DE102007016201A1 - Textile fabric with cleaning power - Google Patents

Abstract

There are textile substrates, eg. As nonwovens, described with cleaning power, which acted upon with a special composition, soaked, coated and / or impregnated. These substrates are very well suited for the cleaning, treatment and / or antimicrobial finishing of hard surfaces and textiles, taking advantage of the effect of light. They are also very good for removing dust from a surface. The substrates can also be used successfully in machine textile washing and drying processes. A particular advantage of the textile fabrics described is that they have self-cleaning forces under the action of light.

Description

The The present invention relates to a textile substrate having detergency, comprising a composition with which the substrate is applied, impregnated, coated and / or impregnated is, wherein this composition humectants, photocatalytic Contains material and surfactant.

she relates to a product comprising a container for storing the substrates. It relates to a method for treating hard surfaces and / or Textiles comprising contacting a hard surface or of textiles with a substrate according to the invention, at and / or followed by exposure of the hard surface to light of a wavelength in the range from 300-1200 nm. It relates to a method for removing dust from a Surface. It relates to a method for automatic self-cleaning of a inventive substrate. It relates to the use of a substrate according to the invention for removal or reduction of stains and stains on hard surfaces or Textiles, for denaturation or growth inhibition of microbes, as well as the use of light, in particular with a wavelength in the range from 300-1200 nm, for the automatic self-cleaning of a substrate according to the invention

By Cleanliness and hygiene could improve people's quality of life and expectations be decisively improved. Make an important contribution to this Cleaning agents of all kinds, such as. B. All-purpose cleaner or special cleaning agents or detergent for Textiles, so-called detergents. These and other cleaners will be in the most diverse embodiments for the commercial and technical needs as well as household needs provided by the industry.

Of the Consumers are interested in efficient detergents, since he knows that surfaces and textile products, even if they look so clean, in microbial Are rarely pure.

A However, microbial colonization of surfaces may, in particular in the presence of a suitable species and number of germs, especially problematic with regard to people with an immunocompromised organism become. It can the resulting problems for example of simple allergies lead to systemic mycoses, causes z. B. by mold spores.

The It is an object of the present invention to provide an agent ready to help, which helps disturbances of human well-being counteract which associated with hygiene deficits can be.

• (a) Feuchthaltemittel
• (b) photokatalytisches Material
• (c) Tensid,

enthält.This object is achieved by the subject matter of the invention. The invention relates to a textile substrate, preferably a textile fabric, having a cleaning capacity, comprising a composition with which the textile substrate is applied, coated, impregnated and / or impregnated, wherein this composition

• (a) humectants
• (b) photocatalytic material
• (c) surfactant,

contains.

Cleaning power in the sense invention means the ability to the intensity soiling or impurities, especially microbial Impurities, e.g. B. on hard surfaces or on textile treatment objects at least to lessen, if not completely, the pollution remove.

The in the substrate according to the invention contained photocatalytic material uses electromagnetic Radiation of a suitable wavelength range, by virtue of which z. As contaminants or microbes by photocatalytic or photochemical reaction, e.g. B. by oxidation or reduction, degradable, can be deactivated or reduced. The photocatalytic material is in particular a daylight-active material, in particular a daylight active bleach, so uses the electromagnetic Radiation of daylight.

The photocatalytic activity of the photocatalytic material advantageously refers to natural or artificial light having a wavelength in the range of 300-1200 nm, preferably between 380 and 800 nm. When the photocatalytic material in particular is perceived by the human eye exploitable radiation of the visible region of the spectrum with wavelengths between 380 and 800 nm for the above purposes of degradation, deactivation or reduction of harmful microflora, then there is a preferred embodiment of the invention.

One Advantage of the subject invention is that both the textile substrate such. As a cloth or sponge or sponge cloth, as such, as well as those treated with it surfaces benefit from the invention. The treated surfaces benefit from the cleaning power of the article according to the invention, in particular in terms of removing colored stains. Likewise benefits but also the textile substrate and thus also the user of the same.

• – rote bis blaue Anthocyanfarbstoffe, wie z. B. Cyanidin, z. B. aus Kirschen oder Heidelbeeren,
• – rotes Betanidin aus der roten Beete,
• – orangerote Carotinoide wie z. B. Lycopin, beta-Carotin, z. B. aus Tomaten oder Möhren,
• – gelbe Curcumafarbstoffe, wie z. B. Curcumin, z. B. aus Curry und Senf,
• – braune Gerbstoffe, z. B. aus Tee, Obst, Rotwein
• – tiefbraune Huminsäure, z. B. aus Kaffee, Tee, Kakao,
• – grünes Chlorophyll, z. B, aus grünen Gräsern,
• – technische Farbstoffe aus Kosmetika, Tinten, Farbstiften,
• – farbige Stoffwechselprodukte und/oder Ausscheidungsprodukte von Schimmelpilzen oder anderer Mirkoflora oder mikrobiellem Bewuchs oder Mikroben,

einen Selbstreinigungseffekt zeigt, als Resultat der Einwirkung elektromagnetischer Strahlung, und somit optisch ansehnlicher bleibt. Dies ist besonders wichtig bei wiederverwendbaren Tüchern, Schwammtüchern oder Schwämmen.Often it is so that you wipes with towels, sponges or sponges in the household spilled liquids, eg. As coffee, ink, curry sauce or red wine. These liquids are at least partially absorbed in the wiping in the cloth, sponge cloth or sponge and leave there then a disturbing color impression, eg. B. brown, while wiping coffee. Usually, the consumer then faces the alternative of disposing of cloth or cleaning it. Advantageously, according to the invention, however, a general cleaning action in the textile substrate (eg cloth, sponge cloth or sponge) is also deployed as such, so that the cloth, sponge cloth or sponge after contamination with soiling, which in particular decrease

• - red to blue anthocyanin dyes, such as. B. cyanidin, z. From cherries or blueberries,
• - red betanidin from the red bed,
• - orange-red carotenoids such. As lycopene, beta-carotene, z. From tomatoes or carrots,
• - Yellow curcuma dyes, such as. B. curcumin, z. From curry and mustard,
• - brown tannins, z. B. from tea, fruit, red wine
• - deep brown humic acid, z. B. from coffee, tea, cocoa,
• - green chlorophyll, z. B, from green grasses,
• - technical dyes of cosmetics, inks, color pencils,
• - colored metabolites and / or excretions of mold or other micro flora or microbial growth or microbes,

shows a self-cleaning effect, as a result of exposure to electromagnetic radiation, and thus visually more attractive. This is especially important for reusable towels, sponges or sponges.

Such Reusable according to the invention towels, Schwammtücher or sponges remain hygienically unproblematic even after repeated use as conventional towels, Sponge cloths or Sponges. As you know, you need namely Microbes, which are regularly in moist towels or sponges settle, for her prospering water. As appropriate substrates such as household towels or sponges in the Usually but not subject to rapid drying, offer they are due to their residual moisture ideal settlement and propagation requirements for microbes, such as B. bacteria and / or fungal colonies. As a result, are used towels and sponges Often heavily polluted microbially and a haven for pathogens. As result the action of electromagnetic radiation in interaction with the contained photocatalytic material in the textile according to the invention Substrate, e.g. As cloth or sponge, the microbes in the substrates of the invention but continuously repulsed or dismantled. This is very beneficial.

Often point used towels, sponge cloths or sponges Furthermore still a bad, usually musty smell on. Also this is counteracted according to the invention. Another advantage of the subject invention is thus in that it helps to reduce, eliminate or neutralize fetid odors contributes both regarding the treated objects as well as the cloth used, Sponge or sponge cloth itself. The fetid odor can be advantageously be mitigated so that a previously existing odor nuisance no longer available. The development of fetid odors can be prevented for a longer period of time become.

This is a big Advantage, since in total (a) a general cleaning performance with (b) Combining the removal of microbes in one step can and in addition (c) blocking or preventing fetid odors each having a long-term effect is provided. This affects both the treated objects as well as the textile substrate used, for. B. cloth. This multiple effect goes over the functionality the established cloths clearly beyond. This multiple effect is especially for those Beneficial users who have a weakened organism (seniors, Ill) and vulnerable react to microbes and germs.

One Another advantage is the skin-friendliness of the textile according to the invention Substrates (cloths). This is especially important because appropriate wipes regularly with your bare hands to be used. The present invention now provides z. Cleaning wipes wide, which have a high cleaning power, even against mold or harmful Microflora, but still be used easily with the bare hand.

advantageously, even the light passes through glass windows in closed living rooms incident (diffused daylight) to achieve the desired cleaning effect against To ensure contamination or microbes. Even light off technical light sources (artificial light), such. B. from commercial lightbulbs (Light bulbs), Halogen lamps, fluorescent tubes, Compact fluorescent lamps (energy-saving lamps) and light sources based on light-emitting diodes, is sufficient to achieve the desired effect to effect. For outdoor applications goes the natural Sunlight, even in diffuse solar radiation, completely out, to achieve very good effects.

The Allow substrates not just the elimination of conventional Pollution, but, as already described, the Elimination, deactivation, denaturation or reduction of Microbes, especially harmful Microflora or microbial growth, especially of algae, Blue-green algae, lichens, sprouts, fungi, molds, mold spores, Yeasts, mites, preferably house dust mites, or more generally of (indoor) pollutants with allergenic potential.

Under Noxa is understood here as a factor affecting the human organism damage, but at least impair the human being in his well-being can. These are especially the factors just mentioned, especially microbiological factors such as viruses, bacteria, fungi, etc.

The Substrate material (textile substrate) is preferably made of porous materials, which are in particular able to absorb a drinking liquid reversibly and deliver. In question are three-dimensional structures, such as sponges, in particular synthetic sponges, preferably however flat towels or rags or sponge cloths. These towels can z. B. consist of a fibrous or cellular flexible material. However, it can according to the invention also about composites of textile materials and slides acting on what a preferred embodiment the invention corresponds, for. B. nonwoven-film composites, for example, two-layer composites, the z. B. consist of a nonwoven and a protective or barrier film, or three-layer composites, the z. B. from a fleece and two protective or barrier film (sandwich structure), wherein the fleece in the middle is. Similarly, three-layer composites are possible, the z. B. consist of two webs and a protective or barrier film (Sandwich structure), with the protective or barrier film in the middle is. Such composites are also textile substrates in the context of the invention.

If the textile substrate a natural and / or synthetic textile substrate comprises material selected from Components comprising wool, cotton, silk, jute, hemp, linen, Sisal, ramie, rayon, cellulose esters, polyvinyl derivatives, polyolefins, Polyamides, polyester, felt, paper, hydrophilic polyurethane foam, Nonwovens, preferably based on viscose or cellulose acetate, Nonwovens, preferably based on polylactides, -glycoliden and their copolyesters and polyvinyl alcohol (derivat) s and any Mixtures thereof, so is a preferred embodiment of the invention.

The textile substrate can z. B. a woven, tufted, with involvement of binding yarns or filaments stitched through wet rollers felted, knitted or knitted textile fabric and it can also be non-woven (not knitted) or knitted textile fabric), so-called Nonwovens act. It can Nonwovens can also be combined with the other materials.

Nonwovens include nonwovens and nonwovens. A nonwoven is a processed layer, web or web of directional or randomly oriented fibers, solidified by friction and / or cohesion and / or adhesion. The fibers may be of natural origin or chemical fibers. They may be present as staple fibers or continuous filaments or formed in situ. Sheet formation can be accomplished by mechanically conditioning and dry laying the fibers in flat ribbon form (dry process), by mechanically conditioning the fibers and laying the fibers on a belt (airlaid), slurrying the fibers in water, and laying them on a wire belt (Wet process) and / or by directly laying the spun-jet spun fibers on a belt or a roll (spunbonding process). The dry process and the spunbond process are preferred. The bonding of the fibers can be carried out by bonding with aqueous dispersions (for example polyacrylates, polyvinyl acetates, butadiene-styrene latices), heat, ultrasound, high frequency, mechanical needling (op with additional binder) and / or by needling with water. As raw materials for nonwovens as well as for all other textile substrates, it is possible to use all the fibers used in the classical textile sector, with the man-made fibers being preferred.

suitable Man-made fibers, which preferably form part of the textile substrates could be, are z. Acetate fibers, alginate fibers, aramid fibers, cupro fibers, Elastane fibers, elasto fibers, Fluorofiber fibers, glass fibers, carbon fibers, lyocell fibers, Metal fibers, modacrylic fibers, modal fibers, polyacrylic fibers, polyamide fibers, Polyester fibers, polyethylene fibers, polyimide fibers, polypropylene fibers, Polychloride fibers, triacetate fibers, Vinylal fibers, viscose fibers. But most suitable are polypropylene fibers, Polyester fibers, viscose fibers, acrylic fibers, polyamide fibers, Fibers based on polylactides, glycolides and their copolyesters, and polyvinyl alcohol (derivative) fibers, and / or mixtures of the foregoing Fibers, but especially polypropylene fibers.

Under the natural fiber, which preferably part of the textile substrates could be, the most suitable fibers are seed fibers, such as B. cotton or Kapok, bast fibers, such. As flax, linen, hemp, jute, hard fibers such as sisal or coconut (fibers), animal fibers such as wool, virgin wool, Alpaca hair, llama hair, camel hair wool, angora wool, mohair, horsehair, goat hair, Silk, fiber blends of the aforementioned fibers. But more suitable are the chemical fibers. It is also the combined use of natural and chemical fibers possible.

in the upper part has already been and for the term "textiles Substrate "as a substitute also used the term "cloth". The term "cloth" is intended to cover all others textile substrates include, in particular sheet-like substrates, such. B. sponges or sponge cloths.

Preferably, wipes according to the invention, in particular conditioning substrates, have an area of 0.002 to 0.25 m ² , preferably of 0.01 to 0.15 m ² , in particular of 0.03 to 0.1 cm ² and particularly preferably of 0.06 to 0.09 m ² . This corresponds to a preferred embodiment of the invention. The wipes may have any shape, but are preferred forms viewed from above (top view) square, rectangular, round, oval or trapezoidal. This corresponds to a preferred embodiment of the invention. The basis weight of the cloth according to the invention is advantageously between 10 and 1000 g / m ² , preferably from 25 to 400 g / m ² , in particular from 30 to 300 g / m ² and particularly preferably from 40 to 200 g / m ² . This corresponds to a preferred embodiment of the invention.

Cloths having a basis weight of in particular 40 to 240 g / m ² , which may still be roughened, sanded, brushed or point calendered, may preferably be used as general-purpose and / or dishcloths. Cloths having a basis weight of in particular 40 to 140 g / m ² , which may still be printed, may preferably be used as sanitary wipes. Wipes having a basis weight of in particular 80 to 200 g / m ² , which are optionally still embossed and / or printed, can preferably be used as window and / or glass cloths. Cloths having a basis weight of in particular 100 to 250 g / m ² , which are optionally still embossed, can preferably be used as a building cleaning cloth. Cloths having a basis weight of in particular 100 to 280 g / m 2, which may still be roughened, sanded, brushed and / or printed, may preferably be used as dusters. Cloths having a basis weight of in particular 140 to 500 g / m 2, which may still be roughened, sanded, brushed and / or printed, may preferably be used as floor cloths.

In a preferred embodiment of the invention the sheet-like substrate according to the invention (Cloth) microfibers, in particular microfibers with a titer in the Range of 0.1 to 1 dtex, preferably 0.3 to 1 dtex.

dtex is a unit of measurement for the Strength of fibers based on their "mean Fineness "or" titer "(titer = mass / length = density × cross-sectional area; unit: dtex = 1 g / 10000 m).

Also according to the invention coarse fibers (> 7 dtex), medium fine fibers (2,4-7 dtex), fine fibers (1-2,4 dtex) and / or mixtures of the above-mentioned can be used and component of the sheet-like invention Be substrate (cloth). This corresponds to a preferred embodiment the invention. It is also possible to use mixtures with microfibers.

In a preferred embodiment of the invention, the object according to the invention is characterized in that the textile substrate comprises two or more layers, each layer being in front of preferably has a different texture, a different abrasiveness and / or a different moisture absorption, and wherein in particular only one of the layers is acted upon by photocatalytic material.

With Texture is the directional orientation of higher structural units of Macromolecules, like they are in textile fibers z. B. in rotation, curl or ripple, meant. The formation of such texture, which is the case with chemical fibers Achieves texturing, gives the fibers, yarns and fabrics (cloth according to the invention) desirable Features such as volume increase, elastic elongation, increased moisture absorption, improved thermal insulation through air pockets, fluffy handle, increased abrasiveness.

When photocatalytic material is according to a preferred embodiment of the invention contain titanium dioxide, in particular a modified one Titanium dioxide, preferably a carbon-modified titanium dioxide.

The photocatalytic material, in particular the (preferably modified) Titanium dioxide, according to a preferred embodiment of the invention in the substrate according to the invention in amounts of advantageously 0.0001 to 30 wt .-%, preferably 0.001 to 20 wt .-%, advantageously 0.01 to 15 wt .-%, in a further advantageous manner 0.1 to 10 wt .-%, even more advantageous 1 to 5 wt .-%, wt .-% based on the total composition, with which the substrate impregnated / acted / impregnated / coated is According to a preferred embodiment it is the (preferably modified) titanium dioxide a carbon-modified titanium dioxide. But it can also differently modified titanium dioxides are used, for example with nitrogen modified titanium dioxide or z. B. with rhodium and / or Platinum ions doped titanium dioxide. However, it is particularly according to the invention preferably that it is non-metal modified titanium dioxide is.

The carbon content of the advantageously carbon-modified titanium dioxide may in a preferred embodiment in the range of 0.01 to 10 wt .-%, preferably from 0.05 to 5.0 wt .-%, advantageously from 0.3 to 1.5 wt. %, in particular from 0.4 to 0.8% by weight. Advantageously, the TiO ₂ content of the carbon-modified titanium dioxide z. B. over 95 wt .-%, 96 wt .-%, 97 wt .-%, 98 wt .-% or 99 wt .-%, based on the total carbon-modified titanium dioxide.

If the carbon only in a surface layer of the titanium dioxide particles is embedded, so is a preferred embodiment. The modified one Titanium dioxide may advantageously additionally contain nitrogen.

If the specific surface of the titanium dioxide, preferably of the modified titanium dioxide, according to BET (BET advantageously determined according to DIN ISO 9277: 2003-05, preferably also simplified according to DIN 66132: 1975-07) preferably 50 to 500 m ² / g, advantageously 100 to 400 m ² / g, in a further advantageous manner 200 to 350 m ² / g, in particular 250 to 300 m ² / g, so is also a preferred embodiment.

The carbon-modified titanium dioxide may according to a preferred embodiment, for. Example, be obtained by intimately mixing a titanium compound having a specific surface area of preferably at least 50 m ² / g by BET, with an organic carbon compound and the mixture is thermally treated at a temperature of up to 350 ° C.

The thereby usable carbonaceous substance can according to a preferred Embodiment one Be carbon compound, which is at least one functional group contains preferably selected from OH, CHO, COOH, NHx, SHx. In particular, it may be in the carbon compound a compound from the group of ethylene glycol, glycerol, succinic acid, pentaerythritol, Carbohydrates, sugar, starch, Alkyl polyglucosides, organoammonium hydroxides or mixtures thereof act. It is also possible, used as the carbonaceous substance soot or activated carbon becomes.

It may also be preferred that the carbonaceous substance, which is advantageously mixed with the titanium compound, after the thermal treatment to the modified titanium dioxide to reach a decomposition temperature of at most 400 ° C, preferably <350 ° C. and particularly preferably <300 ° C.

The titanium compound which can preferably be used for the preparation of the modified titanium dioxide, which according to the aforementioned preferred embodiment with an organic carbon compound intimately ver may be an amorphous, partially crystalline or crystalline titanium oxide or hydrous titanium oxide or a titanium hydrate or a titanium oxyhydrate, which in turn corresponds to a preferred embodiment.

The thermal treatment of the mixture of the titanium compound and the Carbon compound can according to a preferred embodiment advantageously in a continuously operated calcining unit, preferably a rotary kiln are performed. The modified one Titanium dioxide can be, in particular in the context of the previously described, preferably z. B. obtained thereby, that a titanium dioxide (eg with a particle size in the range between 2 to 600 nm or z. B. 3 to 150 nm or z. B. 4 to 100 nm or z. B. 5 to 75 nm or z. B. 10 to 30 nm or z. 200 to 400 nm), such as commercially available in Powder or mud form, takes and from this a suspension in a liquid, as preferably water, produces. To the suspension is then advantageously added a carbonaceous substance and it is mixed. The mixing can be supported by the use from ultrasound. The mixing process (eg stirring) may preferably be several Hours, preferably 2, 4, 6, 8, 10 or 12 hours or even longer. Based on the solids of the suspension, the amount of the carbon compound advantageously 1-40 % By weight, accordingly, the amount of the titanium compound is preferably 60-99 Wt .-%.

After that becomes the liquid removed, for example by filtration, evaporation in vacuo or Decant, and the residue is preferably dried (eg, preferably at temperatures of 70-200 ° C, advantageously over several Hours, for example at least 12 hours) and then calcined, for example at a temperature of at least 260 ° C, preferably z. At 300 ° C, preferably over a period of several hours, preferably 1-4 hours, in particular 3 hours. The calcination can advantageously take place in a closed vessel. It may be advantageous that the calcination temperature, eg. B. 300 ° C, within one hour is reached (slow heating to 300 ° C).

there is preferably a color change of the powder from white to dark brown to beige or slightly yellowish-brownish determine. Too long heating leads to inactive, colorless Powders. The expert can estimate this with a few routine experiments. The Calcination can z. B. advantageously so long until after a color change of the powder from white to dark brown another Color change takes place on beige or slightly yellowish-brownish.

A maximum temperature of 350 ° C should preferably not be exceeded become. Thermal treatment causes decomposition the organic carbon compound on the surface of the Titanium compound, so that preferably a modified titanium dioxide arises, which preferably contains 0.005-4 wt .-% carbon.

After the thermal treatment, the product is advantageously deagglomerated by known methods, for example in a pin mill, jet mill or counter-jet mill. The grain fineness to be achieved depends on the grain size of the starting titanium compound. The particle size or specific surface area of the product is only slightly lower, but of the same order of magnitude as that of the educt. The desired grain fineness of the photocatalyst depends on the field of application of the photocatalyst. It is usually in the range as with TiO ₂ pigments, but may also be below or above.

The in the substrate according to the invention contained photocatalytic material, preferably modified titanium dioxide may advantageously have a particle size in the range between 2 to 600 nm, ie z. B. 3 to 150 nm or z. B. 4 to 100 nm or z. B. 5 to 75 nm or z. B. 10 to 30 nm or z. B. 200 to 400 nm. The particle size of the photocatalytic Although materials, preferably modified titanium dioxide, although preferably in the range of 100-500 nm, advantageously 200-400 nm lie. It may also be preferred that the particle size is very high is small, z. In the range of 2-150 nm, preferably 3-100 nm, advantageously 4-80 nm or z. 5-50 nm or z. B. 8-30 nm or z. B. 10-20 nm is located. Very small particles, eg. B. with a particle size of particular 2, 3, 4, 5 or 10 nm can also form agglomerates with each other, which are then correspondingly larger, z. Up to 600 nm or up to 500 nm or up to 400 nm or until to 300 nm, etc. The particle size can z. Advantageously at values such as 5 nm, 10 nm, 15 nm, 20 nm, 25 nm, 30 nm, 35 nm, 40 nm, 45 nm, 50 nm or 60 nm. Especially very small particle sizes below 50 nm, below 40 nm, below 30 nm or below 20 nm may be preferred. It can be advantageous in the preparation of the modified titanium dioxide micronized titanium dioxide, that is, titanium dioxide with very small particle size, e.g. B. between 2 and 150 nm or z. b. between 5 and 100 nm. The particle size can then z. Advantageously at values such as 2 nm, 3 nm, 4 nm, 5 nm, 10 nm, 15 nm, 20 nm, 25 nm, 30 nm, 35 nm, 40 nm, 45 nm, 50 nm or 60 nm. Such values are preferred.

The bulk density of the preferably modified titanium dioxide is preferably in Range from 100 to 800 g / l, advantageously from 200 to 600 g / l, especially from 300-500 g / l. For example, the bulk density 350 g / l, 400 g / l or 500 g / l. According to a preferred embodiment is the (preferably modified) titanium dioxide in the crystal modification Anatas in front.

The The modified titanium dioxide described above is characterized a very good photocatalytic activity, especially under use from daylight, off. In particular, the perceptible by the human eye Radiation of the visible region of the spectrum with wavelengths between 380 and 800 nm will be for the purposes of mining, deactivating or reducing Impurities from the described modified titanium dioxide very well used.

The textile according to the invention Contains substrate Humectant. When used as humectants glycerol, dimers and Trimers of glycerine, ethylene glycol, propylene glycol, hexylene glycol, Sugar alcohols, such as preferably glucitol, xylitol, mannitol, alkylpolyglucosides, fatty acid glucamides, Sucrose esters, sorbitans, polysorbates, polydextrose, polyethylene glycol, preferably with average molecular weights of 200 to 8000, Propanediols, butanediols, triethylene glycol, orthophosphoric acid, citric acid, urea, Sodium chloride, alums, hydrates of aluminum salts, hydrogenated Glucose syrup, D-glucose and / or mixtures of the aforementioned is, preferably in amounts of 0.01 to 50 wt .-%, advantageously From 0.05 to 40% by weight, more preferably from 0.1 to 30% by weight, more advantageously 0.15-20 Wt .-%, more preferably 0.2-10 wt .-%, in particular 0.25-5 wt .-%, Wt .-% based on the total composition with which the Substrate impregnated / applied / impregnated / coated is, then again is a preferred embodiment of the invention.

We could find that in the presence of, preferably organic, Humectant means a very good effect of the agent against impurities resulted, especially when using glycerol. Especially the effect against microbes and harmful microflora, z. Molds, is very good and also has a long-lasting effect, both the cloth concerns as well as the object treated. advantageously, allows the presence of the humectant is a particularly effective and long-lasting effect of the photocatalytic material.

The textile according to the invention Contains substrate Furthermore Surfactant, preferably nonionic surfactant. If a nonionic surfactant is included, preferably from the group of the alkoxylated alcohols, the alkylphenol polyglycol ethers, the alkoxylated fatty acid alkyl ester, the polyhydroxy fatty acid amides, the alkyl glycosides, the alkyl polyglucosides, the amine oxides, the fatty acid glucamides, and / or the long-chain alkyl sulfoxides, preferably in amounts from 0.01 to 30 wt .-%, advantageously 0.1 to 20 wt .-%, in more advantageously 0.5-15% by weight, more advantageously 1-10 Wt .-%, more preferably 1.5-5 wt .-%, in particular 2-4 wt .-%, Wt .-% based on the total composition with which the Substrate impregnated / applied / impregnated / coated is, then again is a preferred embodiment of the invention.

We could find that in the presence of nonionic surfactant a further improved Effect of the agent resulted, especially when using amine oxide. In particular, the effect against microbes could be compared to recipes, that did not contain nonionic surfactant, should be further improved.

Especially advantageous are formulations which contain a, preferably organic, Humectants and nonionic surfactant, in particular the combination from glycerine and amine oxide.

To a preferred embodiment of the invention the textile according to the invention Substrate anionic surfactant, preferably selected from alkanesulfonates, alkylbenzenesulfonates, Fatty alcohol polyglycol ether sulfates, fatty alcohol sulfates, alkyl sulfates, Monoglyceride sulfates, ester sulfonates, lignosulfonates, fatty acid cyanamides, N-alkyl glutamates anionic sulfosuccinic acid surfactants, fatty acid isethionates, Acylaminol kansulfonates, fatty acid sarcosinates (N-alkyl sarcosinates), ether carboxylic acids and alkyl (ether) phosphates advantageously in amounts of 0.01 to 30 wt .-%, advantageously 0.1 to 20% by weight, more preferably 0.5-15% by weight, more advantageously 1-10 Wt .-%, more preferably 1.5-5 wt .-%, in particular 2-4 wt .-%, Wt .-% in each case based on the total composition, with which the Substrate impregnated / applied / impregnated / coated is.

According to a further preferred embodiment of the invention, the textile substrate according to the invention comprises preservatives, in particular oils, cationic surfactants, in particular esterquats, layered silicates, fatty acid derivatives, silicone oils, polymers, such as preferably silicone-based cationic surfactants or polymers based on polyethylene, preferably in an amount from 0.05 to 20% by weight, preferably 0.1-10 Wt .-%, wt .-% based on the total composition with which the substrate is impregnated / impregnated / impregnated / coated. Even upper limit of 5 wt .-%, 3 wt .-% or 2 wt .-% of Aviviermittel may be useful.

hand modifiers help the grip, the shine, the color brilliance, the softness and / or the smoothness to improve the tissue treated with it. Particularly suitable Esterquats. Esterquat is the collective name for cationic surfactants Compounds with two hydrophobic groups, which via ester bonds with a quaternized di (tri) ethanolamine or an analogous compound connected are. Suitable lubricants are described below. The avivage component includes, for example, quaternary Ammonium compounds such as monoalk (en) yltrimethylammonium compounds, Dialk (en) yldimethylammonium compounds, mono-, di- or triesters of fatty acids with alkanolamines.

wobei in (I) R für einen acyclischen Alkylrest mit 12 bis 24 Kohlenstoffatomen, R¹ für einen gesättigten C₁-C₄ Alkyl- oder Hydroxyalkylrest steht, R² und R³ entweder gleich R oder R¹ sind oder für einen aromatischen Rest stehen. X^– steht entweder für ein Halogenid-, Methosulfat-, Methophosphat- oder Phosphation sowie Mischungen aus diesen. Beispiele für kationische Verbindungen der Formel (I) sind Monotalgtrimethylammoniumchlorid, Monostearyltrimethylammoniumchlorid, Didecyldimethylammoniumchlorid, Ditalgdimethylammoniumchlorid oder Dihexadecylammoniumchlorid.Suitable examples of employable quaternary ammonium compounds are shown, for example, in the formulas (I) and (II):

wherein in (I) R is an acyclic alkyl radical having 12 to 24 carbon atoms, R ^{1 is} a saturated C ₁ -C ₄ alkyl or hydroxyalkyl radical, R ² and R ^{3 are} either R or R ¹ or are an aromatic radical , X ^- is either a halide, methosulfate, methophosphate or phosphate ion and mixtures thereof. Examples of cationic compounds of the formula (I) are monotaltrimethylammonium chloride, monostearyltrimethylammonium chloride, didecyldimethylammonium chloride, ditallowdimethylammonium chloride or dihexadecylammonium chloride.

Compounds of formula (II), (III) and (IV) are so-called ester quats. Esterquats are characterized by excellent biodegradability. In formula (II) R ^{4 is} an aliphatic alk (en) yl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds and / or optionally with substituents; R ⁵ is H, OH or O (CO) R ⁷ , R ⁶ is, independently of R ^5, H, OH or O (CO) R ⁸ , where R ⁷ and R ⁸ are each independently an aliphatic alk (ene) ylrest having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds. m, n and p can each independently be 1, 2 or 3. X can be either a halide, methosulfate, methophosphate or phosphate ion, as well as mixtures of these anions. Preference is given to compounds in which R ^{5 represents} the group O (CO) R ⁷ . Particular preference is given to compounds in which R ^{5 is} the group O (CO) R ⁷ and R ⁴ and R ^{7 are} alk (en) yl radicals having 16 to 18 carbon atoms. Particularly preferred are compounds in which R ^{6 is} also OH. Examples of compounds of the formula (I) are methyl N- (2-hydroxyethyl) -N, N-di (tallowacyloxyethyl) ammonium methosulfate, bis (palmitoyloxyethyl) hydroxyethylmethylammonium methosulfate, 1,2-bis- [tallowloxy] -3-trimethylammoniumpropane chloride or methyl N, N-bis (stearoyloxyethyl) -N- (2-hydroxyethyl) ammonium methosulfate.

Are z. B. quaternized compounds of formula (11) are used which have unsaturated alkyl chains, the acyl groups are preferred, the corresponding fatty acids have an iodine number between 1 and 100, preferably between 5 and 80, more preferably between 10 and 60 and in particular between 15 and 45 and having a cis / trans isomer ratio (in wt%) of greater than 30:70, preferably greater than 50:50, and more preferably equal to or greater than 60:40. Commercial examples are sold by Stepan under the tradename Stepantex ^® methylhydroxyalkyldialkoyloxyalkylammonium or those known under Dehyquart ^® Cognis products, known under Rewoquat ^® products from Degussa or those known under Tetranyl ^® products of Kao. Further preferred compounds are the diesterquats corresponding to formula (III) which are obtainable under the name Rewoquat ^® 3099 W 222 LM or CR.

R ²¹ and R ²² are each independently an aliphatic radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds.

Instead of the ester group O (CO) R, where R is a long-chain alk (en) yl radical, z. B. plasticizer compounds are used which have the following groups: RO (CO), N (CO) R or RN (CO), of which N (CO) R groups are preferred.

wobei R⁹ für H oder einen gesättigten Alkylrest mit 1 bis 4 Kohlenstoffatomen, R¹⁰ und R¹¹ unabhängig voneinander jeweils für einen aliphatischen, gesättigten oder ungesättigten Alkylrest mit 12 bis 18 Kohlenstoffatomen, R¹⁰ alternativ auch für O(CO)R²⁰ stehen kann, wobei R²⁰ einen aliphatischen, gesättigten oder ungesättigten Alkylrest mit 12 bis 18 Kohlenstoffatomen bedeutet, und Z eine NH-Gruppe oder Sauerstoff bedeutet und X^– ein Anion ist. q kann ganzzahlige Werte zwischen 1 und 4 annehmen.In addition to the optional quaternary compounds described above, e.g. B. Other compounds are used as softening component, such as, for example, quaternary imidazolinium compounds of the formula (IV),

where R ^{9 is} H or a saturated alkyl radical having 1 to 4 carbon atoms, R ¹⁰ and R ¹¹ are each independently an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms, R ^{10 may} alternatively be O (CO) R ²⁰ wherein R ^{20 is} an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms, and Z is an NH group or oxygen and X ^{- is} an anion. q can take integer values between 1 and 4.

wobei R¹², R¹³ und R¹⁴ unabhängig voneinander für eine C_1-4-Alkyl-, Alkenyl- oder Hydroxyalkylgruppe steht, R¹⁵ und R¹⁶ jeweils unabhängig ausgewählt eine C_8-28-Alkylgruppe darstellt, X^– ein Anion ist und r eine Zahl zwischen 0 und 5 ist. Ein bevorzugtes Beispiel einer kationischen Abscheidungshilfe gemäß Formel (V) ist 2,3-Bis[talgacyloxy]-3-trimethylammoniumpropanchlorid.Further particularly preferably employable softening compounds are described by formula (V),

wherein R ¹² , R ¹³ and R ¹⁴ independently represent a C _1-4 alkyl, alkenyl or hydroxyalkyl group, each of R ¹⁵ and R ¹⁶ independently represents a C _8-28 alkyl group, X ^{- is} an anion and r is a number between 0 and 5. A preferred example of a cationic deposition aid according to formula (V) is 2,3-bis [tallowacyloxy] -3-trimethylammoniumpropane chloride.

Further usable according to the invention Softening components provide quaternized protein hydrolysates or protonated amines.

Furthermore, cationic polymers are also suitable softening component. Suitable cationic polymers include the polyquaternium polymers as described in the CTFA Cosmetic Ingredient Dictionary (The Cosmetic, Toiletry and Fragrance, Inc., 1997), in particular the Polyquaternium-6, Polyquaternium-7, Polyquaternium, also referred to as Merquats. 10 polymers (Polymer JR, LR and KG series from Amerchol), polyquaternium-4 copolymers such as graft copolymers having a cellulose backbone and quaternary ammonium groups attached via allyldimethylammonium chloride, cationic cellulose derivatives such as cationic guar such as guar hydroxypropyltriammonium chloride, and similar quaternized guar Derivatives (eg Cosmedia Guar from Cognis or the Jaguar series from Rhodia), cationic quaternary sugar derivatives (cationic alkyl polyglucosides), e.g. As the commercial product Glucquat ^® 100, according to CTFA nomenclature a "Lauryl Methyl Gluceth-10 hydroxypropyl Dimonium Chloride", copolymers of PVP and dimethylaminomethacrylate, copolymers of vinylimidazole and vinylpyrrolidone, aminosilicone polymers and copolymers.

Polyquaternized polymers (for example Luviquat ^® Care from BASF.), And cationic biopolymers based on chitin and derivatives thereof, for example, under the trade designation chitosan ^® (manufacturer: Cognis) polymer obtainable.

Some said cationic polymers additionally have skin and / or textile care Properties on.

Also usable are compounds of the formula (VI)

R ¹⁷ can be an aliphatic alk (en) yl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 doublebin be his. s can take values between 0 and 5. R ¹⁸ and R ¹⁹ are each independently H, C _1-4 alkyl or hydroxyalkyl and X ^- is an anion.

Further Suitable softening components include protonated or quaternized Polyamines.

Especially preferred plasticizing components are alkylated quaternary ammonium compounds, of which at least one alkyl chain by an ester group and / or Amido group is interrupted. Very particularly preferred are N-methyl-N- (2-hydroxyethyl) -N, N- (ditalgacyloxyethyl) ammonium methosulfate or bis (palmitoyloxyethyl) hydroxyethyl methyl ammonium methosulfate.

It can Also included are nonionic softening components, such as especially polyoxyalkylene glycol alkanoates, polybutylenes, long chain fatty acids, ethoxylated fatty acid ethanolamides, Alkyl polyglucosides, in particular sorbitan mono, di- and triesters, and fatty acid esters of polycarboxylic acids

Also among the most preferred optionally usable softening agents are cationic cellulose derivatives, cationic starches, copolymers of a diallyl quaternary ammonium salt and an acrylamide, quaternized vinylpyrrolidone vinylimidazole polymer polyglycolamine condensates, quaternized collagen polypeptides, polyethyleneimine, cationized silicon polymer (e.g., amodimethicone), cationic silicon polymers, z. B. prepared in a blend with other components under the trademark Dow Corning 929 (cationized emulsion), copolymers of adipic acid and dimethylaminohydroxypropyldiethylenetriamine, cationic chitin derivatives, cationized guar gum (e.g., Jaguar CBS, Jaguar C-17, Jaguar C-16, etc.) from the Celanese Company), quaternary ammonium salt polymers (e.g., Mirapol A-15, Mirapol AD-1, Mirapol AZ-1, etc., manufactured by the Miranol Division of the Rhone Poulenc Company). Particularly preferred is polyquaternium-11 available as Luviquat.RTM ^® PQ 11 sold by the BASF Corporation.

• a) Wachse wie beispielsweise Carnauba, Spermaceti, Bienenwachs, Lanolin und/oder Derivate derselben und andere.
• b) Hydrophobe Pflanzenextrakte
• c) Kohlenwasserstoffe wie beispielsweise Squalene und/oder Squalane
• d) Höhere Fettsäuren, vorzugsweise solche mit wenigstens 12 Kohlenstoffatomen, beispielsweise Laurinsäure, Stearinsäure, Behensäure, Myristinsäure, Palmitinsäure, Ölsäure, Linolsäure, Linolensäure, Isostearinsäure und/oder mehrfach ungesättigte Fettsäuren und andere.
• e) Höhere Fettalkohole, vorzugsweise solche mit wenigstens 12 Kohlenstoffatomen, beispielsweise Laurylalkohol, Cetylalkohol, Stearylalkohol, Oleylalkohol, Behenylalkohol, Cholesterol und/oder 2-Hexadecanaol und andere.
• f) Ester, vorzugsweise solche wie Cetyloctanoate, Lauryllactate, Myristyllactate, Cetyllactate, Isopropylmyristate, Myristylmyristate, Isopropylpalmitate, Isopropyladipate, Butylstearate, Decyloleate, Cholesterolisostearate, Glycerolmonostearate, Glyceroldistearate, Glyceroltristearate, Alkyllactate, Alkylcitrate und/oder Alkyltartrate und andere.
• g) Lipide wie beispielsweise Cholesterol, Ceramide und/oder Saccharoseester und andere.
• h) Vitamine wie beispielsweise die Vitamine A und E, Vitaminalkylester, einschließlich Vitamin C Alkylester und andere.
• i) Sonnenschutzmittel
• j) Phospholipide
• k) Derivate von alpha-Hydroxysäuren
• m) Germizide für den kosmetischen Gebrauch, sowohl synthetische wie beispielsweise Salicylsäure und/oder andere als auch natürliche wie beispielsweise Neemöl und/oder andere.
• n) Silikone

sowie Mischungen jeglicher vorgenannter Komponenten.According to a preferred embodiment of the invention, skin care products or skin-care active substances are also contained, in particular in amounts of> 0.01% by weight, based on the total composition with which the substrate is impregnated / applied / impregnated / coated. Skin care products (skin-care active substances) may be, in particular, those which give the skin a sensory advantage, eg. By delivering lipids and / or moisturizing factors. Skin care products may, for. Proteins, amino acids, lecithins, lipids, phosphatides, plant extracts, vitamins; Likewise, fatty alcohols, fatty acids, fatty acid esters, waxes, petrolatum, paraffins can act as skin care agents. Skin-care active substances are all those active substances which give the skin a sensory and / or cosmetic advantage. Skin-care active substances are preferably selected from the following substances:

• a) waxes such as carnauba, spermaceti, beeswax, lanolin and / or derivatives thereof and others.
• b) Hydrophobic plant extracts
• c) hydrocarbons such as squalene and / or squalane
• d) Higher fatty acids, preferably those having at least 12 carbon atoms, for example lauric acid, stearic acid, behenic acid, myristic acid, palmitic acid, oleic acid, linoleic acid, linolenic acid, isostearic acid and / or polyunsaturated fatty acids and others.
• e) Higher fatty alcohols, preferably those having at least 12 carbon atoms, for example, lauryl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, behenyl alcohol, cholesterol and / or 2-hexadecanol and others.
• f) esters, preferably such as cetyloctanoates, lauryl lactates, myristyl lactates, cetyl lactates, isopropyl myristates, myristyl myristates, isopropyl palmitates, isopropyl adipates, butyl stearates, decyl oleates, cholesterol stearates, glycerol monostearates, glycerol distearates, glycerol tristearates, alkyl lactates, alkyl citrates and / or alkyl tartrates and others.
• g) lipids such as cholesterol, ceramides and / or sucrose esters and others.
• h) vitamins such as vitamins A and E, vitamin C esters, including vitamin C alkyl esters and others.
• i) sunscreen
• j) phospholipids
• k) derivatives of alpha hydroxy acids
• m) Germicides for cosmetic use, both synthetic and, for example, salicylic acid and / or others as well as natural ones such as neem oil and / or others.
• n) silicones

as well as mixtures of any of the aforementioned components.

preferred skin-care active substances are also essential oils, in particular selected from the group of Angelics fine - Angelics archangelica, aniseed - Pimpinella Anisum, Benzoin siam - Styrax tokinensis, Cabreuva - Myrocarpus fastigiatus, Cajeput - Melaleuca leucadendron, Cistus - Cistrus ladaniferus, Copaiba balm - Copaifera reticulata, costus root - Saussurea discolor, Edeltannennadel - Abies alba, Elemi - Canarium luzonicum, fennel - foeniculum dulce spruce needle - Picea Abies, Geranium - Pelargonium graveolens, Ho leaves - Cinnamonum camphora, immortelle (straw flower) Helichrysum ang., ginger extra - zingiber off., St. John's Wort - Hypericum perforatum, jojoba, chamomile german - Matricaria recutita, chamomile blue fine - Matricaria chamomilla, chamomile rom. - Anthemis nobilis, chamomile wild - Ormensis multicaulis, carrot - Daucus carota, mountain pine - Pinus mugho, lavandin - lavender hybrida, Litsea Cubeba - (May Chang), Manuka - Leptospermum scoparium, melissa - Melissa officinalis, sea pine - Pinus pinaster "Myrrh - Commiphora molmol, myrtle - myrtus communis, Neem - Azadirachta, Niaouli - (MQV) Melaleuca quin. viridiflora, Palmarosa - Cymbopogom martini, Patchouli - Pogostemon Patschuli, Peruvian Balsam - Myroxylon balsamum var. pereirae, Raventsara aromatica, rosewood - Aniba pink odora, sage - salvia officinalis horsetail - Equisetaceae, Yarrow extra - Achillea millefolia, ribwort plantain - Plantago lanceolata, Styrax - Liquidambar orientalis, Tagetes (Marigold) Tagetes patula, Tea Tree - Melaleuca alternifolia, tolu balsam - Myroxylon Balsamum L., Virginia Cedar - Juniperus virginiana, frankincense (Olibanum) - Boswellia carteri, silver fir - Abies alba.

preferred skin-care active substances are also skin-protecting oils, in particular selected from Group algae oil Oleum Phaeophyceae, Aloe Vera Oil Aloe vera brasiliana, apricot kernel oil Prunus armeniaca, arnica Arnica montana, avocado oil Persea americana, borage oil Borago officinalis, calendula oil Calendula officinalis, camellia oil Camellia oleifera, thistle oil Carthamus tinctorius, Peanut Oil Arachis hypogaea, hemp oil Cannabis sativa, hazelnut oil Corylus avellana /, St. John's wort oil Hypericum perforatum, jojoba oil Simondsia chinensis, carrot oil Daucus carota, coconut oil Cocos nucifera, pumpkin seed oil Curcubita pepo, kukui nut oil Aleurites moluccana, macadamia nut oil macadamia ternifolia, almond oil Prunus dulcis, olive oil Olea europaea, peach kernel oil Prunus persica, rapeseed oil Brassica oleifera, castor oil Ricinus communis, black seed oil Nigella sativa, sesame oil Sesamium indicum, sunflower oil Helianthus annus, grapeseed oil Vitis vinifera, walnut oil of Juglans regia, wheat germ oil Triticum sativum.

To a further preferred embodiment of the invention the substrate according to the invention Fragrances (perfume oil), preferably in amounts of from 0.01 to 10% by weight, based on the total composition, with which the substrate impregnated / acted / impregnated / coated is. Promote the fragrances the acceptance of the product by the consumer and convey feeling the cleanliness. Suitable fragrances are described below.

Especially in combination with the humectant and the nonionic surfactant observed a particularly long-lasting odor effect of the fragrances become. This applies both to the substrate according to the invention as such the objects treated with it.

• a) photokatalytisches Material,
• b) Feuchthaltemittel
• c) Niotensid und/oder Aniontensid
• d) optional Kationtensid, vorzugsweise Benzalkoniumchlorid oder Didecylmethylpoly (oxethyl)ammoniumpropionat, vorzugsweise 0 bis 5 Gew.%
• e) optional Gerüststoffe, vorzugsweise Trinatriumcitrat, Natriumsalz der Nitrilotriessigsäure, Natriumphosphonat, Pentanatriumtriphosphat, vorteilhafterweise in einer Menge von 0 Gew.% bis 5 Gew.%, mehr bevorzugt von 0,1Gew.% bis 2 Gew.%;
• f) optional Riechstoff(e), vorzugsweise in einer Menge von 0 Gew.% bis 5 Gew.%, mehr bevorzugt von 0,1Gew.% bis 2 Gew.%;
• g) optional weiteres oberflächenaktives Mittel, vorzugsweise in einer Menge von 0 Gew.% bis 20 Gew.%, insbesondere 0,1 Gew.% bis 10 Gew.%;
• h) optional ein antimikrobielles Mittel, z. B. Alkyldimethylbenzylammoniumsaccharinat, vorzugsweise in einer Menge von 0 Gew.% bis 3 Gew.%, insbesondere von 0,01 Gew.% bis 1 Gew.%;
• i) optional einen Korrosionshemmstoff, z. B. Natriumnitrit, Natriumbenzoat, Monoethanolamin, Triethanolamin oder Ammoniumhydroxid, vorzugsweise in einer Menge von 0 Gew.% bis 20 Gew.%, insbesondere 0,01 Gew.% bis 10 Gew.%
• j) optional Lösemittel und Hydrotrope, vorzugsweise Ethanol, Propylenglycolether, Natriumtoluol- oder -cumolsulfonat, vorzugsweise in einer Menge von 0 Gew.% bis 20 Gew.%, vorteilhafterweise 0,01 Gew.% bis 10 Gew.%, insbesondere 0,1 bis 5 Gew.-%,
• k) Wasser, vorzugsweise in Mengen von ≥ 0 Gew.-%, insbesondere in Mengen > 10 Gew.-%, > 20 Gew.-%, > 30 Gew.-%, > 40 Gew.-%, > 50 Gew.-%, > 60 Gew.-%, > 70 Gew.-%, > 10 Gew.-% oder sogar > 90 Gew.-%,
• l) optional pH-Stellmittel, vorzugsweise gewählt aus der Gruppe der Säuren, wie insbesondere Essigsäure, Citronensäure, Maleinsäure, Ameisensäure, Amidosulfonsäure, Phosphorsäure, Phosphonsäuren, D-Milchsäure, L-Milchsäure, D/L-Milchsäure, Oxalsäure oder aus der Gruppe der Alkalien, wie insbesondere Natronlauge, vorteilhafterweise in Mengen von 0–30 Gew.-%, vorzugsweise 0,01–5 Gew.-%, insbesondere 0,1–3 Gew.-%,
• m) optional Verdicker, insbesondere gewählt aus der Gruppe Hydroxyethylcellulose, Xanthan, Acrylcopolymere, insbesondere im Bereich von 0,03–2 Gew.-%
• n) optional biologische Noxenminderer, wie z. B. Neemöl, Teebaumöl, Farnesol, Tannin(säure), etherische Öle, Terpene, wie insbesondere Citral, Limonen, Beta-Ionon, Linalool, Geraniol, Farnesol, Eugenol, Myrcen oder Carvon, z. B. in Mengen > 0,01 Gew.-%,
• o) optional avivierendes Mittel, vorzugsweise Öle, Kationtenside, wie insbesondere Esterquats, Schichtsilicate, Fettsäure-Derivate,, Siliconöle, Polymere, wie vorzugsweise polymere Kationtenside auf Siliconbasis oder Polymere auf Basis von Polyethylen, insbesondere im Bereich von 0,05 Gew.-% bis 10 Gew.-%,
• p) optional hautpflegende Aktivstoffe, vorzugsweise solche, wie zuvor beschrieben, insbesondere im Bereich von 0,01 Gew.-% bis 10 Gew.-%.

enthält, Gew.-% jeweils bezogen auf die gesamte Zusammensetzung, mit welcher das Substrat imprägniert ist, so liegt wiederum eine bevorzugte Ausführungsform der Erfindung vor.When the textile substrate according to the invention

• a) photocatalytic material,
• b) humectants
• c) nonionic surfactant and / or anionic surfactant
• d) optionally cationic surfactant, preferably benzalkonium chloride or Didecylmethylpoly (oxyethyl) ammonium propionate, preferably 0 to 5 wt.%
• e) optionally builders, preferably trisodium citrate, sodium nitrilotriacetic acid, sodium phosphonate, pentasodium triphosphate, advantageously in an amount of from 0% to 5% by weight, more preferably from 0.1% to 2% by weight;
• f) optionally perfume (s), preferably in an amount of 0% by weight to 5% by weight, more preferably from 0.1% by weight to 2% by weight;
• g) optionally further surfactant, preferably in an amount of 0% by weight to 20% by weight, in particular 0.1% by weight to 10% by weight;
• h) optionally an antimicrobial agent, e.g. B. Alkyldimethylbenzylammoniumsaccharinat, preferably in an amount of 0 wt.% To 3 wt.%, In particular from 0.01 wt.% To 1 wt.%;
• i) optionally a corrosion inhibitor, for. As sodium nitrite, sodium benzoate, monoethanolamine, triethanolamine or ammonium hydroxide, preferably in an amount of 0 wt.% To 20 wt.%, In particular 0.01 wt.% To 10 wt.%
• j) optionally solvent and hydrotropes, preferably ethanol, propylene glycol ether, sodium toluene or cumene sulfonate, preferably in an amount of 0 wt.% To 20 wt.%, Advantageously 0.01 wt.% To 10 wt.%, In particular 0.1 up to 5% by weight,
• k) water, preferably in amounts of ≥ 0 wt .-%, in particular in amounts> 10 wt .-%,> 20 wt .-%,> 30 wt .-%,> 40 wt .-%,> 50 wt. %,> 60% by weight,> 70% by weight,> 10% by weight or even> 90% by weight,
• l) optionally pH adjusting agent, preferably selected from the group of acids, in particular acetic acid, citric acid, maleic acid, formic acid, sulfamic acid, phosphoric acid, phosphonic acids, D-lactic acid, L-lactic acid, D / L-lactic acid, oxalic acid or from the group the alkalis, in particular sodium hydroxide solution, advantageously in amounts of 0-30% by weight, preferably 0.01-5% by weight, in particular 0.1-3% by weight,
• m) optionally thickener, in particular selected from the group hydroxyethyl cellulose, xanthan, acrylic copolymers, in particular in the range of 0.03-2 wt .-%
• n) optionally biological Noxenminderer, such as. As neem oil, tea tree oil, farnesol, tannin (acid), essential oils, terpenes, in particular citral, limonene, beta-ionone, linalool, geraniol, farnesol, eugenol, myrcene or carvone, z. In amounts> 0.01% by weight,
• o) optionally avivating agent, preferably oils, cationic surfactants, in particular esterquats, layered silicates, fatty acid derivatives, silicone oils, polymers, such as preferably silicone-based silicone-based cationic surfactants or polymers based on polyethylene, in particular in the range of 0.05% by weight up to 10% by weight,
• p) optionally skin care active ingredients, preferably those as described above, in particular in the range of 0.01 wt .-% to 10 wt .-%.

contains, wt .-% each based on the total composition with which the substrate is impregnated, so again is a preferred embodiment of the invention.

To a preferred embodiment For example, the composition with the substrate according to the invention (Cloth) impregnated / impregnated / impregnated / coated is, as a dispersion, emulsion, microemulsion, PIT emulsion (PIT = Phase inversion temperature), suspension, aerosol, foam or Be provided paste.

To a preferred embodiment has the substrate according to the invention at least one further, preferably several optional ingredients on, in particular washing, care and / or cleaning active ingredients, advantageously selected from the group comprising anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, acidifiers, Alkalizing agents, antibacterial agents, antioxidants, anti redeposition agents, Antistatic agents, builders, bleaches, bleach activators, Bleach stabilizers, bleach catalysts, cobuilders, dispersants, Electrolytes, enzymes, colorants, colorants, dyes, fluorescers, Fungicides, germicides, odor-complexing substances, auxiliaries, Hydrotrope, rinse aid, Complexing agents, preservatives, corrosion inhibitors, optical Brightener, perfume carrier, pearlescer, pH adjusting agents, Phobic and impregnating agents, Polymers, fragrance (s) (perfume (oil)), source and anti-slip agents, foam inhibitors, phyllosilicates, stain-resistant substances, Silver protectants, silicone oils, Viscosity regulators, Thickening agents, discoloration inhibitors, Graying inhibitors and / or vitamins.

The other optional ingredients of the substrate according to the invention are mainly to be selected according to the respective needs. It can z. B. be useful that substances are included, the scouring effect have (abrasives), preferably marble powder, because of its low hardness also on mechanically sensitive surfaces, eg. As tiles, glass and Enamel leaves no scratch marks. Suitable abrasives are also calcium carbonate, silicates, aluminum oxides (clays). Abrasives can so be included.

To a preferred embodiment the invention, the substrate is characterized in that the contained composition has a pH in the range 4-9, preferably 5-8 and especially 5.5-7.5 having.

To a further preferred embodiment According to the invention, a substrate according to the invention has a weight ratio of Loading composition to substrate in the range of 25: 1-1: 25, preferably 15: 1-1: 15, advantageously 10: 1-1: 10, even more advantageous 5: 1-1: 5, especially 2: 1-1: 2 on.

With Loading composition is meant the entire composition with which the substrate impregnated / acted / impregnated / coated is.

The cloths of the invention (textile substrates) may, for. B. by separate or simultaneous addition of a cleaning composition (cleaning composition = entire composition, with which the substrate is impregnated / impregnated / coated) or by impregnation with the cleaning composition, including foaming surfactants and conditioning agents, into a substrate according to the usual methods, the resulting product then being preferably moist. By "separated" is meant that individual ingredients of the cleaning composition to be added, for example, surfactants and conditioners, may be added sequentially in any order without first being combined with each other. comprehensively z. For example, surfactants and conditioners may be added simultaneously, with or without first combining them. For example, it is possible to add surfactant, if appropriate conditioner, optionally water, optionally binding agent and any other (optional) constituents to be impregnated or impregnated into the substrate by any means known to those skilled in the art. For example, the addition may be by spraying, laser printing, spraying, dipping, soaking or coating.

One Another object of the present invention is a product, comprising a container, preferably a (dosing) bag or (dosing) container containing 1 to 100, preferably 5-50 the substrates according to the invention, the container impermeable for moisture is and is preferably resealable.

One Another object of the invention is a method for cleaning, Treatment and / or antimicrobial equipment hard surfaces, comprising contacting, preferably wiping or rubbing, a hard surface with a textile according to the invention Substrate, at and / or followed by an exposure of the hard surface at light with one wavelength in the range of 300-1200 nm.

Here good cleaning results could be observed, in particular also with regard to the elimination of harmful microflora, in particular Mold symptoms, as well as on the elimination in particular Colored stains of all kinds. Advantageously, the procedure goes with an exceedingly good substrate and material preservation associated, in particular mechanically sensitive surfaces, z. As tiles, glass and enamel are spared.

• (a) Glasartikel und -erzeugnisse, wie vorzugsweise Fenster, Trinkgläser, Glasvitrinen,
• (b) Holz und -erzeugnisse, wie vorzugsweise Möbel, Holzdielen, Parkett
• (c) Sanitärerzeugnisse, wie vorzugsweise Sanitärbecken- und -möbel, Badewannen und Waschbecken, Duschvorhänge, Badezimmerarmaturen, Fliesen
• (d) Kücheneinrichtungsgegenstände und -geschirrartikel, wie vorzugsweise Backofen, Glaskeramikkochfelder, Herdplatten, Küchenmöbel, Küchenarmaturen, Porzellanartikel, Keramikartikel, Grillgeräte (auch Gartengrillgeräte)
• (e) Bauwerk und Baugut, wie vorzugsweise Mauerwerk, tapezierte, lackierte, gestrichene Wände und/oder Decken, Ziegel, Steine, Putzmörtel, Bodenplatten, Fugen, vorzugsweise Zement- und Silikonfugen, Laminat, Kunststoff-Oberflächen, Garagentore, Gipskartonplatten
• (f) Außeneinrichtungsgegenstande und Gartenzubehör, vorzugsweise Gartenmöbel, Treppenstufen, Schwimmbecken, Gehwegbefestigungen aus Holz und Stein, wie z. B. Wegplatten, Gartenhäuser, Holzzäune, Zier- und Obstbäume.

According to a preferred embodiment of the method according to the invention, the hard surfaces are surfaces of the inner area, surfaces of wet spaces and / or surfaces of the outer area, preferably in order

• (a) glassware and articles, such as preferably windows, drinking glasses, glass showcases,
• (b) Wood and products, such as preferably furniture, wood planks, parquet
• (c) Sanitary products, such as sanitary basin and furniture, bathtubs and wash basins, shower curtains, bathroom fixtures, tiles
• (d) kitchen furnishings and utensils, such as, preferably, ovens, glass ceramic hobs, hobs, kitchen furniture, kitchen fittings, porcelain items, ceramics, grills (including garden barbecues)
• (e) structure and property, such as preferably masonry, wallpapered, painted, painted walls and / or ceilings, bricks, bricks, plaster, floor slabs, joints, preferably cement and silicone joints, laminate, plastic surfaces, garage doors, plasterboard
• (f) outdoor furnishings and garden accessories, preferably garden furniture, stair treads, swimming pools, walkway fixtures of wood and stone, such as. B. Path plates, garden sheds, wooden fences, ornamental and fruit trees.

The inventive substrate and method does not offer especially in the aforementioned objects only a good cleaning performance, but also a very good substrate compatibility and -surprise.

If the inventive method on the treatment of mold stains and / or foxing hard surfaces especially indoors, in wet rooms and / or outdoors directed, so is a preferred embodiment of the invention.

One inventive method for the removal, deactivation, inhibition or reduction of microbes, Microflora, microbial growth and / or (interior) noxious with allergenic potential of hard surfaces, especially indoors in wet rooms and / or outside, represents a further preferred embodiment of the invention.

Another object of the invention is a method for removing dust from a surface, wherein the method comprises the step of contacting the surface with a textile according to the invention Substrate comprises, wherein the dust in particular comprises small particles of any shape, texture and density, wherein the particle diameter is preferably smaller than 0.3 mm, advantageously 10-200 .mu.m, in particular 30-200 .mu.m, at and / or followed by an exposure the hard surface of light having a wavelength in the range of 300-1200 nm.

One Another object of the invention is a method for cleaning, Care, antimicrobial equipment, Softening and / or conditioning of textile articles (fabrics, clothing, Eg clothing textiles, home textiles, carpets, etc.) contacting a textile article with a textile according to the invention Substrate, at and / or followed by exposure of the article at light with one wavelength in the range of 300-1200 nm.

If in the process of cleaning, care, antimicrobial equipment and / or Conditioning of textile articles, the contacting takes place immediately, preferably by wiping or abrading the textile article with a textile according to the invention Substrate, so is a preferred embodiment of the invention.

If in the process of cleaning, care, antimicrobial equipment and / or Conditioning of textile articles, the contacting takes place indirectly, preferably in the context of mechanical textile treatment, in particular textile washing and / or drying, wherein an inventive textile substrate to the given to the treating textile article and then the treatment program is started, so is a preferred embodiment of the invention.

If in the aforementioned method, a textile according to the invention Substrate for washing is placed in an automatic washing machine and then a Washing program, in particular washing program is started, preferably in an automatic washing machine with light source, so is a preferred embodiment of the invention.

If an inventive textile Substrate according to the laundry in an automatic clothes dryer is placed and then a drying program is started, preferably in an automatic clothes dryer with light source, so is also a preferred embodiment of the invention.

A further preferred embodiment The invention relates to a method for removing, deactivating, Inhibition or reduction of microorganisms, especially bacteria and germination, in textiles.

One Another object of the invention is a method for automatic Self-cleaning of a substrate according to the invention using of light with one wavelength in the range of 300-1200 nm.

• – rote bis blaue Anthocyanfarbstoffe, wie z. B. Cyanidin, z. B. aus Kirschen oder Heidelbeeren,
• – rotes Betanidin aus der roten Beete,
• – orangerote Carotinoide wie z. B. Lycopin, beta-Carotin, z. B. aus Tomaten oder Möhren,
• – gelbe Curcumafarbstoffe, wie z. B. Curcumin, z. B. aus Curry und Senf,
• – braune Gerbstoffe, z. B. aus Tee, Obst, Rotwein
• – tiefbraune Huminsäure, z. B. aus Kaffee, Tee, Kakao,
• – grünes Chlorophyll, z. B, aus grünen Gräsern,
• – technische Farbstoffe aus Kosmetika, Tinten, Farbstiften
• – farbige Flecken, hervorgerufen durch Stoffwechselprodukte und/oder Ausscheidungsprodukte von Schimmelpilzen oder anderer Mirkoflora oder mikrobiellem Bewuchs oder Mikroben,

unter Einsatz von Licht mit einer Wellenlänge im Bereich von 300–1200 nm.Another object of the invention is the use of a textile substrate according to the invention for the removal or reduction of stains and stains on hard surfaces or textiles, which are based on:

• - red to blue anthocyanin dyes, such as. B. cyanidin, z. From cherries or blueberries,
• - red betanidin from the red bed,
• - orange-red carotenoids such. As lycopene, beta-carotene, z. From tomatoes or carrots,
• - Yellow curcuma dyes, such as. B. curcumin, z. From curry and mustard,
• - brown tannins, z. B. from tea, fruit, red wine
• - deep brown humic acid, z. B. from coffee, tea, cocoa,
• - green chlorophyll, z. B, from green grasses,
• - Technical dyes from cosmetics, inks, color pencils
• - colored stains caused by metabolic and / or excretory products of mold or other microflora or microbial growth or microbes,

using light having a wavelength in the range of 300-1200 nm.

The Use of a textile according to the invention Substrate for denaturation or growth inhibition of molds, Mold spores and lichens or other Mirkoflora or other microbial growth or microbes (indoor) pollutants with allergenic Potential on hard surfaces or textiles using light of a wavelength in the range from 300-1200 nm again represents a preferred embodiment of the invention.

The Use of a textile according to the invention Substrates for the prophylaxis treatment of hard surfaces or Textilieni in the form of an anticipatory defense and inhibition of Stains and stains using light with a wavelength in the range from 300-1200 nm is also a preferred embodiment of the invention.

The Use of a substrate according to the invention as sanitary cleaning cloth, Window and / or glass cloth, Building cleaning cloth, Duster, floor cloth, conditioning substrate for use in automatic textile washing and / or -drying represents a preferred embodiment of the invention.

The Use of light, in particular with a wavelength in the range from 300-1200 nm, for the automatic self-cleaning of a substrate according to the invention is another object of the invention.

One textile according to the invention Substrate can also be used for air purification. An example of this is in particular a substrate according to the invention, which easily flows through air can be, for. B. a curtain. Preferably in combination with an air movement generating object, such. B. one Fan, then can be done an effective air purification, though the air passes through the textile substrate or in contact with it occurs.

Now follows a description of possible Ingredients which are contained in the substrate according to the invention can. If in the following the indication "Gew. -%" is made, then this always refers to the entire composition with which the textile substrate is impregnated / impregnated / impregnated / coated is, unless it is stated otherwise.

The inventive substrate contains Surfactants. The total amount of surfactants is of the intended use dependent. A suitable surfactant content may, for. B. above 0.01 wt .-%, for example in the range of> 1 Wt .-%, z. In the range of 12 to 70% by weight, preferably 15 to 55 wt .-%, in particular 17 to 45 wt .-%, wt .-% based to the entire composition with which the substrate is impregnated / impregnated / coated / coated is.

It are natural also lower amounts of total surfactant used. Possible upper limits can then, for example, at 40% by weight, 35% by weight, 30% by weight, 25% by weight, 20 wt .-%, 15 wt .-% or 10 wt .-% are. For surfactant-poor compositions can the upper limit z. B. even at values such as 8 wt .-%, 6% by weight, 5% by weight, 4% by weight, 3% by weight, 2% by weight or even 1% by weight. lie. Possible Lower limits for the total surfactant can for example, also at values such as 0.1% by weight, 0.5% by weight, 1% by weight, 5% by weight or 10% by weight, based on the total composition, by weight which impregnates / impregnates / impregnates / coats the substrate is.

Next preferably usable surfactants such. B. alkyl ether sulfates, Alkyl sulfonates and / or betaines, but also independent of this, the substrate according to the invention can in particular for improving the cleaning effect, one or more other anionic surfactants, amphoteric surfactants, nonionic surfactants and / or cationic surfactants.

The Alkyl ether sulfates and alkyl sulfonates and the other anionic Surfactants can usually be considered as Alkali metal, alkaline earth metal and / or mono-, di- or trialkanolammonium salt and / or in the form of their with the corresponding alkali metal hydroxide, Alkaline earth metal hydroxide and / or mono-, di- or trialkanolamine used in situ to be neutralized corresponding acid become. Preferred alkali metals here are potassium and in particular Sodium, as alkaline earth metals calcium and in particular magnesium, and as alkanolamines mono-, di- or triethanolamine. Especially preferred are the sodium salts.

Alkyl ether sulfates (fatty alcohol ether sulfates, INCI alkyl ether sulfates) are products of sulfation reactions on alkoxylated alcohols. The person skilled in the art generally understands by alkoxylated alcohols the reaction products of alkylene oxide, preferably ethylene oxide, with alcohols, in the context of the present invention preferably with longer-chain alcohols, ie with aliphatic straight-chain or mono- or multi-branched, acyclic or cyclic, saturated or mono- or polysubstituted unsaturated, preferably straight-chain, acyclic, saturated, alcohols having 6 to 22, preferably 8 to 18, in particular 10 to 16 and particularly preferably 12 to 14 carbon atoms. In general, from n moles of ethylene oxide and one mole of alcohol, depending on the reaction conditions, a complex mixture of addition products of different degrees of ethoxylation (n = 1 to 30, preferably 1 to 20, especially 1 to 10, particularly preferably 2 to 4). Another embodiment of the alkoxylation is the use of mixtures of the alkylene oxides, preferably the mixture of ethylene oxide and propylene oxide. Very particularly preferred in The meaning of the present invention are lower ethoxylated fatty alcohols having 1 to 4 ethylene oxide units (EO), in particular 1 to 2 EO, for example 2 EO, such as Na-C _12-14 fatty alcohol + 2EO sulfate.

The textile according to the invention In a preferred embodiment, substrate may comprise one or more alkyl ether sulfates, z. In an amount> 0.01 Wt .-%, preferably in an amount of 1 to 40 wt .-%, preferably as 2 to 30 wt .-%, in particular 3 to 20 wt .-%. Possible upper limits can for example, at 10 wt .-%, 8 wt .-%, 6 wt .-%, 4 wt.% Or 2 wt .-%, wt .-% based on the total composition, with which the substrate impregnated / acted / impregnated / coated is.

To another embodiment According to the invention, the substrate according to the invention can also be free of alkyl ether sulfates.

The Alkyl sulfonates (INCI Sulfonic Acids) usually have an aliphatic straight-chain or mono- or polysubstituted, acyclic or cyclic, saturated or mono- or polyunsaturated, preferably branched, acyclic, saturated, alkyl radical having 6 to 22, preferably 9 to 20, especially 11 to 18 and especially preferably 13 to 17 carbon atoms.

suitable Accordingly, alkylsulfonates are the saturated alkanesulfonates unsaturated olefin sulfonates and the - himself formally derived from the alkyl ether sulfates underlying alkoxylated Alcohols - Ethersulfonates, where you are terminal Ether sulfonates (n-ether sulfonates) with bound to the polyether chain Sulfonate function and internal Ether sulfonates (i-ether sulfonates) with sulfonate function linked to the alkyl radical.

Preference according to the invention is given to the alkanesulfonates, in particular alkanesulfonates having a branched, preferably secondary, alkyl radical, for example the secondary alkanesulfonate sec. Na C _13-17 alkanesulfonate (INCI Sodium C14-17 Alkyl Sec Sulfonate). The substrate according to the invention may according to a preferred embodiment contain one or more (preferably secondary) alkyl sulfonates, e.g. B. in an amount> 0.01 wt .-%, advantageously 1 to 20 wt .-%, preferably 3 to 12 wt .-%, in particular 4 to 8 wt .-%, wt .-%, based on the total composition with which the substrate is impregnated / impregnated / impregnated / coated.

To another embodiment According to the invention, the substrate according to the invention can also be free of alkyl sulfonates.

The substrate according to the invention may according to a preferred embodiment contain betaines. Suitable betaines are the alkylbetaines, the alkylamidobetaines, the imidazolinium betaines, the sulfobetaines (INCI Sultaines) and the phosphobetaines and preferably satisfy formula I, R ¹ - [CO-X- (CH ₂ ) _n ] _x -N ⁺ (R ² ) (R ³ ) - (CH ₂ ) _m - [CH (OH) -CH ₂ ] _y -Y ^- (I) in the
R ¹ is a saturated or unsaturated C _6-22 alkyl, preferably C _8-18 alkyl group, preferably a saturated C _10-16 alkyl group, for example a saturated C _12-14 alkyl group,
X is NH, NR ⁴ with the C _1-4 -alkyl radical R ⁴ , O or S,
n is a number from 1 to 10, preferably 2 to 5, in particular 3,
x is 0 or 1, preferably 1,
R ² , R ^{3 are} independently a C _1-4 alkyl radical, optionally hydroxy-substituted, such as. B. a hydroxyethyl radical, but especially a methyl radical,
m is a number from 1 to 4, in particular 1, 2 or 3,
y is 0 or 1 and
Y is COO, SO ₃ , OPO (OR ⁵ ) O or P (O) (OR ⁵ ) O, wherein R ^{5 is} a hydrogen atom H or a C _1-4 alkyl radical.

The alkyl and alkylamido betaines, betaines of the formula I having a carboxylate group (Y ^- = COO ^- ) are also called carbobetaines.

Preferred betaines are the alkylbetaines of the formula (Ia), the alkylamidobetaines of the formula (Ib), the sulfobetaines of the formula (Ic) and the amidosulfobetaines of the formula (Id), R ¹ -N ⁺ (CH ₃ ) ₂ -CH ₂ COO ^- (Ia) R ¹ -CO-NH- (CH ₂ ) ₃ -N ⁺ (CH ₃ ) ₂ -CH ₂ COO ^- (Ib) R ^{1 is} -N ⁺ (CH ₃ ) ₂ -CH ₂ CH (OH) CH ₂ SO ₃ ^- (Ic) R ¹ -CO-NH- (CH ₂ ) ₃ -N ⁺ (CH ₃ ) ₂ -CH ₂ CH (OH) CH ₂ SO ₃ ^- (Id) in which R ^{1 has} the same meaning as in formula I.

Especially preferred betaines are the carbobetaines, in particular the carbobetaines of the formula (Ia) and (Ib), extremely preferred the alkylamidobetaines of the formula (Ib).

Examples suitable betaines and sulfobetaines are the following named according to INCI Compounds: Almondamidopropyl Betaine, Apricotamidopropyl Betaine, Avocadamidopropyl Betaine, Babassuamidopropyl Betaine, Behenamidopropyl Betaines, behenyl betaines, betaines, canolamidopropyl betaines, caprylic / capramidopropyl Betaines, carnitines, cetyl betaines, cocamidoethyl betaines, cocamidopropyl Betaine, Cocamidopropyl Hydroxysultaine, Coco-Betaine, Coco Hydroxysultaine, Coco / Oleamidopropyl Betaine, Coco-Sultaine, Decyl Betaine, Dihydroxyethyl Oleyl Glycinate, Dihydroxyethyl Soy Glycinate, Dihydroxyethyl Stearyl Glycinate, Dihydroxyethyl Tallow Glycinate, Dimethicone Propyl PG Betaine, Erucamidopropyl Hydroxysultaine, Hydrogenated Tallow Betaine, Isostearamidopropyl Betaine, Lauramidopropyl Betaine, Lauryl Betaine, Lauryl Hydroxysultaine, Lauryl Sultaine, Milkamidopropyl Betaine, Minkamidopropyl Betaine, Myristamidopropyl betaine, myristyl betaine, oleamidopropyl betaine, Oleamidopropyl Hydroxysultaine, Oleyl Betaine, Olivamidopropyl Betaine, Palmamidopropyl Betaine, Palmitamidopropyl Betaine, Palmitoyl Carnitine, Palm Kernelamidopropyl Betaine, Polytetrafluoroethylene Acetoxypropyl Betaine, Ricinoleamidopropyl Betaine, Sesamidopropyl Betaine, Soyamidopropyl Betaines, stearamidopropyl betaines, stearyl betaines, tallow amidopropyl Betaine, Tallowamidopropyl Hydroxysultaine, Tallow Betaine, Tallow Dihydroxyethyl betaines, undecylenamidopropyl betaines and wheat germamidopropyl Betaine. A preferred betaine is, for example, cocamidopropyl Betaine (cocoamidopropyl betaine) and / or glycine. The substrate according to the invention can according to a preferred embodiment the invention one or more betaines in an amount of z. B.> 0.01 wt .-%, advantageously 1 to 15 wt .-%, preferably 3 to 10 wt .-%, in particular 4 to 8 wt .-%, wt .-% based on the total composition, with which the substrate impregnated / acted / impregnated / coated is.

To another embodiment According to the invention, the substrate according to the invention can also be free from Betainen.

One Inventive substrate may preferably be a surfactant combination of a) alkyl ether sulfate, b) Alkanesulfonate and c) betaine, preferably in a ratio a): b) : c) from 5: 2: 1 to 2: 1: 1. In addition to these surfactants but also independent of these can be included other surfactants.

suitable other anionic surfactants, which in addition but also independent of the aforementioned surfactants or other surfactants are used are in particular aliphatic sulfates such as fatty alcohol sulfates, monoglyceride sulfates and ester sulfonates (sulfo fatty acid esters), Lignosulfonates, alkylbenzenesulfonates, fatty acid cyanamides, anionic sulfosuccinic acid surfactants, fatty, Acylaminoalkanesulfonates (fatty acid taurides), fatty acid sarcosinates, ether and alkyl (ether) phosphates. Is one or more of the aforementioned anionic Contain surfactants, so is a preferred embodiment of the invention.

Suitable further anionic surfactants are also anionic gemini surfactants having a diphenyloxide basic structure, 2 sulfonate groups and an alkyl radical on one or both benzene rings according to the formula ^- O ₃ S (C ₆ H ₃ R) O (C ₆ H ₃ R ¹ ) SO ₃ ^- in which R is an alkyl radical with, for example, 6, 10, 12 or 16 carbon atoms and R 'is R or H (Dowfax ^® Dry hydrotropes Powder with C ₁₆ alkyl radical (s); INCI Sodium Hexyldiphenyl ether sulfonates, Disodium decyl phenyl ether disulfonates, Disodium lauryl phenyl ether disulfonates, Disodium Cetyl phenyl ether disulfonates) and fluorinated anionic surfactants, in particular perfluorinated alkylsulfonates such as ammonium C _9/10 -Perfluoroalkylsulfonat (Fluorad ^® FC 120) and perfluorooctane sulfonic acid potassium salt (Fluorad ^® FC 95 ).

Particularly preferred further anionic surfactants are the anionic sulfosuccinic acid surfactants, sulfosuccinates, sulfosuccinamates and sulfosuccinamides, especially sulfosuccinates and sulfosuccinamates, most preferably sulfosuccinates. The sulfosuccinates are the salts of the mono- and diesters of sulfosuccinic HOOCCH (SO ₃ H) CH ₂ COOH, while the sulfosuccinamates include the salts of the monoamides of sulfosuccinic acid and the sulfosuccinamides the salts of the diamides of Sulfosuccinic acid understands.

at the salts are preferably alkali metal salts, ammonium salts as well as mono-, di- or Trialkanolammonium salts, for example mono-, di- or triethanolammonium salts, in particular special lithium, sodium, potassium or ammonium salts, particularly preferably sodium or ammonium salts, most preferably Sodium salts.

In the sulfosuccinates, one or both carboxyl groups of the sulfosuccinic acid is preferably with one or two identical or different unbranched or branched, saturated or unsaturated, acyclic or cyclic, optionally alkoxylated alcohols having 4 to 22, preferably 6 to 20, in particular 8 to 18 , more preferably 10 to 16, most preferably 12 to 14 carbon atoms esterified. Particularly preferred are the esters of unbranched and / or saturated and / or acyclic and / or alkoxylated alcohols, in particular unbranched, saturated fatty alcohols and / or unbranched, saturated, with ethylene and / or propylene oxide, preferably ethylene oxide, alkoxylated fatty alcohols having a degree of alkoxylation of 1 to 20, preferably 1 to 15, in particular 1 to 10, more preferably 1 to 6, most preferably 1 to 4. The monoesters are preferred in the context of the present invention over the diesters. A particularly preferred sulfosuccinate is Sulfobernsteinsäurelaurylpolyglykolesterdi sodium salt (lauryl EO sulfosuccinate, di-Na salt, INCI Disodium Laureth Sulfosuccinate), for example, as Tego ^® Sulfosuccinat F 30 (Goldschmidt) with a Sulfosuccinatgehalt of 30 wt .-% commercially is available.

In form the sulfosuccinamates or sulfosuccinamides or form both carboxyl groups of sulfosuccinic acid preferably with a primary or secondary Amin, one or two identical or different, unbranched or branched, saturated or unsaturated, acyclic or cyclic, optionally alkoxylated alkyl radicals with 4 to 22, preferably 6 to 20, especially 8 to 18, especially preferably 10 to 16, most preferably Bears 12 to 14 carbon atoms, a carboxylic acid amide. Particular preference is given to unbranched and / or saturated and / or Acyclic alkyl radicals, in particular unbranched, saturated fatty alkyl radicals.

Also suitable are, for example, the following sulfosuccinates and sulfosuccinamates designated according to INCI: ammonium dinonyl sulfosuccinates, ammonium lauryl sulfosuccinates, diammonium dimethicone copolyol sulfosuccinates, diammonium lauramido-MEA sulfosuccinates, diammonium lauryl sulfosuccinates, diammonium oleamido PEG-2 Sulfosuccinate, Diamyl Sodium Sulfosuccinate, Dicapryl Sodium Sulfosuccinate, Dicyclohexyl Sodium Sulfosuccinate, Diheptyl Sodium Sulfosuccinate, Dihexyl Sodium Sulfosuccinate, Diisobutyl Sodium Sulfosuccinate, Dioctyl Sodium Sulfosuccinate, Disodium Cetearyl Sulfosuccinate, Disodium Cocamido MEA Sulfosuccinate, Disodium Cocamido MIPA Sulfosuccinate, Disodium Cocamido PEG-3 Sulfosuccinate, Disodium Coco-Glucoside Sulfosuccinate, Disodium Cocoyl Butyl Gluceth-10 Sulfosuccinate, Disodium C12-15 Pareth Sulfosuccinate, Disodium Deceth-5 Sulfosuccinate, Disodium Deceth-6 Sulfosu ccinate, disodium dihydroxyethyl sulfosuccinyl undecylenate, disodium dimethicone copolyol sulfosuccinate, disodium hydrogenated cottonseed glyceride sulfosuccinate, disodium isodecyl sulfosuccinate, disodium isostearamido MEA sulfosuccinate, disodium isostearamido MIPA sulfosuccinate, disodium isostearyl sulfosuccinate, disodium laneth-5 sulfosuccinate, disodium lauramido MEA sulfosuccinate, disodium Lauramido PEG-2 Sulfosuccinate, Disodium Lauramido PEG-5 Sulfosuccinate, Disodium Laureth-6 Sulfosuccinate, Disodium Laureth-9 Sulfosuccinate, Disodium Laureth-12 Sulfosuccinate, Disodium Lauryl Sulfosuccinate, Disodium Myristamido MEA Sulfosuccinate, Disodium Nonoxynol-10 Sulfosuccinate, Disodium Oleamido MEA -Sulfosuccinates, Disodium Oleamido MIPA Sulfosuccinates, Disodium Oleamido PEG-2 Sulfosuccinates, Disodium Oleth-3 Sulfosuccinates, Disodium Oleyl Sulfosuccinates, Disodium Palmitamido PEG-2 Sulfosuccinates, Disodium Palmitoleamido PEG-2 Sulfosuccinates, Disodium PEG-4 Cocamido MIPA Sulfosu ccinate, disodium PEG-5 laurylcitrate sulfosuccinate, disodium PEG-8 palm glycerides sulfosuccinate, disodium ricinoleamido MEA sulfosuccinate, disodium sitostereth-14 sulfosuccinate, disodium stearamido MEA sulfosuccinate, disodium stearyl sulfosuccinamate, disodium stearyl sulfosuccinate, disodium tallamido MEA sulfosuccinate, disodium Tallowamido MEA Sulfosuccinate, Disodium Tallow Sulfosuccinamate, Disodium Tridecyl Sulfosuccinate, Disodium Undecylenamido MEA Sulfosuccinate, Disodium Undecylenamido PEG-2 Sulfosuccinate, Disodium Wheat Germamido MEA Sulfosuccinate, Disodium Wheat Germamido PEG-2 Sulfosuccinate, Di-TEA Oleamido PEG-2 Sulfosuccinate, Ditridecyl Sodium Sulfosuccinate, Sodium Bisglycol Ricinosulfosuccinate, Sodium / MEA Laureth-2 Sulfosuccinate and Tetrasodium Dicarboxyethyl Stearyl Sulfosuccinamate. Yet another suitable sulfosuccinamate is disodium C _16-18 alkoxypropylene sulfosuccinamate.

Preferred anionic sulfosuccinic are imidosuccinate, mono-Na-sulfosuccinic acid diisobutyl ester (Monawet MB ^® 45), mono-Na-sulfosuccinic acid di-octyl ester (Monawet MO-84 ^® R2W, Rewopol SB ^® DO 75), mono-di-tridecyl Nasulfobernsteinsäure-(Monawet ^® MT 70) Fettalkoholpolyglykolsulfosuccinat-Na-NH ₄ salt (sulfosuccinate S-2), di-Nasulfobernsteinsäure-mono-C _12/14 3EO ester (Texapon ^® SB-3), Natruimsulfobernsteinsäurediisooctylester (Texin DOS 75 ^®) and di-sodium sulfosuccinic acid mono-C _12/18 ester (Texin 128-P ^®), in particular with the inventive ternary surfactant with respect to the flow and / or drying behavior synergistically cooperating mono-Na-sulfosuccinic di-octyl ester.

In a particular embodiment contains the substrate according to the invention as anionic sulfosuccinic acid surfactants one or more sulfosuccinates, sulfosuccinamates and / or sulfosuccinamides, preferably sulfosuccinates and / or sulfosuccinamates, in particular Sulfosuccinates, in an amount of usually 0.001 to 5 wt .-%, preferably 0.01 to 4 wt .-%, in particular 0.1 to 3 wt .-%, particularly preferably 0.2 to 2% by weight, most preferably 0.5 to 1.5 wt .-%, for example 1 wt .-%, wt .-% based on the entire composition with which the substrate is impregnated / impregnated / coated / coated is.

To the amphoteric surfactants (amphoteric surfactants, zwitterionic surfactants), the invention used can be counting Alkylamidoalkylamines, alkyl-substituted amino acids, acylated amino acids or Biosurfactants, of which the betaines are within the scope of the teaching of the invention to be favoured.

The alkylamidoalkylamines (INCI alkylamido alkylamines) are amphoteric surfactants of the formula (III) R ⁹ -CO-NR ¹⁰ - (CH ₂ ) _i -N (R ¹¹ ) - (CH ₂ CH ₂ O) _j - (CH ₂ ) _k - [CH (OH)] _i -CH ₂ -Z-OM ( III) in the
R ⁹ is a saturated or unsaturated C _6-22 alkyl, preferably C _8-18 alkyl group, preferably a saturated C _10-16 alkyl group, for example a saturated C _12-14 alkyl group,
R ^{10 is} a hydrogen atom H or a C _1-4 -alkyl radical, preferably H, a number from 1 to 10, preferably 2 to 5, in particular 2 or 3,
R ^{11 is} a hydrogen atom H or CH ₂ COOM (to M su),
j is a number from 1 to 4, preferably 1 or 2, in particular 1,
k is a number from 0 to 4, preferably 0 or 1,
I 0 or 1, where k = 1, if I = 1,
Z is CO, SO ₂ , OPO (OR ¹² ) or P (O) (OR ¹² ), wherein R ^{12 is} a C _1-4 alkyl radical or M (su), and
M is a hydrogen, an alkali metal, an alkaline earth metal or a protonated alkanolamine, eg. B. protonated mono-, di- or triethanolamine, is.

Preferred representatives satisfy the formulas IIIa to IIId, R ⁹ -CO-NH- (CH ₂ ) ₂ -N (R ¹¹ ) -CH ₂ CH ₂ O-CH ₂ -COOM (IIIa) R ⁹ -CO-NH- (CH ₂ ) ₂ -N (R ¹¹ ) -CH ₂ CH ₂ O-CH ₂ CH ₂ -COOM (IIIb) R ⁹ -CO-NH- (CH ₂ ) ₂ -N (R ¹¹ ) -CH ₂ CH ₂ O-CH ₂ CH (OH) CH ₂ -SO ₃ M (IIIc) R ⁹ -CO-NH- (CH ₂ ) ₂ -N (R ¹¹ ) -CH ₂ CH ₂ O-CH ₂ CH (OH) CH ₂ -OPO ₃ HM (IIId) in which R ¹¹ and M have the same meaning as in formula (III).

Exemplary alkylamidoalkylamines are the following named according to INCI compounds: Cocoamphodipropionic Acid, Cocobetainamido amphopropionates, DEA-Cocoamphodipropionate, Disodium Caproamphodiacetate, Disodium Caproamphodipropionate, Disodium Capryloamphodiacetate, Disodium Capryloamphodipropionate, Disodium Cocoamphocarboxyethylhydroxypropylsulfonate, Disodium Cocoamphodiacetate, Disodium Cocoamphodipropionate, Disodium Isostearoamphodiacetate, Disodium Isostearoamphodipropionate, Disodium laureth 5 Carboxyamphodiacetate, Disodium Lauroamphodiacetate, Disodium Lauroamphodipropionate, Disodium Oleoamphodipropionate, Disodium PPG-2-Isodeceth-7 Carboxyamphodiacetate, Disodium Stearoamphodiacetate, Disodium Tallowamphodiacetate, Disodium Wheatgermamphodiacetate, Lauroamphodipropionic Acid, Quaternium-85, Sodium Caproamphoacetate, Sodium Caproamphohydroxypropylsulfonate, Sodium Caproamphopropionate, Sodium Capryloamphoacetate, Sodium Capryloamphohydroxypropylsulfonate, Sodium Capryl oamphopropionate, sodium cocoamphoacetate, sodium cocoamphohydroxypropylsulfonate, sodium cocoamphopropionate, sodium cornamphopropionate, sodium isostearoamphoa cetate, Sodium Isostearoamphopropionate, Sodium lauroamphoacetate, sodium Lauroamphohydroxypropylsulfonate, Sodium Lauroampho PG-Acetate Phosphate, Sodium Lauroamphopropionate, Sodium Myristoamphoacetate, Sodium Oleoamphoacetate, Sodium Oleoamphohydroxypropylsulfonate, Sodium Oleoamphopropionate, Sodium Ricinoleoamphoacetate, Sodium Stearoamphoacetate, Sodium Stearoamphohydroxypropylsulfonate, Sodium Stearoamphopropionate, Sodium Tallamphopropionate, Sodium Tallowamphoacetate , Sodium Undecylenoamphoacetate, Sodium Undecylenoamphopropionate, Sodium Wheat Germamphoacetate and Trisodium Lauroampho PG Acetate Chloride Phosphate.

Alkyl-substituted amino acids (INCI alkyl-substituted amino acids) preferably usable according to the invention are monoalkyl-substituted amino acids according to formula (IV), R ¹³ -NH-CH (R ¹⁴ ) - (CH ₂ ) _u -COOM '(IV) in the
R ¹³ is a saturated or unsaturated C _6-22 alkyl, preferably C _8-18 alkyl group, preferably a saturated C _10-16 alkyl group, for example a saturated C _12-14 alkyl group,
R ^{14 is} a hydrogen atom H or a C _1-4 -alkyl radical, preferably H,
u is a number from 0 to 4, preferably 0 or 1, in particular 1, and
M is a hydrogen, an alkali metal, an alkaline earth metal or a protonated alkanolamine, eg. B. protonated mono-, di- or triethanolamine, is alkyl-substituted imino acids according to formula (V), R ¹⁵ -N - [(CH ₂ ) _v -COOM ''] ₂ (V) in the
R ¹⁵ is a saturated or unsaturated C _6-22 alkyl, preferably C _8-18 alkyl group, preferably a saturated C _10-16 alkyl group, for example a saturated C _12-14 alkyl group,
v is a number from 1 to 5, preferably 2 or 3, in particular 2, and
M '' is a hydrogen, an alkali metal, an alkaline earth metal or a protonated alkanolamine, e.g. B. protonated mono-, di- or triethanolamine, where M '' in the two carboxy groups may have the same or two different meanings, for. B. hydrogen and sodium or may be twice sodium, and mono- or dialkyl-substituted natural amino acids according to formula (VI), R ¹⁶ -N (R ¹⁷ ) -CH (R ¹⁸ ) -COOM '''(VI) in the
R ¹⁶ is a saturated or unsaturated C _6-22 alkyl, preferably C _8-18 alkyl group, preferably a saturated C _10-16 alkyl group, for example a saturated C _12-14 alkyl group,
R ^{17 is} hydrogen or C _1-4 alkyl, optionally hydroxy or amine substituted, e.g. A methyl, ethyl, hydroxyethyl or aminopropyl radical,
R ^{18 is} the residue of one of the 20 natural α-amino acids H ₂ NCH (R ¹⁸ ) COOH, and
M '''is a hydrogen, an alkali metal, an alkaline earth metal or a protonated alkanolamine, e.g. B. protonated mono-, di- or triethanolamine, is.

Particularly preferred alkyl-substituted amino acids are the aminopropionates according to formula (IVa), R ¹³ -NH-CH ₂ CH ₂ COOM '(IVa) in which R ¹³ and M have the same meaning as in formula (IV).

exemplary alkyl-substituted amino acids are the following named according to INCI Compounds: Aminopropyl Laurylglutamine, Cocaminobutyric Acid, Cocaminopropionic acid, DEA-lauraminopropionate, disodium cocaminopropyl Iminodiacetate, disodium dicarboxyethyl cocopropylenediamine, disodium lauriminodipropionate, Disodium Steariminodipropionate, Disodium Tallowiminodipropionate, Lauraminopropionic Acid, Lauryl Aminopropylglycine, Lauryl Diethylenediaminoglycine, Myristaminopropionic acid, sodium C12-15 alkoxypropyl iminodipropionate, Sodium Cocaminopropionate, Sodium Lauraminopropionate, Sodium Lauriminodipropionate, Sodium Lauroyl Methylaminopropionate, TEA Lauraminopropionate and TEA Myristaminopropionate.

acylated amino acids are also usable. Their use represents a preferred embodiment of the Invention.

Acylated amino acids are amino acids, in particular the 20 natural α-amino acids which carry on the amino nitrogen the acyl radical R ¹⁹ CO of a saturated or unsaturated fatty acid R ¹⁹ COOH, where R ^{19 is} a saturated or unsaturated C _6-22 alkyl radical, preferably C _8-18 Alkyl, in particular a saturated C _10-16 alkyl radical, for example a saturated C _12-14 alkyl radical. The acylated amino acids may also be used as the alkali metal salt, alkaline earth metal salt or alkanolammonium salt, e.g. As mono-, di- or triethanolammonium, are used. Examples of acylated amino acids are those stated ^- INCI summarized under Amino Acids acyl derivatives, for example. Sodium Cocoyl Glutamate, Lauroyl Glutamic Acid, Capryloyl Glycine or Myristoyl Methylalanine.

In a particular embodiment The invention will be a combination of two or more different Amphoteric surfactants, in particular a binary Amphotensidkombination used.

The optional amphotensic surfactant combination preferably contains at least a betaine, especially at least one alkylamidobetaine, especially preferably cocoamidopropylbetaine.

Furthermore, the optional amphoteric surfactants preferably contains at least one amphoteric surfactant is selected from the group comprising Natriumcarboxyethylkokosphosphoethylimidazolin (Phosphoteric ^® TC-6), C _8/10 -Amidopropylbetain (INCI caprylic / Capramidopropyl Betaine, Betaine Tego ^® 810), N-2-hydroxyethyl-N- carboxymethyl-ethylamine fettsäureamido-Na (Rewoteric ^® AMV) and N-caprylic / capric amidoethyl-N-ethyl-propionate-Na (Rewoteric AMVSF ^®) and the betaine 3- (3-cocoamido-propyl) dimethylammonium 2- hydroxypropanesulfonate (INCI sultaines; Rewoteric AM CAS ^®) and the Alkylamidoalkylamin N- [N '(N''-2-hydroxyethyl-N''- carboxyethylaminoethyl) essigsäureamido] -N, N-dimethyl-N-coco-ammonium betaine (Rewoteric ^® QAM 50), in particular together with cocoamidopropylbetaine. In a further preferred embodiment, the substrate according to the invention contains one or more amphoteric surfactants in an amount of> 0.01% by weight, eg. From more than 1% by weight, 2% by weight, 4% by weight or even 8% by weight. In yet another preferred embodiment, the substrate of the invention contains one or more amphoteric surfactants in an amount of less than 2% by weight, e.g. B. <1 wt .-%, wt .-% based on the total composition with which the substrate is impregnated / acted / impregnated / coated.

The inventive substrate can, as already stated, in addition, but also independent of contain other surfactants, one or more nonionic surfactants, z. B. in an amount of 0.001 to 20 wt .-%, preferably 0.01 to 8 wt .-%, in particular 0.1 to 4 wt.%, Particularly preferably 0.2 to 2 wt .-%, wt .-% based on the total composition, with which impregnates / impregnates / impregnates / coats the substrate is.

Prefers Useful nonionic surfactants in the invention are alkoxylates such as polyglycol ethers, fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, end-capped polyglycol ethers, mixed ethers and hydroxy mixed ethers and fatty acid polyglycol ester. Also suitable are block polymers of ethylene oxide and propylene oxide and fatty acid alkanolamides and fatty acid polyglycol ethers. Important classes of nonionic according to the invention Surfactants are furthermore the amine oxides and the sugar surfactants, in particular the Alkylpolyglucosides.

Fettalkoholpolyglykolether are preferably used. Your bet is a preferred one embodiment of the invention.

Under Fettalkoholpolyglykolethern according to the invention with ethylene (EO) and / or propylene oxide (PO) alkoxylated, unbranched or branched, saturated or unsaturated C _10-22 alcohols having a degree of alkoxylation up to 30 to understand, preferably ethoxylated C _10-18 fatty alcohols a degree of ethoxylation of less than 30, preferably with a degree of ethoxylation of 1 to 20, in particular from 1 to 12, particularly preferably from 1 to 8, most preferably from 2 to 5, for example C _12-14 fatty alcohol ethoxylates with 2, 3 or 4 EO or a mixture of the C _12-14 fatty alcohol ethoxylates with 3 and 4 EO in the weight ratio of 1 to 1 or isotridecyl alcohol ethoxylate with 5, 8 or 12 EO.

amine oxides are preferably used. Your bet is a preferred one embodiment of the invention.

The amine oxides suitable in accordance with the invention include alkylamine oxides, in particular alkyldimethylamine oxides, alkylamidoamine oxides and alkoxyalkylamine oxides. Preferred amine oxides satisfy formula II, R ⁶ R ⁷ R ⁸ N ⁺ -O ^- (II) R ⁶ - [CO-NH- (CH ₂ ) _w ] _z -N ⁺ (R ⁷ ) (R ⁸ ) -O ^- (II) in the
R ⁶ is a saturated or unsaturated C _6-22 alkyl, preferably C _8-18 alkyl group, preferably a saturated C _10-16 alkyl group, for example a saturated C _12-14 alkyl group, in the alkylamidoamine oxides over a carbonylamidoalkylene -CO -NH- (CH ₂ ) _z - and in the alkoxyalkylamine oxides via an oxaalkylene group -O- (CH ₂ ) _z - is bonded to the nitrogen atom N, wherein z is in each case a number from 1 to 10, preferably 2 to 5, in particular 3 .
R ⁷ , R ^{8 are} independently a C _1-4 alkyl radical, optionally hydroxy-substituted, such as. B. is a hydroxyethyl radical, in particular a methyl radical.

Examples Suitable amine oxides are the following compounds named according to INCI: Almondamidopropylamine Oxide, Babassuamidopropylamine Oxide, Behenamine Oxides, Cocamidopropyl Amine Oxide, Cocamidopropylamine Oxide, Cocamine Oxides, coco-morpholine oxides, decylamines oxides, decyltetradecylamines Oxides, diaminopyrimidine oxides, dihydroxyethyl C8-10 alkoxypropylamines Oxides, dihydroxyethyl C9-11 alkoxypropylamines oxides, dihydroxyethyl C12-15 alkoxypropylamines oxides, dihydroxyethyl cocamines oxides, dihydroxyethyl Lauramine oxides, dihydroxyethyl stearamines oxides, dihydroxyethyl Tallowamine Oxide, Hydrogenated Palm Kernel Amine Oxide, Hydrogenated Tallowamine oxides, hydroxyethyl hydroxypropyl C12-15 alkoxypropylamines Oxides, isostearamidopropylamine oxides, isostearamidopropyl morpholine Oxides, lauramidopropylamine oxides, lauramine oxides, methyl morpholine Oxides, Milkamidopropyl Amine Oxide, Minkamidopropylamine Oxide, Myristamidopropylamine oxides, myristamine oxides, myristyl / cetyl Amine oxides, Oleamidopropylamine oxides, Oleamine oxides, Olivamidopropylamine Oxides, palmitamidopropylamine oxides, palmitamine oxides, PEG-3 lauramines Oxides, Potassium Dihydroxyethyl Cocamine Oxides Phosphate, Potassium Trisphosphonomethylamine oxides, sesamidopropylamine oxides, soyamidopropylamines Oxides, stearamidopropylamines oxides, stearamines oxides, tallow amidopropyl amines Oxides, tallowamine oxides, undecylenamidopropylamine oxides and wheat Germamidopropylamine oxides. A preferred amine oxide is, for example Cocamidopropylamine oxides (cocoamidopropylamine oxide).

sugar surfactants are preferably used. Your bet is a preferred one embodiment of the invention.

Sugar surfactants are known surface-active compounds, which include, for example, the sugar surfactant classes of the alkyl glucose esters, aldobionamides, gluconamides (sugar acid amides), glycerolamides, glycerol glycolipids, polyhydroxy fatty acid amide sugar surfactants (sugar amides) and alkyl polyglycosides. Preferred sugar surfactants within the scope of the teaching according to the invention are the alkyl polyglycosides and the sugar amides and their derivatives, in particular their ethers and esters. The ethers are the products of the reaction of one or more, preferably one, sugar hydroxy group with a compound containing one or more hydroxy groups, for example C _1-22 alcohols or glycols such as ethylene and / or propylene glycol, the sugar hydroxy group also being polyethylene glycol - And / or polypropylene glycol can carry. The esters are the reaction products of one or more, preferably one, sugar hydroxy group with a carboxylic acid, in particular a C _6-22 fatty acid.

sugar amides are preferably used. Your bet is a preferred one embodiment of the invention.

Particularly preferred sugar amides satisfy the formula R'C (O) N (R '') [Z], in which R 'is a linear or branched, saturated or unsaturated acyl radical, preferably a linear unsaturated acyl radical, with 5 to 21, preferably 5 to 17, in particular 7 to 15, particularly preferably 7 to 13 carbon atoms, R "represents a linear or branched, saturated or unsaturated alkyl radical, preferably a linear unsaturated alkyl radical, having 6 to 22, preferably 6 to 18, in particular 8 to 16, particularly preferably 8 to 14 carbon atoms, a C _1-5 -alkyl radical, in particular a methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, tert-butyl or n-pentyl radical, or hydrogen and Z represent a sugar residue, ie a monosaccharide residue. Particularly preferred sugar amides are the amides of glucose, the glucamides, for example lauroyl-methyl-glucamide.

Alkylpolyglykoside are preferably used. Your bet is a preferred one Embodiment of Invention.

The alkyl polyglycosides (APG) are particularly preferred sugar surfactants within the scope of the teaching according to the invention. APG are nonionic surfactants and are known substances that can be obtained by the relevant methods of preparative organic chemistry. Alkyl polyglucosides are, for. By acid catalyzed reaction (Fischer reaction) of glucose (or starch) or n-butyl glucosides with fat alcoholic accessible.

The inventive substrate can additionally, but also independent of other surfactants, one or more cationic surfactants (cationic surfactants; INCI Quaternary Ammonium Compounds), e.g. B. in a crowd from 0.001 to 10 wt .-%, preferably 0.01 to 4 wt .-%, in particular 0.1 to 3 wt .-%, particularly preferably 0.2 to 2 wt .-%, most preferably 0.5 to 1.5 wt .-%, for example 1 wt .-%, wt .-% based on the entire composition with which the substrate is impregnated / impregnated / coated / coated is.

preferred cationic surfactants are quaternary surfactants Compounds, in particular with an ammonium, sulfonium, phosphonium, Iodonium or arsonium group, which is widely used as antimicrobial Active ingredients are used. Through the use of quaternary surface active Antimicrobial compounds may be antimicrobial Effect of the agent can be further improved.

Particularly preferred cationic surfactants are the quaternary ammonium compounds (QAV, INCI quaternary ammonium compounds) according to the general formula (R ^I ) (R ^II ) (R ^III ) (R ^IV ) N ⁺ X ^- in the R ^I to R ^{IV are} identical or different C _1-22 -alkyl radicals, C _7-28 -aralkyl radicals or heterocyclic radicals, where two or, in the case of an aromatic incorporation as in pyridine, even three radicals together with the nitrogen atom denote the heterocycle, eg. A pyridinium or imidazolinium compound, and X ^{- are} halide ions, sulfate ions, hydroxide ions or like anions. For optimum antimicrobial activity, preferably at least one of the radicals has a chain length of 8 to 18, in particular 12 to 16, carbon atoms.

QAC are tertiary by implementation Amines with alkylating agents, such as. Methyl chloride, benzyl chloride, Dimethyl sulfate, dodecyl bromide, but also ethylene oxide produced. The alkylation of tertiary Amines with a long alkyl radical and two methyl groups succeed especially easy, also the quaternization of tertiary amines with two long residues and one methyl group can help with Methyl chloride be carried out under mild conditions. Amines, over three are long alkyl radicals or hydroxy-substituted alkyl radicals little reactive and are preferably quaternized with dimethyl sulfate.

Suitable QACs are, for example, benzalkonium chloride (N-alkyl-N, N-dimethylbenzylammonium chloride, CAS No. 8001-54-5), benzalkone B (m, p-dichlorobenzyl-dimethyl-C ₁₂ -alkylammonium chloride, CAS No. 58390-78 -6), benzoxonium chloride (benzyldodecyl-bis (2-hydroxyethyl) ammonium chloride), cetrimonium bromide (N-hexadecyl-N, N-timethyl-ammonium bromide, CAS No. 57-09-0), benzetonium chloride (N, N Dimethyl N- [2- [2- [p- (1,1,3,3-tetramethylbutyl) phenoxy] ethoxy] ethyl] benzyl ammonium chloride, CAS No. 121-54-0), dialkyldimethylammonium chlorides such as di-n- decyldimethylammonium chloride (CAS No. 7173-51-5-5), didecyldimethylammonium bromide (CAS No. 2390-68-3), dioctyldimethylammonium chloride, 1-cetylpyridinium chloride (CAS No. 123-03-5) and thiazoline iodide ( CAS No. 15764-48-1) and mixtures thereof. Preferred QACs are the benzalkonium chlorides having C ₈ -C ₁₈ -alkyl radicals, in particular C ₁₂ -C ₁₄ -alkyl-benzyl-dimethylammonium chloride. A particularly preferred QAC Kokospentaethoxymethylammoniummethosulfat (INCI PEG-5 Cocomonium Methosulfate; Rewoquat CPEM ^®).

to Avoidance of possible incompatibilities of cationic surfactants and anionic surfactants may, for. B. aniontensidverträgliches and / or as possible little cationic surfactant used or in a particular embodiment the invention entirely dispensed with cationic or anionic surfactants.

to Further improvement of the substrates according to the invention, the substrate according to the invention a or several additives from the group of surfactants, polymers and the builders (builders, builders) contain, for. B. in an amount of 0.001 to 20% by weight, preferably 0.01 to 5 Wt .-%, in particular 0.1 to 3 wt .-%, particularly preferably 0.2 to 2% by weight, most preferred 0.5 to 1.5 wt .-%, for example 1 wt .-%, wt .-% based on the entire composition with which the substrate is impregnated / impregnated / coated / coated is.

When Additive suitable surfactants are certain of those already above described amphoteric surfactants, other anionic surfactants, nonionic surfactants and cationic surfactants which can be used be repeated at this point. The content of surfactant additives is preferable to choose the total surfactant content is in the quantitative ranges set out above.

To Some of the additives listed below are one or more Trade names are given in brackets, among which the respective commercial available is.

As additives suitable amphoteric surfactants are, in particular Natriumcarboxyethylkokosphosphoethylimidazolin (Phosphoteric ^® TC-6), C _8/10 -Amidopropylbetain (INCI caprylic / Capramidopropyl Betaine, Betaine Tego ^® 810), N-2-hydroxyethyl-N-carboxymethyl-ethylamine fettsäureamido-Na (Rewoteric ^® AMV) and N-caprylic / capric amidoethyl-N-ethyl-propionate-Na (Rewoteric AMVSF ^®) and the betaine 3- (3-cocoamido-propyl) dimethylammonium-2-hydroxypropane (INCI sultaines; Rewoteric ^® AM CAS) and the Alkylamidoalkylamin N- [N '(N''-2-hydroxyethyl-N''- carboxyethylaminoethyl) -essigsäureamido] -N, N-dimethyl-N-coco-ammonium betaine (Rewoteric QAM ^® 50).

Further suitable anionic surfactants which are suitable as additives are, in particular, anionic gemini surfactants having a diphenyl oxide basic structure, 2 sulfonate groups and one alkyl radical on one or both benzene rings according to the formula ^- O ₃ S (C ₆ H ₃ R) O (C ₆ H ₃ R ' ) SO ₃ ^-, in which R is an alkyl radical having, for example, 6, 10, 12 or 16 carbon atoms and R 'is R or H (Dowfax ^® Dry hydrotropes Powder with C ₁₆ alkyl radical (s); INCI Sodium Hexyldiphenyl ether sulfonates, Disodium decyl phenyl ether disulfonates, Disodium lauryl phenyl ether disulfonates, Disodium Cetyl phenyl ether disulfonates) and the fluorinated anionic surfactants ammonium-C _9/10 -Perfluoroalkylsulfonat (Fluorad ^® FC 120), perfluorooctane sulfonic acid potassium salt (Fluorad ^® FC 95) and the sulfosuccinic imidosuccinate, monosodium sulfosuccinic acid diisobutyl ester (Monawet ^® MB 45), mono-Na-sulfosuccinic acid di-octyl ester (Monawet ^® MO 84 R2W, Rewopol ^® SB DO 75), mono-Na-sulfosuccinic acid di -tridecylester (Monawet ^® MT 70) Fettalkoholpolyglykolsulfosuccinat-Na-NH ₄ salt (sulfosuccinate S-2), di-Na-sulfosuccinic acid mono-C _12/14 3EO ester (Texapon ^® SB-3), Natruimsulfobernsteinsäurediisooctylester ( Texin DOS 75 ^®) and di-sodium sulfosuccinic acid mono-C _12/18 ester (Texin ^® 128 P).

As additives suitable nonionic surfactants are in particular C ₁₀ dimethyl amine oxide (Ammonyx ^® DO), C _10/14 -fatty alcohol + 1,2PO + 6,4EO (Dehydol ^® 980), C _12/14 -fatty alcohol + 6 EO (Dehydol ^® LS6) , C ₈ fatty alcohol + 1,2PO + 9EO (Dehydol ^® O10), C _16/20 -Guerbetalkohol + 8EO, n-butyl-closed (Dehypon ^® G2084), mixture of several n-butyl-sealed nonionic surfactants and C _{8 / 10} APG (Dehypon ^® Ke 2555) C _8/10 fatty alcohol + 1PO + 22EO- (2-hydroxydecyl) ether (Dehypon Ke ^® 3447), C _12/14 -fatty alcohol + 5EO + 4PO (Dehypon LS 54 ^® G) C _12/14 fatty alcohol + 5EO + 3PO, methyl closed (Dehypon LS ^® 531), C _12/14 -fatty alcohol + 10EO, n-butyl closed (Dehypon LS ^® L 104), C ₁₁ oxo alcohol + 8EO (Genapol ^® UD 088), C ₁₃ oxo alcohol + 8EO (Genapol ^® X 089), C _13/15 fatty alcohol-EO adduct, n-butyl closed (Plurafac LF ^® 221), and alkoxylated fatty alcohol (Tegotens ^® EC 11).

As additives suitable cationic surfactants are particularly compatible with anionic surfactants, cationic surfactants such as quaternary ammonium compounds, for example Kokospentaethoxymethylammoniummethosulfat (INCI PEG-5 Cocomonium Methosulfate; Rewoquat CPEM ^®).

Polymers suitable as additives in particular maleic acid-acrylic acid copolymer, Na salt (Sokalan ^® CP 5), modified polyacrylic acid Na salt are (Sokalan ^® CP 10), modified polycarboxylate Na salt (Sokalan ^® HP 25), polyalkylene oxide, modified heptamethyltrisiloxane (Silwet ^® L-77), polyalkylene oxide-modified heptamethyltrisiloxane (Silwet ^® L-7608) and polyether (copolymers of polydimethylsiloxanes having ethylene oxide / propylene oxide segments (polyether)), preferably water-soluble linear polyether having terminal polyether as Tegopren ^® 5840, Tegopren ^® 5843, Tegopren ^® 5847, Tegopren ^® 5851, Tegopren ^® 5863 or Tegopren ^® 5878.

As additives suitable builders are, in particular polyaspartic acid-Na-salt, Ethylendiamintriacetatkokosalkylacetamid (Rewopol ^® CHT 12), methylglycine-Tri-Na-salt (Triton ^® ES 9964) and acetophosphonic (Turpinal SL ^®).

Blends with surfactant or polymeric additives show in the case of Monawet MO-84 ^® R2W, Tegopren ^® 5843 and Tegopren 5863 ^® synergism. However, the use of Tegopren grades 5843 and 5863 is less preferred when applied to hard surfaces of glass, especially glassware, since these can apply silicone surfactants to glass.

In a particular embodiment invention, the substrate according to the invention is free from the mentioned Additives.

The viscosity of the composition with which the substrate according to the invention can be impregnated / impregnated / impregnated / coated, can be measured by conventional standard methods (for example, Brookfield LVT-II at 20 rpm and 20 ° C., spindle 3) and can preferably be in Range from 20 to 5000 mPas. Preferred viscosities may also be at values of 700 to 4000 mPas, where values between 1000 and 3000 mPas may be particularly preferred. The viscosity can also assume lower values, for. B. values between 40 and 500 mPas or z. B. 60 to 300 mPas. Values <20 mPas are also possible, eg. In the range of 2 mPAs to <20 mPAs. The values given in each case relate to measurements with the Brookfield LVT-II viscometer at 20 rpm and 20 ° C., spindle 3.

The viscosity the composition with which a substrate according to the invention, can be beaten, is - in particular at a low surfactant content - can be increased by thickening agents and / or can - in particular at a high surfactant content - through the optional water-soluble inorganic salts as well as by solvents be reduced.

to Thickening can one or more polymeric thickening agents are used.

polymers Thickening agents in the context of the present invention are as Polyelectrolytes thickening polycarboxylates, preferably Homo- and copolymers of acrylic acid, especially acrylic acid copolymers such as acrylic acid-methacrylic acid copolymers, and the polysaccharides, in particular heteropolysaccharides, as well as other usual thickening polymers.

suitable Polysaccharides or heteropolysaccharides are the polysaccharide gums, For example, gum arabic, agar, alginates, carrageenans and their Salts, Guar, Guaran, Tragacant, Gellan, Ramsan, Dextran or Xanthan and their derivatives, e.g. B. propoxylated guar, and their mixtures. Other polysaccharide thickeners, such as starches or cellulose derivatives, can alternatively, but preferably in addition to a polysaccharide gum used, for example, strengths of different origin and starch derivatives, e.g. B. hydroxyethyl starch, Stärkephosphatester or starch acetates, or carboxymethylcellulose or its sodium salt, methyl, ethyl, Hydroxyethyl, hydroxypropyl, hydroxypropylmethyl or hydroxyethyl methylcellulose or cellulose acetate.

A preferred polymeric thickener is the microbial anionic heteropolysaccharide xanthan gum derived from Xanthomonas campestris and some other species under aerobic conditions with a molecular weight of 2 -. Is produced 15 × 10 ⁶ and, for example, by the company Kelco under the trade name Keltrol ^®, z. As a cream-colored powder Keltrol ^® T (transparent) or as white granules Keltrol RD (Readily Dispersable).

Acrylic acid polymers suitable as polymeric thickeners are, for example, high molecular weight homopolymers of acrylic acid crosslinked with a polyalkenyl polyether, in particular an allyl ether of sucrose, pentaerythritol or propylene (INCI Carbomer), which are also referred to as carboxyvinyl polymers. Such polyacrylic acids are available, inter alia, from the company. BFGoodrich under the trade name Carbopol ^® , z. Carbopol ^® 940 (molecular weight approximately 4,000,000), Carbopol ^® 941 (molecular weight approximately 1,250,000) or Carbopol ^® 934 (molecular weight approximately 3,000,000).

However, particularly suitable polymeric thickeners are the following acrylic acid copolymers: (i) Copolymers of two or more monomers from the group of acrylic acid, methacrylic acid and their simple, preferably with C _1-4 alkanols formed esters (INCI acrylates copolymer), to which example, the copolymers of methacrylic acid, butyl acrylate and methyl methacrylate (CAS 25035-69-2) or of butyl acrylate and methyl methacrylate (CAS 25852-37-3) and available, for example from Messrs. Rohm & Haas under the trade names Aculyn ^® and Acusol ^® are, for. As the anionic non-associative polymers Aculyn ^® 33 (crosslinked), Acusol ^® 810 and Acusol ^® 830 (CAS 25852-37-3); (ii) crosslinked high molecular weight acrylic acid copolymers, such as those crosslinked with an allyl ether of sucrose or pentaerythritol copolymers of C _10-30 alkyl acrylates with one or more monomers selected from the group of acrylic acid, methacrylic acid and their simple, preferably with C _1-4 Alkanols formed, esters (INCI acrylates / -C10-30 alkyl acrylate crosspolymer) and which are available, for example, from the company BFGoodrich under the trade name Carbopol ^® , z. B. hydrophobized Carbopol ETD2623 ^® and Carbopol® 1382 (INCI Acrylates / C10-30 Alkyl Acrylate Crosspolymer) and Carbopol AQUA ^® 30 (formerly Carbopol ^® EX 473).

Of the Content of polymeric thickener may preferably be between 0.01 and 4 wt .-%, particularly preferably between 0.1 and 2 wt .-%, in particular between 0.5 and 1.5 wt .-% amount. The content of polymeric thickener may also be> 4 wt .-%, wt .-% based on the overall composition with which the substrate is impregnated / impregnated / impregnated / coated is.

In a preferred embodiment However, according to the invention, the substrate is free of polymeric thickening agents.

For stabilization, especially at high surfactant content, one or more dicarboxylic acids and / or salts thereof may be added, in particular a composition of Na salts of adipic, succinic and glutaric acid, as described, for. B. under the trade name Sokalan ^® DSC is available. The use is advantageously carried out in amounts of 0.1 to 8 wt .-%, preferably 0.5 to 7 wt .-%, in particular 1.3 to 6 wt .-% and particularly preferably 2 to 4 wt .-%, Wt .-% based on the total composition with which the substrate is impregnated / impregnated / impregnated / coated.

A change of the dicarboxylic acid (salt) content can - in particular in amounts above 2 wt .-% - too a clear solution contribute to the ingredients. Also within certain limits an influence on the viscosity the mixture by this means possible. Furthermore influenced this component is the solubility the mixture. This component is particularly preferred at high Tensidgehalten used, especially at Tensidgehalten above 30% by weight.

can however, their use is dispensed with, so is the substrate according to the invention preferably free from dicarboxylic acid (salts) n.

In addition to the substances already geannten, but also independently of these, one or more more - especially in cleaning agents for hard surfaces - common auxiliaries and additives, especially hydrotropes, such as xylene or cumene sulfonate, octyl sulfate, butyl glucoside or butyl glycol, UV- stabilizers, perfumes, pearlescent agents (INCI opacifying agents, for example glycol distearate, for example Cutina ^® AGS from Cognis, or mixtures comprising, for example, the Euperlane ^® from Cognis....), dyes, corrosion inhibitors, preservatives ( z. B. the technical also known as Bronopol 2-bromo-2-nitro-1,3-diol (CAS 52-51-7), which is commercially available for example as Myacide ^® BT or as Boots Bronopol BT from Boots ), organic salts, disinfectants, enzymes, pH adjusters and skin feel-improving or nourishing additives (eg dermatologically active substances such as vitamin A, vitamin B2, vitamin B12, vitam in C, vitamin E, D-panthenol, sericerin, collagen partial hydrolyzate, various vegetable protein partial hydrolysates, protein hydrolyzate-fatty acid condensates, liposomes, cholesterol, vegetable and animal oils such. As lecithin, soybean oil, etc., plant extracts such. Aloe vera, azulene, witch hazel extracts, algae extracts, etc., allantoin, AHA complexes) in amounts of usually not more than 5% by weight. However, it is also possible for one or more of these substances to be present in amounts of> 5% by weight, based on the total composition with which the substrate is impregnated / impregnated / impregnated / coated.

The substrates of the invention may contain preservatives, preferably only those are used which have no or only a slight skin-sensitizing potential. Examples are sorbic acid and its salts, benzoic acid and its salts, salicylic acid and its salts, phenoxyethanol, 3-iodo-2-propynyl butylcarbamate, sodium N- (hydroxymethyl) glycinate, biphenyl-2-ol and mixtures thereof. A suitable preservative provides the solvent-free, aqueous combination of diazolidinyl urea, sodium benzoate and potassium sorbate (available as Euxyl K 500 ^® from Schuelke & Mayr), which can be used in a pH range up. 7 In particular, preservatives based on organic acids and / or their salts are suitable for preservation.

It can also contain silicone derivatives. Preferred silicone derivatives are, for example, polydialkyl or alkylaryl siloxanes in which the alkyl groups one to five Have C atoms and are completely or partially fluorinated. preferred Silicones are polydimethylsiloxanes which are optionally derivatized could be and are then amino-functional or quaternized or Si-OH-, Si-H- and / or Si-Cl bonds. The viscosities of the preferred silicones are at 25 ° C in the range between 100 and 100,000 mPas, the silicones preferably in amounts between 0.2 and 5 wt .-%, wt .-% based on the total Composition with which the substrate is impregnated / impregnated / impregnated / coated is, can be used.

Of the pH can be determined by means of usual pH regulators, for example acids like mineral acids or citric acid and / or alkalis such as sodium or potassium hydroxide be, where - especially at desired Hand compatibility - one area from 4 to 9, preferably 5 to 8, in particular 5.5 to 7.5, preferred is.

To adjust and / or stabilize the pH, one or more buffer substances (INCI Buffering Agents) may be contained, usually in amounts of 0.001 to 5 wt .-%, preferably 0.005 to 3 wt .-%, in particular 0.01 to 2 wt .-%, particularly preferably 0.05 to 1 wt .-%, most preferably 0.1 to 0.5 wt .-%, for example, 0.2 wt .-% by weight based on the total composition , with which the substrate is impregnated / loaded / impregnated / coated. Preference is given to buffer substances which are at the same time complexing agents or even chelating agents (INCI chelating agents). Particularly preferred buffer substances are the citric acid or the citrates, in particular the sodium and potassium citrates, for example trisodium citrate.2H ₂ O and tripotassium citrate H ₂ O.

The inventive substrate may preferably comprise complexing agents. This corresponds to a preferred one embodiment the invention. For example, the following are suitable according to INCI Complexing agents, for example, in the International Cosmetic Ingredient Dictionary and Handbook described in more detail are: Aminotrimethylene Phosphonic Acid, Beta-Alanine Diacetic Acid, Calcium Disodium EDTA, Citric Acid, Cyclodextrin, Cyclohexanediamine Tetraacetic Acid, Diammonium Citrate, Diammonium EDTA, Diethylenetriamine Pentamethylene Phosphonic Acid, Dipotassium EDTA, Disodium Azacycloheptane Diphosphonates, Disodium EDTA, Disodium Pyrophosphate, EDTA, Etidronic Acid, Galactic Acid, Gluconic Acid, Glucuronic Acid, HEDTA, Hydroxypropyl Cyclodextrin, methyl cyclodextrin, pentapotassium triphosphate, pentasodium Aminotrimethylene Phosphonates, Pentasodium Ethylenediamine Tetramethylene Phosphonates, Pentasodium Pentetates, Pentasodium Triphosphates, Pentetic Acid, Phytic Acid, Potassium Citrate, Potassium EDTMP, Potassium Gluconate, Potassium Polyphosphate, Potassium Trisphosphonomethylamine Oxides, Ribonic Acid, Sodium Chitosan Methylene Phosphonates, Sodium Citrate, sodium diethylenetriamine pentamethylene phosphonate, sodium Dihydroxyethylglycinate, Sodium EDTMP, Sodium Gluceptate, Sodium Gluconate, Sodium Glycereth-1 Polyphosphate, Sodium Hexametaphosphate, Sodium Metaphosphate, Sodium Metasilicate, Sodium Phytate, Sodium Polydimethylglycinophenolsulfonates, sodium trimetaphosphates, TEA-EDTA, TEA polyphosphates, tetrahydroxyethyl, ethylenediamines, tetrahydroxypropyl Ethylenediamine, tetrapotassium etidronate, tetrapotassium pyrophosphate, Tetrasodium EDTA, Tetrasodium etidronate, Tetrasodium pyrophosphate, Tripotassium EDTA, Trisodium Dicarboxymethyl Alaninate, Trisodium EDTA, Trisodium HEDTA, Trisodium NTA and Trisodium Phosphate.

preferred Complexing agents are tertiary Amines, especially tertiary Alkanolamines (amino alcohols). The alkanolamines have both amino as well as hydroxy and / or ether groups as functional groups. Particularly preferred tertiary Alkanolamines are tri-ethanolamine and tetra-2-hydroxypropyl-ethylenediamine (N, N, N ', N'-tetrakis (2-hydroxy-pro-pyl) ethylenediamine). Particularly preferred combinations of tertiary amines with Zinkricinoleat and one or more ethoxylated fatty alcohols as nonionic solubilizers and optionally solvents are described in the prior art.

One particularly preferred complexing agent is the etidronic acid (1-hydroxyethylidene-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid, HEDP, acetophosphonic, INCI Etidronic Acid) including their salts. In a preferred embodiment, accordingly, as a complexing agent Etidronic acid and / or contain one or more of their salts.

In a particular embodiment contains the substrate according to the invention a complexing agent combination of one or more tertiary amines and one or more other complexing agents, preferably one or more complexing acids or their salts, in particular triethanolamine and / or tetra-2-hydroxypropylethylenediamine and etidronic acid and / or one or more of their salts.

The inventive substrate may advantageously be complexing agent in an amount of usually 0 to 20 wt .-%, preferably 0.1 to 15 wt .-%, in particular 0.5 to 10 wt .-%, particularly preferably 1 to 8 wt .-%, most preferably 1.5 to 6 wt .-%, wt .-% based on the total composition, with which the substrate impregnated / acted / impregnated / coated is.

According to one preferred embodiment The invention can use water as a solvent in the substrate according to the invention be included. The water content of the substrate according to the invention can usually be 10 to 95 wt .-%, preferably 15 to 90 wt .-%, in particular 20 to 80 wt .-%, wt .-% based on the total composition, with which the substrate impregnated / acted / impregnated / coated is.

Possible upper limits for the contained water can for example, also at 75% by weight, 70% by weight, 65% by weight, 60% by weight, 55 wt .-%, 50 wt .-% or 45 wt .-% are. Possible lower limits for the included Water can for example, also at 25% by weight, 30% by weight, 35% by weight, 40% by weight, 45 wt .-%, 50 wt .-% or 55 wt .-%, wt .-% based on the overall composition with which the substrate is impregnated / impregnated / impregnated / coated is.

According to the invention, in addition to Water, but also independent from this, one or more, preferably water-soluble, organic solvents be included, usually in an amount of 5 to 35% by weight, preferably 7 to 25% by weight, in particular 8 to 20 wt .-%. Possible Upper limits for these preferably water-soluble, organic solvents can for example, also at 75% by weight, 70% by weight, 65% by weight, 60% by weight, 55 wt .-%, 50 wt .-% or 45 wt .-%, wt .-% based on the total Composition with which the substrate is impregnated / impregnated / impregnated / coated is.

The solvent is within the scope of the teaching of the invention used as needed, especially as a hydrotrope and Viscosity regulator. It can be solution-enabling act, especially for surfactants and electrolyte and perfume and dye, usually prevents the formation of liquid crystalline phases and usually has Share in the formation of clear products.

Suitable solvents are, for example, saturated or unsaturated, preferably saturated, branched or unbranched C _1-20 -hydrocarbons, preferably C _2-15 -hydrocarbons, having at least one hydroxy group and optionally one or more ether functions COC, ie the carbon atom chain interrupting oxygen atoms.

Preferred solvents are the - optionally unilaterally etherified with a C _1-6 alkanol - C _2-6 alkylene glycols and poly-C _2-3 alkylene glycol having an average of 1 to 9 identical or different, preferably the same, alkylene glycol groups per molecule as well C _1-6 -alcohols, preferably ethanol, n-propanol or isopropanol, especially ethanol.

exemplary solvent are the following named according to INCI Compounds: Alcohol (ethanol), buteth-3, butoxydiglycol, butoxyethanol, Butoxyisopropanol, butoxypropanol, n-butyl alcohol, t-butyl alcohol, Butylenes glycol, butyloctanol, diethylenes glycol, dimethoxydiglycol, Dimethyl ether, dipropylene glycol, ethoxydiglycol, ethoxyethanol, Ethyl hexanediol, glycol, hexanediol, 1,2,6-hexanediol, hexyl alcohol, Hexylene glycol, isobutoxypropanol, isopentyldiol, isopropyl alcohol (iso-propanol), 3-methoxybutanol, methoxy diglycol, methoxyethanol, Methoxyisopropanol, methoxymethylbutanol, methoxy PEG-10, methylal, Methyl alcohol, methyl hexyl ether, methyl propanediol, neopentyl Glycol, PEG-4, PEG-6, PEG-7, PEG-8, PEG-9, PEG-6 methyl ether, pentylenes Glycol, phenoxyethanol, PPG-7, PPG-2-buteth-3, PPG-2 butyl ether, PPG-3 butyl ether, PPG-2 methyl ether, PPG-3 methyl ether, PPG-2 Propyl ether, propanediol, propyl alcohol (n-propanol), propylene Glycol, propylene glycol butyl ether, propylene glycol propyl ether, Tetrahydrofurfuryl alcohol, trimethylhexanol.

Farther preferred are longer chain Polyalkylene glycols, especially polypropylene glycols, such as PPG-400 or PPG-450.

Preferably is the solvent selected from the group comprising methanol, ethanol, propanol, isopropanol, Ethylene glycol, phenoxyethanol, propylene glycol, PPG and mixtures the same.

Most preferred solvents are the C _2-3 alcohols ethanol, n-propanol and / or iso-propanol, especially ethanol, and the polyalkylene glycols, especially polypropylene glycols, especially the PPG-400.

When solubilizers especially for Perfume and dyes can except the solvents described above for example, alkanolamines and alkylbenzenesulfonates with 1 to 3 carbon atoms are used in the alkyl radical.

The inventive substrate contains preferably further one or more water-soluble salts. It may be to act in inorganic and / or organic salts, in one preferred embodiment contains the substrate thereby at least one inorganic salt.

Usable according to the invention inorganic salts are preferably selected from the group comprising colorless water-soluble halides, sulphates, Sulfites, carbonates, bicarbonates, nitrates, nitrites, phosphates and / or oxides of alkali metals, alkaline earth metals, aluminum and / or the transition metals; Furthermore, ammonium salts can be used. Particularly preferred while halides and sulfates of the alkali metals; is preferred the inorganic salt therefore selected from the group comprising Sodium chloride, potassium chloride, sodium sulfate, potassium sulfate as well Mixtures thereof.

The organic salts which can be used according to the invention are, in particular, colorless water-soluble alkali metal, alkaline earth metal, ammonium, aluminum and / or transition metal salts of the carboxylic acids. Preferably, the salts are selected from the group comprising formate, acetate, propionate, citrate, malate, tartrate, succinate, malonate, oxalate, lactate [(D) (L) lactate (enantiomerically pure and / or as an optically inactive mixture)] and mixtures thereof ,

The inventive substrate contains in a preferred embodiment 1 to 20 wt .-%, preferably 1.5 to 15 wt .-%, particularly preferably 2 to 10 wt .-% of at least one water-soluble inorganic and / or 1 to 20 wt .-%, preferably 1.5 to 10 wt .-%, particularly preferably 0.5 to 7 wt .-%, in particular 0.8 to 5 wt .-% of at least one water-soluble organic salt, wt .-% based on the total composition, with which the substrate impregnated / acted / impregnated / coated is.

Next the components mentioned so far, the substrates of the invention contain additional ingredients. These include, for example, more Surfactants, additives for adjusting the viscosity, for stabilization as well more in usual Auxiliaries and additives, such as hydrotropes, UV stabilizers, pearlescing agents, fragrances, Dyes, corrosion inhibitors, preservatives, organic Salts, disinfectants, enzymes, pH adjusters and skin feel-improving or nourishing additives. The substrates of the invention may preferably also with perfume oil (fragrances, Fragrances) perfumed be.

With the term perfume oil are preferred meant self-contained perfume compositions commonly known be used for product scenting and in particular for human Discretion are fragrant. This will be explained with an example. Want a professional z. B. make a detergent fragrant, so he adds him for usually not just a (well) smelling substance, but a collective (well) smelling Substances. Such a collective usually consists of a variety of individual fragrances, eg. More than 10 or 15, preferably up to 100 or more. These fragrances form cooperatively a desired one fragrant, harmonious smell.

One usable perfume oil can be individual Fragrance compounds, eg. B. the synthetic products of the type the esters, ethers, aldehydes, ketones, alcohols and hydrocarbons contain. Fragrance compounds of the ester type are e.g. B. benzyl acetate, Phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, Linalyl acetate, dimethylbenzylcarbinylacetate (DMBCA), phenylethyl acetate, Benzyl acetate, ethyl methyl phenyl glycinate, allyl cyclohexyl propionate, Styrallyl propionate, benzyl salicylate, cyclohexyl salicylate, floramate, Melusat and Jasmecyclat. Ethers include, for example, benzyl ethyl ether and ambroxan, to the aldehydes e.g. B. the linear alkanals with 8-18 C atoms, Citral, citronellal, citronellyloxy-acetaldehyde, cyclamenaldehyde, Lilial and Bourgeonal, to the ketones z. The ionone, ∞-isomethylionone and methyl cedryl ketone, to the alcohols anethole, citronellol, eugenol, Geraniol, linalool, phenylethyl alcohol and terpineol, to the hydrocarbons belong mainly the terpenes like limonene and pinene. However, mixtures are preferred different fragrances used, which together create an appealing Generate fragrance of the perfume oil formed.

The But perfume oils can also natural Contain fragrance mixtures, as they are accessible from plant sources, z. Pine, citrus, jasmine, patchouly, rose or ylang-ylang oil. Also suitable are Muscat sage oil, Chamomile oil, Clove oil, Melissa oil mint oil, Cinnamon leaf oil, lime blossom oil, juniper berry oil, vetiver oil, olibanum oil, galbanum oil and labdanum oil, as well as Orange blossom oil, neroliol, Orange peel oil and sandalwood oil. To be perceptible, one must Perfume volatile being, besides the nature of the functional groups and the structure the molecular weight of the chemical compound also plays an important role plays. So most perfumes have molecular weights up to about 200 Dalton, while Molar masses of 300 daltons and above rather an exception. Due to the different volatility changed by fragrances the smell of a compound of several fragrances perfumes while vaporizing, whereby the odor impressions in "top note", "middle note" body) and "base note" (end note or dry divided out).

Adhesive-resistant fragrances which are advantageously usable in the context of the present invention are, for example, the essential oils such as angelica root oil, aniseed oil, arnica blossom oil, basil oil, Bayöl, Champacablütenöl, Edeltannenöl, Edeltannenzapfenöl, Elemiöl, eucalyptus oil, fennel oil, spruce alder oil, galbanum oil, geranium oil, ginger grass oil, guaiac wood oil , Gurijar balm oil, helichrysum oil, ho oil, ginger oil, iris oil, cajeput oil, calamus oil, chamomile oil, camphor oil, kanaga oil, cardamom oil, cassia oil, pine needle oil, copaϊva balsam oil, coriander oil, spearmint oil, caraway oil, cumin oil, lemongrass oil, musk kernel oil, myrrh oil, clove oil, neroli oil, niaouli oil , Olibanum oil, Origanum oil, Palmarosa oil, Patchouli oil, Peruvian balsam oil, Petitgrain oil, Pepper oil, Peppermint oil, Pimento oil, Pine oil, Rose oil, Rosemary oil, Sandalwood oil, Celery oil, Star aniseed oil, Thuja oil, Thymi oil, verbena oil, vetiver oil, juniper berry oil, wormwood oil, wintergreen oil, ylang-ylang oil, hyssop oil, cinnamon oil, cinnamon oil and cypress oil. But also the higher-boiling or solid fragrances of natural or synthetic origin can be used in the context of the present invention advantageously as adherent fragrances or fragrance mixtures. These compounds include the following compounds and mixtures thereof: ambrettolide, α-amylcinnamaldehyde, anethole, anisaldehyde, anisalcohol, anisole, methyl anthranilate, acetophenone, benzylacetone, benzaldehyde, ethyl benzoate, benzophenone, benzyl alcohol, borneol, bornyl acetate, α-bromostyrene, n -Decylaldehyde, n-dodecylaldehyde, eugenol, eugenol methyl ether, eucalyptol, farnesol, fenchone, fenchyl acetate, geranyl acetate, geranyl formate, heliotropin, heptincarboxylic acid methyl ester, heptaldehyde, hydroquinone dimethyl ether, hydroxycinnamaldehyde, hydroxycinnamyl alcohol, indole, iron, isoeugenol, isoeugenol methyl ether, isosafrole, jasmon , Camphor, Karvakrol, Karvon, p-cresol methyl ether, coumarin, p-methoxyacetophenone, methyl-n-amyl ketone, methyl anthranilate, p-methylacetophenone, methylchavikole, p-methylquinoline, methyl-β-naphthyl ketone, methyl-n-nonylacetaldehyde, methyl-n nonyl ketone, muskon, β-naphthol ethyl ether, β-naphthol methyl ether, nerol, nitrobenzene , n-nonylaldehyde, nonyl alcohol, n-octylaldehyde, p-oxyacetophenone, pentadecanolide, β-phenylethyl alcohol, phenylacetaldehyde dimethylacetal, phenylacetic acid, pulegone, safrole, isoamyl salicylate, methyl salicylate, hexyl salicylate, cyclohexyl salicylate, santalol, skatole, terpineol, thymene, thymol , γ-undelactone, vaniline, veratrum aldehyde, cinnamaldehyde, cinnamyl alcohol, cinnamic acid, cinnamic acid ethyl ester, cinnamic acid benzyl ester. Among the more volatile fragrances which can be used advantageously in the context of the present invention, in particular the lower-boiling fragrances include natural or synthetic origin, which can be used alone or in mixtures. Examples of more readily volatile fragrances are alkyl isothiocyanates (alkyl mustard oils), butanedione, limonene, linalool, linayl acetate and propionate, menthol, menthone, methyl-n-heptenone, phellandrene, phenylacetaldehyde, terpinyl acetate, citral, citronellal.

All The above-mentioned fragrances are alone or in a mixture according to the present invention Invention can be used with the advantages already mentioned.

Especially can also fragrances from the group of allyl alcohol esters, esters of secondary alcohols, Ester tertiary Alcohols, allylic ketones, acetals, ketals, condensation products of amines and aldehydes and / or mixtures thereof.

allyl alcohol are the esters of allyl alcohol, which has the following structural feature has, C (OH) -C = C. examples for Allylalkohlester are in particular Allylamylglycolat, allylanthranilate, Allyl benzoate, allyl butyrate, allyl caprate, allyl caproate, allyl cinnamate, Allylcyclohexane acetate, allylcyclohexanebutyrate, allylcyclohexanepropionate, Allylheptoate, allylnonanoate, allylsalicylate, amylcinnamylacetate, Amyl cinnamyl formate, cinnamyl formates, cinnamyl acetates, cyclogalbanate, Geranyl acetate, geranyl acetoacetate, geranyl benzoate, geranyl cinnamate, Methallyl butyrate, methallyl caproate, neryl acetate, neryl butyrate, amyl cinnamyl formate, Alpha methyl cinnamyl acetate, methyl geranyl tiglate, mertenyl acetate, Farnesyl acetate, fenchyl acetate, geranyl anthranilate, geranyl butyrate, Gerany isobutyrate, geranyl caproate, geranyl caprylate, geranyl ethyl carbonate, Geranyl formate, geranyl furoate, geranyl heptoate, geranyl methoxyacetate, Geranyl pelargonate, geranyl phenylacetate, geranyl phthalate, geranyl propionate, Geranyl iso-propoxyacetate, geranyl valerate, geranyl iso-valerate, trans-2-hexenyl acetate, trans-2-hexenyl butyrate, trans-2-hexenyl caproate, trans-2-hexenylphenylacetate, trans-2-hexenylpropionate, trans-2-hexenyltiglate, trans-2-hexenylvalerate, beta-pentenyl acetate, alpha-phenylallyl acetate, prenyl acetate, trichloromethylphenylcarbinyl acetate and / or mixtures thereof. Allyl alcohol esters may preferably be in the inventive substrate be included.

Examples of Esters of Secondary Alcohols (Secondary alcohols are present when two H atoms are substituted by organic radicals (R ¹ and R ² ) on the carbon atom bearing the OH group [general formulas: R ¹ -CH ( OH) -R ² ]) are in particular ortho-tert-amylcyclohexyl acetate, isoamylbenzylacetate, secondary n-amylbutyrate, amylvinylcarbinylacetate, amylvinylcarbinylpropionate, cyclohexylsalicylate, dihydro-nor-cyclopentadienylacetate, dihydro-nor-cyclopentadienylpropionate, isobornylacetate, isobornylsalicylate, isobornylvalerate, Frutene, 2 Methylbutene-2-ol-4-acetate, methylphenylcarbinylacetate, 2-methyl-3-phenylpropan-2-yl acetate, prenylacetate, 4-tert-butylcyclohexylacetate, verdox (2-tert-butylcyclohexylacetate), I vertenex (4- tert-butylcyclohexyl acetate), Violiff (carboxylic acid 4-cycloocten-1-yl methyl ester), ethenyl-iso-amyl carbinyl acetate, fenchyl acetate, fenchyl benzoate, fenchyl n-butyrate, fenchyl isobutyrate, laevomenthyl acetate, dl-menthyl acetate, menthyl anthranilate, menthyl benzoate, menthyl -iso-butyrate, menthyl formate, laevo-menthylphenyl acetate, menthyl propionate, menthyl salicylate, menthyl iso-valerate, cyclohexyl acetates, cyclohexyl anthranilate, cyclohexyl benzoate, cyclohexyl butyrate, cyclohexyl isobutyrate, cyclohexyl caproate, cyclohexyl cinnamate, cyclohexyl formates, cyclohexylheptoate, cyclohexyl oxalate, cyclohexyl pelargonate, cyclohexyl phenylacetate , Cyclohexyl propionate, cyclohexyl thioglycolate, cyclohexyl valerate, cyclohexyl iso-valerate, methyl amyl acetate, Methylbenzylcarbinylacetat, Methylbutylcyclohexanylacetat, 5-methyl-3-butyl tetrahydropyran-4-yl acetate, methyl citrate, methyl iso-campho lat, 2-methylcyclohexylacetate, 4-methylcyclohexylacetate, 4-methylcyclohexylmethylcarbinylacetate, methylethylbenzylcarbinylacetate, 2-methylheptanol-6-acetate, methylheptenylacetate, alpha-methyl-n-hexylcarbinylformiate, methyl-2-methylbutyrate, methylnonylcarbinylacetate, methylphenylcarbinylacetate, methylphenylcarbinylanthranilate, methylphenylcarbinylbenzoate, methylphenylcarbinyl-n butyrate, methylphenylcarbinyl isobutyrate, methylphenylcarbinyl; Caproate, methylphenylcarbinylcaprylate, methylphenylcarbinyl cinnamate, methylphenylcarbinylformate, methylphenylcarbinylphenylacetate, methylphenylcarbinylpropionate, methylphenylcarbinylsalicylate, methylphenylcarbinyliso-valerate, 3-nonanylacetate, 3-nonenylacetate, nonanediol-2,3-acetate, nonynolacetate, 2-octanylacetate, 3-octanylacetate, n-octyl acetate, sec-octyl-isobutyrate, beta-pentenylacetate, alpha-phenylallylacetate, phenylethylmethylcarbinyliso-valerate, phenylethylene glycol diphenylacetate, phenylethyethylcarbinylacetate, phenylglycoldiacetate, sec-phenylglycol monoacetate, phenylglycolmonobenzoate, isopropylcaprate, isopropylcaproate, isoporppylcaprylate, isopropylcinnamate, para-isopropylcyclohexanyl acetate, propyl glycol diacetate, propylene glycol di-isobutyrate, propylene glycol dipropionate, isopropyl n-heptoate, isopropyl n-hept-1-yne carbonate, isopropyl pelargonate, isopropyl propionate, isopropyl undecylenate, isopropyl n-valerate, isopropyl n-valerate, isopropyl iso-valerate, isopropyl sebacinate, isopu legyl acetate, isopulegyl acetoacetate, isopuleglyisobutyrate, isopulegylformate, thymylpropionate, alpha-2,4-trimethylcyclohexanemethylacetate, trimethylcyclohexylacetate, vanillin triacetate, vanillylidene diacetate, vanillylvanilate, and / or mixtures thereof. These esters may preferably be contained in the substrate according to the invention.

Preferred examples of esters of tertiary alcohols (tertiary alcohols are those in which three H atoms are substituted by organic radicals R ¹ , R ² , R ³ at the α-C atom which carries the OH group (general formula: R ¹ R ² R ³ C-OH)) are tertiary amyl acetate, Caryophylleneacetat, Cedrenylacetat, Cedrylacetat, Dihydromyrcenylacetat, Dihydroterpinylacetat, dimethylbenzyl carbinyl acetate, Dimethylbenzylcarbinylisobutyrat, Dimethylheptenylacetat, Dimethylheptenyl formate, Dimethylheptenylpropionat, Dimethylheptenyl iso-butyrate, Dimethylphenylethylcarbinylacetat, Dimethylphenylethylcarbinyl iso-butyrate Dimethylphenylethylcarbinyl iso-valerate, dihydro-nor-dicyclopentadienylacetate, dimethylbenzylcarbinylbutyrate, dimethylbenzylcarbinylformate, dimethylbenzylcarbinylpropionate, dimethylphenylethylcarbinyl-n-butyrate, dimethylphenyletylcarbinylformate, dimethylphenylethylcarbinylpropionate, elemylacetate, ethynylcyclohexylacetate, eudesylacetate, eugenylcinnamate, eugenylformate, iso-eu genyl formate, Eugenylphenylacetat, Isoeudehylphenylacetat, Guaiylacetat, Hydroxycitronellyl ethyl carbonate, Linallylacetat, Linallylanthranilat, Linallylbenzoat, Linallylbutyrat, Linallyl iosbutyrat, Linallylcarproat, Linallylcaprylat, Linallylcinnamat, Linallylcitronellat, Linallyl formate, Linallylheptoat, Linallyl-N-methyl anthranilate, Linallylmethyltiglat, Linallyl pelargonate, Linallylphenylacetat, Linallylpropionat , Linallyl pyruvate, linallyl salicylate, linallyl n-valerate, linallyl iso-valerate, methylcyclopentenolone butyrate, methylcyclopentenolone propionate, methylethylphenylcarbinylacetate, methylheptincarbonate, methylnicotinate, myrcenylacetates, myrcenylformate, myrcenylpropionate, cis-ocimenylacetate, phenylsalicylate, terpinylacetate, terpinylanthranilate, terpinylbenzoate, terpinyl-n- butyrate, terpinyl isobutyrate, terpinyl cinnamate, terpinyl formate, terpinyl phenylacetate, terpinyl propionate, terpinyl n-valerate, terpinyl iso-valerate, tributyl acetyl citrate, and / or mixtures thereof. These esters may preferably be contained in the substrate according to the invention. Some fragrance esters may be esters of allylic and secondary or allylic and tertiary alcohols, in particular amylvinylcarbinylacetate, amylvinylcarbinylpropionate, hexylvinylcarbinylacetate, 3-nonenylacetate, 4-hydroxy-2-hexenylacetate, linallylanthranilate, linallylbenzoate, linallylbutyrate, linallyliosbutyrate, linallyl carproate, Linallylcaprylat, Linallylcinnamat, Linallylcitronellat, Linallylformat, Linallylheptoat, Linallyl-N-methyl anthranilate, Linallylmethyltiglat, Linallylpelargonat, Llinallylphenylacetat, Linallylpropionat, Linallylpyruvat, Linallylsalicylat, Linallyl-n-valerate, Linallyl-iso-valerate, myrtenol acetate, Nerolidylacetate, Nerolidylbutyrat, beta-pentenyl acetate , Alpha-Phenylallylacetat, and / or mixtures thereof. These esters may also be contained in the substrate according to the invention.

allylic Ketones are over following structural feature, C-C (= O) -C = C. Preferred examples are acetylfuran, allethrolone, allylionone, allylpulegone, amylcyclopentenone, Benzylideneacetone, benzylideneacetophenone, alpha-isomethyl-ionone, 4- (2,6,6-trimethyl-1-cyclohexen-1-yl) 3-buten-2-one, Beta damascone (1- (2,6,6-trimethylcyclohexen-1-yl) -2-buten-1-one), Damascenone (1- (2,6,6-trimethyl-1,3-cyclohexadien-1-yl) -2-buten-1-one), Delta Damascone (1- (2,6,6-trimethyl-3-cyclohexen-1-yl) -2-buten-1-one), Alpha ionone (4- (2,6,6-trimethyl-1-cyclohexenyl-1-yl) -3-butene-2one), beta ionone (4- (2,6,6-trimethyl-1-cyclohexen-1-yl) -3-butene-2-one), gamma methyl ionone, (4- (2,6,6-trimethyl-2-cyclohexyl-1-yl) -3-methyl-3-buten-2-one), Pulegone and / or mixtures thereof. Allylic ketones may preferably in the substrate according to the invention be included.

Acetals are geminal diethers of the general formula R ¹ CH (OR ² ) (OR ³ ). Preferred examples are acetaldehyde-benzyl-beta-methoxyethyl acetal, acetaldehyde-di-iso-amyl acetal, acetaldehyde-di-pentanediol acetal, acetaldehyde-di-n-propyl acetal, acetaldehyde-ethyl-trans-3-hexenyl acetal, acetaldehyde-phenylethylene glycol acetal , Acetaldehyde phenylethyl-n-propylacetal, Cinnamicaldehyd dimethylacetal, acetaldehyde cyl-beta-methoxyethyl acetal, acetaldehyde diiso amylacetal, acetaldehyde, diethyl acetal, acetaldehyde-di-cis-3-hexenyl acetal, acetaldehyde dipentanediol acetal, acetaldehyde-di-n-propyl acetal, acetaldehyde-ethyl-trans-3-hexenyl acetal , Acetaldehyde-phenylethyleneglycol acetal, acetaldehyde, phenylethyl-n-propyl acetal, acetylvinyl dimethyl acetal, alpha-amyl cinnamic aldehyde-di-iso-propyl acetal, p-tert-amyl phenoxy acetaldehyde diethyl acetal, anisaldehyde diethyl acetal, anisaldehyde dimethyl acetal, isoapiols, benzaldehyde diethyl acetal, benzaldehyde di - (ethyleneglycol monobutyl ether) acetal, benzaldehyde dimethylacetal, Benzaldehydethyleneglycolacetal, Benzaldehydglyceryl acetal, Benzaldehydpropylenglycolacetal, Cinnamicaldehyddiethylacetal, Citraldiethyl acetal, citral dimethyl acetal, Citralpropyleneglycolacetal, alpha-Methylcinnamicaldehyd diethylacetal, alpha-Cinnamicaldehyddimethylacetal, phenylacetaldehyde 2,3-butyleneglycol acetal, Phenylacetaldehydcitronellylmethylacetal, Phenylacetaldehyddiall ylacetal, Phenylacetaldehyddiamylacetal, Phenylacetaldehyddibenzylacetal, Phenylacetaldehyddibutylacetal, phenylacetaldehyde, Phenylacetaldehyddigeranylacetal, phenylacetaldehyde dimethylacetal, Phenylacetaldehydethyleneglycolacetal, Phenylacetaldglycerylacetal, Citronellalcyclomonoglycolacetal, Citronellaldiethylacetal, Citronellaldimethylacetal, Citronellaldiphenylethylacetal, Geranoxyacetaldehyddiethylacetal and / or mixtures thereof. Acetals may preferably be included in the substrate according to the invention.

Ketals are geminal diethers of the general formula R ¹ R ² C (OR ³ ) (OR ⁴ ). Preferred examples are acetone diethyl ketal, acetone dimethyl ketal, acetophenone diethyl ketal, methyl amyl catechol ketal, methyl butyl catechol ketal and / or mixtures thereof. Ketals may preferably be included in the substrate according to the invention.

preferred examples for Condensation products of amines and aldehydes are anisaldehyde methyl anthranilate, Aurantiol (hydroxycitronellalmethyl anthranilate), verdantiol (4-tert-butyl-alpha-methyldihydrocinnamaldehyde-methyl anthranilate), Vertosin (2,4-dimethyl-3-cyclohexene carbaldehyde), Hydroxycitronellalethylanthranilate, Hydroxycitronellal linallylanthranilat, Methyl N- (4- (4-hydroxy-4-methylpentyl) -3-cyclohexenylmethylidenes) anthranilate, methylnaphthyl ketone methylanthranilate, Methyl nonyl acetaldehyde methyl anthranilate, methyl N- (3,5,5-trimethylhexylidene) anthranilate, vanillin methyl anthranilate and / or mixtures thereof. Condensation products of amines and aldehydes may preferably in the substrate according to the invention be included.

Especially it is advantageous if fragrances such. Adoxal (2,6,10-trimethyl-9-undecene-1-al), amyl acetate, Anisaldehyde (4-methoxybenzaldehydes), bacdanol (2-ethyl-4- (2,2,3-trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol), Benzaldehyde, benzophenone, benzyl acetate, benzyl salicylate, 3-hexen-1-ol, cetalox (Dodecahydro-3A, 6,6,9A-tetramethyl-naphtho [2,1B] -furan), cis-3-hexenylacetate, cis-3-hexenylsalicylate, Citronellol, coumarin, cyclohexyl salicylate, cymal (2-methyl-3- (para-isopropylphenyl) propionaldehyde), Decyl aldehyde, ethyl vanillin, ethyl 2-methyl butyrate, ethylene braseate, eucalyptol, Eugenol, exaltolide (cyclopentadecanolide), florhydral (3- (3-isopropylphenyl) butanal), galaxolide (1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-gamma-2-benzopyran), gamma decalactone, gamma dodecalactone, geraniol, geranylnitrile, helional (alpha-methyl-3,4, (methylenedioxy) hydrocinnamaldehyde), heliotropin, Hexyl acetate, hexyl cinnamic aldehyde, hexyl salicylate, hydroxyambrane (2-cyclododecylpropanol), Hydroxycitronellal, iso E super (7-acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7, tetramethyl naphthalene), isoeugenol, isojasmon, koavon (acetyl di-isoamylene), Lauryl aldehyde, Irg 201 (methyl 2,4-dihydroxy-3,6-dimethyl benzoate), Lyral (4- (4-hydroxy-4-methyl-pentyl) 3-cylcohexen-1-carboxaldehyde), Majantol (2,2-dimethyl-3- (3-methylphenyl) -propanol), mayor (4- (1-methylethyl) cyclohexanemethanol), methyl anthranilate, methyl beta naphthylketoe, Methylcedrylon (methyl cedryl ketone), methyl chavicol (1-methyloxy-4,2-propen-1-yl benzene), methyl dihydrojasmonate, methylnonylacetaldehyde, musk indanone (4-acetyl-6-tert-butyl-1,1-dimethyl indan), nerol, nonalactone (4-hydroxynonanoic acid, lactone), norlimbanol (1- (2,2,6-trimethylcyclohexyl) -3-hexanol), P.T. Bucinal (2-methyl-3 (para tert butylphenyl) propionaldehyde), para hydroxyphenylbutanone, patchouli, phenylacetaldehyde, phenylethyl acetate, Phenylethylalcohol, Phenylethylphenylacetat, phenylhexanol / phenoxanol (3-methyl-5-phenyl-pentanol), polysantol (3,3-dimethyl-5- (2,2,3-trimethyl-3-cyclopenten-1-yl) -4-penten-2-ol), Rosaphen (2-methyl-5-phenyl pentanol), sandalwood, alpha-terpinene, Tonalid / musk plus (7-acetyl-1,1,3,4,4,6-hexamethyltetralin), Undecalactone, undecavertol (4-methyl-3-decen-5-ol), undecylaldehyde or undecenaldehyde, vanillin and / or mixtures in the substrate according to the invention are included.

• (a) mandelartigem Geruch, wie vorzugsweise Benzaldehyd, Pentanal, Heptenal, 5-Methylfurfural, Methylbutanal, Furfural und/oder Acetophenon oder
• (b) apfelartigem Geruch, wie vorzugsweise (S)-(+)-Ethyl-2-methylbutanoat, Diethylmalonat, Ethylbutyrat, Geranylbutyrat, Geranylisopentanoat, Isobutylacetat, Linalylisopentanoat, (E)-β-Damascone, Heptyl-2-methylbutyrat, Methyl-3-methylbutanoat, 2-Hexenal-pentylmethylbutyrat, Ethylmethylbutyrate und/oder Methyl-2-Methylbutanoat oder
• (c) apfelschalenartigem Geruch, wie vorzugsweise Ethylhexanoat, Hexylbutanoat und/oder Hexylhexanoat oder
• (d) aprikosenartigem Geruch wie vorzugsweise γ-Undecalacton oder
• (e) bananenartigem Geruch, wie vorzugsweise Isobutylacetat, Isoamylacetat, Hexenylacetat und/oder Pentylbutanoat oder
• (f) bittermandelartigem Geruch wie vorzugsweise 4-Acetyltoluol oder
• (g) schwarze Johannisbeere-artigem Geruch wie vorzugsweise Mercaptomethylpentanon und/oder Methoxymethylbutanethiol oder
• (h) zitrusartigem Geruch wie vorzugsweise Linalylpentanoat, Heptanal, Linalylisopentanoat dodecanal, Linalylformiat, α-p-Dimethylstyrol, p-Cymenol, Nonanal, β-Cubebene, (Z)-Limonenoxid, cis-6-Ethenyltetrahydro-2,2,6-trimethylpyran-3-ol, cis-pyranoidlinalooloxid, Dihydrolinalool, 6(10)-Dihydromyrcenol, Dihydromyrcenol, β-Farnesen, (Z)-β-Farnesen, (Z)-Ocimen, (E)-Limonenoxid, Dihydroterpinylacetat, (+)-Limonen, (Epoxymethylbutyl)methylfuran und/oder p-Cymen oder
• (i) kakaoartigem Geruch wie vorzugsweise Dimethylpyrazin, Butylmethylbutyrat und/oder Methylbutanal oder
• (j) kokusnußartigem Geruch, wie vorzugsweise γ-Octalacton, γ-Nonalacton, Methyllaurat, Tetradecanol, Methylnonanoat, (3S,3aS,7aR)-3a,4,5,7a-tetrahydro-3,6-dimethylbenzofuran-2(3H)-on, 5-Butyldihydro-4-methyl-2(3H)-Furanon, Ethylundecanoat und/oder δ-Decalacton oder
• (k) sahneartigem Geruch wie vorzugsweise Diethylacetal, 3-Hydroxy-2-butanon, 2,3-Pentadion und/oder 4-Heptenal oder
• (l) blumenartigem Geruch wie vorzugsweise Benzylalcohol, Phenylessigsäure, Tridecanal, p-Anisylalcohol, Hexanol, (E,E)-Farnesylaceton, Methylgeranat, trans-Crotonaldehyd, Tetradecylaldehyd, Methylanthranilat, Linalooloxid, Epoxylinalool, Phytol, 10-epi-γ-Eudesmol, Neroloxid, Ethyldihydrocinnamat, γ-Dodecalacton, Hexadecanol, 4-Mercapto-4-methyl-2-pentanol, (Z)-Ocimene, Cetylalcohol, Nerolidol, Ethyl-(E)-cinnamat, Elemicin, Pinocarveol, α-Bisabolol, (2R,4R)-Tetrahydro-4-methyl-2-(2-methyl-1-propenyl)-2H-pyran, (E)-Isoelemicin, Methyl-2-methylpropanoat, Trimethylphenylbutenon, 2-Methylanisol, β-Farnesol, (E)-Isoeugenol, Nitro-phenylethan, Ethylvanillat, 6-Methoxyeugenol, Linalool, β-Ionon, Trimethylphenylbutenon, Ethylbenzoat, Phenylethylbenzoat, Isoeugenol und/oder Acetophenone oder
• (m) Frische-Geruch wie vorzugsweise Methylhexanoat, Undecanon, (Z)-limonenoxid, Benzylacetat, Ethylhydroxyhexanoat, Isopropylhexanoat, Pentadecanal, β-Elemene, α-Zingiberene, (E)-Limonenoxid, (E)-p-Mentha-2,8-dien-1-ol, Menthon, Piperiton, (E)-3-Hexenol und/oder Carveol oder
• (n) Frucht-Geruch wie verzugsweise Ethylphenylacetat, Geranylvalerat, γ-Heptalacton, Ethylpropionat, Diethylacetal, Geranylbutyrat, Ethylheptylat, Ethyloctanoat, Methylhexanoat, Dimethylheptenal, Pentanon, Ethyl-3-methylbutanoat, Geranylisovalerat, lobutylacetat, Ehoxypropanol, Mthyl-2-butenal, Methylnonanedion, Linalylacetat, Mthylgeranat, Lmonenoxid, Hdrocinnamicalcohol, Dethylsuccinat, Ehylhexanoat, Ehylmethylpyrazin, Nryletat, Ctronellylbutyrat, Heylacetat, Nonylacetat, Butylmethylbutyrat, Pentenal, Isopentyldimethylpyrazin, p-month-1-en-9-ol, Hexadecanon, Octylacetat, γ-Dodecalacton, Epoxy-β-ionon, Ethyloctenoat, Ethylisohexanoat, Isobornylpropionat, Cedrenol, p-menth-1-en-9-yl acetat, Cadinadien, (Z)-3-Hexenylhexanoat, Ethylcyclohexanoat, 4-Methylthio-2-butanon, 3,5-Octadienon, Methylcyclohexancarboxylat, 2-pentylthiophen, α-Ocimene, Butandiol, Ethylvalerat, Pentanol, Isopiperiton, Butyloctanoat, Ethylvanillat, Methylbutanoat, 2-Mmethylbutylacetat, Propylhexanoat, Butylhexanoat, Isopropylbutanoat, Spathulenol, Butanol, δ-Dodecalacton, Methylquinoxalin, Sesquiphellandren, 2-Hexenol, Ethylbenzoate, Isopropylbenzoat, Ethyllactat und/oder Citronellylisobutyrat oder
• (o) Geranium-artigen Geruch, wie vorzugsweise Geraniol, (E,Z)-2,4-Nonadienal, Octadienon und/oder o-Xylen oder
• (p) weintraubenartigem Geruch wie vorzugsweise Ethyldecanoat und/oder Hexanon oder
• (q) grapefruitartigem Geruch wie vorzugsweise (+)-5,6-Dimethyl-8-isopropenylbicyclo[4.4.0]dec-1-en-3-on und/oder p-Menthenethiol oder
• (r) grasartigem Geruch wie vorzugsweise 2-Ethylpyridin, 2,6-Dimethylnaphthalen, Hexanal und/oder (Z)-3-Hexenol oder
• (s) grüner Note, vorzugsweise 2-Ethylhexanol, 6-Decenal, Dimethylheptenal, Hexanol, Heptanol, Methyl-2-butenal, Hexyloctanoate, Nonansäure, Undecanon, Methylgeranat, Isobornylformiate, Gutanal, Octanal, Nonanal, Epoxy-2-decenal, cis-Linalool, Pyranoxid, Nonanol, alpha, γ-dimethylallylalcohol, (Z)-2-pesten-1-ol, (Z)-3-hexenylbutanoat, Isobutylthiazol, (E)-2-nonenal, 2-dodecenal, (Z)-4-decenal, 2-octenal, 2-hegten-1-al, Bicyclogermacrene, 2-Octenal, α-Thujene, (Z)-β-Farnesene, (–)-γ-Elemene, 2,4-Octadienal, Fucoserraten, Hexenylacetat, Geranylaceton, Valencene, β-Eudesmol, 1-Hexenol, (E)-2-Undecenal, Artemisia keton, Viridiflorol, 2,6-Nonadienal, Trimethylphenylbutenon, 2,4-Nonadienal, Butylisothiocyanat, 2-Pentanol, Elemol, 2-Hexenal, 3-Hexenal, (+)-(E)-Limonenoxid, cis-Isocitral, Dimethyloctadienal, Bornylformiat, Bornylisovalerat, Isobutyraldehyd, 2,4-Hexadienal, Trimethylphenylbutenon, Nonanon, (E)-2-Hexenal, (+)-cis-Rosenoxide, Menthone, Coumarin, (Epoxymethylbutyl)-methylfuran, 2-Hexenol, (E)-2-hexenol und/oder Carvylacetat oder
• (t) Grüner Tee-artigem Geruch, vorzugsweise (–)-Cubenol oder
• (u) kräuterartigem Geruch, vorzugsweise Octanon, Hexyloctanoat, Caryophyllenoxide,. Methylbutenol, Safranal, Benzylbenzoat, Bornylbutyrat, Hexylacetat, β-Bisabolol, Piperitol, β-Selinene, α-Cubebene, p-Menth-1-en-9-ol, 1,5,9,9-Tetramethyl-12-oxabicyclododeca-4,7-dien, T-muurolol, (–)-Cubenol, Levomenol, Ocimene, α-Thujene, p-Menth-1-en-9-yl acetat, Dehydrocarveol, Artemisia alcohol, γ-Muurolene, Hydroxypentanon, (Z)-Ocimene, β-Elemene, δ-Cadinol, (E)-β-Ocimene, (Z)-Dihydrocarvone, α-Cadinol, Calamenen, (Z)-Piperitol. Lavandulol, β-Bourbonene, (Z)-3-Hexenyl-2-methylbutanoat, 4-(1-Methylethyl)benzenemethanol, Artemisia keton, Methyl-2-butenol, Heptanol, (E)-Dihydrocarvon, p-2-Menthen-1-ol, α-Curcumene, Spathulenol, Sesquiphellandren, Citronellylvalerat, Bornylisovalerat, 1,5-Octadien-3-ol, Methylbenzoat, 2,3,4,5-Tetrahydroanisol und/oder Hydroxycalamenen oder
• (v) honigartigem Geruch, vorzugsweise Ethylcinnamate, β-Phenethylacetat, Phenylessigsäure, Phenylethanal, Methylanthranilat, Zimtsäure, β-Damascenone, Ethyl-(E)-cinnamat, 2-Phenylethylalcohol, Citronellylvalerate, Phenylethylbenzoate und/oder Eugenol oder
• (w) Hyazinthen-artigem Geruch, vorzugsweise Hotrienol oder
• (x) jasminartigem Geruch, vorzugsweise Methyljasmonate, Methyldihydroepijasmonat und/oder Methylepijasmonat oder
• (y) lavendelartigem Geruch, vorzugsweise Linalylvalerate und/oder Linalool oder
• (z) zitronenartigem Geruch, vorzugsweise Neral, Octanal, δ-3-Carene, Limonen, Geranial, 4-mercapto-4-methyl-2-pentanol, Citral, 2,3-Dehydro-1,8-cineol und/oder α-Terpinen oder
• (aa) lilienartigem Geruch, vorzugsweise Dodecanal oder
• (bb) magnolienartigem Geruch, vorzugsweise Geranylaceton oder
• (cc) mandarinenartigem Geruch, vorzugsweise Undecanol oder
• (dd) melonenartigem Geruch, vorzugsweise Dimethylheptenal oder
• (ee) Minze-artigem Geruch, vorzugsweise Menthone, Ethylsalicylat, p-Anisaldehyd, 2,4,5,7a-tetrahydro-3,6-dimethyl-benzofuran, Epoxy-p-menthene, Geranial, (Methylbutenyl)methylfuran, Dihydrocarvylacetat, β-Cyclocitral, 1,8-Cineol, β-Phellandrene, Methylpentanon, (+)-Limonen, Dihydrocarveol (–)-Carvon, (E)-p-Mentha-2,8-dien-1-ol, Isopulegylacetat, Piperiton, 2,3-Dehydro-1,8-cineol, α-Terpineol, DL-carvon und/oder α-Phellandrene oder
• (ff) nußartigem Geruch, vorzugsweise 5-methyl-(E)-2-hepten-4-on, γ-Heptalacton, 2-Acetylpyrrol, 3-Octen-2-on, Dihydromethylcyclopentapyrazin, Acetylthiazol, 2-Octenal, 2,4-Heptadienal, 3-Octenon, Hydroxypentanon, Octanol, Dimethylpyrazin, Methylquinoxalin und/oder Acetylpyrrolin oder
• (gg) orangenartigem Geruch, vorzugsweise Methyloctanoat, Undecanon, Decylalcohol, Limonen und/oder 2-Decenal oder
• (hh) Orangenschalen-artigem Geruch, vorzugsweise Decanal und/oder β-Carene oder
• (ii) pfirsichartigem Geruch, vorzugsweise γ-Nonalacton, (Z)-6-Dodecene-γ-lacton, δ-Decalacton, R-δ-Decenolacton, Hexylhexanoat, 5-Octanolid, γ-Decalacton und/oder δ-Undecalacton oder
• (jj) Pfefferminze-artigem Geruch, vorzugsweise Methylsalicylat und/oder I-Menthol oder
• (kk) Kiefer-artigem Geruch, vorzugsweise α-p-Dimethylstyrol, β-Pinene, Bornylbenzoat, δ-Terpinen, Dihydroterpinylacetat und/oder α-Pinen oder
• (ll) ananasartigem Geruch, vorzugsweise Propylbutyrat, Propylpropanoat und/oder Ethylacetat oder
• (mm) pflaumenartigem Geruch, vorzugsweise Benzylbutanoat, oder
• (nn) himbeerartigem Geruch, vorzugsweise β-Ionone oder
• (oo) Rose-artigem Geruch, vorzugsweise β-Phenethylacetat, 2-Ethylhexanol, Geranylvalerat, Geranylacetat, Citronellol, Geraniol, Geranylbutyrat, Geranylisovalerat, Citronellylbutyrat, Citronellylacetat, Isogeraniol, Tetrahydro-4-methyl-2-(2-methyl-1-propenyl)-2,5-cis-2H-pyran, Isogeraniol, 2-Phenylethylalcohol, Citronellylvalerat und/oder Citronellylisobutyrat, oder
• (pp) Grüne Minze-artigem Geruch, vorzugsweise Carvylacetate und/oder Carveol, oder
• (qq) erdbeerenartigem Geruch, vorzugsweise Hexylmethylbutyrat, Methylcinnamat, Pentenal, Methylcinnamate oder
• (rr) süßlichem Geruch, vorzugsweise Benzylalcohol, Ethylphenylacetat, Tridecanal, Nerol, Methylhexanoat, Linalylisovalerat, Undecanaldehyd, Caryophyllenoxid, Linalylacetat, Safranal, Uncineol, Phenylethanal, p-Anisaldehyd, Eudesmol, Ethylmethylpyrazin, Citronellylbutyrat, 4-Methyl-3-penten-2-on, Nonylacetat, 10-Epi-γ-eudesmol, β-Bisabolol, (Z)-6-Dodecen-γ-lacton, β-Farnesene, 2-Dodecenal, γ-Dodecalacton, Epoxy-β-ionon, 2-Undecenal, Styrenglycol, Methylfuraneol, (–)-cis-Rosenoxid, (E)-β-Ocimene, Dimethylmethoxyfuranon, 1,8-Cineole, Ethylbenzaldehyd, 2-Pentylthiophen, α-Farnesene, Methionol, 7-Methoxycoumarin, (Z)-3-Hexenyl-2-methylbutanoat, o-Aminoacetophenon, Viridiflorol, Isopiperitone, β-Sinensal, Ethylvanillat, Methylbutanoat, p-Methoxystyrol, 6-Methoxyeugenol, 4-Hexanolid, δ-Dodecalacton, Sesquiphellandren, Diethylmalat, Linalylbutyrat, Guaiacol, Coumarin, Methylbenzoat, Isopropylbenzoat, Safrole, Durene, γ-Butyrolacton, Ethylisobutyrat und/oder Furfural oder
• (ss) Vanille-artigem Geruch, vorzugsweise Vanillin, Methylvanillat, Acetovanillon und/oder Ethylvanillat oder
• (tt) wassermelonenartigem Geruch, vorzugsweise 2,4-Nonadienal oder
• (uu) holzartigem Geruch, vorzugsweise α-Muurolene, Cadina-1,4-dien-3-ol, Isocaryophyllene, Eudesmol, α-Ionon, Bornylbutyrat, (E)-α-Bergamoten, Linalooloxid, Ethylpyrazin, 10-epi-γ-Eudesmol, Germacrene B, trans-Sabinenhydrat, Dihydrolinalool, Isodihydrocarveol, β-Farnesene, β-Sesquiphellandren, δ-Elemene, α-Calacorene, Epoxy-β-ionon, Germacrene D, Bicyclogermacrene, Alloaromadendrene, α-Thujene, oxo-β-Ionon, (–)-γ-Elemene. γ-Muurolene, Sabinene, α-Guaiene, α-Copaene, γ-Cadinene, Nerolidol, β-Eudesmol, α-Cadinol, δ-Cadinene, 4,5-Dimethoxy-6-(2-propenyl)-1,3-benzodioxol, [1ar(1aalpha,4aalpha,7alpha,7abeta,7balpha)]-decahydro-1,1,7-trimethyl-4-methylene-1H-cycloprop[e]azulen, α-Gurjunen, Guaiol, α-Farnesene, γ-Selinene, 4-(1-Methylethyl)-benzenemethanol, Perillen, Elemol, α-Humulene, β-Caryophyllene und/oder β-Guaiene oder
• (vv) Mischungen aus vorgenannten.

enthalten.The substrate according to the invention can according to a preferred embodiment, in particular fragrances

• (a) almond-like odor, such as preferably benzaldehyde, pentanal, heptenal, 5-methylfurfural, methylbutanal, furfural and / or acetophenone or
• (b) apple-like odor, such as preferably (S) - (+) - ethyl 2-methylbutanoate, diethyl malonate, ethyl butyrate, geranyl butyrate, geranyl isopentanoate, isobutyl acetate, linalyl isopentanoate, (E) -β-damascone, heptyl-2-me thyl butyrate, methyl 3-methyl butanoate, 2-hexenal pentyl methyl butyrate, ethyl methyl butyrate and / or methyl 2-methyl butanoate or
• (c) apple peel-like odor, such as preferably ethylhexanoate, hexylbutanoate and / or hexylhexanoate or
• (d) apricot-like odor, preferably γ-undecalactone, or
• (e) banana-like odor, such as preferably isobutyl acetate, isoamyl acetate, hexenyl acetate and / or pentyl butanoate or
• (f) bitter almond-like odor such as preferably 4-acetyltoluene or
• (g) blackcurrant-like odor, such as preferably mercaptomethylpentanone and / or methoxymethylbutanethiol or
• (c) citrus-like odor such as preferably linalyl pentanoate, heptanal, linalyl isopentanoate dodecanal, linalyl formate, α-p-dimethylstyrene, p-cymenol, nonanal, β-cubebene, (Z) -liminene oxide, cis-6-ethenyl-tetrahydro-2,2,6- trimethylpyran-3-ol, cis-pyranoidlinalooloxide, dihydrolinalool, 6 (10) -dihydromyrcenol, dihydromyrcenol, β-farnesene, (Z) -β-farnesene, (Z) -cime, (E) -liminene oxide, dihydrotypinyl acetate, (+) -Limonen, (Epoxymethylbutyl) methylfuran and / or p-cymene or
• (i) cocoa like odor, preferably dimethylpyrazine, butylmethyl butyrate and / or methylbutanal or
• (j) coconut-like odor, such as preferably γ-octalactone, γ-nonalactone, methyl laurate, tetradecanol, methyl nonanoate, (3S, 3aS, 7aR) -3a, 4,5,7a-tetrahydro-3,6-dimethylbenzofuran-2 (3H) -on, 5-butyldihydro-4-methyl-2 (3H) -furanone, ethyl undecanoate and / or δ-decalactone or
• (k) creamy odor such as preferably diethyl acetal, 3-hydroxy-2-butanone, 2,3-pentadione and / or 4-heptenal, or
• (l) flower-like odor such as preferably benzyl alcohol, phenylacetic acid, tridecanal, p-anisyl alcohol, hexanol, (E, E) -farnesylacetone, methyl geranate, trans-crotonaldehyde, tetradecylaldehyde, methyl anthranilate, linalooloxide, epoxylinalool, phytol, 10-epi-γ-eudesmol , Nerol oxide, ethyldihydrocinnamate, γ-dodecalactone, hexadecanol, 4-mercapto-4-methyl-2-pentanol, (Z) -oximes, cetyl alcohol, nerolidol, ethyl (E) -cinnamate, elemicin, pinocarveol, α-bisabolol, ( 2R, 4R) -Tetrahydro-4-methyl-2- (2-methyl-1-propenyl) -2H-pyran, (E) -Isoelemicin, methyl 2-methylpropanoate, trimethylphenylbutenone, 2-methylanisole, β-farnesol, ( E) isoeugenol, nitro-phenylethane, ethyl vanillate, 6-methoxyeugenol, linalool, β-ionone, trimethylphenylbutenone, ethyl benzoate, phenylethyl benzoate, isoeugenol and / or acetophenones or
• (m) freshness odor, preferably methylhexanoate, undecanone, (Z) -limonoxide, benzylacetate, ethylhydroxyhexanoate, isopropylhexanoate, pentadecanal, β-elemene, α-zingiberene, (E) -liminic oxide, (E) -p-mentha-2, 8-dien-1-ol, menthone, piperone, (E) -3-hexenol and / or carveol or
• (n) Fruit odor, such as ethylphenylacetate, geranylvalerate, γ-heptalactone, ethylpropionate, diethylacetal, geranylbutyrate, ethylheptylate, ethyloctanoate, methylhexanoate, dimethylheptenal, pentanone, ethyl-3-methylbutanoate, geranylisovalerate, lobutylacetate, ethoxypropanol, methyl-2-butenal, Methylnonanedione, linalyl acetate, methyl geranate, ammonium oxide, hdrocinnamic alcohol, ethylsuccinate, ethylhexanoate, ethylmethylpyrazine, ethyl acetate, cetronellyl butyrate, heyl acetate, nonyl acetate, butylmethyl butyrate, pentenal, isopentyldimethylpyrazine, p-month-1-en-9-ol, hexadecanone, octylacetate, γ-dodecalactone, Epoxy β-ionone, ethyloctenoate, ethylisohexanoate, isobornyl propionate, cedrenol, p-menth-1-en-9-yl acetate, cadinadiene, (Z) -3-hexenylhexanoate, ethylcyclohexanoate, 4-methylthio-2-butanone, 3.5 Octadienone, methylcyclohexanecarboxylate, 2-pentylthiophene, α-ocimene, butanediol, ethyl valerate, pentanol, isopiperone, butyl octanoate, ethyl vanillate, methyl butanoate, 2-methylbutyl acetate, propyl hexanoate, butyl hexano at, isopropylbutanoate, spathulenol, butanol, δ-dodecalactone, methylquinoxaline, sesquiphenilene, 2-hexenol, ethyl benzoate, isopropyl benzoate, ethyl lactate and / or citronellyl isobutyrate or
• (o) Geranium-like odor, such as preferably geraniol, (E, Z) -2,4-nonadienal, octadienone and / or o-xylene or
• (p) grape-like odor such as preferably ethyl decanoate and / or hexanone or
• (q) grapefruit-like odor such as preferably (+) - 5,6-dimethyl-8-isopropenylbicyclo [4.4.0] dec-1-en-3-one and / or p-menthenethiol or
• (R) grassy odor such as preferably 2-ethylpyridine, 2,6-dimethylnaphthalene, hexanal and / or (Z) -3-hexenol or
• (s) green note, preferably 2-ethylhexanol, 6-decenal, dimethylheptenal, hexanol, heptanol, methyl-2-butenal, hexyloctanoate, nonanoic acid, undecanone, methyl geranate, isobornylformiate, gutanal, octanal, nonanal, epoxy-2-decenal, cis -Linalool, pyranoxide, nonanol, alpha, γ-dimethylallylalcohol, (Z) -2-pesten-1-ol, (Z) -3-hexenylbutanoate, isobutylthiazole, (E) -2-nonenal, 2-dodecenal, (Z) 4-decenal, 2-octenal, 2-hegten-1-al, bicyclo-mermacrene, 2-octenal, α-thujene, (Z) -β-farnesene, (-) - γ-elemene, 2,4-octadienal, fucoserrate , Hexenylacetate, geranylacetone, valencene, β-eudesmol, 1-hexenol, (E) -2-undecenal, artemisia ketone, viridiflorol, 2,6-nonadienal, trimethylphenylbutenone, 2,4-nonadienal, butylisothiocyanate, 2-pentanol, elemole, 2-hexenal, 3-hexenal, (+) - (E) -liminene oxide, cis-isocitral, dimethyloctadienal, bornyl formate, bornyl isovalerate, isobutyraldehyde, 2,4-hexadienal, trimethylphenylbutenone, nonanone, (E) -2-hexenal, (+) - cis-rose oxides, menthone, coumarin, (epoxymethylbutyl) -methylfuran, 2-hexenol, (E) - 2-hexenol and / or carvyl acetate or
• (t) Green Tea-like odor, preferably (-) - Cubenol or
• (u) herbaceous odor, preferably octanone, hexyloctanoate, caryophyllene oxides ,. Methylbutenol, safranal, benzyl benzoate, bornyl butyrate, hexyl acetate, β-bisabolol, piperitol, β-selenene, α-cubebene, p-menth-1-en-9-ol, 1,5,9,9-tetramethyl-12-oxabicyclododeca- 4,7-diene, T-muurolol, (-) - cubenol, levomenol, ocimene, α-thujene, p-menth-1-en-9-yl acetate, dehydrocarveol, Artemisia alcohol, γ-muurolene, hydroxypentanone, (Z ) -Oximes, β-elemens, δ-cadinol, (E) -β-ocimene, (Z) -dihydrocarvone, α-cadinol, calamine, (Z) -piperitol. Lavandulol, β-bourbonene, (Z) -3-hexenyl-2-methylbutanoate, 4- (1-methylethyl) benzene-demethanol, artemisia ketone, methyl-2-butenol, heptanol, (E) -dihydrocarvone, p-2-menthene 1-ol, α-Curcumene, Spathulenol, Sesquiphellandren, Citronellylvalerat, Bornylisovalerat, 1,5-octadien-3-ol, methyl benzoate, 2,3,4,5-tetrahydroanisole and / or Hydroxycalamenen or
• (v) honey-like odor, preferably ethyl cinnamate, β-phenethyl acetate, phenylacetic acid, phenylethanal, methyl anthranilate, cinnamic acid, β-damascenone, ethyl (E) -cinnamate, 2-phenylethylalcohol, citronellyl valerate, phenylethyl benzoate and / or eugenol or
• (w) Hyacinth-like odor, preferably Hotrienol or
• (x) jasmine-like odor, preferably methyl jasmonate, methyldihydroepijasmonate and / or methylepijasmonate or
• (y) lavender-like odor, preferably linalyl valerate and / or linalool or
• (z) lemon-like odor, preferably, neral, octanal, δ-3-carene, limonene, geranial, 4-mercapto-4-methyl-2-pentanol, citral, 2,3-dehydro-1,8-cineol and / or α -Terpines or
• (aa) lily-like odor, preferably dodecanal or
• (bb) magnolia-like odor, preferably geranylacetone or
• (cc) mandarin-like odor, preferably undecanol or
• (dd) melon-like odor, preferably dimethylheptenal or
• (ee) minty odor, preferably menthone, ethyl salicylate, p-anisaldehyde, 2,4,5,7a-tetrahydro-3,6-dimethylbenzofuran, epoxy-p-menthene, geranial, (methylbutenyl) methylfuran, dihydrocarvyl acetate, β-cyclocitral, 1,8-cineole, β-phellandrene, methylpentanone, (+) - limonene, dihydrocarveol (-) - carvone, (E) -p-mentha-2,8-dien-1-ol, isopulegyl acetate, piperitone , 2,3-dehydro-1,8-cineole, α-terpineol, DL-carvone and / or α-phellandrene or
• (ff) Nutty odor, preferably 5-methyl- (E) -2-hepten-4-one, γ-heptalactone, 2-acetylpyrrole, 3-octen-2-one, dihydromethylcyclopentapyrazine, acetylthiazole, 2-octenal, 2,4 Heptadienal, 3-octenone, hydroxypentanone, octanol, dimethylpyrazine, methylquinoxaline and / or acetylpyrroline or
• (gg) orange-like odor, preferably methyloctanoate, undecanone, decyl alcohol, limonene and / or 2-decenal or
• (hh) orange peel-like odor, preferably decanal and / or beta-carene or
• (ii) peach-like odor, preferably γ-nonalactone, (Z) -6-dodecene-γ-lactone, δ-decalactone, R-δ-decenolactone, hexylhexanoate, 5-octanolide, γ-decalactone and / or δ-undecalactone or
• (jj) peppermint-like odor, preferably methyl salicylate and / or I-menthol or
• (kk) pine-like odor, preferably α-p-dimethylstyrene, β-pinene, bornyl benzoate, δ-terpinene, dihydroterpinyl acetate and / or α-pinene or
• (II) pineapple-like odor, preferably propyl butyrate, propyl propanoate and / or ethyl acetate or
• (mm) plum-like odor, preferably benzyl butanoate, or
• (nn) raspberry-like odor, preferably β-ionone or
• (oo) Rose-like odor, preferably β-phenethyl acetate, 2-ethylhexanol, geranyl valerate, geranyl acetate, citronellol, geraniol, geranyl butyrate, geranyl isovalerate, citronellyl butyrate, citronellyl acetate, isogeraniol, tetrahydro-4-methyl-2- (2-methyl-1) propenyl) -2,5-cis-2H-pyran, isogeraniol, 2-phenylethyl alcohol, citronellyl valerate and / or citronellyl isobutyrate, or
• (pp) spearmint-like odor, preferably carvylacetate and / or carveol, or
• (qq) strawberry-like odor, preferably hexylmethyl butyrate, methyl cinnamate, pentenal, methyl cinnamate or
• (rr) sweet odor, preferably benzyl alcohol, ethyl phenylacetate, tridecanal, nerol, methylhexanoate, linalyl isovalerate, undecanedehyde, caryophyllene oxide, linalyl acetate, safranal, uncinol, phenylethanal, p-anisaldehyde, eudesmol, ethylmethylpyrazine, citronellylbutyrate, 4-methyl-3-pentene-2 -on, nonyl acetate, 10-epi-γ-eudesmol, β-bisabolol, (Z) -6-dodecene-γ-lactone, β-farnesene, 2-dodecenal, γ-dodecalactone, epoxy-β-ionone, 2-undecenal , Styrene glycol, methyl furanol, (-) - cis-rose oxide, (E) -β-octenes, dimethylmethoxyfuranone, 1,8-cineols, ethylbenzaldehyde, 2-pentylthiophene, α-farnesene, methionol, 7-methoxycoumarin, (Z) -3 -Hexenyl 2-methylbutanoate, o-aminoacetophenone, viridiflorol, isopiperitone, β-sinensal, ethyl vanillate, methyl butanoate, p-methoxystyrene, 6-methoxyeugenol, 4-hexanolide, δ-dodecalactone, sesquiphel landren, diethyl malate, linalyl butyrate, guaiacol, coumarin, methyl benzoate, isopropyl benzoate, safroles, durene, γ-butyrolactone, ethyl isobutyrate and / or furfural or
• (ss) vanilla-like odor, preferably vanillin, methyl vanillate, acetovanillon and / or ethyl vanillate or
• (tt) watermelon-like odor, preferably 2,4-nonadienal or
• (uu) woody odor, preferably α-muurolene, cadina-1,4-dien-3-ol, isocaryophyllene, eudesmol, α-ionone, bornyl butyrate, (E) -α-bergamotene, linalooloxide, ethylpyrazine, 10-epi-γ Eudesmol, germacrene B, trans-sabin hydrate, dihydrolinalool, isodihydrocarveol, β-farnesenes, β-sesquiphellandrene, δ-elemene, α-calacorene, epoxy-β-ionone, germacrene D, bicyclo mermose, alloaromadendrene, α-thujene, oxo-β Ionone, (-) - γ-elemene. γ-Muurolene, Sabinene, α-Guaiene, α-Copaene, γ-Cadinene, Nerolidol, β-Eudesmol, α-Cadinol, δ-Cadinene, 4,5-Dimethoxy-6- (2-propenyl) -1,3- benzodioxole, [1ar (1aalpha, 4aalpha, 7alpha, 7abeta, 7balpha)] - decahydro-1,1,7-trimethyl-4-methylene-1H-cycloprop [e] azulen, α-gurjunen, guaiol, α-farnesene, γ -Selenene, 4- (1-methylethyl) -benzenemethanol, Perillen, Elemol, α-Humulenes, β-Caryophyllene and / or β-Guaiene or
• (vv) mixtures of the above.

contain.

In a preferred embodiment contains the substrate according to the invention certain minimum values of perfume oil (fragrances), namely at least 0.00001% by weight, advantageously at least 0.0001% by weight, in considerable advantageously at least 0.001 wt .-%, in a more advantageous manner at least 0.01% by weight, more preferably at least 0.1 Wt .-%, more preferably at least 0.2 wt .-%, in a very advantageous manner at least 0.3 wt .-%, in particularly advantageous Way at least 0.4 wt .-%, in a particularly advantageous manner at least 0.45 wt .-%, in a significantly advantageous manner at least 0.5 wt .-%, in a very advantageous manner, at least 0.55 Wt .-%, in an extremely advantageous manner at least 0.6 wt .-%, in the highest advantageously at least 0.65% by weight, most advantageously at least 0.7% by weight, in an exceptionally advantageous manner at least 0.75% by weight, in exceptionally advantageous Way at least 0.8 wt .-%, in extremely advantageous Way at least 0.85 wt .-%, in particular at least 0.9 wt .-% of Perfume oil,% by weight based on the total composition with which the substrate impregnated / applied / impregnated / coated is.

In a preferred embodiment the perfume oils contain less as 8, advantageously less than 7, in a more advantageous manner less than 6, more preferably less than 5, more advantageously less than 4, more advantageously less as 3, preferably less than 2, in particular no perfumes from the list amylcinnamal, amylcinnamyl alcohol, benzyl alcohol, Benzyl salicylate, cinnamyl alcohol, cinnamal, citral, coumarin, eugenol, Geraniol, hydroxycitronellal, hydroxymethylpentylcyclohexenecarboxaldehyde, Isoeugenol, anisyl alcohol, benzyl benzoate, benzyl cinnamate, citronellol, Farnesol, hexylcinnamaldehyde, lilial, d-limonene, linalool, methylheptin carbonate, 3-methyl-4- (2,6,6-trimethyl-2-cyclohexen-1-yl) -3-buten-2-one, oak moss extract, Tree moss extract.

To a further preferred embodiment can the substrate according to the invention free of perfume oil (fragrances) be.

Claims (34)

Textile substrate with cleaning power, comprising a composition with which the substrate is applied, impregnated, coated and / or impregnated is, this composition (a) humectants (B) photocatalytic material (c) containing surfactant. Substrate according to claim 1, characterized in that that it is a textile fabric is. Substrate according to Claim 1 or 2, characterized that the textile substrate is a natural and / or synthetic comprises textile material, selected from ingredients including wool, cotton, silk, jute, hemp, Linen, sisal, ramie, rayon, cellulose esters, polyvinyl derivatives, Polyolefins, polyamides, polyester, felt, paper, hydrophilic polyurethane foam, Nonwovens, preferably based on viscose or cellulose acetate, Nonwovens, preferably based on polylactides, -glycoliden and their copolyesters and polyvinyl alcohol (derivat) s and any Mixtures thereof. Substrate according to one of Claims 1 to 3, characterized that titanium dioxide is contained as the photocatalytic material, in particular a modified titanium dioxide, preferably one with Carbon modified titanium dioxide. Substrate according to one of Claims 1 to 4, characterized that the, preferably modified, titanium dioxide in amounts of 0.0001 to 30% by weight, preferably 0.01 to 15% by weight, wt.% based on the total composition with which the substrate impregnated charged, soaked and / or coated. Substrate according to one of Claims 1-5, characterized that the carbon content of the carbon-modified titanium dioxide in the range of from 0.01 to 10% by weight, preferably from 0.05 to 5.0% by weight, advantageously from 0.3 to 1.5% by weight, in particular from 0.4 to 0.8% by weight, wt .-% based on the carbon-modified Titanium dioxide. Substrate according to one of claims 1-6, characterized in that the specific surface area of the, preferably modified, titanium dioxide by BET is preferably 50 to 500 m ² / g, advantageously 100 to 400 m ² / g, in particular 200 to 350 m ² / g is. Substrate according to one of claims 1-7, characterized that the particle size of, preferably modified, titanium dioxide in the range of 2-600 nm lies. Substrate according to one of claims 1-8, characterized glycerol, dimers and trimers of glycerine, as humectants, Ethylene glycol, propylene glycol, sugar alcohols, as preferably Glucitol, xylitol, mannitol, alkylpolyglucosides, fatty acid glucamides, Sucrose esters, sorbitans, polysorbates, polydextrose, polyethylene glycol, preferably with average molecular weights of 200 to 8000, Propanediols, butanediols, triethylene glycol, orthophosphoric acid, citric acid, urea, Alums, hydrates of aluminum salts, hydrogenated glucose syrup and / or Mixtures of the above are included, preferably in amounts from 0.01 to 50 wt .-%, advantageously 0.05 to 40 wt .-%, in more advantageously 0.1-30 Wt .-%, more preferably 0.15-20 wt .-%, in even more advantageous Way 0.2-10 Wt .-%, in particular 0.25-5 wt .-%, % By weight based on the total composition with which the substrate impregnated charged, soaked and / or coated. Substrate according to one of Claims 1-9, characterized that a nonionic surfactant is contained, preferably from the group of alkoxylated alcohols, the alkylphenol polyglycol ethers, the alkoxylated fatty acid alkyl esters, the polyhydroxy fatty acid amides, the alkyl glycosides, the alkyl polyglucosides, the amine oxides, the fatty acid glucamides, and / or the long-chain alkyl sulfoxides, preferably in amounts from 0.01 to 30 wt .-%, advantageously 0.1 to 20 wt .-%, in further advantageously 0.5-15 Wt .-%, more preferably 1-10 wt .-%, in even more advantageous Way 1.5-5 Wt .-%, in particular 2-4 Wt .-%, wt .-% based on the total composition, with which the substrate is impregnated, charged, soaked and / or is coated. Substrate according to one of Claims 1-10, characterized that it contains anionic surfactant, preferably selected from alkanesulfonates, alkylbenzenesulfonates, fatty alcohol polyglycol ether sulfates, Fatty alcohol sulfates, alkyl sulfates, monoglyceride sulfates, ester sulfonates, Lignosulfonates, fatty acid cyanamides, N-alkyl glutamates, anionic sulfosuccinic acid surfactants, fatty acid isethionates, Acylaminol kansulfonates, fatty acid sarcosinates (N-alkyl sarcosinates), ether carboxylic acids and alkyl (ether) phosphates preferably in amounts of 0.01 to 30 wt .-%, advantageously 0.1 to 20% by weight, more preferably 0.5-15% by weight, more advantageously 1-10 Wt .-%, more preferably 1.5-5 wt .-%, in particular 2-4 wt .-%, Wt .-% in each case based on the total composition, with which the substrate is impregnated, charged, soaked and / or coated. Substrate according to one of Claims 1-11, characterized that an emollient, preferably oils, cationic surfactants, in particular Esterquats, phyllosilicates, fatty acid derivatives, silicone oils, polymers, such as preferably silicone based cationic surfactants or polymers based on polyethylene, is contained, preferably in one Amount of 0.05 to 20 wt .-%, preferably 0.1-10 wt .-% by weight based on the entire composition with which the substrate impregnates, charged, soaked and / or coated. Substrate according to one of the preceding claims, characterized in that it contains a) photocatalytic material, b) humectants c) nonionic surfactant and / or anionic surfactant d) optionally cationic surfactant, preferably benzalkonium chloride or didecylmethylpoly (oxyethyl) ammonium propionate, preferably 0 to 5% by weight e) optionally builders, preferably trisodium citrate, sodium nitrilotriacetic acid, sodium phosphonate, pentasodium triphosphate, advantageously in one Amount of from 0% to 5% by weight, more preferably from 0.1% to 2% by weight; f) optionally perfume (s), preferably in an amount of 0% by weight to 5% by weight, more preferably from 0.1% by weight to 2% by weight; g) optionally further surfactant, preferably in an amount of 0% by weight to 20% by weight, in particular 0.1% by weight to 10% by weight; h) optionally an antimicrobial agent, e.g. B. Alkyldimethylbenzylammoniumsaccharinat, preferably in an amount of 0 wt.% To 3 wt.%, In particular from 0.01 wt.% To 1 wt.%; i) optionally a corrosion inhibitor, for. Sodium nitrite, sodium benzoate, monoethanolamine, triethanolamine or ammonium hydroxide, preferably in an amount of 0% by weight to 20% by weight, in particular 0.01% by weight to 10% by weight. J) solvents and hydrotropes, preferably ethanol, propylene glycol ethers, Sodium toluene or cumene sulfonate, preferably in an amount of 0 wt.% To 20 wt.%, Advantageously 0.01 wt.% To 10 wt.%, In particular 0.1 to 5 wt .-%, k) water, preferably in amounts of ≥0% by weight, in particular in amounts of> 10% by weight,> 20% by weight,> 30% by weight,> 40% by weight,> 50% by weight,> 60% % By weight,> 70% by weight,> 10% by weight or even> 90% by weight, l) optionally pH adjusting agent, preferably selected from the group of acids, in particular acetic acid, citric acid, maleic acid, Formic acid, amidosulfonic acid, phosphoric acid, phosphonic acids, D-lactic acid, L-lactic acid, D / L-lactic acid, oxalic acid or from the group of alkalis, in particular sodium hydroxide solution, advantageously in amounts of 0-30 wt .-%, preferably preferably 0.01-5% by weight, in particular 0.1-3% by weight, m) optionally thickener, in particular selected from the group hydroxyethylcellulose, xanthan, acrylic copolymers, in particular in the range of 0.03-2% by weight. % n) optional biological Noxenminderer, such as. As neem oil, tea tree oil, farnesol, tannin (acid), essential oils, terpenes, in particular citral, limonene, beta-ionone, linalool, geraniol, eugenol, myrcene or carvone, z. In amounts> 0.01% by weight, o) optionally scavenging agent, preferably oils, cationic surfactants, in particular esterquats, layered silicates, fatty acid derivatives, silicone oils, polymers, such as preferably silicone based cationic surfactants or polyethylene-based polymers , in particular in the range of 0.05 wt .-% to 10 wt .-% m) optionally skin care active ingredients, in particular in the range of 0.01 wt .-% to 10 wt .-%, wt .-% in each case based on the total composition with which the substrate is impregnated, applied, impregnated and / or coated. Substrate according to one of Claims 1-13, characterized that the contained composition has a pH in the range of 4-9, preferably 5-8 and especially 5.5-7.5 having. Substrate according to one of Claims 1-14, characterized that the substrate comprises two or more distinguishable layers, wherein each layer preferably has a different texture, scuffing ability and / or has a different moisture absorption, and in particular only one of the layers applied with photocatalytic material is. Substrate according to one of Claims 1-15, characterized the substrate comprises microfibers, in particular microfibers with a titer in the range of 0.1 to 1 dtex, preferably 0.3 to 1 dtex. Substrate according to one of Claims 1-16, characterized that the weight ratio loading composition and substrate in the range of 25: 1-1: 25, preferably 15: 1-1: 15, advantageously 10: 1-1: 10, even more advantageous 5: 1-1: 5, especially 2: 1-1: 2 lies. Product, comprise a container containing 1 to 100, preferably 5-50 Substrates according to one of the claims 1-17, the container preferably impermeable for moisture is and is preferably resealable. A method of cleaning, treating, and / or antimicrobial hard surface finishing, comprising: contacting a hard surface with an article according to any one of claims 1 to 17, at and / or followed by exposing the hard surface to light having a wavelength in the range of 300 -1200 nm. Process according to claim 19 for the treatment of mold stains and / or foxing on hard surfaces, especially indoors in wet rooms and / or outside. Method according to one of the preceding claims 19 or 20 for the elimination, deactivation, inhibition or reduction of Microbes, microflora, microbial growth and / or (indoor) pollutants with allergenic potential on hard surfaces, especially indoors in wet rooms and / or outside. Method for removing dust from a surface, wherein the method includes the step of contacting the surface with a substrate according to any one of claims 1 to 17, wherein the dust in particular small particles of any shape, texture and density, the particle diameter of these particles preferably being on average is smaller than 0.3 mm, advantageously 10-200 .mu.m, in particular 30-200 .mu.m, at and / or followed by exposure of the hard surface to light with one wavelength in the range of 300-1200 nm. Method of cleaning, care, antimicrobial Equipment, Softening and / or conditioning of textile substrates, comprising: To contact of a textile article with a substrate according to one of claims 1 to 17, at and / or followed by exposure of the textile article at light with one wavelength in the range of 300-1200 nm. Method according to claim 23, characterized the contacting takes place directly, preferably by direct Wiping or abrading the textile substrate with the substrate according to one of the claims 1 to 17. Method according to claim 23, characterized the contacting takes place indirectly, preferably in the frame mechanical textile treatment, in particular textile washing and / or Drying, wherein a substrate according to one of claims 1 to 17 is given to the textile article to be treated and then the treatment program is started. Method according to claim 25, characterized in that a substrate according to one of claims 1 to 17 for washing in an automatic washing machine is placed and then a Washing program, in particular washing program is started, preferably in an automatic washing machine with Light source. Method according to claim 25, characterized in that a substrate according to one of claims 1 to 17 for washing in an automatic clothes dryer is placed and then a drying program is started, preferably in an automatic clothes dryer with light source. Method according to one of the preceding claims 23-27, to Removal, deactivation, inhibition or reduction of microorganisms, especially bacteria and germs, in textiles. Method for automatic self-cleaning of a Substrate according to one of the claims 1-17, using light having a wavelength in the range of 300-1200 nm. Use of a substrate according to any one of claims 1-17 for Removal or reduction of stains and stains on hard surfaces or textiles that go back on: - Red to blue anthocyanin dyes, such as. B. cyanidin, z. B. from cherries or blueberries, - red Betanidin from the red bed, - orange-red carotenoids like z. As lycopene, beta-carotene, z. From tomatoes or carrots, - yellow Curcuma dyes, such as. B. curcumin, z. From curry and mustard, - brown Tannins, e.g. B. from tea, fruit, red wine - deep brown humic acid, z. B. from coffee, tea, cocoa, - green chlorophyll, z. B, out green grasses, - technical Dyes made from cosmetics, inks, colored pencils - colored Spots caused by metabolites and / or excretory products Molds or other Mirkoflora or microbial growth or microbes, using light with a wavelength in the range from 300-1200 nm. Use of a substrate according to any one of claims 1-17 for Denaturation or growth inhibition of molds, mold spores and lichens or other micro flora or other microbial growth or microbes (indoor) pollutants with allergenic potential on hard surfaces or textiles using light of a wavelength in the range from 300-1200 nm. Use of a substrate according to any one of claims 1-17 for Prophylaxis treatment of hard surfaces or textiles in shape an anticipatory defense and inhibition of stains and stains using light having a wavelength in the range of 300-1200 nm. Use of a substrate according to any one of claims 1-17 as Sanitary cleaning cloth, Window and / or glass cloth, cleaning cloth, Duster, floor cloth, conditioning substrate for use in automatic textile washing and / or drying. Use of light, in particular with a wavelength in the range from 300-1200 nm, for automatic self-cleaning of a substrate after a the claims 1-17.