CZ306030B6 - Vodná pesticidní koncentrátová mikroemulzní kompozice - Google Patents

Vodná pesticidní koncentrátová mikroemulzní kompozice Download PDF

Info

Publication number: CZ306030B6
Authority: CZ; Czechia
Prior art keywords: carbon atoms; hydrocarbyl; independently; hydrogen; linear
Prior art date: 2001-05-21

Application number

CZ2003-3166A

Other languages

Czech (cs)

English (en)

Other versions

CZ20033166A3 (cs

Inventor

Norman R. Pallas

Jane L. Gillespie

Lata Singh

Xiaodong C. Xu

Original Assignee

Monsanto Technology Llc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2001-05-21

Filing date

2002-05-21

Publication date

2016-07-07

2001-05-21 Priority claimed from PCT/US2001/016550 external-priority patent/WO2001089302A2/en

2001-11-19 Priority claimed from US09/988,352 external-priority patent/US7135437B2/en

2002-05-21 Application filed by Monsanto Technology Llc filed Critical Monsanto Technology Llc

2004-08-18 Publication of CZ20033166A3 publication Critical patent/CZ20033166A3/cs

2016-07-07 Publication of CZ306030B6 publication Critical patent/CZ306030B6/cs

Links

239000012141 concentrate Substances 0.000 title claims abstract description 49
239000004530 micro-emulsion Substances 0.000 title claims abstract description 33
230000000361 pesticidal effect Effects 0.000 title claims abstract description 10
239000000203 mixture Substances 0.000 title claims description 514
238000003860 storage Methods 0.000 claims abstract description 19
125000004432 carbon atom Chemical group C* 0.000 claims description 456
239000003381 stabilizer Substances 0.000 claims description 325
125000000217 alkyl group Chemical group 0.000 claims description 296
239000004094 surface-active agent Substances 0.000 claims description 294
125000001183 hydrocarbyl group Chemical group 0.000 claims description 284
229910052739 hydrogen Inorganic materials 0.000 claims description 264
239000001257 hydrogen Substances 0.000 claims description 264
XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 claims description 194
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 175
239000005562 Glyphosate Substances 0.000 claims description 146
229940097068 glyphosate Drugs 0.000 claims description 146
125000000743 hydrocarbylene group Chemical group 0.000 claims description 145
UUEVFMOUBSLVJW-UHFFFAOYSA-N oxo-[[1-[2-[2-[2-[4-(oxoazaniumylmethylidene)pyridin-1-yl]ethoxy]ethoxy]ethyl]pyridin-4-ylidene]methyl]azanium;dibromide Chemical compound [Br-].[Br-].C1=CC(=C[NH+]=O)C=CN1CCOCCOCCN1C=CC(=C[NH+]=O)C=C1 UUEVFMOUBSLVJW-UHFFFAOYSA-N 0.000 claims description 129
-1 amine salt Chemical class 0.000 claims description 93
150000002431 hydrogen Chemical class 0.000 claims description 88
150000003839 salts Chemical class 0.000 claims description 70
125000003118 aryl group Chemical group 0.000 claims description 69
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 68
150000001412 amines Chemical class 0.000 claims description 56
125000002768 hydroxyalkyl group Chemical group 0.000 claims description 48
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 48
239000003093 cationic surfactant Substances 0.000 claims description 47
229910001868 water Inorganic materials 0.000 claims description 46
239000000839 emulsion Substances 0.000 claims description 31
239000002736 nonionic surfactant Substances 0.000 claims description 27
239000002253 acid Substances 0.000 claims description 26
150000001450 anions Chemical class 0.000 claims description 25
150000001875 compounds Chemical class 0.000 claims description 23
150000002148 esters Chemical class 0.000 claims description 22
238000002425 crystallisation Methods 0.000 claims description 21
230000008025 crystallization Effects 0.000 claims description 21
239000000575 pesticide Substances 0.000 claims description 21
229910052799 carbon Inorganic materials 0.000 claims description 20
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 19
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 17
239000008346 aqueous phase Substances 0.000 claims description 16
150000003242 quaternary ammonium salts Chemical class 0.000 claims description 15
XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 13
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 12
229930182470 glycoside Natural products 0.000 claims description 12
125000000623 heterocyclic group Chemical group 0.000 claims description 12
239000003960 organic solvent Substances 0.000 claims description 11
125000001453 quaternary ammonium group Chemical group 0.000 claims description 11
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 10
239000012736 aqueous medium Substances 0.000 claims description 10
150000004985 diamines Chemical class 0.000 claims description 10
WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims description 10
125000004429 atom Chemical group 0.000 claims description 9
229910052757 nitrogen Inorganic materials 0.000 claims description 9
229910052700 potassium Inorganic materials 0.000 claims description 9
239000011591 potassium Substances 0.000 claims description 9
QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 claims description 8
125000004122 cyclic group Chemical group 0.000 claims description 8
239000006185 dispersion Substances 0.000 claims description 8
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 8
PVSGXWMWNRGTKE-UHFFFAOYSA-N 5-methyl-2-[4-methyl-5-oxo-4-(propan-2-yl)-4,5-dihydro-1H-imidazol-2-yl]pyridine-3-carboxylic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC=C(C)C=C1C(O)=O PVSGXWMWNRGTKE-UHFFFAOYSA-N 0.000 claims description 7
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 7
125000004433 nitrogen atom Chemical group N* 0.000 claims description 7
239000011734 sodium Substances 0.000 claims description 7
229910052708 sodium Inorganic materials 0.000 claims description 7
NQQVFXUMIDALNH-UHFFFAOYSA-N picloram Chemical compound NC1=C(Cl)C(Cl)=NC(C(O)=O)=C1Cl NQQVFXUMIDALNH-UHFFFAOYSA-N 0.000 claims description 6
239000000725 suspension Substances 0.000 claims description 5
YIVXMZJTEQBPQO-UHFFFAOYSA-N 2,4-DB Chemical compound OC(=O)CCCOC1=CC=C(Cl)C=C1Cl YIVXMZJTEQBPQO-UHFFFAOYSA-N 0.000 claims description 4
239000002794 2,4-DB Substances 0.000 claims description 4
MZHCENGPTKEIGP-UHFFFAOYSA-N 2-(2,4-dichlorophenoxy)propanoic acid Chemical compound OC(=O)C(C)OC1=CC=C(Cl)C=C1Cl MZHCENGPTKEIGP-UHFFFAOYSA-N 0.000 claims description 4
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 4
IAJOBQBIJHVGMQ-UHFFFAOYSA-N 2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid Chemical compound CP(O)(=O)CCC(N)C(O)=O IAJOBQBIJHVGMQ-UHFFFAOYSA-N 0.000 claims description 4
HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 claims description 4
239000005561 Glufosinate Substances 0.000 claims description 4
239000005595 Picloram Substances 0.000 claims description 4
150000001408 amides Chemical class 0.000 claims description 4
GINJFDRNADDBIN-FXQIFTODSA-N bilanafos Chemical compound OC(=O)[C@H](C)NC(=O)[C@H](C)NC(=O)[C@@H](N)CCP(C)(O)=O GINJFDRNADDBIN-FXQIFTODSA-N 0.000 claims description 4
IWEDIXLBFLAXBO-UHFFFAOYSA-N dicamba Chemical compound COC1=C(Cl)C=CC(Cl)=C1C(O)=O IWEDIXLBFLAXBO-UHFFFAOYSA-N 0.000 claims description 4
QYPPRTNMGCREIM-UHFFFAOYSA-N methylarsonic acid Chemical compound C[As](O)(O)=O QYPPRTNMGCREIM-UHFFFAOYSA-N 0.000 claims description 4
FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 claims description 4
NRZWQKGABZFFKE-UHFFFAOYSA-N trimethylsulfonium Chemical class C[S+](C)C NRZWQKGABZFFKE-UHFFFAOYSA-N 0.000 claims description 4
WNTGYJSOUMFZEP-UHFFFAOYSA-N 2-(4-chloro-2-methylphenoxy)propanoic acid Chemical compound OC(=O)C(C)OC1=CC=C(Cl)C=C1C WNTGYJSOUMFZEP-UHFFFAOYSA-N 0.000 claims description 3
NUPJIGQFXCQJBK-UHFFFAOYSA-N 2-(4-isopropyl-4-methyl-5-oxo-4,5-dihydro-1H-imidazol-2-yl)-5-(methoxymethyl)nicotinic acid Chemical compound OC(=O)C1=CC(COC)=CN=C1C1=NC(C)(C(C)C)C(=O)N1 NUPJIGQFXCQJBK-UHFFFAOYSA-N 0.000 claims description 3
239000005500 Clopyralid Substances 0.000 claims description 3
239000005566 Imazamox Substances 0.000 claims description 3
239000005627 Triclopyr Substances 0.000 claims description 3
VGPYEHKOIGNJKV-UHFFFAOYSA-N asulam Chemical compound COC(=O)NS(=O)(=O)C1=CC=C(N)C=C1 VGPYEHKOIGNJKV-UHFFFAOYSA-N 0.000 claims description 3
HUBANNPOLNYSAD-UHFFFAOYSA-N clopyralid Chemical compound OC(=O)C1=NC(Cl)=CC=C1Cl HUBANNPOLNYSAD-UHFFFAOYSA-N 0.000 claims description 3
150000002338 glycosides Chemical class 0.000 claims description 3
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
JXTHEWSKYLZVJC-UHFFFAOYSA-N naptalam Chemical compound OC(=O)C1=CC=CC=C1C(=O)NC1=CC=CC2=CC=CC=C12 JXTHEWSKYLZVJC-UHFFFAOYSA-N 0.000 claims description 3
FIKAKWIAUPDISJ-UHFFFAOYSA-L paraquat dichloride Chemical compound [Cl-].[Cl-].C1=C[N+](C)=CC=C1C1=CC=[N+](C)C=C1 FIKAKWIAUPDISJ-UHFFFAOYSA-L 0.000 claims description 3
FFSSWMQPCJRCRV-UHFFFAOYSA-N quinclorac Chemical compound ClC1=CN=C2C(C(=O)O)=C(Cl)C=CC2=C1 FFSSWMQPCJRCRV-UHFFFAOYSA-N 0.000 claims description 3
REEQLXCGVXDJSQ-UHFFFAOYSA-N trichlopyr Chemical compound OC(=O)COC1=NC(Cl)=C(Cl)C=C1Cl REEQLXCGVXDJSQ-UHFFFAOYSA-N 0.000 claims description 3
GXEKYRXVRROBEV-FBXFSONDSA-N (1r,2s,3r,4s)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic acid Chemical compound C1C[C@@H]2[C@@H](C(O)=O)[C@@H](C(=O)O)[C@H]1O2 GXEKYRXVRROBEV-FBXFSONDSA-N 0.000 claims description 2
XZIDTOHMJBOSOX-UHFFFAOYSA-N 2,3,6-TBA Chemical compound OC(=O)C1=C(Cl)C=CC(Cl)=C1Cl XZIDTOHMJBOSOX-UHFFFAOYSA-N 0.000 claims description 2
GQQIAHNFBAFBCS-UHFFFAOYSA-N 2-[2-chloro-5-(1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)-4-fluorophenoxy]acetic acid Chemical compound C1=C(Cl)C(OCC(=O)O)=CC(N2C(C3=C(CCCC3)C2=O)=O)=C1F GQQIAHNFBAFBCS-UHFFFAOYSA-N 0.000 claims description 2
MPPOHAUSNPTFAJ-UHFFFAOYSA-N 2-[4-[(6-chloro-1,3-benzoxazol-2-yl)oxy]phenoxy]propanoic acid Chemical compound C1=CC(OC(C)C(O)=O)=CC=C1OC1=NC2=CC=C(Cl)C=C2O1 MPPOHAUSNPTFAJ-UHFFFAOYSA-N 0.000 claims description 2
UPMXNNIRAGDFEH-UHFFFAOYSA-N 3,5-dibromo-4-hydroxybenzonitrile Chemical compound OC1=C(Br)C=C(C#N)C=C1Br UPMXNNIRAGDFEH-UHFFFAOYSA-N 0.000 claims description 2
CTSLUCNDVMMDHG-UHFFFAOYSA-N 5-bromo-3-(butan-2-yl)-6-methylpyrimidine-2,4(1H,3H)-dione Chemical compound CCC(C)N1C(=O)NC(C)=C(Br)C1=O CTSLUCNDVMMDHG-UHFFFAOYSA-N 0.000 claims description 2
239000005476 Bentazone Substances 0.000 claims description 2
239000005489 Bromoxynil Substances 0.000 claims description 2
HSSBORCLYSCBJR-UHFFFAOYSA-N Chloramben Chemical compound NC1=CC(Cl)=CC(C(O)=O)=C1Cl HSSBORCLYSCBJR-UHFFFAOYSA-N 0.000 claims description 2
NDUPDOJHUQKPAG-UHFFFAOYSA-N Dalapon Chemical compound CC(Cl)(Cl)C(O)=O NDUPDOJHUQKPAG-UHFFFAOYSA-N 0.000 claims description 2
LBGPXIPGGRQBJW-UHFFFAOYSA-N Difenzoquat Chemical compound C[N+]=1N(C)C(C=2C=CC=CC=2)=CC=1C1=CC=CC=C1 LBGPXIPGGRQBJW-UHFFFAOYSA-N 0.000 claims description 2
239000005630 Diquat Substances 0.000 claims description 2
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 2
DHAHEVIQIYRFRG-UHFFFAOYSA-N Fluoroglycofen Chemical compound C1=C([N+]([O-])=O)C(C(=O)OCC(=O)O)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 DHAHEVIQIYRFRG-UHFFFAOYSA-N 0.000 claims description 2
PXRROZVNOOEPPZ-UHFFFAOYSA-N Flupropanate Chemical compound OC(=O)C(F)(F)C(F)F PXRROZVNOOEPPZ-UHFFFAOYSA-N 0.000 claims description 2
NUFNQYOELLVIPL-UHFFFAOYSA-N acifluorfen Chemical compound C1=C([N+]([O-])=O)C(C(=O)O)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 NUFNQYOELLVIPL-UHFFFAOYSA-N 0.000 claims description 2
OTSAMNSACVKIOJ-UHFFFAOYSA-N azane;carbamoyl(ethoxy)phosphinic acid Chemical compound [NH4+].CCOP([O-])(=O)C(N)=O OTSAMNSACVKIOJ-UHFFFAOYSA-N 0.000 claims description 2
ZOMSMJKLGFBRBS-UHFFFAOYSA-N bentazone Chemical compound C1=CC=C2NS(=O)(=O)N(C(C)C)C(=O)C2=C1 ZOMSMJKLGFBRBS-UHFFFAOYSA-N 0.000 claims description 2
CNBGNNVCVSKAQZ-UHFFFAOYSA-N benzidamine Natural products C12=CC=CC=C2C(OCCCN(C)C)=NN1CC1=CC=CC=C1 CNBGNNVCVSKAQZ-UHFFFAOYSA-N 0.000 claims description 2
QZXCCPZJCKEPSA-UHFFFAOYSA-N chlorfenac Chemical compound OC(=O)CC1=C(Cl)C=CC(Cl)=C1Cl QZXCCPZJCKEPSA-UHFFFAOYSA-N 0.000 claims description 2
FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 claims description 2
229940106681 chloroacetic acid Drugs 0.000 claims description 2
SYJFEGQWDCRVNX-UHFFFAOYSA-N diquat Chemical compound C1=CC=[N+]2CC[N+]3=CC=CC=C3C2=C1 SYJFEGQWDCRVNX-UHFFFAOYSA-N 0.000 claims description 2
239000002609 medium Substances 0.000 claims description 2
229960002939 metizoline Drugs 0.000 claims description 2
LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 claims description 2
238000006116 polymerization reaction Methods 0.000 claims description 2
150000003335 secondary amines Chemical class 0.000 claims description 2
RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 claims description 2
125000005537 sulfoxonium group Chemical group 0.000 claims description 2
150000003512 tertiary amines Chemical class 0.000 claims description 2
OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 claims 1
OVSKIKFHRZPJSS-DOMIDYPGSA-N 2-(2,4-dichlorophenoxy)acetic acid Chemical compound OC(=O)[14CH2]OC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-DOMIDYPGSA-N 0.000 claims 1
CLQMBPJKHLGMQK-UHFFFAOYSA-N 2-(4-isopropyl-4-methyl-5-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC=CC=C1C(O)=O CLQMBPJKHLGMQK-UHFFFAOYSA-N 0.000 claims 1
CABMTIJINOIHOD-UHFFFAOYSA-N 2-[4-methyl-5-oxo-4-(propan-2-yl)-4,5-dihydro-1H-imidazol-2-yl]quinoline-3-carboxylic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC2=CC=CC=C2C=C1C(O)=O CABMTIJINOIHOD-UHFFFAOYSA-N 0.000 claims 1
239000005504 Dicamba Substances 0.000 claims 1
YQVMVCCFZCMYQB-UHFFFAOYSA-N Flamprop Chemical compound C=1C=C(F)C(Cl)=CC=1N(C(C)C(O)=O)C(=O)C1=CC=CC=C1 YQVMVCCFZCMYQB-UHFFFAOYSA-N 0.000 claims 1
239000005981 Imazaquin Substances 0.000 claims 1
BGZZWXTVIYUUEY-UHFFFAOYSA-N fomesafen Chemical compound C1=C([N+]([O-])=O)C(C(=O)NS(=O)(=O)C)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 BGZZWXTVIYUUEY-UHFFFAOYSA-N 0.000 claims 1
WXUNXXKSYBUHMK-UHFFFAOYSA-N methyl 4-methyl-2-(4-methyl-5-oxo-4-propan-2-yl-1h-imidazol-2-yl)benzoate;methyl 5-methyl-2-(4-methyl-5-oxo-4-propan-2-yl-1h-imidazol-2-yl)benzoate Chemical compound COC(=O)C1=CC=C(C)C=C1C1=NC(C)(C(C)C)C(=O)N1.COC(=O)C1=CC(C)=CC=C1C1=NC(C)(C(C)C)C(=O)N1 WXUNXXKSYBUHMK-UHFFFAOYSA-N 0.000 claims 1
NDNKHWUXXOFHTD-UHFFFAOYSA-N metizoline Chemical compound CC=1SC2=CC=CC=C2C=1CC1=NCCN1 NDNKHWUXXOFHTD-UHFFFAOYSA-N 0.000 claims 1
YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 claims 1
IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 359
LIOPHZNMBKHGAV-UHFFFAOYSA-M potassium;2-(phosphonomethylamino)acetate Chemical compound [K+].OC(=O)CNCP(O)([O-])=O LIOPHZNMBKHGAV-UHFFFAOYSA-M 0.000 description 149
238000011156 evaluation Methods 0.000 description 138
238000012360 testing method Methods 0.000 description 138
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125000000304 alkynyl group Chemical group 0.000 description 46
235000008504 concentrate Nutrition 0.000 description 45
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ZEKANFGSDXODPD-UHFFFAOYSA-N glyphosate-isopropylammonium Chemical compound CC(C)N.OC(=O)CNCP(O)(O)=O ZEKANFGSDXODPD-UHFFFAOYSA-N 0.000 description 35
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238000011282 treatment Methods 0.000 description 18
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 15
229920003171 Poly (ethylene oxide) Polymers 0.000 description 15
235000019441 ethanol Nutrition 0.000 description 15
239000005631 2,4-Dichlorophenoxyacetic acid Substances 0.000 description 13
239000012071 phase Substances 0.000 description 13
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150000003973 alkyl amines Chemical group 0.000 description 12
125000005018 aryl alkenyl group Chemical group 0.000 description 11
125000002887 hydroxy group Chemical group [H]O* 0.000 description 11
230000005764 inhibitory process Effects 0.000 description 11
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238000000034 method Methods 0.000 description 10
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
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MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Natural products OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 8
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235000019198 oils Nutrition 0.000 description 8
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229940038773 trisodium citrate Drugs 0.000 description 1
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
235000015112 vegetable and seed oil Nutrition 0.000 description 1
239000008158 vegetable oil Substances 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1

Classifications

- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals

Landscapes

Life Sciences & Earth Sciences (AREA)
General Health & Medical Sciences (AREA)
Health & Medical Sciences (AREA)
Pest Control & Pesticides (AREA)
Agronomy & Crop Science (AREA)
Plant Pathology (AREA)
Engineering & Computer Science (AREA)
Dentistry (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Environmental Sciences (AREA)
Dispersion Chemistry (AREA)
Chemical & Material Sciences (AREA)
Toxicology (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)

CZ2003-3166A 2001-05-21 2002-05-21 Vodná pesticidní koncentrátová mikroemulzní kompozice CZ306030B6 (cs)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
PCT/US2001/016550 WO2001089302A2 (en)	2000-05-19	2001-05-21	Aqueous pesticide formulations and novel surfactants
US92652101A	2001-11-14	2001-11-14
US09/988,352 US7135437B2 (en)	2000-05-19	2001-11-19	Stable liquid pesticide compositions
PCT/US2002/016032 WO2002096199A2 (en)	2001-05-21	2002-05-21	Stable liquid pesticide compositions

Publications (2)

Publication Number	Publication Date
CZ20033166A3 CZ20033166A3 (cs)	2004-08-18
CZ306030B6 true CZ306030B6 (cs)	2016-07-07

Family

ID=32830104

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CZ2003-3166A CZ306030B6 (cs)	2001-05-21	2002-05-21	Vodná pesticidní koncentrátová mikroemulzní kompozice

Country Status (7)

Country	Link
AR (1)	AR036024A1 (es)
CA (1)	CA2447869C (es)
CO (1)	CO5540357A2 (es)
CR (1)	CR7161A (es)
CZ (1)	CZ306030B6 (es)
MY (1)	MY140071A (es)
PL (1)	PL367441A1 (es)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0485207A1 (en) *	1990-11-07	1992-05-13	Rhone-Poulenc Agrochimie	Stabilized oil-in-water emulsions
GB2267825A (en) *	1992-05-26	1993-12-22	Dowelanco	Herbicide microemulsion concentrate
EP0617894A1 (en) *	1993-04-02	1994-10-05	Monsanto Europe S.A./N.V.	Liquid concentrated herbicidal glyphosate compositions
DE19752552A1 (de) *	1997-11-27	1999-06-02	Hoechst Schering Agrevo Gmbh	Tensidsysteme für flüssige wässrige Zubereitungen
WO2001010210A2 (en) *	1999-08-11	2001-02-15	Monsanto Technology Llc	Microemulsion coformulation of a graminicide and a water-soluble herbicide

2002
- 2002-05-21 CA CA2447869A patent/CA2447869C/en not_active Expired - Lifetime
- 2002-05-21 MY MYPI20021868A patent/MY140071A/en unknown
- 2002-05-21 CZ CZ2003-3166A patent/CZ306030B6/cs not_active IP Right Cessation
- 2002-05-21 PL PL02367441A patent/PL367441A1/xx not_active Application Discontinuation
- 2002-05-21 AR ARP020101886A patent/AR036024A1/es active IP Right Grant
2003
- 2003-11-20 CO CO03102526A patent/CO5540357A2/es not_active Application Discontinuation
- 2003-11-21 CR CR7161A patent/CR7161A/es not_active Application Discontinuation

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0485207A1 (en) *	1990-11-07	1992-05-13	Rhone-Poulenc Agrochimie	Stabilized oil-in-water emulsions
GB2267825A (en) *	1992-05-26	1993-12-22	Dowelanco	Herbicide microemulsion concentrate
EP0617894A1 (en) *	1993-04-02	1994-10-05	Monsanto Europe S.A./N.V.	Liquid concentrated herbicidal glyphosate compositions
DE19752552A1 (de) *	1997-11-27	1999-06-02	Hoechst Schering Agrevo Gmbh	Tensidsysteme für flüssige wässrige Zubereitungen
WO2001010210A2 (en) *	1999-08-11	2001-02-15	Monsanto Technology Llc	Microemulsion coformulation of a graminicide and a water-soluble herbicide

Also Published As

Publication number	Publication date
PL367441A1 (en)	2005-02-21
CZ20033166A3 (cs)	2004-08-18
AR036024A1 (es)	2004-08-04
CO5540357A2 (es)	2005-07-29
MY140071A (en)	2009-11-30
CR7161A (es)	2004-07-02
CA2447869C (en)	2010-08-10
CA2447869A1 (en)	2002-12-05

Publication	Publication Date	Title
AU2002259275B2 (en)	2007-03-22	Stable liquid pesticide compositions
US7723265B2 (en)	2010-05-25	Pesticide compositions containing oxalic acid
AU2002318146B2 (en)	2007-05-10	Pesticide concentrates containing etheramine surfactants
CA2439689C (en)	2012-12-04	Pesticide compositions containing oxalic acid
AU2002259275A1 (en)	2003-05-08	Stable liquid pesticide compositions
EP1133233B1 (en)	2004-09-08	Highly concentrated aqueous glyphosate compositions
RU2190329C2 (ru)	2002-10-10	Гербицидные композиции, способ уничтожения или подавления сорняков или нежелательных растений
AU2002318146A1 (en)	2003-05-15	Pesticide concentrates containing etheramine surfactants
MXPA05002368A (es)	2005-05-23	Composiciones de pesticidas que contienen acidos dicarboxilicos.
AU2002245592A1 (en)	2003-03-13	Pesticide compositions containing oxalic acid
US20030096708A1 (en)	2003-05-22	Pesticide concentrates containing etheramine surfactants
RU2291619C2 (ru)	2007-01-20	Водные композиции гербицидного концентрата, способ снижения содержания поверхностно-активного компонента в водной композиции гербицидного концентрата, способ подавления роста ипомеи, твердая композиция гербицидного концентрата
CZ306030B6 (cs)	2016-07-07	Vodná pesticidní koncentrátová mikroemulzní kompozice
NZ547570A (en)	2008-03-28	Stable liquid pesticide compositions
NZ527766A (en)	2006-08-31	Pesticide compositions containing oxalic acid
HUP0401010A2 (hu)	2004-09-28	Éteramin felületaktív anyagokat tartalmazó peszticid koncentrátumok

Legal Events

Date	Code	Title	Description
2022-06-01	MK4A	Patent expired	Effective date: 20220521