CR9805A - Proceso para la produccion de amidas - Google Patents
Proceso para la produccion de amidasInfo
- Publication number
- CR9805A CR9805A CR9805A CR9805A CR9805A CR 9805 A CR9805 A CR 9805A CR 9805 A CR9805 A CR 9805A CR 9805 A CR9805 A CR 9805A CR 9805 A CR9805 A CR 9805A
- Authority
- CR
- Costa Rica
- Prior art keywords
- formula
- compound
- reaction
- amidas
- production
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 8
- 239000003638 chemical reducing agent Substances 0.000 abstract 2
- 125000006527 (C1-C5) alkyl group Chemical group 0.000 abstract 1
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 abstract 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical group FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 1
- 229910052731 fluorine Inorganic materials 0.000 abstract 1
- 239000011737 fluorine Chemical group 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical group II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C211/57—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings being part of condensed ring systems of the carbon skeleton
- C07C211/61—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings being part of condensed ring systems of the carbon skeleton with at least one of the condensed ring systems formed by three or more rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
- C07C205/06—Compounds containing nitro groups bound to a carbon skeleton having nitro groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
- C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
- C07C209/325—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups reduction by other means than indicated in C07C209/34 or C07C209/36
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
- C07C209/70—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by reduction of unsaturated amines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2603/00—Systems containing at least three condensed rings
- C07C2603/56—Ring systems containing bridged rings
- C07C2603/58—Ring systems containing bridged rings containing three rings
- C07C2603/60—Ring systems containing bridged rings containing three rings containing at least one ring with less than six members
- C07C2603/66—Ring systems containing bridged rings containing three rings containing at least one ring with less than six members containing five-membered rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Hydrogenated Pyridines (AREA)
Abstract
Se refiere al proceso para la preparacion de compuestos de la formula en la cual R1 y R2 son cada uno independientes de los otros hidrogeno o C1-C5 alkilo y R3 es CF3 o CF2H por a) reaccion de un compuesto de la formula (II) en la cual R1 y R2 son como estan definidas para la formula (I) con al menos un agente reductor para formar un compuesto de formula (III) en el cual R1 y R2 son como estan definidas para la formula (I), y b) reaccion de ese compuesto con al menos un agente reductor para formar un compuesto de la formula (IV) en el cual R1 y R2, son como estan definidos en la formula (I) y (c) reaccion de ese compuesto con un compuesto de formula (V) en el cual Q es cloro, fluor, bromo, yodo, hidroxido o C1-C6 alkoxi y R3 es como se define en la formula (I) para formar el compuesto de la formula (I); y para intermediarios novedosos para utilizarse en ese proceso.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH15202005 | 2005-09-16 | ||
| CH2962006 | 2006-02-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CR9805A true CR9805A (es) | 2008-07-31 |
Family
ID=37467494
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CR9805A CR9805A (es) | 2005-09-16 | 2008-03-07 | Proceso para la produccion de amidas |
Country Status (18)
| Country | Link |
|---|---|
| US (3) | US7994341B2 (es) |
| EP (3) | EP2253622A1 (es) |
| JP (1) | JP5118043B2 (es) |
| CN (5) | CN101979374A (es) |
| AR (1) | AR058050A1 (es) |
| AU (1) | AU2006291419B2 (es) |
| BR (1) | BRPI0616238B1 (es) |
| CA (1) | CA2622097C (es) |
| CL (1) | CL2011000514A1 (es) |
| CO (1) | CO6382182A2 (es) |
| CR (1) | CR9805A (es) |
| EA (2) | EA201000345A1 (es) |
| EC (1) | ECSP088264A (es) |
| ES (1) | ES2397932T3 (es) |
| IL (2) | IL189757A (es) |
| SG (1) | SG165380A1 (es) |
| TW (2) | TW200804292A (es) |
| WO (1) | WO2007031323A1 (es) |
Families Citing this family (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE516275T1 (de) * | 2002-08-22 | 2011-07-15 | Syngenta Participations Ag | Microbiozide (z.b. fungizide) 1,2,3- triazolderivate |
| BRPI0710305A2 (pt) * | 2006-04-06 | 2011-08-09 | Syngenta Participations Ag | composições fingicidas |
| PL2086944T3 (pl) | 2006-11-03 | 2010-06-30 | Basf Se | Sposób wytwarzania difluormetylopirazolilokarboksylanów |
| UA96971C2 (ru) * | 2006-12-21 | 2011-12-26 | Басф Се | Способ получения фторметилзамещенных гетероциклических соединений |
| PT2120577E (pt) * | 2007-03-16 | 2014-12-22 | Syngenta Ltd | Nova forma sólida de um microbiocida |
| WO2008145740A1 (de) | 2007-06-01 | 2008-12-04 | Basf Se | Verfahren zur herstellung n-substituierter (3-dihalomethyl-1-methyl-pyrazol-4-yl)carboxamide |
| BRPI0812958A2 (pt) | 2007-06-15 | 2014-12-09 | Basf Se | Processo para preparar compostos, uso de compostos, e, compostos |
| EP2008996A1 (en) | 2007-06-27 | 2008-12-31 | Syngeta Participations AG | Process for the production of pyrazoles |
| EP2262756B1 (en) | 2008-02-29 | 2016-08-31 | Basf Se | Process for preparing alkyl 2-alkoxymethylene-4,4-difluoro-3-oxobutyrates |
| EP2297111B1 (de) | 2008-05-02 | 2012-06-20 | Basf Se | Verfahren zur herstellung halogensubstituierter 2-(aminomethyliden)-3-oxobuttersäureester |
| WO2009133178A1 (de) | 2008-05-02 | 2009-11-05 | Basf Se | Verfahren zur herstellung von 2-(aminomethyliden)-4,4-difluor-3-oxobuttersäureestern |
| WO2009135808A2 (de) | 2008-05-05 | 2009-11-12 | Basf Se | Verfahren zur herstellung von 1,3,4-substituierten pyrazolverbindungen |
| DK2285779T3 (da) | 2008-05-08 | 2013-06-24 | Basf Se | Fremgangsmåde til fremstilling af arylcarboxamider |
| CN102026982A (zh) * | 2008-05-14 | 2011-04-20 | 先正达参股股份有限公司 | 制备酰胺的方法 |
| EP2307384B1 (en) | 2008-07-21 | 2012-04-25 | Basf Se | Process for preparing 1,3-disubstituted pyrazolecarboxylic esters |
| CN102197016B (zh) * | 2008-10-27 | 2013-12-18 | 先正达参股股份有限公司 | 苯并降冰片烯的制备方法 |
| JP2012513961A (ja) * | 2008-12-24 | 2012-06-21 | シンジェンタ リミテッド | 殺菌剤の調製方法 |
| WO2011098386A1 (en) | 2010-02-09 | 2011-08-18 | Syngenta Participations Ag | Process for the preparation of an anthranilic acid derivative |
| JP5684895B2 (ja) * | 2010-04-20 | 2015-03-18 | シンジェンタ パーティシペーションズ アクチェンゲゼルシャフト | ピラゾールカルボン酸アミドの調製方法 |
| CN103097362B (zh) * | 2010-06-07 | 2015-06-10 | 陶氏益农公司 | 作为杀真菌剂的吡嗪基甲酰胺 |
| US8309747B2 (en) * | 2010-07-06 | 2012-11-13 | Chevron Phillips Chemical Company Lp | Process for synthesizing bridged cyclopentadienyl-indenyl metallocenes |
| EP2632901B1 (en) | 2010-10-27 | 2018-09-12 | Solvay Sa | Process for the preparation of pyrazole-4-carboxamides |
| WO2012065947A1 (en) * | 2010-11-15 | 2012-05-24 | Bayer Cropscience Ag | 5-halogenopyrazolecarboxamides |
| US20140128617A1 (en) * | 2011-06-21 | 2014-05-08 | Wahed Ahmed Moradi | Method for producing pyrazolylcarboxanilides |
| EP2850066B1 (de) * | 2012-05-14 | 2016-03-16 | Bayer CropScience AG | Verfahren zum herstellen von 1-alkyl-3-fluoralkyl-1h-pyrazol-4-carbonsäurechloriden |
| US20150175974A1 (en) * | 2012-06-11 | 2015-06-25 | Syngenta Participations Ag | Producing solids and related mother liquors |
| CN104649973B (zh) | 2013-11-25 | 2017-02-15 | 沈阳中化农药化工研发有限公司 | 一种吡唑酰胺类化合物及其用途 |
| GB201403438D0 (en) * | 2014-02-27 | 2014-04-16 | Syngenta Participations Ag | Polymorphs |
| EP2980078A1 (en) | 2014-07-29 | 2016-02-03 | Solvay SA | Process for the preparation of pyrazole-4-carboxamides |
| BR112017014498B1 (pt) | 2015-05-06 | 2022-05-31 | Shenyang Sinochem Agrochemicals R&D Co., LTD | Composto de amida e o método de preparação e uso do mesmo |
| EP3408259A1 (en) | 2016-01-28 | 2018-12-05 | Solvay SA | Halogen substituted diketones, pyrazole compounds and processes for the manufacture of pyrazole compounds |
| JP2019515938A (ja) | 2016-05-10 | 2019-06-13 | ソルヴェイ（ソシエテ アノニム） | ３−（ハロアルキルまたはホルミル）−１ｈ−ピラゾール−４−カルボン酸またはエステルを含む組成物、その製造、およびカルボキサミド調製のためのその使用 |
| JP2019524765A (ja) | 2016-08-02 | 2019-09-05 | ソルヴェイ（ソシエテ アノニム） | ピラゾールカルボン酸および誘導体の製造に有用なヒドラジニル化合物の製造、ヒドラジニル化合物ならびにその使用 |
| CN106045910B (zh) * | 2016-08-15 | 2017-10-10 | 浙江永太科技股份有限公司 | 一种3‑(二氟甲基)‑1‑甲基‑1h‑吡唑‑4‑羧酸的合成方法 |
| CN106279025B (zh) * | 2016-08-15 | 2017-10-10 | 浙江永太科技股份有限公司 | 一种含吡唑环的二酯化合物及其制备方法 |
| EP3535245A1 (en) | 2016-11-07 | 2019-09-11 | Solvay SA | Process for the manufacture of carboxylic acids or carboxylic acid derivatives |
| WO2018201272A1 (en) | 2017-05-02 | 2018-11-08 | Solvay Fluor Gmbh | Process for the manufacture of carboxylic acids or carboxylic acid derivatives |
| US20200181091A1 (en) * | 2017-08-28 | 2020-06-11 | Japan Finechem Company, Inc. | Production method for pyrazole-4-carboxamide derivative |
| EP3495351A1 (en) | 2017-12-08 | 2019-06-12 | Solvay Sa | Oxidation of a pyrazolyl ketone compound to the corresponding carboxylic acid |
| JP2021506879A (ja) | 2017-12-22 | 2021-02-22 | ソルヴェイ（ソシエテ アノニム） | ピラゾールカルボン酸誘導体及びその前駆体の製造のための方法 |
| CN111454157B (zh) * | 2020-05-14 | 2022-07-22 | 利民化学有限责任公司 | 一种3-硝基苯炔的制备方法 |
| CN112174891B (zh) * | 2020-11-02 | 2022-02-01 | 浙江省农业科学院 | 一种氟唑菌苯胺代谢物的制备方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10228103A1 (de) | 2002-06-24 | 2004-01-15 | Bayer Cropscience Ag | Fungizide Wirkstoffkombinationen |
| ATE516275T1 (de) * | 2002-08-22 | 2011-07-15 | Syngenta Participations Ag | Microbiozide (z.b. fungizide) 1,2,3- triazolderivate |
| GB0224316D0 (en) * | 2002-10-18 | 2002-11-27 | Syngenta Participations Ag | Chemical compounds |
| GB0422401D0 (en) * | 2004-10-08 | 2004-11-10 | Syngenta Participations Ag | Fungicidal compositions |
| CA2626312C (en) * | 2005-10-25 | 2014-10-07 | Hans Tobler | Heterocyclic amide derivatives useful as microbiocides |
-
2006
- 2006-09-14 BR BRPI0616238A patent/BRPI0616238B1/pt not_active IP Right Cessation
- 2006-09-14 TW TW095133966A patent/TW200804292A/zh unknown
- 2006-09-14 CN CN2010105057332A patent/CN101979374A/zh active Pending
- 2006-09-14 CN CN2010105057313A patent/CN101962363A/zh active Pending
- 2006-09-14 TW TW101130220A patent/TWI436984B/zh not_active IP Right Cessation
- 2006-09-14 CA CA2622097A patent/CA2622097C/en not_active Expired - Fee Related
- 2006-09-14 EP EP10175064A patent/EP2253622A1/en not_active Withdrawn
- 2006-09-14 CN CN2010105057366A patent/CN101962364B/zh not_active Expired - Fee Related
- 2006-09-14 CN CN2010105056984A patent/CN101979375A/zh active Pending
- 2006-09-14 JP JP2008530418A patent/JP5118043B2/ja not_active Expired - Fee Related
- 2006-09-14 AU AU2006291419A patent/AU2006291419B2/en not_active Ceased
- 2006-09-14 EP EP06805725A patent/EP1928838B1/en not_active Not-in-force
- 2006-09-14 WO PCT/EP2006/008982 patent/WO2007031323A1/en not_active Ceased
- 2006-09-14 US US12/066,683 patent/US7994341B2/en active Active
- 2006-09-14 SG SG201006670-2A patent/SG165380A1/en unknown
- 2006-09-14 CN CN2006800365540A patent/CN101277938B/zh not_active Expired - Fee Related
- 2006-09-14 EA EA201000345A patent/EA201000345A1/ru unknown
- 2006-09-14 EP EP10175067.7A patent/EP2253623B1/en not_active Not-in-force
- 2006-09-14 ES ES06805725T patent/ES2397932T3/es active Active
- 2006-09-14 EA EA200800840A patent/EA013638B1/ru not_active IP Right Cessation
- 2006-09-15 AR ARP060104046A patent/AR058050A1/es not_active Application Discontinuation
-
2008
- 2008-02-25 IL IL189757A patent/IL189757A/en not_active IP Right Cessation
- 2008-03-07 CR CR9805A patent/CR9805A/es unknown
- 2008-03-12 EC EC2008008264A patent/ECSP088264A/es unknown
- 2008-04-16 CO CO08038479A patent/CO6382182A2/es not_active Application Discontinuation
-
2011
- 2011-03-10 CL CL2011000514A patent/CL2011000514A1/es unknown
- 2011-08-05 US US13/198,739 patent/US8436037B2/en not_active Expired - Fee Related
- 2011-12-26 IL IL217212A patent/IL217212A0/en unknown
-
2013
- 2013-05-07 US US13/889,041 patent/US8680337B2/en active Active
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CR9805A (es) | Proceso para la produccion de amidas | |
| CR11129A (es) | Proceso para la produccion de pirazoles | |
| PE20120617A1 (es) | Procesos para preparar cobicistat y sus productos intermedios | |
| BR112012024401A2 (pt) | processo de preparo de derivados de 3-ceto-benzofurano | |
| ECSP077290A (es) | Derivados de isoxazolina y su uso como herbicidas | |
| PE20130375A1 (es) | Compuestos de triazolopiridinas y triazolopirazinas inhibidores de c-met y composiciones de los mismos | |
| CO6251313A2 (es) | Proceso para la preparacion de pirazoles | |
| WO2008128934A3 (en) | Fluorinated dyes and their use in electrophoretic display devices | |
| AR071537A1 (es) | Proceso para preparar derivados de acido 2-amino-5-cianobenzoico | |
| AR074982A1 (es) | Metodos para la preparacion de fungicidas | |
| CO6260016A2 (es) | Uso de los compuestos de sulfoanilida como herbicida | |
| EA201301315A1 (ru) | Способ получения промежуточных соединений эстетрола | |
| PE20090881A1 (es) | Procedimiento de sintesis del (7-metoxi-1-naftil) acetonitrilo como intermediario en la sintesis de la agomelatina | |
| AR104790A1 (es) | Método para la fabricación de agentes nucleantes para endurecimiento de hormigón | |
| AR105812A1 (es) | Métodos para la preparación de inhibidores de proteína deacetilasa | |
| PH12015502684B1 (en) | New compounds having triple activities of thrombolysis, antithrombotic and radical scavenging, and synthesis, nano-structure and use thereof | |
| AR065980A1 (es) | Metodos para preparar compuestos basados en imidazol | |
| CL2008003897A1 (es) | Proceso para la preparacion de 1-(2h-isoquinolinas)6-sustituidas por ciclacion de un dimetilano-vinil-benzonitrilo; los compuestos intermediarios utilizados; y la preparacion de uno de ellos. | |
| AR073008A1 (es) | Compuestos de 2- aminopirimidina como potentes inhibidores de hsp-90 | |
| ECSP088224A (es) | Proceso para la producción de anilinas | |
| AR077332A1 (es) | Procesos para la alquilacion de pirazoles | |
| AR066609A1 (es) | Compuesto organico de azufre y su uso para controlar artropodos daninos | |
| AR064002A1 (es) | Quinazolinas sustituidas | |
| CL2012000270A1 (es) | Procedimiento de preparacion de ivabradina y de sus sales de adicion por formacion del anillo benzoacepino; y los compuestos intermediarios considerados en el procedimiento. | |
| EA200702419A1 (ru) | Новые соединения как агонисты glp-1 |