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CN1165235C - Pesticide preparation mixed with azadirachtin and Bt - Google Patents

Pesticide preparation mixed with azadirachtin and Bt Download PDF

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CN1165235C
CN1165235C CNB011193972A CN01119397A CN1165235C CN 1165235 C CN1165235 C CN 1165235C CN B011193972 A CNB011193972 A CN B011193972A CN 01119397 A CN01119397 A CN 01119397A CN 1165235 C CN1165235 C CN 1165235C
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azadirachtin
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pesticide
wettable powder
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CN1335064A (en
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徐汉虹
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South China Agricultural University
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South China Agricultural University
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Abstract

The present invention provides a mixed nimbin pesticide having the advantages of high efficiency, low toxicity, no pollution, no harm to human and livestock, and low possibility of pesticide resistance generated by pests. In the mixed nimbin pesticide, the synergistic effect and the negative cross resistance relationship between the active components of nimbin and Bt are used for overcoming the pesticide resistance of pests, enhancing the application effect of the pesticide, and enlarging the application range of the pesticide. The deficiencies of the single-agent pesticides can be overcome owning to the synergistic effect of the components of the mixed nimbin pesticide in the application process. The pesticide is particularly suitable for controlling various pests with strong pesticide resistance.

Description

印楝素与Bt混配的农药制剂Pesticide preparation mixed with azadirachtin and Bt

本发明属于一种混配农药,具体地,涉及印楝素如何与其他杀虫剂混配。The invention belongs to a kind of mixed pesticide, in particular how to mix azadirachtin with other pesticides.

由于人们长期赖于单于使用某一类型的杀虫剂,害虫容易产生抗药性,致使杀虫剂的化学用药量急剧增加,不仅加重农民的经济负担、污染环境,而且由于大量杀灭害虫的天敌,导致害虫的猖獗危害。目前市场上拥有大量的混配杀虫剂,但绝大多数为化学农药之间的混配,这些混剂大都含有有机磷类,对人畜的毒性较大,易引起人畜中毒,而且经较长时间使用后,害虫也会产生抗药性。Because people rely on a single type of insecticide for a long time, pests are prone to develop resistance, resulting in a sharp increase in the amount of chemical pesticides used, which not only increases the economic burden on farmers and pollutes the environment, but also due to the large number of insecticides. Natural enemies, leading to rampant damage of pests. At present, there are a large number of mixed insecticides on the market, but most of them are mixed with chemical pesticides. Most of these mixed agents contain organic phosphorus, which are highly toxic to humans and animals, and can easily cause human and animal poisoning. Pests can also develop resistance over time.

本发明的目的在于研制一类以植物印楝种子中的印楝素为杀虫活性成分,通过与高效、低毒的Bt杀虫剂进行合理的混配后,获得可以克服害虫抗药性的印楝素混配农药制剂。The purpose of the present invention is to develop a class of azadirachtin in the seeds of neem plant as the insecticidal active ingredient, after reasonable mixing with high-efficiency, low-toxic Bt insecticides, to obtain azadirachtin that can overcome the resistance of pests Neem mixed with pesticide preparations.

本发明利用印楝种子进行浸提,成为含有一定浓度的印楝素提取液,提取液经浓缩蒸干后成浓缩液。The invention utilizes neem seeds to carry out leaching to obtain an extract solution containing a certain concentration of azadirachtin, and the extract solution is concentrated and evaporated to dryness to form a concentrated solution.

本发明利用植物印楝种子中的印楝素为杀虫活性成分,通过与生物农药Bt混配,并配入适量助剂制备成混配农药印楝素+Bt可湿性粉剂制剂。The invention utilizes the azadirachtin in the neem seed of the plant as an insecticidal active ingredient, mixes it with the biopesticide Bt, and adds an appropriate amount of auxiliary agent to prepare a mixed pesticide azadirachtin+Bt wettable powder preparation.

混配农药印楝素+Bt可湿性粉剂制剂中各成分含量配比是:印楝素含量为0.1-35%(重量);Bt含量含量为0.5-50%(重量);润湿剂含量为1-20%(重量);分散剂含量为7-30%(重量);防腐剂含量为0.1-2.9%(重量);填料含量为15-75%(重量);各组分总和为100%。The content ratio of each component in the mixed pesticide azadirachtin+Bt wettable powder preparation is: the content of azadirachtin is 0.1-35% (weight); the content of Bt is 0.5-50% (weight); the content of wetting agent is 1-20% (weight); dispersant content is 7-30% (weight); preservative content is 0.1-2.9% (weight); filler content is 15-75% (weight); the sum of each component is 100% .

混配农药印楝素+Bt可湿性粉剂制剂中的润湿剂组分是选自:木质素磺酸盐、烷基苯磺酸盐、拉开粉、多山梨醇酯中的任一种或多种;分散剂组分是选自:萘磺酸盐、烷基磺酸盐、聚氧乙基醚磺酸盐、二异丙基磷酸盐任一种或多种;防腐剂组分是选自:活性炭、碱土金属任一种或多种;填料组分是选自:高岭土、硅藻土、活性炭任一种或多种。The wetting agent component in the mixed pesticide azadirachtin+Bt wettable powder formulation is selected from: any one of lignosulfonate, alkylbenzenesulfonate, pull-open powder, polysorbate ester or Various; the dispersant component is selected from any one or more of naphthalene sulfonate, alkyl sulfonate, polyoxyethyl ether sulfonate, diisopropyl phosphate; the preservative component is selected From: any one or more of activated carbon and alkaline earth metal; the filler component is selected from: any one or more of kaolin, diatomaceous earth, and activated carbon.

混配农药印楝素+Bt可湿性粉剂制剂中各成分含量的最优配比是:印楝素含量为0.3-20%(重量);Bt含量为1-1.5%(重量);润湿剂含量为5-15%(重量);分散剂含量为10-25%(重量);防腐剂含量为1-1.5%(重量);填料含量为45-65%(重量);各组分总和为100%。The optimum proportioning ratio of each component content in the mixed pesticide azadirachtin+Bt wettable powder preparation is: azadirachtin content is 0.3-20% (weight); Bt content is 1-1.5% (weight); wetting agent The content is 5-15% (weight); the dispersant content is 10-25% (weight); the preservative content is 1-1.5% (weight); the filler content is 45-65% (weight); the sum of each component is 100%.

混配农药印楝素+Bt可湿性粉剂制剂在制备过程中,采用常规的农药可湿性粉剂加工工艺即可。During the preparation process of the mixed pesticide azadirachtin+Bt wettable powder preparation, the conventional pesticide wettable powder processing technology can be adopted.

为了更好地理解发明的实质,下面用实例来详细说明发明的技术内容,但本发明的内容并不局限于此。In order to better understand the essence of the invention, the technical content of the invention is described in detail below with examples, but the content of the present invention is not limited thereto.

实施例一:生产1.2%的(印楝素+Bt)可湿性粉剂Embodiment one: produce 1.2% (Azadirachtin+Bt) wettable powder

印楝素含量          0.8%(重量)Azadirachtin content 0.8% (weight)

Bt含量              0.4%(重量)Bt content 0.4% (weight)

润湿剂              15%(重量)Wetting agent 15% (weight)

分散剂              20%(重量)Dispersant 20% (weight)

防腐剂              1.3%(重量)Preservatives 1.3% (weight)

填料                62.5%(重量)Filler 62.5% (weight)

实施例二:生产1.5%的(印楝素+Bt)可湿性粉剂Embodiment two: produce 1.5% (Azadirachtin+Bt) wettable powder

印楝素含量         0.9%(重量)Azadirachtin content 0.9% (weight)

Bt含量             0.6%(重量)Bt content 0.6% (weight)

润湿剂             15%(重量)Wetting agent 15% (weight)

分散剂             20%(重量)Dispersant 20% (weight)

防腐剂             1.3%(重量)Preservatives 1.3% (weight)

填料               62.2%(重量)Filler 62.2% (weight)

实施例三:生产10%的(印楝素+Bt)可湿性粉剂Embodiment three: produce 10% (Azadirachtin+Bt) wettable powder

印楝素含量         9%(重量)Azadirachtin content 9% (weight)

Bt含量             1%(重量)Bt content 1% (weight)

润湿剂             12%(重量)Wetting agent 12% (weight)

分散剂             16%(重量)Dispersant 16% (weight)

防腐剂             1.2%(重量)Preservatives 1.2% (weight)

填料               60.8%(重量)Filler 60.8% (weight)

实施例四:生产11%的(印楝素+Bt)可湿性粉剂Embodiment four: produce 11% (azadirachtin+Bt) wettable powder

印楝素含量         9.8%(重量)Azadirachtin content 9.8% (weight)

Bt含量             1.2%(重量)Bt content 1.2% (weight)

润湿剂             12%(重量)Wetting agent 12% (weight)

分散剂             15%(重量)Dispersant 15% (weight)

防腐剂             1.2%(重量)Preservatives 1.2% (weight)

填料              60.8%(重量)Filler 60.8% (weight)

实施例五:生产20%的(印楝素+Bt)可湿性粉剂Embodiment five: produce 20% (azadirachtin+Bt) wettable powder

印楝素含量        18.6%(重量)Azadirachtin content 18.6% (weight)

Bt含量            1.4%(重量)Bt content 1.4% (weight)

润湿剂            13%(重量)Wetting agent 13% (weight)

分散剂            14%(重量)Dispersant 14% (weight)

防腐剂            1.2%(重量)Preservatives 1.2% (weight)

填料              51.8%(重量)Filler 51.8% (weight)

实施例六:生产22%的(印楝素+Bt)可湿性粉剂Embodiment six: produce 22% (azadirachtin+Bt) wettable powder

印楝素含量        20%(重量)Azadirachtin content 20% (weight)

Bt含量            2%(重量)Bt content 2% (weight)

润湿剂            10%(重量)Wetting agent 10% (weight)

分散剂            20%(重量)Dispersant 20% (weight)

防腐剂            1.0%(重量)Preservatives 1.0% (weight)

填料              47%(重量)Filler 47% (weight)

实施例七:生产45%的(印楝素+Bt)可湿性粉剂Embodiment seven: produce 45% (azadirachtin+Bt) wettable powder

印楝素含量        1%(重量)Azadirachtin content 1% (weight)

Bt含量            44%(重量)Bt content 44% (weight)

润湿剂            5%(重量)Wetting agent 5% (weight)

分散剂            19%(重量)Dispersant 19% (weight)

防腐剂              1%(重量)Preservatives 1% (weight)

填料                30%(重量)Filler 30% (weight)

实施例八:生产50%的(印楝素+Bt)可湿性粉剂Embodiment eight: produce 50% (azadirachtin+Bt) wettable powder

印楝素含量          3%(重量)Azadirachtin content 3% (weight)

Bt含量              47%(重量)Bt content 47% (weight)

润湿剂              10%(重量)Wetting agent 10% (weight)

分散剂              20%(重量)Dispersant 20% (weight)

防腐剂              1.5%(重量)Preservatives 1.5% (weight)

填料                18.5%(重量)Filler 18.5% (weight)

本发明的有益效果如下:The beneficial effects of the present invention are as follows:

1.本发明在配制印楝素+Bt可湿性粉剂制剂过程中,通过加入多种供选用的润湿剂、分散剂、防腐剂和填料,系统深入解决了印楝素+Bt可湿性粉剂制剂分散性能差、易污染等难题。1. In the process of preparing azadirachtin+Bt wettable powder preparation, the present invention solves the problem of azadirachtin+Bt wettable powder preparation in depth by adding a variety of wetting agents, dispersants, preservatives and fillers for selection. Poor dispersion performance, easy to pollute and other problems.

2.印楝素与Bt按前述选定比例混配后,不仅保持了生物农药本身的众多优点,而且混剂的用药量降低,药效大幅度提高,弥补了印楝素植物性杀虫剂对鳞翅目害虫胃毒作用效果差的弱点。该混剂对天然杀虫剂的开发应用具有深远的意义。2. After the azadirachtin and Bt are mixed according to the aforementioned selected ratio, not only the advantages of the biopesticide itself are maintained, but also the dosage of the mixture is reduced, and the drug effect is greatly improved, which makes up for the azadirachtin botanical insecticide. The weak point of poor stomach poisoning effect on lepidopteran pests. The mixture has far-reaching significance for the development and application of natural insecticides.

3.印楝素与Bt属两类作用机制不同的杀虫剂,混配后的印楝素+Bt可湿性粉剂制剂不仅扩大了害虫防治谱,且对同时发生的害虫有较均匀的药效,从而延缓甚至克服害虫种群演替后可能成为优势种的抗药性。该混剂在对蔬菜上抗性小菜蛾治理过程中的施用效果尤为显著。3. Azadirachtin and Bt are two types of insecticides with different mechanisms of action. The mixed azadirachtin + Bt wettable powder formulation not only expands the spectrum of pest control, but also has a more uniform drug effect on simultaneous pests , so as to delay or even overcome the resistance of the dominant species after the succession of the pest population. The application effect of the mixture is particularly remarkable in the process of controlling resistant diamondback moth on vegetables.

4.由于制备印楝素+Bt可湿性粉剂制剂所需各物质的配伍及配比合理,可极大地减轻对所杀灭各种害虫天敌的毒害作用,对生态环境的损害和污染较小,有利于保护人畜安全。是一类能够防治多种农林害虫,毒付作用小,并可克服害虫抗药性的印楝素混剂。4. Due to the reasonable compatibility and ratio of the various substances required for the preparation of azadirachtin+Bt wettable powder preparations, it can greatly reduce the poisonous effect on the natural enemies of various pests that are killed, and the damage and pollution to the ecological environment are small. Conducive to the protection of human and animal safety. It is a kind of azadirachtin mixture that can prevent and control various agricultural and forestry pests, has little toxic effect, and can overcome the resistance of pests.

Claims (8)

1.一种由印楝素与Bt混配而成的印楝素与Bt可湿性粉剂制剂,其特征在于混配农药制剂中各成分含量配比按重量计:印楝素含量为0.1-35%;Bt含量为0.5-50%;润湿剂含量为1-20%;分散剂含量为7-30%;防腐剂含量为0.1-2.9%;填料含量为15-75%;各组分总和为100%。1. Azadirachtin and Bt wettable powder preparation formed by mixing azadirachtin and Bt is characterized in that the content ratio of each component in the mixed pesticide preparation is by weight: azadirachtin content is 0.1-35 %; Bt content is 0.5-50%; wetting agent content is 1-20%; dispersant content is 7-30%; preservative content is 0.1-2.9%; filler content is 15-75%; is 100%. 2.根据权利要求1所述的混配农药印楝素与Bt可湿性粉剂制剂,其特征在于所述的润湿剂组分是选自:木质素磺酸盐、烷基苯磺酸盐、拉开粉、多山梨醇酯中的任一种或多种。2. the mixed pesticide azadirachtin and Bt wettable powder preparation according to claim 1, is characterized in that described wetting agent component is selected from: lignosulfonate, alkylbenzenesulfonate, Any one or more of pull-off powder and polysorbate. 3.根据权利要求1所述的混配农药印楝素与Bt可湿性粉剂制剂,其特征在于所述的分散剂组分是选自:萘磺酸盐、烷基磺酸盐、聚氧乙基醚磺酸盐、二异丙基磷酸盐任一种或多种。3. the mixed pesticide azadirachtin and Bt wettable powder preparation according to claim 1, is characterized in that described dispersant component is selected from: naphthalene sulfonate, alkyl sulfonate, polyoxyethylene Any one or more of base ether sulfonate and diisopropyl phosphate. 4.根据权利要求1所述的混配农药印楝素与Bt可湿性粉剂制剂,其特征在于所述的防腐剂为:活性炭。4. The mixed pesticide azadirachtin and Bt wettable powder formulation according to claim 1, characterized in that the preservative is: activated carbon. 5.根据权利要求1所述的混配农药印楝素与Bt可湿性粉剂制剂,其特征在于所述的填料组分是选自:高岭土、硅藻土、活性炭任一种或多种。5. The mixed pesticide azadirachtin and Bt wettable powder formulation according to claim 1, characterized in that the filler component is selected from any one or more of kaolin, diatomaceous earth, and activated carbon. 6.根据权利要求1所述的混配农药印楝素与Bt可湿性粉剂制剂,其特征在于混配农药可湿性粉剂制剂中各成分含量的配比按重量计:印楝素含量为0.3-20%;Bt含量为1-1.5%;润湿剂含量为5-15%;分散剂含量为10-25%;防腐剂含量为1-1.5%;填料含量为45-65%;各组分总和为100%。6. the mixed pesticide azadirachtin and Bt wettable powder preparation according to claim 1 is characterized in that the proportioning ratio of each component content in the mixed pesticide wettable powder preparation is by weight: azadirachtin content is 0.3- 20%; Bt content 1-1.5%; wetting agent content 5-15%; dispersant content 10-25%; preservative content 1-1.5%; filler content 45-65%; The sum is 100%. 7.根据权利要求1所述的印楝素与Bt混配的可湿性粉剂,其特征在于各组分含量按重量计:印楝素含量为1%;Bt含量为44%;润湿剂含量为5%;分散剂含量为19%;防腐剂含量为1%;填料含量为30%。7. The wettable powder mixed with azadirachtin and Bt according to claim 1 is characterized in that each component content is by weight: azadirachtin content is 1%; Bt content is 44%; wetting agent content 5%; dispersant content is 19%; preservative content is 1%; filler content is 30%. 8.根据权利要求1所述的印楝素与Bt混配的可湿性粉剂,其特征在于各组分含量按重量计:印楝素含量为3%;Bt含量为47%;润湿剂含量为10%;分散剂含量为20%;防腐剂含量为1.5%;填料含量为18.5%。8. The wettable powder mixed with azadirachtin and Bt according to claim 1, wherein the content of each component is by weight: azadirachtin content is 3%; Bt content is 47%; wetting agent content 10%; dispersant content 20%; preservative content 1.5%; filler content 18.5%.
CNB011193972A 2001-06-04 2001-06-04 Pesticide preparation mixed with azadirachtin and Bt Expired - Fee Related CN1165235C (en)

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CN99116209A Division CN1094040C (en) 1999-05-28 1999-05-28 Nimbin mixed pesticide preparation and its preparing method

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CN102027999A (en) * 2010-11-18 2011-04-27 黑龙江大学 Bacillus thuringiensis wettable powder containing pullulan polysaccharide and preparation method thereof
CN103814956B (en) * 2014-03-04 2015-12-09 中南林业科技大学 Camellia oleifera cake extract and bacillus thuringiensis compound insecticide and preparation method thereof
CN106490011A (en) * 2016-10-31 2017-03-15 郑州思辩科技有限公司 A kind of biological insecticides of preventing and treating lepidoptera pest and preparation method thereof
CN108935505A (en) * 2017-05-18 2018-12-07 河北昊阳化工有限公司 A kind of mixed pesticide composition for killing subterranean pest-insect

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