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CN201217287Y - Biaxially oriented nylon pre-coated film - Google Patents

Biaxially oriented nylon pre-coated film Download PDF

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Publication number
CN201217287Y
CN201217287Y CNU2008200803895U CN200820080389U CN201217287Y CN 201217287 Y CN201217287 Y CN 201217287Y CN U2008200803895 U CNU2008200803895 U CN U2008200803895U CN 200820080389 U CN200820080389 U CN 200820080389U CN 201217287 Y CN201217287 Y CN 201217287Y
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precoatingfiltration
thickness
film
layer
dual
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Expired - Lifetime
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CNU2008200803895U
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Chinese (zh)
Inventor
钟玉
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BEIJING KANGDE XIN COMPOSITE MATERIAL Co Ltd
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BEIJING KANGDE XIN COMPOSITE MATERIAL Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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    • Y02E10/50Photovoltaic [PV] energy

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Abstract

Disclosed is a dual-direction tensile nylon precoatingfiltration, which is applied to the printing film covering field; the precoatingfiltration comprises a substrate, a middle layer and a hot melting glue layer; the precoatingfiltration is characterized in that: the substrate is the dual-direction tensile nylon film (BOPA); the middle layer is the polyethyleneimine (PEI); and the hot melting glue layer is the EVA hot melting glue. The middle layer and the hot melting layer are all sequentially coated and combined on a surface of the substrate. The substrate has a thickness of 12 to 20 microns, the middle layer has a thickness of 0.01 to 0.03 microns (the coating quantity is between 0.009 to 0.011g/m<2>); and the hot melting glue layer has a thickness of 15 to 40 microns. The dual-direction tensile nylon precoatingfiltration has the beneficial effects that: the barrier performance, the puncture resisting performance and the impact resisting performance are fine, the light degree is high, the hot sealing and the moisture absorption performances are better, and the covering film has the printing performance. The dual-direction tensile nylon precoatingfiltration is mainly applied to the packing field and the coating film field for the top grade books and magazine covers; and the dual-direction tensile nylon precoatingfiltration has the advantages of stable product quality, environment protecting, secure, convenient, energy saving and high-efficiency, so as to satisfy the users requirements for the covering film.

Description

Biaxial tension nylon pre-coating film
Technical field
The utility model relates to printing film coating technique field, and particularly the important materials pre-coating film of overlay film is a kind of pre-coating film that adopts the extrusion composite technology technology to make.
Background technology
The printed matter overlay film is the important means of post-press finishing, the final personal value of its decision print product.The coating technique of printed matter is meant with plastic sheeting and covers above the paper printing matter, the middle adhesive that uses, after the heating pressurized treatments, two kinds of materials of different nature of plastic sheeting and paper are bonded together, form paper/the mould incrustation process technology of unification.It plays protection and decorative effect to printed matter, is widely used in the packages printing field, on the Surface Machining as Front cover of book and periodical, propaganda picture album, map, advertising specialty bag, senior packing box etc.Overlay film can divide promptly films and two kinds of pre-coating films.
Promptly be coated with membrane technology and be that the international sixties rise to coating technique behind the seal of printed matter, package.But this technology is directly used in the overlay film process and is contained benzene solvent, thereby has brought the three big drawbacks that can't overcome owing to self technology:
(1) environmental issue: because the volatilization of noxious material benzene and overflowing has caused air pollution and brought very big harm for the producer and user's health; Simultaneously, the harmful substance that residues in the overlay film has harmful effect to consumer's health.
(2) quality problems: owing to still have volatile substance benzene constantly to overflow after the overlay film processing, very easily between film and paper, form bubble, make printing product surface be vaporific, influence fineness, definition and the colour vividness of printing; Sometimes because of bonding strength is not enough, even cause cracking, fold and demoulding.In addition, the production equipment automaticity of promptly filming is low, has reduced the overlay film yield rate.
(3) safety problem: owing to contain volatile organic solvent benzene in the solution, form flammable, explosive atmosphere easily around the liquid bath, and the plastic basis material that the uses generation static that rub causes disaster hidden-trouble in operation process.Such accident number had taken place, and little then the shutdown stops production, and greatly then machine burns, and factory building caves in, casualties.
The pre-coating film film coating technique is the green technology of sustainable development.The pre-coating film film coating technique also can be referred to as environmental friendliness technology or clean technologies, has realized the protection environment, protects the health, has kept the safety in production.In pre-coating film production and the use, the volatilization that toxic gas does not take place is polluted, and therefore, effectively improves working environment, eliminates the disaster hidden-trouble that production site and product are stored; Use the pre-coating film product,, can be widely used on the packing of books and periodicals (especially student textbook), food, tobacco and wine, medicine etc. the consumer not being constituted potential threat owing to wherein do not have the hazard residue material; The process procedures such as allotment, coating and oven dry of binder have been saved simultaneously, the whole film covering process can in seconds be finished, and can not produce pollution to environment, does not have disaster hidden-trouble, do not need to clean automatic double surface gluer etc. yet, can realize high speed, efficient, high-quality overlay film; Pre-coating film has promoted the color saturation of printed matter and definition, has obviously increased its artistic effect; and printed matter played a protective role; make it water-fast, moisture resistance, fast light, prevent pollution, anti-chemical corrosion; increase the service life; improve durability, collection and the ornamental value of printed matter greatly, promoted the commercial competitiveness and the added value of product.
Pre-coating film structure difference, adopt the base material difference different with hot melt adhesive layer, the performance of pre-coating film product has very big-difference, and the effect of product also has very big difference behind the overlay film, as aspects such as color saturation, brightness, tensile strength, wide degree, flatness.
The utility model content
The purpose of this utility model is: a kind of biaxial tension nylon (BOPA) pre-coating film is provided, improve the exquisite degree of printing, constant product quality, not only environmental protection, safety, convenience, energy-conservation, efficient, and can satisfy some clients to overlay film after product requirement have good barrier, puncture resistance and impact resistance, high brightness, the demand of heat sealability and hygroscopicity, impressionability preferably.Owing to not with an organic solvent, do not overcome the deficiency of promptly filming and existing.
The technical solution adopted in the utility model is: biaxial tension nylon (BOPA) pre-coating film, comprise base material, intermediate layer and hot melt adhesive layer, it is characterized in that: on the surface of base material intermediate layer and hot melt adhesive layer are arranged successively, the width of base material, intermediate layer and hot melt adhesive layer is identical.Base material is BON biaxially oriented nylon film (BOPA), and the intermediate layer is polymine (PEI), and hot melt adhesive layer is the EVA PUR.Intermediate layer and hot melt adhesive layer evenly apply successively, are compounded on the surface of base material.The thickness of base material is between the 12-20 micron, and (coated weight is 0.009-0.011g/m to the thickness in intermediate layer at the 0.01-0.03 micron 2) between, the thickness of hot melt adhesive layer is between the 15-40 micron.
Technical scheme is preferably: the thickness of base material is between the 12-15 micron, and (coated weight is 0.009-0.01g/m to the thickness in intermediate layer at the 0.01-0.02 micron 2) between, the thickness of hot melt adhesive layer is between the 15-30 micron.
The composite production line that utilizes extruder and equipment complex to form is coated in the intermediate layer on the surface of base material, at last hot melt adhesive layer is compounded on the intermediate layer production biaxial tension nylon (BOPA) pre-coating film.After the thickness of base material and EVA hot melt adhesive layer carries out suitable combination, can obtain different products.Above-mentioned extruder and equipment complex and combination process are well known to those skilled in the art.
The EVA PUR is a kind of solid meltability polymer that does not need solvent, moisture-free 100%; Be solid at normal temperatures, heating and melting becomes and can flow to uniform temperature, and the liquid of certain viscosity is arranged.EVA PUR after the fusion is light yellow or colourless.The EVA PUR is become to be grouped into by basic resin, tackifier, viscosity modifier and antioxidant etc.At present, apply level EVA PUR product and mainly rely on import, domestic no appropriate level production.
Polymine (PEI) molecular formula is: [CH 2CH 2NH-] n, there is the product supply in Shanghai DiC Ink Co., Ltd, but the utility model adopts U.S.'s imported product.
The beneficial effects of the utility model: biaxial tension nylon (BOPA) pre-coating film, with BON biaxially oriented nylon film (BOPA) as base material, with the pre-coating film of EVA PUR as hot melt adhesive layer, have good barrier, puncture resistance and impact resistance, high brightness, the characteristics of heat sealability and hygroscopicity, impressionability preferably, improved the exquisite degree of printing.Mainly implement overlay film at high-grade books and periodicals, journal surface.Biaxial tension nylon (BOPA) pre-coating film constant product quality, and have environmental protection, safety, convenience, energy-conservation, efficient advantage, can satisfy some clients to overlay film after product requirement.Owing to not with an organic solvent, do not overcome the deficiency of promptly filming and existing.Its product will have the field of above-mentioned requirements to be more widely used at high-grade books and periodicals, journal surface etc.
Description of drawings
Fig. 1 is biaxial tension nylon (BOPA) pre-coating film cross section structure schematic diagram.
Among the figure, 1. base material, 2. intermediate layer, 3. hot melt adhesive layer.
The specific embodiment
Embodiment 1: with width is that 1316 millimeters biaxial tension nylon (BOPA) pre-coating film is an example, is elaborated.
Consult Fig. 1.Biaxial tension nylon (BOPA) pre-coating film width is 1316 millimeters.Base material 1, intermediate layer 2 are identical with the width of hot melt adhesive layer 3.Biaxial tension nylon (BOPA) pre-coating film haves three layers, and ground floor is a base material 1, and the second layer is that the intermediate layer is a hot melt adhesive layer 3 for 2, the three layers.Former base material adopts BON biaxially oriented nylon film (BOPA), 1336 millimeters of width.Intermediate layer 2 is polymine (PEI), and hot melt adhesive layer 3 is EVA PURs.Intermediate layer 2 and hot melt adhesive layer 3 evenly apply successively, are compounded on the surface of base material 1, and through the side cut system, both sides of the edge are cut off 20 millimeters altogether behind the composite hot melt glue-line 3, and final products will be than narrow 20 millimeter of the width of former base material.At the fabric width edge, thickness deviation≤2 micron.12 microns of the thickness of base material 1, the thickness in intermediate layer 2 are at 0.015 micron, and hot melt adhesive layer 3 compound thickness are 18.5 microns.

Claims (2)

1、一种双向拉伸尼龙预涂膜,包括基材(1)、中间层(2)和热熔胶层(3),其特征在于:基材(1)的一个表面上依次有中间层(2)和热熔胶层(3),基材(1)、中间层(2)和热熔胶层(3)的宽度相同,基材(1)是双向拉伸聚酯薄膜,中间层(2)是聚乙烯亚胺,热熔胶层(3)是EVA热熔胶,基材(1)的厚度在12-20微米之间,中间层(2)的厚度在0.01-0.03微米之间,热熔胶层(3)的厚度在15-40微米之间。1. A biaxially stretched nylon precoat film, comprising a base material (1), an intermediate layer (2) and a hot-melt adhesive layer (3), is characterized in that: an intermediate layer is arranged successively on a surface of the base material (1) (2) and hot-melt adhesive layer (3), the width of base material (1), middle layer (2) and hot-melt adhesive layer (3) is identical, and base material (1) is biaxially stretched polyester film, middle layer (2) is polyethyleneimine, the hot melt adhesive layer (3) is EVA hot melt adhesive, the thickness of the substrate (1) is between 12-20 microns, and the thickness of the middle layer (2) is between 0.01-0.03 microns Between, the thickness of the hot melt adhesive layer (3) is between 15-40 microns. 2、根据权利要求1所述的双向拉伸尼龙预涂膜,其特征是:所述的基材(1)的厚度在12-15微米之间,中间层(2)的厚度在0.01-0.02微米之间,热熔胶层(3)的厚度在15-30微米之间。2. The biaxially oriented nylon precoat film according to claim 1, characterized in that: the thickness of the substrate (1) is between 12-15 microns, and the thickness of the middle layer (2) is 0.01-0.02 Between microns, the thickness of the hot melt adhesive layer (3) is between 15-30 microns.
CNU2008200803895U 2008-05-05 2008-05-05 Biaxially oriented nylon pre-coated film Expired - Lifetime CN201217287Y (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111492499A (en) * 2017-12-18 2020-08-04 大日本印刷株式会社 Battery packaging material, method for producing the same, and battery
CN114590002A (en) * 2022-03-03 2022-06-07 中塑新材料科技(杭州)有限公司 High-sealing strong heat-resistant composite film

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111492499A (en) * 2017-12-18 2020-08-04 大日本印刷株式会社 Battery packaging material, method for producing the same, and battery
CN114590002A (en) * 2022-03-03 2022-06-07 中塑新材料科技(杭州)有限公司 High-sealing strong heat-resistant composite film

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C56 Change in the name or address of the patentee
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Address after: 215634 Jiangsu Province, Zhangjiagang City Environmental Protection New Material Industrial Park Road on the north side of Hong Kong, Hong Chen Hua Road West

Patentee after: Jiangsu kangdexin composite materials Limited by Share Ltd

Address before: 102200, 26, Zhenxing Road, Changping science and Technology Park, Beijing, Changping District

Patentee before: Beijing kangde xin composite material Co., Ltd.

CX01 Expiry of patent term
CX01 Expiry of patent term

Granted publication date: 20090408