DE10117502A1 - Facial tissues for hair care - Google Patents

Abstract

The invention relates to the use of cosmetic towels for styling hair, said towels being characterised in that they are impregnated with a solution containing (a) film forming media and (b) cationic surfactants.

Description

Field of the Invention

The invention is in the field of hair care and relates to the use of Facial tissues for styling hair.

State of the art

Facial tissues are a form of application that are increasing in the field of personal care gaining importance. It is usually wet wipes that represent textile tissue or tissue paper, which with a cleaning or caring formulation are soaked.

Based on the cleaning desired for the first market-ready facial tissues function, care is increasingly the focus today. For example, in the international patent application WO 95/35411 wet wipes proposed, which with are impregnated with a lotion which, in addition to mineral oil, fatty acid esters, fatty alcohol ethoxylates and Contain fatty alcohols. Numerous patent applications describe cleaning wipes, at where solutions are drawn onto different tissues. More recently cloths are also available that are in dry form and moistened before use have to be described as representative in patent applications WO 99/13861 and WO 01/08657.

These wipes are primarily used for the care and cleaning of the skin. Also, if the application in the hair area is mentioned, the applications are single on cleaning or conditioning effects. They enable simple, clean and quick use, which is also desirable in the field of hair cosmetics. So would be styling applications are also conceivable in which the formulations for shaping the hair can be applied with the help of cosmetic wipes. But here comes the Schwie The fact that the manufacture of facial tissues involves the application of thin solutions required so that the preparations can be absorbed by the tissue. Styling-  However, preparations generally have gel-like cones due to the polymers they contain resistance or increased viscosity.

It is therefore an object of the present invention to provide facial tissues for styling hair to provide using well-tolerated excipients, which a tech nisch simple and inexpensive production enable.

The application form is intended for a quick, clean and even distribution of the preparation allow hair to grow. Furthermore, the wording should not be one rigid hair bonding, so that the elasticity of the hair is retained and the Application does not lead to drying out and high brittleness of the hair.

Description of the invention

The invention relates to the use of facial tissues which are characterized in that they are impregnated with a solution containing

• a) film makers and
• b) cationic surfactants

for styling hair

It was found that facial tissues, the film formers in combination with cationic Contain surfactants that perform complex tasks in an excellent way. While the Film formers responsible for the later styling of the hair enable the cationic surfactants a simple preparation of the application form, since they by the Her removing the surface tension simplify the absorption of the solution into the tissue. The impregnation solutions proved to be easy to process. The tensi also improve de the distribution of the film formers in the hair. The selected film makers had one good shaping properties with strong hold without loss of elasticity and volume of the hair or lead to increased fragility, but on the other hand set the viscosity of the impregnation solutions is only slightly high, so that the processable guaranteed. The volume of the hair and the shine remained for hours received after application. The formulation is easy to comb out, so that after lazy rinsing of the hair is not necessary.

The application form "cosmetic tissue" enables hairstyle design with a very good one mechanical distribution of the formulation in the hair, good design options and without leaving a sticky feeling. A simple and hygienic application for Shaping the hair is therefore also possible where hand washing according to conventional methods chem styling process can not be carried out.  

film formers

Common film formers are, for example, chitosan, microcrystalline chitosan, quater nated chitosan, polyvinylpyrrolidone, vinylpyrrolidone-vinyl acetate copolymers, polymers the acrylic acid series, quaternary cellulose derivatives, collagen, hyaluronic acid or its sal ze and similar compounds.

Cationic biopolymers

Chitosans, which also belong to the group of hydrocolloids, are among the best known and most preferred cationic biopolymers in the sense of the invention. From a chemical point of view, these are partially deacetylated chitins of different molecular weights, which contain the following - idealized - monomer unit (I):

The chitosans are made from chitin, preferably the shell residues from Crustaceans, which are available in large quantities as cheap raw materials. The Chitin is used for the first time by Hackmann et al. have been described is, usually initially deproteinized by adding bases, by adding mineral acids demineralized and finally deacetylated by adding strong bases, whereby the molecular weights can be distributed over a wide spectrum. Corresponding Ver Driving are made of Makromol, for example. Chem. 177, 3589 (1976) or the French known patent application FR 2701266 A1 known. Such types are preferred set as in the German patent applications DE 44 42 987 A1 and DE 195 37 001 A1 (Henkel) and which have an average molecular weight of 800,000 up to 1,200,000 Daltons, a Brookfield viscosity (1% by weight in glycolic acid) below of 5000 mPas, a degree of deacetylation in the range of 80 to 88% and an ash layer hold less than 0.3 wt .-%. In addition to the chitosans as a typical cationi In terms of the invention, biopolymers are also anionic, nonionic or cationic onically derivatized chitosans, such as. B. carboxylation, succinylation, alkoxylation or quaternization products in question, such as those in the German patent  DE 37 13 099 C2 and the German patent application DE 196 04 180 A1 become.

The term cationic biopolymers also includes related feedstocks such as gelatin, collagens and collagen breakdown products.

Cationic surfactants

Typical examples of cationic surfactants are quaternary ammonium compounds, as in for example, the dimethyl distearyl ammonium chloride, or cetyl trimethyl ammonium chloride. Ester quats, in particular quaternized fatty acid trialkanolamine ester salts, can also be used be used.

Quaternized fatty acid trietha are generally referred to as "esterquats" understood nolamine ester salts. These are known substances that can be found in the relevant methods of preparative organic chemistry can be obtained. In this To in relation to the international patent application WO 91/01295 (Henkel) after which one triethanolamine in the presence of hypophosphorous acid with fatty acid Ren partially esterified, air passed and then with dimethyl sulfate or ethylene oxide quaternized. From the German patent DE-C1 43 08 794 (Henkel) is also a Process for the preparation of solid ester quats known in which the quaternization of Triethanolamine esters in the presence of suitable dispersants, preferably fatty alcohol fetch, perform. Overviews on this topic are, for example, by R. Puchta et al. in Tens. Surf. Det., 30, 186 (1993), M. Brock in Tens. Surf. Det. 30, 394 (1993), R. Lagerman et al. in J. Am. Oil. Chem. Soc., 71, 97 (1994) and I. Shapiro in Cosm. Toil. 109, 77 (1994) appeared.

The quaternized fatty acid triethanolamine ester salts follow the formula (II)

in which R ¹ CO for an acyl radical with 6 to 22 carbon atoms, R ² and R ³ independently of one another for hydrogen or R ¹ CO, R ⁴ for an alkyl radical with 1 to 4 carbon atoms or a (CH ₂ CH ₂ O) _q H -Group, m, n and p in total for 0 or numbers from 1 to 12, q for numbers from 1 to 12 and X for halide, alkyl sulfate or alkyl phosphate. Typical examples of esterquats which can be used in the context of the invention are products based on caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, isostearic acid, stearic acid, oleic acid, elaidic acid, arachic acid, behenic acid and erucic acid and the like technical blends, such as those that occur in the pressure splitting of natural fats and oils. Technical C _12/18 coconut fatty acids and in particular partially hardened C _16/18 tallow or palm fatty acids as well as C _16/18 fatty acid cuts rich in elamidic acid are preferably used. The fatty acids and the triethanolamine can be used in a molar ratio of 1.1: 1 to 3: 1 to produce the quaternized esters. With regard to the application properties of the ester quats, an application ratio of 1.2: 1 to 2.2: 1, preferably 1.5: 1 to 1.9: 1, has proven to be particularly advantageous. The preferred ester quats represent technical mixtures of mono-, di- and triesters with an average degree of esterification of 1.5 to 1.9 and are derived from technical C _16/18 tallow or palm fatty acid (iodine number 0 to 40) , From an application point of view, quaternized fatty acid triethaolamine ester salts of the formula (II) have proven to be particularly advantageous in which R ¹ CO is an acyl radical having 16 to 18 carbon atoms, R ^{2 is} R ¹ CO, R ^{3 is} hydrogen, R ^{4 is} a methyl group , m, n and p are 0 and X is methyl sulfate.

In addition to the quaternized fatty acid triethanolamine ester salts, quaternized ester salts of fatty acids with diethanolalkylamines of the formula (III) are also suitable as esterquats,

in which R ¹ CO for an acyl radical with 6 to 22 carbon atoms, R ² for hydrogen or R ¹ CO, R ⁴ and R ⁵ independently of one another for alkyl radicals with 1 to 4 carbon atoms, m and n in total for 0 or numbers from 1 to 12 and X represents halide, alkyl sulfate or alkyl phosphate.

Finally, the quaternized ester salts of fatty acids with 1,2-dihydroxypropyl dialkylamines of the formula (IV) should be mentioned as a further group of suitable ester quats,

in which R ¹ CO for an acyl radical with 6 to 22 carbon atoms, R ² for hydrogen or R ¹ CO, R ⁴ , R ⁶ and R ⁷ independently of one another for alkyl radicals with 1 to 4 carbon atoms, m and n in total for 0 or numbers from 1 to 12 and X represents halide, alkyl sulfate or alkyl phosphate.

With regard to the selection of the preferred fatty acids and the optimal degree of esterification the examples given for (II) also apply to the esterquats of the formulas (III) and (IV). The ester quats usually come in the form of 50 to 90% by weight alcoholic solutions on the market, which can be easily diluted with water if required.

Tissue papers and tissue tissue for facial tissues

Tissue papers and tissues to which the present invention relates can be constructed in one or more layers. As a rule, the papers have a weight per square meter of 10 to 65, preferably 15 to 30 g and a density of 0.6 g / cm ³ and less.

In addition to the paper-based tissues, appropriate tissue fabrics are also possible, the be made from fiber or fleece. Examples of natural fibers include silk, Cellulose, keratin, wool, cotton, jute, linen, flak, for synthetic fibers acetate, Acrylate, cellulose ester, polyamide, polyester, polyolefin, polyvinyl alcohol, polyurethane Fibers. The use of hydrophilic fibers, natural fibers such as tree, is preferred here woolen fabrics and cotton blended fabrics are particularly preferred due to additives hydrophi gated polyolefin fabric. Reaction products of 1 part of polyethylene glycol with 2 parts of fat Acids with 10 to 12 carbon atoms or their derivatives are used to hydrophilize the Fabric containing polyolefin used.

The fabric can be in the form of gloves and is then preferably multilayer, so that the inner fabric layer of the glove is more hydrophobic and has a barrier function and protection from hand contact with the formulation or moisture offers.  

Cleaning solution and solvent

The weight ratio of the dry tissue to the applied cleaning solution should be 1: 0.1 to 1: 5, preferably 1: 0.5 to 1: 3 and particularly preferably 1: 1 to 1: 2. The solvent of the cleaning solution should consist of water or what water / alcohol mixtures exist. Isopropanol, propanol and ethanol are used as alcohols used. The drying time, the hold and the shine can be determined by the alcohol content of styled hair. With a high amount of alcohol and certain auxiliary agents used However, fabrics create a gel that is too solid or brittle and dries out the hair Rüst. The solutions used for the impregnation contain 0 to 95% by weight alcohol, preferably 3 to 70% by weight of alcohol, particularly preferably 5 to 40% by weight of alcohol.

Also in the manufacture of dry facial tissues that are moistened before use be, the alcohol content of the solution used has a decisive influence, since the Drying rate and thus the manufacturing costs can be optimized.

The viscosity of the impregnation solutions is due to the presence of film formers sometimes too high to be absorbed into the wipes by the capillary action of the tissue to become. To lower the viscosity, alcohols or alcohols are preferred hol / water mixtures used as solvents.

production method

The method for producing the facial tissues according to the invention is characterized in that a tissue containing a solution

• a) film makers and
• b) cationic surfactants

moistened and optionally subsequently dried out the solvent. It can moistening by spraying the solution onto the tissue or immersing the tissue be carried out in the impregnation solution.

For the subsequent drying, the viscosity of the solution used is, on the one hand, other on the one hand, the desired product is crucial.

If a dry cloth is desired as the product, use a defined one before use Amount of water must be moistened, so the solvent should be during production the impregnated wipes to a residual content of 0.1 to 3 wt .-%, preferably of below 0.1% by weight - based on the weight of the cloth. This can be achieved in that the moistened wipes at an elevated temperature,  exposed to a warm air stream, roller drying, or vacuum drying become.

A major reason for a subsequent drying after impregnation is in the Find viscosity of the solution to be processed. Since the capillary action of the pores of the Cloth tissue is only sufficient to absorb thin solutions Impregnation solutions before moistening the tissue are sufficient up to one for the absorption low viscosity can be diluted with solvent. The key is here also the surface tension of the solution, which depends on the choice and amount of surfactants can be optimized. After moistening, the excess solvent becomes again dried off. The subsequent drying is at the desired level of moisture the towels broken off. This is determined by the ease of use. The Adequate amounts of styling agents must also be removed from the cloth to be given to the hair. Malleability of the hair, distribution of substances in the hair and the moisture content of the hair obtained after application plays a decisive role ending role. Depending on the composition of the recipe, the amount and the type of film former the moisture content of the wipes can be adjusted.

Facial tissues, the solvents in amounts of 10 to 70 wt .-%, preferably 30 to 50 wt .-% - Contained in relation to the damp cleaning cloth - lead to a freeze simple and clean application form.

The type of solvent, for example the amount of alcohol used, is determined the drying process and the quality of the subsequent product. The dry The process of treatment of the treated hair can be crucial due to larger amounts of alcohol be shortened.

Industrial applicability

The use of facial tissues is suggested, characterized in that they are impregnated with a solution which typically has the following composition:

• 1. 0.1-5% by weight, preferably 0.3-3% by weight, in particular 0.5-1% by weight cationic biopolymers and / or
• 2. 0.1-20% by weight, preferably 1-15% by weight, in particular 5-10% by weight Vinyl pyrrolidone / vinyl acetate copolymers and / or polyvinyl pyrrolidone
• 3. 0.1-5% by weight, preferably 0.3-3% by weight, in particular 0.5-1% by weight cationic surfactants

for styling hair.  

Protein hydrolyzates in particular can also be used as particularly mild surfactants vegetable products based on wheat in amounts of 0.1 to 10% by weight, preferably 1 to 5% by weight of the impregnation solution can be added.

Depending on the degree of drying during manufacture, the wipes according to the invention contain

• 1. 0.01-25% by weight, preferably 0.1-10% by weight, in particular 0.5-5% by weight cationic biopolymers and / or
• 2. 0.01-25% by weight, preferably 0.1-15% by weight, in particular 0.5-10% by weight Vinyl pyrrolidone / vinyl acetate copolymers and / or polyvinyl pyrrolidone
• 3. 0.01-25% by weight, preferably 0.1-10% by weight, in particular 0.5-5% onic surfactants

based on the weight of the facial tissue.

The solutions used for impregnation can also be used as additional aids and additives substances mild surfactants, emulsifiers, consistency agents, thickeners, other polymers, Silicone compounds, lecithins, phospholipids, biogenic agents, antidandruff agents, Kon contain preservatives, perfume oils, dyes and the like.

surfactants

Anionic, nonionic and / or amphoteric can be used as further surface-active substances or amphoteric surfactants, the proportion of which is usually around 1 is up to 70, preferably 5 to 50 and in particular 10 to 30% by weight. Typical case Games for anionic surfactants are soaps, alkylbenzenesulfonates, alkanesulfonates, olefinsulfo nates, alkyl ether sulfonates, glycerol ether sulfonates, α-methyl ester sulfonates, sulfo fatty acids, Alkyl sulfates, fatty alcohol ether sulfates, glycerol ether sulfates, fatty acid ether sulfates, Hy Droxy mixed ether sulfates, monoglyceride (ether) sulfates, fatty acid amide (ether) sulfates, mono- and Dialkyl sulfosuccinates, mono- and dialkyl sulfosuccinamates, sulfotriglycerides, amide soaps, E. thercarboxylic acids and their salts, fatty acid isethionates, fatty acid sarcosinates, fatty acid dew ride, N-acylamino acids, such as acyl lactylates, acyl tartrates, acyl glutamates and Acyl aspartates, alkyl oligoglucoside sulfates and alkyl (ether) phosphates. Unless the anionic If surfactants contain polyglycol ether chains, these can be conventional, preferably however, have a narrow homolog distribution. Typical examples of nonionic Surfactants are fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, fatty acid poly glycol esters, fatty acid amide polyglycol ethers, fatty amine polyglycol ethers, alkoxylated triglycerides, Mixed ethers or mixed formals, optionally partially oxidized alk (en) yl oligoglycosides or Glucoronic acid derivatives, fatty acid-N-alkylglucamides, protein hydrolyzates (especially vegetable  Wheat-based products), polyol fatty acid esters, sugar esters, sorbitan esters, polysors bate and amine oxides. If the nonionic surfactants contain polyglycol ether chains, these are a conventional, but preferably a narrow homolog distribution exhibit. Typical examples of amphoteric or zwitterionic surfactants are alkyl betaines, Alkyl amido betaines, aminopropionates, aminoglycinates, imidazolinium betaines and sulfobetai ne. The surfactants mentioned are exclusively known compounds. With regard to the structure and manufacture of these substances, see relevant reviews for example J. Falbe (ed.), "Surfactants in Consumer Products", Springer Verlag, Berlin, 1987, pp. 54-124 or J. Falbe (ed.), "Catalysts, surfactants and mineral oil additive ", Thieme Verlag, Stuttgart, 1978, pp. 123-217. Typical examples for particularly suitable mild, d. H. Surfactants that are particularly compatible with the skin are fatty alcohol poly glycol ether sulfates, monoglyceride sulfates, mono- and / or dialkyl sulfosuccinates, fatty acids sethionates, fatty acid sarcosinates, fatty acid taurides, fatty acid glutamates, α-olefin sulfonates, Ether carboxylic acids, alkyl oligoglucosides, fatty acid glucamides, alkyl amido betaines, amphoace tale and / or protein fatty acid condensates, the latter preferably based on wheat pro teinen.

emulsifiers

Examples of suitable emulsifiers are nonionic surfactants from at least one of the following groups:

• - Addition products of 2 to 30 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear fatty alcohols with 8 to 22 C atoms, to fatty acids with 12 to 22 C atoms, of alkylphenols with 8 to 15 carbon atoms in the alkyl group and alkylamines with 8 to 22 Carbon atoms in the alkyl radical;
• - Alkyl and / or alkenyl oligoglycosides with 8 to 22 carbon atoms in the alk (en) yl radical and their ethoxylated analogues;
• - Adducts of 1 to 15 moles of ethylene oxide with castor oil and / or hydrogenated castor oil;
• - Adducts of 15 to 60 moles of ethylene oxide with castor oil and / or hydrogenated castor oil;
• Partial esters of glycerol and / or sorbitan with unsaturated, linear or saturated, branched fatty acids with 12 to 22 carbon atoms and / or hydroxycarboxylic acids with 3 to 18 carbon atoms and their adducts with 1 to 30 moles of ethylene oxide;
• - Partial esters of polyglycerol (average degree of self-condensation 2 to 8), polye ethylene glycol (molecular weight 400 to 5000), trimethylolpropane, pentaerythritol, sugar alcohols  (e.g. sorbitol), alkyl glucosides (e.g. methyl glucoside, butyl glucoside, lauryl gluco sid) and polyglucosides (e.g. cellulose) with saturated and / or unsaturated linea Ren or branched fatty acids with 12 to 22 carbon atoms and / or hydroxycar bonic acids with 3 to 18 carbon atoms and their adducts with 1 to 30 mol of ethyl oxide;
• - Mixed esters of pentaerythritol, fatty acids, citric acid and fatty alcohol according to DE 11 65 574 PS and / or mixed esters of fatty acids with 6 to 22 carbon atoms, Methyl glucose and polyols, preferably glycerin or polyglycerin.
• - Mono-, di- and trialkyl phosphates as well as mono-, di- and / or tri-PEG-alkyl phosphates and their salts;
• - lanolin alcohol;
• - Polysiloxane-polyalkyl-polyether copolymers or corresponding derivatives;
• - Block copolymers e.g. B. Polyethylene glycol 30 dipolyhydroxystearate;
• - polymer emulsifiers, e.g. B. Pemulen types (TR-1, TR-2) from Goodrich;
• - Polyalkylene glycols as well
• - glycerol.

Ethylene Oxide

The addition products of ethylene oxide and / or of propylene oxide with fatty alcohols, fatty acids, alkylphenols or with castor oil are known, commercially available products. These are homolog mixtures whose average degree of alkoxylation is the ratio of the amounts of ethylene oxide and / or propylene oxide and Substrate with which the addition reaction is carried out corresponds. C _12/18 - fatty acid monoesters and diesters of adducts of ethylene oxide with glycerol are known from DE 20 24 051 PS as refatting agents for cosmetic preparations.

Alkyl and / or alkenyl oligoglycosides

Alkyl and / or alkenyl oligoglycosides, their preparation and their use are out known in the art. They are manufactured in particular through implementation of glucose or oligosaccharides with primary alcohols with 8 to 18 carbon atoms men. Regarding the Glycosidrestes applies that both monoglycosides in which a cycli shear sugar residue is glycosidically bound to the fatty alcohol, as well as oligomeric gly cosides with a degree of oligomerization of up to preferably about 8 are suitable. The degree of oligomerization  is a statistical mean, one for such techni common homolog distribution is based on products.

partial glycerides

Typical examples of suitable partial glycerides are hydroxystearic acid monoglyceride, Hydroxystearic acid diglyceride, isostearic acid monoglyceride, isostearic acid diglyceride, Oleic acid monoglyceride, oleic acid diglyceride, ricinoleic acid moglyceride, ricinoleic acid diglyceride, Linoleic acid monoglyceride, Linoleic acid diglyceride, Linolenic acid monoglyceride, Linolenic acid diglyceride, erucic acid monoglyceride, erucic acid diglyceride, tartaric acid monoglyceride, Tartaric acid diglyceride, citric acid monoglyceride, citric diglyceride, malic acid mo noglyceride, malic acid diglyceride and their technical mixtures, the subordinate may still contain small amounts of triglyceride from the manufacturing process. e addition products of 1 to 30, preferably 5 to 10, mol of E are also suitable ethylene oxide to the partial glycerides mentioned.

sorbitan

Sorbitan monoisostearate, sorbitan sesquiisostearate and sorbitan come as sorbitan esters diisostearate, sorbitan triisostearate, sorbitan monooleate, sorbitan sesquioleate, sorbitan dioleate, sorbitan trioleate, sorbitan monoerucate, sorbitan sesquierucate, sorbitan dierucate, Sorbitan trierucate, sorbitan monoricinoleate, sorbitan sesquicinoleate, sorbitan diricinoleate, Sorbitan triricinoleate, sorbitan monohydroxystearate, sorbitan sesquihydroxystearate, Sorbi tandihydroxystearate, sorbitan trihydroxystearate, sorbitan monotartrate, sorbitan sesqui tartrate, sorbitan ditartrate, sorbitan tritartrate, sorbitan monocitrate, sorbitan sesquicitrate, Sorbitan citrate, sorbitan tricrate, sorbitan monomaleate, sorbitan sesquimaleate, sorbitan dimaleate, sorbitan trimaleate and their technical mixtures. Are also suitable Addition products of 1 to 30, preferably 5 to 10 moles of ethylene oxide to the ge called sorbitan esters.

polyglycerol

Typical examples of suitable polyglycerol esters are polyglyceryl-2 dipolyhydroxystea rate (Dehymuls® PGPH), polyglycerol-3-diisostearate (Lameform® TGI), polyglyceryl-4 Isostearate (Isolan® GI 34), Polyglyceryl-3 Oleate, Diisostearoyl Polyglyceryl-3 Diisostearate  (Isolan® PDI), Polyglyceryl-3 Methylglucose Distearate (Tego Care® 450), Polyglyceryl-3 Beeswax (Cera Bellina®), Polyglyceryl-4 Caprate (Polyglycerol Caprate T2010 / 90), Polyglyceryl-3 Cetyl Ether (Chimexane® NL), Polyglyceryl-3 Distearate (Cre mophor® GS 32) and Polyglyceryl Polyricinoleate (Admul® WOL 1403) Polyglyceryl Di merate isostearates and their mixtures. Examples of other suitable polyol esters are the mono-, di- and optionally reacted with 1 to 30 mol ethylene oxide Triester of trimethylolpropane or pentaerythritol with lauric acid, coconut fatty acid, Tallow fatty acid, palmitic acid, stearic acid, oleic acid, behenic acid and the like.

Anionic emulsifiers

Typical anionic emulsifiers are aliphatic fatty acids with 12 to 22 carbon atoms, such as palmitic acid, stearic acid or behenic acid, and Dicar bonic acids with 12 to 22 carbon atoms, such as azelaic acid or Seba cinsäure.

Amphoteric emulsifiers

Zwitterionic surfactants can also be used as emulsifiers. Zwitterionic surfactants are those surface-active compounds which carry at least one quaternary ammonium group and at least one carboxylate and one sulfonate group in the molecule. Particularly suitable zwitterionic surfactants are the so-called betaines such as the N-alkyl-N, N-dimethylammonium glycinate, for example the coconut alkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinate, for example the coconut acylaminopropyldimethylammonium glycinate, and 2-alkyl-3-carboxylmethyl 3-hydroxyethylimidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group and the cocoacylaminoethylhydroxyethylcarboxymethyl glycinate. The fatty acid amide derivative known under the CTFA name Cocamidopropyl Betaine is particularly preferred. Suitable emulsifiers are ampholytic surfactants. Ampholytic surfactants are surface-active compounds which, in addition to a C _8/18 alkyl or acyl group, contain at least one free amino group and at least one -COOH or -SO ₃ H group in the molecule and are capable of forming internal salts. Examples of suitable ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each with about 8 to 18 carbon atoms in the alkyl group. Particularly preferred ampholytic surfactants are N-coconut alkylaminopropionate, coconut acylaminoethylaminoproponate and C _12/18 acyl sarcosine

Consistency generator and thickener

The main consistency agents are fatty alcohols or hydroxy fatty alcohols from 12 to 22 and preferably 16 to 18 carbon atoms and in addition partial glycerides, fatty acids or hydroxy fatty acids. A combination of these substances with alkylo is preferred ligoglucosides and / or fatty acid-N-methylglucamides of the same chain length and / or Po lyglycerinpoly-12-hydroxystearates. Suitable thickeners are, for example, Aerosil Types (hydrophilic silicas), polysaccharides, especially xanthan gum, guar guar, Agar-agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl and hydro xypropyl cellulose, also high molecular weight polyethylene glycol mono- and diesters of fat acids, polyacrylates, (e.g. Carbopole® and Pemulen types from Goodrich; Synthalene® from Sigma; Keltrol types from Kelco; Seppic Sepigel types; Salcare types from Allied Col loids), polyacrylamides, polymers and polyvinyl alcohol. Have proven to be particularly effective also bentonites, such as B. Bentone® Gel VS-5PC (Rheox), which is a Mixture of cyclopentasiloxane, disteardimonium hectorite and propylene carbonate. Surfactants such as, for example, ethoxylated fatty acid glycerides and esters are also suitable of fatty acids with polyols such as pentaerythritol or trimethylolpropane, Fettal alcohol ethoxylates with a narrow homolog distribution or alkyl oligoglucosides as well as elect rolytes such as table salt and ammonium chloride.

polymers

Suitable cationic polymers are, for example, cationic cellulose derivatives, such as. B. a quaternized hydroxyethyl cellulose, which is marketed under the name Polymer JR 400® by Amerchol is available, cationic starch, copolymers of diallylammonium salts and Ac rylamide, quaternized vinyl pyrrolidone / vinyl imidazole polymers, such as. B. Luviquat® (BASF), Condensation products of polyglycols and amines, quaternized collagen polypeptides, such as for example lauryldimonium hydroxypropyl hydrolyzed collagen (Lamequat®L / Grünau), quaternized wheat polypeptides, polyethyleneimine, cationic silicone polymers, such as. B. Amo dimethicone, copolymers of adipic acid and dimethylaminohydroxypropyldiethylenetriamine (Cartaretine® / Sandoz), copolymers of acrylic acid with dimethyldiallylammonium chloride (Merquat® 550 / Chemviron), polyaminopolyamides, e.g. B. described in FR 2252840 A.  and their crosslinked water-soluble polymers, optionally microcrystalline, Condensation products from dihaloalkylene, such as. B. dibromobutane with bisdialkylamines, such as B. bis-dimethylamino-1,3-propane, cationic guar gum, such as. B. Jaguar® CBS, Yes guar® C-17, Jaguar® C-16 from Celanese, quaternized ammonium salt polymers such as z. B. Mirapol® A-15, Mirapol® AD-1, Mirapol® A2-1 from Miranol.

Examples of anionic, zwitterionic, amphoteric and nonionic polymers are se vinyl acetate / crotonic acid copolymers, vinyl pyrrolidone / vinyl acrylate copolymers, vinylace tat / butyl maleate / isobornyl acrylate copolymers, methyl vinyl ether / maleic anhydride copoly mers and their esters, uncrosslinked and polyols crosslinked polyacrylic acids, acrylamido propyltrimethylammonium chloride / acrylate [] copolymers, octylacrylamide / methylmethacrylic lat / tert-butylaminoethyl methacrylate / 2 [] - hydroxypropyl methacrylate copolymers, vinnylpyrroli don / dimethylaminoethylmet [] acrylate / vinylcaprolactam [] terpolymers and optionally derivatized cellulose ethers and silicones in question. Other suitable polymers and Verdi agents are in Cosm. Toil. 108, 95 (1993).

silicone compounds

Suitable silicone compounds are, for example, dimethylpolysiloxanes, methylphenylpoly siloxanes, cyclic silicones and amino, fatty acid, alcohol, polyether, epoxy, fluorine, gly Kosid- and / or alkyl-modified silicone compounds that both flow at room temperature sig as well as resinous. Simethicones, in which there are are mixtures of dimethicones with an average chain length of 200 to 300 dimethylsiloxane units and hydrogenated silicates. A detailed overview suitable volatile silicones are also found by Todd et al. in cosm. Toil. 91, 27 (1976).

Biogenic agents

Examples of biogenic active substances are tocopherol, tocopherol acetate and tocopherol palmitate, ascorbic acid, (deoxy) ribonucleic acid and its fragmentation products, β- Glucans, retinol, bisabolol, allantoin, phytantriol, panthenol, AHA acids, amino acids, Ceramides, pseudoceramides, essential oils, plant extracts, such as. B. Prunus extract, Bam to understand baranus extract and vitamin complexes.  

Antidandruff agents

Piroctone olamine (1-hydroxy-4-methyl-6- (2,4,4- trimythylpentyl) -2- (1H) -pyridinone monoethanolamine salt), Baypival® (Climbazole), Ketocona zol®, (4-acetyl-1 - {- 4- [2- (2.4-dichlorophenyl) r-2- (1H-imidazol-1-ylmethyl) -1,3-dioxylan-c-4- ylmethoxyphenyl} piperazine, ketoconazole, elubiol, selenium disulfide, sulfur colloidal, sulfur Polyethylene glycol sorbitan monooleate, sulfur ricinole polyhexylate, sulfur tar distillates, Salicylic acid (or in combination with hexachlorophene), undexylenic acid monoethanolamide Sulfosuccinate Na salt, Lamepon® UD (protein undecylenic acid condensate), zinc pyrithione, Aluminum pyrithione and magnesium pyrithione / dipyrithione magnesium sulfate in question.

preservative

Suitable preservatives are, for example, phenoxyethanol, formaldehyde solution, Parabens, pentanediol or sorbic acid and those under the name Surfacine® be knew silver complexes and those in Appendix 6, Parts A and B of the Cosmetics Ordinance led further substance classes.

Perfume oils and flavors

Perfume oils include mixtures of natural and synthetic fragrances. well Natural fragrances are extracts of flowers (lily, lavender, rose, jasmine, neroli, ylang- Ylang), stems and leaves (geranium, patchouli, petitgrain), fruits (anise, coriander, Caraway, juniper), fruit peels (bergamot, lemon, oranges), roots (mace, ange lica, celery, cardamom, costus, iris, calmus), wood (pine, sandal, guaiac, cedar, Rosewood), herbs and grasses (tarragon, lemongrass, sage, thyme), needles and Twigs (spruce, fir, pine, mountain pine), resins and balsams (galbanum, elemi, benzoin, Myrrh, olibanum, opoponax). Animal raw materials are also possible, as with for example civet and castoreum. Typical synthetic fragrance compounds are Pro products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type. olfactory Compounds of the ester type are e.g. B. benzyl acetate, phenoxyethyl isobutyrate, p-tert.- Butylcyclohexylacetate, Linalylacetat, Dimethylbenzylcarbinylacetat, Phenylethylacetat, Lina lylbenzoate, benzyl formate, ethyl methylphenylglycinate, allylcyclohexylpropionate, styrallylpropi onate and benzyl salicylate. The ethers include, for example, benzyl ethyl ether and the alde hyden z. B. the linear alkanals with 8 to 18 carbon atoms, citral, citronellal, citronel lyloxyacetaldehyde, cyclamenaldehyde, hydroxycitronellal, lilial and bourgeonal, to the ketones  z. B. the Jonone, α-isomethyl ionone and methyl cedryl ketone, to the alcohols anethole, Citronellol, eugenol, isoeugenol, geraniol, linalool, phenylethyl alcohol and terpineol Hydrocarbons mainly include the terpenes and balms. To be favoured however, mixtures of different fragrances are used, which together make an appealing Generate fragrance. Also essential oils of lower volatility, mostly as an aro Mac components are used as perfume oils, e.g. B. sage oil, chamomile oil, Clove oil, lemon balm oil, mint oil, cinnamon leaf oil, linden blossom oil, juniper berry oil, vetiver oil, Oliban oil, galbanum oil, labolanum oil and lavandin oil. Bergamot oil, Dihydromyrcenol, lilial, lyral, citronellol, phenylethyl alcohol, α-hexylcinnamaldehyde, geraniol, Benzylacetone, cyclamenaldehyde, linalool, boisambrene forte, ambroxan, indole, hedione, Sandelice, lemon oil, mandarin oil, orange oil, allylamyl glycolate, cyclover valley, lavandin oil, Muscat sage oil, β-damascone, geranium oil bourbon, cyclohexyl salicylate, Vertofix Coeur, Iso-E-Super, Fixolide NP, Evernyl, Iraldein gamma, phenylacetic acid, geranyl acetate, benzy Lacetat, Rosenoxid, Romilllat, Irotyl and Floramat used alone or in mixtures.

The flavors include, for example, peppermint oil, spearmint oil, anise oil, star anise oil, Küm mel oil, eucalyptus oil, fennel oil, lemon oil, wintergreen oil, clove oil, menthol and the like in question.

dyes

Suitable dyes are those which are suitable and approved for cosmetic purposes are used, such as those used in the publication "Cosmetic Colorants" the dye commission of the German Research Foundation, Verlag Che mie, Weinheim, 1984, pp. 81-106 are compiled. Examples are cooking ale red A (C.I. 16255), Patent Blue V (C.I. 42051), Indigotin (C.I. 73015), Chlorophyllin (C.I. 75810), Chi noling yellow (C.I. 47005), titanium dioxide (C.I. 77891), indanthrene blue RS (C.I. 69800) and madder lacquer (C.I. 58000). Luminol may also be present as the luminescent dye. This color substances are usually in concentrations of 0.001 to 0.1 wt .-%, based on the whole mixture, used.

The total proportion of auxiliaries and additives can be 1 to 50, preferably 5 to 40% by weight. based on the mean - amount.  

Examples

Different impregnation solutions were made by simply mixing the components manufactured; then thin cotton gloves weighing 12 g each with 20 g of the solutions moistened and rubbed into the hair to be treated.

In a second experiment, the gloves impregnated with solution 4, 5 or 6 were used Dried at 30 ° C for 3, 6 or 24 hours. The semi-dry gloves were oh ne added water for styling hair that impregnates the dried (30 ° C, 24 h) The gloves were moistened again with 17 g water before use.

Table 1

Composition of the impregnation solution concentrates

Claims (12)

1. Use of facial tissues, characterized in that they are impregnated with a solution containing

• a) film makers and
• b) cationic surfactants

for styling hair. 2. Use of facial tissues according to claim 1, characterized in that the facial tissues as component (a) cationic biopolymers in amounts of 0.01 up to 25% by weight - based on the weight of the facial tissue. 3. Use of facial tissues according to claims 1 and / or 2 ,. thereby ge indicates that the facial tissue as component (a) vinyl pyrrolidone / vinyl acetate copolymers and / or polyvinylpyrrolidone in amounts of 0.01 to 25% by weight - based on the weight of the facial tissue - included. 4. Use of facial tissues according to at least one of claims 1 to 3, because characterized in that the facial tissues as component (b) cationic Surfactants in amounts of 0.01 to 25 wt .-% - based on the weight of the cosmetic cloths - included. 5. Use of facial tissues according to at least one of claims 1 to 4, because characterized in that the facial tissues water in amounts of 10 to 70 wt .-% - based on the damp cleaning cloth - included. 6. Use of facial tissues according to at least one of claims 1 to 5, because characterized in that the facial tissues alcohol in amounts of 10 to 70 wt .-% - based on the damp cleaning cloth - included. 7. Use of facial tissues according to at least one of claims 1 to 6, because characterized by the weight ratio of dry tissue to applied Solution 1: 0.1 to 1: 5. 8. Use of facial tissues according to at least one of claims 1 to 7, because characterized in that the facial tissues hydrolyzed as a further component contain vegetable proteins   9. A process for the production of facial tissues according to at least one of claims 1 to 8, characterized in that a fabric containing a solution

• a) film makers and
• b) cationic surfactants

moistened. 10. A process for the production of cosmetic tissues according to at least one of claims 1 to 9, characterized in that a fabric containing a solution

• a) film makers and
• b) cationic surfactants

moistened and then the solvent to a residual content of 0.1 to 50 wt .-% - based on the weight of the facial tissue - dried out. 11. Use of facial tissues according to at least one of claims 1 to 10, because characterized in that they are moistened with water before use. 12. Use of facial tissues according to at least one of claims 1 to 11, because characterized by that they are in the form of gloves.