DE10132915A1 - Aqueous emulsion carrier for oxidation hair dye contains fatty alcohols or glycerol esters of saturated fatty acids, surfactants and lanolin or glyceryl monooleate - Google Patents
Aqueous emulsion carrier for oxidation hair dye contains fatty alcohols or glycerol esters of saturated fatty acids, surfactants and lanolin or glyceryl monooleateInfo
- Publication number
- DE10132915A1 DE10132915A1 DE2001132915 DE10132915A DE10132915A1 DE 10132915 A1 DE10132915 A1 DE 10132915A1 DE 2001132915 DE2001132915 DE 2001132915 DE 10132915 A DE10132915 A DE 10132915A DE 10132915 A1 DE10132915 A1 DE 10132915A1
- Authority
- DE
- Germany
- Prior art keywords
- composition according
- dye carrier
- carrier composition
- amino
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 150000002191 fatty alcohols Chemical class 0.000 title claims abstract description 17
- 239000004166 Lanolin Substances 0.000 title claims abstract description 11
- 229940039717 lanolin Drugs 0.000 title claims abstract description 11
- 235000019388 lanolin Nutrition 0.000 title claims abstract description 11
- 230000003647 oxidation Effects 0.000 title claims abstract description 11
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 11
- 150000002314 glycerols Chemical class 0.000 title claims abstract description 9
- 235000003441 saturated fatty acids Nutrition 0.000 title claims abstract description 9
- 150000004671 saturated fatty acids Chemical class 0.000 title claims abstract description 7
- 239000000263 2,3-dihydroxypropyl (Z)-octadec-9-enoate Substances 0.000 title claims abstract description 6
- RZRNAYUHWVFMIP-GDCKJWNLSA-N 3-oleoyl-sn-glycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-GDCKJWNLSA-N 0.000 title claims abstract description 6
- RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 title claims abstract description 6
- 239000004094 surface-active agent Substances 0.000 title claims description 4
- 239000000839 emulsion Substances 0.000 title abstract description 12
- 239000000118 hair dye Substances 0.000 title abstract description 8
- 239000000975 dye Substances 0.000 claims abstract description 57
- 239000000203 mixture Substances 0.000 claims abstract description 33
- 239000007800 oxidant agent Substances 0.000 claims abstract description 14
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 9
- 125000000129 anionic group Chemical group 0.000 claims abstract description 8
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 8
- 239000002243 precursor Substances 0.000 claims abstract description 8
- 230000001590 oxidative effect Effects 0.000 claims abstract description 7
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 5
- -1 glycerol ester Chemical class 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 229930195729 fatty acid Natural products 0.000 claims description 5
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 3
- 229960000541 cetyl alcohol Drugs 0.000 claims description 3
- 238000004043 dyeing Methods 0.000 claims description 3
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 claims description 3
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 2
- 229960003237 betaine Drugs 0.000 claims description 2
- 229920006317 cationic polymer Polymers 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 229930182478 glucoside Natural products 0.000 claims description 2
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 claims description 2
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims 2
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims 1
- 239000006071 cream Substances 0.000 abstract 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 17
- 239000000126 substance Substances 0.000 description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 6
- 239000003531 protein hydrolysate Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 230000003750 conditioning effect Effects 0.000 description 4
- REZOIPSCCRVWNN-UHFFFAOYSA-N tetratriacontan-17-ol Chemical compound CCCCCCCCCCCCCCCCCC(O)CCCCCCCCCCCCCCCC REZOIPSCCRVWNN-UHFFFAOYSA-N 0.000 description 4
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 238000010168 coupling process Methods 0.000 description 3
- 238000005859 coupling reaction Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 2
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 2
- NLMKTBGFQGKQEV-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-hexadecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical group CCCCCCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO NLMKTBGFQGKQEV-UHFFFAOYSA-N 0.000 description 2
- HCPJEHJGFKWRFM-UHFFFAOYSA-N 2-amino-5-methylphenol Chemical compound CC1=CC=C(N)C(O)=C1 HCPJEHJGFKWRFM-UHFFFAOYSA-N 0.000 description 2
- ALQKEYVDQYGZDN-UHFFFAOYSA-N 2-amino-6-methylphenol Chemical compound CC1=CC=CC(N)=C1O ALQKEYVDQYGZDN-UHFFFAOYSA-N 0.000 description 2
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 2
- 229940018563 3-aminophenol Drugs 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- LUSZGTFNYDARNI-UHFFFAOYSA-N Sesamol Chemical compound OC1=CC=C2OCOC2=C1 LUSZGTFNYDARNI-UHFFFAOYSA-N 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- PHYFQTYBJUILEZ-UHFFFAOYSA-N Trioleoylglycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC PHYFQTYBJUILEZ-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 230000003766 combability Effects 0.000 description 2
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 2
- 239000000982 direct dye Substances 0.000 description 2
- OJLOUXPPKZRTHK-UHFFFAOYSA-N dodecan-1-ol;sodium Chemical compound [Na].CCCCCCCCCCCCO OJLOUXPPKZRTHK-UHFFFAOYSA-N 0.000 description 2
- 229940075529 glyceryl stearate Drugs 0.000 description 2
- 229940093915 gynecological organic acid Drugs 0.000 description 2
- 230000037308 hair color Effects 0.000 description 2
- GGNQRNBDZQJCCN-UHFFFAOYSA-N hydroxyhydroquinone Natural products OC1=CC=C(O)C(O)=C1 GGNQRNBDZQJCCN-UHFFFAOYSA-N 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 239000011975 tartaric acid Substances 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 2
- NKNCGBHPGCHYCQ-UHFFFAOYSA-N (2,5-diaminophenyl)methanol Chemical compound NC1=CC=C(N)C(CO)=C1 NKNCGBHPGCHYCQ-UHFFFAOYSA-N 0.000 description 1
- WVOAPRDRMLHUMI-UHFFFAOYSA-N (2-methylnaphthalen-1-yl) acetate Chemical compound C1=CC=C2C(OC(=O)C)=C(C)C=CC2=C1 WVOAPRDRMLHUMI-UHFFFAOYSA-N 0.000 description 1
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- XGNXYCFREOZBOL-UHFFFAOYSA-N 1,3-benzodioxol-5-amine Chemical compound NC1=CC=C2OCOC2=C1 XGNXYCFREOZBOL-UHFFFAOYSA-N 0.000 description 1
- VIXBPSTZNCRCJE-UHFFFAOYSA-N 1,3-bis[4-amino-n-(2-hydroxyethyl)anilino]propan-2-ol Chemical compound C1=CC(N)=CC=C1N(CCO)CC(O)CN(CCO)C1=CC=C(N)C=C1 VIXBPSTZNCRCJE-UHFFFAOYSA-N 0.000 description 1
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 1
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-dioxonaphthalene Natural products C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 description 1
- BOKGTLAJQHTOKE-UHFFFAOYSA-N 1,5-dihydroxynaphthalene Chemical compound C1=CC=C2C(O)=CC=CC2=C1O BOKGTLAJQHTOKE-UHFFFAOYSA-N 0.000 description 1
- HHVMYUPMJJDVPG-UHFFFAOYSA-N 1-(2,5-diaminophenyl)ethanol Chemical compound CC(O)C1=CC(N)=CC=C1N HHVMYUPMJJDVPG-UHFFFAOYSA-N 0.000 description 1
- XAWPKHNOFIWWNZ-UHFFFAOYSA-N 1h-indol-6-ol Chemical compound OC1=CC=C2C=CNC2=C1 XAWPKHNOFIWWNZ-UHFFFAOYSA-N 0.000 description 1
- ORVPXPKEZLTMNW-UHFFFAOYSA-N 1h-indol-7-ol Chemical compound OC1=CC=CC2=C1NC=C2 ORVPXPKEZLTMNW-UHFFFAOYSA-N 0.000 description 1
- GZVVXXLYQIFVCA-UHFFFAOYSA-N 2,3-dimethylbenzene-1,4-diamine Chemical compound CC1=C(C)C(N)=CC=C1N GZVVXXLYQIFVCA-UHFFFAOYSA-N 0.000 description 1
- SYEYEGBZVSWYPK-UHFFFAOYSA-N 2,5,6-triamino-4-hydroxypyrimidine Chemical compound NC1=NC(N)=C(N)C(O)=N1 SYEYEGBZVSWYPK-UHFFFAOYSA-N 0.000 description 1
- BWAPJIHJXDYDPW-UHFFFAOYSA-N 2,5-dimethyl-p-phenylenediamine Chemical compound CC1=CC(N)=C(C)C=C1N BWAPJIHJXDYDPW-UHFFFAOYSA-N 0.000 description 1
- KEEQZNSCYCPKOJ-UHFFFAOYSA-N 2,6-diethylbenzene-1,4-diamine Chemical compound CCC1=CC(N)=CC(CC)=C1N KEEQZNSCYCPKOJ-UHFFFAOYSA-N 0.000 description 1
- BXBOXUNPNIJELB-UHFFFAOYSA-N 2,6-dimethoxypyridine-3,5-diamine Chemical compound COC1=NC(OC)=C(N)C=C1N BXBOXUNPNIJELB-UHFFFAOYSA-N 0.000 description 1
- MJAVQHPPPBDYAN-UHFFFAOYSA-N 2,6-dimethylbenzene-1,4-diamine Chemical compound CC1=CC(N)=CC(C)=C1N MJAVQHPPPBDYAN-UHFFFAOYSA-N 0.000 description 1
- BQHMISUMCDYQTR-UHFFFAOYSA-N 2-(1,3-benzodioxol-5-ylamino)ethanol Chemical compound OCCNC1=CC=C2OCOC2=C1 BQHMISUMCDYQTR-UHFFFAOYSA-N 0.000 description 1
- ZFFAFXDAFACVBX-UHFFFAOYSA-N 2-(2,4-diamino-5-methylphenoxy)ethanol Chemical compound CC1=CC(OCCO)=C(N)C=C1N ZFFAFXDAFACVBX-UHFFFAOYSA-N 0.000 description 1
- UEANEAODIZOETQ-UHFFFAOYSA-N 2-(2,4-diaminophenoxy)acetic acid Chemical compound NC1=CC=C(OCC(O)=O)C(N)=C1 UEANEAODIZOETQ-UHFFFAOYSA-N 0.000 description 1
- WCPGNFONICRLCL-UHFFFAOYSA-N 2-(2,4-diaminophenoxy)ethanol Chemical compound NC1=CC=C(OCCO)C(N)=C1 WCPGNFONICRLCL-UHFFFAOYSA-N 0.000 description 1
- KULOFVMDAJSPOK-UHFFFAOYSA-N 2-(2,5-diaminophenoxy)ethanol Chemical compound NC1=CC=C(N)C(OCCO)=C1 KULOFVMDAJSPOK-UHFFFAOYSA-N 0.000 description 1
- KWSVXCAQFTWTEF-UHFFFAOYSA-N 2-(2,5-diaminophenyl)ethanol Chemical compound NC1=CC=C(N)C(CCO)=C1 KWSVXCAQFTWTEF-UHFFFAOYSA-N 0.000 description 1
- VPNFSZXMQLABLM-UHFFFAOYSA-N 2-(2-ethoxyanilino)ethanol Chemical compound CCOC1=CC=CC=C1NCCO VPNFSZXMQLABLM-UHFFFAOYSA-N 0.000 description 1
- SBUMIGFDXJIPLE-UHFFFAOYSA-N 2-(3-amino-4-methoxyanilino)ethanol Chemical compound COC1=CC=C(NCCO)C=C1N SBUMIGFDXJIPLE-UHFFFAOYSA-N 0.000 description 1
- ZTNLMELMADJSAH-UHFFFAOYSA-N 2-(3-aminoanilino)ethanol Chemical compound NC1=CC=CC(NCCO)=C1 ZTNLMELMADJSAH-UHFFFAOYSA-N 0.000 description 1
- JEGKOEYHLJTZGJ-UHFFFAOYSA-N 2-(3-hydroxyanilino)acetamide Chemical compound NC(=O)CNC1=CC=CC(O)=C1 JEGKOEYHLJTZGJ-UHFFFAOYSA-N 0.000 description 1
- KDBUTNSQYYLYOY-UHFFFAOYSA-N 2-(4,5-diaminopyrazol-1-yl)ethanol Chemical compound NC=1C=NN(CCO)C=1N KDBUTNSQYYLYOY-UHFFFAOYSA-N 0.000 description 1
- WFXLRLQSHRNHCE-UHFFFAOYSA-N 2-(4-amino-n-ethylanilino)ethanol Chemical compound OCCN(CC)C1=CC=C(N)C=C1 WFXLRLQSHRNHCE-UHFFFAOYSA-N 0.000 description 1
- YATFNFXGMVOFKB-UHFFFAOYSA-N 2-(aminomethyl)benzene-1,4-diamine Chemical compound NCC1=CC(N)=CC=C1N YATFNFXGMVOFKB-UHFFFAOYSA-N 0.000 description 1
- AVKBLCWBDLLVRL-UHFFFAOYSA-N 2-(methoxymethyl)benzene-1,4-diamine Chemical compound COCC1=CC(N)=CC=C1N AVKBLCWBDLLVRL-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- DEZOGYCXWGTILF-UHFFFAOYSA-N 2-[(4-chlorophenyl)methyl]pyrazole-3,4-diamine Chemical compound NC1=C(N)C=NN1CC1=CC=C(Cl)C=C1 DEZOGYCXWGTILF-UHFFFAOYSA-N 0.000 description 1
- BYYOWEYWJDNTBJ-UHFFFAOYSA-N 2-[(4-methylphenyl)methyl]pyrazole-3,4-diamine Chemical compound C1=CC(C)=CC=C1CN1C(N)=C(N)C=N1 BYYOWEYWJDNTBJ-UHFFFAOYSA-N 0.000 description 1
- PBBRFJWECSDSDZ-UHFFFAOYSA-N 2-[2,4-diamino-5-(2-hydroxyethoxy)phenoxy]ethanol Chemical compound NC1=CC(N)=C(OCCO)C=C1OCCO PBBRFJWECSDSDZ-UHFFFAOYSA-N 0.000 description 1
- DMUXRIHPNREBPF-UHFFFAOYSA-N 2-[2-[2-[2-(2,5-diaminophenoxy)ethoxy]ethoxy]ethoxy]benzene-1,4-diamine Chemical compound NC1=CC=C(N)C(OCCOCCOCCOC=2C(=CC=C(N)C=2)N)=C1 DMUXRIHPNREBPF-UHFFFAOYSA-N 0.000 description 1
- QSQJPVOCPBBFNL-UHFFFAOYSA-N 2-[2-amino-4-(methylamino)phenoxy]ethanol Chemical compound CNC1=CC=C(OCCO)C(N)=C1 QSQJPVOCPBBFNL-UHFFFAOYSA-N 0.000 description 1
- MQMMMSDSVNOFJM-UHFFFAOYSA-N 2-[3-amino-n-(2-hydroxyethyl)anilino]ethanol Chemical compound NC1=CC=CC(N(CCO)CCO)=C1 MQMMMSDSVNOFJM-UHFFFAOYSA-N 0.000 description 1
- KBHHZOYDILVUBF-UHFFFAOYSA-N 2-[4-amino-n-(2-hydroxyethyl)-3-methylanilino]ethanol Chemical compound CC1=CC(N(CCO)CCO)=CC=C1N KBHHZOYDILVUBF-UHFFFAOYSA-N 0.000 description 1
- ISCYHXYLVTWDJT-UHFFFAOYSA-N 2-[4-amino-n-(2-hydroxyethyl)anilino]ethanol Chemical compound NC1=CC=C(N(CCO)CCO)C=C1 ISCYHXYLVTWDJT-UHFFFAOYSA-N 0.000 description 1
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- ATGUVEKSASEFFO-UHFFFAOYSA-N p-aminodiphenylamine Chemical compound C1=CC(N)=CC=C1NC1=CC=CC=C1 ATGUVEKSASEFFO-UHFFFAOYSA-N 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 229940101267 panthenol Drugs 0.000 description 1
- 235000020957 pantothenol Nutrition 0.000 description 1
- 239000011619 pantothenol Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- MIROPXUFDXCYLG-UHFFFAOYSA-N pyridine-2,5-diamine Chemical compound NC1=CC=C(N)N=C1 MIROPXUFDXCYLG-UHFFFAOYSA-N 0.000 description 1
- VHNQIURBCCNWDN-UHFFFAOYSA-N pyridine-2,6-diamine Chemical compound NC1=CC=CC(N)=N1 VHNQIURBCCNWDN-UHFFFAOYSA-N 0.000 description 1
- PZRKPUQWIFJRKZ-UHFFFAOYSA-N pyrimidine-2,4,5,6-tetramine Chemical compound NC1=NC(N)=C(N)C(N)=N1 PZRKPUQWIFJRKZ-UHFFFAOYSA-N 0.000 description 1
- DQAKJEWZWDQURW-UHFFFAOYSA-N pyrrolidonecarboxylic acid Chemical class OC(=O)N1CCCC1=O DQAKJEWZWDQURW-UHFFFAOYSA-N 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- GUQPDKHHVFLXHS-UHFFFAOYSA-M sodium;2-(2-dodecoxyethoxy)ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOS([O-])(=O)=O GUQPDKHHVFLXHS-UHFFFAOYSA-M 0.000 description 1
- 229940001941 soy protein Drugs 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/0077—Preparations with possibly reduced vat, sulfur or indigo dyes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/925—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of animal origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Emergency Medicine (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Zoology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Cosmetics (AREA)
Abstract
Description
Gegenstand der Erfindung ist eine spezielle Farbstoffträgermasse und ein Mittel zum oxidativen Färben von Haaren mit verbesserten haarpflegenden Eigenschaften, das durch Vermischen dieser Farbstoffträgermasse mit einer Oxidationsmittelzubereitung erhalten wird. The invention relates to a special dye carrier and a Agent for oxidative coloring of hair with improved hair care properties, by mixing this dye carrier is obtained with an oxidizing agent preparation.
Oxidationshaarfarben sind ein zentraler Bestandteil eines jeden der Haarbehandlung dienenden, kosmetischen Produktsortiments. Sie bestehen aus zwei Komponenten, die kurz vor dem Gebrauch miteinander vermischt und dann auf das zu färbende Haar aufgetragen werden. Oxidation hair colors are a central part of everyone Hair treatment serving cosmetic product range. she consist of two components that are used just before each other mixed and then applied to the hair to be dyed.
Die erste Komponente wird als Farbstoffträgermasse bezeichnet und enthält die Farbstoffe. Sie kann als Flüssigkeit oder Gel und insbesondere als Emulsion vorliegen. The first component is referred to as the dye carrier and contains the dyes. It can be used as a liquid or gel and in particular exist as an emulsion.
Die bisher bekannten emulsionsförmigen Farbstoffträgermassen haben jedoch eine Reihe von Nachteilen, insbesondere im Hinblick auf den haarpflegenden Effekt. So ermöglichen diese Mittel zum Beispiel nur eine unzureichende Verbesserung der Nass- und Trockenkämmbarkeit, wobei zudem der Konditionierungseffekt in der Regel bereits nach der ersten Haarwäsche wieder verschwunden ist. The previously known emulsion-like dye carrier compositions have however, there are a number of disadvantages, particularly with regard to the hair conditioning effect. For example, these funds only enable one insufficient improvement in wet and dry combability, whereby in addition, the conditioning effect usually already after the first Shampooing has disappeared again.
Aufgabe der vorliegenden Erfindung ist es daher, ein Mittel zum oxidativen Färben von Haaren auf der Basis einer emulsionsförmigen Farbstoffträgermasse zur Verfügung zu stellen, das eine stabile und homogene Emulsion sowie eine optimale Viskosität aufweist und zusätzlich eine hervorragende und dauerhafte Konditionierung der Haare bewirkt. The object of the present invention is therefore to provide a means for oxidative dyeing of hair based on an emulsion To provide dye carrier mass, which is stable and homogeneous emulsion and an optimal viscosity and additionally an excellent and permanent conditioning of the hair causes.
Es wurde nunmehr gefunden, dass die vorgenannten Anforderungen in hervorragender Weise erfüllt werden können, wenn eine emulsionsförmige Farbstoffträgermasse auf der Basis von anionischen und/oder nichtionischen Emulgatoren, Fettalkoholen und/oder Fettsäureestern sowie Glyceryloleat und/oder Lanolin verwendet wird. It has now been found that the aforementioned requirements in can be met excellently if one emulsion-like dye carrier mass based on anionic and / or nonionic emulsifiers, fatty alcohols and / or fatty acid esters and glyceryl oleate and / or lanolin is used.
Gegenstand der vorliegenden Erfindung ist daher eine emulsionsförmige Farbstoffträgermasse, welche (a) Wasser, (b) Oxidationsfarbstoffvorstufen sowie gegebenenfalls zusätzlich direkt auf das Haar aufziehende Farbstoffe, (c) Fettalkohole und/oder Glycerinester gesättigter Fettsäuren, (d) anionische und/oder nicht-ionische und/oder amphotere Tenside und (e) Lanolin und/oder Glycerylmonooleat enthält. The present invention therefore relates to an emulsion Dye carrier mass, which (a) water, (b) oxidation dye precursors as well as, if necessary, additionally directly on the hair Dyes, (c) fatty alcohols and / or glycerol esters of saturated fatty acids, (d) anionic and / or non-ionic and / or amphoteric surfactants and (e) contains lanolin and / or glyceryl monooleate.
Als Oxidationsfarbstoffvorstufen können Kupplersubstanzen und Entwicklersubstanzen sowie mit sich selbst kuppelnde Farbstoffvorstufen verwendet werden. Coupling substances and Developer substances as well as self-coupling dye precursors be used.
Die Oxidationsfarbstoffvorstufen werden in der Farbstoffträgermasse entweder in Form der freien Base oder in Form ihrer physiologisch unbedenklichen Salze mit anorganischen oder organischen Säuren, wie zum Beispiel als Chlorid, Sulfat, Phosphat, Acetat, Propionat, Lactat oder Citrat, eingesetzt. The oxidation dye precursors are in the dye carrier either in the form of the free base or in the form of its physiological harmless salts with inorganic or organic acids, such as for example as chloride, sulfate, phosphate, acetate, propionate, lactate or Citrate.
Als Entwicklersubstanzen können beispielsweise genannt werden:
1,4-Diaminobenzol (p-Phenylendiamin), 1,4-Diamino-2-methyl-benzol
(p-Toluylendiamin), 1,4-Diamino-2,6-dimethyl-benzol, 1,4-Diamino-3,5-
diethyl-benzol, 1,4-Diamino-2,5-dimethyl-benzol, 1,4-Diamino-2,3-
dimethyl-benzol, 2-Chlor-1,4-diaminobenzol, 1,4-Diamino-2-(thiophen-2-
yl)benzol, 1,4-Diamino-2-(thiophen-3-yl)benzol, 1,4-Diamino-2-(pyridin-3-
yl)benzol, 2,5-Diaminobiphenyl, 1,4-Diamino-2-methoxymethyl-benzol,
1,4-Diamino-2-aminomethyl-benzol, 1,4-Diamino-2-hydroxymethyl-benzol,
1,4-Diamino-2-(2-hydroxyethoxy)-benzol, 2-(2-(Acetylamino)ethoxy)-1,4-
diamino-benzol, 4-Phenylamino-anilin, 4-Dimethylamino-anilin,
4-Diethylamino-anilin, 4-Dipropylamino-anilin, 4-[Ethyl(2-hydroxyethyl)-
amino]-anilin, 4-[Di(2-hydroxyethyl)amino]-anilin, 4-[Di(2-hydroxyethyl)-
amino]-2-methyl-anilin, 4-[(2-Methoxyethyl)amino]-anilin,
4-[(3-Hydroxypropyl)amino]-anilin, 4-[(2,3-Dihydroxypropyl)amino]-anilin, 1,4-Diamino-2-
(2-hydroxyethyl)-benzol, 1,4-Diamino-2-(1-hydroxyethyl)-benzol,
1,4-Diamino-2-(1-methylethyl)-benzol,
1,3-Bis[(4-aminophenyl)(2-hydroxyethyl)amino]-2-propanol, 1,4-Bis[(4-Aminophenyl)amino]-butan,
1,8-Bis(2,5-diaminophenoxy)-3,6-dioxaoctan, 4-Amino-phenol, 4-Amino-3-
methyl-phenol, 4-Amino-3-(hydroxymethyl)-phenol,
4-Amino-3-fluorphenol, 4-Methylamino-phenol, 4-Amino-2-(aminomethyl)-phenol,
4-Amino-2-(hydroxymethyl)-phenol, 4-Amino-2-fluorphenol, 4-Amino-2-
[(2-hydroxyethyl)-amino]methyl-phenol, 4-Amino-2-methyl-phenol,
4-Amino-2-(methoxymethyl)-phenol, 4-Amino-2-(2-hydroxyethyl)-phenol,
5-Amino-salicylsäure, 2,5-Diamino-pyridin, 2,4,5,6-Tetraamino-pyrimidin,
2,5,6-Triamino-4-(1H)-pyrimidon, 4,5-Diamino-1-(2-hydroxyethyl)-1H-
pyrazol, 4,5-Diamino-1-(1-methylethyl)-1H-pyrazol, 4,5-Diamino-1-[(4-
methylphenyl)methyl]-1H-pyrazol, 1-[(4-Chlorphenyl)methyl]-4,5-diamino-
1H-pyrazol, 4,5-Diamino-1-methyl-1H-pyrazol, 2-Amino-phenol, 2-Amino-
6-methyl-phenol, 2-Amino-5-methyl-phenol und 2,4-Dihydroxy-phenol.
The following can be named as developer substances:
1,4-diaminobenzene (p-phenylenediamine), 1,4-diamino-2-methyl-benzene (p-toluenediamine), 1,4-diamino-2,6-dimethyl-benzene, 1,4-diamino-3, 5-diethyl-benzene, 1,4-diamino-2,5-dimethyl-benzene, 1,4-diamino-2,3-dimethyl-benzene, 2-chloro-1,4-diaminobenzene, 1,4-diamino- 2- (thiophene-2-yl) benzene, 1,4-diamino-2- (thiophene-3-yl) benzene, 1,4-diamino-2- (pyridin-3-yl) benzene, 2,5-diaminobiphenyl , 1,4-diamino-2-methoxymethyl-benzene, 1,4-diamino-2-aminomethyl-benzene, 1,4-diamino-2-hydroxymethyl-benzene, 1,4-diamino-2- (2-hydroxyethoxy) -benzene, 2- (2- (acetylamino) ethoxy) -1,4-diamino-benzene, 4-phenylamino-aniline, 4-dimethylamino-aniline, 4-diethylamino-aniline, 4-dipropylamino-aniline, 4- [ethyl (2-hydroxyethyl) amino] aniline, 4- [di (2-hydroxyethyl) amino] aniline, 4- [di (2-hydroxyethyl) amino] -2-methylaniline, 4 - [(2- Methoxyethyl) amino] aniline, 4 - [(3-hydroxypropyl) amino] aniline, 4 - [(2,3-dihydroxypropyl) amino] aniline, 1,4-diamino-2- (2-hydroxyethyl) benzene , 1,4-diamino-2- (1-hydroxyethyl) benzene, 1,4-diamino-2- (1-methyl thyl) benzene, 1,3-bis [(4-aminophenyl) (2-hydroxyethyl) amino] -2-propanol, 1,4-bis [(4-aminophenyl) amino] butane, 1,8-bis ( 2,5-diaminophenoxy) -3,6-dioxaoctane, 4-amino-phenol, 4-amino-3-methylphenol, 4-amino-3- (hydroxymethyl) -phenol, 4-amino-3-fluorophenol, 4 -Methylamino-phenol, 4-amino-2- (aminomethyl) phenol, 4-amino-2- (hydroxymethyl) phenol, 4-amino-2-fluorophenol, 4-amino-2- [(2-hydroxyethyl) - amino] methylphenol, 4-amino-2-methylphenol, 4-amino-2- (methoxymethyl) phenol, 4-amino-2- (2-hydroxyethyl) phenol, 5-amino-salicylic acid, 2, 5-diamino-pyridine, 2,4,5,6-tetraamino-pyrimidine, 2,5,6-triamino-4- (1H) -pyrimidone, 4,5-diamino-1- (2-hydroxyethyl) -1H- pyrazole, 4,5-diamino-1- (1-methylethyl) -1H-pyrazole, 4,5-diamino-1 - [(4-methylphenyl) methyl] -1H-pyrazole, 1 - [(4-chlorophenyl) methyl ] -4,5-diamino-1H-pyrazole, 4,5-diamino-1-methyl-1H-pyrazole, 2-amino-phenol, 2-amino-6-methyl-phenol, 2-amino-5-methyl- phenol and 2,4-dihydroxyphenol.
Als Kupplersubstanzen können beispielsweise genannt werden:
N-(3-Dimethylamino-phenyl)-harnstoff, 2,6-Diamino-pyridin, 2-Amino-4-[(2-
hydroxyethyl)amino]-anisol, 2,4-Diamino-1-fluor-5-methyl-benzol,
2,4-Diamino-1-methoxy-5-methyl-benzol, 2,4-Diamino-1-ethoxy-5-methyl-
benzol, 2,4-Diamino-1-(2-hydroxyethoxy)-5-methyl-benzol,
2,4-Di[(2-hydroxyethyl)amino]-1,5-dimethoxy-benzol, 2,3-Diamino-6-
methoxy-pyridin, 3-Amino-6-methoxy-2-(methylamino)-pyridin,
2,6-Diamino-3,5-dimethoxy-pyridin, 3,5-Diamino-2,6-dimethoxy-pyridin,
1,3-Diaminobenzol, 2,4-Diamino-1-(2-hydroxyethoxy)-benzol,
1,3-Diamino-4-(2,3-dihydroxypropoxy)-benzol, 1,3-Diamino-4-(3-
hydroxypropoxy)-benzol, 1,3-Diamino-4-(2-methoxyethoxy)-benzol,
2,4-Diamino-1,5-di(2-hydroxyethoxy)-benzol, 1-(2-Aminoethoxy)-2,4-
diamino-benzol, 2-Amino-1-(2-hydroxyethoxy)-4-methylamino-benzol,
2,4-Diaminophenoxy-essigsäure, 3-[Di(2-hydroxyethyl)amino]-anilin,
4-Amino-2-di[(2-hydroxyethyl)amino]-1-ethoxy-benzol, 5-Methyl-2-(1-
methylethyl)-phenol, 3-[(2-Hydroxyethyl)amino]-anilin, 3-[(2-Aminoethyl)-
amino]-anilin, 1,3-Di(2,4-diaminophenoxy)-propan,
Di(2,4-diaminophenoxy)-methan, 1,3-Diamino-2,4-dimethoxy-benzol,
2,6-Bis(2-hydroxyethyl)amino-toluol, 4-Hydroxyindol, 3-Dimethylamino-phenol,
3-Diethylamino-phenol, 5-Amino-2-methyl-phenol, 5-Amino-4-fluor-2-
methyl-phenol, 5-Amino-4-methoxy-2-methyl-phenol, 5-Amino-4-ethoxy-2-
methyl-phenol, 3-Amino-2,4-dichlor-phenol, 5-Amino-2,4-dichlor-phenol,
3-Amino-2-methyl-phenol, 3-Amino-2-chlor-6-methyl-phenol,
3-Aminophenol, 2-[(3-Hydroxyphenyl)amino]-acetamid, 5-[(2-Hydroxyethyl)amino]-
4-methoxy-2-methyl-phenol, 5-[(2-Hydroxyethyl)amino)-2-methyl-phenol,
3-[(2-Hydroxyethyl)amino]-phenol, 3-[(2-Methoxyethyl)amino]-phenol,
5-Amino-2-ethyl-phenol, 5-Amino-2-methoxy-phenol, 2-(4-Amino-2-
hydroxyphenoxy)-ethanol, 5-[(3-Hydroxypropyl)amino]-2-methyl-phenol,
3-[(2,3-Dihydroxypropyl)amino]-2-methyl-phenol, 3-[(2-Hydroxyethyl)-
amino]-2-methyl-phenol, 2-Amino-3-hydroxy-pyridin, 2,6-Dihydroxy-3,4-
dimethylpyridin, 5-Amino-4-chlor-2-methyl-phenol, 1-Naphthol, 2-Methyl-1-
naphthol, 1,5-Dihydroxy-naphthalin, 1,7-Dihydroxy-naphthalin,
2,3-Dihydroxy-naphthalin, 2,7-Dihydroxy-naphthalin,
2-Methyl-1-naphtholacetat, 1,3-Dihydroxy-benzol, 1-Chlor-2,4-dihydroxy-benzol, 2-Chlor-1,3-
dihydroxy-benzol, 1,2-Dichlor-3,5-dihydroxy-4-methyl-benzol, 1,5-Dichlor-
2,4-dihydroxy-benzol, 1,3-Dihydroxy-2-methyl-benzol, 3,4-Methylendioxy-
phenol, 3,4-Methylendioxy-anilin, 5-[(2-Hydroxyethyl)amino]-1,3-
benzodioxol, 6-Brom-1-hydroxy-3,4-methylendioxy-benzol,
3,4-Diaminobenzoesäure, 3,4-Dihydro-6-hydroxy-1,4(2H)-benzoxazin, 6-Amino-3,4-
dihydro-1,4(2H)-benzoxazin, 3-Methyl-1-phenyl-5-pyrazolon,
5,6-Dihydroxy-indol, 5,6-Dihydroxy-indolin, 5-Hydroxy-indol, 6-Hydroxy-
indol, 7-Hydroxy-indol und 2,3-Indolindion.
Examples of coupler substances that can be mentioned are:
N- (3-Dimethylaminophenyl) urea, 2,6-diamino-pyridine, 2-amino-4 - [(2-hydroxyethyl) amino] anisole, 2,4-diamino-1-fluoro-5-methyl -benzene, 2,4-diamino-1-methoxy-5-methyl-benzene, 2,4-diamino-1-ethoxy-5-methyl-benzene, 2,4-diamino-1- (2-hydroxyethoxy) -5 -methyl-benzene, 2,4-di [(2-hydroxyethyl) amino] -1,5-dimethoxy-benzene, 2,3-diamino-6-methoxy-pyridine, 3-amino-6-methoxy-2- ( methylamino) pyridine, 2,6-diamino-3,5-dimethoxy-pyridine, 3,5-diamino-2,6-dimethoxy-pyridine, 1,3-diaminobenzene, 2,4-diamino-1- (2- hydroxyethoxy) benzene, 1,3-diamino-4- (2,3-dihydroxypropoxy) benzene, 1,3-diamino-4- (3-hydroxypropoxy) benzene, 1,3-diamino-4- (2- methoxyethoxy) benzene, 2,4-diamino-1,5-di (2-hydroxyethoxy) benzene, 1- (2-aminoethoxy) -2,4-diamino-benzene, 2-amino-1- (2-hydroxyethoxy ) -4-methylamino-benzene, 2,4-diaminophenoxyacetic acid, 3- [di (2-hydroxyethyl) amino] aniline, 4-amino-2-di [(2-hydroxyethyl) amino] -1-ethoxy- benzene, 5-methyl-2- (1-methylethyl) phenol, 3 - [(2-hydroxyethyl) amino] aniline, 3 - [(2-aminoethyl) amino] -a niline, 1,3-di (2,4-diaminophenoxy) propane, di (2,4-diaminophenoxy) methane, 1,3-diamino-2,4-dimethoxy-benzene, 2,6-bis (2- hydroxyethyl) aminotoluene, 4-hydroxyindole, 3-dimethylamino-phenol, 3-diethylamino-phenol, 5-amino-2-methyl-phenol, 5-amino-4-fluoro-2-methyl-phenol, 5-amino- 4-methoxy-2-methylphenol, 5-amino-4-ethoxy-2-methylphenol, 3-amino-2,4-dichlorophenol, 5-amino-2,4-dichlorophenol, 3- Amino-2-methylphenol, 3-amino-2-chloro-6-methylphenol, 3-aminophenol, 2 - [(3-hydroxyphenyl) amino] -acetamide, 5 - [(2-hydroxyethyl) amino] - 4-methoxy-2-methylphenol, 5 - [(2-hydroxyethyl) amino) -2-methylphenol, 3 - [(2-hydroxyethyl) amino] phenol, 3 - [(2-methoxyethyl) amino] -phenol, 5-amino-2-ethylphenol, 5-amino-2-methoxyphenol, 2- (4-amino-2-hydroxyphenoxy) ethanol, 5 - [(3-hydroxypropyl) amino] -2- methyl phenol, 3 - [(2,3-dihydroxypropyl) amino] -2-methyl phenol, 3 - [(2-hydroxyethyl) amino] -2-methyl phenol, 2-amino-3-hydroxy-pyridine , 2,6-dihydroxy-3,4-dimethylpyridine, 5-amino-4-chloro-2-methylphenol, 1-naphthol, 2-methyl-1-naphthol, 1,5-dihydroxy-naphthalene, 1,7-dihydroxy-naphthalene, 2,3-dihydroxy-naphthalene, 2,7-dihydroxy-naphthalene, 2-methyl-1-naphthol acetate, 1, 3-dihydroxy-benzene, 1-chloro-2,4-dihydroxy-benzene, 2-chloro-1,3-dihydroxy-benzene, 1,2-dichloro-3,5-dihydroxy-4-methyl-benzene, 1, 5-dichloro-2,4-dihydroxy-benzene, 1,3-dihydroxy-2-methyl-benzene, 3,4-methylenedioxyphenol, 3,4-methylenedioxy-aniline, 5 - [(2-hydroxyethyl) amino] -1,3- benzodioxole, 6-bromo-1-hydroxy-3,4-methylenedioxy-benzene, 3,4-diaminobenzoic acid, 3,4-dihydro-6-hydroxy-1,4 (2H) -benzoxazine, 6- Amino-3,4-dihydro-1,4 (2H) -benzoxazine, 3-methyl-1-phenyl-5-pyrazolone, 5,6-dihydroxy-indole, 5,6-dihydroxy-indoline, 5-hydroxy-indole , 6-hydroxy-indole, 7-hydroxy-indole and 2,3-indolinedione.
Die Kupplersubstanzen und Entwicklersubstanzen werden vorzugsweise in etwa equimolarer Menge eingesetzt. Es ist jedoch nicht nachteilig, wenn die Kupplersubstanzen gegenüber den Entwicklersubstanzen in einem Überschuß oder Unterschuß verwendet werden, wobei sowohl die Entwicklerkomponente ein Gemisch von bekannten Entwicklersubstanzen als auch die Kupplerkomponente ein Gemisch von bekannten Kupplersubstanzen darstellen kann. The coupler substances and developer substances are preferred used in an approximately equimolar amount. However, it is not a disadvantage if the coupler substances compared to the developer substances in an excess or deficit can be used, both the Developer component is a mixture of known developer substances as well as the coupler component a mixture of known Can represent coupler substances.
Als mit sich selbstkuppelnde Farbvorstufen können beispielsweise genannt werden: 2-Amino-5-methylphenol, 2-Amino-6-methylphenol, 2-Amino-5-ethoxyphenol und 2-Propyl-amino-5-aminopyridin. For example, with self-coupling color precursors are mentioned: 2-amino-5-methylphenol, 2-amino-6-methylphenol, 2-amino-5-ethoxyphenol and 2-propyl-amino-5-aminopyridine.
Die Gesamtmenge der in der Farbstoffträgermasse enthaltenen Oxidationsfarbstoffvorstufen beträgt etwa 0,01 bis 12 Gewichtsprozent, insbesondere etwa 0,2 bis 4 Gewichtsprozent. The total amount contained in the dye vehicle Oxidation dye precursors is about 0.01 to 12 percent by weight, in particular about 0.2 to 4 percent by weight.
Zur Erzielung bestimmter Farbnuancen können ferner auch übliche direktziehende Farbstoffe aus der Gruppe der basichen oder sauren Farbstoffe, der Triphenylmethanfarbstoffe, der aromatischen Nitrofarbstoffe, der Azofarbstoffe und der Anthrachinonfarbstoffe in der Farbstoffträgermasse enthalten sein. To achieve certain shades of color, conventional ones can also be used direct dyes from the group of basic or acidic Dyes, the triphenylmethane dyes, the aromatic Nitro dyes, azo dyes and anthraquinone dyes in the Dye carrier mass may be included.
Die Gesamtmenge der direktziehenden Farbstoffe beträgt in der erfindungsgemässen Farbstoffträgermasse etwa 0,01 bis 7 Gewichtsprozent, vorzugsweise etwa 0,2 bis 4 Gewichtsprozent. The total amount of direct dyes is Dye carrier composition according to the invention is approximately 0.01 to 7 % By weight, preferably about 0.2 to 4% by weight.
Der in der emulsionsförmigen Farbstoffträgermasse enthaltene Fettalkohol kann sowohl natürlicher als auch synthetischer Herkunft sein, wobei C12- bis C24-Fettalkohole, insbesondere Cetylalkohol und Stearylalkohol, oder deren Gemische, bevorzugt sind. Als Glycerinester gesättigter Fettsäuren sind insbesondere Glycerinester von gesättigten C10- bis C20- Fettsäuren, beispielsweise Glycerinmonostearat, zu nennen. The fatty alcohol contained in the emulsion-like dye carrier mass can be of either natural or synthetic origin, C 12 to C 24 fatty alcohols, in particular cetyl alcohol and stearyl alcohol, or mixtures thereof, being preferred. Glycerol esters of saturated fatty acids include, in particular, glycerol esters of saturated C 10 to C 20 fatty acids, for example glycerol monostearate.
Die Einsatzmenge des Fettalkohols und/oder Glycerinesters gesättigter Fettsäuren in der Farbstoffträgermasse beträgt etwa 5 bis 20 Gewichtsprozent, vorzugsweise 7 bis 15 Gewichtsprozent. The amount of fatty alcohol and / or glycerol ester saturated Fatty acids in the dye carrier mass is about 5 to 20 % By weight, preferably 7 to 15% by weight.
Die nichtionischen und/oder anionischen und/oder amphoteren Tenside werden in einer Gesamtmenge von etwa 0,1 bis 25 Gewichtsprozent, vorzugsweise etwa 0,5 bis 20 Gewichtsprozent, eingesetzt. Als nichtionische Tenside können insbesondere oxethylierte C10- bis C20- Fettalkohole, oxethylierte Sorbitanfettsäure-(C12 bis C18)-partialester, oxethylierte Glycerinfettsäure-(C12 bis C18)-partialester, wobei ein Oxethylierungsgrad von 1 bis 30, insbesondere von 2 bis 6, bevorzugt ist, (C12 bis C18)-Alkylglucoside oder Gemische dieser Verbindungen eingesetzt werden. Als anionische Tenside können insbesondere Alkylsulfate, Alkylethersulfate mit einem C10- bis C20-Alkylrest, wobei ein Oxethylierungsgrad von 1 bis 8, insbesondere von 1 bis 6, bevorzugt ist, oder Gemische derselben eingesetzt werden. Als amphotere Tenside können beispielsweise Betaintenside und sulfatierte Imidazolinderivate (z. B. Miranol®-Typen) genannt werden. Besonders bevorzugt ist die Verwendung von C10- bis C20-Alkylethersulfaten mit einem Oxethylierungsgrad von 1 bis 6, beispielsweise Natriumlaurylalkoholdiglykolethersulfat, alleine oder im Gemisch mit nichtionischen und/oder amphoteren Tensiden. The nonionic and / or anionic and / or amphoteric surfactants are used in a total amount of about 0.1 to 25 percent by weight, preferably about 0.5 to 20 percent by weight. Suitable nonionic surfactants may, in particular ethoxylated C 10 - to C 20 - fatty alcohols, ethoxylated sorbitan (C 12 to C 18) -partialester, ethoxylated glycerol fatty (C 18 to C 12) -partialester, wherein a degree of ethoxylation from 1 to 30, in particular from 2 to 6, preferably, (C 12 to C 18 ) alkyl glucosides or mixtures of these compounds are used. Anionic surfactants which can be used are, in particular, alkyl sulfates, alkyl ether sulfates having a C 10 -C 20 -alkyl radical, a degree of oxyethylation of 1 to 8, in particular 1 to 6, being preferred, or mixtures thereof. Examples of amphoteric surfactants that can be mentioned are betaine surfactants and sulfated imidazoline derivatives (for example Miranol® types). Particular preference is given to using C 10 -C 20 -alkyl ether sulfates with a degree of oxethylation of 1 to 6, for example sodium lauryl alcohol diglycol ether sulfate, alone or in a mixture with nonionic and / or amphoteric surfactants.
Die erfindungsgemäße Farbstoffträgermasse enthält das Lanolin und/oder Glycerylmonooleat in einer Gesamtmenge von etwa 0,2 bis 15 Gewichtsprozent, vorzugsweise 1 bis 10 Gewichtsprozent. The dye carrier composition according to the invention contains the lanolin and / or Glyceryl monooleate in a total amount of about 0.2 to 15 % By weight, preferably 1 to 10% by weight.
In einer bevorzugten Ausführungsform enthält die erfindungsgemäße Farbstoffträgermasse zusätzlich mindestens ein kationisches Polymer, vorzugsweise ein kationisches Cellulosederivat (z. B. Polyquaternium-10), ein Dimethyldiallylammoniumchlorid/Acrylamid-Copolymer (z. B. Polyquaternium-7; Merquat®550) oder ein Poly-(dimethyldiallylammoniumchlorid) (z. B. Polyquaternium-6; Merquat®100), in einer Einsatzmenge von etwa 0,1 bis 5 Gewichtsprozent. In a preferred embodiment, the invention contains Dye carrier additionally at least one cationic polymer, preferably a cationic cellulose derivative (e.g. Polyquaternium-10), a dimethyldiallylammonium chloride / acrylamide copolymer (e.g. Polyquaternium-7; Merquat®550) or a Poly (dimethyldiallylammonium chloride) (e.g. Polyquaternium-6; Merquat®100), in one Amount used from about 0.1 to 5 percent by weight.
Gegebenenfalls können der erfindungsgemäßen Farbstoffträgermasse spezielle Pflegestoffe und/oder Wirkstoffe, wie zum Beispiel Aminosäuren; Proteinhydrolysate, beispielsweise Keratinhydrolysate, Elastinhydrolysate, Kollagenhydrolysate, Seidenproteinhydrolysate, Milcheiweißhydrolysate, Sojaproteinhydrolysate oder Weizenproteinhydrolysate; Panthenol; Allantoin; Pyrrolidoncarbonsäuren oder deren Salze; Pflanzenextrakte oder Vitamine; alleine oder in Kombination miteinander, zugesetzt werden, wobei diese Verbindungen vorzugsweise in einer Gesamtkonzentration von etwa 0,01 bis 5 Gewichtsprozent, insbesondere etwa 0,01 bis 1 Gewichtsprozent, in der Farbstoffträgermasse enthalten sind. Optionally, the dye carrier composition according to the invention special care substances and / or active substances, such as amino acids; Protein hydrolyzates, for example keratin hydrolyzates, elastin hydrolyzates, Collagen hydrolyzates, silk protein hydrolyzates, milk protein hydrolyzates, Soy protein hydrolyzates or wheat protein hydrolyzates; panthenol; allantoin; Pyrrolidone carboxylic acids or their salts; plant extracts or vitamins; added alone or in combination are, these compounds preferably in one Total concentration of about 0.01 to 5 percent by weight, especially about 0.01 to 1 percent by weight in the dye vehicle.
Darüber hinaus können der Farbstoffträgermasse Antioxidantien, wie zum Beispiel Ascorbinsäure, Thioglykolsäure oder Natriumsulfit, oder Komplexbildner für Schwermetalle, beispielsweise Ethylendiaminotetraacetat oder Nitriloessigsäure, in einer Menge von bis zu etwa 0,5 Gewichtsprozent; sowie Parfümöle in einer Menge von bis zu etwa 1 Gewichtsprozent zugesetzt werden. In addition, the dye carrier antioxidants such as Example ascorbic acid, thioglycolic acid or sodium sulfite, or Complexing agent for heavy metals, for example ethylene diaminotetraacetate or Nitriloacetic acid, in an amount up to about 0.5 percent by weight; and perfume oils in an amount of up to about 1 percent by weight be added.
Je nach Zusammensetzung kann die erfindungsgemäße Farbstoffträgermasse schwach sauer, neutral oder alkalisch reagieren. Insbesondere weist sie einen pH-Wert von 6,5 bis 12 auf, wobei die basische Einstellung vorzugsweise mit Ammoniak erfolgt. Es können aber auch organische Amine, zum Beispiel Monoethanolamin und Triethanolamin, oder auch anorganische Basen wie Natriumhydroxid und Kaliumhydroxid Verwendung finden. Für eine pH-Einstellung im sauren Bereich kommen anorganische oder organische Säuren, zum Beispiel Phosphorsäure, Essigsäure, Zitronensäure oder Weinsäure, in Betracht. Depending on the composition, the invention Dye carrier mass react weakly acidic, neutral or alkaline. In particular it has a pH of 6.5 to 12, with the basic setting preferably with ammonia. But it can also be organic Amines, for example monoethanolamine and triethanolamine, or also inorganic bases such as sodium hydroxide and potassium hydroxide Find use. Come for a pH adjustment in the acidic range inorganic or organic acids, for example phosphoric acid, Acetic acid, citric acid or tartaric acid.
Für die Anwendung zur oxidativen Färbung von Haaren vermischt man die vorstehend beschriebene Farbstoffträgermasse unmittelbar vor dem Gebrauch mit einem flüssigen oder emulsionsförmigen Oxidationsmittel und trägt eine für die Haarfärbebehandlung ausreichende Menge, je nach Haarfülle, im allgemeinen etwa 50 bis 200 Gramm, dieses Gemisches auf das Haar auf. Das nach dem Vermischen der Farbstoffträgermasse mit dem Oxidationsmittel erhaltene gebrauchsfertige Oxidationshaarfärbemittel hat vorzugsweise einen pH-Wert von etwa 6 bis 11,5. For the application for the oxidative coloring of hair one mixes the above-described dye carrier immediately before Use with a liquid or emulsion oxidizer and wears an amount sufficient for hair dye treatment, depending on Hair fullness, generally about 50 to 200 grams, of this mixture hair on. That after mixing the dye carrier with ready to use the oxidizer received Oxidation hair dye preferably has a pH of about 6 to 11.5.
Als Oxidationsmittel zur Entwicklung der Haarfärbung kommen hauptsächlich Wasserstoffperoxid oder dessen Additionsverbindungen an Harnstoff, Melamin, Natriumborat oder Natriumcarbonat in Form einer 3- bis 12prozentigen, vorzugsweise 6prozentigen, wässrigen Lösung, aber auch Luftsauerstoff in Betracht. Vorzugsweise wird eine cremeförmige Oxidationsmittelzubereitung mit einem Gehalt von etwa 1 bis 6 Gewichtsprozent eines C12- bis C24-Fettalkohols natürlicher oder synthetischer Herkunft, insbesondere Cetylalkohol und/oder Stearylalkohol, verwendet. Wird eine 3- bis 6prozentige Wasserstoffperoxid-Lösung als Oxidationsmittel verwendet, so beträgt das Gewichtsverhältnis zwischen Farbstoffträgermasse und Oxidationsmittel etwa 5 : 1 bis 1 : 4, vorzugsweise jedoch etwa 2 : 1 bis 1 : 3. Grössere Mengen an Oxidationsmittel werden vor allem bei höheren Farbstoffkonzentrationen in der Farbstoffträgermasse, oder wenn gleichzeitig eine stärkere Bleichung des Haares beabsichtigt ist, verwendet. The main oxidizing agents used to develop hair color are hydrogen peroxide or its addition compounds with urea, melamine, sodium borate or sodium carbonate in the form of a 3 to 12 percent, preferably 6 percent, aqueous solution, but also atmospheric oxygen. A cream-shaped oxidizing agent preparation with a content of about 1 to 6 percent by weight of a C 12 to C 24 fatty alcohol of natural or synthetic origin, in particular cetyl alcohol and / or stearyl alcohol, is preferably used. If a 3 to 6 percent hydrogen peroxide solution is used as the oxidizing agent, the weight ratio between the dye carrier mass and the oxidizing agent is about 5: 1 to 1: 4, but preferably about 2: 1 to 1: 3. Larger amounts of oxidizing agent are used, especially with larger ones Dye concentrations in the dye carrier mass, or if at the same time a stronger bleaching of the hair is intended, is used.
Man läßt das Gemisch bei 15 bis 50 Grad Celsius etwa 10 bis 45 Minuten lang, vorzugsweise 30 Minuten lang, auf das Haar einwirken, spült sodann das Haar mit Wasser aus und trocknet es. Gegebenenfalls wird im Anschluß an diese Spülung mit einem Shampoo gewaschen und eventuell mit einer schwachen organischen Säure, wie zum Beispiel Zitronensäure oder Weinsäure, nachgespült. Anschließend wird das Haar getrocknet. Falls erforderlich kann das Haar vor dem Trocknen zur Frisur gelegt werden. The mixture is left at 15 to 50 degrees Celsius for about 10 to 45 minutes act on the hair for long, preferably 30 minutes, then rinse the hair with water and dries it. If necessary, in Following this conditioner washed with a shampoo and possibly with a weak organic acid, such as citric acid or tartaric acid, rinsed. The hair is then dried. If necessary, the hair can be put to the hairstyle before drying become.
Ein weiterer Gegenstand der vorliegenden Erfindung ist ein 2-Komponenten-Mittel zum oxidativen Färben von Haaren bestehend aus 2 unmittelbar vor der Anwendung zu vermischenden Komponenten (A) und (B), welches dadurch gekennzeichnet ist, dass die Komponente (A) die vorstehend beschriebene Farbstoffträgermasse ist, und die Komponente (B) eine cremeförmige Oxidationsmittelzubereitung mit einem Gehalt an (a) etwa 3 bis 12 Gewichtsprozent eines Oxidationsmittels, vorzugsweise Wasserstoffperoxid, und (b) etwa 1 bis 6 Gewichtsprozent eines C12- bis C24-Fettalkohols natürlicher oder synthetischer Herkunft ist. Another object of the present invention is a 2-component agent for the oxidative dyeing of hair consisting of 2 components (A) and (B) to be mixed immediately before use, which is characterized in that component (A) is the one described above Dye carrier mass, and component (B) is a cream-shaped oxidizing agent preparation containing (a) about 3 to 12 percent by weight of an oxidizing agent, preferably hydrogen peroxide, and (b) about 1 to 6 percent by weight of a C 12 to C 24 fatty alcohol, natural or is of synthetic origin.
Das mit der erfindungsgemäßen Farbstoffträgermasse erhaltene Haarfärbemittel weist einen gegenüber handelsüblichen Mittel deutlich verbesserten und haltbareren Haarkonditionierungseffekt auf. Weiterhin liegt die erfindungsgemäße Farbstoffträgermasse in Form einer homogenen und stabilen Emulsion vor, die ein sehr gutes Emulgiervermögen sowie eine hohe Viskositätskonstanz besitzt. In diesem Zusammenhang ist insbesondere die leichte Vermischbarkeit der Farbstoffträgermasse mit dem Oxidationsmittel sowie die Tatsache, dass die Viskosität der Farbstoffträgermasse weitgehend unabhängig von Art und Menge der enthaltenen Farbstoffe ist, hervorzuheben. The one obtained with the dye carrier composition according to the invention Hair dye clearly shows one compared to commercially available agents improved and more durable hair conditioning effect. Farther the dye carrier composition according to the invention is in the form of a homogeneous and stable emulsion, which is a very good Has emulsifying power and a high viscosity constancy. In this The connection is particularly easy to mix Dye carrier mass with the oxidizing agent and the fact that the viscosity of the dye carrier is largely independent of Art and the amount of dyes contained is to be emphasized.
Die nachfolgenden Beispiele sollen den Gegenstand der Erfindung näher
erläutern, ohne den Gegenstand auf diese Beispiele zu beschränken.
Beispiel 1
Oxidationshaarfärbemittel
Man vermischt vor dem Gebrauch 60 g der Farbstoffträgermasse mit 60 g der Wasserstoffperoxid-Emulsion. Der pH-Wert des erhaltenen gebrauchsfertigen Mittels beträgt etwa 10. 60 g of the dye carrier mass are mixed with 60 g before use the hydrogen peroxide emulsion. The pH of the obtained ready-to-use agent is about 10.
Das erhaltene gebrauchsfertige Mittel wird auf das Haar aufgetragen und
nach einer Einwirkungszeit von 30 Minuten bei Raumtemperatur mit
Wasser ausgespült. Anschliessend wird das Haar getrocknet. Das Haar
erhält eine mittelbraune Färbung.
Oxidationshaarfärbemittel
Man vermischt vor dem Gebrauch 60 g der Farbstoffträgermasse mit 60 g der Wasserstoffperoxid-Emulsion. Der pH-Wert des erhaltenen gebrauchsfertigen Mittels beträgt etwa 10,1. 60 g of the dye carrier mass are mixed with 60 g before use the hydrogen peroxide emulsion. The pH of the obtained ready-to-use agent is approximately 10.1.
Das erhaltene gebrauchsfertige Mittel wird auf das Haar aufgetragen und nach einer Einwirkungszeit von 30 Minuten bei Raumtemperatur mit Wasser ausgespült. Anschliessend wird das Haar getrocknet. Das Haar erhält eine blonde Färbung. The ready-to-use agent obtained is applied to the hair and after an exposure time of 30 minutes at room temperature Water rinsed out. The hair is then dried. The hair gets a blonde color.
Das Färbemittel gemäß Beispiel 1 bzw. 2 wurde jeweils mit einem nicht- erfindungsgemäßen Färbemittel, bei dem das Glyceryloleat bzw. das Lanolin mengengleich durch Wasser ersetzt wurde (Beispiel 1a bzw. 2a), verglichen. Die Anwendung der Färbemittel erfolgte hierbei in der in den Beispielen 1 und 2 beschriebenen Weise. Eine Beurteilung der Haareigenschaften durch eine Gruppe von Friseuren ergab, dass die mit einem Mittel gemäß Beispiel 1 bzw. 2 gefärbten Haare einen deutlichen angenehmeren Griff und eine wesentlich bessere Kämmbarkeit aufwiesen, als die mit den nicht-erfindungsgemäßen Mitteln 1a bzw. 2a gefärbten Haare. The colorant according to Example 1 or 2 was in each case with a non- Colorant according to the invention, in which the glyceryl oleate or Lanolin was replaced by water in equal quantities (Examples 1a and 2a), compared. The colorants were used in the Examples 1 and 2 described way. An assessment of the Hair properties by a group of hairdressers revealed that having a medium according to Example 1 or 2 colored hair a clear more comfortable grip and a much better combability had than that with the non-inventive means 1a and 2a dyed hair.
Alle in der vorliegenden Anmeldung angegebenen Prozentzahlen stellen, soweit nicht anders angegeben, Gewichtsprozente dar. All percentages given in the present application represent unless otherwise stated, percentages by weight.
Claims (14)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2001132915 DE10132915A1 (en) | 2001-07-06 | 2001-07-06 | Aqueous emulsion carrier for oxidation hair dye contains fatty alcohols or glycerol esters of saturated fatty acids, surfactants and lanolin or glyceryl monooleate |
| JP2002177839A JP3693252B2 (en) | 2001-07-06 | 2002-06-19 | Oxidative hair dye |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2001132915 DE10132915A1 (en) | 2001-07-06 | 2001-07-06 | Aqueous emulsion carrier for oxidation hair dye contains fatty alcohols or glycerol esters of saturated fatty acids, surfactants and lanolin or glyceryl monooleate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE10132915A1 true DE10132915A1 (en) | 2003-01-30 |
Family
ID=7690912
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2001132915 Withdrawn DE10132915A1 (en) | 2001-07-06 | 2001-07-06 | Aqueous emulsion carrier for oxidation hair dye contains fatty alcohols or glycerol esters of saturated fatty acids, surfactants and lanolin or glyceryl monooleate |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP3693252B2 (en) |
| DE (1) | DE10132915A1 (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2883737A1 (en) * | 2005-03-31 | 2006-10-06 | Oreal | COLORING COMPOSITION COMPRISING A GLYCERYLE ESTER AND A METHOD OF COLORING KERATIN FIBERS USING THE SAME |
| US7550015B2 (en) | 2005-03-31 | 2009-06-23 | L'oreal S.A. | Dye composition with a reduced content of starting materials, and process for dyeing keratin fibers using the same |
| US7569078B2 (en) | 2005-03-31 | 2009-08-04 | L'oreal S.A. | Dye composition comprising at least one cellulose and process for dyeing keratin fibers using the dye composition |
| US7575605B2 (en) | 2005-03-31 | 2009-08-18 | L'oreal S.A. | Dye composition comprising at least one glycerol ester and a process for dyeing keratin fibers using the composition |
| US7578854B2 (en) | 2005-03-31 | 2009-08-25 | L'oreal S.A. | Dye composition comprising at least one fatty acid ester and process for dyeing keratin fibers using the same |
| US7651533B2 (en) | 2005-03-31 | 2010-01-26 | Oreal | Dye composition with a reduced content of starting materials, process for dyeing keratin fibers using the same and device therefor |
| EP2879649B1 (en) | 2012-08-02 | 2018-11-07 | L'oreal | Dyeing composition comprising at least one fatty substance, at least one oxidizing agent and at least one non-ionic, anionic and amphoteric surfactant |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6636243B2 (en) * | 2014-11-05 | 2020-01-29 | ヘンケルジャパン株式会社 | Oxidative hair dye |
| FR3128632B1 (en) * | 2021-10-29 | 2024-07-12 | Oreal | Composition comprising the combination of two specific oxidation coloring precursors and a fatty acid and glycerol ester. |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3732147A1 (en) * | 1987-09-24 | 1989-04-06 | Henkel Kgaa | EMULSION-SHAPED HYDROGEN PEROXIDE PREPARATIONS FOR BLONDING AND OXIDATIVE COLORING OF THE HAIR |
| DE4017718A1 (en) * | 1990-06-01 | 1991-12-05 | Wella Ag | OXIDATION HAIR FIBER FROM AN EMULSION-SHAPED DYE CARRIER AND AN EMULSION-SHAPED, OXIDATION-CONTAINING COMPOSITION AND METHOD FOR THE OXIDATIVE COLORING OF HAIR |
| DE4122748A1 (en) * | 1991-07-10 | 1993-01-14 | Wella Ag | Inexpensive physiologically tolerated oxidative hair dyeing agent - comprising 2,5-di:amino:toluene-2,6-di:amino:pyridine, resorcinol and amino-methylphenol or its deriv(s). |
| DE4216381A1 (en) * | 1992-05-18 | 1993-11-25 | Wella Ag | Oxidative hair dye on the basis of a creamy carrier and method for dyeing hair |
| DE4332965A1 (en) * | 1993-09-28 | 1995-03-30 | Wella Ag | An oxidation hair dye comprising a cream-colored dye carrier mass and a preparation containing a polymer and an oxidizing agent, and a process for the oxidative dyeing of hair |
| DE4408506C2 (en) * | 1994-03-14 | 1996-07-04 | Schwarzkopf Gmbh Hans | Aqueous hair dye |
| JPH09249537A (en) * | 1996-03-13 | 1997-09-22 | Shiseido Co Ltd | Oxidation hair dye and its production |
| JP3195557B2 (en) * | 1996-03-16 | 2001-08-06 | ウエラ アクチェンゲゼルシャフト | Mixed wax and cosmetics containing it |
| JPH09255541A (en) * | 1996-03-28 | 1997-09-30 | Shiseido Co Ltd | Hair-bleaching and dyeing composition |
| JP2000351719A (en) * | 1999-06-09 | 2000-12-19 | Pola Chem Ind Inc | Hair dyeing agent |
| DE19961229C1 (en) * | 1999-12-18 | 2001-04-05 | Wella Ag | Preparation of 2-aminomethyl-1,4-diamino-benzene or salt, used in colorant for keratinous fibers, e.g. hair, involves reacting 2-(N-acylaminomethyl)-4-nitrophenol with haloacetamide, rearrangement, reduction and deacetylation |
-
2001
- 2001-07-06 DE DE2001132915 patent/DE10132915A1/en not_active Withdrawn
-
2002
- 2002-06-19 JP JP2002177839A patent/JP3693252B2/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2883737A1 (en) * | 2005-03-31 | 2006-10-06 | Oreal | COLORING COMPOSITION COMPRISING A GLYCERYLE ESTER AND A METHOD OF COLORING KERATIN FIBERS USING THE SAME |
| EP1716840A1 (en) * | 2005-03-31 | 2006-11-02 | L'oreal | Hair-dye composition containing a glycerol ester and the corresponding hair-dyeing process |
| US7550015B2 (en) | 2005-03-31 | 2009-06-23 | L'oreal S.A. | Dye composition with a reduced content of starting materials, and process for dyeing keratin fibers using the same |
| US7569078B2 (en) | 2005-03-31 | 2009-08-04 | L'oreal S.A. | Dye composition comprising at least one cellulose and process for dyeing keratin fibers using the dye composition |
| US7575605B2 (en) | 2005-03-31 | 2009-08-18 | L'oreal S.A. | Dye composition comprising at least one glycerol ester and a process for dyeing keratin fibers using the composition |
| US7578854B2 (en) | 2005-03-31 | 2009-08-25 | L'oreal S.A. | Dye composition comprising at least one fatty acid ester and process for dyeing keratin fibers using the same |
| US7651533B2 (en) | 2005-03-31 | 2010-01-26 | Oreal | Dye composition with a reduced content of starting materials, process for dyeing keratin fibers using the same and device therefor |
| EP2879649B1 (en) | 2012-08-02 | 2018-11-07 | L'oreal | Dyeing composition comprising at least one fatty substance, at least one oxidizing agent and at least one non-ionic, anionic and amphoteric surfactant |
| EP2879649B2 (en) † | 2012-08-02 | 2022-08-24 | L'oreal | Dyeing composition comprising at least one fatty substance, at least one oxidizing agent and at least one non-ionic, anionic and amphoteric surfactant |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3693252B2 (en) | 2005-09-07 |
| JP2003040748A (en) | 2003-02-13 |
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| R081 | Change of applicant/patentee |
Effective date: 20110628 Owner name: WELLA GMBH, DE Free format text: FORMER OWNER: WELLA AKTIENGESELLSCHAFT, 64274 DARMSTADT, DE |
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