contains, so is another preferred embodiment of the invention. Such a fragrance composition also makes it possible good results regarding the intended replacement of Lilial, especially with regard to a pronounced substantivity of the desired Fragrance impression during or as a result of textile washing.

According to one another preferred embodiment of the invention the perfume composition according to the invention Florol and / or Dimethylphenylethylcarbinol.

wobei die Reste R, R¹, R², unabhängig voneinander, für ein Wasserstoffatom oder für einen organischen Rest, insbesondere für eine lineare oder verzweigte, substituierte oder unsubstituierte Alkyl- oder Alkylengruppe von C₁ bis C₂₀ stehen, wobei es bevorzugt ist, dass sich die Reste R¹ und R² entsprechen. Bevorzugt ist R = H oder CH₃.In a further preferred embodiment of the invention, the perfume composition according to the invention comprises an oxazolidine according to formula (I),

wherein the radicals R, R ¹ , R ² independently of one another represent a hydrogen atom or an organic radical, in particular a linear or branched, substituted or unsubstituted alkyl or alkylene group of C ₁ to C ₂₀ , it being preferred that that the radicals R ¹ and R ² correspond. Preferably R = H or CH ₃ .

genannt Silvialoxazolidin, vorzugsweise enthalten in Mengen von 0,1–90 Gew.-%, insbesondere von 1–40 Gew.-%, Gew.-% bezogen auf die Gesamtmenge der Duftstoffkomposition, so liegt eine weitere bevorzugte Ausführungsform der Erfindung vor. Vorzugsweise ist auch in der Formel (II) R = H oder CH₃. Erfindungsgemäße Duftstoffkompositionen, welche Silvialoxazolidin enthalten, ermöglichen besonders gute Ergebnisse hinsichtlich des angestrebten Ersatzes von Lilial. Ferner ermöglichen sie besonders lang anhaltende Dufterlebnisse, insbesondere bei der Textilwäsche.When an oxazolidine according to formula (I) is contained, wherein in this formula both radicals R ¹ and R ^{2 are} each an isobutyl radical [ie for (CH ₃ ) ₂ -CH-CH ₂ -], corresponding to an oxazolidine according to Formula (II)

called silvialoxazolidine, preferably in amounts of 0.1-90 wt .-%, in particular 1-40 wt .-%, wt .-% based on the total amount of the perfume composition, so is a further preferred embodiment of the invention. Preferably, also in the formula (II) R = H or CH ₃ . Perfume compositions according to the invention which contain silvialoxazolidine enable particularly good results with regard to the intended replacement of Lilial. Furthermore, they allow particularly long-lasting fragrance experiences, especially in the textile laundry.

genannt Cyclamoxazolidin, enthalten vorzugsweise in Mengen von 0,1–90 Gew.-%, insbesondere von 1–40 Gew.-%, so handelt es sich um eine weitere bevorzugte Ausführungsform der Erfindung. Vorzugsweise ist auch in der Formel (III) R = H oder CH₃. Erfindungsgemäße Duftstoffkompositionen, welche Cyclamoxazolidin enthalten, ermöglichen ganz besonders gute Ergebnisse hinsichtlich des angestrebten Ersatzes von Lilial, insbesondere im Anwendungsbereich der Wasch- oder Reinigungsmittel, vor allem mit Blick auf eine ausgeprägte Substantivität des angestrebten Dufteindruckes bei bzw. in Folge der Textilwäsche.If an oxazolidine according to formula (I) is present, in which formula both radicals R ¹ and R ^{2 are} each an isopropyl radical [that is to say (CH ₃ ) ₂ -CH-], corresponding to an oxazolidine of the formula (III)

called cyclamoxazolidine, preferably contain in amounts of 0.1-90 wt .-%, in particular 1-40 wt .-%, so it is a further preferred embodiment of the invention. Preferably, also in the formula (III) R = H or CH ₃ . Fragrance compositions according to the invention which contain cyclamoxazolidine allow particularly good results with regard to the intended replacement of Lilial, in particular in the field of use of detergents or cleaners, especially with a view to a pronounced substantivity of the desired fragrance impression in or as a result of textile washing.

A Fragrance composition of the invention can, but must not limited to the aforementioned ingredients. Advantageously, the Duftstoffkomposition also other common ingredients contain, for example, essential oils, flower oils, extracts of vegetable and animal drugs, absolues, resinoids and natural products isolated, chemically altered (semisynthetic) and purely synthetically derived fragrances etc. The fragrance composition may advantageously be with solvents also diluted as desired be stabilized with emulsifier (s), if desired or necessary is.

One Another subject of the present application is a perfume having means, in particular detergents or cleaners or cosmetic agent comprising a fragrance composition according to the invention. If the following is an agent according to the invention, so unless otherwise stated, is one such Perfume-containing agent containing a fragrance composition according to the invention includes, but in particular to a corresponding detergent or cleaning agent or cosmetic agent. A fragrance is within the meaning of this invention any fragrance, including flavors and essences, especially those fragrances that are essentially positive in humans Trigger the sensation of smell.

According to one preferred embodiment when the perfumery agent is a textile treatment agent, an ironing aid, a cleaning cloth, a detergent, a cleaning agent, in particular for hard and / or soft surfaces, a household cleaner, a care product, a laundry detergent, a room scenting agent, an air freshener, a conditioner, a colorant, a fabric softener, a conditioning substrate, a drug, a pesticide, a cleaning agent, a food, a cosmetic, a fertilizer, a building material, an adhesive, a bleach, a descaling agent, a Car care products, floor care products, Herdpflegemittel, leather care products, furniture care products, a scouring agent, a disinfectant, a fragrance, a mold remover and / or a precursor of the aforementioned means.

Especially Detergents and cleaners (in particular laundry detergents or detergents) Textile care agents, such as. As fabric softener, but also detergents for hard Surfaces, for example, a tile, a bathroom or sanitary cleaner) and any care products are particularly preferred, as are the Air freshener and room fragrance. Preferred cosmetic Agents are preferably intended for skin and / or hair care. Examples are hair shampoo, cleansing lotion, shower gel or a bar of soap to call. However, most preferred are any textile treatment agents, such as detergent or softener, in liquid as in solid form.

According to a preferred embodiment, the perfume-containing agent has a proportion by weight of the perfume composition according to the invention of ≥ 10 ^-6 wt .-% and ≦ 50 wt .-%, preferably ≥ 10 ^-5 wt .-% and ≦ 40 wt .-%, preferably ≥ 10 ^-4 wt .-% and ≤ 30 wt .-%, more preferably ≥ 10 ^-3 wt .-% and ≤ 20 wt .-%, even more preferably ≥ 10 ^-2 wt .-% and ≤ 10 wt .-% and most preferably ≥ 0.03 wt .-% and ≤ 5 wt .-%, based on the total weight of the composition , on.

To a further preferred embodiment the perfume agent is at least partially solid Form, in a gel Shape, in foamy Shape and / or in liquid Form before. If it is in solid form, then preferably in the form of Granules, powders, shaped articles with at least one phase and / or molded articles.

It is an advantage of the invention that the Duftstoffkomposition very is stable. Also in the various matrices and remedies, such as For example, detergents or detergents, the perfume composition is stable and the fragrance of the scented agent is stable even during storage. A particular advantage of Duftstoffkompositionen consists in their pronounced substantivity, which allows a particularly long lasting fragrance effect. It is an advantage of the invention that the perfume composition according to the invention, alone and in mixture with other fragrances, a fragrance-enhancing Effect, d. H. the entire scent impression on scented Object becomes more intense and he stops longer at.

According to a further preferred embodiment, the perfume-containing agent beyond the Duftstoffkomposition addition, at least one further perfume, advantageously have several other perfumes, preferably with a total weight content of these other perfumes of> 0 wt .-% and <50 wt .-%, preferably ≥ 10 ^-6 wt .-% and ≤ 40 wt .-%, preferably ≥ 10 ^-5 wt .-% and ≤ 30 wt .-%, more preferably ≥ 10 ^-4 wt .-% and ≤ 20 wt .-%, even more preferably ≥10 ^-3 wt% and ≤ 15 wt%, even more preferably ≥10 ^-2 wt% and ≤10 wt%, and most preferably ≥10 wt% and ≤5 Wt .-%, based on the total weight of the composition.

To a further preferred embodiment are the additional (s) Perfume (s) in the perfuming agent selected from the group comprising fragrances with notes of green notes, citrus notes, Lavender notes, Flowery notes, Aldehyde notes, Chypre notes, Fougere notes, Spice notes, Oriental notes, wood notes, tobacco notes and / or leather notes.

To a further preferred embodiment are the additional (s) Perfume (s) in the perfuming agent selected from the group includes fragrances natural or synthetic Origin, preferably more volatile Perfumes, higher boiling Fragrances, solid fragrances and / or adherent fragrances.

It a particular advantage of the invention is that the perfume composition according to the invention, alone and in mixture with other fragrances, a fragrance-enhancing Effect, d. H. the fragrance impression on scented object is more intense and he stops longer especially when used in connection with textile washing or Maintenance.

Tenacious Fragrances that can be used in the context of the present invention are, for example, essential oils such as angelica root oil, aniseed oil, arnica blossom oil, basil oil, bay oil, bergamot oil, champa blossom oil, fir pine oil, pinecone oil, elemi oil, eucalyptus oil, fennel oil, spruce alder oil, galbanum oil, geranium oil, ginger grass oil, guaiac wood oil, guriuri balm oil, helichrysum oil, ho oil, ginger oil , Iris oil, cajeput oil, calamus oil, chamomile oil, camphor oil, kanaga oil, cardamom oil, cassia oil, pine oil, copaiba balsam, coriander oil, spearmint oil, caraway oil, cumin oil, lavender oil, lemon grass oil, lime oil, tangerine oil, lemon balm oil, musk oil, myrrh oil, clove oil, neroli oil, niaouli oil , Olibanum Oil, Orange Oil, Origanum Oil, Palmarosa Oil, Patchouli Oil, Peru Balsam Oil, Petitgrain Oil, Pepper Oil, Peppermint Oil, Pimento Oil, Pine Oil, Rose Oil, Rosemary Oil, Sandalwood Oil, Celery Oil, Spik Oil, Star Aniseed Oil, Turpentine Oil, Thuja Oil, Thyme Oil, Verbena Oil, Vetiver Oil, Juniper Berry Oil, Vermouth Oil , Wintergreen oil, Ylang-Ylang-Ö l, hyssop oil, cinnamon oil, cinnamon oil, lemon oil, lemon oil and cypress oil.

But also higher-boiling or solid fragrances of natural or synthetic origin can be used in the context of the present invention as adherent fragrances or fragrance mixtures, ie fragrances. These compounds include the following compounds and mixtures thereof: ambrettolide, α-amylcinnamaldehyde, anethole, anisaldehyde, anisalcohol, anisole, methyl anthranilate, acetophenone, benzylacetone, benzaldehyde, ethyl benzoate, benzophenone, benzyl alcohol, benzyl acetate, benzyl benzoate, benzyl formate, benzyl valerate, borneol , Bornyl acetate, α-bromostyrene, n-decyl aldehyde, n-dodecyl alde hyd, eugenol, eugenol methyl ether, eucalyptol, farnesol, fenchone, fenchyl acetate, geranyl acetate, geranyl formate, heliotropin, heptincarboxylic acid methyl ester, heptaldehyde, hydroquinone dimethyl ether, hydroxycinnamaldehyde, hydroxycinnamyl alcohol, indole, iron , Isoeugenol, isoeugenol methyl ether, isosafrole, Jas mon, camphor, karvakrol, karvon, p-cresol methyl ether, coumarin, p-methoxyacetophenone, methyl n-amyl ketone, methyl anthraniloic acid methyl ester, p-methylacetophenone, methylchavikole, p-methylquinoline, methyl-β-naphthyl ketone, methyl n-nonylacetaldehyde, methyl n-nonyl ketone, muskon, β-naphthol ethyl ether, β-naphthol methyl ether, nerol, nitrobenzene, n-nonyl aldehyde, nonyl alcohol, r-octyl aldehyde, p-oxy-acetophenone, pentadecanolide, β-phenylethyl alcohol, phenylacetaldehyde dimethyacetal, Phenylacetic acid, pulegone, safrol, salicylic acid isoamyl ester, methyl salicylate, hexyl salicylate, cyclohexyl salicylate, santalol, skatole, terpineol, thymine, thymol, γ-undelactone, vaniline, veratrumaldehyde, cinnamaldehyde, cinnamyl alcohol, cinnamic acid, ethyl cinnamate, cinnamic acid cinnamate.

To the more volatile Include fragrances especially the lower-boiling fragrances natural or synthetic origin used alone or in mixtures can be. Examples of easier volatile Fragrances are alkyl isothiocyanates (alkyl mustard oils), butanedione, limonene, linalool, Linayl acetate and propionate, menthol, menthone, methyl-n-heptenone, Phellandrene, phenylacetaldehyde, terpinyl acetate, citral, citronellal.

to accelerated or delayed Release of fragrances, in particular of the fragrance compositions according to the invention, can all methods known in the art are used, as far as they appear to the skilled person to be suitable. According to one preferred embodiment The invention comprises the agent according to the invention supported and / or encapsulated perfume, wherein it is preferred that the fragrance composition according to the invention supported and / or encapsulated.

To a further preferred embodiment has the perfume-containing agent, in particular washing, Care or cleaning agent, at least one, preferably several, active components, in particular washing, care, cleaning active and / or cosmetic components, advantageously selected from the group comprising anionic surfactants, cationic surfactants, amphoteric Surfactants, nonionic surfactants, acidifiers, alkalizers, Anti-crease compounds, antibacterial agents, antioxidants, Anti redeposition agents, antistatic agents, builders, bleaches, Bleach activators, bleach stabilizers, bleach catalysts, ironing aids, Co-builders, fragrances, anti-shrinkage agents, electrolytes, enzymes, Colorants, colorants, Dyes, color transfer inhibitors, Fluorescers, fungicides, germicides, odor-complexing substances, Aids, Hydrotropes, Rinse Aids, Complexing agents, preservatives, corrosion inhibitors, optical Brighteners, perfumes, Perfume carrier, pearlescer, pH adjusters, repellents and impregnating agents, polymers, swelling agents and Slip Resists, Foam Inhibitors, Phyllosilicates, Dirt Repellent Fabrics, silver protectants, silicone oils, UV protectants, viscosity regulators, thickeners, Discoloration inhibitors, Grayness inhibitors, vitamins and / or fabric softeners.

in the For the purposes of this invention, data refer to the agent according to the invention in% by weight, unless otherwise stated, on the total weight of the agent according to the invention.

The Quantities of the individual ingredients in the inventive compositions are based on the purpose of the respective funds and the expert is of the order of magnitude the quantities of ingredients to be used or can these the associated Refer to technical literature. Depending on the purpose of the inventive agent For example, the surfactant content will be higher or lower. Usually is z. For example, the surfactant content of, for example, detergents between 10 and 50 wt .-%, preferably between 12.5 and 30 wt .-% and in particular between 15 and 25 wt .-% while Cleaning agent for automatic dishwashing usually between 0.1 and 10% by weight, preferably between 0.5 and 7.5% by weight and in particular between 1 and 5 wt .-% surfactants.

Washing according to the invention or detergents can especially builders, surfactants, enzymes, Bleaching agents, such as preferably organic and / or inorganic Peroxygen compounds, peroxygen activators, water-miscible organic solvents, Sequestering agents, electrolytes, pH regulators, thickeners and other excipients, such as soil release agents, optical brighteners, Grayness inhibitors, dye transfer inhibitors, Foam regulators and dyes included.

The compositions of the invention may contain surfactants, in particular anionic surfactants, nonionic surfactants and mixtures thereof, as well as cationic surfactants in question. Suitable nonionic surfactants are in particular ethoxylation and / or propoxylation products of alkyl glycosides and / or linear or branched alcohols having in each case 12 to 18 carbon atoms in the alkyl moiety and 3 to 20, preferably 4 to 10 alkyl ether groups. Furthermore, corresponding ethoxylation and / or propoxylation of N-alkylamines, vicinal diols, fatty acid esters and fatty acid amides corresponding to said long-chain alcohol derivatives with respect to the alkyl part, and of alkylphenols having 5 to 12 C atoms in the alkyl radical useful.

suitable anionic surfactants are in particular soaps and those containing or sulfonate groups preferably contain alkali ions as cations. Usable soaps are preferably the alkali metal salts of the saturated or unsaturated fatty acids with 12 to 18 carbon atoms. Such fatty acids can also be in not completely neutralized Form are used. Among the useful surfactants of the sulfate type belong the salts of sulfuric acid half esters of fatty alcohols containing 12 to 18 carbon atoms and the sulfation products of mentioned nonionic surfactants with a low degree of ethoxylation. Suitable surfactants of the sulfonate type include linear ones Alkylbenzenesulfonates with 9 to 14 C atoms in the alkyl moiety, alkanesulfonates with 12 to 18 carbon atoms, as well as olefinsulfonates with 12 to 18 carbon atoms, in the implementation of corresponding monoolefins with sulfur trioxide arise, as well as alpha sulfo fatty acid esters, which in the sulfonation of fatty acid methyl or ethyl esters arise.

Cationic surfactants are preferably selected from esterquats and / or quaternary ammonium compounds (QAV) according to the general formula (R ^I ) (R ^II ) (R ^III ) (R ^IV ) N ⁺ X ^- in which R ^I to R ^{IV represent} the same or different C _1-22 -alkyl, C _7-28 -Arylalkylreste or heterocyclic radicals, wherein two or in the case of an aromatic inclusion as in pyridine even three radicals together with the nitrogen atom, the heterocycle, z. A pyridinium or imidazolinium compound, and X ^{- represents} halide ions, sulfate ions, hydroxide ions or like anions. QACs are by reacting tertiary amines with alkylating agents, such as. As methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethylene oxide produced. The alkylation of tertiary amines with a long alkyl radical and two methyl groups succeeds particularly easily, and the quaternization of tertiary amines with two long radicals and one methyl group can be carried out with the aid of methyl chloride under mild conditions. Amines which have three long alkyl radicals or hydroxy-substituted alkyl radicals are less reactive and are quaternized, for example, with dimethyl sulfate. Candidate QACs are, for example, benzalkonium chloride (N alkyl-N, N dimethyl-benzylammonium chloride), benzalkone B (m, p-dichlorobenzyl-dimethyl-C ₁₂ -alkylammonium chloride, benzoxonium chloride (benzyl-dodecyl-bis (2-hydroxyethyl) -ammonium chloride ), Cetrimonium bromide (N-hexadecyl-N, N-trimethyl-ammonium bromide), benzetonium chloride (N, N-dimethyl-N [2- [2- [p- (1,1,3,3-tetramethylbutyl) -phenoxy] -ethoxy] - ethyl] benzylammonium chloride), dialkyldimethylammonium chlorides such as di-n-decyldimethylammonium chloride, didecyldimethylammonium bromide, dioctyldimethylammonium chloride, 1-cetylpyridinium chloride and thiazoline iodide, and mixtures thereof Preferred QACs are the benzalkonium chlorides having C ₈ -C ₂₂ -alkyl radicals , in particular C ₁₂ -C ₁₄ -alkyl-benzyl-dimethylammonium chloride.

verstanden werden, in der R⁵ für einen Alkyl- oder Alkenylrest mit 12 bis 22 Kohlenstoffatomen und 0, 1, 2 oder 3 Doppelbindungen, R⁶ und R⁷ unabhängig voneinander für H, OH oder O(CO)R⁵, s, t und u jeweils unabhängig voneinander für den Wert 1, 2 oder 3 und X^– für ein Anion, insbesondere Halogenid, Methosulfat, Methophosphat oder Phosphat sowie Mischungen aus diesen, steht. Bevorzugt sind Verbindungen, die für R⁶ die Gruppe O(CO)R⁵ und für R⁵ einen Alkylrest mit 16 bis 18 Kohlenstoffatomen enthalten. Besonders bevorzugt sind Verbindungen, bei denen R⁷ zudem für OH steht. Beispiele für Verbindungen der Formel (IV) sind Methyl-N-(2-hydroxyethyl)-N,N-di(talgacyl-oxyethyl)ammonium-methosulfat, Bis-(palmitoyl)-ethyl-hydroxyethyl-methyl-ammonium-methosulfat oder Methyl-N,N-bis(acyloxyethyl)-N-(2-hydroxyethyl)ammonium-methosulfat. Werden quarternierte Verbindungen der Formel (IV) eingesetzt, die ungesättigte Gruppen aufweisen, sind die Acylgruppen bevorzugt, deren korrespondierende Fettsäuren eine Jodzahl zwischen 5 und 80, vorzugsweise zwischen 10 und 60 und insbesondere zwischen 15 und 45 aufweisen und/oder die ein cis/trans-Isomerenverhältnis (in Mol-%) von größer als 30:70, vorzugsweise größer als 50:50 und insbesondere größer als 70:30 haben. Handelsübliche Beispiele sind die von der Firma Stepan unter dem Warenzeichen Stepantex^® vertriebenen Methylhydroxyalkyldialkoyloxyalkylammoniummethosulfate oder die unter dem Handelsnamen Dehyquart^® bekannten Produkte der Firma Cognis Deutschland GmbH beziehungsweise die unter der Bezeichnung Rewoquat^® bekannten Produkte des Herstellers Goldschmidt-Witco.Under EsterquatS are here preferably compounds of the general formula IV,

in which R ^{5 is} an alkyl or alkenyl radical having 12 to 22 carbon atoms and 0, 1, 2 or 3 double bonds, R ⁶ and R ^{7 are} independently H, OH or O (CO) R ⁵ , s, t and u are each independently of the other the value 1, 2 or 3 and X ^{- is} an anion, in particular halide, methosulfate, methophosphate or phosphate and mixtures of these. Preference is given to compounds which contain the group O (CO) R ⁵ for R ⁶ and an alkyl radical having 16 to 18 carbon atoms for R ⁵ . Particularly preferred are compounds in which R ^{7 is} also OH. Examples of compounds of the formula (IV) are methyl N- (2-hydroxyethyl) -N, N-di (tallowacyl-oxyethyl) ammonium methosulfate, bis (palmitoyl) -ethyl-hydroxyethyl-methyl-ammonium methosulfate or methyl -N, N-bis (acyloxyethyl) -N- (2-hydroxyethyl) ammonium methosulfate. If quaternized compounds of the formula (IV) which have unsaturated groups are used, preference is given to the acyl groups whose corresponding fatty acids have an iodine number between 5 and 80, preferably between 10 and 60 and in particular between 15 and 45 and / or which have a cis / trans Isomer ratio (in mol%) of greater than 30:70, preferably greater than 50:50 and in particular greater than 70:30 have. Commercial examples are sold by Stepan under the trade name Stepantex® ^® methylhydroxyalkyldialkoyloxyalkylammonium or those known under the trade name Dehyquart® ^® products from Cognis Germany GmbH or the known under the name Rewoquat ^® products by manufacturer Goldschmidt-Witco.

Surfactants are present in the detergents according to the invention in proportions of preferably from 5% by weight to 50% by weight, in particular from 8% by weight to 30% by weight. In particular, in laundering agents are preferably up to 30 wt .-%, in particular 5 wt .-% to 15 wt .-% of surfactants, under These preferably at least partially cationic surfactants used.

An agent according to the invention preferably contains at least one water-soluble and / or water-insoluble, organic and / or inorganic builder. The water-soluble organic builder substances include polycarboxylic acids, in particular citric acid and sugar acids, monomeric and polymeric aminopolycarboxylic acids, in particular methylglycinediacetic acid, nitrilotriacetic acid and ethylenediaminetetraacetic acid and polyaspartic acid, polyphosphonic acids, in particular aminotris (methylenephosphonic acid), ethylenediaminetetrakis (methylenephosphonic acid) and 1-hydroxyethane-1,1-diphosphonic acid, polymeric hydroxy compounds such as dextrin and polymeric (poly) carboxylic acids, polymeric acrylic acids, methacrylic acids, maleic acids and copolymers thereof, which may also contain polymerized small amounts of polymerizable substances without carboxylic acid functionality. The molecular weight of the homopolymers of unsaturated carboxylic acids is generally between 5,000 and 200,000, that of the copolymers between 2,000 and 200,000, preferably 50,000 to 120,000, in each case based on the free acid. A particularly preferred acrylic acid-maleic acid copolymer has a molecular weight of 50,000 to 100,000. Suitable, although less preferred, compounds of this class are copolymers of acrylic or methacrylic acid with vinyl ethers, such as vinylmethyl ethers, vinyl esters, ethylene, propylene and styrene, in which the acid content is at least 50% by weight. As water-soluble organic builders, it is also possible to use terpolymers which contain two unsaturated acids and / or salts thereof as monomers and vinyl alcohol and / or a vinyl alcohol derivative or a carbohydrate as the third monomer. The first acidic monomer or its salt is derived from a monoethylenically unsaturated C ₃ -C ₈ -carboxylic acid and preferably from a C ₃ -C ₄ -monocarboxylic acid, in particular from (meth) -acrylic acid. The second acidic monomer or its salt can be a derivative of a C ₄ -C ₈ -dicarboxylic acid, with maleic acid being particularly preferred. The third monomeric unit is formed in this case of vinyl alcohol and / or preferably an esterified vinyl alcohol. In particular, preferred are vinyl alcohol derivatives which are an ester of short-chain carboxylic acids, for example C ₁ -C ₄ carboxylic acids, with vinyl alcohol. Preferred polymers contain from 60% by weight to 95% by weight, in particular from 70% by weight to 90% by weight, of (meth) acrylic acid or (meth) acrylate, particularly preferably acrylic acid or acrylate, and maleic acid or Maleinate and 5 wt .-% to 40 wt .-%, preferably 10 wt .-% to 30 wt .-% of vinyl alcohol and / or vinyl acetate. Very particular preference is given to polymers in which the weight ratio of (meth) acrylic acid or (meth) acrylate to maleic acid or maleate is between 1: 1 and 4: 1, preferably between 2: 1 and 3: 1 and in particular 2: 1 and 2 , 5: 1 lies. Both the amounts and the weight ratios are based on the acids. The second acidic monomer or its salt can also be a derivative of an allylsulfonic acid which is in the 2-position with an alkyl radical, preferably with a C ₁ -C ₄ -alkyl radical, or an aromatic radical which is preferably derived from benzene or benzene derivatives , is substituted. Preferred terpolymers contain from 40% by weight to 60% by weight, in particular from 45 to 55% by weight, of (meth) acrylic acid or (meth) acrylate, particularly preferably acrylic acid or acrylate, from 10% by weight to 30% by weight. %, preferably 15 wt .-% to 25 wt .-% methallylsulfonic acid or Methallylsulfonat and as the third monomer 15 wt .-% to 40 wt .-%, preferably 20 wt .-% to 40 wt .-% of a carbohydrate. This carbohydrate may be, for example, a mono-, di-, oligo- or polysaccharide, mono-, di- or oligosaccharides being preferred. Particularly preferred is sucrose. The use of the third monomer presumably incorporates predetermined breaking points into the polymer which are responsible for the good biodegradability of the polymer. These terpolymers generally have a molecular weight between 1,000 and 200,000, preferably between 200 and 50,000 and in particular between 3,000 and 10,000. Further preferred copolymers are those which have as monomers acrolein and acrylic acid / acrylic acid salts or vinyl acetate. The organic builder substances can be used, in particular for the preparation of liquid agents, in the form of aqueous solutions, preferably in the form of 30 to 50 percent by weight aqueous solutions. All of the acids mentioned are generally used in the form of their water-soluble salts, in particular their alkali metal salts.

organic Builders can if desired in amounts up to 40 wt .-%, in particular up to 25 wt .-% and preferably from 1% by weight to 8% by weight. Quantities close to the mentioned upper limit are preferably in pasty or liquid, in particular, water-containing agents according to the invention are used. Laundry aftertreatment preparations according to the invention, such as As fabric softener, if necessary also be free of organic builder.

Suitable water-soluble inorganic builder materials are, in particular, alkali metal silicates and polyphosphates, preferably sodium triphosphate. Crystalline or amorphous alkali metal aluminosilicates, in amounts of up to 50% by weight, preferably not more than 40% by weight, and in liquid agents, in particular of 1% by weight, are particularly suitable as water-insoluble, water-dispersible inorganic builder materials. to 5 wt .-%, used. Among these, preferred are the detergent grade crystalline sodium aluminosilicates, especially zeolite A, P and optionally X. Amounts near the above upper limit are preferably used in solid, particulate agents. In particular, suitable aluminosilicates have no particles with a particle size greater than 30 .mu.m and preferably consist of at least 80% by weight of particles having a size of less than 10 .mu.m.

Suitable substitutes or partial substitutes for the said aluminosilicate are crystalline alkali silicates which may be present alone or in a mixture with amorphous silicates. The alkali metal silicates useful as builders in the compositions according to the invention preferably have a molar ratio of alkali metal oxide to SiO ₂ below 0.95, in particular from 1: 1.1 to 1:12, and may be present in amorphous or crystalline form. Preferred alkali metal silicates are the sodium silicates, in particular the amorphous sodium silicates, with a molar ratio of Na ₂ O: SiO ₂ of 1: 2 to 1: 2.8. The crystalline silicates which may be present alone or in admixture with amorphous silicates, are crystalline layer silicates with the general formula of Na ₂ Si _x O used _{2x + 1} · y H ₂ O in which x, known as the modulus, an integer of 1, 9 to 4 and y is a number from 0 to 20 and preferred values for x are 2, 3 or 4. Preferred crystalline phyllosilicates are those in which x in the abovementioned general formula assumes the values 2 or 3. In particular, both β- and δ-sodium disilicates (Na ₂ Si ₂ O ₅ .yH ₂ O) are preferred. Also prepared from amorphous alkali silicates, practically anhydrous crystalline alkali metal silicates of the abovementioned general formula in which x is a number from 1.9 to 2.1, can be used in inventive compositions. In a further preferred embodiment of the composition according to the invention, a crystalline sodium layer silicate with a modulus of 2 to 3 is used, as can be prepared from sand and soda. Crystalline sodium silicates with a modulus in the range from 1.9 to 3.5 are used in a further preferred embodiment of compositions according to the invention. If alkali metal aluminosilicate, in particular zeolite, is also present as an additional builder substance, the weight ratio of aluminosilicate to silicate, based in each case on anhydrous active substances, is preferably 1:10 to 10: 1. In agents containing both amorphous and crystalline alkali metal silicates, the weight ratio of amorphous alkali metal silicate to crystalline alkali metal silicate is preferably 1: 2 to 2: 1 and especially 1: 1 to 2: 1.

builders are in the detergents according to the invention preferably in amounts of up to 60% by weight, in particular of 5% by weight to 40 wt .-%, contained. Laundry aftertreatment preparations according to the invention, such as. fabric softener, are preferably free of inorganic builder.

When suitable peroxygen compounds are in particular organic peracids or peracid salts of organic acids, such as phthalimidopercaproic acid, perbenzoic acid or Salts of diperdodecanedioic acid, Hydrogen peroxide and under the conditions of use hydrogen peroxide donating inorganic salts, such as perborate, percarbonate and / or Persilikat, into consideration. If solid peroxygen compounds can be used these are used in the form of powders or granules which can also be enveloped in a manner known in principle. Particularly preferred Alkali percarbonate, alkali perborate monohydrate or especially in liquid agents Hydrogen peroxide in the form of aqueous solutions, containing 3 wt .-% to 10 wt .-% hydrogen peroxide used. If a detergent according to the invention Bleaches, preferably containing peroxygen compounds these in amounts of preferably up to 50 wt .-%, in particular from 5% to 30% by weight. The addition of small amounts known bleach stabilizers such as phosphonates, Bristles or metaborates and metasilicates and magnesium salts such as magnesium sulfate may be useful.

As bleach activators, it is possible to use compounds which, under perhydrolysis conditions, give aliphatic peroxycarboxylic acids having preferably 1 to 10 C atoms, in particular 2 to 4 C atoms, and / or optionally substituted perbenzoic acid. Suitable substances are those which carry O- and / or N-acyl groups of the stated C atom number and / or optionally substituted benzoyl groups. Preference is given to polyacylated alkylenediamines, in particular tetraacetylethylenediamine (TAED), acylated triazine derivatives, in particular 1,5-diacetyl-2,4-dioxohexahydro-1,3,5-triazine (DADHT), acylated glycolurils, in particular tetraacetylglycoluril (TAGU), N- Acylimides, in particular N-nonanoylsuccinimide (NOSI), acylated phenolsulfonates, in particular n-nonanoyl or isononanoyloxybenzenesulfonate (n- or iso-NOBS), carboxylic anhydrides, in particular phthalic anhydride, acylated polyhydric alcohols, in particular triacetin, ethylene glycol diacetate, 2,5-diacetoxy- 2,5-dihydrofuran and enol esters, and also acetylated sorbitol and mannitol or mixtures thereof (SORMAN), acylated sugar derivatives, in particular pentaacetylglucose (PAG), pentaacetylfruktose, tetraacetylxylose and octaacetyllactose as well as acetylated, optionally N-alkylated glucamine and gluconolactone, and / or N-acylated Lactams, for example N-benzoyl-caprolactam. Hydrophilic substituted acyl acetals and acyl lactams are also preferably used. Combinations of conventional bleach activators can also be used. Such bleach activators can in üb Volume range, preferably in amounts of 1 wt .-% to 10 wt .-%, in particular 2 wt .-% to 8 wt .-%, based on the total agent, be included.

In addition to the above conventional bleach activators or in their place may also Sulfonimines and / or bleach-enhancing transition metal salts or transition metal complexes be included as so-called bleach catalysts. To those in question upcoming transition metal compounds belong in particular manganese, iron, cobalt, ruthenium or molybdenum-salene complexes and whose N-analogues, manganese, iron, cobalt, ruthenium or molybdenum-carbonyl complexes, manganese, Iron, cobalt, ruthenium, molybdenum, titanium, vanadium and copper complexes with nitrogen-containing tripod ligands, cobalt, iron, copper and ruthenium-ammine complexes. Combinations of bleach activators and transition metal bleach catalysts can also be used. Bleach-enhancing transition metal complexes, in particular with the central atoms Mn, Fe, Co, Cu, Mo, V, Ti and / or Ru, can in usual Quantities, preferably in an amount up to 1 wt .-%, in particular from 0.0025 wt% to 0.25 wt%, and more preferably from 0.01 Wt .-% to 0.1 wt .-%, each based on the total agent used become.

When Enzymes useful in the compositions are those of the class of Proteases, cutinases, amylases, pullulanases, hemicellulases, cellulases, Lipases, oxidases and peroxidases and mixtures thereof in question. Particularly suitable are fungi or bacteria, such as Bacillus subtilis, Bacillus licheniformis, Streptomyces griseus, Humicola lanuginosa, Humicola insolens, Pseudomonas pseudoalcaligenes or Pseudomonas cepacia derived enzymatic agents. The optionally used enzymes can on carriers adsorbed and / or in coating substances be embedded to protect against premature inactivation. she are in the detergents according to the invention preferably not over 5 wt .-%, in particular from 0.2 wt .-% to 2 wt .-%, included.

The Means can as optical brighteners, for example, derivatives of diaminostilbenedisulfonic acid or containing their alkali metal salts. For example, salts are suitable 4,4'-bis (2-anilino-4-morpholino-1,3,5-triazinyl-6-amino) stilbene-2,2'-disulphonic acid or similarly constructed compounds that replace the morpholino group a diethanolamino group, a methylamino group, an anilino group or carry a 2-methoxyethylamino group. Furthermore, brighteners the type of substituted Diphenylstyryle be present, for example the alkali salts of 4,4'-bis (2-sulfostyryl) -diphenyl, 4,4'-bis (4-chloro-3-sulfostyryl) -diphenyl or 4- (4-chlorostyryl) -4 '- (2-sulfostyryl) -diphenyls. Mixtures of the aforementioned brightener can be used.

To the suitable foam inhibitors include, for example, organopolysiloxanes and their mixtures with microfine, optionally silanized silica and Pa-raffinwachse and mixtures thereof with silanated silica or Bisfettsäure-alkylenediamides. With advantages are also mixtures of different foam inhibitors used, for example, those of silicones, paraffins or waxes. Preferably, the foam inhibitors, in particular silicone and / or Paraffin-containing foam inhibitors, on a granular, in water soluble or dispersible carrier substance bound. Especially are mixtures of paraffin waxes and bistearylethylenediamides prefers.

In addition, the Means also contain components that the oil and Fettauswaschbarkeit from Textile positively influence, so-called soil release agents. This effect is particularly evident when a textile is dirty is, which previously several times with a detergent according to the invention, that this oil and fat-dissolving Component contains was washed. Among the preferred oil and fat dissolving components counting for example, nonionic cellulose ethers such as methyl cellulose and methylhydroxypropylcellulose with a proportion of methoxyl groups from 15 to 30% by weight and of hydroxypropoxyl groups from 1 to 15 Wt .-%, each based on the nonionic cellulose ether, and the known from the prior art polymers of phthalic acid and / or of terephthalic acid or derivatives thereof with monomeric and / or polymeric diols, in particular polymers of ethylene terephthalates and / or polyethylene glycol terephthalates or anionic and / or nonionic modified derivatives of this.

The compositions may also color transfer inhibitors, preferably in amounts of from 0.1 wt .-% to 2 wt .-%, in particular 0.1 wt .-% to 1 wt .-%, containing in a preferred embodiment of the invention polymers Vinylpyrrolidone, vinylimidazole, vinylpyridine N-oxide or copolymers of these are. Polyvinylpyrrolidones having molecular weights of from 15,000 to 50,000 as well as polyvinylpyrrolidones having molecular weights of more than 1,000,000, in particular from 1,500,000 to 4,000,000, N-vinylimidazole / N-vinylpyrrolidone copolymers, polyvinyl oxazolidones, copolymers based on vinyl monomers, and polyvinylpyrrolidones, are useful Carboxylic acid amides, pyrrolidone group-containing polyesters and polyamides, grafted polyamidoamines and Polyethylenimi ne, polymers containing amide groups from secondary amines, polyamine N-oxide polymers, polyvinyl alcohols and copolymers based on acrylamidoalkenylsulfonic acids. However, it is also possible to use enzymatic systems comprising a peroxidase and hydrogen peroxide or a substance which produces hydrogen peroxide in water. The addition of a mediator compound for the peroxidase, for example an acetosyringone, a phenol derivative or a phenotiazine or phenoxazine, is preferred in this case, whereby also above-mentioned polymeric Farbübertragungsinhibitorwirkstoffe can be used. Polyvinylpyrrolidone preferably has an average molecular weight in the range from 10 000 to 60 000, in particular in the range from 25 000 to 50 000, for use in compositions according to the invention. Among the copolymers, those of vinylpyrrolidone and vinylimidazole in a molar ratio of 5: 1 to 1: 1 having an average molecular weight in the range of 5,000 to 50,000, especially 10,000 to 20,000 are preferred.

graying have the task of suspended from the textile fiber dirt suspended in the fleet to keep. These are water-soluble Colloids mostly organic nature suitable, such as starch, glue, Gelatin, salts of ether carboxylic acids or ether sulfonic acids the strength or the cellulose or salts of acidic sulfuric acid esters cellulose or starch. Also water-soluble, Acidic group-containing polyamides are suitable for this purpose. Farther can be used other than the above-mentioned starch derivatives, for Example aldehyde starches. Preference is given to cellulose ethers, such as carboxymethylcellulose (Na salt), Methylcellulose, hydroxyalkylcellulose and mixed ethers, such as methylhydroxyethylcellulose, Methylhydroxypropylcellulose, methylcarboxymethylcellulose and their Mixtures, for example in amounts of 0.1 to 5 wt .-%, based on the means used.

To in the compositions according to the invention, especially when in liquid or pastier Form, usable organic solvents include alcohols with 1 to 4 C-atoms, in particular methanol, ethanol, isopropanol and tert-butanol, diols having 2 to 4 C atoms, in particular ethylene glycol and propylene glycol, as well as mixtures thereof and those mentioned Classes of derivable ether. Such water-miscible solvent are in the detergents according to the invention preferably in amounts of not more than 30 wt .-%, in particular from 6% to 20% by weight.

to Setting a desired, through the mixture of the rest Non-self-inflicting pH components can be used agents according to the invention system and environmentally friendly Acids, in particular citric acid, Acetic acid, Tartaric acid, malic acid, lactic acid, glycolic acid, succinic acid, glutaric acid and / or adipic acid, but also mineral acids, especially sulfuric acid, or bases, in particular ammonium or alkali metal hydroxides. Such pH regulators are in the inventive compositions preferably not over 20 wt .-%, in particular from 1.2 wt .-% to 17 wt .-%, contain.

The Preparation of solid compositions according to the invention prepares no difficulties and can, in principle, known manner, for example by spray drying or granulation, wherein peroxygen compound and bleach catalyst possibly later be added. The fragrance composition according to the invention and optionally further fragrances are preferably at the end of the preparation applied to the agent. For the preparation of agents according to the invention with elevated Bulk density, especially in the range of 650 g / l to 950 g / l, is an extrusion step preferred method. The preparation of liquid inventive agents also prepares no difficulties and can also be known Way, wherein the Duftstoffkomposition invention and optionally further fragrances preferably at the end of the preparation in the agent will be introduced.

According to one preferred embodiment can the teaching of the invention to be used, the perfume part in laundry, cleaning and personal care products significantly lower. This makes it possible to perfumed products even for such to offer the most sensitive consumers the normally perfumed products due to special incompatibilities and irritations only limited or at all can not use. In this context, mainly skin care products and deodorants, but also detergents, such as. B. to call hand detergent.

• – Aniontenside, wie vorzugsweise Alkylbenzolsulfonat, Alkylsulfat, z. B. in Mengen von vorzugsweise 5–30 Gew.-%
• – Nichtionische Tenside, wie vorzugsweise Fettalkoholpolyglycolether, Alkylpolyglucosid, Fettsäureglucamid z. B. in Mengen von vorzugsweise 0,5–15 Gew.-%
• – Gerüststoffe, wie z. B. Zeolith, Polycarboxylat, Natriumcitrat, in Mengen von z. B. 0–70 Gew.-%, vorteilhafterweise 5–60 Gew.-%, vorzugsweise 10–55 Gew.-%, insbesondere 15–40 Gew.-%,
• – Alkalien, wie z. B. Natriumcarbonat, in Mengen von z. B. 0–35 Gew.-% vorteilhafterweise 1–30 Gew.-%, vorzugsweise 2–25 Gew.-%, insbesondere 5–20 Gew.-%,
• – Bleichmittel, wie z. B. Natriumperborat, Natriumpercarbonat, in Mengen von z. B. 0–30 Gew.-% vorteilhafterweise 5–25 Gew.-%, vorzugsweise 10–20 Gew.-%,
• – Korrosionsinhibitoren, z. B. Natriumsilicat, in Mengen von z. B. 0–10 Gew.-%, vorteilhafterweise 1–6 Gew.-%, vorzugsweise 2–5 Gew.-%, insbesondere 3–4 Gew.-%,
• – Stabilisatoren, z. B. Phosphonate, vorteilhafterweise 0–1 Gew.-%,
• – Schauminhibitor, z. B. Seife, Siliconöle, Paraffine vorteilhafterweise 0–4 Gew.-%, vorzugsweise 0,1–3 Gew.-%, insbesondere 0,2–1 Gew.-%,
• – Enzyme, z. B. Proteasen, Amylasen, Cellulasen, Lipasen, vorteilhafterweise 0–2 Gew.-%, vorzugsweise 0,2–1 Gew.-%, insbesondere 0,3–0,8 Gew.-%,
• – Vergrauungsinhibitor, z. B. Carboxymethylcellulose, vorteilhafterweise 0–1 Gew.-%,
• – Verfärbungsinhibitor, z. B. Polyvinylpyrrolidon-Derivate, vorteilhafterweise 0–2 Gew.-%,
• – Stellmittel, z. B. Natriumsulfat, vorteilhafterweise 0–20 Gew.-%,
• – Optische Aufheller, z. B. Stilben-Derivat, Biphenyl-Derivat, vorteilhafterweise 0–0,4 Gew.-%, insbesondere 0,1–0,3 Gew.-%,
• – ggf. weitere Duftstoffe
• – ggf. Wasser
• – ggf. Seife
• – ggf. Bleichaktivatoren
• – ggf. Cellulosderivate
• – ggf. Schmutzabweiser,

Gew.-% jeweils bezogen auf das gesamte Mittel.A preferred solid, in particular powdered detergent according to the invention, in addition to the fragrance composition according to the invention preferably contain components which, for. B. are selected from the following:

• - Aniontenside, such as preferably alkylbenzenesulfonate, alkyl sulfate, z. B. in amounts of preferably 5-30 wt .-%
• Nonionic surfactants, such as preferably fatty alcohol polyglycol ethers, alkylpolyglucoside, fatty acid glucamide z. B. in amounts of preferably 0.5-15 wt .-%
• - builders, such. As zeolite, polycarboxylate, sodium citrate, in amounts of z. B. 0-70 wt .-%, advantage conveniently 5-60% by weight, preferably 10-55% by weight, in particular 15-40% by weight,
• - Alkalis, such as. For example, sodium carbonate, in amounts of z. B. 0-35 wt .-% advantageously 1-30 wt .-%, preferably 2-25 wt .-%, in particular 5-20 wt .-%,
• - Bleaching agents, such as. For example, sodium perborate, sodium percarbonate, in amounts of z. B. 0-30 wt .-% advantageously 5-25 wt .-%, preferably 10-20 wt .-%,
• - corrosion inhibitors, z. For example, sodium silicate, in amounts of z. B. 0-10 wt .-%, advantageously 1-6 wt .-%, preferably 2-5 wt .-%, in particular 3-4 wt .-%,
• - Stabilizers, z. As phosphonates, advantageously 0-1 wt .-%,
• Foam inhibitor, e.g. As soap, silicone oils, paraffins advantageously 0-4 wt .-%, preferably 0.1-3 wt .-%, in particular 0.2-1 wt .-%,
• - enzymes, eg. B. proteases, amylases, cellulases, lipases, advantageously 0-2 wt .-%, preferably 0.2-1 wt .-%, in particular 0.3-0.8 wt .-%,
• - Grayness inhibitor, z. B. carboxymethylcellulose, advantageously 0-1 wt .-%,
• - Discoloration inhibitor, z. B. polyvinylpyrrolidone derivatives, advantageously 0-2 wt .-%,
• - Adjusting agent, z. For example, sodium sulfate, advantageously 0-20 wt .-%,
• - Optical brightener, z. B. stilbene derivative, biphenyl derivative, advantageously 0-0.4 wt .-%, in particular 0.1-0.3 wt .-%,
• - If necessary, other fragrances
• - If necessary water
• - if necessary, soap
• - optionally bleach activators
• - If necessary, cellulose derivatives
• - if necessary dirt deflector,

% By weight, based in each case on the total agent.

In another preferred embodiment According to the invention, the washing or cleaning agent is in liquid form before, preferably in gel form. Preferred liquid detergents or cleaners have water contents of z. B. 10-95 wt .-%, preferably 20-80 wt .-% and especially 30-70 Wt .-%, based on the total agent. In the case of liquid concentrates the water content may also be particularly low, z. B. <30 wt .-%, preferably <20 wt .-%, in particular <15 wt .-%, % By weight, based in each case on the total agent. The liquid means can also non-aqueous solvent contain.

• – Aniontenside, wie vorzugsweise Alkylbenzolsulfonat, Alkylsulfat, z. B. in Mengen von vorzugsweise 5–40 Gew.-%
• – Nichtionische Tenside, wie vorzugsweise Fettalkoholpolyglycolether, Alkylpolyglucosid, Fettsäureglucamid z. B. in Mengen von vorzugsweise 0,5–25 Gew.-%
• – Gerüststoffe, wie z. B. Zeolith, Polycarboxylat, Natriumcitrat, vorteilhafterweise 0–15 Gew.-%, vorzugsweise 0,01–10 Gew.-%, insbesondere 0,1–5 Gew.-%,
• – Schauminhibitor, z. B. Seife, Siliconöle, Paraffine, in Mengen von z. B. 0–10 Gew.-%, vorteilhafterweise 0,1–4 Gew.-%, vorzugsweise 0,2–2 Gew.-%, insbesondere 1–3 Gew.-%,
• – Enzyme, z. B. Proteasen, Amylasen, Cellulasen, Lipasen, in Mengen von z. B. 0–3 Gew.-%, vorteilhafterweise 0,1–2 Gew.-%, vorzugsweise 0,2–1 Gew.-%, insbesondere 0,3–0,8 Gew.-%,
• – Optische Aufheller, z. B. Stilben-Derivat, Biphenyl-Derivat, in Mengen von z. B. 0–1 Gew.-%, vorteilhafterweise 0,1–0,3 Gew.-%, insbesondere 0,1–0,4 Gew.-%,
• – ggf. weitere Duftstoffe
• – ggf. Stabilisatoren,
• – Wasser
• – ggf. Seife, in Mengen von z. B. 0–25 Gew.-%, vorteilhafterweise 1–20 Gew.-%, vorzugsweise 2–15 Gew.-%, insbesondere 5–10 Gew.-%,
• – ggf. Lösungsmittel (vorzugsweise Alkohole), vorteilhafterweise 0–25 Gew.-%, vorzugsweise 1–20 Gew.-%, insbesondere 2–15 Gew.-%, Gew.-% jeweils bezogen auf das gesamte Mittel.

A preferred liquid, in particular gel detergent according to the invention, in addition to the perfume composition according to the invention preferably contain components which, for. B. are selected from the following:

• - Aniontenside, such as preferably alkylbenzenesulfonate, alkyl sulfate, z. B. in amounts of preferably 5-40 wt .-%
• Nonionic surfactants, such as preferably fatty alcohol polyglycol ethers, alkylpolyglucoside, fatty acid glucamide z. B. in amounts of preferably 0.5-25 wt .-%
• - builders, such. B. zeolite, polycarboxylate, sodium citrate, advantageously 0-15 wt .-%, preferably 0.01-10 wt .-%, in particular 0.1-5 wt .-%,
• Foam inhibitor, e.g. As soap, silicone oils, paraffins, in amounts of z. B. 0-10 wt .-%, advantageously 0.1-4 wt .-%, preferably 0.2-2 wt .-%, in particular 1-3 wt .-%,
• - enzymes, eg. As proteases, amylases, cellulases, lipases, in amounts of z. B. 0-3 wt .-%, advantageously 0.1-2 wt .-%, preferably 0.2-1 wt .-%, in particular 0.3-0.8 wt .-%,
• - Optical brightener, z. B. stilbene derivative, biphenyl derivative, in amounts of z. B. 0-1 wt .-%, advantageously 0.1-0.3 wt .-%, in particular 0.1-0.4 wt .-%,
• - If necessary, other fragrances
• - stabilizers if necessary,
• - Water
• - If necessary, soap, in quantities of z. B. 0-25 wt .-%, advantageously 1-20 wt .-%, preferably 2-15 wt .-%, in particular 5-10 wt .-%,
• - If necessary, solvents (preferably alcohols), advantageously 0-25 wt .-%, preferably 1-20 wt .-%, in particular 2-15 wt .-%, wt .-% in each case based on the total agent.

• – Kationische Tenside, wie insbesondere Esterquats, z. B. in Mengen von 5–30 Gew.-%,
• – Cotenside, wie z. B. Glycerolmonostearat, Stearinsäure, Fettalkohole, Fettalkoholethoxylate, z. B. in Mengen von 0–5 Gew.-%, vorzugsweise 0,1–4 Gew.-%,
• – Emulgatoren, wie z. B. Fettaminethoxylate, z. B. in Mengen von 0–4 Gew.-%, vorzugsweise 0,1–3 Gew.-%,
• – ggf. weitere Duftstoffe
• – Farbstoffe, vorzugsweise im ppm-Bereich
• – Stabilisatoren, vorzugsweise im ppm-Bereich
• – Lösemittel, wie insbesondere Wasser, in Mengen von vorzugsweise 60–90 Gew.-%,
• – Gew.-% jeweils bezogen auf das gesamte Mittel.

A preferred liquid fabric softener according to the invention may contain, in addition to the perfume composition according to the invention, preferably components which are selected from the following:

• - Cationic surfactants, such as in particular esterquats, z. In amounts of 5-30% by weight,
• - cosurfactants, such as. As glycerol monostearate, stearic acid, fatty alcohols, fatty alcohol ethoxylates, eg. In Men from 0-5 wt .-%, preferably 0.1-4 wt .-%,
• - emulsifiers, such as. B. fatty amine ethoxylates, e.g. In amounts of 0-4 wt.%, Preferably 0.1-3 wt.%,
• - If necessary, other fragrances
• - Dyes, preferably in the ppm range
• Stabilizers, preferably in the ppm range
• Solvents, in particular water, in amounts of preferably 60-90% by weight,
• -% by weight, based in each case on the total agent.

One Another object of the present invention is the use a perfume composition according to the invention to produce a lily of the valley fragrance, especially in washing, cleaning or personal care applications.

One Another object of the present invention is the use a perfume composition according to the invention for the substitution of Lilial, especially in detergents or cleaners as well as in cosmetic products.

One Another object of the invention is the use of a Duftstoffkomposition invention for the substitution of lilial in fragrance compositions or perfumed Agents, especially in fragrance-containing detergents or cleaners as well as perfume-containing cosmetic agents, preferably for Production of a more luscious Lily-valley scent compared to Lilial, especially in washing, cleaning or personal care applications.

Claims (15)

Fragrance composition, characterized in that it contains at least 1 component selected from (a) 3- (4-tert-butylphenyl) propionaldehyde (Bourgeonal) (preferably in amounts of 0.01-99% by weight, advantageously 0.01- 40% by weight, in particular from 0.1 to 20% by weight), (b) 2-methyl-4-phenylbutan-2-ol (dimethylphenylethylcarbinol) (preferably in amounts of from 0.01 to 99% by weight , advantageously in amounts of 0.01-20% by weight, in particular 0.01-15% by weight), (c) cis-4- (isopropyl) cyclohexanemethanol (Mayol) (preferably in amounts of 0.01 -99% by weight, advantageously in amounts of 0.01-20% by weight, in particular of 0.5-15% by weight), (d) 1- (1-hydroxyethyl) -4- (1) methylethyl) cyclohexane (mixture of diastereoisomers) (mugetanol) (preferably in amounts of 0.01-99% by weight, advantageously in amounts of 0.01-90% by weight, in particular of 0.5-40% by weight). %), (e) (4-methyl-3-pentenyl) cyclohexenecarbaldehyde (citrusal) (preferably in amounts of 0.01-99% by weight, advantageously in amounts of 0.01-40% by weight, especially 0.1-20% by weight), (f) 3- (p- (2-methylpropyl) phenyl) -2-methylpropionaldehyde (Silvial) ( preferably in amounts of 0.01-99% by weight, advantageously in amounts of 0.1-90% by weight, in particular of 1-40% by weight), (g) 3-p-cumenyl-2 methylpropionaldehyde (cyclamenaldehyde) (preferably in amounts of 0.01-99% by weight, advantageously in amounts of 0.1-90% by weight, in particular 1-40% by weight), (h) mixture of: cis-tetrahydro-2-isobutyl-4-methyl-pyran-4-ol; trans-tetrahydro-2-isobutyl-4-methyl-pyran-4-ol; (Florol) (preferably in amounts of 0.01-99 wt .-%, advantageously in amounts of 0.1-40 wt .-%, in particular 1-40 wt .-%), Duftstoffkomposition, characterized in that they at least 2, preferably at least 3, advantageously at least 4, more preferably at least 5, more preferably at least Contains 6 components from group (a) to (h), in particular all components (a) to (h) contains. Fragrance composition according to claim 1 or 2, characterized in that it contains at least 2, preferably at least 4, advantageously at least 6, more preferably at least 8, even more advantageously at least 10 components from the group (i) to (w): (i) Methoxy-2,6-dimethylheptan-1-al (methoxymelonal) (preferably in amounts of 0.01-10% by weight, especially 0.01-5% by weight), (j) 5,9-dimethyl -4,8-decadienal (geraldehyde) (preferably in amounts of 0.01-10% by weight, especially 0.01-5% by weight), (k) beta-methyl-3- (1-methylethyl ) benzenepropanal (Florhydral) (preferably in amounts of 0.01-10% by weight, in particular of 0.01-5% by weight), (1) octahydro-8,8-dimethylnaphthalenes-2-carbaldehyde (cyclomyral) (preferably in amounts of 0.01-10 % By weight, in particular 0.01-5% by weight), (m) alpha-methyl-1,3-benzodioxole-5-propionaldehyde (helional) (preferably in amounts of 0.01-20% by weight). %, in particular 0.01-5% by weight), (n) 5-methyl-2- (1-methylbutyl) -5-propyl-1,3-dioxane (troenan) (preferably in amounts of 0.01 -10% by weight, in particular 0.01-5% by weight), (o) 3- (o-ethylphenyl) -2,2-dimethylpropionaldehyde (Floralozone) (preferably in amounts of 0.01-10% by weight) %, in particular 0.01-5% by weight), (p) farnesol (preferably in amounts of 0.01-30% by weight, in particular 0.01-5% by weight), q) 3,7,11-trimethyldodeca-1,6,10-trien-3-ol, (mixture of isomers) (nerolidol) (preferably in amounts of 0.01-50% by weight, in particular 0.01-40 % By weight), (r) cyclohexyl salicylate (preferably in amounts of 0.01-20% by weight, especially 0.1-10% by weight), (s) hexyl salicylate (preferably in amounts of 0.01%) -20 wt .-%, in particular of 0.1-10 wt .-%) (t) Benzylsalicylat (preferably in amounts of 0.01-20 wt .-%, esp other 0.1-10% by weight), (u) amylsalicylate (preferably in amounts of 0.01-20% by weight, especially 1-10% by weight), (v) triethyl citrate (preferably in Amounts of 1-90% by weight, in particular of 5-80% by weight) and / or (w) dipropylene glycol (preferably in amounts of 1-90% by weight, in particular of 5-80% by weight) , Wt .-% each based on the total amount of the perfume composition. Perfume composition according to one of claims 1 to 3, characterized in that they Cyclamenaldehyd, Silvial and / or Contains Mugetanol, and at least 4 further components from the group (i) to (w), preferably cyclamenaldehyde and silvial or cyclamenaldehyde and Mugetanol or else Silvial and Mugetanol or in particular Cyclamenaldehyde, Silvial and Mugetanol is included. Perfume composition according to any one of claims 1-4, characterized characterized in that it contains Citrusal, Bourgeonal and / or Mayol. Perfume composition according to any one of claims 1-5, characterized characterized in that they are Florol and / or Dimethylphenylethylcarbinol contains. Fragrance composition according to any one of claims 1-6, characterized in that it comprises at least one oxazolidine according to formula (I),

wherein the radicals R, R ¹ , R ² independently of one another represent a hydrogen atom or an organic radical, in particular a linear or branched, substituted or unsubstituted alkyl or alkylene group of C ₁ to C ₂₀ , it being preferred that that the radicals R ¹ and R ² correspond. Fragrance composition according to claim 7, characterized in that an oxazolidine according to formula (I) is contained, wherein in this formula both radicals R ¹ and R ^{2 are} each an isobutyl radical [ie for (CH ₃ ) ₂ -CH-CH ₂ - ], corresponding to an oxazolidine according to formula (II)

called silvialoxazolidine, preferably contained in amounts of 0.1-90 wt .-%, in particular of 1-40 wt .-%, wt .-% based on the total amount of the perfume composition. Fragrance composition according to claim 7 or 8, characterized in that an oxazolidine according to formula (I) is contained, wherein in this formula both radicals R ¹ and R ^{2 are} each an isopropyl radical [ie for (CH ₃ ) ₂ -CH-] corresponding to an oxazolidine according to formula (III)

called cyclamoxazolidine, preferably contained in amounts of 0.1-90 wt .-%, in particular 1-40 wt .-% Perfume-containing agent, in particular washing or detergent or cosmetic agent, characterized it is a fragrance composition according to any one of claims 1 to 9 includes. Perfume-containing composition according to claim 8, characterized in that the proportion by weight of the perfume composition ≥ 10 ^-6 wt .-% and ≤ 50 wt .-%, preferably ≥ 10 ^-5 wt .-% and ≤ 40 wt .-%, preferably ≥ 10 ^-4 wt .-% and ≤ 30 wt .-%, more preferably ≥ 10 ^-3 wt .-% and ≤ 20 wt .-%, even more preferably ≥ 10 ^-2 wt .-% and ≤ 10 wt. % and most preferably ≥0.03 wt% and ≤5 wt%, based on the total weight of the composition. Perfume-containing agent according to any one of claims 10-11, characterized in that the agent is supported and / or encapsulated Perfume, it being preferred that the perfume composition according to one of the claims 1 to 9 supported and / or encapsulated. Perfume-containing agent according to any one of claims 10-12, characterized characterized in that the perfume-containing agent at least a washing, care, cleaning active and / or cosmetic component having. Use of a fragrance composition according to a the claims 1 to 9 for producing a lily of the valley fragrance, in particular for washing, cleaning or personal care applications. Use of a fragrance composition according to a the claims 1 to 9 for the substitution of Lilial, especially in washing or Detergents and in cosmetic products.