CN1911013A - Synergistic compound pesticide contg. pyridaben and pyridaben, and its application - Google Patents
Synergistic compound pesticide contg. pyridaben and pyridaben, and its application Download PDFInfo
- Publication number
- CN1911013A CN1911013A CN 200510041444 CN200510041444A CN1911013A CN 1911013 A CN1911013 A CN 1911013A CN 200510041444 CN200510041444 CN 200510041444 CN 200510041444 A CN200510041444 A CN 200510041444A CN 1911013 A CN1911013 A CN 1911013A
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- CN
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- Prior art keywords
- pyridaben
- fluacrypyrim
- application
- insecticidal compositions
- synergistic insecticidal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- DWFZBUWUXWZWKD-UHFFFAOYSA-N pyridaben Chemical compound C1=CC(C(C)(C)C)=CC=C1CSC1=C(Cl)C(=O)N(C(C)(C)C)N=C1 DWFZBUWUXWZWKD-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 239000005663 Pyridaben Substances 0.000 title claims abstract description 42
- 230000002195 synergetic effect Effects 0.000 title claims abstract description 11
- 150000001875 compounds Chemical class 0.000 title claims description 3
- 239000000575 pesticide Substances 0.000 title description 3
- -1 assistant Substances 0.000 claims abstract description 10
- 239000000546 pharmaceutical excipient Substances 0.000 claims abstract description 7
- 239000002131 composite material Substances 0.000 claims abstract description 3
- MXWAGQASUDSFBG-RVDMUPIBSA-N fluacrypyrim Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1COC1=CC(C(F)(F)F)=NC(OC(C)C)=N1 MXWAGQASUDSFBG-RVDMUPIBSA-N 0.000 claims description 43
- 239000000203 mixture Substances 0.000 claims description 15
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 14
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 claims description 11
- 238000002360 preparation method Methods 0.000 claims description 11
- 241000607479 Yersinia pestis Species 0.000 claims description 8
- 230000000749 insecticidal effect Effects 0.000 claims description 8
- 230000000361 pesticidal effect Effects 0.000 claims description 8
- 230000000694 effects Effects 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- 241001454293 Tetranychus urticae Species 0.000 claims description 4
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 2
- 239000006071 cream Substances 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- 241000488583 Panonychus ulmi Species 0.000 abstract description 3
- 239000002917 insecticide Substances 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 18
- 238000000034 method Methods 0.000 description 10
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 9
- 239000002994 raw material Substances 0.000 description 9
- 238000005303 weighing Methods 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000003905 agrochemical Substances 0.000 description 3
- 230000002438 mitochondrial effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 241001124076 Aphididae Species 0.000 description 2
- 241000207199 Citrus Species 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- 241000255777 Lepidoptera Species 0.000 description 2
- 241000488581 Panonychus citri Species 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 235000020971 citrus fruits Nutrition 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 230000000241 respiratory effect Effects 0.000 description 2
- 230000029058 respiratory gaseous exchange Effects 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 102100025287 Cytochrome b Human genes 0.000 description 1
- 102000019265 Cytochrome c1 Human genes 0.000 description 1
- 108010075028 Cytochromes b Proteins 0.000 description 1
- 108010007528 Cytochromes c1 Proteins 0.000 description 1
- 241001583841 Empoasca decipiens Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000220324 Pyrus Species 0.000 description 1
- 241000256247 Spodoptera exigua Species 0.000 description 1
- 241001454295 Tetranychidae Species 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 231100000636 lethal dose Toxicity 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 210000003470 mitochondria Anatomy 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000007115 recruitment Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A synergistic composite insecticide for preventing and controlling the agricultural mite and red spider contains two active components including proportionally pyridaben, assistant, and excipient.
Description
Technical field
The present invention relates to a kind of Pesticidal combination and uses thereof, especially a kind of is the Pesticidal combination and the application thereof of main active with pyridaben and fluacrypyrim.
Background technology
Pyridaben (adopted name: Pyridaben) chemical name: 2-tertiary butyl-5-(4-tertiary butyl benzylthio)-4-chloro-3 (2H)-pyridazinone
Chemical structural formula:
Key property: Insecticidal and acaricidal agent, wide spectrum, efficient, hold and imitate longly, have action of contace poison.
Controlling object: citrus: Panonychus citri, tetranychid, unguiculus mite, beginning tetranychid, rust mite, aleyrodid, aphid etc.; Cotton: cotton spider mites, cotton leafhopper etc.; Apple: tetranychid, rust mite, aphid etc.
Fluacrypyrim (test code number: NA83, adopted name: fluacrypyrim, trade name: Titaron) be first methoxy acrylic miticide by BASF AG development, the exploitation of Japanese Cao Da company.Fluacrypyrim is on the basis of methoxy acrylic bactericide, and is synthetic at random, and find through optimization.The chemical name of fluacrypyrim is methyl (E)-2-{a-[2-isopropoxy-6-(trifluoromethyl) pyrimidine-4-base oxygen base]-o-tolyl }-the 3-methoxy-methyl acrylate.
Fluacrypyrim is that the mitochondrial respiratory inhibitor promptly shifts the mitochondrial breathing of inhibition by electronics between cytochrome b and c1.Extranuclear mitochondria mainly by breathing to cell provides energy (ATP), if mitochondrial respiratory is obstructed, can not produce ATP, and cell will be dead.
Fluacrypyrim is mainly used in multiple mite class such as European red mite, the citrus red mite etc. in control fruit tree such as apple, citrus, the pears etc.The mixture main component is that methoxy acrylic ester compounds such as fluacrypyrim and a lot of organophosphorus compound are formed in the patent, is used for anti-ly curing the disease, insect pest.Two spotted spider mite increases gradually in present resistance, the agent of agricultural chemicals list descends gradually to the effect of control of insect, and the synergistic complex of agricultural chemicals is expanding prevention spectrum and the effective measures that improve desinsection quick-acting and lasting effect, but still finds no the Pesticidal combination that closes pyridaben and fluacrypyrim up to now.
Summary of the invention
The purpose of this invention is to provide that a kind of what prevent and treat mite pest is the Pesticidal combination and the application thereof of main active with pyridaben and fluacrypyrim.
Technical scheme of the present invention is:
A kind of Synergistic insecticidal compositions that contains pyridaben and fluacrypyrim, it is characterized in that it is by primary activity composition pyridaben, fluacrypyrim, auxiliary agent, the composite cream preparation that forms of excipients, the weight portion of each component is: 0.1～30 part of pyridaben, fluacrypyrim: 0.5～30, auxiliary agent: 3～15, excipient: surplus.
Described auxiliary agent is the one or more combinations in calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, polyoxyethylene polyoxy third rare block compound or the polyoxyethylene nonylphenol ether, and excipient is dimethylbenzene or solvent naphtha or its combination.
The Synergistic insecticidal compositions that contains pyridaben and fluacrypyrim of the present invention is that effective ingredient is present in the composition with the synergy effective dose.
Optimum weight part of pyridaben and fluacrypyrim is respectively 0.5～20 and 1～25 in the composition.
The application of Pesticidal combination of the present invention on the control mite pest, the especially application on the control two spotted spider mite.
Beneficial effect of the present invention:
Pesticidal combination of the present invention compared with prior art produces following beneficial effect: (1) is compared with single agent, and said composition has notable synergistic to lepidoptera pest, has obviously improved control efficiency; (2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously, reduce control recruitment cost; (3) alternative high-toxic pesticide, and reduce the field dosage significantly, effectively reduce environmental pollution and residue of pesticide; (4) have concurrently quick-acting and long-acting; (5) compare with single agent product, produce and the use cost reduction; (6) suppress the resistance enhancing of lepidoptera pest to agricultural chemicals; (7) reduction is to the toxicity of warm blooded animal.
Embodiment
The present invention is further illustrated below in conjunction with embodiment.
Embodiment 1:
Take by weighing pyridaben 10 gram, fluacrypyrim 2 grams, calcium dodecyl benzene sulfonate 4 grams, phenethyl phenol polyethenoxy ether 3 grams, surplus dimethylbenzene and add to gross weight 100.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 12% pyridaben fluacrypyrim missible oil.
Carry out indoor synergy biologicall test, the selection beet exigua larvae is a target pest, and every processing repeats 3 times, and every concentration is handled 30, presses the abundant method of Sun Yun with the LC50 value and calculates co-toxicity coefficient:
The toxicity test effect of table 1 pyridaben fluacrypyrim=10: 2 pairs of two spotted spider mite
| Concentration (μ g/mL) | I | II | III | |||
| Examination borer population (head) | Dead borer population (head) | Examination borer population (head) | Dead borer population (head) | Examination borer population (head) | Dead borer population (head) | |
| 100 | 10 | 9 | 10 | 7 | 10 | 8 |
| 20 | 10 | 8 | 10 | 7 | 10 | 8 |
| 4 | 10 | 6 | 10 | 6 | 10 | 8 |
| 0.8 | 10 | 6 | 10 | 5 | 10 | 5 |
| 0.16 | 10 | 5 | 10 | 3 | 10 | 4 |
| 0.032 | 10 | 1 | 10 | 2 | 10 | 3 |
| 0.0064 | 10 | 1 | 10 | 1 | 10 | 2 |
| 0.000128 | 10 | 2 | 10 | 0 | 10 | 2 |
| CK | 10 | 2 | 10 | 0 | 10 | 0 |
Regression equation: Y=4.94158+0.528111X
Lethal concentration: LC50=1.290102 μ g/mL (95% confidence limit: 0.533609-3.89801 μ g/mL)
Embodiment is prevented and treated the field control effectiveness test of beet armyworm, and the contrast medicine is that the result is as follows:
Result of the test:
| Handle (doubly) | Radix (head/20 leaves) | Preventive effect (%) | |||||
| 1 day | 3 days | 10 days | 15 days | 20 days | |||
| Embodiment 1 | 1000 | 432 | 100Aa | 96.7Aa | 95.9Aa | 88.1Aa | 81.2Aa |
| 1500 | 577 | 99.5Aa | 94.2Aa | 92.7Aa | 81.4AA | 70.2Aab | |
| 2000 | 535 | 99.4Aa | 92.5Aa | 87.6Aa | 75.0Aa | 63.8Ab | |
| 15% pyridaben EC1500 | 497 | 82.3Ba | 89.2Ba | 76.4Cc | 79.5Aa | 64.5Ab | |
| 5% fluacrypyrim missible oil 1500 | 499 | 79.2Cc | 81.2Bb | 82,6Bb | 53.4Bb | 43.9Cc | |
| The CK rate that goes down | 491 | -4.7 | 6.4 | -38.2 | 29.2 | 31.1 | |
Annotate: a is illustrated on α=0.05 level remarkable, and b is illustrated on α=0.05 level variant, and c is illustrated on α=0.05 level not remarkable; A is illustrated on α=0.01 level remarkable, and B is illustrated on α=0.01 level variant, and C is illustrated on α=0.01 level not remarkable;
Embodiment 2:
Take by weighing pyridaben 0.1 gram, fluacrypyrim 0.5, calcium dodecyl benzene sulfonate 2 grams, phenethyl phenol polyethenoxy ether 1 gram, surplus dimethylbenzene to 100 gram.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 0.6% pyridaben fluacrypyrim missible oil.
Embodiment 3:
Take by weighing pyridaben 0.1 gram, fluacrypyrim 30, calcium dodecyl benzene sulfonate 7 grams, phenethyl phenol polyethenoxy ether 8 grams, balance solvent oil to 100 gram.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 30.1% pyridaben fluacrypyrim missible oil.
Embodiment 4:
Take by weighing pyridaben 30 grams, fluacrypyrim 0.5, calcium dodecyl benzene sulfonate 2 grams, phenethyl phenol polyethenoxy ether 1 gram, surplus dimethylbenzene to 100 gram.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 30.5% pyridaben fluacrypyrim missible oil.
Embodiment 5:
Take by weighing pyridaben 30 grams, fluacrypyrim 30, calcium dodecyl benzene sulfonate 7 grams, phenethyl phenol polyethenoxy ether 8 grams, balance solvent oil to 100 gram.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 60% pyridaben fluacrypyrim missible oil.
Embodiment 6:
Take by weighing pyridaben 0.5 gram, fluacrypyrim 1, calcium dodecyl benzene sulfonate 2 grams, phenethyl phenol polyethenoxy ether 1 gram, surplus dimethylbenzene to 100 gram.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 1.5% pyridaben fluacrypyrim missible oil.
Embodiment 7:
Take by weighing pyridaben 20 grams, fluacrypyrim 25, calcium dodecyl benzene sulfonate 7 grams, phenethyl phenol polyethenoxy ether 8 grams, balance solvent oil to 100 gram.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 45% pyridaben fluacrypyrim missible oil.
Embodiment 8:
Take by weighing pyridaben 0.5 gram, fluacrypyrim 25, calcium dodecyl benzene sulfonate 2 grams, phenethyl phenol polyethenoxy ether 1 gram, surplus dimethylbenzene to 100 gram.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 25.5% pyridaben fluacrypyrim missible oil.
Embodiment 9:
Take by weighing pyridaben 20 grams, fluacrypyrim 1, calcium dodecyl benzene sulfonate 7 grams, phenethyl phenol polyethenoxy ether 8 grams, balance solvent oil to 100 gram.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 21% pyridaben fluacrypyrim missible oil.
Above-mentioned result shows, the complex composition of pyridaben and phonetic mite ester is compared with two single doses and to be had following advantages: (1) has significantly improved the omnidistance prevention effect to red spider; (2) have quick-acting and the long holding effect of enhancing concurrently, the desinsection effect of 3 days, 10 days and 15 days all is significantly higher than each single dose after the dispenser.
Claims (6)
1, a kind of Synergistic insecticidal compositions that contains pyridaben and fluacrypyrim, it is characterized in that it is by primary activity composition pyridaben, fluacrypyrim, auxiliary agent, the composite cream preparation that forms of excipients, the weight portion of each component is: 0.1～30 part of pyridaben, fluacrypyrim: 0.5～30, auxiliary agent: 3～15, excipient: surplus.
2, the Synergistic insecticidal compositions that contains pyridaben and fluacrypyrim according to claim 1, it is characterized in that described auxiliary agent is the one or more combinations in calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, polyoxyethylene polyoxy third rare block compound or the polyoxyethylene nonylphenol ether, excipient is dimethylbenzene or solvent naphtha or its combination.
3, the Synergistic insecticidal compositions that contains pyridaben and fluacrypyrim according to claim 1 is characterized in that effective ingredient is present in the composition with the synergy effective dose.
4, the Synergistic insecticidal compositions that contains pyridaben and fluacrypyrim according to claim 1 is characterized in that the weight portion of pyridaben and fluacrypyrim is respectively 0.5～20 and 1～25.
5, the application of the described Pesticidal combination of claim 1 on the control mite pest.
6, the application of Pesticidal combination according to claim 5 on the control two spotted spider mite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100414440A CN100375595C (en) | 2005-08-12 | 2005-08-12 | Synergistic compound pesticide contg. pyridaben and pyridaben, and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100414440A CN100375595C (en) | 2005-08-12 | 2005-08-12 | Synergistic compound pesticide contg. pyridaben and pyridaben, and its application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1911013A true CN1911013A (en) | 2007-02-14 |
| CN100375595C CN100375595C (en) | 2008-03-19 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100414440A Expired - Fee Related CN100375595C (en) | 2005-08-12 | 2005-08-12 | Synergistic compound pesticide contg. pyridaben and pyridaben, and its application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100375595C (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101990893A (en) * | 2010-11-01 | 2011-03-30 | 吴明龙 | Pesticide composition containing etoxazole and pyridaben |
| CN102113488A (en) * | 2010-12-30 | 2011-07-06 | 青岛泰生生物科技有限公司 | A kind of insecticidal and acaricidal composition containing cyflumetate |
| CN102726413A (en) * | 2012-07-12 | 2012-10-17 | 江苏艾津农化有限责任公司 | Mite-killing pesticide composition containing pyridaben and fenpyroximate |
| CN102972404A (en) * | 2012-12-24 | 2013-03-20 | 海利尔药业集团股份有限公司 | Pesticidal composition containing fluacrypyrim and cyflumetofen |
| CN103416408A (en) * | 2012-05-18 | 2013-12-04 | 陕西美邦农药有限公司 | A kind of insecticidal composition containing pyrimaben |
| CN103583524A (en) * | 2013-11-26 | 2014-02-19 | 陕西农心作物科技有限公司 | Insecticide composition containing pyriminostrobin and pyridaben |
| CN105707080A (en) * | 2012-05-18 | 2016-06-29 | 陕西美邦农药有限公司 | Insecticidal composite with fluacrypyrim |
| CN105851008A (en) * | 2012-06-27 | 2016-08-17 | 陕西美邦农药有限公司 | Pesticide composition containing acequinocyl |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1225976C (en) * | 2004-01-14 | 2005-11-09 | 深圳市诺普信农化有限公司 | Synergistic insecticide and acaricide composition |
-
2005
- 2005-08-12 CN CNB2005100414440A patent/CN100375595C/en not_active Expired - Fee Related
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101990893A (en) * | 2010-11-01 | 2011-03-30 | 吴明龙 | Pesticide composition containing etoxazole and pyridaben |
| CN102113488A (en) * | 2010-12-30 | 2011-07-06 | 青岛泰生生物科技有限公司 | A kind of insecticidal and acaricidal composition containing cyflumetate |
| CN103416408A (en) * | 2012-05-18 | 2013-12-04 | 陕西美邦农药有限公司 | A kind of insecticidal composition containing pyrimaben |
| CN103416408B (en) * | 2012-05-18 | 2016-06-08 | 陕西美邦农药有限公司 | A kind of insecticidal composition containing pyrimaben |
| CN105707080A (en) * | 2012-05-18 | 2016-06-29 | 陕西美邦农药有限公司 | Insecticidal composite with fluacrypyrim |
| CN105707080B (en) * | 2012-05-18 | 2018-07-03 | 陕西美邦农药有限公司 | A kind of Pesticidal combination containing fluacrypyrim |
| CN105851008A (en) * | 2012-06-27 | 2016-08-17 | 陕西美邦农药有限公司 | Pesticide composition containing acequinocyl |
| CN102726413A (en) * | 2012-07-12 | 2012-10-17 | 江苏艾津农化有限责任公司 | Mite-killing pesticide composition containing pyridaben and fenpyroximate |
| CN102972404A (en) * | 2012-12-24 | 2013-03-20 | 海利尔药业集团股份有限公司 | Pesticidal composition containing fluacrypyrim and cyflumetofen |
| CN103583524A (en) * | 2013-11-26 | 2014-02-19 | 陕西农心作物科技有限公司 | Insecticide composition containing pyriminostrobin and pyridaben |
| CN103583524B (en) * | 2013-11-26 | 2015-11-18 | 陕西农心作物科技有限公司 | A kind of Pesticidal combination containing phonetic mite amine and pyridaben |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100375595C (en) | 2008-03-19 |
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