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CN1731587A - Vertical type wide bandgap semiconductor device structure and making method - Google Patents

Vertical type wide bandgap semiconductor device structure and making method Download PDF

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CN1731587A
CN1731587A CN 200510043057 CN200510043057A CN1731587A CN 1731587 A CN1731587 A CN 1731587A CN 200510043057 CN200510043057 CN 200510043057 CN 200510043057 A CN200510043057 A CN 200510043057A CN 1731587 A CN1731587 A CN 1731587A
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metal layer
single crystal
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epitaxial layer
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CN100403550C (en
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郝跃
王中林
陈军峰
张进城
张春福
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Xidian University
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Abstract

本发明公开了一种垂直型半导体器件结构及制作方法。主要解决宽禁带半导体材料、器件高缺陷密度及大功率器件散热的问题。采用立体形三维纳米结构,包括衬底、垂直单晶、外延层、金属层、介质层,其中垂直单晶与衬底表面垂直,外延层与垂直单晶平行,金属层平行于衬底的表面,且至少有一层,介质层平行于各金属层之间,进行绝缘隔离,金属层与外延层的界面构成欧姆接触或整流接触,在金属层面上连接外引线。通过在衬底上生长垂直单晶,在该垂直单晶的表面外延多层外延材料,并在衬底上淀积金属层形成欧姆接触和整流接触,在各金属层上引出源极、栅极、漏极外引线。本发明散热能力强、电性能高,可用于大功率器件和微波功率器件的制作。

Figure 200510043057

The invention discloses a vertical semiconductor device structure and a manufacturing method. It mainly solves the problems of wide bandgap semiconductor materials, high defect density of devices and heat dissipation of high-power devices. A three-dimensional nanostructure is adopted, including a substrate, a vertical single crystal, an epitaxial layer, a metal layer, and a dielectric layer, wherein the vertical single crystal is perpendicular to the surface of the substrate, the epitaxial layer is parallel to the vertical single crystal, and the metal layer is parallel to the surface of the substrate , and there is at least one layer, the dielectric layer is parallel to each metal layer for insulation isolation, the interface between the metal layer and the epitaxial layer forms an ohmic contact or a rectifying contact, and the outer lead is connected on the metal layer. By growing a vertical single crystal on the substrate, epitaxial multi-layer epitaxial material on the surface of the vertical single crystal, and depositing a metal layer on the substrate to form ohmic contact and rectifying contact, the source and gate are drawn out on each metal layer , Drain outer lead. The invention has strong heat dissipation capability and high electrical performance, and can be used in the manufacture of high-power devices and microwave power devices.

Figure 200510043057

Description

垂直型宽禁带半导体器件结构及制作方法Vertical wide bandgap semiconductor device structure and manufacturing method

技术领域technical field

本发明属于微电子技术领域,涉及半导体材料、器件制作技术,具体的说是一种半导体器件的结构及其制作方法,可用于制作高质量的异质结构器件、大功率器件等,可有效的降低材料的缺陷密度、提高器件的散热性能。The invention belongs to the technical field of microelectronics, relates to semiconductor materials and device manufacturing technologies, and specifically relates to a structure of a semiconductor device and a manufacturing method thereof, which can be used to manufacture high-quality heterostructure devices, high-power devices, etc., and can effectively Reduce the defect density of the material and improve the heat dissipation performance of the device.

背景技术Background technique

近年来因为以碳化硅SiC、氮化镓GaN为代表的第三代宽禁带半导体具有大禁带宽度、高临界场强、高热导率、高载流子饱和速率、异质结界面二维电子气浓度高等优良特性,使其受到了人们广泛的关注。在理论上,利用这些材料制作的高电子迁移率晶体管HEMT、异质结双极晶体管HBT、发光二极管LED、激光二极管LD等器件将具有现有器件无法比拟的优异性能,因此近年来国内外对其进行了广泛而深入的研究并相继取得了令人瞩目的成果。In recent years, the third-generation wide-bandgap semiconductors represented by silicon carbide SiC and gallium nitride GaN have large bandgap width, high critical field strength, high thermal conductivity, high carrier saturation rate, and two-dimensional heterojunction interface. The excellent characteristics such as high electron gas concentration have attracted widespread attention. In theory, high electron mobility transistor HEMT, heterojunction bipolar transistor HBT, light-emitting diode LED, laser diode LD and other devices made of these materials will have excellent performance that cannot be compared with existing devices. It has conducted extensive and in-depth research and has achieved remarkable results.

然而,目前第三代宽禁带半导体材和相关器件面临的一个重大障碍就是没有天然的单晶材料,难以获得高质量的材料。与此同时,随着以第三代宽禁带半导体材料为基础的大功率器件以及微波功率器件的集成度、功率密度越来越高,其散热问题也越来越严重,使得相关器件及电路的设计、制造也变的越来越困难。However, a major obstacle facing the third-generation wide-bandgap semiconductor materials and related devices is that there is no natural single crystal material, and it is difficult to obtain high-quality materials. At the same time, as the integration and power density of high-power devices based on third-generation wide-bandgap semiconductor materials and microwave power devices are getting higher and higher, their heat dissipation problems are becoming more and more serious, making related devices and circuits The design and manufacture of these materials are also becoming more and more difficult.

以GaN材料为例。80年代末Nakamura等人提出了利用二步法在蓝宝石衬底上外延生长GaN材料的方案,参见Nakamura S,GaN growth using GaN buffer layer,Jpn.J Appl Phys,1991;30(10):L 1705~L 1707。该方案是在蓝宝石衬底上首先生长一层GaN缓冲层,以降低由蓝宝石与GaN晶格失配所引起的高缺陷密度,然后在缓冲层上再生长GaN材料。该方案虽然能够获得比采用单步工艺质量更好的GaN材料,但是由于GaN材料(0001)生长面与蓝宝石衬底(0001)晶面的晶格失配高达约13.8%,所以即使采用了此方案生长的GaN材料的缺陷密仍高达108-1010/cm2以上。Take GaN material as an example. In the late 1980s, Nakamura et al. proposed a two-step method to epitaxially grow GaN materials on sapphire substrates, see Nakamura S, GaN growth using GaN buffer layer, Jpn.J Appl Phys, 1991; 30(10): L 1705 ~L 1707. The solution is to first grow a GaN buffer layer on the sapphire substrate to reduce the high defect density caused by lattice mismatch between sapphire and GaN, and then re-grow GaN material on the buffer layer. Although this solution can obtain GaN materials with better quality than the single-step process, the lattice mismatch between the (0001) growth plane of the GaN material and the (0001) crystal plane of the sapphire substrate is as high as about 13.8%. The defect density of the GaN material grown by the scheme is still as high as 10 8 -10 10 /cm 2 or more.

1993年Detchprohm和Amano等人进一步提出了在ZnO衬底上生长GaN材料的方案,参见Detchprohm T,Amano H,Hiramatsu K,et al.J.Cryst Growth,1993,128:384。该方案是在蓝宝石衬底上首先外延一层ZnO材料用作GaN材料外延生长的衬底;然后利用ZnO材料的晶格结构和晶格常数与GaN材料相近的特性在ZnO材料的表面外延一层GaN材料。虽然ZnO材料与GaN材料具有相近的晶体结构和晶格常数,但是由于ZnO材料与蓝宝石材料之间较大的晶格失配导致通过外延生长的ZnO材料具有较高的缺陷密度,因此在ZnO衬底上生长出的GaN材料的缺陷密度仍然很高。In 1993, Detchprohm and Amano et al. further proposed a plan to grow GaN materials on ZnO substrates, see Detchprohm T, Amano H, Hiramatsu K, et al.J.Cryst Growth, 1993, 128:384. The scheme is to first epitaxially layer a layer of ZnO material on the sapphire substrate as the substrate for the epitaxial growth of GaN material; GaN material. Although the ZnO material and the GaN material have similar crystal structures and lattice constants, the ZnO material grown by epitaxy has a higher defect density due to the large lattice mismatch between the ZnO material and the sapphire material. The defect density of the GaN material grown on the bottom is still very high.

1999年Xu和Wu等人提出了利用芯片倒装工艺提高散热能力的方案,参见Xu J J,Wu YF,Keller S,et al.1-8GHz GaN based power amplifier using FC bonding.IEEE MicrowGuided Wave Lett,1999,9:277。该方案是一种将有源器件管芯翻转,通过凸点将管芯焊接到另一块基板上的方法,此方法在微波电路领域经常用于有源器件与电路基板的组装,对于微波大功率电路制作,该方案常用于器件的散热。该方案虽然在一定程度上改善了器件的散热能力,但是,由于平面工艺的固有限制以及器件的功率密度和集成度的不断提高,该方案已经无法满足大功率器件进一步发展的需要。因此,要解决这些问题就只有寻找新的技术途径。In 1999, Xu and Wu et al. proposed a plan to improve heat dissipation by using flip-chip technology, see Xu J J, Wu YF, Keller S, et al.1-8GHz GaN based power amplifier using FC bonding.IEEE MicrowGuided Wave Lett, 1999, 9:277. This solution is a method of flipping the core of the active device and soldering the core to another substrate through bumps. This method is often used in the field of microwave circuits for the assembly of active devices and circuit substrates. For high-power microwave Circuit fabrication, this solution is often used for heat dissipation of devices. Although this solution improves the heat dissipation capability of the device to a certain extent, due to the inherent limitations of the planar process and the continuous improvement of the power density and integration of the device, this solution has been unable to meet the needs of further development of high-power devices. Therefore, to solve these problems, only to find new technical approaches.

发明的内容content of the invention

本发明的目的在于克服上述已有技术的不足,提供一种垂直型宽禁带半导体器件的结构及其制作方法,以解决目前第三代宽禁带半导体材料、器件的高缺陷密度以及大功率器件散热所存在的问题,满足各种基于第三代宽禁带半导体材料的器件及电路的性能要求。The purpose of the present invention is to overcome the deficiencies of the above-mentioned prior art, to provide a structure of a vertical wide bandgap semiconductor device and its manufacturing method, to solve the problem of high defect density and high power of the third generation wide bandgap semiconductor materials and devices. The problem of device heat dissipation can meet the performance requirements of various devices and circuits based on the third-generation wide bandgap semiconductor materials.

实现本发明的目的的技术方案是:在衬底表面的垂直单晶上通过控制外延层所用的材料和不同的工艺流程制作立体形三维纳米结构的半导体器件及电路。该器件结构主要由衬底、垂直单晶、外延层、金属层、介质层组成;该垂直单晶与衬底表面垂直,该外延层与垂直单晶平行,该金属层平行于衬底的表面,且至少有一层,该介质层平行于各金属层之间,进行绝缘隔离;金属层与外延层的界面构成欧姆接触或整流接触,并在各金属层上引出外引线。The technical solution for realizing the object of the present invention is: on the vertical single crystal on the surface of the substrate, by controlling the materials used in the epitaxial layer and different technological processes, a three-dimensional nanostructure semiconductor device and circuit are produced. The device structure is mainly composed of a substrate, a vertical single crystal, an epitaxial layer, a metal layer, and a dielectric layer; the vertical single crystal is perpendicular to the surface of the substrate, the epitaxial layer is parallel to the vertical single crystal, and the metal layer is parallel to the surface of the substrate , and there is at least one layer, the dielectric layer is parallel to each metal layer for insulation and isolation; the interface between the metal layer and the epitaxial layer forms an ohmic contact or a rectifying contact, and an outer lead is drawn on each metal layer.

制作所述立体半导体器件的方法,按如下过程进行:The method for making the three-dimensional semiconductor device is carried out as follows:

首先,根据器件类型选择衬底、单晶、外延、金属、介质材料,并对衬底材料进行表面处理,使其具有平整的表面;其次,在经过表面处理的衬底材料上利用胶体晶体法或光刻掩膜的方法制作所需的催化剂模板;第三,使用单晶材料在衬底材料上利用汽相-液相-固相VLS、汽相-固相VS、液相-固相LS机制生长出垂直单晶纳米结构;第四,在垂直单晶的侧面通过分子束外延MBE或金属有机化学汽相淀积MOCVD技术外延生长至少一层外延层;第五,使用金属层材料以及介质材料在垂直外延层表面通过淀积、腐蚀等工艺形成至少一层金属层和介质层,构成器件所需的欧姆接触或整流接触;第六,通过定向刻蚀和淀积技术在平行于衬底材料表面的各金属层上分别引出源极、栅极、漏极的外引线,形成基本的器件单元。First, select the substrate, single crystal, epitaxy, metal, and dielectric material according to the device type, and perform surface treatment on the substrate material to make it have a flat surface; secondly, use the colloidal crystal method on the surface-treated substrate material or photolithographic mask method to make the required catalyst template; third, use single crystal material on the substrate material to utilize vapor phase-liquid phase-solid phase VLS, vapor phase-solid phase VS, liquid phase-solid phase LS Mechanism to grow vertical single-crystal nanostructures; fourth, epitaxially grow at least one epitaxial layer on the side of the vertical single crystal by molecular beam epitaxy MBE or metal organic chemical vapor deposition MOCVD technology; fifth, use metal layer materials and dielectric The material forms at least one metal layer and a dielectric layer on the surface of the vertical epitaxial layer through deposition, corrosion and other processes to form the ohmic contact or rectifying contact required by the device; sixth, through directional etching and deposition technology in parallel to the substrate The outer leads of the source, gate and drain are respectively drawn out from each metal layer on the surface of the material to form a basic device unit.

利用本发明的方法,重复上述第五步,即可在每根垂直单晶上生长多个器件,则这时构成电路的器件将形成一种立体网状分布,这种形式的电路的制造和设计方法将不同于现有的平面制造工艺和设计方法,将推动半导体制造和设计技术从传统的2D领域发展到3D领域。Utilize the method of the present invention, repeat above-mentioned fifth step, can grow a plurality of devices on each vertical single crystal, then the device that constitutes circuit will form a kind of three-dimensional network distribution at this moment, the manufacture of this form of circuit and The design method will be different from the existing planar manufacturing process and design method, which will promote the development of semiconductor manufacturing and design technology from the traditional 2D field to the 3D field.

上述半导体器件结构,其中的垂直单晶可以采用柱状单晶,也可以是带状单晶或其它具有垂直形貌的结构,该垂直单晶的侧面为生长外延层的衬底,依次外延有至少一层的外延层。The above-mentioned semiconductor device structure, wherein the vertical single crystal can be a columnar single crystal, or a ribbon single crystal or other structures with vertical morphology, the side of the vertical single crystal is the substrate for growing the epitaxial layer, and the epitaxy has at least One layer of epitaxial layer.

上述半导体器件结构,其中最外面的外延层的表面自下而上依次形成多层金属层和介质层的交替结构,即第一金属层和第一介质层,第二金属层和第二介质层,第三金属层。The above-mentioned semiconductor device structure, wherein the surface of the outermost epitaxial layer forms an alternating structure of multi-layer metal layers and dielectric layers sequentially from bottom to top, that is, the first metal layer and the first dielectric layer, the second metal layer and the second dielectric layer , the third metal layer.

上述半导体器件结构,其中金属层与最外面的外延层的界面构成欧姆接触或整流接触是由第一金属层与最外面的外延层组成欧姆接触,形成源极;由第二金属层与最外面的外延层组成整流接触,形成栅极;由第三金属层与最外面的外延层组成欧姆接触,形成漏极。The semiconductor device structure above, wherein the interface between the metal layer and the outermost epitaxial layer forms an ohmic contact or a rectifying contact is formed by the first metal layer and the outermost epitaxial layer forming an ohmic contact to form a source; the second metal layer and the outermost The epitaxial layer forms a rectifying contact to form a gate; the third metal layer and the outermost epitaxial layer form an ohmic contact to form a drain.

上述半导体器件结构,如果采用导电衬底材料,则可用该导电衬底代替第一金属层,成为两层金属层,即由导电衬底与最外面的外延层组成欧姆接触,形成源极。If the above-mentioned semiconductor device structure uses a conductive substrate material, the conductive substrate can be used to replace the first metal layer to form two metal layers, that is, the conductive substrate and the outermost epitaxial layer form an ohmic contact to form a source.

本发明由于采用立体的器件界结构,在单位面积的衬垫材料上生长的的垂直单晶阵列所具有的表面积远大于其衬底材料的表面积,因此在同样的器件密度、器件类型与同样的环境下,其散热能力将远高于平面工艺所得的电路或器件;同时由于器件制作在具有很低的缺陷密度的垂直单晶上,因此如果进行外延的材料与垂直单晶具有相同或相近的晶体结构、晶格常数、热膨胀系数等参数,则外延层与垂直单晶的界面处晶格失配将大为减少,外延层材料中的缺陷密度也将大大的降低,从而获得其他方法难以得到的高质量的外延单晶材料;此外由于在器件的制作过程中选择高热导率的衬底材料和垂直单晶材料,并且可以腐蚀掉金属层之间的介质材料使用空气作为介质,利用空气的对流作用进行散热,可进一步提高器件、电路的散热能力。Because the present invention adopts the three-dimensional device boundary structure, the surface area of the vertical single crystal array grown on the liner material per unit area is much larger than the surface area of the substrate material, so the same device density, device type and the same In the environment, its heat dissipation capability will be much higher than that of the circuit or device obtained by the planar process; at the same time, since the device is fabricated on a vertical single crystal with a very low defect density, if the material for epitaxy has the same or similar thermal conductivity as the vertical single crystal Crystal structure, lattice constant, thermal expansion coefficient and other parameters, the lattice mismatch at the interface between the epitaxial layer and the vertical single crystal will be greatly reduced, and the defect density in the epitaxial layer material will also be greatly reduced, so that it is difficult to obtain by other methods. high-quality epitaxial single crystal material; in addition, due to the selection of high thermal conductivity substrate material and vertical single crystal material in the manufacturing process of the device, and the dielectric material between the metal layers can be etched away using air as the medium, the use of air Heat dissipation by convection can further improve the heat dissipation capacity of devices and circuits.

附图说明Description of drawings

图1是本发明器件的结构剖面图Fig. 1 is the structural sectional view of device of the present invention

图2是本发明器件的制作流程图Fig. 2 is the fabrication flowchart of device of the present invention

图3是本发明基于ZnO纳米柱状单晶的AlGaN/GaN HFET单管器件剖面图Fig. 3 is the sectional view of the AlGaN/GaN HFET single-tube device based on the ZnO nano columnar single crystal of the present invention

图4是本发明基于ZnO纳米带状单晶的AlGaN/GaN HFET单管器件剖面图Fig. 4 is the sectional view of the AlGaN/GaN HFET single-tube device based on the ZnO nanoribbon single crystal of the present invention

图5是本发明基于阵列ZnO纳米柱状单晶的AlGaN/GaN微波功率器件剖面图Fig. 5 is the sectional view of the AlGaN/GaN microwave power device based on the arrayed ZnO nano columnar single crystal of the present invention

具体实施方式Detailed ways

参照图1,本发明的器件结构由衬底、垂直单晶、外延层、金属层、介质层组成。Referring to Fig. 1, the device structure of the present invention is composed of a substrate, a vertical single crystal, an epitaxial layer, a metal layer, and a dielectric layer.

该衬底为整个器件的基座,在其表面制作各种器件。垂直单晶垂直生长在衬底的表面,该垂直单晶可以是六角形截面的柱状单晶,也可以是四边形截面的带状单晶或其它具有垂直形貌的结构。该垂直单晶的侧面作为生长外延层的衬底,在其侧面依次外延有多层不同厚度的外延层,各个外延层平行于垂直单晶的侧面,形成与衬底垂直的垂直外延层。最外面的外延层表面自下而上是多层金属层和介质层的交替结构,例如,第一金属层1和第一介质层1,第二金属层2和第二介质层2,第三金属层3。不同的金属层与最外面的外延层的界面构成欧姆接触或整流接触,例如,第一金属层与最外面的外延层组成欧姆接触形成源极;第二金属层与最外面的外延层组成整流接触形成栅极;第三金属层与最外面的外延层组成欧姆接触形成漏极。每个介质层的作用是对各个金属层进行绝缘隔离,并且对金属层的淀积起到支撑的作用。在各金属层上分别引出源极、栅极、漏极的外引线。The substrate is the base of the entire device, and various devices are fabricated on its surface. The vertical single crystal grows vertically on the surface of the substrate, and the vertical single crystal can be a columnar single crystal with a hexagonal cross section, or a ribbon single crystal with a quadrangular cross section or other structures with vertical morphology. The side of the vertical single crystal is used as a substrate for growing epitaxial layers, and multiple layers of epitaxial layers with different thicknesses are epitaxially extended on the side of the vertical single crystal. Each epitaxial layer is parallel to the side of the vertical single crystal to form a vertical epitaxial layer perpendicular to the substrate. The surface of the outermost epitaxial layer is an alternating structure of multiple metal layers and dielectric layers from bottom to top, for example, the first metal layer 1 and the first dielectric layer 1, the second metal layer 2 and the second dielectric layer 2, the third Metal layer 3. The interface between different metal layers and the outermost epitaxial layer forms an ohmic contact or a rectifying contact. For example, the first metal layer forms an ohmic contact with the outermost epitaxial layer to form a source; the second metal layer forms a rectifying contact with the outermost epitaxial layer. The contact forms the gate; the third metal layer forms an ohmic contact with the outermost epitaxial layer to form the drain. The role of each dielectric layer is to insulate and isolate each metal layer, and to support the deposition of the metal layer. Outer leads of the source, gate and drain are respectively drawn out on each metal layer.

参照图2,制作所述立体半导体器件的具体步骤为:Referring to Fig. 2, the specific steps of making the three-dimensional semiconductor device are:

第一步,首先选择外延层材料,接着选择垂直单晶材料,然后选择衬底材料,最后根据最外面的外延层材料选择各金属层材料和介质材料;The first step is to select the epitaxial layer material first, then select the vertical single crystal material, then select the substrate material, and finally select the metal layer material and dielectric material according to the outermost epitaxial layer material;

该外延材料的选择:首先根据器件和电路的要求选择材料,即对于散热能力要求高的器件和电路选用热导率高的外延层材料,对于速度要求高的电路选用迁移率高的外延层材料;然后确定使器件性能最优的外延层材料的生长晶向。The selection of the epitaxial material: first select the material according to the requirements of the device and circuit, that is, select the epitaxial layer material with high thermal conductivity for the device and circuit with high heat dissipation capability, and select the epitaxial layer material with high mobility for the circuit with high speed requirement ; Then determine the growth crystal direction of the epitaxial layer material to optimize the device performance.

该垂直单晶的材料选择:首先根据已选定的外延层材料选择与其晶体结构相同的垂直单晶材料;其次选择侧面与外延层生长面晶格失配最小的垂直单晶材料并确定垂直单晶的生长方向;最后选择热导率高的垂直单晶材料。The material selection of the vertical single crystal: first, select the vertical single crystal material with the same crystal structure according to the selected epitaxial layer material; secondly, select the vertical single crystal material with the smallest lattice mismatch between the side surface and the growth plane of the epitaxial layer and determine the vertical single crystal material. The growth direction of the crystal; finally, a vertical single crystal material with high thermal conductivity is selected.

该衬底材料的选择:首先根据已选定的垂直单晶材料,选择满足垂直单晶生长条件的衬底材料;其次选择热导率高的衬底材料。The selection of the substrate material: first, according to the selected vertical single crystal material, select the substrate material that meets the vertical single crystal growth conditions; secondly, select the substrate material with high thermal conductivity.

该金属材料的选择:根据已选定的最外面的外延层材料选择与其能够组成良好的欧姆接触或整流接触的金属材料。The selection of the metal material: according to the selected outermost epitaxial layer material, select a metal material that can form a good ohmic contact or rectifying contact with it.

该介质材料的选择:首先选择具有绝缘能力的介质;其次选择热导率高的介质材料。The selection of the dielectric material: firstly, select the medium with insulating ability; secondly, select the dielectric material with high thermal conductivity.

根据所述选择各类材料的原则,本发明选择的外延层材料可以是GaN、AlGaN、ZnO、GaAs、AlGaAs等;选择的垂直单晶材料根据外延层材料的不同可以是ZnO、GaN等;选择的外衬底材料可以是多晶蓝宝石、单晶蓝宝石、单晶GaN等;选择的金属层根据外延层材料和接触类型的不同可以是Al、Au、Ti/Ag等;选择的介质材料可以是SiO2、Si3N4、空气等。According to the principle of selecting various materials, the epitaxial layer material selected by the present invention can be GaN, AlGaN, ZnO, GaAs, AlGaAs, etc.; the vertical single crystal material selected can be ZnO, GaN, etc. according to the difference of the epitaxial layer material; The outer substrate material can be polycrystalline sapphire, single crystal sapphire, single crystal GaN, etc.; the selected metal layer can be Al, Au, Ti/Ag, etc. according to the epitaxial layer material and contact type; the selected dielectric material can be SiO 2 , Si 3 N 4 , air, etc.

第二步,对所选衬底材料进行表面处理,使其具有平整、光滑的表面;The second step is to carry out surface treatment on the selected substrate material to make it have a flat and smooth surface;

第三步,在经过表面处理的衬底材料上根据器件及电路的需要利用胶体晶体法或光刻掩膜的方法制作催化剂模板;The third step is to make a catalyst template on the surface-treated substrate material according to the needs of the device and the circuit by using the colloidal crystal method or the method of photolithography mask;

第四步,使用垂直单晶材料在衬底材料上利用汽相-液相-固相VLS、汽相-固相VS、液相-固相LS机制生长出垂直单晶;垂直单晶的分布、密度、几何形貌等参数可通过生长条件、催化剂类型、衬底晶向等进行控制;The fourth step is to use the vertical single crystal material to grow vertical single crystals on the substrate material using vapor-liquid-solid VLS, vapor-solid VS, and liquid-solid LS mechanisms; the distribution of vertical single crystals , density, geometry and other parameters can be controlled by growth conditions, catalyst type, substrate crystal orientation, etc.;

第五步,使用外延层材料在垂直单晶的表面通过MBE或MOCVD外延生长至少一层外延层,通过控制外延的时间、环境等因素控制外延层的厚度、导电类型、组分等参数调整器件的特性;The fifth step is to use the epitaxial layer material to epitaxially grow at least one epitaxial layer on the surface of the vertical single crystal by MBE or MOCVD, and control the thickness, conductivity type, composition and other parameters of the epitaxial layer by controlling the epitaxial time, environment and other factors to adjust the device characteristics;

第六步,使用金属层材料以及介质材料在垂直于外延层的衬底表面通过电子束蒸发、热蒸发的方法淀积以及腐蚀工艺形成三层金属层和两层介质层,制作欧姆接触或整流接触,并根据散热需要可采用腐蚀的方法刻蚀掉介质层,提高器件的散热能力;The sixth step is to use metal layer materials and dielectric materials on the substrate surface perpendicular to the epitaxial layer to form three layers of metal layers and two layers of dielectric layers through electron beam evaporation, thermal evaporation and corrosion processes to make ohmic contacts or rectifiers. Contact, and according to the heat dissipation needs, the dielectric layer can be etched away by etching to improve the heat dissipation capacity of the device;

第七步,通过定向刻蚀和淀积在平行于衬底材料表面的各金属层上分别引出源极、栅极、漏极的外引线。In the seventh step, the outer leads of the source, gate and drain are respectively drawn out on each metal layer parallel to the surface of the substrate material by directional etching and deposition.

实例1Example 1

本发明制作基于ZnO纳米柱状单晶的垂直型单管AlGaN/GaN HFET器件。The invention manufactures a vertical single-tube AlGaN/GaN HFET device based on ZnO nano columnar single crystal.

外延层材料选用:AlGaN,GaN。Epitaxial layer material selection: AlGaN, GaN.

垂直单晶材料选用:ZnO。Vertical single crystal material selection: ZnO.

衬底材料选用:单晶蓝宝石的(2-1-10)晶面。Substrate material selection: (2-1-10) crystal face of single crystal sapphire.

金属材料选用:Au、Ti/Ag、Al。Metal material selection: Au, Ti/Ag, Al.

介质材料选用:SiO2Dielectric material selection: SiO 2 .

参照图3,本实例器件的结构及制作过程如下:Referring to Figure 3, the structure and manufacturing process of the device in this example are as follows:

1、ZnO纳米柱状单晶的生长1. Growth of ZnO nano-columnar single crystal

第一步,单层自组装亚微米球阵列的制作。The first step is the fabrication of monolayer self-assembled submicron sphere arrays.

选用蓝宝石为衬底。采用胶体晶体法制作亚微米球阵列,选用的胶体晶体为聚苯乙烯亚微米球,聚苯乙烯球的直径约为895nm。首先对衬底进行20分钟的超声波降解,接着在空气气氛中,约1000摄氏度左右再进行约3小时的退火处理,以获得平整且具有亲水性质的衬底表面;然后在其表面滴数滴含有聚苯乙烯球的溶液,等待几分钟后使溶液扩散均匀,将其缓慢的放入去离子水中,静置数分钟后将其取出即可得到单层自组装的亚微米球阵列。Select sapphire as the substrate. The colloidal crystal method is used to fabricate the submicron sphere array, and the selected colloidal crystal is polystyrene submicron sphere, and the diameter of the polystyrene sphere is about 895 nm. First, ultrasonically degrade the substrate for 20 minutes, and then perform annealing treatment at about 1000 degrees Celsius for about 3 hours in an air atmosphere to obtain a flat and hydrophilic substrate surface; then drop a few drops on the surface For the solution containing polystyrene spheres, wait for a few minutes to make the solution diffuse evenly, slowly put it into deionized water, and take it out after standing for a few minutes to obtain a monolayer self-assembled submicron sphere array.

第二步,催化剂模板的制作。The second step is the fabrication of the catalyst template.

首先,将金粒子溅射或者热蒸发到第一步获得的单层自组装亚微米球阵列上;然后,用甲苯溶液刻蚀掉聚苯乙烯球即可在衬底材料表面得到所需的催化剂模板。First, gold particles are sputtered or thermally evaporated onto the single-layer self-assembled submicron sphere array obtained in the first step; then, the polystyrene spheres are etched away with toluene solution to obtain the required catalyst on the surface of the substrate material template.

第三步,生长ZnO纳米柱状单晶。The third step is to grow ZnO nano columnar single crystal.

本例中ZnO纳米柱状单晶通过VLS机制进行生长。其尺寸通过生长的温度、压力、时间等进行控制。所用的原材料中包含等质量的ZnO粉末和石墨粉末,其中石墨粉末用于降低生长时所需的反应温度。首先,将原材料混合后放入氧化铝制试管中央的氧化铝舟上,同时制作好催化剂模板的衬底材料置于氧化铝制试管气流的下游位置;然后,利用水平管式炉以每分钟50度的速率将铝制试管加热到950度,并保持20到30分钟,期间以Ar为载气;最后,关闭管式炉,在氩气气氛中冷却至室温。In this example, ZnO nano-columnar single crystals are grown by VLS mechanism. Its size is controlled by growth temperature, pressure, time, etc. The raw materials used include ZnO powder and graphite powder of equal mass, wherein the graphite powder is used to reduce the reaction temperature required for growth. First, mix the raw materials and put them on the alumina boat in the center of the alumina test tube, and at the same time, the substrate material with the catalyst template is placed in the downstream position of the alumina test tube air flow; then, use a horizontal tube furnace at 50 per minute Heat the aluminum test tube to 950°C at a rate of 20°C for 20 to 30 minutes with Ar as the carrier gas; finally, close the tube furnace and cool to room temperature in an argon atmosphere.

所得的ZnO纳米柱状单晶垂直于衬底材料表面,形貌为六角形柱状晶体,ZnO纳米柱状单晶六个侧面的晶向为[2-1-10]或[0001]方向。ZnO纳米柱状单晶的高度约为1500纳米,直径约为200纳米。The obtained ZnO nano-column single crystal is perpendicular to the surface of the substrate material and has a hexagonal columnar crystal shape, and the crystal orientations of the six sides of the ZnO nano-columnar single crystal are [2-1-10] or [0001]. The ZnO nano-columnar single crystal has a height of about 1500 nm and a diameter of about 200 nm.

将所得的样品在乙醇中进行超声波降解以降低ZnO纳米柱状单晶的密度,获得所需的单根ZnO纳米柱状单晶。The obtained sample is ultrasonically degraded in ethanol to reduce the density of the ZnO nano-columnar single crystal, and obtain the desired single ZnO nano-columnar single crystal.

2、GaN及AlGaN外延层的外延生长2. Epitaxial growth of GaN and AlGaN epitaxial layers

本例中GaN及AlGaN外延层通过MBE方法进行外延生长。In this example, GaN and AlGaN epitaxial layers are epitaxially grown by MBE method.

利用MBE/MOCVD方法首先在柱状ZnO纳米柱状单晶的表面外延生长一层非掺杂的GaN外延层;Using the MBE/MOCVD method, a non-doped GaN epitaxial layer is first epitaxially grown on the surface of the columnar ZnO nano-columnar single crystal;

然后,在GaN外延层表面再外延一层n型掺杂的AlGaN外延层。Then, an n-type doped AlGaN epitaxial layer is epitaxially deposited on the surface of the GaN epitaxial layer.

3、第一金属层、第二金属层、第三金属层以及介质层的制作3. Production of the first metal layer, the second metal layer, the third metal layer and the dielectric layer

首先,通过真空和电子束蒸发Al、Ti/Ag在衬底上制作第一金属层,该第一金属层与AlGaN外延层形成欧姆接触构成源极。First, the first metal layer is formed on the substrate by vacuum and electron beam evaporation of Al and Ti/Ag, and the first metal layer forms an ohmic contact with the AlGaN epitaxial layer to form a source.

接着,在平行于衬底的第一金属层上淀积一层SiO2形成绝缘层;Next, deposit a layer of SiO on the first metal layer parallel to the substrate to form an insulating layer;

然后,通过真空和电子束蒸发Au在介质层上制作第二金属层,该第二金属层与AlGaN外延层形成整流接触构成栅极。Then, a second metal layer is formed on the dielectric layer by vacuum and electron beam evaporation of Au, and the second metal layer forms a rectifying contact with the AlGaN epitaxial layer to form a gate.

接着,在平行于衬底的第二金属层上淀积一层SiO2形成绝缘层;Next, deposit a layer of SiO on the second metal layer parallel to the substrate to form an insulating layer;

最后,利用和制作源极相同的方法制作第三金属层,该第三金属层与AlGaN外延层形成欧姆接触构成漏极。Finally, the third metal layer is fabricated by the same method as that of the source electrode, and the third metal layer forms an ohmic contact with the AlGaN epitaxial layer to form the drain electrode.

4、器件的形成4. Device formation

首先,在ZnO纳米柱状单晶的外围利用定向刻蚀技术进行刻蚀,在平行与衬底的各金属层上形成具有不同高度的台阶型结构;First, use directional etching technology to etch the periphery of the ZnO nano-columnar single crystal to form a stepped structure with different heights on each metal layer parallel to the substrate;

然后,在相应的台阶上淀积Cu或Al形成外电极并连接外引线。Then, deposit Cu or Al on the corresponding steps to form external electrodes and connect external leads.

利用这种方法制得的HFET器件与采用MOCVD方法在蓝宝石上外延制得的HFET器件相比,其材料的缺陷密度显著降低,因此器件的性能有很大的提高。Compared with the HFET device prepared by MOCVD epitaxy on sapphire, the defect density of the material of the HFET device prepared by this method is significantly reduced, so the performance of the device is greatly improved.

实例2Example 2

本发明制作基于ZnO纳米带状单晶的垂直型单管AlGaN/GaN HFET器件。The invention manufactures a vertical single-tube AlGaN/GaN HFET device based on ZnO nanoribbon single crystal.

外延层材料选用:AlGaN,GaN。Epitaxial layer material selection: AlGaN, GaN.

垂直单晶材料选用:ZnO。Vertical single crystal material selection: ZnO.

衬底材料选用:多晶蓝宝石。Substrate material selection: polycrystalline sapphire.

金属材料选用:Au、Ti/Ag、Al。Metal material selection: Au, Ti/Ag, Al.

介质材料选用:Si3N4Dielectric material selection: Si 3 N 4 .

参照图4,本实例器件的结构及制作过程如下:Referring to Figure 4, the structure and manufacturing process of the device in this example are as follows:

1、ZnO纳米带状单晶的生长1. Growth of ZnO nanoribbon single crystal

本例中ZnO纳米带状单晶通过VS机制进行生长,选用的衬底为蓝宝石多晶材料。所用的原材料为ZnO粉末与1%的Li2O粉末。首先,将原材料混合后放入氧化铝制试管中央的氧化铝舟上,同时将蓝宝石多晶衬底材料置于氧化铝制试管气流的下游位置,并将管式炉抽真空至约10-3Torr以去除残留的氧气;然后,利用水平管式炉以每分钟升温20度的速度将其加热到1350度,并在200mbar的压力下保持120分钟,期间以Ar为载气;最后,关闭管式炉,在氩气气氛中冷却至室温。In this example, the ZnO nanoribbon single crystal is grown through the VS mechanism, and the selected substrate is sapphire polycrystalline material. The raw materials used are ZnO powder and 1% Li 2 O powder. First, the raw materials are mixed and placed on the alumina boat in the center of the alumina test tube, while the sapphire polycrystalline substrate material is placed at the downstream position of the alumina test tube airflow, and the tube furnace is evacuated to about 10 -3 Torr to remove residual oxygen; then, use a horizontal tube furnace to heat it to 1350 degrees at a rate of 20 degrees per minute, and keep it at a pressure of 200 mbar for 120 minutes, during which Ar is the carrier gas; finally, close the tube furnace and cooled to room temperature in an argon atmosphere.

所得的纳米带状单晶垂直于衬底材料表面,形貌为四边形带状晶体,ZnO纳米带状单晶的侧面的晶向为[01-10]和[0001]方向,纳米带状单晶的高度约为10微米,宽度为2微米。The obtained nanoribbon-shaped single crystal is perpendicular to the surface of the substrate material, and its appearance is a quadrilateral ribbon-shaped crystal. The crystal directions of the sides of the ZnO nanoribbon-shaped single crystal are [01-10] and [0001] directions, and the nanoribbon-shaped single crystal The height is about 10 microns and the width is 2 microns.

将所得的样品在乙醇中进行超声波降解以降低ZnO纳米带状单晶的密度,获得所需的单根ZnO纳米带状单晶。The obtained sample was ultrasonically degraded in ethanol to reduce the density of the ZnO nanoribbon single crystal, and obtain the desired single ZnO nanoribbon single crystal.

2、GaN及AlGaN外延层的外延生长2. Epitaxial growth of GaN and AlGaN epitaxial layers

本例中GaN及AlGaN外延层通过MBE方法进行外延生长。In this example, GaN and AlGaN epitaxial layers are epitaxially grown by MBE method.

利用MBE/MOCVD方法首先在ZnO纳米带状单晶的表面外延生长一层非掺杂的GaN外延层;Using the MBE/MOCVD method, a non-doped GaN epitaxial layer is first epitaxially grown on the surface of the ZnO nanoribbon single crystal;

其次,在GaN外延层表面再外延一层非掺杂的AlGaN外延层;Secondly, a non-doped AlGaN epitaxial layer is epitaxially deposited on the surface of the GaN epitaxial layer;

然后,在AlGaN外延层表面再外延一层n型掺杂的AlGaN外延层。Then, an n-type doped AlGaN epitaxial layer is epitaxially deposited on the surface of the AlGaN epitaxial layer.

3、第一金属层、第二金属层、第三金属层以及介质层的制作3. Production of the first metal layer, the second metal layer, the third metal layer and the dielectric layer

首先,通过真空和电子束蒸发Al、Ti/Ag在衬底上制作第一金属层,该第一金属层与AlGaN外延层形成欧姆接触构成源极。First, the first metal layer is formed on the substrate by vacuum and electron beam evaporation of Al and Ti/Ag, and the first metal layer forms an ohmic contact with the AlGaN epitaxial layer to form a source.

接着,在平行于衬底的第一金属层上淀积一层Si3N4形成绝缘层。Next, a layer of Si 3 N 4 is deposited on the first metal layer parallel to the substrate to form an insulating layer.

然后,通过真空和电子束蒸发Au在介质层上制作第二金属层,该第二金属层与AlGaN外延层形成整流接触构成栅极。Then, a second metal layer is formed on the dielectric layer by vacuum and electron beam evaporation of Au, and the second metal layer forms a rectifying contact with the AlGaN epitaxial layer to form a gate.

接着,在平行于衬底的第二金属层上淀积一层Si3N4形成绝缘层;Next, deposit a layer of Si 3 N 4 on the second metal layer parallel to the substrate to form an insulating layer;

最后,利用和制作源极相同的方法制作第三金属层,该第三金属层与AlGaN外延层形成欧姆接触构成漏极。Finally, the third metal layer is fabricated by the same method as that of the source electrode, and the third metal layer forms an ohmic contact with the AlGaN epitaxial layer to form the drain electrode.

4、器件的形成4. Device formation

首先,在ZnO纳米带状单晶的外围利用定向刻蚀技术进行刻蚀,在平行与衬底的各金属层上形成具有不同高度的台阶型结构。Firstly, the directional etching technique is used to etch the periphery of the ZnO nanoribbon single crystal to form a stepped structure with different heights on each metal layer parallel to the substrate.

然后,在相应的台阶上淀积Cu或Al形成外电极并连接外引线。Then, deposit Cu or Al on the corresponding steps to form external electrodes and connect external leads.

实例3Example 3

本发明制作基于阵列ZnO纳米柱状单晶的空气隔离垂直型网状AlGaN/GaN微波功率器件。The invention manufactures an air-isolated vertical mesh AlGaN/GaN microwave power device based on arrayed ZnO nano-column single crystals.

外延层材料选用:AlGaN,GaNEpitaxial layer material selection: AlGaN, GaN

垂直单晶材料选用:ZnOVertical single crystal material selection: ZnO

衬底材料选用:n型掺杂的GaN导电材料;Substrate material selection: n-type doped GaN conductive material;

金属材料选用:Au、Ti/Ag、AlMetal material selection: Au, Ti/Ag, Al

介质材料选用:空气Medium material selection: air

参照图5,本实例的结构及制作过程如下:Referring to Figure 5, the structure and production process of this example are as follows:

1、阵列ZnO纳米柱状单晶的生长1. Growth of arrayed ZnO nanocolumnar single crystals

第一步,催化剂模板制作The first step, catalyst template making

首先,在GaN衬底上利用热蒸发法淀积一层Au催化剂薄层;First, a thin layer of Au catalyst is deposited on the GaN substrate by thermal evaporation;

然后,根据器件的分布密度和散热需要设计并制作光刻掩膜板;Then, according to the distribution density and heat dissipation requirements of the device, design and make a photolithography mask;

最后,在Au催化剂层表面覆盖一层光刻胶,进行光刻并且腐蚀掉剩余的光刻胶,留下网状分布的催化剂层。Finally, a layer of photoresist is covered on the surface of the Au catalyst layer, photolithography is carried out and the remaining photoresist is etched away, leaving a network-shaped distribution of the catalyst layer.

第二步,ZnO纳米柱状单晶阵列的生长。所采用的步骤和实例1相同。The second step is the growth of ZnO nano columnar single crystal array. The steps adopted are identical to Example 1.

和实例1不同的是:在最后获得纳米柱状单晶阵列后不用在乙醇中进行超声波降解,保持纳米柱状单晶阵列的完整性。The difference from Example 1 is that no ultrasonic degradation in ethanol is required after the nano-columnar single-crystal array is finally obtained, so as to maintain the integrity of the nano-columnar single-crystal array.

2、GaN及AlGaN材料的外延生长2. Epitaxial growth of GaN and AlGaN materials

GaN及AlGaN材料的外延技术与实例1中采取的技术相同。The epitaxial technology of GaN and AlGaN materials is the same as that adopted in Example 1.

3、第一金属层、第二金属层以及介质层的制作3. Fabrication of the first metal layer, the second metal layer and the dielectric layer

首先,在衬底上淀积一层SiO2形成绝缘层。First, a layer of SiO2 is deposited on the substrate to form an insulating layer.

接着,通过真空和电子束蒸发Au在介质层上制作第一金属层,该第一金属层与AlGaN外延层形成整流接触构成栅极。Next, a first metal layer is formed on the dielectric layer by vacuum and electron beam evaporation of Au, and the first metal layer forms a rectifying contact with the AlGaN epitaxial layer to form a gate.

然后,在平行于衬底的第二金属层上淀积一层SiO2形成绝缘层。Then, deposit a layer of SiO 2 on the second metal layer parallel to the substrate to form an insulating layer.

最后,通过真空和电子束蒸发Al、Ti/Ag介质层上制作第二金属层,该第二金属层与AlGaN外延层形成欧姆接触构成漏极。Finally, a second metal layer is formed on the Al and Ti/Ag dielectric layer by vacuum and electron beam evaporation, and the second metal layer forms an ohmic contact with the AlGaN epitaxial layer to form a drain.

此例中,源极由n型GaN导电衬底与外延层材料形成的欧姆接触构成。In this example, the source electrode is formed by the ohmic contact formed by the n-type GaN conductive substrate and the epitaxial layer material.

在各个金属层制作完毕后,利用选择腐蚀的方法将金属层之间的SiO2介质材料去掉,以形成空气隔离结构。After each metal layer is manufactured, the SiO 2 dielectric material between the metal layers is removed by selective etching to form an air isolation structure.

4、器件的形成4. Device formation

首先,在ZnO纳米柱状单晶阵列边缘的外围利用定向刻蚀技术进行刻蚀,在平行与衬底的各金属层上形成具有不同高度的台阶型结构。First, the periphery of the ZnO nano-columnar single-crystal array is etched by directional etching technology to form stepped structures with different heights on each metal layer parallel to the substrate.

其次,在相应的台阶上淀积Cu或Al形成外电极并连接外引线。Second, deposit Cu or Al on the corresponding steps to form external electrodes and connect external leads.

利用这种方法构造的器件所有ZnO纳米柱状单晶上的器件单元为并联关系,所制得的微波功率器件的总功率为所有ZnO纳米柱状单晶上生长的器件的功率之总和。因此其功率密度为ZnO纳米柱状单晶的密度乘以每个器件的功率。All the device units on the ZnO nano-column single crystal of the device constructed by this method are connected in parallel, and the total power of the prepared microwave power device is the sum of the power of all devices grown on the ZnO nano-column single crystal. Therefore, its power density is the density of ZnO nano-columnar single crystal multiplied by the power of each device.

这种方法构成的微波器件在器件密度和传统平面工艺所制作的微波功率器件相同的情况下,具有更大的表面积,同时由于器件之间通过空气进行隔离,其散热能力将大为提高。The microwave device formed by this method has a larger surface area when the device density is the same as that of the microwave power device produced by the traditional planar process. At the same time, the heat dissipation capacity of the device will be greatly improved because the devices are separated by air.

对于本领域的专业人员来说,在了解了本发明内容和原理后,能够在不背离本发明的原理和范围的情况下,根据本发明的方法进行形式和细节上的各种修正和改变,但是这些基于本发明的修正和改变仍在本发明的权利要求保护范围之内。For those skilled in the art, after understanding the content and principles of the present invention, they can make various amendments and changes in form and details according to the methods of the present invention without departing from the principles and scope of the present invention. But these amendments and changes based on the present invention are still within the protection scope of the claims of the present invention.

Claims (6)

1.一种垂直型宽禁带半导体器件结构,其特征在于采用立体形三维纳米结构,包括衬底、垂直单晶、外延层、金属层、介质层;该垂直单晶与衬底表面垂直,该外延层与垂直单晶平行,该金属层平行于衬底的表面,且至少有一层,该介质层平行于各金属层之间,进行绝缘隔离;金属层与外延层的界面构成欧姆接触或整流接触,并在各金属层上引出外引线。1. A vertical wide bandgap semiconductor device structure is characterized in that a three-dimensional nanostructure is adopted, including a substrate, a vertical single crystal, an epitaxial layer, a metal layer, and a dielectric layer; the vertical single crystal is perpendicular to the substrate surface, The epitaxial layer is parallel to the vertical single crystal, the metal layer is parallel to the surface of the substrate, and there is at least one layer, and the dielectric layer is parallel to each metal layer for insulation isolation; the interface between the metal layer and the epitaxial layer forms an ohmic contact or Rectify the contacts and lead out the outer leads on each metal layer. 2.根据权利要求1所述的半导体器件结构,其特征在于垂直单晶可以采用柱状单晶,也可以带状单晶或其它具有垂直形貌的纳米结构,该垂直单晶的侧面为生长外延层的衬底,依次外延有至少一层的外延层。2. semiconductor device structure according to claim 1, it is characterized in that vertical single crystal can adopt columnar single crystal, also can ribbon single crystal or other have the nanostructure of vertical shape, the side of this vertical single crystal is growth epitaxy layers of the substrate, in turn epitaxially have at least one epitaxial layer. 3.根据权利要求1或2所述的半导体器件结构,其特征在于最外面的外延层的表面自下而上依次形成多层金属层和介质层的交替结构,即第一金属层和第一介质层,第二金属层和第二介质层,第三金属层。3. The semiconductor device structure according to claim 1 or 2, characterized in that the surface of the outermost epitaxial layer forms an alternating structure of multilayer metal layers and dielectric layers sequentially from bottom to top, that is, the first metal layer and the first Dielectric layer, second metal layer and second dielectric layer, third metal layer. 4.根据权利要求1或3所述的半导体器件结构,其特征在于金属层与外延层的界面构成欧姆接触或整流接触是由第一金属层与最外面的外延层组成欧姆接触,形成源极;由第二金属层与最外面的外延层组成整流接触,形成栅极;由第三金属层与最外面的外延层组成欧姆接触,形成漏极。4. The semiconductor device structure according to claim 1 or 3, characterized in that the interface between the metal layer and the epitaxial layer forms an ohmic contact or a rectifying contact is formed by the first metal layer and the outermost epitaxial layer forming an ohmic contact, forming a source ; A rectifying contact is formed by the second metal layer and the outermost epitaxial layer to form a gate; an ohmic contact is formed by the third metal layer and the outermost epitaxial layer to form a drain. 5.根据权利要求1或3所述的半导体器件结构,其特征在于第一金属层可由导电衬底代替,即由导电衬底与最外面的外延层组成欧姆接触,形成源极。5. The semiconductor device structure according to claim 1 or 3, characterized in that the first metal layer can be replaced by a conductive substrate, that is, the conductive substrate and the outermost epitaxial layer form an ohmic contact to form a source. 6.制作权利要求1半导体器件的方法,按如下过程进行:6. make the method for claim 1 semiconductor device, carry out as follows: 第一步,根据器件类型选择衬底材料、垂直单晶材料、外延层材料、金属层材料以及介质材料,并对所选衬底材料进行表面处理,使其具有平整的表面;The first step is to select the substrate material, vertical single crystal material, epitaxial layer material, metal layer material and dielectric material according to the device type, and perform surface treatment on the selected substrate material to make it have a flat surface; 第二步,在经过表面处理的衬底材料上根据器件及电路的需要利用胶体晶体法或光刻掩膜的方法制作催化剂模板;The second step is to make a catalyst template on the surface-treated substrate material according to the needs of the device and the circuit by using the colloidal crystal method or the method of photolithography mask; 第三步,使用垂直单晶材料在衬底材料上利用汽相-液相-固相VLS、汽相-固相VS、液相-固相LS机制生长出垂直单晶纳米结构;The third step is to use vertical single crystal materials to grow vertical single crystal nanostructures on the substrate material by using vapor-liquid-solid VLS, vapor-solid VS, and liquid-solid LS mechanisms; 第四步,使用外延层材料在垂直单晶的表面通过分子束外延MBE或金属有机化学汽相淀积MOCVD外延生长至少一层外延层;The fourth step is to use the epitaxial layer material to epitaxially grow at least one epitaxial layer on the surface of the vertical single crystal by molecular beam epitaxy MBE or metal organic chemical vapor deposition MOCVD; 第五步,使用金属层材料以及介质材料在垂直于外延层的衬底表面通过淀积、腐蚀工艺形成至少一层金属层和介质层,构成器件的欧姆接触或整流接触;The fifth step is to use the metal layer material and the dielectric material to form at least one layer of metal layer and dielectric layer on the substrate surface perpendicular to the epitaxial layer through deposition and corrosion processes to form the ohmic contact or rectifying contact of the device; 第六步,通过定向刻蚀和淀积在平行于衬底材料表面的各金属层上分别引出源极、栅极、漏极的外引线,形成基本的器件单元。In the sixth step, the outer leads of the source, gate and drain are respectively drawn out on each metal layer parallel to the surface of the substrate material by directional etching and deposition to form basic device units.
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