DE102004026095A1 - Verfahren zur Herstellung von Isocyanaten - Google Patents
Verfahren zur Herstellung von Isocyanaten Download PDFInfo
- Publication number
- DE102004026095A1 DE102004026095A1 DE102004026095A DE102004026095A DE102004026095A1 DE 102004026095 A1 DE102004026095 A1 DE 102004026095A1 DE 102004026095 A DE102004026095 A DE 102004026095A DE 102004026095 A DE102004026095 A DE 102004026095A DE 102004026095 A1 DE102004026095 A1 DE 102004026095A1
- Authority
- DE
- Germany
- Prior art keywords
- phosgene
- isocyanates
- mass
- hydrogen chloride
- isocyanate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000012948 isocyanate Substances 0.000 title claims abstract description 66
- 150000002513 isocyanates Chemical class 0.000 title claims abstract description 65
- 238000000034 method Methods 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 claims abstract description 106
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 54
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims abstract description 49
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims abstract description 49
- 150000001412 amines Chemical class 0.000 claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims description 34
- 238000006243 chemical reaction Methods 0.000 claims description 29
- 239000000376 reactant Substances 0.000 claims description 13
- 150000003141 primary amines Chemical class 0.000 claims description 6
- 125000003277 amino group Chemical group 0.000 claims description 4
- 238000010924 continuous production Methods 0.000 claims description 4
- 239000005059 1,4-Cyclohexyldiisocyanate Substances 0.000 claims description 3
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 2
- 239000007791 liquid phase Substances 0.000 claims description 2
- 239000007858 starting material Substances 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 description 12
- 239000002904 solvent Substances 0.000 description 11
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 10
- 239000012442 inert solvent Substances 0.000 description 10
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 9
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 6
- CKDWPUIZGOQOOM-UHFFFAOYSA-N Carbamyl chloride Chemical class NC(Cl)=O CKDWPUIZGOQOOM-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 238000004064 recycling Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 3
- 235000013877 carbamide Nutrition 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000010626 work up procedure Methods 0.000 description 3
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical compound N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- JLVWYWVLMFVCDI-UHFFFAOYSA-N diethyl benzene-1,3-dicarboxylate Chemical compound CCOC(=O)C1=CC=CC(C(=O)OCC)=C1 JLVWYWVLMFVCDI-UHFFFAOYSA-N 0.000 description 2
- -1 isocyanate compounds Chemical class 0.000 description 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- DGTNSSLYPYDJGL-UHFFFAOYSA-N phenyl isocyanate Chemical compound O=C=NC1=CC=CC=C1 DGTNSSLYPYDJGL-UHFFFAOYSA-N 0.000 description 2
- 239000005056 polyisocyanate Substances 0.000 description 2
- 229920001228 polyisocyanate Polymers 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- LZPJHIHLDYQHLE-UHFFFAOYSA-N 1,1-diisocyanato-4-methylcyclohexane Chemical compound CC1CCC(N=C=O)(N=C=O)CC1 LZPJHIHLDYQHLE-UHFFFAOYSA-N 0.000 description 1
- WFTKISKQZWBTFC-UHFFFAOYSA-N 1,1-diisocyanatocyclohexane Chemical compound O=C=NC1(N=C=O)CCCCC1 WFTKISKQZWBTFC-UHFFFAOYSA-N 0.000 description 1
- RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- PAUHLEIGHAUFAK-UHFFFAOYSA-N 1-isocyanato-1-[(1-isocyanatocyclohexyl)methyl]cyclohexane Chemical compound C1CCCCC1(N=C=O)CC1(N=C=O)CCCCC1 PAUHLEIGHAUFAK-UHFFFAOYSA-N 0.000 description 1
- VRVUKQWNRPNACD-UHFFFAOYSA-N 1-isocyanatopentane Chemical compound CCCCCN=C=O VRVUKQWNRPNACD-UHFFFAOYSA-N 0.000 description 1
- YJVNFUVXKJBJJB-UHFFFAOYSA-N 3-isocyanatobutylbenzene Chemical compound O=C=NC(C)CCC1=CC=CC=C1 YJVNFUVXKJBJJB-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000004992 fission Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- CZALJDQHONFVFU-UHFFFAOYSA-N isocyanatocyclopentane Chemical compound O=C=NC1CCCC1 CZALJDQHONFVFU-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C265/00—Derivatives of isocyanic acid
- C07C265/12—Derivatives of isocyanic acid having isocyanate groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C263/00—Preparation of derivatives of isocyanic acid
- C07C263/10—Preparation of derivatives of isocyanic acid by reaction of amines with carbonyl halides, e.g. with phosgene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/14—Fractional distillation or use of a fractionation or rectification column
- B01D3/141—Fractional distillation or use of a fractionation or rectification column where at least one distillation column contains at least one dividing wall
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C263/00—Preparation of derivatives of isocyanic acid
- C07C263/18—Separation; Purification; Stabilisation; Use of additives
- C07C263/20—Separation; Purification
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C265/00—Derivatives of isocyanic acid
- C07C265/14—Derivatives of isocyanic acid containing at least two isocyanate groups bound to the same carbon skeleton
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/569,445 US20070232827A1 (en) | 2004-05-25 | 2002-05-21 | Isocyanate Production Method |
| DE102004026095A DE102004026095A1 (de) | 2004-05-25 | 2004-05-25 | Verfahren zur Herstellung von Isocyanaten |
| BRPI0511449-7A BRPI0511449B1 (pt) | 2004-05-25 | 2005-05-21 | Processo contínuo para a preparação de isocianatos |
| ES05752554T ES2753382T3 (es) | 2004-05-25 | 2005-05-21 | Procedimiento para la preparación de isocianatos |
| JP2007513769A JP4833966B2 (ja) | 2004-05-25 | 2005-05-21 | イソシアナートの製造方法 |
| PCT/EP2005/005520 WO2005115974A1 (fr) | 2004-05-25 | 2005-05-21 | Procédé de production d'isocyanates |
| PT57525545T PT1753715T (pt) | 2004-05-25 | 2005-05-21 | Método de produção de isocianato |
| EP05752554.5A EP1753715B1 (fr) | 2004-05-25 | 2005-05-21 | Procede de production d'isocyanates |
| HUE05752554A HUE045895T2 (hu) | 2004-05-25 | 2005-05-21 | Izocianát elõállítási eljárás |
| CNA2005800168641A CN1956948A (zh) | 2004-05-25 | 2005-05-21 | 异氰酸酯的制备方法 |
| KR1020067025595A KR101213954B1 (ko) | 2004-05-25 | 2006-12-05 | 이소시아네이트 제조 방법 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102004026095A DE102004026095A1 (de) | 2004-05-25 | 2004-05-25 | Verfahren zur Herstellung von Isocyanaten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE102004026095A1 true DE102004026095A1 (de) | 2005-12-15 |
Family
ID=34993201
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE102004026095A Withdrawn DE102004026095A1 (de) | 2004-05-25 | 2004-05-25 | Verfahren zur Herstellung von Isocyanaten |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20070232827A1 (fr) |
| EP (1) | EP1753715B1 (fr) |
| JP (1) | JP4833966B2 (fr) |
| KR (1) | KR101213954B1 (fr) |
| CN (1) | CN1956948A (fr) |
| BR (1) | BRPI0511449B1 (fr) |
| DE (1) | DE102004026095A1 (fr) |
| ES (1) | ES2753382T3 (fr) |
| HU (1) | HUE045895T2 (fr) |
| PT (1) | PT1753715T (fr) |
| WO (1) | WO2005115974A1 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016142475A1 (fr) | 2015-03-12 | 2016-09-15 | Basf Se | Procédé de séparation d'un flux de substances contenant du phosgène et de l'acide chlorhydrique |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101255869B1 (ko) * | 2005-04-05 | 2013-04-17 | 미쓰이 가가쿠 가부시키가이샤 | 폴리이소시아네이트 제조 장치 및 가스 처리 장치 |
| DE102005037328A1 (de) | 2005-08-04 | 2007-02-08 | Basf Ag | Verfahren zur Herstellung von Isocyanaten |
| DE102006022448A1 (de) * | 2006-05-13 | 2007-11-15 | Bayer Materialscience Ag | Verfahren zur Herstellung von Isocyanaten |
| WO2008071564A1 (fr) * | 2006-12-11 | 2008-06-19 | Basf Se | Procédé de fabrication d'isocyanates |
| US7813839B2 (en) * | 2006-12-14 | 2010-10-12 | Bayer Materialscience Ag | Process for controlling a production process |
| EP2060560B1 (fr) * | 2007-11-14 | 2016-04-13 | Covestro Deutschland AG | Préparation d'isocyanates de couleur claire |
| PT2828235T (pt) * | 2012-03-19 | 2018-02-07 | Covestro Deutschland Ag | Processo para a produção de isocianatos |
| EP3313815B1 (fr) | 2015-06-29 | 2019-07-31 | Covestro Deutschland AG | Procédé de préparation de chlorure d'hydrogène pour réactions chimiques |
| JP7285924B2 (ja) * | 2018-12-26 | 2023-06-02 | 万華化学集団股▲フン▼有限公司 | 気相でイソシアネートを調製する方法 |
| CN111961185B (zh) * | 2020-08-27 | 2022-07-12 | 万华化学集团股份有限公司 | 一种多亚甲基多苯基多异氰酸酯组合物及其制备方法 |
| CN111995549B (zh) * | 2020-09-03 | 2023-01-13 | 万华化学集团股份有限公司 | 制备mdi的方法和光气制备方法 |
| CN116888071A (zh) * | 2021-02-17 | 2023-10-13 | 巴斯夫欧洲公司 | 分离光气和氯化氢的方法 |
| CN116239502B (zh) * | 2022-12-14 | 2024-06-07 | 上海奕朗化工有限公司 | 通过1,5-戊二胺合成1,5-戊二异氰酸酯的方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3234253A (en) * | 1962-09-06 | 1966-02-08 | Du Pont | Two-stage phosgenation process for preparing aromatic isocyanates |
| BE711392A (fr) * | 1968-02-28 | 1968-07-01 | Gnii Pi Azotnoj | |
| US3631092A (en) * | 1969-02-05 | 1971-12-28 | Basf Wyandotte Corp | Process for the production of 1 3-cyclohexylene diisocyanates |
| DE3403204A1 (de) * | 1984-01-31 | 1985-08-14 | Basf Ag, 6700 Ludwigshafen | Verfahren zur kontinuierlichen herstellung von organischen mono- und/oder polyisocyanaten |
| CN1077099C (zh) * | 1994-11-17 | 2002-01-02 | 拜尔公司 | 制备异氰酸酯的方法 |
| DE19817691A1 (de) * | 1998-04-21 | 1999-10-28 | Basf Ag | Verfahren zur Herstellung von Mischungen aus Diphenylmehandiisocyanaten und Polyphenylen-polymethylen-polyisocyanaten mit vermindertem Gehalt an chlorierten Nebenprodukten und verminderter Jodfarbzahl |
| JP2004035491A (ja) * | 2002-07-04 | 2004-02-05 | Mitsui Takeda Chemicals Inc | 芳香族ポリイソシアネートの製造装置および製造方法 |
| DE10250131A1 (de) * | 2002-10-28 | 2004-05-06 | Basf Ag | Verfahren zur Herstellung von Chlor aus Salzsäure |
| DE10261187A1 (de) * | 2002-12-20 | 2004-07-08 | Basf Ag | Verfahren zur Herstellung von Isocyanaten |
-
2002
- 2002-05-21 US US11/569,445 patent/US20070232827A1/en not_active Abandoned
-
2004
- 2004-05-25 DE DE102004026095A patent/DE102004026095A1/de not_active Withdrawn
-
2005
- 2005-05-21 PT PT57525545T patent/PT1753715T/pt unknown
- 2005-05-21 EP EP05752554.5A patent/EP1753715B1/fr not_active Expired - Lifetime
- 2005-05-21 WO PCT/EP2005/005520 patent/WO2005115974A1/fr not_active Ceased
- 2005-05-21 ES ES05752554T patent/ES2753382T3/es not_active Expired - Lifetime
- 2005-05-21 HU HUE05752554A patent/HUE045895T2/hu unknown
- 2005-05-21 BR BRPI0511449-7A patent/BRPI0511449B1/pt not_active IP Right Cessation
- 2005-05-21 CN CNA2005800168641A patent/CN1956948A/zh active Pending
- 2005-05-21 JP JP2007513769A patent/JP4833966B2/ja not_active Expired - Fee Related
-
2006
- 2006-12-05 KR KR1020067025595A patent/KR101213954B1/ko not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016142475A1 (fr) | 2015-03-12 | 2016-09-15 | Basf Se | Procédé de séparation d'un flux de substances contenant du phosgène et de l'acide chlorhydrique |
| US10252912B2 (en) | 2015-03-12 | 2019-04-09 | Basf Se | Separation of a phosgene- and hydrogen chloride-comprising stream |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1753715A1 (fr) | 2007-02-21 |
| JP4833966B2 (ja) | 2011-12-07 |
| EP1753715B1 (fr) | 2019-08-07 |
| KR20070029188A (ko) | 2007-03-13 |
| HUE045895T2 (hu) | 2020-01-28 |
| KR101213954B1 (ko) | 2012-12-18 |
| US20070232827A1 (en) | 2007-10-04 |
| JP2008500296A (ja) | 2008-01-10 |
| PT1753715T (pt) | 2019-11-04 |
| WO2005115974A1 (fr) | 2005-12-08 |
| BRPI0511449A (pt) | 2007-12-26 |
| ES2753382T3 (es) | 2020-04-08 |
| CN1956948A (zh) | 2007-05-02 |
| BRPI0511449B1 (pt) | 2015-06-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8130 | Withdrawal |