DE102004034039A1 - Extrusion method for processing raw material in extruder to extrudate comprises filling the material; homogenizing; exhausting; transporting; mixing, milling; transporting material to ejection zone; condensing; and transporting extrudate - Google Patents
Extrusion method for processing raw material in extruder to extrudate comprises filling the material; homogenizing; exhausting; transporting; mixing, milling; transporting material to ejection zone; condensing; and transporting extrudate Download PDFInfo
- Publication number
- DE102004034039A1 DE102004034039A1 DE102004034039A DE102004034039A DE102004034039A1 DE 102004034039 A1 DE102004034039 A1 DE 102004034039A1 DE 102004034039 A DE102004034039 A DE 102004034039A DE 102004034039 A DE102004034039 A DE 102004034039A DE 102004034039 A1 DE102004034039 A1 DE 102004034039A1
- Authority
- DE
- Germany
- Prior art keywords
- extruder
- raw material
- transporting
- extrudate
- roller
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 56
- 239000002994 raw material Substances 0.000 title claims abstract description 34
- 238000001125 extrusion Methods 0.000 title claims abstract description 26
- 238000002156 mixing Methods 0.000 title claims abstract description 11
- 238000012545 processing Methods 0.000 title claims abstract description 11
- 238000011049 filling Methods 0.000 title claims abstract description 9
- 238000003801 milling Methods 0.000 title abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000004033 plastic Substances 0.000 claims abstract description 24
- 229920003023 plastic Polymers 0.000 claims abstract description 24
- 238000010438 heat treatment Methods 0.000 claims abstract description 20
- 238000001816 cooling Methods 0.000 claims abstract description 9
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000007906 compression Methods 0.000 claims abstract description 4
- 230000006835 compression Effects 0.000 claims abstract description 4
- 239000001913 cellulose Substances 0.000 claims abstract 5
- 229920002678 cellulose Polymers 0.000 claims abstract 5
- 238000000034 method Methods 0.000 claims description 36
- 239000000835 fiber Substances 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 5
- 230000005540 biological transmission Effects 0.000 claims description 4
- 239000002023 wood Substances 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 3
- 235000013339 cereals Nutrition 0.000 claims description 2
- 238000002485 combustion reaction Methods 0.000 claims description 2
- 235000013312 flour Nutrition 0.000 claims description 2
- 229920001169 thermoplastic Polymers 0.000 claims description 2
- 239000004416 thermosoftening plastic Substances 0.000 claims description 2
- -1 polypropylene Polymers 0.000 claims 2
- 244000198134 Agave sisalana Species 0.000 claims 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims 1
- 235000017491 Bambusa tulda Nutrition 0.000 claims 1
- 244000025254 Cannabis sativa Species 0.000 claims 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 claims 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 claims 1
- 244000060011 Cocos nucifera Species 0.000 claims 1
- 235000013162 Cocos nucifera Nutrition 0.000 claims 1
- 240000000491 Corchorus aestuans Species 0.000 claims 1
- 235000011777 Corchorus aestuans Nutrition 0.000 claims 1
- 235000010862 Corchorus capsularis Nutrition 0.000 claims 1
- 241000196324 Embryophyta Species 0.000 claims 1
- 241001521135 Fringilla coelebs Species 0.000 claims 1
- 235000004431 Linum usitatissimum Nutrition 0.000 claims 1
- 240000006240 Linum usitatissimum Species 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 244000082204 Phyllostachys viridis Species 0.000 claims 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- 239000004743 Polypropylene Substances 0.000 claims 1
- 239000011425 bamboo Substances 0.000 claims 1
- 235000009120 camo Nutrition 0.000 claims 1
- 235000005607 chanvre indien Nutrition 0.000 claims 1
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- 235000009566 rice Nutrition 0.000 claims 1
- 239000010902 straw Substances 0.000 claims 1
- 238000000265 homogenisation Methods 0.000 abstract description 5
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 15
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 238000011161 development Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 241000237858 Gastropoda Species 0.000 description 2
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- 239000008187 granular material Substances 0.000 description 2
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- 238000003825 pressing Methods 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- 241000283153 Cetacea Species 0.000 description 1
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- 150000001875 compounds Chemical class 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 238000009415 formwork Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
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- 239000011159 matrix material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
Classifications
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- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
Description
Die Erfindung betrifft ein Extrusionsverfahren zum Bearbeiten von Rohmaterial, bestehend aus Kunststoffmaterial und zellulosehaltigem Material, in einem Extruder in Form eines Planetwalzenextruders, zu einem Extrudat, sowie einen Extruder mit dem auch ein solches Verfahren durchführbar ist.The Invention relates to an extrusion process for processing raw material, consisting of plastic material and cellulosic material, in an extruder in the form of a planetary roller extruder, to a Extrudate, as well as an extruder with which such a process feasible is.
Die Bearbeitung kann dabei aus einem Mischen, Verschneiden, Entgasen, Entwässern, Kompaktieren und/oder Granulieren bestehen. Es existieren eine Vielzahl von. Vorrichtungen zur Verarbeitung von zellulosehaltigem Material, insbesondere Naturfasern und zur Einmischung desselben in eine Kunststoffmatrix. Allgemein beruhen die Verfahren, die von den Vorrichtungen ausgeführt werden, auf einem Pressvorgang, wobei mittels einer Lochmatrize Pellets u.ä. hergestellt werden können.The Processing can consist of mixing, blending, degassing, Drain, Compaction and / or granulation exist. There are a multitude from. Apparatus for processing cellulosic material, in particular natural fibers and for incorporation thereof into a plastic matrix. Generally, the methods performed by the devices are on a pressing process, whereby by means of a perforated die pellets etc. produced can be.
So
offenbart die
Die
Ebenfalls
bekannt sind Schneckenextruder unterschiedlichster Ausgestaltung,
welche jedoch im wesentlichen Kunststoffe zu Granulat oder Pulver verarbeiten
können.
So zeigt die
Die Verwendung eines derartigen Extruders für eine Rohmaterialmischung aus Kunststoffmaterial und zellulosehaltigem Material ist jedoch nicht bekannt. Eine solche Verwendung wäre auch nicht möglich, da der Wassergehalt des zellulosehaltigen Materials, welcher teilweise z.B. bei Holz zwischen 10 und 80 % liegt, und welcher dadurch eine erheblichen Menge von während des Extrusionsvorgangs erzeugten Wassers bzw. Wasserdampfs mit sich brächte, zu einer minderen Qualität des Extrudats führen würde. So würden das Extrudat einen hohen Anteil von durch Wasser bzw. Wasserdampf erzeugte Blasen zeigen, die das homogene Gefüge und die Stabilität des Extrudats erheblich einschränken würden.The Use of such an extruder for a raw material mixture of plastic material and cellulosic material, however not known. Such a use would not be possible because the water content of the cellulosic material, which partially e.g. with wood between 10 and 80% lies, and which thereby a considerable amount of during the water or water vapor produced by the extrusion process would entail a lesser quality of the extrudate would. So would the extrudate a high proportion of water or water vapor produced bubbles show the homogeneous structure and the stability of the extrudate considerably restrict would.
Im Übrigen ist die Extrusion von Naturfasern mit einem Wassergehalt von 10 bis 80% bei allen bekannten Verfahren zumindest im oberen genannten Prozentbereich problematisch und kann derzeit nur unter Zugabe von Additiven, welche die Feuchtigkeit binden oder überhaupt nicht funktionieren.Incidentally, is the extrusion of natural fibers with a water content of 10 to 80% in all known processes, at least in the above-mentioned percentage range problematic and can currently only with the addition of additives, which bind the moisture or at all do not work.
Aufgabe der Erfindung ist es, ein Extrusionsverfahren sowie einen Extruder vorzuschlagen, das bzw. der einen hohen Anteil von Naturfasern mit einem Wassergehalt von 10% bis 80% energie- und umweltschonend, mit hoher Homogenität, unter geringen Produktionkosten und vergleichsweiser Blasenfreiheit extrudieren kann.task The invention is an extrusion process and an extruder to propose that a high proportion of natural fibers with a water content of 10% to 80% energy and environmental friendly, with high homogeneity, under low production costs and comparatively bladder-free can extrude.
Die erfindungsgemäße Aufgabe wird verfahrenstechnisch dadurch gelöst, dass folgende Verfahrensschritte während des Umlaufbetriebs einer Hauptschnecke des Planetwalzenextruders, unter ständigem, geregeltem Zugeben oder Entzug von thermischer Energie über die gesamte Länge der Hauptschnecke, insbesondere durch die Verbrennung und Einleitung von Gas und/oder die Zugabe von Druckluft, durchlaufen werden:
- a) Einfüllen des Kunststoffmaterials und des zellulosehaltigem Rohmaterials, in eine Einfüllzone des Planetwalzenextruders,
- b) Homogenisieren durch Mischen und Verdichten des Rohmaterials durch die Hauptschnecke,
- c) Abführen des durch Erhitzen und/oder Verdichten des Rohmaterials angefallenen Gases, Wasserdampfs und/oder Wassers,
- d) Transportieren des Rohmaterials in eine Homogenisierungszone des Planetwalzenextruders durch die Hauptschnecke,
- e) Mischen und Zerkleinern des Rohmaterials durch die Hauptschnecke und umlaufende Planetenzahnradwalzen,
- f) Transportieren des Rohmaterials in eine Ausstoßzone des Planetwalzenextruders durch die Hauptschnecke,
- g) Abführen des durch Erhitzen und/oder Verdichten des Rohmaterials angefallenen Gases und/oder Wasserdampfs und Wassers,
- h) Verdichten des Materials durch einen Verdichtungsschneckenabschnitt der Hauptschnecke und
- i) Transport des Extrudats aus dem Planetwalzenextruder durch die Hauptschnecke.
- a) filling the plastic material and the cellulosic raw material into a filling zone of the planetary roller extruder,
- b) homogenizing by mixing and compacting the raw material through the main screw,
- c) discharging the gas, water vapor and / or water incurred by heating and / or compressing the raw material,
- d) transporting the raw material into a homogenization zone of the planetary roller extruder through the main screw,
- e) Mixing and comminuting the raw material through the main screw and rotating planetary gear rollers,
- f) transporting the raw material into an ejection zone of the planetary roller extruder through the main screw,
- g) removing the gas and / or water vapor and water produced by heating and / or compressing the raw material,
- h) compacting the material through a compression screw section of the main screw and
- i) Transport of the extrudate from the planetary roller extruder through the main screw.
Zudem löst die erfindungsgemäße Aufgabe ein Extruder zum Bearbeiten von aus Kunststoffmaterial und zellulosehaltigem Material bestehendem Rohmaterial, zusammengesetzt aus Kunststoffmaterial und zellulosehaltigem Material, aufweisend einen Motor, ein Getriebe, einen Antrieb, drei axial hintereinander angeordnete Extruderwellen in jeweils einem Extruderzylinder, ein Heizsystem und ein Luftkühlsystem, dadurch gekennzeichnet, dass die erste und zweite Extruderwelle in Form einer Schneckenwelle kraft- und formschlüssig mit der dazwischengelagerten dritten Extruderwelle oder Stirnwalze in Form einer Zahnradwalze verbunden sind, um welche sich eine geraden Anzahl von gleich langen, parallel zu einer axialen Drehachse der Zahnradwalze angeordneten Planetenzahnradwalzen befindet.In addition, the object of the invention solves an extruder for processing of plastic material and cellulosic material existing raw material, composed of Kunststoffmate Rial and cellulosic material, comprising a motor, a gear, a drive, three axially successively arranged extruder shafts in each case an extruder barrel, a heating system and an air cooling system, characterized in that the first and second extruder shaft in the form of a worm shaft and positive fit with the intermediate third extruder shaft or front roller in the form of a gear roller are connected, around which there is an even number of equal length, arranged parallel to an axial axis of rotation of the gear roller planetary gear rollers.
Das Verfahren erlaubt, im Gegensatz zu allen bekannten Verfahren, die Verarbeitung von zellulosehaltigem Material mit einem Wassergehalt von bis zu 80% und ist damit auch für die Verwendung von frischem, sog. grünem Holz geeignet. Insbesondere kann gänzlich auf etwaige Bindemittel für die Aufnahme von Wasser verzichtet werden. Durch die verfahrensgemäße frühzeitige Beheizung des Rohmaterials vor dem eigentlichen Pressvorgang, ist eine erstaunliche Vortrocknung möglich, die zusammen mit den anderen erfindungsgemäßen Verfahrensschritten zu einer Wasserreduktion von bis zu 1% Wassergehalt des Extrudats im Endzustand führt. Die Verwendung einer Gasfeuerung, vorzugsweise mittels Propangas, erlaubt eine schnelle Regelung der Temperatur und ist im Gegensatz zur bei Extruders üblicherweise verwendeten elektrischen Heizung zudem erheblich kostengünstiger und umweltgerechter umzusetzen. Bei einer vergleichsweise geringen Umdrehung der Hauptschnecke von etwa 10 bis 20 Umdrehungen pro Minute kann zudem ein überraschend hoher Ausstoß von Extrudat erreicht werden, der die übliche Ausstoßmenge von etwa 200 kg pro Stunde um ein Vielfaches, d.h. je nach Größe des Extruders um einen Faktor 2 bis 11 übertrifft. Werden zudem als Kunststoffmaterial natürliche Thermoplasten und Modifikatoren verwendet, führt dies zu einer erheblich verbesserten Umweltverträglichkeit sowohl während der Produktion, als auch bei der Verwendung des erzeugten Extrudates. Beim Durchlauf des Rohmaterials durch die erfindungsgemäßen Verfahrensschritte ist noch der durch die Homogenisierungszone erreichte hohe Grad an Homogenisierung des vorgetrockneten Rohmaterials vorteilhaft, der schon vor der eigentlichen Verdichtung unter einem Druck von bis zu 200 bar erreicht wird.The Procedure allows, in contrast to all known methods, the Processing of cellulosic material with a water content up to 80% and is therefore also for the use of fresh, so-called green Wood suitable. In particular, may be based entirely on any binder for receiving be dispensed with water. Due to the procedural early Heating the raw material before the actual pressing process is one amazing pre-drying possible, which together with the other method steps according to the invention a water reduction of up to 1% water content of the extrudate in Final state leads. The Use of a gas firing, preferably by means of propane gas allowed a quick control of the temperature and is unlike at Extruders usually used electric heater also significantly cheaper and environmentally sound implementation. At a comparatively low Rotation of the main screw from about 10 to 20 revolutions per minute It can also be a surprise high output of Extrudate can be achieved, which is the usual discharge rate of about 200 kg per hour by a multiple, i. depending on the size of the extruder exceeds by a factor of 2 to 11. Become also as a plastic material natural thermoplastics and modifiers used, this leads to a much improved environmental impact both during the Production, as well as in the use of the extrudate produced. During the passage of the raw material through the process steps according to the invention is still the high degree reached by the homogenization zone advantageous for homogenization of the pre-dried raw material, even before the actual compression under a pressure of up to 200 bar is reached.
Natürlich erlaubt das Verfahren auch weiterhin Materialzusätze beispielsweise von Langlasfasern, insbesondere von Gummimehl zur Steigerung der Schlagfestigkeit des Extrudats oder von hydrophoben Zuschlagstoffen zur Veränderung von dessen Wasseraufnahmefähigkeit.Of course allowed the process also continues to provide material additives, for example, long-fiber lasers, in particular of powdered rubber to increase the impact resistance of the Extrudates or hydrophobic additives to change of its water absorption capacity.
Auch kann eine verbesserte Verarbeitung auch durch eine Wasserzugabe von bis zu. 5% erreicht werden. Im übrigen ist keinerlei vorherige Vertrocknung eines Compounds bzw. des Rohmaterials, insbesondere der Naturfasern erforderlich. Somit handelt es sich um ein im wesentlichen kontinuierlich ausführbares Direktextrusionsverfahren.Also can be improved processing also by adding water from up to. 5% can be achieved. Otherwise, no previous Drying of a compound or the raw material, in particular the natural fibers required. Thus, it is essentially one continuously executable Direct extrusion process.
Selbstverständlich muss auch eine teilweise Überlappung der erfindungsgemäßen Verfahrensschritte nicht wesentlich von Nachteil und kann sogar erwünscht sein.Of course you have to also a partial overlap the process steps according to the invention not significantly disadvantageous and may even be desirable.
Eine erfindungsgemäße Weiterbildung des Verfahrens ist es, dass das zellulosehaltige Material als Mehl oder in Granulatform, insbesondere mit einem durchschnittlichen Korndurchmesser von bis zu 20mm dem Extrusionsverfahren. zugegeben wird, da hierdurch eine weitere Zerkleinerung durch das Extrusionsverfahren unterbleiben kann, jedoch erbringt das Verfahren auch dann eine gute Qualität, wenn die zellulosehaltigen Materialen unzerkleinert zugeführt werden.A inventive development of the method is that the cellulosic material as flour or in granular form, especially with an average Grain diameter of up to 20mm the extrusion process. added is, as a result of this further comminution by the extrusion process can be omitted, but the process also provides a good quality, when the cellulosic materials are fed undecomposed.
Wird das Kunststoffmaterial vor der Zugabe des zellulosehaltigen Materials dem Verfahren zugeführt, wird eine verbesserter Durchlauf mit geringerer Wandhaftung innerhalb der Extrusionszylinder erreicht, was zu einer geringeren erforderlichen Antriebsenergie führt.Becomes the plastic material prior to the addition of the cellulosic material fed to the process, will be an improved pass with less wall adhesion within the extrusion cylinder reaches, resulting in a lower required Drive energy leads.
Eine Weiterbildung der Erfindung ist es, dass das Rohmaterial einen Anteil von 70 bis 95. Gewichtsprozent zellulosehaltigen Materials und einen Anteil von 30 bis 5 Gewichtsprozent Kunststoffmaterials aufweist, da das zellulosehaltige Material mit derartigem Gewichtsanteil generell zu Extrudaten mit zum Teil hervorragenden Materialeigenschaften wie Recycelbarkeit und Umweltverträglichkeit führt.A Development of the invention is that the raw material a share from 70 to 95% by weight of cellulosic material and a proportion from 30 to 5 weight percent plastic material, since the cellulosic material with such weight fraction generally to extrudates with sometimes excellent material properties how recyclability and environmental friendliness leads.
Der erfindungsgemäße Extruder erfordert nur einen Motor ein Getriebe und einen Antrieb und kann schon aus diesem Grund für die Anwendung äußerst kostengünstig hergestellt und vertrieben werden. Die Stirnwalze mit den umlaufenden Zahnradwalzen mischen und zerkleinern das Rohmaterial in bisher unbekannter Qualität, die in ihrer Homogenität bisher nicht erreicht wurde. Dabei können die Extruderwellen in einer erfindungsgemäßen Weiterbildung sogar einstückig mit der Stirnwalze verbunden werden, ohne irgendwelche verfahrenstechnischen Nachteile hervorzurufen. Zwischen der Extruderzylinderwand, den Planetenzahnrädern und der Stirnwalze wird das Rohmaterial zerrieben, jedoch ist zwischen der Stirnwalze und den Planetenzahnradwalzen immer ein Kraftschluss vorhanden. Im übrigen ist das Planetenwal zensystem einfach zu warten, da die einzelnen Planetenzahnradwalzen entweder axial herausziehbar oder nach Öffnen des entsprechenden Extruderzylinders entnehmbar sind.Of the extruder according to the invention only one engine requires a transmission and a drive and can for that reason alone the application produced extremely cheaply and distributed. The front roller with the rotating gear wheels mix and shred the raw material in previously unknown quality, which in their homogeneity has not been reached yet. In this case, the extruder shafts in a development of the invention even in one piece be connected to the front roller, without any procedural To cause disadvantages. Between the extruder cylinder wall, the Planetary gears and the front roller is the raw material grated, however, is between the front roller and the planetary gears always a traction available. Furthermore The planetary whale system is easy to maintain as the individual Planetenzahnradwalzen either axially withdrawn or after opening the corresponding extruder cylinder can be removed.
Ebenfalls vorteilhaft sind alle in den Unteransprüchen genannten Erfindungsmerkmale.Also advantageous are all mentioned in the dependent claims invention features.
Im folgenden wird anhand eines Ausführungsbeispiels der erfindungsgemäße Extruder beschrieben:in the The following will be based on an embodiment the extruder according to the invention described:
Es
zeigt
Das
Extrudersystem
- 11
- Extrusionssystemextrusion system
- 22
- Extruderextruder
- 3, 4, 53, 4, 5
- Extruderzylinderextruder barrel
- 66
- Hauptschneckemain screw
- 7, 8, 97, 8, 9
- Extruderwelleextruder shaft
- 1010
- SchneckengewindeWorm
- 1111
- Motorengine
- 1212
- Getriebetransmission
- 1313
- Antriebdrive
- 1414
- Materialeinlassmaterial inlet
- 1515
- Materialauslassmaterial outlet
- 16, 17, 1816 17, 18
- Heiz- und Kühleinrichtungheating and cooling device
- 1919
- Versorgungsleitungensupply lines
- 2020
- DruckluftbehälterAir receiver
- 2121
- Gasbehältergas tank
- 2222
- KunststoffmaterialeinlassPlastic material inlet
- 2323
- ZellulosematerialeinlassCellulosic material inlet
- 24, 2524 25
- Gasauslassgas outlet
- 2626
- Wasserauslasswater outlet
- 2727
- StromversorgungseinrichtungPower supply means
- 28, 29, 3028 29, 30
- Anschlussconnection
- 3131
- Steuerungseinrichtungcontrol device
- 3232
- Temperiervorrichtungtempering
Claims (17)
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| DE102004034039A DE102004034039B4 (en) | 2004-07-13 | 2004-07-13 | Extrusion process and extruder for cellulosic material |
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| DE102004034039A DE102004034039B4 (en) | 2004-07-13 | 2004-07-13 | Extrusion process and extruder for cellulosic material |
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| DE102004034039A1 true DE102004034039A1 (en) | 2006-02-09 |
| DE102004034039B4 DE102004034039B4 (en) | 2008-04-17 |
Family
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