DE10129712A1 - Cosmetic composition, for e.g. hair care, contains a cationic polymer and a polymer obtained by polymerisation of unsaturated monomers in the presence of a polyalkylene oxide-containing silicone - Google Patents

Abstract

Cosmetic compositions contain cationic polymers (1) based on acrylic monomers, N-vinyl-lactams and amine-containing monomers, and polymers (2) obtained by copolymerization of ethylenically unsaturated monomers in the presence of polyalkylene oxide-containing silicone derivatives. Cosmetic compositions contain cationic polymer(s) (1) and other polymer(s) (2) in a cosmetically acceptable medium. Polymers (1) are obtained by radical copolymerization of (wt. %): (a) monomer(s) of formula (A) (50-70); (b) monomer(s) of formula (B) (5-40); (c) unsaturated monomer with amine-containing group(s) (5-40); and (d) polyalkylene oxide (PAO)-containing silicone derivative (0-5). Polymers (2) are obtained by radical copolymerization of ethylenically unsaturated monomers (e) in the presence of PAO-containing silicone derivatives (f). X = O or NR'; R' = H or 1-8C alkyl; R '' = tertiary-butyl, or 2-22C alkyl in up to 40 wt. % of monomer A (based on a, b, c and d); and n = 1-3.

Description

The invention relates to a cosmetic composition, the at least one cationic polymer and at least one other than the cationic polymer Polymer contains. It also refers to a cosmetic Method, in particular a method for strengthening and / or for the hold of the hairstyle using this composition as well as the use of this composition for manufacture a cosmetic formulation for in particular the hold and / or informing the hairstyle and on the use of it Composition for the manufacture of skin cosmetics Formulations.

Among the most widespread on the cosmetics market hair cosmetic compositions, in particular those for Inform and / or for the hold of the hairstyle, differs the compositions to be atomized, the main ones from a mostly alcoholic or aqueous and one or consist of several substances.

If the compositions for strengthening and / or for holding the For hairstyle purposes, these fabrics are generally polymeric Resins whose job is to make films between your hair form, also called setting agent, mixed with various cosmetic Additives. These compositions are general either in a pressurized using a propellant Aerosol container or filled in a pump bottle.

Hair gels and foams are also known, in general before blow-drying or water waves on damp hair be applied. To get the hairstyle in shape and firm, followed by a blow drying or a water wave. These gels or foams can also contain polymers.

However, these hair cosmetic compositions are common the disadvantage, the cosmetic properties of the hair too change. So the hair can become brittle, difficult to comb be more pleasant to the touch and look pleasant lose or no longer stand. So you're looking for hair cosmetic compositions, the good cosmetic Give properties, especially with regard to the light Combability, softness and touch.

In addition, these hair cosmetic compositions also have the big disadvantage that they lead to a "flaking" effect. For the purposes of this invention, "flaking" means Property of drying the hair cosmetic composition obtained fabric, after applying a powder to the hair to build. The powder naturally falls on the shoulders or Clothing of the user or he sits on the comb or in the Brush firmly and this is disadvantageous.

So there is a need for skin and hair cosmetics Compositions, in particular hair cosmetic compositions find that do not have all of the above disadvantages and which in particular firmly strengthen the hairstyle and at the same time give good cosmetic properties, without one "Flaking" effect.

It was found that if you have special cationic Polymers combined with special, further polymers, it is possible to obtain cosmetic compositions that meet the above meet the requirements mentioned.

• a) 50 bis 70 Gew.-% eines oder mehrerer Monomeren der Formel A
  
  
  x = O, NR',
  R' = H, C₁-C₈-Alkyl,
  R" = tert.-Butyl,
• b) 5 bis 45 Gew.-% eines oder mehrerer Monomeren der Formel B
  
  
  mit n = 1 bis 3,
• c) 5 bis 40 Gew.-% eines monoethylenisch ungesättigten Monomers mit mindestens einer aminhaltigen Gruppe,
• d) 0 bis 5 Gew.-% eines polyalkylenoxid-haltigen Silikonderivats,

wobei bis zu 40 Gew.-%, bezogen auf (a), (b), (c) und (d) des Monomeren (a) durch ein Monomer der Formel A mit R" = C₂-C₂₂-Alkyl ersetzt sein können,
und das weitere Polymerisat erhältlich ist durch radikalische Copolymerisation von

• 1. ethylenisch ungesättigte Monomere in Gegenwart von
• 2. polyalkylenoxid-haltigen Silikonderivaten.

The invention relates to a cosmetic composition which contains, in a cosmetically acceptable medium, at least one cationic polymer and at least one other polymer different from the cationic polymer, the cationic polymer being obtainable by radical copolymerization of

• a) 50 to 70 wt .-% of one or more monomers of the formula A.
  
  
  x = O, NR ',
  R '= H, C ₁ -C ₈ alkyl,
  R "= tert-butyl,
• b) 5 to 45% by weight of one or more monomers of the formula B.
  
  
  with n = 1 to 3,
• c) 5 to 40% by weight of a monoethylenically unsaturated monomer with at least one amine-containing group,
• d) 0 to 5% by weight of a polyalkylene oxide-containing silicone derivative,

wherein up to 40 wt .-%, based on (a), (b), (c) and (d) of the monomer (a) can be replaced by a monomer of the formula A with R "= C ₂ -C ₂₂ alkyl can,
and the further polymer is obtainable by radical copolymerization of

• 1. ethylenically unsaturated monomers in the presence of
• 2. Silicone derivatives containing polyalkylene oxide.

Another object of the invention relates to the use this composition in hair and skin cosmetics Formulations.

Another object of the invention relates to a cosmetic Hairdressing method, in particular a method for setting and / or for the hold of the hairstyle, using the aforementioned Composition.

Another object of the invention relates to the use this composition for the manufacture of a hair cosmetic Formulation, in particular for the stop and / or that Informing the hairstyle is intended.

The cationic polymers are described in WO 00/11051.

• a) 50 bis 70 Gew.-% eines oder mehrerer Monomeren der Formel A
  
  
  x = O, NR',
  R' = H, C₁-C₈-Alkyl,
  R" = tert.-Butyl,
• b) 5 bis 45 Gew.-% eines oder mehrerer Monomeren der Formel B
  
  
  mit n = 1 bis 3,
• c) 5 bis 40 Gew.-% eines monoethylenisch ungesättigten Monomers mit mindestens einer aminhaltigen Gruppe,
• d) 0 bis 5 Gew.-% eines polyalkylenoxid-haltigen Silikonderivats,

wobei bis zu 40 Gew.-%, bezogen auf (a), (b), (c) und (d) des Monomeren (a) durch ein Monomer der Formel A mit R" = C₂-C₂₂-Alkyl ersetzt sein können. These cationic polymers can be obtained by radical copolymerization of

• a) 50 to 70 wt .-% of one or more monomers of the formula A.
  
  
  x = O, NR ',
  R '= H, C ₁ -C ₈ alkyl,
  R "= tert-butyl,
• b) 5 to 45% by weight of one or more monomers of the formula B.
  
  
  with n = 1 to 3,
• c) 5 to 40% by weight of a monoethylenically unsaturated monomer with at least one amine-containing group,
• d) 0 to 5% by weight of a polyalkylene oxide-containing silicone derivative,

wherein up to 40 wt .-%, based on (a), (b), (c) and (d) of the monomer (a) can be replaced by a monomer of the formula A with R "= C ₂ -C ₂₂ alkyl can.

Preferred monomers (a) are compounds of the formula A in which R 'is H and CH ₃ and XO and NH; tert-butyl acrylate, N-tert-butyl acrylamide and / or tert-butyl methacrylate are particularly preferred.

Monomer I can also be made from mixtures with different R 'and X are significant, preferably the monomers (a) with the meaning X = NR 'referred only in amounts up to 20 wt .-% on (a), (b) and (c).

The monomer (a) is preferably used in amounts of 51 to 65% by weight, Monomer (b) preferably in amounts of 5 to 39% by weight and monomer (c) preferably used in amounts of 10 to 30% by weight.

In the context of the present invention, the term "C ₂ -C ₂₂ alkyl" includes straight-chain, branched and cyclic alkyl groups. These are preferably straight-chain and in particular branched alkyl groups.

The following compounds are preferred as the monomer of the formula A in which R "= C ₂ -C ₂₂ -alkyl:
N-butyl (meth) acrylate, n-octyl (meth) acrylate, 1,1,3,3-tetramethylbutyl (meth) acrylate, ethylhexyl (meth) acrylate, n-nonyl (meth) acrylate, n-decyl (meth ) acrylate, n-undecyl (meth) acrylate, tridecyl (meth) acrylate, myristyl (meth) acrylate, pentadecyl (meth) acrylate, pamityl (meth) acrylate, heptadecyl (meth) acrylate, nonadecyl (meth) acrylate, Arrachinyl (meth) acrylate, behenyl (meth) acrylate, lignocerenyl (meth) acrylate, cerotinyl (meth) acrylate, melissinyl (meth) acrylate, palmitoeinyl (meth) acrylate, oleyl (meth) acrylate, linolyl (meth) - acrylate, stearyl (meth) acrylate, lauryl (meth) acrylate and mixtures thereof as well as n-tert-butyl (meth) acrylamide, n-octyl (meth) acrylamide, 1,1,3,3-tetramethylbutyl- ( meth) acrylamide, ethylhexyl (meth) acrylamide, n-nonyl (meth) acrylamide, n-decyl (meth) acrylamide, n-undecyl (meth) acrylamide, tridecyl- (meth) acrylamide, myristyl (meth) acrylamide, pentadecyl (meth ) acrylamide, palmityl (meth) acrylamide, heptadecyl (meth) acrylamide, nonadecyl (meth) acrylamide, arrachinyl (meth) acrylamide, behenyl (meth) acrylam id, lignocerenyl (meth) acrylamide, cerotinyl (meth) acrylamide, melissinyl (meth) acrylamide, palmitoleinyl (meth) acrylamide, oleyl (meth) acrylamide, linolyl (meth) acrylamide, stearyl (meth) acrylamide, lauryl (meth) acrylamide and mix of them.

The following are very particularly preferred:
N-butyl (meth) acrylate, n-octyl (meth) acrylamide, lauryl acrylic (meth) acrylate and stearyl (meth) acrylate, the term "(meth) acrylate" including the methacrylates and acrylates.

Monomers (b) are compounds of structure B


with n = 1 to 3,
vinylpyrrolidone (VP), vinylcaprolactam (VCap) or mixtures thereof are preferred.

A part of (B), up to 4% by weight, based on the total (a) + (b) + (c), can be replaced by a hydrophilic nonionic monomer of structure B '


R = H, CH ₃
X = O, NH
m = 0 to 50
n = 0 to 50
m + n ≥ 5
R "= H, C ₁ -C ₂₂ alkyl or phenyl.

In the formula B ', R "preferably denotes a hydrogen atom and a C _1-4 alkyl group, with a methyl group being particularly preferred. Examples of such a (meth) acrylate monomer include hydroxy (meth) acrylate, hydroxypropyl (meth) acrylate, polyethylene glycol mono (meth) acrylate, polypropylene glycol mono (meth) acrylate, methoxypolyethylene glycol (meth) acrylate, methoxypolypropylene glycol mono (meth) acrylate, ethoxypolyethylene glycol mono (meth) acrylate, butoxypolyethylene glycol mono (meth) acrylate and phenoxypolyethylene glycol mono (meth) acrylate.

Monomers which are used as monomers (c) are: at least one monoethylenically unsaturated group and at least have an amine-containing group.

Preferred monomers (c) are compounds represented by the following general structure


in which
R '= H, CH ₃
X = O, NH R ''',R''''= the same or different and for CH ₃ , -C ₂ H ₅ , -C ₃ H ₇ , -C ₄ H ₉ , -tert.-C ₄ H _{9 can} stand
p = 1 to 5.

• - N,N-Dimethylaminoethyl(meth)acrylat
• - N,N-Dimethylaminopropyl(meth)acrylat
• - N,N-Dimethylaminoethyl(meth)acrylamid
• - N,N-Dimethylaminopropyl(meth)acrylamid.

Particularly suitable monomers (c) are:

• - N, N-dimethylaminoethyl (meth) acrylate
• - N, N-dimethylaminopropyl (meth) acrylate
• - N, N-dimethylaminoethyl (meth) acrylamide
• - N, N-dimethylaminopropyl (meth) acrylamide.

• - N,N-Dimethylaminoethylmethacrylat
• - N,N-Dimethylaminoethylmethacrylamid
• - N,N-Dimethylaminopropylmethacrylamid.

Particularly suitable monomers (c) are:

• - N, N-dimethylaminoethyl methacrylate
• - N, N-dimethylaminoethyl methacrylamide
• - N, N-dimethylaminopropyl methacrylamide.

The monomers (c) are used in amounts of 5 to 40, preferably 10 to 30 wt .-% used.

The monomers of groups (a) to (d) can each individually or used in a mixture with other monomers from the same group become.

• a) tert.-Butylacrylat, N-tert.-Butyl-acrylamid und/oder tert.- Butylmethacrylat, insbesondere tert.-Butylacrylat
• b) Vinylpyrrolidon und/oder Vinylcaprolactam
• c) Dimethylaminoalkyl(meth)acrylat und/oder Dimethylaminoalkyl(meth)acrylamid
• d) polyalkylenoxidhaltigem Silikonderivat.

Cationic polymers which are obtainable by free-radical polymerization of are particularly preferred

• a) tert-butyl acrylate, N-tert-butyl acrylamide and / or tert-butyl methacrylate, especially tert-butyl acrylate
• b) vinyl pyrrolidone and / or vinyl caprolactam
• c) dimethylaminoalkyl (meth) acrylate and / or dimethylaminoalkyl (meth) acrylamide
• d) polyalkylene oxide-containing silicone derivative.

• a) 51 bis 65 Gew.-% tert.-Butylacrylat, N-tert.-Butylacrylamid und/oder tert.-Butylmethacrylat, insbesondere tert.-Butylacrylat
• b) 10 bis 30 Gew.-% Vinylpyrrolidon und/oder Vinylcaprolactam
• c) 10 bis 30 Gew.-% Dimethylaminoalkyl(meth)acrylat und/oder Dimethylaminoalkyl(meth)acrylamid
• d) 0,1 bis 5 Gew.-% polyalkylenoxidhaltigem Silikonderivat

mit der Maßgabe, dass sich die Mengen zu 100% addieren. Cationic polymers which are obtainable by are particularly preferred

• a) 51 to 65 wt .-% tert-butyl acrylate, N-tert-butyl acrylamide and / or tert-butyl methacrylate, especially tert-butyl acrylate
• b) 10 to 30% by weight of vinyl pyrrolidone and / or vinyl caprolactam
• c) 10 to 30% by weight of dimethylaminoalkyl (meth) acrylate and / or dimethylaminoalkyl (meth) acrylamide
• d) 0.1 to 5 wt .-% polyalkylene oxide-containing silicone derivative

with the proviso that the amounts add up to 100%.

The polymers can be prepared according to those known per se Process of free radical polymerization, e.g. B. by Solution polymerization, emulsion polymerization, Suspension polymerization, precipitation polymerization, reverse Suspension polymerization or reverse emulsion polymerization take place without that the methods that can be used are limited to this.

The preparation is preferably carried out as solution polymerization in solvents such as water, methanol, ethanol, isopropanol or mixtures of these solvents. You choose the quantities Monomers and solvents expediently such that 30 to 70% by weight solutions are formed.

The polymerization usually takes place at temperatures of 50 to 140 ° C and at normal pressure or under autogenous pressure.

As initiators for radical polymerization, the the usual water-soluble and water-insoluble peroxo- and / or azo compounds are used, for example Alkali or ammonium peroxydisulfates, dibenzoyl peroxide, tert.- Butyl perpivalate, tert-butyl per-2-ethylhexanoate, Di-tert-butyl peroxide, tert-butyl hydroperoxide, azo-bis-isobutyronitrile, Azobis (2-amidinopropane) dihydrochloride or 2,2'-azobis (2-methylbutyronitrile). Initiator mixtures or redox Initiator systems like Ascorbic acid / iron (II) sulfate / sodium peroxodisulfate, tert-butyl hydroperoxide / sodium sulfite, tert-butyl hydroperoxide / sodium hydroxymethanesulfinate. The initiators can are used in the usual amounts, for example in Amounts of 0.05 to 5 wt .-%, based on the amount of polymerizing monomers.

The cosmetic compositions can contain 0.1 to 30% by weight, preferably 0.2 to 20% by weight of the cationic polymer contain.

The polymers are preferred either with a monovalent Acid or with a polyvalent acid or with a Polycarboxylic acid, partially or neutralized, or with one Quaternizing agent (alkyl halide or dialkyl sulfate) in the usual way quaternized.

The polymer is in particular with phosphoric acid or Acid mixture partially or completely neutralized with phosphoric acid.

Organic acids, mono-, di-, tricarboxylic acids (e.g. fatty acid, lactic acid, tartaric acid, citric acid) or mineral acids (e.g. hydrochloric acid, H ₂ SO ₄ , H ₃ PO ₄ ) can be used as acids.

To keep the residual vinyl lactam (VP or VCap) low obtained, the product solution after the polymerization with 2,5-Dimethyl-2,5-di (tert-butylperoxy) hexane (Trigonox 101) post-polymerized at approx. 130 ° C / 3-10 h. With that the remaining salary of vinyl lactam monomers reduced to <100 ppm.

The polymers preferably have a glass transition temperature of above 25 ° C and a K value of 25 to 70, preferably 25 to 50 (measured according to Fikentscher).

A particularly suitable additive for the polymers according to the invention are fatty acid amides, in particular those with a chain length of C ₁₂ -C ₂₂ . Erucic acid amide and stearic acid amide are particularly preferred. The fatty acid amides are used in an amount of up to 0.1% by weight, based on the polymer.

These differ from the cationic polymers Polymers are described in WO 99/04750.

The other polymers are water-soluble or water dispersible, or in the event that they are made from monomers neutralizable residues exist, water-soluble in neutralized form or water dispersible.

For the purposes of the invention, "water-dispersible" means polymers meant that in contact with water within 24 hours Form fluid that is not visible to the eye without optical aids solid particles can be recognized. To check if a polymer is water dispersible, 100 mg of the polymer in the form of a 100 µm thick film in 100 ml of water (20 ° C) and placed on a commercial shaking table shaken for 24 hours. If after shaking, no more solid particles are visible, that Fluid is turbid, however, is the polymer water-dispersible; without cloudiness it is said to be water soluble.

The silicone compounds are not during the polymerization present, but are mixed in after the polymerization, so you usually get very soft sticky films that are for the Applications according to the invention in hair cosmetics unsuitable are.

This indicates that it is during the polymerization possibly to graft the polymers onto the Silicone compounds can come, and this has good film properties such as freedom from tack, high surface smoothness and hardness. It mechanisms other than grafting are also conceivable, through which the inventive polymers to their advantageous Properties come.

Suitable polymerizable monomers (e) can be preferred ethylenically unsaturated monomers can be used. It can either a single monomer or combinations of two or more monomers are used. By polymerizable is meant that the monomers used using any conventional synthetic method can be polymerized.

For example, this can be solution polymerization, Emulsion polymerization, reverse emulsion polymerization, Suspension polymerization, reverse suspension polymerization or Precipitation polymerization, without the methods used on it are limited. In solution polymerization, water, usual organic solvents or those according to the invention Silicone derivatives themselves can be used as solvents.

Monomers that are initiated with a free radical Reaction can be polymerized are preferred. The term ethylenically unsaturated means that the monomers at least a polymerizable carbon-carbon double bond possess, which can be mono-, di-, tri-, or tetrasubstituted.

The monomers (e) of the polysiloxane-containing polymers of present invention can from 50 to 99.9 wt .-%, preferably 70 Make up to 99 wt .-%, particularly preferably 85 to 98 wt .-%.

The preferred ethylenically unsaturated monomers (e) can be described by the following general formula:

XC (O) CR ⁷ = CHR ⁶

in which
X is selected from the group consisting of -OH, -OM, -OR ⁸ , NH ₂ , -NHR ⁸ , N (R ⁸ ) ₂ ;
M is a cation selected from the group consisting of: Na +, K +, Mg ++, Ca ++, Zn ++, NH4 +, alkylanmonium, dialkylammonium, trialkylammonium and tetraalkylammonium;
the radicals R ⁸ can be selected identically or differently from the group consisting of -H, C ₁ -C ₄₀ linear or branched-chain alkyl radicals, N, N-dimethylaminoethyl, 2-hydroxyethyl, 2-methoxyethyl, 2-ethoxyethyl, hydroxypropyl, methoxypropyl or ethoxypropyl.

R ⁷ and R ⁶ are independently selected from the group consisting of: -H, C ₁ -C ₈ linear or branched chain alkyl chains, methoxy, ethoxy, 2-hydroxyethoxy, 2-methoxyethoxy and 2-ethoxyethyl.

Representative but not limiting examples of suitable ones Monomers (e) are, for example, acrylic acid and its salts, esters and amides. The salts can be of any non-toxic Metal, ammonium or substituted ammonium counterions be derived.

The esters can be derived from C ₁ -C ₄₀ linear, C ₃ -C ₄₀ branched, or C ₃ -C ₄₀ carbocyclic alcohols, from polyfunctional alcohols with 2 to about 8 hydroxyl groups such as ethylene glycol, hexylene glycol, glycerol, and 1,2, 6-hexanetriol, from amino alcohols or from alcohol ethers such as methoxyethanol and ethoxyethanol or polyethylene glycols.

Also suitable are N, N-dialkylaminoalkyl acrylates and methacrylates and N-dialkylaminoalkyl acrylates and methacrylamides of the general formula (II)


with R ⁹ = H, alkyl with 1 to 8 C atoms,
R ¹⁰ = H, methyl,
R ¹¹ = alkylene with 1 to 24 carbon atoms, optionally substituted by alkyl,
R ¹² , R ¹³ = C ₁ -C ₄₀ alkyl radical,
Z = nitrogen for x = 1 or oxygen for x = 0.

The amides can be unsubstituted, N-alkyl or N-alkylamino monosubstituted, or N, N-dialkyl-substituted or N, N-dialkylamino, where the alkyl or alkylamino groups of C ₁ -C ₄₀ linear, C ₃ -C ₄₀ branched, or C ₃ -C ₄₀ carbocyclic units are derived. In addition, the alkylamino groups can be quaternized.

Preferred monomers of formula II are N, N-dimethylaminomethyl (meth) acrylate, N, N-diethylaminomethyl (meth) acrylate, N, N-dimethylaminoethyl (meth) acrylate, N, N-diethylaminoethyl (meth) acrylate.

Monomers (e) which can also be used are substituted acrylic acids and salts, esters and amides thereof, where the substituents on the carbon atoms are in the two or three positions of acrylic acid and are selected independently of one another from the group consisting of C ₁ -C ₄ -alkyl , -CN, COOH particularly preferably methacrylic acid, ethacrylic acid and 3-cyanoacrylic acid. These salts, esters and amides of these substituted acrylic acids can be selected as described above for the salts, esters and amides of acrylic acid.

Other suitable monomers (e) are vinyl and allyl esters of C ₁ -C ₄₀ linear, C ₃ -C ₄₀ branched chain or C ₃ -C ₄₀ carbocyclic carboxylic acids (e.g. vinyl acetate, vinyl propionate, vinyl neononanoate, vinyl neoundecanoic acid or t-butyl benzoic acid vinylester); Vinyl or allyl halides, preferably vinyl chloride and allyl chloride, vinyl ethers, preferably methyl, ethyl, butyl or dodecyl vinyl ether, vinylformamide, vinyl methylacetamide, vinylamine; Vinyl lactams, preferably vinyl pyrrolidone and vinyl caprolactam, vinyl or allyl-substituted heterocyclic compounds, preferably vinyl pyridine, vinyl oxazoline and allyl pyridine.

N-vinylimidazoles of the general formula III are furthermore suitable, in which R ¹⁴ to R ¹⁶ independently of one another are hydrogen, C ₁ -C ₄ -alkyl or phenyl:

Further suitable monomers (e) are diallylamines of the general formula (IV)


with R ¹⁷ = C ₁ to C ₂₄ alkyl.

Other suitable monomers (e) are vinylidene chloride; and Hydrocarbons with at least one carbon-carbon Double bond, preferably styrene, alpha-methylstyrene, tert-butylstyrene, Butadiene, isoprene, cyclohexadiene, ethylene, propylene, 1-butene, 2-butene, isobutylene, vinyl toluene, and mixtures of these Monomers.

Particularly suitable monomers (e) are acrylic acid, methacrylic acid, ethyl acrylic acid, methyl acrylate, ethyl acrylate, propyl acrylate, n-butyl acrylate, iso-butyl acrylate, t-butyl acrylate, 2-ethylhexyl acrylate, decyl acrylate, methyl methacrylate, ethyl methacrylate, butyl methacrylate, nyl butyl acrylate , t-butyl methacrylate, 2-ethylhexyl methacrylate, decyl methacrylate, methyl ethacrylate, ethyl ethacrylate, n-butyl ethacrylate, iso-butyl ethacrylate, t-butyl ethacrylate, 2-ethylhexyl ethacrylate, decyl ethacrylate, 2,3-dihydroxypropyl acrylate, 2,3-dihydroxyl hydroxyl methacrylate, hydroxyl acrylate , 2-hydroxyethyl methacrylate, 2-hydroxyethyl ethacrylate, 2-methoxyethyl acrylate, 2-methoxyethyl methacrylate, 2-methoxyethyl ethacrylate, 2-ethoxyethyl methacrylate, 2-ethoxyethyl ethacrylate, hydroxypropyl methacrylate, glyceryl monoacrylate, glyceryl monomethacrylate, polyalkylene acid, such as sulfonated acrylate (meth) acrylate, for example,
Acrylamide, methacrylamide, ethacrylamide, N-methyl acrylamide, N, N-dimethylacrylamide, N-ethyl acrylamide, N-isopropylacrylamide, N-butylacrylamide, Nt-butylacrylamide, N-octylacrylamide, Nt-octylacrylamide, N-octadecylacrylamide, N-phenylacrylamide Methyl methacrylamide, N-ethyl methacrylamide, N-dodecyl methacrylamide, 1-vinylimidazole, 1-vinyl-2-methylimidazole, N, N-dimethylaminomethyl (meth) acrylate, N, N-diethylaminomethyl (meth) acrylate, N, N-dimethylaminoethyl (meth) acrylate, N, N-diethylaminoethyl (meth) acrylate, N, N-dimethylaminobutyl (meth) acrylate, N, N-diethylaminobutyl (meth) acrylate, N, N-dimethylaminohexyl (meth) acrylate, N, N-dimethylaminooctyl (meth) acrylate, N, N-dimethylaminododecyl (meth) acrylate, N- [3- (dimethylamino) propyl] methacrylamide, N- [3- (dimethylamino) propyl] acrylamide, N- [3- (dimethylamino) butyl] methacrylamide, N- [8- (dimethylamino) octyl] methacrylamide, N- [12- (dimethylamino) dodecyl] methacrylamide, N- [3- (diethylamino) propyl] methacrylamide, N- [3- (diethylamino) propyl] acrylamide;
Maleic acid, fumaric acid, maleic anhydride and its half esters, crotonic acid, itaconic acid, diallyldimethylammonium chloride, vinyl ether (for example: methyl, ethyl, butyl or dodecyl vinyl ether), vinyl formamide, vinyl methylacetamide, vinylamine; Methyl vinyl ketone, maleimide, vinyl pyridine, vinyl imidazole, vinyl furan, styrene, styrene sulfonate, allyl alcohol, and mixtures thereof.

Of these, acrylic acid, methacrylic acid, Maleic acid, fumaric acid, crotonic acid, maleic anhydride as well its half ester, methyl acrylate, methyl methacrylate, ethyl acrylate, Ethyl methacrylate, n-butyl acrylate, n-butyl methacrylate, t-butyl acrylate, t-butyl methacrylate, isobutyl acrylate, Isobutyl methacrylate, 2-ethylhexyl acrylate, N-t-butyl acrylamide, N-octylacrylamide, 2-hydroxyethyl acrylate, hydroxypropyl acrylate, 2-hydroxyethyl methacrylate, hydroxypropyl methacrylate, alkylene glycol (meth) - acrylates, unsaturated sulfonic acids such as Acrylamidopropanesulfonic acid, vinyl pyrrolidone, vinyl caprolactam, vinyl ether (e.g .: methyl, ethyl, butyl or dodecyl vinyl ether), Vinylformamide, vinylmethylacetamide, vinylamine, 1-vinylimidazole, 1-vinyl-2-methylimidazole, N, N-dimethylaminomethyl methacrylate and N- [3- (dimethylamino) propyl] methacrylamide; 3-methyl-1-vinylimidazolium chloride, 3-methyl-1-vinylimidazolium methyl sulfate, N, N-dimethylaminoethyl methacrylate, N- [3- (dimethylamino) propyl] - methacrylamide quaternized with methyl chloride, methyl sulfate or Diethyl sulfate.

Monomers with a basic nitrogen atom can can be quaternized as follows:

For the quaternization of the amines, for example, are suitable Alkyl halides with 1 to 24 carbon atoms in the alkyl group, e.g. B. Methyl chloride, methyl bromide, methyl iodide, ethyl chloride, ethyl bromide, Propyl chloride, hexyl chloride, dodecyl chloride, lauryl chloride and Benzyl halides, especially benzyl chloride and benzyl bromide. Other suitable quaternizing agents are dialkyl sulfates, especially dimethyl sulfate or diethyl sulfate. The quaternization The basic amines can also be mixed with alkylene oxides such as ethylene oxide or propylene oxide in the presence of acids. Preferred quaternizing agents are: methyl chloride, Dimethyl sulfate or diethyl sulfate.

The quaternization can take place before the polymerization or after the Polymerization can be carried out.

In addition, the reaction products of unsaturated acids, such as. As acrylic acid or methacrylic acid, with a quaternized epichlorohydrin of the general formula (V) can be used (R ¹⁸ = C ₁ - to C ₄₀ -alkyl).

Examples include: (Meth) acryloyloxyhydroxypropyltrimethylammonium chloride and (Meth) acryloyloxyhydroxypropyltriethylammonium chloride.

The basic monomers can also be cationized by with mineral acids, such as. B. sulfuric acid, hydrochloric acid, Hydrobromic acid, hydroiodic acid, phosphoric acid or Nitric acid, or with organic acids, such as. B. Formic acid, acetic acid, lactic acid, or citric acid, neutralized become.

In addition to the above monomers can be used as monomers (e) so-called macromonomers such as silicone-containing ones Macromonomers with one or more radically polymerizable Groups or alkyloxazoline macromonomers are used as they are are described for example in EP 408 311.

Furthermore, fluorine-containing monomers such as, for example are described in EP 558423, crosslinking or the molecular weight regulating compounds in combination or be used alone.

The usual ones known to the person skilled in the art can be used as regulators Compounds such as sulfur compounds (e.g .: Mercaptoethanol, 2-ethylhexylthioglycolate, thioglycolic acid or Dodecyl mercaptan) and tribromochloromethane or other compounds regulating the molecular weight of the polymers obtained act, are used.

It may also contain thiol groups Silicone compounds are used.

Silicone-free controllers are preferably used.

Crosslinking monomers include compounds with at least two ethylenically unsaturated double bonds can be used like for example esters of ethylenically unsaturated carboxylic acids, such as acrylic acid or methacrylic acid and polyhydric alcohols, Ethers of at least dihydric alcohols such as Vinyl ether or allyl ether. Straight-chain are also suitable or branched, linear or cyclic aliphatic or aromatic hydrocarbons over at least two Have double bonds, which in the aliphatic Hydrocarbons must not be conjugated. Amides are also suitable of acrylic and methacrylic acid and N-allylamines of at least divalent amines such as (1,2-diaminoethane, 1,3-diaminopropane). Also triallylamine or equivalent Ammonium salts, N-vinyl compounds of urea derivatives, at least divalent amides, cyanurates or urethanes. Further suitable crosslinkers are divinyldioxane, tetraallylsilane or Tetravinylsilane.

Particularly preferred crosslinkers are, for example Methylenebisacrylamide, triallylamine and triallylammonium salts, Divinylimidazole, N, N'-divinylethylene urea, reaction products polyhydric alcohols with acrylic acid or methacrylic acid, Methacrylic acid esters and acrylic acid esters of polyalkylene oxides or polyhydric alcohols with ethylene oxide and / or propylene oxide and / or Epichlorohydrin have been implemented.

In the polymerization of the monomers (e), if appropriate also other polymers such as polyamides, polyurethanes, Polyesters, homo- and copolymers of ethylenically unsaturated Monomers are present. Examples of such in part in the Polymers used in cosmetics are those under the trade names well-known polymers Amerhold ™, Ultrahold ™, Ultrahold Strong ™, Luviflex ™ VBM, Luvimer ™, Acronal ™, Acudyne ™, Stepanhold ™, Lovocryl ™, Versatyl ™, Amphomer ™ or Eastma AQ ™.

Such or other polymers can also be used after the polymerization can be added to the polymer preparations according to the invention.

The monomers A according to the invention can, provided that they are ionizable Groups contain, before or after the polymerization, in part or be completely neutralized with acids or bases for example, water solubility or dispersibility to set a desired dimension.

As a neutralizing agent for monomers bearing acid groups For example, mineral bases such as sodium carbonate, Alkali hydroxides and ammonia, organic bases such as amino alcohols especially 2-amino-2-methyl-1-propanol, monoethanolamine, Diethanolamine, triethanolamine, triisopropanolamine, tri [(2-hydroxy) 1- Propyl] amine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-hydroxymethyl-1,3-propanediol and diamines such as lysine be used.

As a neutralizing agent for cationizable groups Monomers can, for example, mineral acids such as hydrochloric acid, Sulfuric acid or phosphoric acid, and organic acids such as Carboxylic acids, lactic acid, citric acid or others are used become.

Auxiliaries such as plasticizers, Film forming aids, pigments, perfumes or others, alone or in Combination, to be present during the polymerization and / or after be added to the polymerization.

When using the polymers according to the invention in the It is hair cosmetics, especially when used as a setting agent advantageously the glass transition temperature of the polymers by suitable Combination of ethylenically unsaturated monomers on values higher than 20 ° C.

Suitable silicone derivatives (f) and / or (d) are those under the INCI name known as Dimethicone Copolyole or silicone surfactant Connections such as those under the brand names Abil® (from T. Goldschmidt), Alkasil® (from Rhône-Poulenc), Silicone Polyol Copolymer® (from Genesee), Belsil® (from Fa. Wacker), Silwet® (from Witco, Greenwich, CT, USA) or Dow Corning (from Dow Corning) available These include Compounds with CAS numbers 64365-23-7; 68937-54-2; 68938-54-5; 68937-55-3.

Particularly suitable monomers (f) and / or (d) are those which contain the following structural elements:


in which:




R ^{6 is} an organic radical of 1 to 40 carbon atoms, which may contain amino, carboxylic acid or sulfonate groups or, if c = O, also means the anion of an inorganic acid, and where the radicals R ^{1 may be} identical or different, and either come from the group of aliphatic hydrocarbons with 1 to 20 carbon atoms, are cyclic aliphatic hydrocarbons with 3 to 20 C atoms, are aromatic in nature or are equal to R ⁵ , where:


with the proviso that at least one of the radicals R ¹ , R ² or R ^{3 is} a polyalkylene oxide-containing radical as defined above,
and n is an integer from 1 to 6,
x and y are integers such that the molecular weight of the polysiloxane block is between 300 and 30,000,
a, b can be integers between 0 and 50 with the proviso that the sum of a and b is greater than 0 and C is 0 or 1.

Preferred radicals R ² and R ⁵ are those in which the sum of a + b is between 5 and 30.

The groups R ¹ are preferably selected from the following group: methyl, ethyl, propyl, butyl, isobutyl, pentyl, isopentyl, hexyl, octyl, decyl, dodecyl and octadecyl, cycloaliphatic radicals, especially cyclohexyl, aromatic groups, especially phenyl or naphthyl, mixed aromatic-aliphatic radicals such as benzyl or phenylethyl as well as tolyl and xylyl and R ⁵ .

Particularly suitable radicals R ⁴ are those in which, in the case of R ⁴ = - (CO) _c -R ⁶ R ⁶ , denotes any alkyl, cycloalkyl or aryl radical which has between 1 and 40 C atoms and which has further ionogenic groups like NH ₂ , COOH, SO ₃ H can wear.

Preferred inorganic radicals R ⁶ are, for the case c = O, phosphate and sulfate.

Particularly preferred silicone derivatives (f) and / or (d) are those of the general structure:

The silicone derivatives (f) and / or (d) are usually in quantities from 0.1 to 50, preferably from 1 to 20, particularly preferably from Contain 2-15 wt .-% in the polymer according to the invention.

Particularly suitable polymers are those that are water-soluble are or whose water dispersibility is so great that they are in a solvent mixture water: ethanol = 50:50 (vol .-%: vol .-%) in an amount of more than 0.1 g / l, preferably more than 0.2 g / l, are soluble.

In the event that the polymers consist of monomers which Carrying neutralizable residues are such polymers preferred, which in the neutralized form in one Solvent mixture water: ethanol = 50:50 (vol .-%: vol .-%) in one amount of more than 0.1 g / l, preferably more than 0.2 g / l, are soluble.

A particularly preferred further polymer is, for example a under the trade name Luviflex ™ Silk (INCI name: PEG / PPG-25/25 Dimethicone / acrylates / t-butyl acrylates; BASF Aktiengesellschaft) available polymer.

The composition advantageously contains 0.01 to 20% by weight and preferably 0.05 to 10% by weight of further polymer, based on the preparation.

The cosmetically acceptable medium preferably consists of water and one or more cosmetically acceptable solvents, such as alcohols or water-solvent mixtures, these Solvents are preferably alcohols with 1 to 4 carbon atoms.

Of these alcohols, ethanol and isopropanol can be named. Ethanol is particularly preferred.

The composition of the invention can also be at least an additive selected from the group consisting of Surfactants other than those of the invention, the perfumes, the filters, the Preservatives, vitamins, polymers other than those of the invention, the vegetable, the mineral or synthetic Oils other than those of the invention, thickeners, and any any other classically in cosmetic Contain compositions used additive.

Of course, the specialist will take care that the Possible composition (s) to be added according to the invention Select connection (s) so that the intrinsically with the Composition related to the invention Properties due to the planned addition not or not substantially to be changed.

These compositions can be in different forms, filled in particular in pump bottles or in aerosol containers to apply the composition in atomized form or in the form of foam. Such filling forms are appropriate, for example, if you have a spray, a paint or a foam for setting or for treating the hair would like to receive. The compositions according to the invention can also in the form of a cream, a gel, an emulsion, a Lotion or wax.

If the composition according to the invention in the form of an aerosol filled to get a varnish or foam, it contains at least one blowing agent that is among the volatile Hydrocarbons such as B. n-butane, propane, isobutane, pentane, a halogenated hydrocarbon and mixtures thereof can be selected. You can also use carbon dioxide gas Nitric oxide, dimethyl ether (DME), nitrogen, compressed air use as a blowing agent. You can also use blowing agent mixtures use. Dimethyl ether is preferably used.

The blowing agent is advantageously in a concentration between 5 and 90 wt .-%, based on the total weight of the Composition, in the aerosol device and in particular in a concentration between 10 and 60%.

The compositions according to the invention can also be used in cosmetic preparations are used to care for the skin. The skin care products are in particular as W / O or O / W skin creams, day and night creams, eye creams, face creams, Anti-wrinkle creams, moisturizing creams, bleaching creams, vitamin creams, Skin lotions, care lotions and moisturizing lotions. The compositions according to the invention can be applied to the Skin, nails, lips, hair, eyebrows and the Eyelashes are applied.

The compositions according to the invention are especially for dry or damp hair as hairdressing products suitable.

All percentages are relative percentages in weight, based on the total weight of the composition, and m. a. means matière active (active ingredient).

Examples 1 to 22 Cationic polymers example 1

Feed 1: 1200 g of monomer mixture of 612 g of tert-butyl acrylate, 120 g of dimethylaminopropylacrylamide and 468 g of vinyl pyrrolidone
Feed 2: 2.4 g of Wako V59 = 2,2'-azobis (2-methylbutyronitrile) in 450 g of ethanol
Feed 3: 3.6 g Wako V59 in 90 g ethanol
Feed 4: 77 g of 40% phosphoric acid (in ethanol)

A mixture of 240 g of feed 1, 60 g of feed 2 and 270 g of ethanol was heated to 75 ° C. After the polymerization started, recognizable by an increase in viscosity, the rest of the Feed 1 in 4 h and feed 2 in 5 h at 78 ° C. with stirring added and 4 g polymerized at 80 ° C. After dosing From feed 3 in 1/2 h, the product became 8 g / 80 ° C afterpolymerized. At a temperature of about 40 ° C with stirring Feed 4 metered in in about 30 minutes. You got a clear one light yellow solution.

The other products in the following table can be produced analogously. The polymers have a K value (measured in 1% ethanolic solution) of 37 to about 45 and a Pro / Bu compatibility> 60%. Examples

TBA: tert-butyl acrylate
TMBA: tert-butyl methacrylate
NtBAM: tert-butyl acrylamide
SMA: stearin methacrylate
VP: vinyl pyrrolidone
VCap: vinyl caprolactam
DMAPMA: dimethylaminopropyl methacrylamide

Example 14 (TBA: DMAPMA: VP: SMA: Balsil = 50.5: 15: 28: 6: 0.5)

• 1. 2.4 g of Belsil® DMC 6031 (Wacker), 6 g of water and 64 g of ethanol were introduced into the polymerization kettle which had been flushed with N ₂ .
• 2. The solution was warmed to 75 ° C and stirred.
• 3. 242.4 g TBA, 72 g DMAPMA, 134.3 g VP and 28.8 g SMA added.
• 4. 1 g of 2,2'-azobis (2-methylbutyronitrile) (V-59, WAKO), dissolved in 170 g of ethanol were added.
• 5. After a temperature of 70 ° C has been reached 96 g of the monomer feed and 17 g of the initiator solution added.
• 6. The remaining monomer feed and initiator addition were added within 4 to 5 hours.
• 7. After the end of the feed, 2 hours at 80 ° C. touched.
• 8. If necessary after treatment with hydrogen peroxide and The polymer was activated carbon with lactic acid neutralized.

The following polymers (Examples 15 to 22) were prepared analogously to Example 14. table

Examples 23-29

50 g of feed 1 and 3.75 g of feed 2 are added dropwise to a stirred receiver. The mixture is then heated to 78 ° C. The rest of feed 1 and feed 2 are then added dropwise within 1.5 h. The mixture is stirred for a further 2 h. Then feed 3 is within 15 min. added dropwise and stirred at 78 ° C for 3 h. Example 23 Template: 175 g ethanol, 7.5 g Dow Corning 190 ™
Feed 1: 251 g of t-butyl acrylate, 86 g of methacrylic acid, 37 g of ethyl acrylate, 75 g of ethanol
Feed 2: 2 g of t-butyl perpivalate, 100 g of ethanol
Feed 3: 1.5 g of t-butyl perpivalate, 57 g of ethanol. Example 24 template: 175 g of ethanol, 18.75 g of Dow Corning 190 ™
Feed 1: 251 g of t-butyl acrylate, 86 g of methacrylic acid, 37 g of ethyl acrylate, 75 g of ethanol
Feed 2: 2 g of t-butyl perpivalate, 100 g of ethanol
Feed 3: 1.5 g of t-butyl perpivalate, 57 g of ethanol. Example 25 template: 175 g of ethanol, 37.5 g of Dow Corning 190 ™
Feed 1: 251 g of t-butyl acrylate, 86 g of methacrylic acid, 37 g of ethyl acrylate, 75 g of ethanol
Feed 2: 2 g of t-butyl perpivalate, 100 g of ethanol
Feed 3: 1.5 g of t-butyl perpivalate, 57 g of ethanol. Example 26 template: 175 g of ethanol, 18.75 g of Belsil DMC 6031 ™
Feed 1: 251 g of t-butyl acrylate, 86 g of methacrylic acid, 37 g of ethyl acrylate, 75 g of ethanol
Feed 2: 2 g of t-butyl perpivalate, 100 g of ethanol
Feed 3: 1.5 g of t-butyl perpivalate, 57 g of ethanol. Example 27 Template: 175 g of ethanol, 37.5 g of Belsil DMC 6031 ™
Feed 1: 279 g of t-butyl acrylate, 96 g of methacrylic acid, 75 g of ethanol
Feed 2: 2 g of t-butyl perpivalate, 100 g of ethanol
Feed 3: 1.5 g of t-butyl perpivalate, 57 g of ethanol. Example 28 template: 175 g of ethanol, 37.5 g of Belsil DMC 6032 ™
Feed 1: 300 g of t-butyl acrylate, 75 g of methacrylic acid, 75 g of ethanol
Feed 2: 2 g of t-butyl perpivalate, 100 g of ethanol
Feed 3: 1.5 g of t-butyl perpivalate, 57 g of ethanol. Example 29 template: 175 g of ethanol
Feed 1: 251 g of t-butyl acrylate, 86 g of methacrylic acid, 37 g of ethyl acrylate, 75 g of ethanol
Feed 2: 2 g of t-butyl perpivalate, 100 g of ethanol
Feed 3: 1.5 g of t-butyl perpivalate, 57 g of ethanol Examples 30 to 52

Examples 53 to 75

Claims (18)

1. Cosmetic composition which contains, in a cosmetically acceptable medium, at least one cationic polymer and at least one other polymer different from the cationic polymer, the cationic polymer being obtainable by radical copolymerization of a) 50 to 70 wt .-% of one or more monomers of the formula A.


X = O, NR ',
R '= H, C ₁ -C ₈ alkyl,
R "= tert-butyl, b) 5 to 45% by weight of one or more monomers of the formula B.


with n = 1 to 3, c) 5 to 40% by weight of a monoethylenically unsaturated monomer with at least one amine-containing group, d) 0 to 5% by weight of a polyalkylene oxide-containing silicone derivative, wherein up to 40 wt .-%, based on (a), (b), (c) and (d) of the monomer (a) can be replaced by a monomer of the formula A with R "= C ₂ -C ₂₂ alkyl can,
and the further polymer is obtainable by radical copolymerization of a) ethylenically unsaturated monomers in the presence of b) polyalkylene oxide-containing silicone derivatives. 2. Composition according to claim 1, characterized in that the cationic polymer is obtainable by radical copolymerization of a) 51 to 65% by weight of the monomer of the formula A, b) 5 to 39% by weight of the monomer of the formula B, c) 10 to 30 wt .-% of the amine-containing monomer. 3. Composition according to one of the preceding claims, characterized in that the monomer (a) tert-butyl acrylate, N-tert-butyl acrylamide and / or means tert-butyl methacrylate. 4. Composition according to one of the preceding claims, characterized in that the monomer (b) vinyl pyrrolidone and / or vinyl caprolactam. 5. Composition according to one of the preceding claims, characterized in that the monomer (c) Dimethylaminoalkyl (meth) acrylate and / or dimethylaminoalkyl (meth) acrylamide is. 6. Composition according to one of the preceding claims, characterized in that the monomers of the formula I with R "= C ₂ -C ₂₂ alkyl are N-butylacrylamide, N-octylacrylamide, lauryl (meth) acrylate or stearyl (meth ) is acrylate. 7. Composition according to one of the preceding claims, characterized in that the cationic polymer is obtainable by radical polymerization of a) tert-butyl acrylate, N-tert-butyl acrylamide and / or tert-butyl methacrylate, especially tert-butyl acrylate b) vinyl pyrrolidone and / or vinyl caprolactam c) dimethylaminoalkyl (meth) acrylate and / or dimethylaminoalkyl (meth) acrylamide d) polyalkylene oxide-containing silicone derivative. 8. Composition according to one of the preceding claims, containing a cationic polymer according to claim 1 in an amount of 0.1 to 30 wt .-% based on the preparation. 9. Composition according to one of the preceding claims, characterized in that the cationic polymer with a monovalent acid, preferably with a polyvalent Acid or a polycarboxylic acid, partially or neutralized is quaternized, or with a quaternizing agent becomes. 10. The composition according to any one of claim 9, characterized characterized in that the cationic polymer with phosphoric acid or an acid mixture with phosphoric acid partially or is completely neutralized. 11. The composition according to claim 1, characterized in that as the polyalkylene oxide-containing silicone derivatives (d) and / or (f) those of the formula I are used:


in which:




R ^{6 is} an organic radical of 1 to 40 carbon atoms, which may contain amino, carboxylic acid or sulfonate groups or, if c = O, also means the anion of an inorganic acid,
and wherein the radicals R ^{1 can be} identical or different and either come from the group of aliphatic hydrocarbons with 1 to 20 carbon atoms, are cyclic aliphatic hydrocarbons with 3 to 20 C atoms, are aromatic in nature or are equal to R ⁵ , where:


with the proviso that at least one of the radicals R ¹ , R ² or R ^{3 is} a polyalkylene oxide-containing radical as defined above,
and n is an integer from 1 to 6,
x and y are integers such that the molecular weight of the polysiloxane block is between 300 and 30,000,
a, b can be integers between 0 and 50 with the proviso that the sum of a and b is greater than 0 and c is 0 or 1. 12. The composition according to claim 11, characterized in that formula I has the following meaning:


13. The composition according to claim 1, characterized in that the further polymer is obtainable by polymerizing
50 to 99.9% by weight (s) and
0.1 to 50 wt% (f). 14. Composition according to one of the preceding claims, containing a further polymer in an amount of 0.01 up to 20 wt .-%, in particular 0.05 to 10 wt .-%, based on the preparation. 15. Composition according to one of the preceding claims, characterized in that they also have a Contains fatty acid amide. 16. Composition according to one of the preceding claims, characterized in that it also contains an additive from the group consisting of surfactants, perfumes, the filters, the preservatives, the proteins, the Vitamins, the polymers other than those of the invention, the Mineral, vegetable or synthetic oils and Contains thickeners. 17. Use of a composition according to one of claims 1 to 16 for the manufacture of a cosmetic product, especially a hair cosmetic product. 18. Use of a composition according to any one of claims 1 to 16 for the skin, the nails, the lips, the hair, the Eyebrows and eyelashes.