DE1081993B - Cleaning agents in piece form - Google Patents
Cleaning agents in piece formInfo
- Publication number
- DE1081993B DE1081993B DES49819A DES0049819A DE1081993B DE 1081993 B DE1081993 B DE 1081993B DE S49819 A DES49819 A DE S49819A DE S0049819 A DES0049819 A DE S0049819A DE 1081993 B DE1081993 B DE 1081993B
- Authority
- DE
- Germany
- Prior art keywords
- cleaning agent
- agent according
- detergent substance
- glucose
- sulfonated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012459 cleaning agent Substances 0.000 title claims description 9
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 11
- 239000008103 glucose Substances 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 10
- 239000003599 detergent Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 3
- 229920001353 Dextrin Polymers 0.000 claims description 3
- 239000004375 Dextrin Substances 0.000 claims description 3
- 229930195725 Mannitol Natural products 0.000 claims description 3
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 claims description 3
- 235000019425 dextrin Nutrition 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims description 3
- 239000000594 mannitol Substances 0.000 claims description 3
- 235000010355 mannitol Nutrition 0.000 claims description 3
- 235000013379 molasses Nutrition 0.000 claims description 3
- 239000000600 sorbitol Substances 0.000 claims description 3
- 235000000346 sugar Nutrition 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 150000002193 fatty amides Chemical class 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 229910003002 lithium salt Inorganic materials 0.000 claims 1
- 159000000002 lithium salts Chemical class 0.000 claims 1
- 150000008163 sugars Chemical class 0.000 claims 1
- 150000003871 sulfonates Chemical class 0.000 claims 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000000344 soap Substances 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- -1 sodium alkylarylsulfonate Chemical class 0.000 description 3
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 235000010356 sorbitol Nutrition 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004067 bulking agent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- KWKXNDCHNDYVRT-UHFFFAOYSA-N dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1 KWKXNDCHNDYVRT-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000001727 glucose Nutrition 0.000 description 1
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229940095696 soap product Drugs 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Description
DEUTSCHESGERMAN
Es ist ein Verfahren zur Herstellung von Seifenoder sonstigen Reinigungsstücken aus Fettalkoholen bekannt, die ausschließlich aus schwefelsauren Fettalkoholen mit 50bis 9O°/oLaurin- und Myristinalkohol und 50 bis 10% Cetyl- und Stearinalkohol bestehen.It is a process for making soaps or other cleaning bars from fatty alcohols known exclusively from sulfuric fatty alcohols with 50 to 90% lauric and myristic alcohol and 50 to 10% cetyl and stearic alcohol.
Diese schwefelsauren Erzeugnisse, deren Wassergehalt in geeigneter Weise eingestellt wurde, haben eine passende Beschaffenheit für die üblichen Verarbeitungen in der Seifenherstellung wie etwa Strangziehen. Walzen, also für die Verarbeitung zu Schnitzeln, Blättern, Bändern od. dgl. mit nachfolgendem Formen zu Toilettenkugeln, Blöcken, Stangen od. dgl.These sulfuric acid products, the water content of which has been appropriately adjusted, have a suitable consistency for the usual processing in soap production such as drawing. Rollers, i.e. for processing into chips, leaves, ribbons or the like, with subsequent shaping to toilet balls, blocks, rods or the like.
Das Einbringen von Duftstoffen, Farbstoffen od. dgl. stellt keine Schwierigkeiten dar, und die üblichen Geräte der Seifenherstellung sind anwendungsfähig.The introduction of fragrances, dyes or the like. poses no difficulties and the usual soap making equipment is applicable.
Es wurde nun gefunden, daß der Gehalt an waschaktiven Stoffen ohne wesentliche Verminderung der Güte des Erzeugnisses durch Einbringen eines inerten und billigeren Stoffes herabgesetzt werden kann, vorausgesetzt, daß ein solcher inerter Stoff einwandfrei in Wasse»" löslich ist, die Eigenschaften des aktiven Stoffes nicht verschlechtert und sich zur \rerarbeitung und Formgebung wie der aktive Stoff selbst eignet.It has now been found that the content of washing-active substances can be reduced by introducing an inert and cheaper substance without a significant reduction in the quality of the product, provided that such an inert substance is perfectly soluble in water, the properties of the active substance are not deteriorated and lends itself to \ r preparing as well as shape as the active substance.
Die diese Bedingungen am besten erfüllenden Erzeugnisse sind Zucker, Dextrin, !Melasse, Glukose, Mannit, Sorbit usw.The products that best meet these conditions are sugar, dextrin, molasses, glucose, Mannitol, sorbitol, etc.
Glukose vereinigt in sich die meisten Eigenschaften, die sich mit der Beschaffenheit des Seifenerzeugnisses oder sonstigen Reinigungsmittels vereinbaren lassen.Glucose combines most of the properties that are related to the composition of the soap product or other cleaning agents.
L'l-i'rraschenderweise wurde nun gefunden, daß man 35 bis 60% Glukose in Reinigungsmittel einbringen kann, die aus Alkoholgemischen mit den vorgenannten Anteilen hergestellt sind, ohne daß dadurch weder die Reinigungskraft noch die Schaumbildung beeinträchtigt wird. Es wurde sogar eine wesentliche Verminderung des Verbrauches bereits angefeuchteter Reinigungsstücke festgestellt, wenn der inerte Füllstoff in genügend großer Menge eingebracht wird.It has now been found, surprisingly, that one 35 to 60% glucose can be introduced into detergents made from alcohol mixtures with the aforementioned Proportions are made without affecting neither the cleaning power nor the foam formation will. There was even a significant reduction in the consumption of already moistened cleaning pieces found when the inert filler is introduced in a sufficiently large amount.
Der günstigste Gehalt an Glukose beträgt etwa 35 bis 451Vo. Eine solche Masse eignet sich in einwandfreier Weise für alle Verarbeitungen der Seifenherstellung und läßt sich auch zwischen der Herstellung und der Formgebung einwandfrei aufbewahren.The most favorable glucose content is around 35 to 45 1 Vo. Such a mass is perfectly suitable for all processing operations in soap production and can also be perfectly stored between production and shaping.
Weitere Forschungen zur Gewinnung anderer Reinigungsmittelstücke haben zur Feststellung geführt, daß die Füllstoffe, insbesondere Glukose, die leichte Herstellung von Reinigungsmittelstücken mit anderen Grundstoffen, etwa mit Alkylarylsulfonaten, sulfonierten Fettamiden, sulfonierten Monoglyceriden od. dgl., oder deren Gemische, sowie aus Gemischen des einen oder anderen dieser Reinigungsmittel mit nicht ionischen Stoffen gestatten.Further research to obtain other detergent pieces have led to the finding that the bulking agents, especially glucose, are the easiest to manufacture of detergent bars with other base materials, e.g. with alkylarylsulfonates, sulfonated Fatty amides, sulfonated monoglycerides or the like, or mixtures thereof, as well as mixtures of the one or other of these cleaning agents with non-ionic substances.
Glukose ergibt in all diesen Fällen die gleiche Wirkung, d. h. die Erzeugung eines Agglomerates aus Reinigungsmittel in StückformGlucose gives the same effect in all of these cases; H. the generation of an agglomerate Detergent in bar form
Anmelder:Applicant:
Societe Anonyme d'InnovationsSociete Anonyme d'Innovations
Chimiques »Sinnova« ou »Sadic«,Chimiques »Sinnova« or »Sadic«,
Beauval, Trilport, Seine-et-MarneBeauval, Trilport, Seine-et-Marne
(Frankreich)(France)
Vertreter: Dr. G. W. LotterhosRepresentative: Dr. G. W. Lotterhos
und Dr.-Ing. H. W. Lotterhos, Patentanwälte,and Dr.-Ing. H. W. Lotterhos, patent attorneys,
Frankfurt/M., Lichtensteinstr. 3Frankfurt / M., Lichtensteinstr. 3
Beanspruchte Priorität:
Frankreich vom 25. August 1955 und 3. Januar 1956Claimed priority:
France from August 25, 1955 and January 3, 1956
Edouard Hug, Meaux, Seine-et-Marne (Frankreich),
ist als Erfinder genannt wordenEdouard Hug, Meaux, Seine-et-Marne (France),
has been named as the inventor
dem aktiven Stoff und den Füllstoffen, ohne daß diese dadurch wassergierig werden. Es können auf diese Weise dem gemäß dem vorgenannten Verfahren hergestellten Reinigungsmittel 35 bis 60%, vorzugsweise 35 bis 45%, Glukose eingegeben werden, wenn als Grundstoffe die vorgenannten schwefelsauren Fettalkohole oder sonstigen Reinigungsstoffe benutzt werden, ohne daß dadurch die Eigenschaften der Haltbarkeit, der Reinigungskraft und der Schaumbildung beeinträchtigt werden. Die anderen genannten Bestandteile, wie Zucker, Dextrin, Melasse, Mannit und Sorbit, erzeugen die gleiche Wirkung. Aus wirtschaftlichen Gründen wird aber Glukose bevorzugt.the active substance and the fillers without making them greedy for water. In this way, 35 to 60%, preferably 35 to 45%, of glucose can be added to the cleaning agent produced according to the above-mentioned process, if the above-mentioned sulfuric acid fatty alcohols or other cleaning agents are used as base materials, without impairing the properties of durability or cleaning power and the formation of foam are impaired. The other ingredients mentioned, such as sugar, dextrin, molasses, mannitol, and sorbitol, produce the same effect. However, for economic reasons, glucose is preferred.
Die Erfindung gestattet die Herstellung von Gemischen, die sich für alle üblichen Verarbeitungen in der Seifenherstellung eignen. Es ergibt sich daraus der Vorteil, daß keine neuen Einrichtungen erforderlich sind, und daß auch gleichzeitig die so hergestellten Reinigungsstücke mit Sicherheit eine sehr homogene Beschaffenheit erhalten.The invention allows the preparation of mixtures that are suitable for all common processing in suitable for soap production. This has the advantage that no new facilities are required are, and that at the same time the cleaning pieces produced in this way are certainly very homogeneous Preserved texture.
Als nicht beschränkendes Beispiel wird nachfolgend die Herstellung eines Reinigungsstückes aus Natriumalkylarylsulfonat und Glukose beschrieben.As a non-limiting example, the following is the manufacture of a cleaning bar from sodium alkylarylsulfonate and glucose.
Natriumalkylarylsulfonat wird in der üblichen Weise durch Eingießen des sulfonierten Produktes eines handelsüblichen Alkylaryls, etwa Dodecylbenzol, unter Abkühlung in die berechnete Menge einer 40%igenSodium alkylarylsulfonate is in the usual manner by pouring the sulfonated product of a commercial alkylaryls, such as dodecylbenzene, with cooling into the calculated amount of a 40% strength
. , .. 009 51Ο/Ϊ15. , .. 009 51Ο / Ϊ15
Natronlauge hergestellt. Es ergibt sich daraus eine dickflüssige Paste. Diese Paste wird in eine konzentrierte und heiße Glukoselösung in solcher Menge eingebracht, daß das Endprodukt 35 bis 45% Glukose enthält. Wegen des Steifwerdens der Atasse wird dieser Vorgang vorzugsweise in einem Gerät der Wernerschen Art durchgeführt. Das gewonnene Produkt ist eine halbfette Masse, die sich leicht strangpressen und wie Toiletteseife formen läßt. Während des Pilierens können Duftstoffe und sonstige erwünschte Bestandteile eingebracht werden.Caustic soda produced. The result is a thick paste. This paste is concentrated in one and hot glucose solution is added in such an amount that the final product is 35 to 45% glucose contains. Because of the stiffening of the atasse, this process is preferably carried out in a Werner device Kind carried out. The product obtained is a semi-fat mass that can be easily extruded and how to mold toilet soap. Fragrances and other desired ingredients can be added during the paving process be introduced.
Das X'atriumalkylarylsulfonat kann auch durch das Alkylarylsiilfonat des Magnesiums, des Kaliums usw. oder durch deren Gemische mit dem Xatriumsalz ersetzt werden. Es können ferner Alkylarylsulfonate im Gemisch mit sulfonierten Amiden oder Monoglyceride als Grundstoff benutzt werden, die man dann mit den vorgenannten Grundstoffen vermischt.The sodium alkylarylsulfonate can also be replaced by the alkylarylsilphonate of magnesium, potassium, etc. or be replaced by their mixtures with the sodium salt. It can also be alkylarylsulfonates im Mixture with sulfonated amides or monoglycerides can be used as a base material, which can then be mixed with the the aforementioned raw materials mixed.
Claims (5)
Österreichische Patentschrift Nr. 139 853;
USA.-Patentschrift Xr. 2 181 087.Considered publications:
Austrian Patent No. 139 853;
U.S. Patent Xr. 2,181,087.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1081993X | 1955-08-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1081993B true DE1081993B (en) | 1960-05-19 |
Family
ID=9610459
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DES49819A Pending DE1081993B (en) | 1955-08-25 | 1956-08-02 | Cleaning agents in piece form |
Country Status (3)
| Country | Link |
|---|---|
| BE (2) | BE540691A (en) |
| DE (1) | DE1081993B (en) |
| FR (3) | FR1111670A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1284555B (en) * | 1962-03-05 | 1968-12-05 | Cyclo Chemicals Ltd | Textile cleaning agents |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT139853B (en) * | 1932-07-30 | 1934-12-27 | Adolf Dr Welter | Process for the production of dry, no longer caking and quickly soluble products for dyeing, washing and cleaning purposes. |
| US2181087A (en) * | 1937-07-07 | 1939-11-21 | American Cyanamid & Chem Corp | Detergent composition |
-
0
- BE BE545658D patent/BE545658A/xx unknown
- BE BE540691D patent/BE540691A/xx unknown
-
1954
- 1954-09-21 FR FR1111670D patent/FR1111670A/en not_active Expired
-
1955
- 1955-08-25 FR FR68013D patent/FR68013E/en not_active Expired
-
1956
- 1956-01-03 FR FR68929D patent/FR68929E/en not_active Expired
- 1956-08-02 DE DES49819A patent/DE1081993B/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT139853B (en) * | 1932-07-30 | 1934-12-27 | Adolf Dr Welter | Process for the production of dry, no longer caking and quickly soluble products for dyeing, washing and cleaning purposes. |
| US2181087A (en) * | 1937-07-07 | 1939-11-21 | American Cyanamid & Chem Corp | Detergent composition |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1284555B (en) * | 1962-03-05 | 1968-12-05 | Cyclo Chemicals Ltd | Textile cleaning agents |
Also Published As
| Publication number | Publication date |
|---|---|
| FR68929E (en) | 1958-07-23 |
| FR68013E (en) | 1958-03-27 |
| FR1111670A (en) | 1956-03-02 |
| BE545658A (en) | |
| BE540691A (en) |
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