DE1049352B - Mixture for making soap bubbles - Google Patents
Mixture for making soap bubblesInfo
- Publication number
- DE1049352B DE1049352B DENDAT1049352D DE1049352DA DE1049352B DE 1049352 B DE1049352 B DE 1049352B DE NDAT1049352 D DENDAT1049352 D DE NDAT1049352D DE 1049352D A DE1049352D A DE 1049352DA DE 1049352 B DE1049352 B DE 1049352B
- Authority
- DE
- Germany
- Prior art keywords
- mixture
- soap bubbles
- borax
- mixtures
- fatty alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims description 21
- 239000000344 soap Substances 0.000 title claims description 8
- 241000416162 Astragalus gummifer Species 0.000 claims description 10
- 229920001615 Tragacanth Polymers 0.000 claims description 10
- 229910021538 borax Inorganic materials 0.000 claims description 9
- 229920000159 gelatin Polymers 0.000 claims description 9
- 235000019322 gelatine Nutrition 0.000 claims description 9
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 9
- 239000004328 sodium tetraborate Substances 0.000 claims description 9
- -1 fatty alcohol sulfonate Chemical class 0.000 claims description 8
- 108010010803 Gelatin Proteins 0.000 claims description 5
- 239000008273 gelatin Substances 0.000 claims description 5
- 235000011852 gelatine desserts Nutrition 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000002270 dispersing agent Substances 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 2
- 239000003925 fat Substances 0.000 claims 1
- 239000003921 oil Substances 0.000 claims 1
- 239000001993 wax Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000008149 soap solution Substances 0.000 description 5
- 239000001828 Gelatine Substances 0.000 description 4
- 239000003755 preservative agent Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000196 tragacanth Substances 0.000 description 2
- 235000010487 tragacanth Nutrition 0.000 description 2
- 229940116362 tragacanth Drugs 0.000 description 2
- 201000004624 Dermatitis Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 208000010668 atopic eczema Diseases 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/384—Animal products
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Zoology (AREA)
- Inorganic Chemistry (AREA)
- Medicinal Preparation (AREA)
- Detergent Compositions (AREA)
Description
KL. 8 O —KL. 8 O -
EiTERNAT. KL. B Ol fEgg parent. KL. B Ol f
PATENTAMTPATENT OFFICE
BOIF f 7 / GOBOIF f 7 / GO
A 20670 IVc/8 οA 20670 IVc / 8 ο
ANMELDETAG: 5. JULI 1954REGISTRATION DATE: JULY 5, 1954
BEKANNTMACHUNG
DER ANMELDUNG
DND AUSGABE DEK
AÜSLEGESCHRIFT: 29. J A N U A R 1 9 5 9NOTICE
THE REGISTRATION
DND ISSUE DEC
ADDRESS: 29 JANUARY 1 9 5 9
Die Erfindung befaßt sich mit der Herstellung von Mischungen aus Feitalkoholsulfonaten, Borax, Gelatine, Tragantgummi, gegebenenfalls unter Mitverwendung von Konservierungs- und/oder Dispergierungsmitteln; solche Mischungen ergeben nach der Dispersion in Wasser unschädliche und ungiftige, nichtätzende Lösungen, welche sich zur Herstellung von Seifenblasen eignen.The invention is concerned with the production of mixtures of Feitalkoholsulfonaten, Borax, Gelatine, gum tragacanth, optionally with the use of preservatives and / or dispersants; such mixtures produce harmless and non-toxic after dispersion in water, non-corrosive solutions, which are suitable for making soap bubbles.
Zur Anfertigung von Lösungen, aus denen sich Seifenblasen herstellen lassen, werden bisher meist echte Seifen, d. 1Ii. die Natrium- oder Kaliumsalze höhermolekular er Fettsäuren verwendet. Es ist schon verschiedentlich vorgeschlagen worden, solchen Seifenlösungen zur Verbesserung der Blasenbildung Tragantgummi, Gelatine oder andere Leimstoffe als Verdickungsmittel zuzusetzen und als Zusatz zur Wasserenthärtung kleine Mengen Borax zu verwenden. Derartige Zusätze erleichtern die Blasenbildung und erhöhen Haltbarkeit und Farbigkeit der Seifenblasen.For the production of solutions from which soap bubbles can be produced, real soaps, i. 1 ii. the sodium or potassium salts of higher molecular weight fatty acids are used. Various proposals have already been made to add gum tragacanth, gelatine or other glue as a thickening agent to such soap solutions to improve the formation of bubbles, and to use small amounts of borax as an additive for water softening. Such additives facilitate the formation of bubbles and increase the durability and color of the soap bubbles.
Seifenlösungen haben indessen den Nachteil, daß sie bei länger dauernder Einwirkung die Haut, insbesondere bei Kindern, reizen und Ekzeme verursachen können und daß sie nicht mehr als harmlos angesehen werden können, wenn sie in den Mund oder gar in den Schlund geraten. Darüber hinaus haben Seifenlösungen den Nachteil, daß sie infolge ihres Alkaligehalts Flecke auf Möbeln, Stoffen usw. verursachen.Soap solutions, however, have the disadvantage that they damage the skin, in particular if they are exposed to them for a long time in children, can irritate and cause eczema and that they are no longer considered harmless can be seen if they get in the mouth or even in the throat. Furthermore Soap solutions have the disadvantage that, due to their alkali content, they leave stains on furniture, fabrics, etc. cause.
Die Erfindung verwendet in bestimmter Weise hergestellte Kombinationen von Fettalkoholsulfonaten mit Borax, Gelatine, Tragant und gegebenenfalls Konservierungsmitteln, denen noch Hilfsmittel zur Dispersion dieser Mischungen in Wasser zugesetzt werden können und die die obenerwähnten Nachteile nicht besitzen. Es ist zwar bereits vorgeschlagen worden, auch Fettalkoholsulfonate in Mischung mit Tragant und Leim zu verwenden, jedoch hat sich in zahlreichen Versuchen herausgestellt, daß es optimale Mischungen gibt, deren Lösungen in Wasser den üblichen Seifenlösungen weit überlegen sind. Solche Mischungen bestehen aus 42 bis 44% Fettalkoholsulfonat, 34 bis 35 % Borax, 17 bis 18 % Gelatine und 3 °/o Tragantgummi, denen noch bis zu 4 °/o Konservierungs- und/oder Dispe^gierungsmittel zugesetzt werden können. Die angegebenen Zahlen beziehen sich auf Gewichtsprozente, wenn man davon ausgeht, daß sämtliche Bestandteile fest bzw. pulverförmig sind.The invention uses combinations of fatty alcohol sulfonates prepared in a specific manner with borax, gelatine, tragacanth and, if necessary, preservatives, which still have aids for Dispersion of these mixtures in water can be added and which has the above-mentioned disadvantages not own. It has already been proposed to also use fatty alcohol sulfonates as a mixture To use tragacanth and glue, however, it has been found in numerous experiments that it is optimal There are mixtures whose solutions in water are far superior to the usual soap solutions. Such mixtures consist of 42 to 44% fatty alcohol sulfonate, 34 to 35% borax, 17 to 18% gelatin and 3% gum tragacanth to which up to 4% preservative and / or dispersants can be added. The figures given relate to to percentages by weight, assuming that all components are solid or powdery.
Diese Mischungen sind nicht nur für die menschliche Gesundheit ganz und gar unschädlich, wie sich
auf Grund einer gutachtlichen Prüfung herausgestellt hat, sondern sie sind darüber hinaus den echten
Seifenlösungen bezüglich des Blasenbildungsvermögens und der Schönheit der erzeugten Blasen
Mischung zur Herstellung
von SeifenblasenThese mixtures are not only completely harmless to human health, as has been found on the basis of an expert examination, but they are also the real soap solutions with regard to the bubble-forming capacity and the beauty of the bubble mixture produced
of soap bubbles
Anmelder:
A/B Alfred Ulimann & Co., StockholmApplicant:
A / B Alfred Ulimann & Co., Stockholm
Vertreter: Dipl.-Ing. H. Fecht, Patentanwalt,
Wiesbaden, Hohenlohestr. 21Representative: Dipl.-Ing. H. Fecht, patent attorney,
Wiesbaden, Hohenlohestr. 21
wesentlich überlegen. Auf Grund ihrer Alkalifreiheit ist auch die Fleckenbildungsmöglichkeit ausgeschlossen. Da die Mischungen in trockener Form, gegebenenfalls auch tablettiert, zum Absatz gelangen, stellen sich Verpackung, Lagerhaltung, Verteilung und Verkauf denkbar einfach. Für den Verbrauch ist die fertige Mischung in Wasser aufzulösen.substantially superior. Because they are alkali-free, the possibility of staining is also excluded. Since the mixtures are sold in dry form, possibly also in tablets, Packaging, warehousing, distribution and sales are extremely easy. For consumption is to dissolve the finished mixture in water.
Im einzelnen erfolgt die Herstellung zweckmäßig in der nachfolgend geschilderten Weise:In detail, the production is expediently carried out in the manner described below:
Fettalkoholsulfonat wird bei Zimmertemperatur mit Tragantgummi vermischt. Danach wird die erforderliche Gelatine mit Borax, gleichfalls bei Zimmertemperatur, vermischt. Diese beiden Gemische, nämlich Fettalkoholsulfonat und Tragantgummi einerseits bzw. Gelatine und Borax andererseits werden wiederum bei Zimmertemperatur miteinander vermischt und das Gemenge der vier Grundbestandteile etwa 1 Stunde lang auf 50 bis 90° C zum Vertreiben von Feuchtigkeit erhitzt. Nach der Erhitzung und Trocknung wird das Gemisch abermals sorgfältig gerührt, zweckmäßig in einer Mischmaschine, worauf man es auf Zimmertemperatur erkalten läßt. Die Mischung ist dann vollkommen homogen. Nach Bedarf setzt man dieser Mischung noch ein Konservierungsmittel zu, um sie vor Verderb zu schützen, insbesondere wenn eine längere Lagerung beabsichtigt oder unvermeidlich ist.Fatty alcohol sulfonate is mixed with gum tragacanth at room temperature. After that, the required Gelatine mixed with borax, also at room temperature. These two mixtures, namely fatty alcohol sulfonate and gum tragacanth on the one hand and gelatin and borax on the other hand again mixed together at room temperature and the mixture of the four basic ingredients Heated to 50 to 90 ° C for about 1 hour to drive off moisture. After heating and Drying, the mixture is again carefully stirred, expediently in a mixer, whereupon let it cool down to room temperature. The mixture is then completely homogeneous. Upon need if you add a preservative to this mixture to protect it from spoilage, especially if longer storage is intended or unavoidable.
Das fertige Gemisch kann vorteilhaft auch zu Tabletten verpreßt werden. In diesem Fall wird dem Pulver ein den Zerfall der geformten Mischung in Wasser beschleunigender Zusatzstoff, zweckmäßigerweise ein Kohlensäure entwickelndes Mittel, beigefügt. The finished mixture can advantageously also be compressed into tablets. In this case the Powder an additive which accelerates the disintegration of the formed mixture in water, expediently a carbonating agent added.
809 747/407809 747/407
Bei der Auflösung der Tabletten oder des Pulvers in Wasser soll die Temperatur mindestens 20° C und höchstens 60° C betragen. Das Gewichtsverhältnis zwischen festem Stoff und Wasser soll etwa 1 : 10 betragen. When dissolving the tablets or the powder in water, the temperature should be at least 20 ° C and not exceed 60 ° C. The weight ratio between solid and water should be about 1:10.
Als Beispiele für eine zweckmäßige Zusammensetzung der Mischungen werden die nachstehenden Rezepturen genannt:The following are given as examples of a suitable composition of the mixtures Recipes called:
B e i s ρ i e 1 1B e i s ρ i e 1 1
Fettalkoholsulfonat etwa 44 °/oFatty alcohol sulfonate about 44%
Borax etwa 35 %Borax about 35%
Gelatine etwa 18 °/oGelatin about 18%
Tragantgummi etwa 3 %> ,Gum tragacanth about 3%>,
Fettalkoholsulfonat etwa 42 %■Fatty alcohol sulfonate about 42% ■
Borax >etwa 34 %Borax> about 34%
\\ 4 ■* 4 ■ *
Gelatine etwa 17 % '■,Gelatin about 17%,
Tragantgummi, etwa 3 %Gum tragacanth, about 3%
Konservierutjgs- und Disper-Preservation and dispersing
gierungsimttel etwa 4 °/oGierungsimttel about 4 ° / o
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1265455A GB780355A (en) | 1955-05-02 | 1955-05-02 | Dissoluble preparation, a method for its manufacture and a solution manufactured from the preparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1049352B true DE1049352B (en) | 1959-01-29 |
Family
ID=10008679
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT1049352D Pending DE1049352B (en) | 1955-05-02 | Mixture for making soap bubbles |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE537797A (en) |
| DE (1) | DE1049352B (en) |
| FR (1) | FR1123216A (en) |
| GB (1) | GB780355A (en) |
| NL (1) | NL85446C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6008172A (en) * | 1994-06-09 | 1999-12-28 | Broshi; Oded | Non-toxic, pleasant tasting bubble making composition |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022258453A1 (en) * | 2021-06-07 | 2022-12-15 | Unilever Ip Holdings B.V. | A tablet composition |
-
0
- DE DENDAT1049352D patent/DE1049352B/en active Pending
-
1955
- 1955-04-20 NL NL196899A patent/NL85446C/xx active
- 1955-04-20 BE BE537797D patent/BE537797A/xx unknown
- 1955-05-02 FR FR1123216D patent/FR1123216A/en not_active Expired
- 1955-05-02 GB GB1265455A patent/GB780355A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6008172A (en) * | 1994-06-09 | 1999-12-28 | Broshi; Oded | Non-toxic, pleasant tasting bubble making composition |
Also Published As
| Publication number | Publication date |
|---|---|
| BE537797A (en) | 1959-06-05 |
| NL85446C (en) | 1957-06-15 |
| FR1123216A (en) | 1956-09-19 |
| NL196899B (en) | 1957-01-15 |
| GB780355A (en) | 1957-07-31 |
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