CN1776034A - Medical X-ray developing fiber and its preparing method - Google Patents
Medical X-ray developing fiber and its preparing method Download PDFInfo
- Publication number
- CN1776034A CN1776034A CN 200510032523 CN200510032523A CN1776034A CN 1776034 A CN1776034 A CN 1776034A CN 200510032523 CN200510032523 CN 200510032523 CN 200510032523 A CN200510032523 A CN 200510032523A CN 1776034 A CN1776034 A CN 1776034A
- Authority
- CN
- China
- Prior art keywords
- polypropylene
- medical
- masterbatch
- ray developing
- flexibilizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims abstract description 14
- -1 polypropylene Polymers 0.000 claims abstract description 63
- 239000004743 Polypropylene Substances 0.000 claims abstract description 62
- 229920001155 polypropylene Polymers 0.000 claims abstract description 62
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 44
- 239000012744 reinforcing agent Substances 0.000 claims abstract description 20
- 239000002270 dispersing agent Substances 0.000 claims abstract description 19
- 238000001816 cooling Methods 0.000 claims abstract description 18
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 10
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 238000009987 spinning Methods 0.000 claims abstract description 5
- 238000005520 cutting process Methods 0.000 claims abstract 2
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 44
- 238000004519 manufacturing process Methods 0.000 claims description 27
- 239000000843 powder Substances 0.000 claims description 16
- 229920002943 EPDM rubber Polymers 0.000 claims description 15
- 229920001577 copolymer Polymers 0.000 claims description 15
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 13
- 239000002994 raw material Substances 0.000 claims description 9
- 229920001971 elastomer Polymers 0.000 claims description 8
- 239000005060 rubber Substances 0.000 claims description 8
- 238000009954 braiding Methods 0.000 claims description 6
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 claims description 5
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 5
- 235000013539 calcium stearate Nutrition 0.000 claims description 5
- 239000008116 calcium stearate Substances 0.000 claims description 5
- RINCXYDBBGOEEQ-UHFFFAOYSA-N succinic anhydride Chemical compound O=C1CCC(=O)O1 RINCXYDBBGOEEQ-UHFFFAOYSA-N 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 238000004804 winding Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 238000004040 coloring Methods 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 5
- 229920000915 polyvinyl chloride Polymers 0.000 description 5
- 239000004800 polyvinyl chloride Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 239000012567 medical material Substances 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- VSAWBBYYMBQKIK-UHFFFAOYSA-N 4-[[3,5-bis[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-2,4,6-trimethylphenyl]methyl]-2,6-ditert-butylphenol Chemical compound CC1=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C1CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 VSAWBBYYMBQKIK-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 206010018910 Haemolysis Diseases 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000000641 cold extrusion Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Artificial Filaments (AREA)
Abstract
A medical x ray developing fiber and making method, which contains cross blending and agitating polypropylene, barium sulphate, compatibilizing agent, reinforcing agent, flexibilizer, antioxidant, cooling down agglomerate, coloring agglomerate and dispersant, then melting extruding, cooling and cutting to form agglomerate A which is put into screw extruder to extrude spinning and then wound into silk bobbin by winder, finally worked in hospital gauze. Said invention has advantages of high stretching strength, break down extensibility, washing resisting, folding resisting and high temperature resisting.
Description
Technical field
A kind ofly weave medical fibre material and the manufacture method thereof that gauze is used, belong to field of medical materials.
Background technology
The doctor will check the used gauze quantity of operation at perioperatively, if discrepancy is arranged, then might be retained in gauze in the patient body, at this moment need to confirm, if common cotton gauze, have no idea whether to leave over gauze and gauze position, can only operate on again and in the patient body, search for, bring huge misery to patient and family members in patient's vitro detection.Therefore,, can whether leave over gauze and confirm the particular location of gauze in patient's vitro detection, will bring convenience, shorten operating time, reduce patient's misery to the doctor by certain instrument if try every possible means in gauze to add some composition.The most frequently used means are to add the composition that some can develop in the gauze under the X-ray irradiation, detecting with the shadowgraph instrument, just can confirm the position of gauze.
No. 92216310 patent proposes a kind of interlayer mode, is matrix with rubber, makes film, in the middle of two membranes, fill the barium sulfate powder, make the thin slice that accompanies barium sulfate, embed in the common gauze, development effect is good, shortcoming also clearly because the barium sulfate powder is unfixing, can be slided in thin slice, often omit, can not wash, gauze is too thick simultaneously, lacks folding property.
No. 94216671 patent proposes a kind of " aseptic medical development gauze ", inserts wire in common gauze, makes simply, and shortcoming is exactly that gauze is too hard, can not fold, also easy Piercing Pain patient.
No. 00118923 patent proposes a kind of application pattern, utilize silica gel, barium sulfate, salt compounded of iodine and vulcanizing agent to be coated on the common gauze and form developing fiber by cold extrusion, heat cure, its shortcoming is a poor heat resistance, and gauze is softening easily, volatilization, not washable when high-temperature sterilization, and foldability is also poor.
No. 94247141 patent proposes a kind of " operation development gauze ", forms with common gauze and the development line that contains developer, and the development line is mixed by natural rubber, barium sulfate and iodine and forms, and shortcoming is can not be high temperature resistant, and is softening easily, and gaseous volatilization is arranged.
No. 99116463 patent is improved at the fibrous material of making gauze, is carrier with polyvinyl chloride, and barium sulfate is made developer, through blend, copolymerization, crosslinked improvement, sprays silk then, stretches, draws, is fixed to filament shape product.Shortcoming is that polyvinyl chloride is to contain cl material, residual Vinyl Chloride Monomer is arranged, human body is caused adverse effect, be unfit to do medical material, part country has made laws and has banned use of pvc material to be used for medical and packaging for foodstuff, and China does packaging material for food in September, 2005 with regard to polyvinyl chloride and proposed query.In addition, this polyvinyl chloride wire is thicker, and is not washable, and bad folding, heat-resisting ability is poor.
It is carrier that No. 200510031410 patent application documents propose with polypropylene, fills barium sulfate and prepares the polypropylene developing fiber for medical use, and the product fiber number is very little, and is very soft, inweaves gauze easily.But because prescription is not good enough, therefore, product is more crisp, and fibre strength is lower, and percentage elongation is also lower.
Summary of the invention
The purpose of this invention is to provide a kind of medical X-ray developing fiber and manufacture method thereof, both development effect was good to accomplish hospital gauze with this kind fiber product braiding, and itself is nontoxic, high temperature-resistant disinfected, and washable folding is folded, and very high strength and percentage elongation are arranged again.
The present invention has three kinds of manufacture methods.The production stage of first method is as follows:
1, get the raw materials ready according to following weight proportion:
Polypropylene chip or powder 30～35% barium sulfate 60～68%
Compatilizer 0.5～3% reinforcing agent 0.5～5%
Flexibilizer 0.1～2% antioxidant 0.1～1%
Polypropylene cooling masterbatch 0.1～2% dispersant 0.1～1%
Polypropylene Masterbatch 0～5%
Compatilizer a kind of in maleic anhydride (MAH), succinyl oxide, the EP rubbers preferably wherein; Reinforcing agent is ethylene-octene copolymer (POE); Flexibilizer is ethylene propylene diene rubber (EPDN) or acrylate rubber; The antioxidant model is a kind of in 1010,3114,330 preferably; Dispersant is a kind of in polypropylene wax, barium stearate, the calcium stearate preferably; The color of polypropylene Masterbatch is blue, black, and hyacinthine, orange-yellow etc.
2, above-mentioned raw materials is progressively added in the mixing agitator stir, 59～90 ℃ of whipping temps, mixing time 15-25 minute, melt extrude at 190～250 ℃ through single screw rod or double screw extruder then, be cut into particle, make master batch A;
3, master batch A drops into screw extruder after super-dry, melt extrudes at 190～260 ℃, forms fiber through spinning pack, forms silk tube B with up-coiler under 400～1000 meters/minute winding speed, uses for the hospital gauze braiding.
The production stage of second method is as follows:
1, get the raw materials ready according to following weight ratio:
Polypropylene chip or powder 30～35% barium sulfate 60～68%
Compatilizer 0.5～3% reinforcing agent 0.5～5%
Flexibilizer 0.1～2% antioxidant 0.1～1%
Wet master batch 0.1～2% dispersant 0.1～1% falls in polypropylene
Compatilizer a kind of in maleic anhydride (MAH), succinyl oxide, the EP rubbers preferably wherein; Reinforcing agent is ethylene-octene copolymer (POE); Flexibilizer is ethylene propylene diene rubber (EPDN) or acrylate rubber; The antioxidant model is a kind of in 1010,3114,330 preferably; Dispersant is a kind of in polypropylene wax, barium stearate, the calcium stearate preferably; The color of polypropylene Masterbatch is blue, black, and hyacinthine, orange-yellow etc.
2, above-mentioned raw materials is progressively added in the mixing agitator stir, 59～90 ℃ of whipping temps, mixing time 15-25 minute, melt extrude at 190～250 ℃ through single screw rod or double screw extruder then, be cut into particle, make master batch C;
3, master batch C is after super-dry, the also removal moisture drying of polypropylene Masterbatch of gross weight 0.5～5% will be accounted for, master batch C and Masterbatch are evenly mixed, drop into screw extruder, melt extrude at 190～260 ℃, form fiber through spinning pack, under 400～1000 meters/minute winding speed, form silk tube B, use for the hospital gauze braiding with up-coiler.
The production stage of the third method is as follows:
1, at first will cut into slices polypropylene, polypropylene cooling masterbatch, maleic anhydride, ethylene-octene copolymer, the ethylene propylene diene rubber of shape is ground into powder with pulverizer;
2, get the raw materials ready ratio and the production stage of above-mentioned powder, produce medical X-ray developing fiber silk tube according to first kind of production method.
The present invention compares with existing production technology, and following characteristics are arranged:
1, the present invention is carrier with the polypropylene, for polyvinyl chloride, human body is free from side effects, and no hemolytic reaction belongs to green material.
2, developing fiber of the present invention is that multifilament, filament number are less, smooth and soft, and braiding property is good, anti-high humidity sterilization, and washable folding is folded.
3, because the present invention has used reinforcing agent and flexibilizer, further improved TENSILE STRENGTH, elongation at break and the back processing characteristics of developing fiber, be suitable for extensive continuous and stable production.With the hospital gauze intensity height that its braiding forms, good toughness, development effect is obvious, wash resistant, folded, the anti-high humidity sterilization of folding and nontoxic, and serviceability is good.
The specific embodiment
Embodiment one
Production stage is identical with first method recited above, and the weight proportion of each component is:
Polypropylene powder 32% barium sulfate 62%
Compatilizer maleic anhydride 1% reinforcing agent ethylene-octene copolymer 1%
Flexibilizer ethylene propylene diene rubber 1% antioxidant 1010 0.1%
Polypropylene cooling masterbatch 1% dispersant polypropylene wax 0.1%
Polypropylene Masterbatch 1.8%
Embodiment two
Production stage is identical with example one, and the weight proportion of each component is:
Polypropylene powder 30% barium sulfate 68%
Reinforcing agent ethene one octene copolymer 0.5% compatilizer succinyl oxide 0.5%
Flexibilizer ethylene propylene diene rubber 0.6% antioxidant 3,114 0.2%
Polypropylene cooling masterbatch 0.1% dispersant barium stearate 0.1%
Embodiment three
Production stage is identical with example one, and the weight proportion of each component is:
Polypropylene powder 30% barium sulfate 60%
Compatilizer EP rubbers 3.0% reinforcing agent ethylene-octene copolymer 0.5%
Flexibilizer ACM 2% antioxidant 330 1%
Polypropylene cooling masterbatch 2.0% dispersant calcium stearate 1%
Polypropylene Masterbatch 0.5%
Embodiment four
Production stage is identical with example one, and the weight proportion of each component is:
Polypropylene powder 30% barium sulfate 60%
Compatilizer maleic anhydride 0.5% reinforcing agent ethylene-octene copolymer 4.1%
Flexibilizer ethylene propylene diene rubber 0.1% antioxidant 1010 0.1%
Polypropylene cooling masterbatch 0.1% dispersant polypropylene wax 0.1%
Polypropylene Masterbatch 5.0%
Embodiment five
Production stage is identical with example one, and the weight proportion of each component is:
Polypropylene powder 30% barium sulfate 60%
Compatilizer maleic anhydride 0.5% reinforcing agent ethylene-octene copolymer 5%
Flexibilizer ethylene propylene diene rubber 0.1% antioxidant 1010 0.1%
Polypropylene cooling masterbatch 0.1% dispersant polypropylene wax 0.1%
Polypropylene Masterbatch 4.1%
Embodiment six
Production stage is identical with example one, and the weight proportion of each component is:
Polypropylene powder 35% barium sulfate 60%
Compatilizer maleic anhydride 0.5% reinforcing agent ethylene-octene copolymer 4.1%
Flexibilizer ethylene propylene diene rubber 0.1% antioxidant 1010 0.1%
Polypropylene cooling masterbatch 0.1% dispersant polypropylene wax 0.1%
Embodiment seven
Production stage is identical with second kind of production method recited above, and the weight proportion of each component is:
Polypropylene powder 32% barium sulfate 62%
Compatilizer maleic anhydride 0.8% reinforcing agent ethylene-octene copolymer 0.5%
Flexibilizer ethylene propylene diene rubber 2% antioxidant 1010 0.1%
Polypropylene cooling masterbatch 0.5% dispersant polypropylene wax 0.1%
Polypropylene Masterbatch 2%
Embodiment eight
Production stage is identical with example seven, and the weight proportion of each component is:
Polypropylene powder 31% barium sulfate 60%
Compatilizer succinyl oxide 1.5% reinforcing agent ethylene-octene copolymer 0.5%
Flexibilizer ACM 1% antioxidant 1010 0.1%
Polypropylene cooling masterbatch 0.7% dispersant barium stearate 0.2%
Polypropylene Masterbatch 5%
Embodiment nine
Production stage is identical with example seven, and the weight proportion of each component is:
Polypropylene powder 32% barium sulfate 62%
Compatilizer EP rubbers 1.5% reinforcing agent ethylene-octene copolymer 1.3%
Flexibilizer ethylene propylene diene rubber 1% antioxidant 1010 0.1%
Polypropylene cooling masterbatch 1% dispersant calcium stearate 0.1%
Polypropylene Masterbatch 1%
Embodiment ten
Production stage is identical with the third method recited above, and the weight proportion of each component is:
Polypropylene chip 32% barium sulfate 62%
Compatilizer maleic anhydride 1% reinforcing agent ethylene-octene copolymer 0.8%
Flexibilizer ethylene propylene diene rubber 1% antioxidant 1010 0.1%
Polypropylene cooling masterbatch 1% dispersant polypropylene wax 0.1%
Polypropylene Masterbatch 2%
Claims (7)
1, a kind of medical X-ray developing fiber is characterized in that the weight proportion of each component is:
Polypropylene 30～35% barium sulfate 60～68%
Compatilizer 0.5～3% reinforcing agent 0.5～5%
Flexibilizer 0.1～2% antioxidant 0.1～1%
Polypropylene cooling masterbatch 0.1～2% dispersant 0.1～1%
Polypropylene Masterbatch 0～5%
Wherein reinforcing agent is ethene one octene copolymer, and flexibilizer is ethylene propylene diene rubber or ACM.
2, medical X-ray developing fiber according to claim 1 is characterized in that preferably a kind of in maleic anhydride, succinyl oxide, the EP rubbers of compatilizer.
3, medical X-ray developing fiber according to claim 1 and 2 is characterized in that the antioxidant model is preferably a kind of in 1010,3114,330.
4, medical X-ray developing fiber according to claim 1 and 2 is characterized in that preferably a kind of in polypropylene wax, barium stearate, the calcium stearate of dispersant.
5, a kind of medical X-ray developing fiber manufacture method is characterized in that production stage is as follows:
A, get the raw materials ready according to following weight proportion:
Polypropylene chip or powder 30-35% barium sulfate 60-68%
Compatilizer 0.5～3% reinforcing agent 0.5～5%
Flexibilizer 0.1～2% antioxidant 0.1～1%
Polypropylene cooling masterbatch 0.1～2% dispersant 0.1～1%
Polypropylene Masterbatch 0～5%
B, above-mentioned raw materials progressively added in the mixing agitator stir, 59～90 ℃ of whipping temps, mixing time 15-25 minute, melt extrude at 190～250 ℃ through single screw rod or double screw extruder then, be cut into particle, make master batch A;
C, master batch A drop into screw extruder after super-dry, melt extrude at 190～260 ℃, form fiber through spinning pack, form silk tube B with up-coiler under 400～1000 meters/minute winding speed, use for the braiding hospital gauze.
6, a kind of medical X-ray developing fiber manufacture method according to claim 5, polypropylene, polypropylene cooling masterbatch, maleic anhydride, ethylene-octene copolymer, the ethylene propylene diene rubber of the shape that it is characterized in that at first will cutting into slices are ground into powder with pulverizer.
7, a kind of medical X-ray developing fiber manufacture method is characterized in that production stage is as follows:
A, get the raw materials ready according to following weight proportion
Polypropylene chip or powder 30～35% barium sulfate 60～68%
Compatilizer 0.5～3% reinforcing agent 0.5～5%
Flexibilizer 0.1～2%, antioxidant 0.1～1%
Polypropylene cooling masterbatch 0.1～2% dispersant 0.1～1%
B, above-mentioned raw material are progressively added in the mixing agitator stir, 59～90 ℃ of whipping temps, mixing time 15～25 minutes melt extrudes at 190～250 ℃ through single screw rod or double screw extruder then and is cut into particle, makes master batch C;
C, master batch C are through after the removal moisture drying, the also removal moisture drying of polypropylene Masterbatch of gross weight 0.5～5% will be accounted for, master batch C and Masterbatch are evenly mixed, drop into screw extruder, melt extrude at 190～260 ℃, form fiber through spinning pack, under 400～1000 meters/minute winding speed, form silk tube B with up-coiler.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510032523 CN1776034A (en) | 2005-12-06 | 2005-12-06 | Medical X-ray developing fiber and its preparing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510032523 CN1776034A (en) | 2005-12-06 | 2005-12-06 | Medical X-ray developing fiber and its preparing method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1776034A true CN1776034A (en) | 2006-05-24 |
Family
ID=36765743
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200510032523 Pending CN1776034A (en) | 2005-12-06 | 2005-12-06 | Medical X-ray developing fiber and its preparing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1776034A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009059457A1 (en) * | 2007-11-07 | 2009-05-14 | U-Bond Inc. | Functional fiber, preparation method thereof and fabric made of it |
| WO2009067840A1 (en) * | 2007-11-27 | 2009-06-04 | U-Bond Inc. | Imitating natural plant fiber, preparation method thereof and fabric made of it |
| CN101701095B (en) * | 2009-11-24 | 2011-06-15 | 王崇高 | Folding-resisting antibacterial resin |
| CN103948968A (en) * | 2014-05-13 | 2014-07-30 | 天津德岩科技有限公司 | In-vivo implanted composite material with X-ray developing performance and preparation method of in-vivo implanted composite material |
| CN104562262A (en) * | 2015-02-02 | 2015-04-29 | 苏州爱立方服饰有限公司 | Antistatic textile fiber material and preparation method thereof |
| CN104814555A (en) * | 2015-05-21 | 2015-08-05 | 南通美铭锦纶有限公司 | X-ray absorption compound fabric |
| CN105086134A (en) * | 2015-06-12 | 2015-11-25 | 福路明精密管材（北京）有限公司 | Medical macromolecular material and preparation method therefor |
| CN105903061A (en) * | 2016-05-25 | 2016-08-31 | 青岛明月生物医用材料有限公司 | Production technology of self-adhesion X-ray medical developing line and medical gauze |
| CN111388685A (en) * | 2020-03-27 | 2020-07-10 | 苏州欣影生物医药技术有限公司 | Fluorescent and X-ray dual-function developing material, preparation method and application |
-
2005
- 2005-12-06 CN CN 200510032523 patent/CN1776034A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009059457A1 (en) * | 2007-11-07 | 2009-05-14 | U-Bond Inc. | Functional fiber, preparation method thereof and fabric made of it |
| WO2009067840A1 (en) * | 2007-11-27 | 2009-06-04 | U-Bond Inc. | Imitating natural plant fiber, preparation method thereof and fabric made of it |
| EA017657B1 (en) * | 2007-11-27 | 2013-02-28 | Новеко Трейдинг 2008 Ллк | Imitating natural plant fiber, preparation method thereof and fabric made of it |
| AU2007361791B2 (en) * | 2007-11-27 | 2013-03-21 | Noveko Trading 2008 Llc | Imitating natural plant fiber, preparation method thereof and fabric made of it |
| CN101701095B (en) * | 2009-11-24 | 2011-06-15 | 王崇高 | Folding-resisting antibacterial resin |
| CN103948968A (en) * | 2014-05-13 | 2014-07-30 | 天津德岩科技有限公司 | In-vivo implanted composite material with X-ray developing performance and preparation method of in-vivo implanted composite material |
| CN103948968B (en) * | 2014-05-13 | 2019-02-19 | 天津德岩科技有限公司 | Et al. Ke composite material and preparation method with X-ray developing performance |
| CN104562262A (en) * | 2015-02-02 | 2015-04-29 | 苏州爱立方服饰有限公司 | Antistatic textile fiber material and preparation method thereof |
| CN104814555A (en) * | 2015-05-21 | 2015-08-05 | 南通美铭锦纶有限公司 | X-ray absorption compound fabric |
| CN105086134A (en) * | 2015-06-12 | 2015-11-25 | 福路明精密管材（北京）有限公司 | Medical macromolecular material and preparation method therefor |
| CN105903061A (en) * | 2016-05-25 | 2016-08-31 | 青岛明月生物医用材料有限公司 | Production technology of self-adhesion X-ray medical developing line and medical gauze |
| CN111388685A (en) * | 2020-03-27 | 2020-07-10 | 苏州欣影生物医药技术有限公司 | Fluorescent and X-ray dual-function developing material, preparation method and application |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1014794B (en) | Air-permeable membrane and method for manufacturing the same | |
| CN1073130C (en) | Polyolefin compositions having good transparency and impact resistance | |
| CN1776034A (en) | Medical X-ray developing fiber and its preparing method | |
| CN1223712C (en) | Polyester fiber and method for producing polyester composition | |
| CN109796734A (en) | A kind of polylactic acid biodegradable composite material | |
| CN109608762B (en) | Syndiotactic polypropylene composition for 3D printing, syndiotactic polypropylene composite material and preparation method thereof | |
| CN85105362A (en) | Surgical thread made of vinylidene fluoride copolymer | |
| CN115340724B (en) | Starch-based antibacterial material and preparation method thereof | |
| CN1136425A (en) | Porous sheet and absorbent article using same | |
| CN105970336A (en) | Fishery trawling and pursing polyester monofilament manufacturing method | |
| CN1008750B (en) | The production method of high-strength polyethylene netting twine | |
| CN1687495A (en) | Developing fiber for medical use and preparation method thereof | |
| CN1268792C (en) | High-efficient conductive fibre and preparing method thereof | |
| CN113214615A (en) | Ternary complete biodegradable film and preparation method thereof | |
| CN1730739A (en) | Preparation method of ultraviolet resistant, quick moisture absorption dry polyester fiber | |
| CN111979599A (en) | A kind of preparation method of barium-containing developable functional polypropylene fiber | |
| CN1887364A (en) | Biodegradable medical extracorporeal fixing material possessing shape memory function | |
| CN1546567A (en) | Flame-retardant, smoke-absorbing polycarbonate alloy | |
| CN102775694A (en) | Transparent toughened polyvinyl chloride composition and its preparation method | |
| CN110237784A (en) | Lignin micro-/ nano ball, enhancing polylactic acid 3D printing material and preparation method thereof | |
| CN108676348A (en) | A kind of preparation method and applications of pulp cavity glue 3D printing composite material | |
| CN1025788C (en) | Method for preparing polyvinyl chloride plasticizer from animal and vegetable oil | |
| CN110592721A (en) | Composite fiber of colored polylactic acid and glycolide-trimethylene carbonate copolymer and preparation method thereof | |
| CN1796452A (en) | Composition of emulational plastic and preparation method | |
| CN100336950C (en) | Polyvinyl chloride fiber, method for producing the polyvinyl chloride fiber and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| AD01 | Patent right deemed abandoned | ||
| C20 | Patent right or utility model deemed to be abandoned or is abandoned |