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CN1674261A - Manufacturing method of flash memory - Google Patents

Manufacturing method of flash memory Download PDF

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Publication number
CN1674261A
CN1674261A CN 200410031578 CN200410031578A CN1674261A CN 1674261 A CN1674261 A CN 1674261A CN 200410031578 CN200410031578 CN 200410031578 CN 200410031578 A CN200410031578 A CN 200410031578A CN 1674261 A CN1674261 A CN 1674261A
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dielectric layer
substrate
manufacture method
mask
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CN1309055C (en
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王进忠
杜建志
毕嘉慧
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Powerchip Semiconductor Corp
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Abstract

A method for manufacturing flash memory includes providing substrate including multiple element isolation structures to define active region, forming tunnel dielectric layer and mask layer on substrate of active region in sequence. Then, a portion of each of the device isolation structures is removed to form a plurality of trenches. Then, a dielectric layer is formed on the substrate to cover the mask layer and the surfaces of the trenches. Then, after filling the sacrificial layer into the trenches, the sacrificial layer is used as a self-aligned mask to remove a portion of the dielectric layer. Then, the mask layer is removed to expose the tunneling dielectric layer. Then, a conductor layer is formed on the substrate. Then, part of the conductor layer is removed until the top of the sacrificial layer is exposed. Then, after removing the sacrificial layer, an inter-gate dielectric layer is formed on the substrate. Then, after forming a control gate on the inter-gate dielectric layer, a source region and a drain region are formed in the substrate at two sides of the control gate.

Description

闪速存储器的制造方法Manufacturing method of flash memory

技术领域technical field

本发明涉及一种存储元件的制造方法,且特别是涉及一种闪速存储器及浮置栅极的制造方法。The present invention relates to a manufacturing method of a memory element, and in particular to a manufacturing method of a flash memory and a floating gate.

背景技术Background technique

闪速存储器是一种可电除且可程序化的只读存储器(Electrically ErasableProgrammable Read-Only Memory,EEPROM),其具有可写入、可抹除以及断电后仍可保存数据的优点,因此是个人计算机和电子设备所广泛采用的一种存储元件。此外,闪速存储器为一种非挥发性存储(Non-Volatile Memory,NVM)元件,其具有非挥发性存储体积小、存取速度快及耗电量低的优点,且因其数据抹除(Erasing)时采用「一块一块」(Block by Block)抹除的方式,所以更具有操作速度快的优点。Flash memory is a kind of electrically erasable and programmable read-only memory (Electrically Erasable Programmable Read-Only Memory, EEPROM), which has the advantages of being writable, erasable, and can still save data after power failure, so it is A memory element widely used in personal computers and electronic equipment. In addition, flash memory is a non-volatile memory (Non-Volatile Memory, NVM) component, which has the advantages of small non-volatile memory, fast access speed and low power consumption, and because of its data erasure ( Erasing) adopts the "block by block" (Block by Block) erasing method, so it has the advantage of fast operation speed.

典型的闪速存储器元件以掺杂的多晶硅制作浮置栅极(Floating Gate)与控制栅极(Control Gate)。而且,控制栅极直接设置在浮置栅极上,浮置栅极与控制栅极之间以介电层相隔,而浮置栅极与衬底间以穿隧氧化层(Tunneling Oxide)相隔(亦即所谓堆栈栅极闪速存储器)。此闪速存储器元件是利用控制栅极上所施加的正或负电压来控制浮置栅极中的电荷的注入与排出,以达到存储的功能。A typical flash memory device uses doped polysilicon to make a floating gate (Floating Gate) and a control gate (Control Gate). Moreover, the control gate is directly arranged on the floating gate, the floating gate and the control gate are separated by a dielectric layer, and the floating gate and the substrate are separated by a tunneling oxide (Tunneling Oxide) ( Also known as stacked gate flash memory). The flash memory device utilizes the positive or negative voltage applied on the control gate to control the injection and discharge of charges in the floating gate to achieve the storage function.

图1A至图1C所绘示为现有一种闪速存储器元件的部分制造流程剖面示意图。FIG. 1A to FIG. 1C are schematic cross-sectional views showing part of the manufacturing process of a conventional flash memory device.

请参照图1A,提供衬底100,且在衬底100中已形成有多个元件隔离结构102以定义出元件的有源区104,而且在有源区104的衬底100上已形成有穿隧介电层106。Referring to FIG. 1A, a substrate 100 is provided, and a plurality of element isolation structures 102 have been formed in the substrate 100 to define an active region 104 of the element, and a penetrating structure has been formed on the substrate 100 of the active region 104. tunnel dielectric layer 106 .

然后,于衬底100上形成一层导体层108,以覆盖元件隔离结构102与穿隧介电层106。接着,进行平坦化工艺,移除部分的导体层108,并且使得导体层108的顶部表面平坦。Then, a conductive layer 108 is formed on the substrate 100 to cover the device isolation structure 102 and the tunneling dielectric layer 106 . Next, a planarization process is performed to remove part of the conductive layer 108 and make the top surface of the conductive layer 108 flat.

接着,请参照图1B,于导体层108上形成图案化的掩膜层109,此图案光的掩膜层109暴露元件隔离结构102上的部分导体层108。然后,以图案化的掩膜层109为掩模,移除部分导体层108,而于元件隔离结构102上的导体层108中形成多个沟槽107,且所保留下来的导体层108为浮置栅极110。Next, please refer to FIG. 1B , a patterned mask layer 109 is formed on the conductive layer 108 , and the patterned mask layer 109 exposes part of the conductive layer 108 on the device isolation structure 102 . Then, using the patterned mask layer 109 as a mask, part of the conductor layer 108 is removed, and a plurality of trenches 107 are formed in the conductor layer 108 on the device isolation structure 102, and the remaining conductor layer 108 is a floating Set gate 110.

然后,请参照图1C,在移除图案化的掩膜层109后,于衬底100上形成栅极间介电层112,以覆盖浮置栅极110。接着,于栅极间介电层112上形成控制栅极114。Then, referring to FIG. 1C , after removing the patterned mask layer 109 , an inter-gate dielectric layer 112 is formed on the substrate 100 to cover the floating gate 110 . Next, a control gate 114 is formed on the inter-gate dielectric layer 112 .

在上述工艺中,浮置栅极110利用微影蚀刻工艺以形成之。然而,由于此微影蚀刻工艺需依序进行去水烘烤、涂底、上掩膜、前烘、曝光、曝光后烘烤、显影、坚膜以及蚀刻等等步骤。因此不但耗费时间,而且还会增加许多工艺成本。In the above process, the floating gate 110 is formed by a lithographic etching process. However, the lithographic etching process needs to perform dehydration baking, priming, masking, pre-baking, exposure, post-exposure baking, development, hardening, and etching in sequence. Therefore, it is not only time-consuming, but also increases a lot of process costs.

另外,在上述工艺中,由于利用化学机械研磨法(Chemical MechanicalPolishing,CMP)来平坦化导体层108,而在进行化学机械研磨的过程中并无终止层作为研磨终止的参考依据。因此,每次工艺所保留下来的导体层108的厚度不一,即浮置栅极110的厚度无法获得有效地控制。In addition, in the above process, since the conductive layer 108 is planarized by chemical mechanical polishing (CMP), there is no termination layer as a reference for polishing termination during the chemical mechanical polishing process. Therefore, the thickness of the conductor layer 108 remaining in each process is different, that is, the thickness of the floating gate 110 cannot be effectively controlled.

另一方面,若浮置栅极与控制栅极之间的栅极耦合率(Gate Couple Ratio,GCR)越大,则其操作所需的工作电压将越低。而提高栅极耦合率的方法包括增加栅极间介电层的电容或减少穿遂氧化层的电容。其中,增加栅极间介电层电容的方法为增加控制栅极层与浮置栅极之间所夹的面积。因此,若所形成的沟槽107的尺寸越小,则浮置栅极与控制栅极之间所夹的面积会越大,栅极耦合率越大。然而,在图案化导体层108的过程中,沟槽107的尺寸受到微影蚀刻工艺其对于微小尺寸的工艺限制,即无法形成更微小的沟槽107。因此使得控制栅极与浮置栅极之间所夹的面积无法更进一步增加,进而影响元件的效能。On the other hand, if the gate coupling ratio (Gate Couple Ratio, GCR) between the floating gate and the control gate is larger, the operating voltage required for its operation will be lower. The method for improving the gate coupling ratio includes increasing the capacitance of the inter-gate dielectric layer or reducing the capacitance of the tunnel oxide layer. Wherein, the method for increasing the capacitance of the inter-gate dielectric layer is to increase the area between the control gate layer and the floating gate. Therefore, if the size of the formed trench 107 is smaller, the area between the floating gate and the control gate will be larger, and the gate coupling ratio will be larger. However, in the process of patterning the conductive layer 108 , the size of the trench 107 is limited by the lithographic etching process for a tiny size, that is, it is impossible to form a finer trench 107 . Therefore, the area between the control gate and the floating gate cannot be further increased, thereby affecting the performance of the device.

发明内容Contents of the invention

有鉴于此,本发明的目的就是在提供一种闪速存储器的制造方法,可以解决现有浮置栅极的厚度不易控制的问题,还可以增加浮置栅极与控制栅极之间的栅极耦合率,进而提升元件效能。In view of this, the object of the present invention is to provide a method for manufacturing a flash memory, which can solve the problem that the thickness of the existing floating gate is not easy to control, and can also increase the gate thickness between the floating gate and the control gate. Polar coupling rate, thereby improving device performance.

本发明的再一目的是提供一种浮置栅极的制造方法,以省去用于制作浮置栅极的掩模,即可以减少一道微影蚀刻工艺,因此可以简化工艺。Another object of the present invention is to provide a method for manufacturing a floating gate, so as to omit the mask used for manufacturing the floating gate, that is, reduce one lithographic etching process, and thus simplify the process.

本发明提出一种闪速存储器的制造方法,此方法先提供衬底,此衬底上已依序形成有穿隧介电层、第一导体层、垫氧化层与图案化的掩模层。之后,以图案化的掩模层为掩模,移除部分的垫氧化层、第一导体层、穿隧介电层与衬底,以于衬底中形成多个第一沟槽。然后,于这些第一沟槽内填入绝缘材料,以形成多个元件隔离结构。接着,移除每一个元件隔离结构的一部分,以形成多个第二沟槽,且所保留下来的每一个元件隔离结构的顶部介于穿隧介电层与掩模层之间。继之,于衬底上形成介电层,以覆盖掩模层与这些第二沟槽的表面。之后,于这些第二沟槽内填入牺牲层,其中牺牲层与介电层的材质具有不同的蚀刻选择性。然后,以此牺牲层为自行对准掩模,移除部分介电层。接着,移除掩模层,以暴露出垫氧化层。继之,移除垫氧化层,以暴露出第一导体层。之后,于衬底上形成第二导体层。继之,移除部分的第二导体层直到暴露出牺牲层的顶部,且第二导体层与第一导体层构成浮置栅极,其中移除部分的第二导体层直到暴露出牺牲层的顶部的方法可为化学机械研磨法,且第二导体层与牺牲层的材质具有不同的蚀刻选择性。然后,移除牺牲层。接着,于衬底上形成栅极间介电层,以覆盖浮置栅极。继之,于栅极间介电层上形成控制栅极。之后,于控制栅极两侧的衬底中分别形成源极区与漏极区。The invention proposes a method for manufacturing a flash memory. The method firstly provides a substrate on which a tunnel dielectric layer, a first conductor layer, a pad oxide layer and a patterned mask layer have been sequentially formed. Afterwards, using the patterned mask layer as a mask, part of the pad oxide layer, the first conductor layer, the tunnel dielectric layer and the substrate are removed to form a plurality of first trenches in the substrate. Then, insulating material is filled into the first trenches to form a plurality of device isolation structures. Next, a part of each element isolation structure is removed to form a plurality of second trenches, and the remaining top of each element isolation structure is interposed between the tunneling dielectric layer and the mask layer. Then, a dielectric layer is formed on the substrate to cover the mask layer and the surfaces of the second grooves. Afterwards, a sacrificial layer is filled in the second trenches, wherein the materials of the sacrificial layer and the dielectric layer have different etching selectivities. Then, using the sacrificial layer as a self-alignment mask, part of the dielectric layer is removed. Next, the mask layer is removed to expose the pad oxide layer. Then, the pad oxide layer is removed to expose the first conductive layer. Afterwards, a second conductor layer is formed on the substrate. Next, part of the second conductor layer is removed until the top of the sacrificial layer is exposed, and the second conductor layer and the first conductor layer form a floating gate, wherein part of the second conductor layer is removed until the top of the sacrificial layer is exposed. The top method can be a chemical mechanical polishing method, and the materials of the second conductive layer and the sacrificial layer have different etching selectivities. Then, the sacrificial layer is removed. Next, an inter-gate dielectric layer is formed on the substrate to cover the floating gate. Then, a control gate is formed on the inter-gate dielectric layer. Afterwards, a source region and a drain region are respectively formed in the substrate on both sides of the control gate.

由于本发明在形成浮置栅极的过程中,先于元件隔离结构上形成第二沟槽,然后再依序于第二沟槽中填入介电层与牺牲层,并且藉由此介电层与此牺牲层所构成的堆栈结构来形成浮置栅极。因此利用本发明的方法可以省去制作浮置栅极的掩模,即可以减少一道微影蚀刻工艺,进而节省工艺成本。Because in the process of forming the floating gate in the present invention, the second trench is formed on the element isolation structure first, and then the dielectric layer and the sacrificial layer are filled in the second trench in sequence, and by this dielectric layer and the sacrificial layer to form a floating gate. Therefore, by using the method of the present invention, the mask for making the floating gate can be omitted, that is, one lithographic etching process can be reduced, thereby saving the process cost.

另外,由于本发明所形成的浮置栅极其厚度与所形成的介电层与牺牲层的总高度有关,因此浮置栅极的厚度可藉由所形成的介电层与牺牲层的总高度来决定,于是浮置栅极的厚度可以获得较好地控制。In addition, since the thickness of the floating gate formed in the present invention is related to the total height of the formed dielectric layer and the sacrificial layer, the thickness of the floating gate can be determined by the total height of the formed dielectric layer and the sacrificial layer. To decide, so the thickness of the floating gate can be better controlled.

此外,由于本发明可以藉由形成厚度较厚的介电层,以缩小第二沟槽的尺寸,进而形成尺寸较大的浮置栅极。因此控制栅极与浮置栅极之间所夹的面积可以提升,进而提升栅极耦合率。In addition, because the present invention can reduce the size of the second trench by forming a thicker dielectric layer, thereby forming a larger floating gate. Therefore, the area between the control gate and the floating gate can be increased, thereby increasing the gate coupling rate.

本发明提出一种浮置栅极的制造方法,此方法先提供衬底,此衬底包括有多个元件隔离结构以定义出有源区,且此有源区的衬底上依序形成有穿隧介电层与掩模层。然后,移除每一个元件隔离结构的一部分,以形成多个沟槽,且所保留下来的元件隔离结构的顶部介于穿隧介电层与掩模层之间。接着,于衬底上形成介电层,以覆盖掩模层与这些沟槽的表面。之后,于这些沟槽内填入牺牲层,其中牺牲层与介电层的材质具有不同的蚀刻选择性。继之,以牺牲层为自行对准掩模,移除部分的介电层。然后,移除掩模层,以暴露出穿隧介电层。接着,于衬底上形成导体层。继之,移除部分的导体层直到暴露出牺牲层的顶部,其中移除部分的导体层直到暴露出牺牲层的顶部的方法可为化学机械研磨法,且导体层与牺牲层的材质具有不同的蚀刻选择性。之后,移除牺牲层。The present invention proposes a method for manufacturing a floating gate. In this method, a substrate is firstly provided, and the substrate includes a plurality of device isolation structures to define an active region, and the substrate of the active region is sequentially formed with tunneling dielectric layer and mask layer. Then, a part of each element isolation structure is removed to form a plurality of trenches, and the tops of the remaining element isolation structures are interposed between the tunneling dielectric layer and the mask layer. Then, a dielectric layer is formed on the substrate to cover the mask layer and the surfaces of the grooves. Afterwards, a sacrificial layer is filled in the trenches, wherein the materials of the sacrificial layer and the dielectric layer have different etching selectivities. Then, using the sacrificial layer as a self-alignment mask, part of the dielectric layer is removed. Then, the mask layer is removed to expose the tunnel dielectric layer. Next, a conductor layer is formed on the substrate. Then, remove part of the conductive layer until the top of the sacrificial layer is exposed, wherein the method of removing part of the conductive layer until the top of the sacrificial layer is exposed can be a chemical mechanical polishing method, and the materials of the conductive layer and the sacrificial layer are different. etch selectivity. Afterwards, the sacrificial layer is removed.

由于本发明的形成浮置栅极的制造方法,先于元件隔离结构上形成沟槽,然后再依序于沟槽中填入介电层与牺牲层,并且藉由此介电层与此牺牲层所构成的堆栈结构来形成浮置栅极。因此利用本发明的方法可以省去用于制作浮置栅极的掩模,即可以减少一道微影蚀刻工艺,进而节省工艺成本。Due to the manufacturing method for forming the floating gate of the present invention, the trench is formed on the device isolation structure first, and then the dielectric layer and the sacrificial layer are filled in the trench sequentially, and the dielectric layer and the sacrificial layer are connected to each other. Layers are stacked to form a floating gate. Therefore, using the method of the present invention can save the mask used for making the floating gate, that is, can reduce a lithographic etching process, thereby saving the process cost.

此外,由于本发明所形成的浮置栅极其厚度与所形成的介电层与牺牲层的总高度有关,因此浮置栅极的厚度可藉由所形成的介电层与牺牲层的总高度来决定,于是浮置栅极的厚度可以获得较好地控制。In addition, since the thickness of the floating gate formed in the present invention is related to the total height of the formed dielectric layer and the sacrificial layer, the thickness of the floating gate can be determined by the total height of the formed dielectric layer and the sacrificial layer. To decide, so the thickness of the floating gate can be better controlled.

为让本发明的上述和其它目的、特征、和优点能更明显易懂,下文特举优选实施例,并配合附图,作详细说明如下。In order to make the above and other objects, features, and advantages of the present invention more comprehensible, preferred embodiments are described below in detail with accompanying drawings.

附图说明Description of drawings

图1A至图1C所绘示为现有一种闪速存储器的制造流程剖面示意图;FIG. 1A to FIG. 1C are schematic cross-sectional schematic diagrams illustrating a manufacturing process of a conventional flash memory;

图2A至图2F所绘示为本发明优选实施例的一种闪速存储器的制造流程剖面示意图。2A to 2F are schematic cross-sectional views showing a manufacturing process of a flash memory according to a preferred embodiment of the present invention.

附图标记说明Explanation of reference signs

100、200:衬底100, 200: Substrate

102、214、214a:元件隔离结构102, 214, 214a: Component isolation structure

104、204:有源区104, 204: active area

106、206、206a:穿隧介电层106, 206, 206a: tunneling dielectric layer

107、212、215:沟槽107, 212, 215: Groove

108、208、208a、220、220a:导体层108, 208, 208a, 220, 220a: conductor layer

109:掩膜层109: mask layer

110、221:浮置栅极110, 221: floating gate

112、222:栅极间介电层112, 222: inter-gate dielectric layer

114、224:控制栅极114, 224: control grid

202:开口202: opening

209、209a:垫氧化层209, 209a: pad oxide layer

210:掩模层210: mask layer

216、216a:介电层216, 216a: dielectric layer

217:牺牲堆栈层217: Sacrificial stack layer

218:牺牲层218: Sacrificial layer

W1、W2、W3、W4:宽度W1, W2, W3, W4: Width

具体实施方式Detailed ways

图2A至图2F所示,其绘示依照本发明一优选实施例的一种闪速存储器的制造流程剖面示意图。FIG. 2A to FIG. 2F are schematic cross-sectional views illustrating a manufacturing process of a flash memory according to a preferred embodiment of the present invention.

首先,请参照图2A,提供衬底200,此衬底200例如是硅衬底。然后,在此衬底200上依序形成穿隧介电层206、导体层208、垫氧化层209与图案化的掩模层210,且图案化的掩模层210具有开口202,此开口202暴露后续预定形成元件隔离结构的区域。First, please refer to FIG. 2A , a substrate 200 is provided, such as a silicon substrate. Then, a tunneling dielectric layer 206, a conductor layer 208, a pad oxide layer 209, and a patterned mask layer 210 are sequentially formed on the substrate 200, and the patterned mask layer 210 has an opening 202, and the opening 202 A region to be subsequently formed with an element isolation structure is exposed.

其中,穿隧介电层206的材质例如是氧化硅,其形成方法例如是热氧化法,而所形成的厚度例如是70埃至90埃。导体层208的材质例如是掺杂多晶硅,其形成方法例如是利用化学气相沉积法形成一层未掺杂多晶硅层(未绘示)后,进行离子注入步骤以形成之,而所形成的厚度例如是500埃至1000埃。另外,垫氧化层209的材质例如是氧化硅,其形成方法例如是热氧化法,而所形成的厚度例如是15埃至50埃。此外,掩模层210的材质包括与垫氧化层209、导体层208、穿隧介电层206及衬底200具有不同蚀刻选择性的材质,其例如是氮化硅,且其厚度例如是1500埃至2000埃。图案化掩模层210的方法例如是微影蚀刻技术。Wherein, the material of the tunneling dielectric layer 206 is, for example, silicon oxide, and its formation method is, for example, thermal oxidation, and the formed thickness is, for example, 70 angstroms to 90 angstroms. The material of the conductive layer 208 is, for example, doped polysilicon, and its formation method is, for example, to form an undoped polysilicon layer (not shown) by chemical vapor deposition, and then perform ion implantation to form it. The formed thickness is, for example, is 500 angstroms to 1000 angstroms. In addition, the material of the pad oxide layer 209 is, for example, silicon oxide, and its formation method is, for example, thermal oxidation, and the formed thickness is, for example, 15 angstroms to 50 angstroms. In addition, the material of the mask layer 210 includes a material having a different etching selectivity from the pad oxide layer 209, the conductive layer 208, the tunnel dielectric layer 206, and the substrate 200, such as silicon nitride, and its thickness is, for example, 1500 Angstroms to 2000 Angstroms. The method of patterning the mask layer 210 is, for example, photolithography.

之后,请参照图2B,以图案化的掩模层210为蚀刻掩模,移除部分的垫氧化层209、导体层208、穿隧介电层206,并于衬底200中形成多个沟槽212,而于衬底200上留下穿隧介电层206a、导体层208a与垫氧化层209a。其中,所形成的沟槽212的深度例如是3000埃至4000埃。Afterwards, referring to FIG. 2B , using the patterned mask layer 210 as an etching mask, part of the pad oxide layer 209 , the conductive layer 208 , and the tunneling dielectric layer 206 are removed, and a plurality of trenches are formed in the substrate 200 The trench 212 is formed, leaving the tunnel dielectric layer 206 a , the conductive layer 208 a and the pad oxide layer 209 a on the substrate 200 . Wherein, the depth of the formed trench 212 is, for example, 3000 angstroms to 4000 angstroms.

然后,于沟槽212中填入绝缘材料,以形成多个元件隔离结构214,并定义出有源区204。元件隔离结构214的形成方法例如是利用高密度等离子化学气相沉积法(High Density Plasma Chemical Vapor Deposition,HDP-CVD),形成一整层绝缘材料层(未绘示)后,再利用化学机械研磨法移除沟槽212以外的绝缘材料层以形成之。Then, an insulating material is filled in the trenches 212 to form a plurality of device isolation structures 214 and define the active region 204 . The method for forming the device isolation structure 214 is, for example, to use high density plasma chemical vapor deposition (High Density Plasma Chemical Vapor Deposition, HDP-CVD) to form a whole layer of insulating material (not shown), and then use chemical mechanical polishing The layer of insulating material outside the trench 212 is removed to form it.

值得注意的是,在上述的步骤中先形成穿隧介电层206,再进行形成元件隔离结构214等相关步骤。因此可以避免因先形成元件隔离结构214,而于后续进行热工艺以形成穿隧介电层206的过程中,造成在邻近元件隔离结构214处形成鸟嘴(Bird’s Beak),进而影响元件效能的问题。It should be noted that in the above steps, the tunneling dielectric layer 206 is formed first, and then related steps such as forming the device isolation structure 214 are performed. Therefore, it can be avoided that due to the formation of the element isolation structure 214 first, in the subsequent thermal process to form the tunnel dielectric layer 206, a bird's beak (Bird's Beak) will be formed adjacent to the element isolation structure 214, thereby affecting the performance of the element. question.

接着,请参照图2C,移除每一个元件隔离结构214中的部分绝缘材料,以形成多个沟槽215,且所保留下来的元件隔离结构214a的顶部介于穿隧介电层206a与掩模层210之间。其中,移除元件隔离结构214的部分绝缘材料,以形成多个沟槽215的方法包括利用干蚀刻所进行的回蚀刻法。Next, referring to FIG. 2C , part of the insulating material in each element isolation structure 214 is removed to form a plurality of trenches 215 , and the top of the remaining element isolation structure 214 a is between the tunneling dielectric layer 206 a and the mask. between the mold layers 210 . Wherein, the method of removing part of the insulating material of the device isolation structure 214 to form the plurality of trenches 215 includes an etch-back method performed by dry etching.

继之,于衬底200上形成介电层216,以覆盖掩模层210与沟槽215的表面。其中,介电层216的材质包括与后续所形成的导体层的材质具有不同蚀刻选择性的材料,其例如是氮化硅。介电层216的形成方法例如是化学气相沉积法,而所形成的厚度例如是200埃至1000埃。此外,在本实施例中,介电层216与掩模层210的材质例如是相同。Next, a dielectric layer 216 is formed on the substrate 200 to cover the surface of the mask layer 210 and the trench 215 . Wherein, the material of the dielectric layer 216 includes a material having a different etch selectivity from the material of the subsequently formed conductor layer, such as silicon nitride. The dielectric layer 216 is formed by, for example, chemical vapor deposition, and the formed thickness is, for example, 200 angstroms to 1000 angstroms. In addition, in this embodiment, the materials of the dielectric layer 216 and the mask layer 210 are, for example, the same.

之后,于沟槽215内填入牺牲层218,且此牺牲层218填满沟槽215。其中,牺牲层218的材质包括与后续所形成的导体层的材质具有不同蚀刻选择性的材料,其例如是氧化硅。牺牲层218的形成方法例如是于衬底200上形成一整层牺牲材料层(未绘示)后,再利用化学机械研磨法或是回蚀刻法移除沟槽215以外的牺牲材料层以形成之。另外,在又一优选实施例中,牺牲层218的形成方法例如是利用旋转涂布法(Spin Coating)将一整层旋涂式玻璃(Spin-On Glass,SOG)涂布于衬底200上,以形成牺牲材料层(未绘示)后,再利用回蚀刻法移除沟槽215以外的牺牲材料层以形成之。Afterwards, a sacrificial layer 218 is filled in the trench 215 , and the sacrificial layer 218 fills the trench 215 . Wherein, the material of the sacrificial layer 218 includes a material having a different etch selectivity from the material of the subsequently formed conductor layer, such as silicon oxide. The sacrificial layer 218 is formed by, for example, forming a whole layer of sacrificial material layer (not shown) on the substrate 200, and then removing the sacrificial material layer outside the trench 215 by chemical mechanical polishing or etching back to form Of. In addition, in another preferred embodiment, the formation method of the sacrificial layer 218 is, for example, coating a whole layer of spin-on glass (Spin-On Glass, SOG) on the substrate 200 by using a spin coating method (Spin Coating). , to form a sacrificial material layer (not shown), and then use an etch-back method to remove the sacrificial material layer outside the trench 215 to form it.

然后,请参照图2D,以此牺牲层218为自行对准掩模,移除部分的介电层216。由于牺牲层218与介电层216的材质具有不同的蚀刻选择性,因此仅有牺牲层218下方的介电层216a会被保留下来,其余介电层216皆会被移除,而形成由介电层216a与牺牲层218所构成的牺牲堆栈层217。而且,在本实施例中,由于介电层216与掩模层210的材质为相同(例如皆为氮化硅),因此在移除部分介电层216的过程,同时移除掩模层210。Then, referring to FIG. 2D , using the sacrificial layer 218 as a self-alignment mask, part of the dielectric layer 216 is removed. Since the materials of the sacrificial layer 218 and the dielectric layer 216 have different etching selectivities, only the dielectric layer 216a below the sacrificial layer 218 will be retained, and the rest of the dielectric layer 216 will be removed to form a dielectric layer 216a. The sacrificial stack layer 217 formed by the electrical layer 216 a and the sacrificial layer 218 . Moreover, in this embodiment, since the dielectric layer 216 and the mask layer 210 are made of the same material (for example, both are silicon nitride), the mask layer 210 is removed at the same time during the process of removing part of the dielectric layer 216. .

继的,移除垫氧化层209a,以暴露出导体层208a。其中,垫氧化层209a的移除方法包括湿式蚀刻法,例如使用氢氟酸溶液作为蚀刻液。的后,于衬底200上形成导体层220。由于导体层220下方系已先形成有导体层208a,因此导体层220可更易形成于其上。此外,导体层220的材质例如是掺杂多晶硅,其形成方法例如是利用化学气相沉积法形成一层未掺杂多晶硅层(未绘示)后,进行离子注入步骤以形成之。Next, the pad oxide layer 209a is removed to expose the conductive layer 208a. Wherein, the removal method of the pad oxide layer 209a includes a wet etching method, such as using a hydrofluoric acid solution as an etching solution. After that, the conductor layer 220 is formed on the substrate 200 . Since the conductive layer 208a has been formed under the conductive layer 220, the conductive layer 220 can be formed on it more easily. In addition, the material of the conductive layer 220 is, for example, doped polysilicon, and its formation method is, for example, forming an undoped polysilicon layer (not shown) by chemical vapor deposition, and then performing ion implantation to form it.

之后,请参照图2E,移除部分的导体层220直到暴露出牺牲层218的顶部,且保留下来的导体层220a与导体层208a构成浮置栅极221。其中,移除部分的导体层220直到暴露出牺牲层218的顶部的方法例如是化学机械研磨法,且在研磨的过程中以与其具有不同蚀刻选择性的牺牲层218作为研磨终止层,因此所保留下来的导体层220a的厚度与牺牲堆栈层217的总高度有关。于是,浮置栅极221的厚度可以获得较好地控制。After that, referring to FIG. 2E , part of the conductive layer 220 is removed until the top of the sacrificial layer 218 is exposed, and the remaining conductive layer 220 a and the conductive layer 208 a form the floating gate 221 . Wherein, the method of removing part of the conductor layer 220 until the top of the sacrificial layer 218 is exposed is, for example, a chemical mechanical polishing method, and the sacrificial layer 218 having a different etching selectivity is used as the polishing stop layer during the polishing process, so the The thickness of the remaining conductive layer 220 a is related to the total height of the sacrificial stack layer 217 . Therefore, the thickness of the floating gate 221 can be better controlled.

此外,值得一提的是,先前于图2C中的沟槽215的侧壁上所形成的介电层216,其厚度会影响所形成的导体层220a的尺寸,进而影响浮置栅极221与控制栅极(未绘示)之间所夹的面积。因此在先前的步骤中,可以藉由形成较厚的介电层216来缩小沟槽215的宽度,进而缩小相邻二导体层220a之间的间距,而获得尺寸较大的导体层220a。举例来说,在图2C中,若沟槽215的原本的宽度W1为2000埃,二个沟槽215之间的掩模层210的宽度W2为1500埃,则在沉积500埃的介电层216后,此沟槽215的宽度W3会缩减为1000埃,而使得原本仅能形成宽度为1500埃(即掩模层的宽度W2)的导体层220a,形成如图2E所示的宽度W4为2500埃的导体层220a。因此可以藉由形成较厚的介电层216,来增加浮置栅极221与控制栅极之间所夹的面积,进而增加元件的效能。In addition, it is worth mentioning that the thickness of the dielectric layer 216 previously formed on the sidewall of the trench 215 in FIG. The area between the control gates (not shown). Therefore, in the previous step, the width of the trench 215 can be reduced by forming a thicker dielectric layer 216 , thereby reducing the distance between two adjacent conductor layers 220 a to obtain a conductor layer 220 a with a larger size. For example, in FIG. 2C, if the original width W1 of the trenches 215 is 2000 angstroms, and the width W2 of the mask layer 210 between the two trenches 215 is 1500 angstroms, then a dielectric layer of 500 angstroms is deposited. After 216, the width W3 of the trench 215 will be reduced to 1000 angstroms, so that only a conductor layer 220a with a width of 1500 angstroms (that is, the width W2 of the mask layer) can be formed, and the width W4 shown in FIG. 2E is formed as 2500 Angstroms of conductor layer 220a. Therefore, the area between the floating gate 221 and the control gate can be increased by forming a thicker dielectric layer 216, thereby increasing the performance of the device.

继之,请参照图2F,移除牺牲层218,此牺牲层218的移除方法包括湿式蚀刻法,例如使用氢氟酸溶液作为蚀刻液。值得一提的是,在上述形成浮置栅极的工艺中,先于元件隔离结构214上形成沟槽215,然后再依序于沟槽215中填入介电层216与牺牲层218,并且藉由介电层216a与牺牲层218所构成的牺牲堆栈结构217来形成浮置栅极221。因此利用本发明的方法可以省去浮置栅极的微影蚀刻工艺,进而节省工艺成本。Next, referring to FIG. 2F , the sacrificial layer 218 is removed. The removal method of the sacrificial layer 218 includes a wet etching method, such as using a hydrofluoric acid solution as an etching solution. It is worth mentioning that, in the above process of forming the floating gate, the trench 215 is first formed on the element isolation structure 214, and then the dielectric layer 216 and the sacrificial layer 218 are filled in the trench 215 in sequence, and The floating gate 221 is formed by the sacrificial stack structure 217 formed by the dielectric layer 216 a and the sacrificial layer 218 . Therefore, the lithographic etching process of the floating gate can be omitted by using the method of the present invention, thereby saving the process cost.

接着,于衬底200上形成栅极间介电层222,以覆盖介电层216a与浮置栅极221。其中,栅极间介电层222的材质例如是氧化硅/氮化硅/氧化硅,且其形成方法例如是先以热氧化法形成一层氧化硅层,再利用化学气相沉积法形成氮化硅层与另一层氧化硅层,而所形成的氧化硅/氮化硅/氧化硅的厚度例如是40埃至50埃/45埃至70埃/50埃至70埃。当然,栅极间介电层222的材质也可以是氧化硅/氮化硅等。Next, an inter-gate dielectric layer 222 is formed on the substrate 200 to cover the dielectric layer 216 a and the floating gate 221 . Wherein, the material of the inter-gate dielectric layer 222 is, for example, silicon oxide/silicon nitride/silicon oxide, and its formation method is, for example, to form a silicon oxide layer by thermal oxidation, and then form a nitride layer by chemical vapor deposition. A silicon layer and another silicon oxide layer, and the thickness of the formed silicon oxide/silicon nitride/silicon oxide is, for example, 40 angstrom to 50 angstrom/45 angstrom to 70 angstrom/50 angstrom to 70 angstrom. Certainly, the material of the inter-gate dielectric layer 222 may also be silicon oxide/silicon nitride or the like.

继之,于栅极间介电层222上形成控制栅极224。其中,控制栅极224的材质例如是掺杂多晶硅,且其形成方法例如是利用化学气相沉积法形成一整层未掺杂多晶硅层(未绘示)后,进行离子注入步骤以形成之。之后,于控制栅极224两侧的衬底200中分别形成源极区(未绘示)与漏极区(未绘示),其形成方法例如是进行离子注入步骤,以于控制栅极224两侧的衬底200中注入掺杂剂而形成之。而后续完成闪速存储器的工艺为本领域内的技术人员所公知,在此不再赘述。Next, a control gate 224 is formed on the inter-gate dielectric layer 222 . Wherein, the material of the control gate 224 is, for example, doped polysilicon, and its formation method is, for example, forming a whole layer of undoped polysilicon layer (not shown) by chemical vapor deposition, and then performing ion implantation to form it. Afterwards, a source region (not shown) and a drain region (not shown) are respectively formed in the substrate 200 on both sides of the control gate 224. The formation method is, for example, performing ion implantation steps, so that the control gate 224 It is formed by injecting dopants into the substrate 200 on both sides. The subsequent process for completing the flash memory is well known to those skilled in the art, and will not be repeated here.

值得注意的是,本发明除了上述的实施例外,在另一优选实施例中,在如图2D所示的移除垫氧化层209a的步骤之后,还包括先移除导体层208a,之后再依序进行形成导体层220以及后续如图2E与图2F所示的步骤,以完成闪速存储器的制作。如此所形成的闪速存储器其浮置栅极221仅由导体层220a所构成。另外,在又一优选实施例中,在如图2A所示的提供衬底200的步骤中,仅于衬底200上形成穿隧介电层206与掩模层210,因此所形成的闪速存储器其浮置栅极221同样仅由导体层220a所构成。此外,在另一优选实施例中,在如图2F所示的移除牺牲层218的步骤之后,还包括先移除介电层216a,再依序进行形成栅极间介电层222与控制栅极224等步骤,以完成闪速存储器的制作。It is worth noting that, in addition to the above-mentioned embodiment, in another preferred embodiment of the present invention, after the step of removing the pad oxide layer 209a as shown in FIG. The formation of the conductor layer 220 and the subsequent steps shown in FIG. 2E and FIG. 2F are performed sequentially to complete the fabrication of the flash memory. In the flash memory thus formed, the floating gate 221 is only composed of the conductive layer 220a. In addition, in yet another preferred embodiment, in the step of providing the substrate 200 as shown in FIG. The floating gate 221 of the memory is also only composed of the conductor layer 220a. In addition, in another preferred embodiment, after the step of removing the sacrificial layer 218 as shown in FIG. Gate 224 and other steps to complete the fabrication of the flash memory.

综上所述,本发明至少具有下面的优点:In summary, the present invention has at least the following advantages:

1.由于本发明在形成浮置栅极的过程中,先于元件隔离结构上形成沟槽,然后再依序于沟槽中填入介电层与牺牲层,并且藉由此介电层与此牺牲层所构成的牺牲堆栈结构来形成浮置栅极。因此利用本发明的方法可以省去制作浮置栅极的掩模,即可以减少一道微影蚀刻工艺,进而节省工艺成本。1. In the process of forming the floating gate, the present invention first forms a trench on the element isolation structure, and then fills the trench with a dielectric layer and a sacrificial layer in sequence, and through the dielectric layer and the sacrificial layer The sacrificial stack structure formed by the sacrificial layer is used to form the floating gate. Therefore, by using the method of the present invention, the mask for making the floating gate can be omitted, that is, one lithographic etching process can be reduced, thereby saving the process cost.

2.由于本发明所形成的浮置栅极其厚度与所形成的介电层与牺牲层的总高度有关,因此浮置栅极的厚度可藉由所形成的介电层与牺牲层的总高度来决定,于是浮置栅极的厚度可以获得较好地控制。2. Since the thickness of the floating gate formed in the present invention is related to the total height of the formed dielectric layer and the sacrificial layer, the thickness of the floating gate can be determined by the total height of the formed dielectric layer and the sacrificial layer To decide, so the thickness of the floating gate can be better controlled.

3.由于本发明可以藉由形成厚度较厚的介电层,以缩小沟槽的尺寸,进而形成尺寸较大的浮置栅极。因此控制栅极与浮置栅极之间所夹的面积可以提升,进而提升栅极耦合率,而使元件具有优选的效能。3. Because the present invention can reduce the size of the trench by forming a thicker dielectric layer, thereby forming a larger floating gate. Therefore, the area between the control gate and the floating gate can be increased, thereby increasing the gate coupling rate, so that the device has optimal performance.

4.由于本发明先形成穿隧介电层,再进行形成元件隔离结构等相关步骤。因此可以避免因先形成元件隔离结构,而于后续进行热工艺以形成穿隧介电层的过程中,造成在邻近元件隔离结构处形成鸟嘴,进而影响元件效能的问题。4. In the present invention, the tunneling dielectric layer is formed first, and then related steps such as forming an element isolation structure are performed. Therefore, it is possible to avoid the problem that bird's beaks are formed adjacent to the device isolation structure during the subsequent thermal process to form the tunneling dielectric layer due to the device isolation structure being formed first, thereby affecting device performance.

虽然本发明已结合优选实施例公开如上,然其并非用来限定本发明,任何本领域内的技术人员,在不脱离本发明的精神和范围内,当可作些许的更动与润饰,因此本发明的保护范围以所附权利要求所界定的为准。Although the present invention has been disclosed above in conjunction with preferred embodiments, it is not intended to limit the present invention. Any person skilled in the art may make some changes and modifications without departing from the spirit and scope of the present invention. Therefore The scope of protection of the present invention is defined by the appended claims.

Claims (20)

1. the manufacture method of a flash memory comprises:
One substrate is provided, is formed with a mask layer of a tunneling dielectric layer, one first conductor layer, a pad oxide and patterning on this substrate in regular turn;
This mask layer with patterning is a mask, removes this pad oxide of part, this first conductor layer, this tunneling dielectric layer and this substrate, to form a plurality of first grooves in this substrate;
In those first grooves, insert an insulating material, to form a plurality of component isolation structures;
Remove the part of each those component isolation structure, forming a plurality of second grooves, and the top of each those component isolation structure that is remained is between this tunneling dielectric layer and this mask layer;
On this substrate, form a dielectric layer, to cover the surface of this mask layer and those second grooves;
In those second grooves, insert a sacrifice layer;
With this sacrifice layer is an alignment mask voluntarily, removes this dielectric layer of part;
Remove this mask layer, to expose this pad oxide;
Remove this pad oxide, to expose this first conductor layer;
On this substrate, form one second conductor layer;
Remove this second conductor layer of part up to the top that exposes this sacrifice layer, and this second conductor layer and this first conductor series of strata constitute a floating grid;
Remove this sacrifice layer;
On this substrate, form a gate dielectric layer, to cover this floating grid;
On this gate dielectric layer, form a control grid; And
In this substrate of these control grid both sides, form an one source pole district and a drain region respectively.
2. the manufacture method of flash memory as claimed in claim 1, wherein this sacrifice layer has different etching selectivities with the material of this dielectric layer, and this sacrifice layer has different etching selectivities with the material of this second conductor layer.
3. the manufacture method of flash memory as claimed in claim 2, wherein the material of this sacrifice layer comprises silica.
4. the manufacture method of flash memory as claimed in claim 2, wherein the material of this dielectric layer comprises silicon nitride.
5. the manufacture method of flash memory as claimed in claim 1 wherein removes the method for this second conductor layer of part up to the top that exposes this sacrifice layer and comprises chemical mechanical milling method.
6. the manufacture method of flash memory as claimed in claim 1, wherein this dielectric layer is identical with the material of this mask layer, and in the process that removes this dielectric layer of part, removes this mask layer simultaneously.
7. the manufacture method of flash memory as claimed in claim 1, wherein after removing this sacrifice layer with form before this gate dielectric layer, also comprise removing this dielectric layer.
8. the manufacture method of flash memory as claimed in claim 1, wherein the formation method of those second grooves comprises the etch-back method of utilizing dry ecthing to carry out.
9. the manufacture method of flash memory as claimed in claim 1, wherein after removing this pad oxide with form before this second conductor layer, also comprise removing this first conductor layer, and formed this floating grid is made of this second conductor layer.
10. the manufacture method of a floating grid comprises:
One substrate is provided, and this substrate includes a plurality of component isolation structures defining an active area, and is formed with a tunneling dielectric layer and a mask layer in regular turn on this substrate of this active area;
Remove the part of each those component isolation structure, forming a plurality of grooves, and the top of each those component isolation structure that is remained is between this tunneling dielectric layer and this mask layer;
On this substrate, form a dielectric layer, to cover the surface of this mask layer and those grooves;
In those grooves, insert a sacrifice layer;
With this sacrifice layer is an alignment mask voluntarily, removes this dielectric layer of part;
Remove this mask layer, to expose this tunneling dielectric layer;
On this substrate, form one first conductor layer;
Remove this first conductor layer of part up to the top that exposes this sacrifice layer; And
Remove this sacrifice layer.
11. the manufacture method of floating grid as claimed in claim 10, wherein this sacrifice layer has different etching selectivities with the material of this dielectric layer, and this sacrifice layer has different etching selectivities with the material of this first conductor layer.
12. the manufacture method of floating grid as claimed in claim 11, wherein the material of this sacrifice layer comprises silica.
13. the manufacture method of floating grid as claimed in claim 11, wherein the material of this dielectric layer comprises silicon nitride.
14. the manufacture method of floating grid as claimed in claim 10 wherein removes the method for this first conductor layer of part up to the top that exposes this sacrifice layer and comprises chemical mechanical milling method.
15. the manufacture method of floating grid as claimed in claim 10, wherein this dielectric layer is identical with the material of this mask layer, and in the process that removes this dielectric layer of part, removes this mask layer simultaneously.
16. the manufacture method of floating grid as claimed in claim 15, wherein the material of this dielectric layer and this mask layer comprises silicon nitride.
17. the manufacture method of floating grid as claimed in claim 10, wherein the formation method of those grooves comprises the etch-back method of utilizing dry ecthing to carry out.
18. the manufacture method of floating grid as claimed in claim 10 wherein after removing this sacrifice layer, also comprises removing this dielectric layer.
19. the manufacture method of floating grid as claimed in claim 10, wherein also comprise between this tunneling dielectric layer of this substrate that is provided and this mask layer and be formed with one second conductor layer and a pad oxide in regular turn, and after removing this mask layer with form before this first conductor layer, also comprise removing this pad oxide, to expose this second conductor layer.
20. the manufacture method of floating grid as claimed in claim 19, wherein after removing this pad oxide with form before this first conductor layer, also comprise removing this second conductor layer.
CNB200410031578XA 2004-03-25 2004-03-25 Manufacturing method of flash memory Expired - Fee Related CN1309055C (en)

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CN100524699C (en) * 2006-05-12 2009-08-05 旺宏电子股份有限公司 Flash memory and manufacturing method thereof
CN100536106C (en) * 2006-01-19 2009-09-02 力晶半导体股份有限公司 Method for manufacturing conductive wire

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Publication number Priority date Publication date Assignee Title
TW337044B (en) * 1994-11-28 1998-07-21 At & T Corp Method for manufacturing source/drain formation for flash EEPROM capable of avoiding electrical shorting
KR100255512B1 (en) * 1996-06-29 2000-05-01 김영환 Flash memory device manufacturing method
JP3564420B2 (en) * 2001-04-27 2004-09-08 三菱重工業株式会社 gas turbine
KR100426483B1 (en) * 2001-12-22 2004-04-14 주식회사 하이닉스반도체 Method of manufacturing a flash memory cell

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Publication number Priority date Publication date Assignee Title
CN100536106C (en) * 2006-01-19 2009-09-02 力晶半导体股份有限公司 Method for manufacturing conductive wire
CN100524699C (en) * 2006-05-12 2009-08-05 旺宏电子股份有限公司 Flash memory and manufacturing method thereof

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