CN201217285Y - Biaxially oriented polypropylene pre-coated film - Google Patents
Biaxially oriented polypropylene pre-coated film Download PDFInfo
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- CN201217285Y CN201217285Y CNU2008200803876U CN200820080387U CN201217285Y CN 201217285 Y CN201217285 Y CN 201217285Y CN U2008200803876 U CNU2008200803876 U CN U2008200803876U CN 200820080387 U CN200820080387 U CN 200820080387U CN 201217285 Y CN201217285 Y CN 201217285Y
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- 239000011127 biaxially oriented polypropylene Substances 0.000 title claims description 16
- 229920006378 biaxially oriented polypropylene Polymers 0.000 title claims description 5
- -1 polypropylene Polymers 0.000 claims abstract description 8
- 239000004743 Polypropylene Substances 0.000 claims abstract 7
- 229920001155 polypropylene Polymers 0.000 claims abstract 7
- 239000010410 layer Substances 0.000 claims description 49
- 239000004831 Hot glue Substances 0.000 claims description 31
- 238000000576 coating method Methods 0.000 claims description 25
- 239000011248 coating agent Substances 0.000 claims description 24
- 239000000463 material Substances 0.000 claims description 15
- 230000002457 bidirectional effect Effects 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000000758 substrate Substances 0.000 abstract description 15
- 229920002873 Polyethylenimine Polymers 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 230000008018 melting Effects 0.000 abstract 5
- 238000002844 melting Methods 0.000 abstract 5
- 239000003292 glue Substances 0.000 abstract 4
- 239000000047 product Substances 0.000 description 19
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 238000005516 engineering process Methods 0.000 description 9
- 238000003475 lamination Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000007888 film coating Substances 0.000 description 6
- 238000009501 film coating Methods 0.000 description 6
- 239000002131 composite material Substances 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000208125 Nicotiana Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 238000009966 trimming Methods 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
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Abstract
Description
技术领域 technical field
本实用新型涉及印刷覆膜技术领域,特别涉及覆膜的重要材料预涂膜,是一种采用挤出复合工艺技术制造的预涂膜。The utility model relates to the technical field of printing film coating, in particular to a pre-coating film which is an important material of the film coating, and is a pre-coating film manufactured by extrusion composite technology.
背景技术 Background technique
印刷品覆膜是印后加工的重要手段,它决定印刷产品的最终身价。印刷品的覆膜工艺是指用塑料薄膜覆盖在纸张印刷品上面,中间使用粘合剂,通过加热加压处理后,使塑料薄膜和纸张两种不同性质的物质粘合在一起,形成纸/塑合一的表面装饰加工技术。它对印刷品起保护和装饰作用,被广泛应用于包装印刷领域,如书刊封面、宣传画册、地图、广告礼品袋、高级包装盒等的表面加工上。覆膜可分即涂膜和预涂膜两种。Printed matter lamination is an important means of post-press processing, which determines the final value of printed products. The lamination process of printed matter refers to covering the paper printed matter with a plastic film, using an adhesive in the middle, and after heat and pressure treatment, the plastic film and paper are bonded together to form a paper/plastic composite. One of the most advanced surface decoration processing technology. It protects and decorates printed matter, and is widely used in the field of packaging and printing, such as the surface processing of book covers, brochures, maps, advertising gift bags, and high-end packaging boxes. The coating can be divided into two types: coating film and pre-coating film.
即涂膜技术是国际六十年代兴起的对印刷品、包装品的印后覆膜工艺。但该技术在覆膜过程中直接使用含苯溶剂,因而带来了由于自身工艺而无法克服的三大弊端:That is, film coating technology is a post-press lamination process for printed matter and packaging that emerged in the 1960s. However, this technology directly uses benzene-containing solvents in the coating process, which brings three major disadvantages that cannot be overcome due to its own process:
(1)环保问题:由于有毒物质苯的挥发和溢出,造成了空气污染并给生产者和使用者的身体带来极大危害;同时,残留于覆膜中的有害物质对消费者的健康有不良影响。(1) Environmental protection issues: due to the volatilization and overflow of the toxic substance benzene, it causes air pollution and brings great harm to the health of producers and users; at the same time, the harmful substances remaining in the film are harmful to the health of consumers. adverse effects.
(2)质量问题:由于覆膜加工后仍有挥发物质苯不断溢出,极易在膜和纸张之间形成气泡,使印品表面呈雾状,影响印品的光洁度、清晰度及色彩鲜艳度;有时因粘合强度不够,甚至造成开裂、皱折和脱膜。此外,即涂膜的生产设备自动化程度低,降低了覆膜成品率。(2) Quality problems: Since benzene, a volatile substance, continues to overflow after the film coating process, it is easy to form air bubbles between the film and the paper, making the surface of the printed product foggy, affecting the smoothness, clarity and color vividness of the printed product ; Sometimes due to insufficient bonding strength, it even causes cracking, wrinkling and stripping. In addition, that is, the production equipment of the coating film has a low degree of automation, which reduces the yield of the coating film.
(3)安全问题:由于溶液中含有挥发性有机溶剂苯,容易在液槽周围形成可燃、易爆炸的气体氛围,而使用的塑料基材在运转过程中摩擦产生静电,造成火灾隐患。已经发生过这样的事故数起,小则停机停产,大则机器烧毁,厂房坍塌,人员伤亡。(3) Safety issues: Since the solution contains benzene, a volatile organic solvent, it is easy to form a flammable and explosive gas atmosphere around the liquid tank, and the plastic substrate used generates static electricity during operation, causing fire hazards. There have been several accidents like this, ranging from shutdowns to stop production, to machine burns, plant collapses, and casualties.
预涂膜覆膜技术是可持续发展的环保技术。预涂膜覆膜技术亦可称之为环境友好技术或清洁技术,实现了保护环境、保护健康、安全生产。预涂膜生产及使用过程中,不发生有毒气体的挥发污染,因此,有效改善工作环境,消除生产场地及产品贮存的火灾隐患;使用预涂膜产品,由于其中没有有害残留物质,可广泛应用于书刊(尤其是学生课本)、食品、烟酒、药物等的包装上,对消费者不构成潜在威胁;同时省去了黏合剂的调配、涂覆以及烘干等工艺环节,整个覆膜过程可以在几秒钟内完成,对环境不会产生污染,没有火灾隐患,也不需要清洗涂胶设备等,能实现高速、高效、高质量覆膜;预涂膜提升了印刷品的色彩饱和度和清晰度、明显增加其艺术效果,并对印刷品起到保护作用,使之耐水、耐潮、耐光、防止污染、防化学腐蚀,延长使用寿命,大大提高印刷品的耐用性、收藏及观赏价值,提升了产品的商业竞争力和附加值。Pre-coating film coating technology is a sustainable environmental protection technology. Pre-coating film coating technology can also be called environmentally friendly technology or clean technology, which realizes environmental protection, health protection and safe production. During the production and use of pre-coated film, no volatilization and pollution of toxic gases will occur. Therefore, the working environment can be effectively improved, and fire hazards in production sites and product storage can be eliminated; pre-coated film products can be widely used because there are no harmful residual substances in them. It does not pose a potential threat to consumers on the packaging of books (especially student textbooks), food, tobacco, alcohol, and drugs; at the same time, it saves the process of adhesive preparation, coating, and drying. It can be completed in a few seconds, it will not pollute the environment, there is no fire hazard, and there is no need to clean the gluing equipment, etc., and it can achieve high-speed, high-efficiency, high-quality lamination; the pre-coated film improves the color saturation and color of the printed matter. Clarity, significantly increase its artistic effect, and protect the printed matter, making it water-resistant, moisture-resistant, light-resistant, anti-pollution, anti-chemical corrosion, prolong the service life, greatly improve the durability, collection and ornamental value of the printed matter, and enhance the Commercial competitiveness and added value of products.
预涂膜结构不同、采用基材不同和热熔胶层不同,预涂膜产品的性能会有很大差异,覆膜后产品的效果也会有很大的区别,如色彩饱和度、亮度、抗张强度、挺阔度、平整度等方面。The pre-coating film structure is different, the base material is different and the hot-melt adhesive layer is different, the performance of the pre-coating film product will be very different, and the effect of the product after lamination will also be very different, such as color saturation, brightness, Tensile strength, width, flatness, etc.
实用新型内容Utility model content
本实用新型的目的是:提供一种双向拉伸聚丙烯(BOPP)预涂膜,提高印品的精美程度,产品质量稳定,不仅环保、安全、方便、节能、高效,而且能满足大部分客户对覆膜后产品要求具有高色彩饱和度、高亮度的需求,并且此种预涂膜还具有物美价廉、易加工、品种规格多(可分为亮光与亚光、单面电晕与双面电晕预涂膜)、应用领域广的特点。由于不使用有机溶剂,克服即涂膜存在的不足。The purpose of this utility model is: to provide a biaxially oriented polypropylene (BOPP) pre-coating film, which can improve the exquisiteness of printed products and stabilize product quality. It is not only environmentally friendly, safe, convenient, energy-saving and efficient, but also can satisfy most customers. The products after lamination are required to have high color saturation and high brightness, and this kind of pre-coating film also has high quality and low price, easy processing, and many varieties and specifications (can be divided into bright and matte, single-sided corona and double-sided) Surface corona pre-coating film), wide range of applications. Since no organic solvent is used, the shortcoming of the coating film is overcome.
本实用新型采用的技术方案是:双向拉伸聚丙烯(BOPP)预涂膜,包括基材、中间层和热熔胶层,其特征在于:基材的一个表面上依次有中间层和热熔胶层,基材、中间层和热熔胶层的宽度相同。基材是双向拉伸聚丙烯薄膜(BOPP),中间层是聚乙烯亚胺(PEI),热熔胶层是EVA热熔胶。中间层和热熔胶层依次均匀涂覆、复合在基材的一个表面上。基材的厚度在12-20微米之间,中间层的厚度在0.01-0.03微米(涂覆量为0.009-0.011g/m2)之间,热熔胶层复合的厚度在10-40微米之间。The technical scheme adopted by the utility model is: a biaxially oriented polypropylene (BOPP) pre-coating film, including a base material, an intermediate layer and a hot-melt adhesive layer, and is characterized in that: one surface of the base material has an intermediate layer and a hot-melt adhesive layer in sequence. Adhesive layer, base material, intermediate layer and hot melt adhesive layer have the same width. The substrate is biaxially oriented polypropylene film (BOPP), the middle layer is polyethyleneimine (PEI), and the hot-melt adhesive layer is EVA hot-melt adhesive. The middle layer and the hot-melt adhesive layer are uniformly coated and compounded on one surface of the base material in sequence. The thickness of the substrate is between 12-20 microns, the thickness of the intermediate layer is between 0.01-0.03 microns (the coating amount is 0.009-0.011g/m 2 ), and the thickness of the hot melt adhesive layer is between 10-40 microns between.
较好的技术方案是:基材的厚度在12-18微米之间,中间层的厚度在0.01-0.02微米(涂覆量为0.009-0.01g/m2)之间,热熔胶层的厚度在10-30微米之间。A better technical solution is: the thickness of the substrate is between 12-18 microns, the thickness of the intermediate layer is between 0.01-0.02 microns (the coating amount is 0.009-0.01g/m 2 ), the thickness of the hot melt adhesive layer is Between 10-30 microns.
利用挤出机和复合设备组成的复合生产线,将中间层涂覆在基材的一个表面上,最后将热熔胶层复合在中间层上,生产双向拉伸聚丙烯(BOPP)预涂膜。基材和EVA热熔胶层的厚度进行适当的组合后,可以获得不同的产品。上述挤出机和复合设备以及复合工艺是本领域技术人员熟知的。Using the composite production line composed of extruder and composite equipment, the intermediate layer is coated on one surface of the substrate, and finally the hot melt adhesive layer is composited on the intermediate layer to produce biaxially oriented polypropylene (BOPP) pre-coated film. Different products can be obtained by properly combining the thickness of the base material and the EVA hot melt adhesive layer. The above-mentioned extruder, compounding equipment and compounding process are well known to those skilled in the art.
EVA热熔胶是一种不需溶剂、不含水分100%的固体可熔性聚合物;在常温下为固体,加热熔融到一定温度变为能流动,且有一定粘性的液体。熔融后的EVA热熔胶,呈浅黄色或无色。EVA热熔胶由基本树脂、增粘剂、粘度调节剂和抗氧剂等成分组成。目前,涂覆级EVA热熔胶产品主要依靠进口,国内无合适级别产品生产。EVA hot melt adhesive is a solid meltable polymer that does not require solvents and does not contain 100% moisture; it is solid at room temperature, and when heated and melted to a certain temperature, it becomes a fluid and viscous liquid. The melted EVA hot melt adhesive is light yellow or colorless. EVA hot melt adhesives are composed of basic resins, tackifiers, viscosity modifiers and antioxidants. At present, coating-grade EVA hot-melt adhesive products mainly rely on imports, and there are no suitable grades of products produced in China.
聚乙烯亚胺(PEI)分子式是:[-CH2CH2NH-]n,上海DIC油墨有限公司有产品供应,本实用新型采用美国进口产品。Polyethyleneimine (PEI) molecular formula is: [-CH 2 CH 2 NH-]n, Shanghai DIC Ink Co., Ltd. has product supply, and the utility model adopts the product imported from the United States.
本实用新型的有益效果:双向拉伸聚丙烯(BOPP)预涂膜,以双向拉伸聚丙烯(BOPP)薄膜作为基材,以EVA热熔胶作为热熔胶层的预涂膜,具有物美价廉、易加工、高亮度、品种规格多(可分为亮光与亚光、单面电晕与双面电晕预涂膜)、应用领域广的特点,提高了印品的精美程度。可以在大部分纸张印刷品表面实施覆膜。双向拉伸聚丙烯(BOPP)预涂膜产品质量稳定,并具有环保、安全、方便、节能、高效优势,能满足大部分客户对覆膜后产品要求。由于不使用有机溶剂,克服即涂膜存在的不足。其产品必将会在纸张印刷品覆膜领域得到更加广泛的应用。Beneficial effects of the utility model: biaxially oriented polypropylene (BOPP) pre-coated film, with biaxially oriented polypropylene (BOPP) film as the base material, and EVA hot-melt adhesive as the pre-coated film of the hot-melt adhesive layer, has a good quality Cheap, easy to process, high brightness, many varieties and specifications (can be divided into glossy and matte, single-sided corona and double-sided corona pre-coating films), and wide application fields, which improves the exquisiteness of printed products. Lamination can be applied to the surface of most paper prints. Biaxially oriented polypropylene (BOPP) pre-coated film has stable quality, and has the advantages of environmental protection, safety, convenience, energy saving and high efficiency, and can meet most customers' requirements for film-coated products. Since no organic solvent is used, the shortcoming of the coating film is overcome. Its products will be more widely used in the field of paper printing lamination.
附图说明 Description of drawings
图1是双向拉伸聚丙烯(BOPP)预涂膜横剖面结构示意图。Fig. 1 is a cross-sectional schematic diagram of a biaxially oriented polypropylene (BOPP) precoat film.
图中,1.基材,2.中间层,3.热熔胶层。In the figure, 1. Substrate, 2. Intermediate layer, 3. Hot melt adhesive layer.
具体实施方式 Detailed ways
实施例1:以宽度为1770毫米的双向拉伸聚丙烯(BOPP)预涂膜为例,进行详细说明。Embodiment 1: Take a biaxially oriented polypropylene (BOPP) precoat film with a width of 1770 mm as an example to describe in detail.
参阅图1。双向拉伸聚丙烯(BOPP)预涂膜宽度为1770毫米。基材1、中间层2和热熔胶层3的宽度相同。双向拉伸聚丙烯(BOPP)预涂膜有3层,第一层是基材1,第二层为中间层2,第三层为热熔胶层3。原基材采用双向拉伸聚丙烯(BOPP)薄膜,宽度1795毫米。中间层2是聚乙烯亚胺(PEI),热熔胶层3是EVA热熔胶。中间层2和热熔胶层3依次均匀涂覆、复合在基材1的一个表面上,复合热熔胶层3后经过切边系统,两侧边缘共被切掉25毫米,最终产品将比原基材的宽度窄25毫米左右。在幅宽边沿,厚度偏差≤2微米。基材1的厚度12微米,中间层2的厚度为0.015微米,热熔胶层3复合的厚度为10微米。See Figure 1. Biaxially oriented polypropylene (BOPP) pre-coated film width is 1770 mm. The
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102794966A (en) * | 2012-08-06 | 2012-11-28 | 北京康得新复合材料股份有限公司 | Glue-free bidirectional stretching polypropylene film used for paper-plastic composite and preparation method thereof |
| CN103146318A (en) * | 2013-03-19 | 2013-06-12 | 安徽国风塑业股份有限公司 | Pre-coating film for paper-plastic lamination and preparation method thereof |
| CN104927695A (en) * | 2015-07-14 | 2015-09-23 | 潮安新纪源实业有限公司 | Super-sticky precoating and preparation method and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102794966A (en) * | 2012-08-06 | 2012-11-28 | 北京康得新复合材料股份有限公司 | Glue-free bidirectional stretching polypropylene film used for paper-plastic composite and preparation method thereof |
| CN103146318A (en) * | 2013-03-19 | 2013-06-12 | 安徽国风塑业股份有限公司 | Pre-coating film for paper-plastic lamination and preparation method thereof |
| CN104927695A (en) * | 2015-07-14 | 2015-09-23 | 潮安新纪源实业有限公司 | Super-sticky precoating and preparation method and application thereof |
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Address after: 215634 Jiangsu Province, Zhangjiagang City Environmental Protection New Material Industrial Park Road on the north side of Hong Kong, Hong Chen Hua Road West Patentee after: Jiangsu kangdexin composite materials Limited by Share Ltd Address before: 102200, 26, Zhenxing Road, Changping science and Technology Park, Beijing, Changping District Patentee before: Beijing kangde xin composite material Co., Ltd. |
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Granted publication date: 20090408 |